EP3059344A1 - Procédé de fabrication de papier comprenant de la pâte à papier blanchie de manière chimique, thermique et mécanique convenant à une doublure de libération et produits et utilisations associés - Google Patents

Procédé de fabrication de papier comprenant de la pâte à papier blanchie de manière chimique, thermique et mécanique convenant à une doublure de libération et produits et utilisations associés Download PDF

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EP3059344A1
EP3059344A1 EP16397503.0A EP16397503A EP3059344A1 EP 3059344 A1 EP3059344 A1 EP 3059344A1 EP 16397503 A EP16397503 A EP 16397503A EP 3059344 A1 EP3059344 A1 EP 3059344A1
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Prior art keywords
paper
pulp
bleached
equal
range
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EP3059344B1 (fr
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Janne ANTILA
Jukka KOTILAINEN
Jussi LEINONEN
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UPM Specialty Papers Oy
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UPM Kymmene Oy
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/001—Release paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed

Definitions

  • the invention relates to a method for obtaining low weight high quality paper comprising bleached chemithermomechanical pulp, the paper suitable for use as a layer of a release liner.
  • the invention further relates to low weight high quality paper comprising bleached chemithermomechanical pulp, the paper suitable for use as a layer of a release liner.
  • the invention further relates to a method for manufacturing bleached chemithermomechanical pulp, which is suitable for use in a layer of a release liner.
  • the invention further relates to use of bleached chemithermomechanical pulp when manufacturing paper suitable for use as a layer of a release liner.
  • the invention further relates to use of bleached chemithermomechanical pulp in a release liner.
  • a release liner refers to a product comprising a substrate layer and a release coating, such as a silicon polymer based compound, applied on at least one side of the substrate layer.
  • the substrate layer comprises a support layer and a primer layer applied on at least one side of the support layer.
  • the support layer is made of paper comprising cellulose fibers from bleached chemical pulp, such as bleached Kraft pulp.
  • the substrate layer comprises a surface sized or coated layer applied on the paper.
  • the amount of hardwood in the paper manufacturing process is typically high, in order to obtain release liner having a high transparency level.
  • a particular use for a release liner is as backing material in labelling applications with adhesive labels.
  • Adhesive labels may be, for example, self-adhesive labels or pressure sensitive labels.
  • a release liner comprising a plurality of adhesive labels is typically wound on a roll and used in a labelling process.
  • the number of products to be labelled in a labelling process may be very large.
  • a roll of release liner may comprise even several kilometres of winded release liner.
  • a substrate layer for a release liner is transported from a paper manufacturer to a label manufacturer, wherein a release coating may be applied on the substrate layer, thereby finishing the release liner, on which the label stock is manufactured.
  • the label stock comprising the release liner may be further transported to an end user prior to labelling of products.
  • a single roll of release liner should therefore be manufactured in a manner configured to reduce the life cycle costs of the release liner, without reducing the quality of the release liner for the intended purpose.
  • release liner manufacturing there is a demand for a lighter release liner roll weight, which would reduce the costs of transportation, as described above.
  • the release liner should withstand the functional requirements set by the end purpose, such as a labelling system.
  • the mechanical properties of the release liner such as surface smoothness, surface density and tearing resistance, should be suitable for the release liner to function properly.
  • the substrate layer is coated by applying a silicone based release coating on the substrate layer in a quantity of equal to or less than 2 g/m 2 per side, to provide a functional release coating on the substrate layer.
  • the specific volume and tearing resistance of a conventional paper are typically also reduced.
  • the smoothness of the paper surface may thus decrease, which has a negative effect on the subsequent release coating.
  • An option to improve the surface smoothness could be to calender the paper more. Calendering, however, further reduces the specific volume and the paper thickness. Reduction in the paper thickness may lead to problems in the label manufacturing process, as the stencils used to die cut the label stock are typically designed to operate at predefined paper thickness. This would necessitate new stencils to replace the previously used stencils, which would be an extra cost and extra operation for a label manufacturer.
  • Chemithermomechanical pulp may be manufactured by a hybrid process wherein wood chips are first pretreated with chemicals, heated for a short period and subsequently refined by mechanical means.
  • the manufacturing method of chemithermomechanical pulp produces high yield pulp, typically having a yield in the range of 80 to 95 wt.-%, wherein compounds other than cellulose fibers present in the wood material have been preserved to a large extent.
  • Bleached chemithermomechanical pulp may be obtained from the chemithermomechanical pulp by bleaching with chemicals, such as sodium hydroxide and/or hydrogen peroxide.
  • Bleached chemithermomechanical pulp has high light scattering properties in paper.
  • Bleached chemithermomechanical pulp has conventionally been used in paper manufacturing to increase stiffness and opacity, which in release liners is undesired.
  • bleached chemithermomechanical pulp differ from bleached chemical pulp, such as Kraft pulp.
  • Bleached chemithermomechanical pulp may be configured to increase the amount of cellulose fibers in a specific volume of the paper, without increasing the grammage of the paper.
  • a paper comprising bleached chemithermomechanical pulp may have the same thickness as a paper comprising only bleached chemical pulp, but wherein the grammage has been reduced compared to the paper comprising only bleached chemical pulp, while preserving the density of the paper sufficient for a release coating.
  • bleached chemithermomechanical pulp may be configured to increase the bulk of the paper, while maintaining a desired ratio between the grammage and thickness of the paper.
  • the composition of the bleached chemithermomechanical pulp may be configured to increase the bulk of the paper such that sufficient transparency of the paper is maintained. This enables providing paper suitable for existing labelling processes, wherein less raw materials, when measured by the weight of the raw materials, may be used for manufacturing paper having the same thickness as earlier.
  • the formed paper has a lighter mass per unit area and a sufficient quality such as transparency, surface smoothness and strength, for a subsequent release coating.
  • Bleached chemithermomechanical pulp may thus be used to change the ratio of the bulk to the grammage in the paper, such that the density of the paper surface remains suitable for release coating purposes.
  • Bleached chemithermomechanical pulp may further be used to replace at least some of bleached chemical pulp, such as bleached Kraft pulp, in the paper.
  • bleached chemithermomechanical pulp may be arranged to have a composition configured to optimize the process conditions of a paper manufacturing process, where said bleached chemithermomechanical pulp is used.
  • bleached chemithermomechanical pulp may comprise cellulose fibers from both hardwood and softwood.
  • Bleached chemithermomechanical pulp comprising a mixture of hardwood and softwood may be used to improve the manufacturing process conditions of paper comprising bleached chemithermomechanical pulp, such that the production time of the paper on the machine may be extended.
  • bleached chemithermomechanical pulp comprising a mixture of hardwood and softwood may be used to improve the internal bond strength of the paper web during manufacturing process.
  • bleached chemithermomechanical pulp comprising a mixture of hardwood and softwood may be used to reduce the brittleness of paper formed from the paper web during manufacturing process.
  • the method of manufacturing bleached chemithermomechanical pulp may thus be used to obtain a pulp composition comprising a blend of cellulose fibers of different origin.
  • the bleached chemithermomechanical pulp may be manufactured in an alkaline pH, such as equal to or higher than pH 7, to improve the runnability of the paper manufacturing process.
  • an amount of said pulp composition is added to a pulp mixture used in forming a paper web, the runnability of the paper web on the paper machine may be improved, such that the manufacturing process of the paper may be continued longer, such as several days or even weeks.
  • the composition of the bleached chemithermomechanical pulp may be used to improve paper quality, such as the tearing strength of the paper manufactured on the machine.
  • the presence of softwood fraction, such as spruce, in the bleached chemithermomechanical pulp has been observed to improve the characteristics of the bleached chemithermomechanical pulp in the paper manufacturing process.
  • the percentage of the softwood in the bleached chemithermomechanical pulp may be varied.
  • the amount of bleached chemithermomechanical pulp in a pulp mixture used for making paper suitable for a release liner layer may be varied.
  • the proportion of bleached chemithermomechanical pulp in the pulp mixture the specific volume of paper formed from the pulp mixture may be changed.
  • the density of the paper may be configured to decrease as a function of the content of the bleached chemithermomechanical pulp in the paper.
  • a pulp mixture may comprise cellulose fibers of bleached chemithermomechanical pulp equal to or less than 50 wt.-% of the weight of the paper.
  • the bleached chemithermomechanical pulp may be used for example in a range of 1 to 50 wt.-%, such in the range of 5 to 45 wt.-%, or in the range of 10 to 35 wt.-%.
  • a bleached chemithermomechanical pulp may comprise softwood equal to or less than 50 wt.-% of the bleached chemithermomechanical pulp.
  • bleached chemithermomechanical pulp comprising softwood
  • Bleached chemithermomechanical pulp may comprising softwood for example in a range of 1 to 50 wt.-%, such in the range of 5 to 45 wt.-%, or in the range of 10 to 35 wt.-%.
  • the use of bleached chemithermomechanical pulp comprising both aspen and spruce enables production of paper suitable for release liner layer, where the ratio of the bulk to the grammage in the paper has been increased.
  • the paper manufacturing process may be configured to use less refining, which saves energy.
  • the paper surface may further be calendered into a desired thickness, such that the ratio of grammage to thickness of the paper in micrometres is maintained at a level equal to or higher than 1.0.
  • This enables manufacturing of low grammage paper, which has a high surface density suitable for a release coating, and a thickness equal to or less than 100 micrometers, preferably equal to or less than 80 micrometers, most preferably equal to or less than 60 micrometres.
  • Due to high surface density also the amount of other raw materials beside fibers, such as primer layer pigments and additives used in the release liner manufacturing process, may be reduced.
  • the surface density in this context refers to the smoothness and/or porosity of paper surface determinable by the Bekk method (ISO 5627 standard).
  • a paper suitable for use as a layer of a release liner having density equal to or less than 1200 kg/m 3 , preferably in the range of 1000 to 1200 kg/m 3 , most preferably in the range of 1050 to 1150 kg/m 3 , the paper having a ratio of grammage to thickness of the paper in micrometres equal to or higher than 1.0, wherein the grammage refers to the weight of the paper in grams per square meter, the paper comprising cellulose fibres from
  • a method for manufacturing paper suitable for use as a layer of a release liner comprising:
  • a paper suitable for use as a layer of a release liner and/or a method for manufacturing paper suitable for use as a layer of a release liner the paper further having a transparency level of equal to or higher than 28%.
  • the paper further comprises cellulose fibers of bleached chemithermomechanical pulp equal to or less than 50 wt.-% of the weight of the paper, such as in the range of 1 to 50 wt.-%, preferably in the range of 5 to 45 wt.-%, most preferably in the range of 10 to 35 wt.-%.
  • the bleached chemithermomechanical pulp further comprises softwood equal to or less than 50 wt.-%, such as in the range of 1 to 50 wt.-%, preferably in the range of 5 to 45 wt.-%, most preferably in the range of 10 to 35 wt.-%.
  • a paper suitable for use as a layer of a release liner having a grammage equal to or higher than 30 grams per square meter and a transparency level of equal to or higher than 28%, the paper comprising cellulose fibers from bleached chemical pulp and bleached chemithermomechanical pulp made of hardwood and softwood, wherein the amount of cellulose fibers in a specific volume of the paper is increased by the bleached chemithermomechanical pulp such that the density of the paper is equal to or less than 1200 kg/m 3 , preferably in the range of 1000 to 1200 kg/m 3 , most preferably in the range of 1050 to 1150 kg/m 3 , and the ratio of grammage to thickness of the paper in micrometers is equal to or higher than 1.0.
  • a method for manufacturing paper suitable for use as a layer of a release liner comprising:
  • a paper suitable for use as a layer of a release liner comprising cellulose fibers from bleached chemical pulp and bleached chemithermomechanical pulp, wherein the bleached chemithermomechanical pulp comprises cellulose fibres from hardwood and softwood, and the bleached chemithermomechanical pulp is configured to increase the ratio of the bulk to the grammage in the paper, such that the ratio of grammage to thickness of the paper in micrometres is equal to or higher than 1.0, wherein the grammage refers to the weight of the paper in grams per square meter.
  • a method for manufacturing paper suitable for use as a layer of a release liner comprising:
  • a method for manufacturing bleached chemithermomechanical pulp comprising cellulose fibers from hardwood and softwood, the method comprising:
  • Sx and Sz represent coordinate directions orthogonal to each other.
  • a release liner support layer in this context refers to paper comprising cellulose fibers, which has been manufactured on a paper machine.
  • a release liner substrate layer in this context refers to paper comprising a primer layer, such as a sizing layer or a coating layer, applied on at least one side of the paper.
  • a release liner in this context refers to paper comprising a release coating applied on at least one side of the paper.
  • the paper is typically manufactured of cellulose fibers containing pulp, wherein the pulp originates from wood. Wood species differ from each other in their mechanical properties and chemical compositions. Wood species typically used in paper manufacturing may be divided into two main groups denoted as softwood and hardwood, wherein hardwoods have a more complex structure than softwoods.
  • deciduous and/or angiosperm trees are typically hardwood, whereas coniferous trees are typically softwood.
  • Softwood and hardwood have distinguished mechanical characteristics and chemical composition, which differ from each other. By selection of the wood species and the wood processing method, different types of pulp having different qualities may be obtained. Softwood and hardwood therefore may be used to provide different pulp compositions, each composition having a different purpose in paper manufacturing.
  • the wood material is first chipped and further processed into more fibrous form by mechanical or chemical method.
  • wood is typically treated in a chemical process, such as Kraft process, to separate cellulose fibers from the other compounds and to obtain essentially wood free pulp comprising cellulose fibers.
  • a high transparency level of the paper is desirable. Bleaching is typically used to improve the brightness and whiteness of the pulp and to remove any remaining compounds from the pulp, such as lignin, which may cause darkening of the pulp.
  • a paper suitable for a release liner layer typically has a transparency level of equal to or higher than 40%, preferably equal to or higher than 60%, such as in the range of 40% to 85%, when grammage is less than 70 grams per square meter.
  • a paper suitable for a release liner support layer typically has a transparency level of equal to or higher than 28%, preferably equal to or higher than 33%, such as in the range of 28% to 85%, when grammage is equal to or higher than 70 grams per square meter.
  • the paper support for release liner support layer may have been made essentially of bleached chemical pulp, such as bleached Kraft pulp.
  • the combination of bleached chemical pulp comprising hardwood and softwood may also be used to improve the burst strength and tensile strength of the paper.
  • the processing method while providing strong cellulose fibers from bleached chemical pulp, however, requires large amounts of wood.
  • the bleached chemical pulp is furthermore generally refined to a high level, to improve the smoothness and density of the paper surface, which is a cost factor in manufacturing.
  • a drawback of the refining is, that while reduction of the average fiber length of the cellulose fibers in the pulp improves the subsequent surface density of a paper, refining also decreases the specific volume of the formed paper, as shorter fibers may be packed closer in the paper web. Refining also increases the moisture uptake of the pulp, such that larger amounts of water needs to be removed from the paper web. The refining requires energy, which also increases the production costs.
  • cellulose pulp refers to material originating from wooden material, which has been processed into fibrous form, such as fibers.
  • the cellulose pulp may have been obtained via mechanical methods, chemical methods, or by using a semi-chemical method, wherein a combination of mechanical and chemical methods is used.
  • Chemical pulp refers to cellulose pulp obtained from a process wherein fibers have been produced through chemical methods. Chemical pulp may be bleached to form bleached chemical pulp. When forming chemical pulp, heat and chemicals are used to break down lignin, which binds the cellulose fibers together, such that the cellulose fibers are degraded to a less degree than in mechanical pulp. Chemical methods may be used to provide fibers having increased strength. Chemical pulp is typically stronger than pulp produced via other methods. Examples of a chemical methods are, for example, Sulphite process and Kraft process. Kraft process uses sodium sulphide to separate cellulose fibers from other compounds in the wood material. Unbleached kraft pulp typically has a dark brown color. For release paper purposes, unbleached chemical pulp is bleached to further remove residual lignin, which increases the pulp whiteness and brightness, and improves the transparency of paper made of the bleached chemical pulp.
  • Mechanical pulp refers to cellulose pulp obtained from a process wherein fibers have been produced through mechanical methods.
  • An example of a mechanical method is, for example, grinding-stone ground wood (SGW). When the wood is steamed prior to grinding it is known as pressure ground wood pulp (PGW). Steam treatment may be used to reduce the amount of energy needed in pulping and to decrease the mechanical damage of the process to the fibers.
  • SGW grinding-stone ground wood
  • PGW pressure ground wood pulp
  • Steam treatment may be used to reduce the amount of energy needed in pulping and to decrease the mechanical damage of the process to the fibers.
  • mechanical pulping typically gives a higher yield of cellulose in a pulp form.
  • the yield of mechanical pulp may be in the range of 85 to 95 wt.-% of the raw material.
  • mechanical pulp contains large amount of fine particles, hemicellulose and lignin compounds.
  • Mechanical pulp therefore has a high opacity level.
  • Mechanical pulp may also have limited brightness, at least compared to chemical pulps. Mechanical pulp containing lignin compounds may react with light and oxygen, which leads to darkening of the pulp colour, denoted as photo yellowing. Mechanical pulp has a broad fiber size distribution, which may be used to improve paper surface smoothness. Mechanical pulp may also be used to improve the bulk of the paper. The tensile and tear strength of mechanical pulp is relatively weak; as such it typically is not suitable for release liners.
  • thermomechanical pulp is pulp produced by processing wood chips using heat and a mechanical refining.
  • thermomechanical pulping mechanical force such as crushing or grinding is applied to wood chips having a moisture content in the range of 25 to 30 wt.-%, such that heat and water vapour is generated, which softens the lignin in the chips such that the chips are separated into fibers.
  • the pulp may be then screened and cleaned, and the operation may be repeated to remaining chips until a desired fibrillation level is obtained.
  • the yield of thermomechanical pulp may be in the range of 85 to 95 wt.-% of the raw material.
  • the aim is to facilitate the refining of the fibers, not to remove lignin. Due to the lignin present in the thermomechanical pulp, the fibers are hard and rigid.
  • Chemithermomechanical pulp is a hybrid process wherein the wood chips are first pretreated by applying chemicals on the chips and then refined to pulp by mechanical means.
  • chemithermomechanical pulping wood chips are pretreated with sodium carbonate, sodium hydroxide, sodium sulphite and/or other chemicals prior to mechanical refining, such that heat and water vapour is generated, which softens the lignin in the chips such that the chips are separated into fibers.
  • the mechanical refining may be done with equipment similar to used when obtaining mechanical pulp.
  • the conditions of the chemical treatment are less vigorous than in a chemical pulping process. Typically, a lower temperature, shorter duration and less extreme pH is used.
  • thermomechanical pulp the aim is to facilitate the refining of the fibers, not to remove lignin.
  • Chemithermomechanical pulp therefore may comprise lignin and other wood originating compounds in addition to cellulose fibers.
  • BCTMP Bleached chemithermomechanical pulp
  • the chemicals used to bleach pulp may comprise various oxidising compounds such as chlorine dioxide, oxygen, ozone and/or hydrogen peroxide.
  • Thickness of a paper refers to the apparent thickness, determined as single sheet thickness of a paper according to ISO 534:2011.
  • a release coating is applied on a support layer
  • the thickness of the paper denotes the final thickness of the support layer in micrometers.
  • a release coating is applied on a substrate layer
  • the thickness of the paper denotes the final thickness of the substrate layer comprising the support layer in micrometers.
  • the final thickness denotes the thickness of a substrate or support layer after a calendering treatment prior to applying a release coating, when calendering is used such that the thickness of the support or substrate layer is reduced, respectively.
  • papers used in release liners are calendered to a final thickness before forming a release liner by applying the release coating.
  • the final thickness refers to the thickness of the substrate or the support layer, respectively.
  • the thickness of a paper is also referred to as the caliper of a paper. The thickness is expressed in micrometers ( ⁇ m).
  • a paper manufactured on a paper machine has compressibility and inhomogeneity, therefore the thickness may be given as an averaged value of several measurements results from a paper sample, as described in the standard ISO 534.
  • the thickness of a paper is related to the grammage of paper. To compare the thickness of papers with different grammage, the specific volume may be used.
  • Thickness of a release liner refers to the apparent thickness, determined as single sheet thickness of a paper according to ISO 534:2011, of the release liner comprising the layers present in the release liner.
  • the release liner comprises a release coating and a substrate layer, wherein the substrate layer comprises a support layer and one or more primer layers.
  • the release liner may comprises a release coating and a support layer without a primer layer.
  • the thickness of a release liner refers to the apparent thickness of the release liner comprising the release coating and the support layer.
  • the thickness of the substrate layer and/or support layer may be determined by subtracting the thickness of the release coating from the thickness of the release liner.
  • Specific volume denoted as bulk, is measured as volume per unit mass, typically expressed in cubic centimeters per gram (cm 3 /g). Specific volume in this context refers to apparent specific sheet volume. Specific volume therefore represents inverse of the paper density. Paper density in this context refers to mass per unit volume of a paper, typically expressed in kilograms per cubic meters (kg/m 3 ). The specific volume and density are calculated from a single sheet thickness of paper according to ISO 534:2011. The density of a paper comprising bleached chemithermomechanical pulp may be equal to or less than 1200 kg/m 3 , preferably in the range of 1000 to 1200 kg/m 3 , most preferably in the range of 1050 to 1150 kg/m 3 .
  • Paper grammage in this context refer to the basis weight of the paper, given in grams per square meter (g/m 2 ) of very smooth paper types, such as glassine paper or super calendared paper.
  • the paper types comprising bleached chemithermomechanical pulp suitable for a release liner preferably have a grammage equal to or less than 120 g/m 2 , preferably equal to or less than 80 g/m 2 , most preferably equal to or less than 70 g/m 2 .
  • paper types comprising bleached chemithermomechanical pulp suitable for a release liner preferably have a grammage equal to or higher than 30 g/m 2 , such as equal to or higher than 40 g/m 2 , for example in the range of, 30 to 120 g/m 2 , or in the range of, 40 to 100 g/m 2 .
  • paper types comprising bleached chemithermomechanical pulp, and having a grammage in the range of 40 to 80 g/m 2 most preferably in the range of 50 to 70 g/m 2 , benefit of the increase in bulk.
  • Roughness of the paper can be determined by Parker Print-Surf (PPS) method according to ISO 8791, for example by using a PPS tester.
  • PPS Parker Print-Surf
  • a PPS tester uses a contact air leak principle, which measures airflow between substrate in a ring having an aperture.
  • Paper water absorptiveness can be given as Cobb values determined according to ISO 535.
  • the standard specifies a method of determining the water absorptiveness of sized paper under standard conditions.
  • Fiber furnish analysis according to ISO standards ISO 9184-1 and 9184-4:1990 may be used in identification of papermaking fibers from a paper.
  • the analysis may be used, for example, to distinguish cellulose fibers produced by chemical, semi-chemical, such as chemithermomechanical, or mechanical method from each other.
  • the analysis may further be used, for example, in differentiation of cellulose fibers produced by kraft or sulphite process in hardwood pulps and in differentiation of cellulose fibers from softwood and hardwood from each other.
  • Metso Fiber Image Analyzer (Metso FS5) is an example of a device, which can be used according to the manufacturer's instructions to perform the fiber furnish analysis.
  • a high resolution camera may be used to acquire a greyscale image of a sample, of which image the properties of the fibers in the sample may be determined.
  • the greyscale image may be acquired from a sample placed in a transparent sample holder, such as a cuvette, using a 0.5 millimetre depth of focus according to ISO 16505-2 standard.
  • the wood species used in a paper may be distinguished by comparison method, wherein a sample fiber is compared against a known reference fiber. Fiber length may be determined according to ISO 16065-N.
  • a paper suitable for use as a layer of a release liner refers to paper manufactured on a paper machine.
  • paper quality and suitability for coating with a silicon polymer based compound i.e. release coating
  • Bekk method may be used for determining the smoothness and/or porosity of paper for release liner.
  • ISO 5627 standard may be used.
  • Gurley method may be used for determining the air permeability of paper.
  • ISO 5636-5:2013 standard may be used.
  • a paper suitable for release liner are smoothness of at least 900 sec/min (ISO 5627), density of at least 1.0, such as in the range of 1.0 to 1.2, wherein the density refers to grammage (ISO536) per thickness (ISO534), porosity equal to or less than 15000 pm/Pas (ISO11004) and transparency of equal to or higher than 40%, preferably equal to or higher than 44% when the paper grammage is less than 70 g/m 2 , or equal to or higher than 28%, preferably equal to or higher than 33% when the paper grammage is equal to or higher than 70 g/m 2 (ISO2470), the parameter values corresponding to ISO standards referred in parentheses.
  • paper types lending themselves for release liner applications are vegetable parchment, greaseproof paper, coated papers and glassine. Of these, glassine is preferred for industrial manufacturing of high quality release liner, due to the mechanical properties of the paper obtained in the manufacturing process.
  • Vegetable parchment paper is a paper typically made of waterleaf sheet (unsized sheet of paper, made from chemical wood pulp) by treating it in a bath of sulfuric acid. The treated paper is washed thoroughly to remove the acid and then dried. This chemical treatment forms a very tough, stiff paper with an appearance similar to a genuine parchment. However, paper treated in this manner has a tendency to become brittle and to wrinkle upon drying.
  • Vegetable parchment is therefore often treated with a plasticizing agent, such as glycerine or glucose.
  • Coated papers comprise variety of papers, having in common a coating layer applied on the paper surface and then calendered to modify the surface properties of the product.
  • Coated paper which may be used as release liner is typically woodfree coated paper, made of chemical pulp, such as Kraft pulp. A coat weight in the range of 5 to 12 g/m 2 per side is generally used.
  • the coating layer typically comprises pigments, such as calcium carbonate and/or kaolin and binders, such as starch, polyvinyl alcohol and/or latex.
  • Glassine is widely used in release liner for self-adhesive materials.
  • Glassine is paper typically made of bleached chemical pulp, having a grammage in the range of 30 to 160 g/m 2 .
  • Glassine used for manufacturing a release liner is coated with a primer layer which is compatible with a silicone polymer based release coating.
  • a primer layer coating in the range of 1 to 10 g/m 2 per side, typically in the range of 2 to 5g/m 2 per side, is used.
  • a mixture used to form a primer layer for glassine may comprise water soluble binders such as starch, polyvinyl alcohol and/or carboxymethyl cellulose.
  • the pulp When producing glassine paper, the pulp is refined to obtain a fiber fineness, which enables a dense, nearly unporous, paper surface to be obtained. Such a surface is resistant to air and liquids such as oil and water.
  • the pulp slurry When manufacturing glassine paper, the pulp slurry is first refined to a high level, the formed paper web is then pressed and dried, and a primer layer coating is applied on the paper web surface.
  • Glassine is calendered with a multi-nip calender or a supercalender before or after applying the primer layer, to obtain a product having high density surface, high impact strength, high tear resistance and transparency. Glassine, however, has a lower dimensional stability than a conventional coated paper. Therefore, shrinkage of the formed fiber web when manufacturing glassine paper is higher than with conventional coated paper.
  • Greaseproof paper is similar to glassine in grammage. The main difference between greaseproof paper and glassine is in the calendering treatment. While glassine is typically supercalendered, greaseproof paper is not. Hence, greaseproof paper has a diminished tearing resistance when compared to glassine.
  • Figure 1 a shows, by way of an example, a three-dimensional structure of a paper PAP1 manufactured on a paper machine on a machine direction DIR MD , which refers to the travelling direction of the paper web and paper on the machine.
  • the properties of the paper may be different in the machine direction and in a direction perpendicular to the machine direction along the surface of the paper.
  • the paper PAP1 may be used as a support layer SUP1, for a release liner.
  • the paper PAP1 surface may be coated, for example by applying a size coating on at least one side of the paper. When the paper PAP1 is uncoated, the thickness of the paper may be equal to the thickness D SUP1 of the support layer SUP1.
  • the paper PAP1 may be coated by a first primer layer PL1 and/or by a second primer layer PL2.
  • the first primer layer PL1 and the second primer layer PL2 may be located on opposite sides of the paper.
  • the thickness of the paper may be equal to the combined thickness of the support layer D SUP1 and the primer layer D PL1 .
  • the thickness of the paper PAP1 may be equal to the combined thickness of the support layer D SUP1 and the primer layers D PL1 , D PL2 .
  • the thickness of the paper PAP1 refers to the apparent thickness D app of a single sheet of a paper after calendering to a final thickness, measured according to ISO 534:2011 as described above.
  • a release liner comprising bleached chemithermomechanical pulp
  • the grammage of the paper is typically equal to or less than 120 g/m 2 .
  • the grammage may be, for example, equal to or less than 80g/m 2 , preferably equal to or less than 70 g/m 2 , such as in the range of 30 to 120 g/m 2 .
  • the grammage of the paper may be in the range of 35 to 80g/m 2 , most preferably in the range of 50 to 70 g/m 2 .
  • a paper manufactured to have a grammage higher than 70 g/m 2 typically has a transparency level of equal to or higher than 28%, preferably equal to or higher than 33%, such as in the range of 28% to 85%.
  • a paper manufactured to have a grammage equal to or less than 70 g/m 2 typically has a transparency level of equal to or higher than 40%, preferably equal to or higher than 45%, most preferably equal to or higher than 60%, such as in the range of 40% to 85%.
  • the grammage of the paper is to a large extent defined already when the paper web is formed on the paper machine, when the pulp slurry is fed to the wire.
  • the bleached chemithermomechanical pulp is mixed with bleached chemical pulp, such that a pulp mixture comprising bleached chemical pulp and bleached chemithermomechanical pulp is formed.
  • the presence of the bleached chemithermomechanical pulp in the pulp mixture changes the composition of the pulp mixture such that the bulk of paper formed from the pulp mixture is increased.
  • Bleached chemithermomechanical pulp comprises different fiber length distribution and higher stiffness compared to bleached chemical pulp.
  • Bleached chemithermomechanical pulp may therefore be arranged to increase the specific volume per unit area of the forming paper web.
  • bleached chemithermomechanical pulp can be used to increase the ratio of the paper bulk to the grammage of the paper, when compared to similar paper made of only bleached chemical pulp.
  • bleached chemithermomechanical pulp can be configured to increase the bulk such that the grammage of the paper can be decreased, while maintaining the thickness of the paper in micrometres at the same level as in a paper made of only bleached chemical pulp.
  • Bleached chemithermomechanical pulp can therefore be used to produce paper having the same thickness in micrometers, but less grammage as paper made of only bleached chemical pulp.
  • Bleached chemithermomechanical pulp typically comprises a fiber length distribution, wherein the content of fine particles is increased in comparison to a similar bleached chemical pulp.
  • Mechanical refining increases the amount of fine particles, i.e. particles such as fibers typically having a fiber length equal to or less than 0.6 millimeters.
  • the amount of fibers in a specific volume in a formed paper web may therefore increase.
  • the increased amount of fine particles also enables maintaining the paper surface density sufficient, such that similar or even less amounts of release coating can be used on the paper comprising bleached chemithermomechanical pulp, as with paper made of only bleached chemical pulp.
  • the bleached chemithermomechanical pulp provided means to increase the ratio of the bulk to the grammage in the paper, such that the ratio of grammage to thickness of the paper in micrometres could be retained equal to or higher than 1.0.
  • Figure 1 b shows, by way of an example, a method for manufacturing paper PAP1 comprising bleached chemithermomechanical pulp BCTMP, the paper PAP1 suitable for use as a layer of a release liner REL1.
  • a pulp mixture MIX1 comprising cellulose fibers may be formed by mixing 1 together different pulps. The mixing may be performed, for example by homogenising pulp mixture MIX1 in a mixer.
  • the pulp mixture MIX1 may comprise bleached chemical pulp PULP1, PULP2 and bleached chemithermomechanical pulp BCTMP.
  • the amount of bleached chemithermomechanical pulp in the pulp mixture may be varied.
  • the amount of bleached chemithermomechanical pulp BCTMP in the pulp mixture is equal to or less than 50 wt.-% of the weight of the pulp mixture, such that the pulp mixture MIX1 also comprises bleached chemical pulp PULP1, PULP2.
  • the pulp mixture may comprise bleached chemithermomechanical pulp BCTMP an amount of 5 wt.-% or more, such as equal to or higher than 10 wt.-%, or equal to or higher than 25 wt.-%.
  • the amount of bleached chemithermomechanical pulp BCTMP in the pulp mixture may be used to change the production cost structure of the release liner REL1.
  • the bleached chemical pulp may comprise hardwood pulp PULP1, such as bleached hardwood pulp from a Kraft process.
  • the presence of cellulose fibers from chemically treated hardwood in the pulp mixture MIX1 is advantageous for the brightness and transparency of the product.
  • the bleached chemical pulp comprises both hardwood pulp PULP1 and softwood pulp PULP2.
  • the chemically treated softwood in the pulp mixture MIX1 in general has a longer average fiber length than chemically treated hardwood, and is advantageous for the strength properties of the formed paper web WEB1.
  • the hardwood pulp PULP1 and the softwood pulp PULP2 are bleached pulp from a Kraft process.
  • the bleached chemical pulp PULP1, PULP2 and/or the bleached chemithermomechanical pulp BCTMP may be refined separately at a refining section of a paper machine prior to forming the pulp mixture MIX1.
  • the bleached chemical pulp which may comprise hardwood pulp PULP1 and softwood pulp PULP2
  • the bleached chemithermomechanical pulp BCTMP may be refined together when forming the pulp mixture MIX1 by mixing 1.
  • the fiber length distribution in pulp mixture MIX1 is different.
  • the pulp mixture MIX1 refining may be used to prevent the fibers form being refined excessively, such that the amount of fine particles in the pulp mixture MIX1 may be reduced.
  • the pulp mixture MIX1 may have a Schopper-Riegler value equal to or less than 70, preferably equal to or less than 50, such as in the range of 25 to 55, preferably in the range of 30 to 50.
  • the pulp mixture MIX1 may have a Canadian Standard Freeness value of equal to or more than 90 ml, preferably equal to or more than 180ml, such as in the range of 180 to 500 ml, preferably in the range of 215 to 425 ml.
  • the pulp mixture MIX1 may have a Canadian Standard Freeness value, for example, equal to or higher than 130 ml, preferably equal to or higher than 140 ml, such as equal to or higher than 300, preferably equal to or higher than 325 ml.
  • pulp which comprises water is subjected to shear and stress forces.
  • cutting and fibrillation of the cellulose fibers is obtained.
  • Refining may be performed by means of mechanical action, for example by using bars, drums, beaters or refiners. Refining, and in particular refining to a high degree, may sometimes be referred to as beating.
  • the bleached chemical pulp PULP1, PULP2 and/or the bleached chemithermomechanical pulp BCTMP may have a Schopper-Riegler value equal to or less than 70, preferably equal to or less than 50, such as in the range of 25 to 55, preferably in the range of 30 to 50.
  • the bleached chemical pulp PULP1, PULP2 and/or the bleached chemithermomechanical pulp BCTMP may have a Canadian Standard Freeness value of equal to or more than 90 ml, preferably equal to or more than 180ml, such as in the range of 180 to 500 ml, preferably in the range of 215 to 425 ml.
  • the bleached chemical pulp PULP1, PULP2 and/or the bleached chemithermomechanical pulp BCTMP may have a Canadian Standard Freeness value, for example, equal to or higher than 130 ml, preferably equal to or higher than 140 ml, such as equal to or higher than 300, preferably equal to or higher than 325 ml.
  • Schopper Riegler (SR) Freeness and Canadian Standard Freeness are tests used to measure the extent of refining of a pulp.
  • Refining and in particular refining to a high degree, may sometimes be referred to as beating.
  • Refining reduces the average fiber length of cellulose, which decreases the tear strength of a paper formed from the pulp.
  • Refining also leads to fibrillation, wherein the cellulose fiber bundles conventionally tightly bound by hydrogen bonds become separated to some extent.
  • the detachment of hydrogen bonds between fibers increases the pulp surface area and enables hydrogen bonding between fibers and water.
  • the increased pulp surface area leads to hydration and the pulp absorbs water and swells.
  • Refining increases the tensile and reduces the tearing strength of a paper formed from the pulp due to higher surface areas and increased hydrogen bonding between fibers.
  • the amount of mechanical energy used in refining correlates with the reduction of fiber length and fibrillation. By using more energy, fibers having shorter average fiber length and increased surface area may be obtained. This enables formation of a dense and smooth paper surface.
  • the amount of mechanical energy used in refining correlates with the water drainage resistance, which may be measured by the Schopper Riegler (SR) Freeness test.
  • the Schopper Riegler (SR) Freeness test provides an empirical measurement value of the drainage resistance of a pulp slurry A higher Schopper Riegler (SR) Freeness test value indicates higher amount of water to be removed from a formed paper web during the release liner manufacturing process
  • the Schopper Riegler (SR) Freeness value represents the inverse of the volume of water collected divided by ten.
  • the Schopper Riegler (SR) Freeness value may be determined using a SCAN-C 19:65 test method.
  • the Canadian Standard Freeness represents the drainability of a pulp suspension in water in millilitres (ml).
  • the Canadian Standard Freeness value may be determined using an ISO 5267-2:2001 test method.
  • the refined pulp mixture MIX1 is further mixed with water to form a pulp suspension.
  • the basic qualities of the paper PAP1, such as paper type and suitability for different applications, are already determined to a large extent when forming 2 the paper web WEB1 from the pulp mixture MIX1.
  • Filler chemicals CH2 such as viscosity modifiers, pigments or binder material, may be introduced 3 directly to the pulp mixture MIX1.
  • Filler chemicals CH2 such as viscosity modifiers, pigments or binder material, may be introduced 3 directly to the pulp mixture MIX1.
  • Filler chemicals CH2 such as viscosity modifiers, pigments or binder material
  • Minor amounts of recycled filler chemicals may be end up into the pulp mixture MIX1 through reject recycling 4, when refined reject fiber material is reused by addition of the recycled reject fiber material into the pulp mixture MIX1.
  • paper web WEB1 is formed 2 from the pulp mixture MIX1.
  • the pulp mixture MIX1 is typically introduced in a concentration between 0.25 and 3 wt.-%, such as in the range of 0.3 and 2 wt.-%, preferably less than 1 wt.-%, such as in the range of 0.3 to 0.8wt.-%.
  • the weight percentage (wt.-%) refers to the dry content of the mixture.
  • the dry content of the mixture is defined as the concentration of solids by weight in a mixture.
  • the dry content of a paper web is defined as the concentration of solids by weight in a paper web.
  • the dry content of a paper web formed from the pulp mixture MIX1 comprises both fibers any chemicals such as pigments or binder material introduced into the pulp mixture MIX1 through recycling 4, of refined reject fiber material, which remains in the formed paper web WEB1.
  • the paper web WEB1 is formed from the pulp suspension and dewatered.
  • the formed paper web is typically forced against the forming wire.
  • the solid particles in the suspension are to a certain degree trapped initially by the wire and later by the accumulating wet web.
  • a part of the solid particles, referred to as fine particles, may flow through the wire, and are recycled 5 back to the pulp suspension. These recycled fine particles have an impact on the manufacturing process, in particular when forming a paper web.
  • the recycling arrangement is referred to as the short circulation of the pulp suspension.
  • the amount of recycled fine particles defines a retention level, which describes the ability of the formed paper web to retain fine particles on the web, and therefore the balance between drainage and formation of the paper web.
  • Fine particles in this context refer to particles having a maximum dimension equal to or less than 0.2 millimetres, when determined by an optical analyser.
  • the content of fine particles in a bleached chemical pulp, such as kraft pulp varies depending of the used wood species and extent of refining. For example in aspen, the content of fine particles in a bleached chemical pulp may be in the range of 14 wt.-% or less.
  • the content of fine particles in a mechanical and chemithermomechanical pulp is typically higher than in bleached chemical pulp, such as equal to or higher than 20 wt.-%.
  • a low retention level is an indication of a high amount of fine particles flowing through the formed paper web and through the wire into the short circulation, which may lead to accumulation of the particles in the pulp suspension.
  • the paper web After dewatering, the paper web is moved on a press section to reduce the moisture content of the paper web further.
  • the press section of a paper machine typically comprises a number of rolls for guiding and/or pressing the paper web.
  • the paper web is then moved from the press section to a drying section of a paper machine. In the drying section, the paper web is heated to evaporate most of the remaining moisture in the paper web.
  • the paper web may have a dry content level equal to or more than 90 wt.-%, for example in the range of 90 to 95 wt.-%.
  • the method therefore comprises a step for reducing moisture content 6 of the paper web WEB1 in a press section, and a step for drying the paper web WEB1 in a drying section, thereby forming paper PAP1.
  • the finishing 7 of the paper PAP1 can be done by surface sizing and calendering treatment.
  • the surface sizing and calendering treatment improve the smoothness of the paper surface.
  • a surface sizing refers to a primer layer applied on the formed paper PAP1.
  • Surface sizing and calendering treatment may be used to reduce the thickness of the paper. Therefore surface sizing and calendering treatment may be used in reducing the specific volume of the paper PAP1.
  • the ratio of grammage to thickness of the paper in micrometres is maintained equal to or higher than 1.0.
  • a paper having a surface sizing may also be denoted as a substrate layer, comprising a paper support SUP1 and one or more primer layers applied on the paper support.
  • a primer layer may be applied on one side or on both sides of the paper PAP1.
  • the primer layer typically comprises size coating, pigments and/or filler chemicals, such as described above for glassine paper.
  • the primer layer coating may be applied in the range of 1 to 10 g/m 2 per side, typically the amount of applied primer layer is in the range of 2 to 5 g/m 2 per side.
  • the calendering treatment may be done on the formed paper PAP1 before or after applying the primer layer.
  • the calendaring treatment may comprise use of a calender, multi-nip calender or super calender to modify the surface properties of the paper PAP1 and to reach the final thickness for the paper PAP1.
  • paper having a thickness in the range of 35 to 100 micrometres is typical.
  • paper comprising bleached chemithermomechanical pulp may have a thickness less than 70 micrometres, such as in the range of 40 to 68 micrometres, most preferably in the range of 45 to 60 micrometres.
  • a sufficient density at such thickness values is typically equal to or less than 1200 kg/m 3 , such as in the range of 1000 to 1200 kg/m 3 or in the range of 1050 to 1150 kg/m 3 .
  • the thickness of a paper comprising bleached chemithermomechanical pulp may be equal to or less than 100 micrometres.
  • a release liner REL1 may be obtained from the substrate layer comprising a paper support SUP1 and one or more primer layers applied on the paper support by applying a release coating 8 on the substrate layer.
  • a release liner may be used, for example, to form a combination comprising the release liner and an adhesive label or label stock LAB1.
  • a typical example of a release coating contains silicone polymer, and the coating is applied in a quantity of equal to or less than 2 g/m 2 per side, such as in the range of 0.7 to 2 g/m 2 , preferably in the range of 0.8 to 1.5 g/m 2 .
  • bleached chemithermomechanical pulp used in paper manufacturing is made of hardwood.
  • Some examples of hardwood suitable for manufacturing chemithermomechanical pulp comprise aspen and eucalyptus.
  • Eucalyptus belongs to the genus Eucalyptus, of which an example species used in pulp processing is Eucalyptus globulus.
  • Aspen belongs to the genus Populus, comprising species such as Populus tremuloides and Populus tremula.
  • Aspen is a widely used hardwood, which is suitable for bleached chemithermomechanical pulp.
  • Aspen is a tall, fast growing deciduous tree, which is widely available.
  • the wood of aspen has a homogeneous structure with good mechanical properties for both mechanical and chemical pulping.
  • the bark of aspen is easy to remove, which facilitates the processability of the logs.
  • the aspen fibers, while of hardwood, are flexible and promote inter-fiber bonding in a paper web.
  • the vessels of aspen are large compared to the fibers and may comprise 20 to 30% by volume of the wood.
  • mechanical pulps aspen is advantageous compared to many softwoods, due to lower yellowing of the fibers.
  • bleached chemithermomechanical pulp made of a hardwood such as aspen may mixed with bleached chemical pulp, such as Kraft pulp, to modify the ratio of the bulk to the grammage of the paper, as described above, such that the amount of fibers per unit area may be increased to improve the density of the paper surface, without increasing the grammage of the paper.
  • the increase in bulk produced with the bleached chemithermomechanical pulp may thus be used for calendaring the paper into a final thickness having a sufficient density, typically equal to or less than 1200 kg/m 3 , suitable for a release coating and a sufficient transparency, typically equal to or higher than 35%, such as equal to or higher than 40%, to be used as a release liner.
  • Aspen fibers have small average fiber length, and have a large specific surface (m 2 /g) that scatter light. This increases the brightness and opaqueness in a paper. When the amount of fibers having small average fiber length is increased in paper, the scattering of light typically increases. The refining of bleached chemithermomechanical pulp made of aspen should therefore minimized, to preserve the fiber length of the individual fibers in the formed pulp.
  • the scattering of light may also be reduced by calendaring the paper such that the thickness of the paper is reduced, which improves the transparency.
  • the transparency of the paper is dependent of the thickness of the paper, such that papers having a thickness and grammage equal to or higher than 70 g/m 2 typically have a lower transparency level than papers having less thickness.
  • Figures 2a and 2b show by way of an example, comparative data showing a difference in distribution of fiber length and fine particle content between bleached chemical pulp and bleached chemithermomechanical pulp.
  • Figure 2a is a measurement of bleached chemical pulp made of aspen.
  • the number weighted average length L(n) is 0.67 millimeters
  • the length weighted average length L(l) is 0.88 millimeters
  • the weight weighted average length L(w) is 1.04 millimeters.
  • the number weighted average amount of fine particles is 14.03% and the length weighted average amount of fine particles is 2.15%.
  • Figure 2b is a measurement of bleached chemithermomechanical pulp made of aspen.
  • the number weighted average length L(n) is 0.54 millimeters
  • the length weighted average length L(l) is 0.77 millimeters
  • the weight weighted average length L(w) is 0.92 millimeters.
  • the number weighted average amount of fine particles is 21.11% and the length weighted average amount of fine particles is 4.56%.
  • the fiber analysis was done by using a Metso Fiber Image Analyzer (Metso FS5).
  • the figures 2a and 2b show that in aspen, as in many hardwood species having similar fiber length, that bleached chemithermomechanical pulp made of hardwood comprises a large number of fine particles.
  • the average fiber length distribution of bleached chemithermomechanical pulp also differs from bleached chemical pulp.
  • the bleached chemithermomechanical pulp contains a higher proportion of particles having a small average fiber length.
  • the number weighted average amount of fine particles in bleached chemithermomechanical pulp is 21%, and 14% in the bleached chemical pulp.
  • the increase in the amount of fine particles in the bleached chemithermomechanical pulp compared to the bleached chemical pulp is 50%, which can have an impact in the retention level of fine particles in a paper manufacturing process comprising bleached chemithermomechanical pulp of hardwood.
  • the chemical composition of the bleached chemithermomechanical pulp differing from bleached chemical pulp may also have an effect on the refining of a pulp mixture comprising both bleached chemical pulp and bleached chemithermomechanical pulp.
  • One of the observed difficulties relates to a higher concentration of the fine particles in the short circulation of a paper machine on the wire section, where water is removed by drainage from the forming paper web.
  • the bleached chemithermomechanical pulp made of hardwood such as aspen comprises a low retention capability, such that fine particles may migrate through the formed paper web and end up into the short circulation of the paper machine, thereby accumulating into the pulp suspension used for forming the paper web. This may destabilise the wet end chemistry of the paper machine. Difficulties, such as foaming tendency of the pulp suspension may lead to web breaks in the manufacturing process.
  • the use of bleached chemithermomechanical pulp made of hardwood in glassine paper was tested on a paper machine.
  • the pulp mixture used to manufacture the paper comprised bleached chemical pulp of hardwood and softwood and 25 wt.-% of bleached chemithermomechanical pulp made of aspen.
  • the paper grade manufactured had a grammage of 57g/m 2 and was calendared into a final thickness of 53 micrometers ( ⁇ m).
  • the paper was measured to have a density of 1087 kg/m 3 . Measurements were taken from the paper manufacturing process at consecutive time points up to a time point of 42 hours, in order to observe the development of parameter used in characterizing the quality of the manufactured paper and suitability for release liner support layer purpose. During the measurement period the content of bleached chemithermomechanical pulp added into the pulp mixture was maintained at 25 wt.-% of the pulp mixture.
  • Figures 3a, 3b and 3c are trend diagrams representing by way of examples the development of paper transparency (%), top side roughness (PPS) and back side water absorptiveness (CobbA60) as a function of time in a paper manufacturing process, wherein the pulp suspension comprises 25 wt.-% of bleached chemithermomechanical pulp made of aspen. From Figure 3a it can be observed, that the transparency of the paper decreased in the manufacturing process as a function of time, when the content of bleached chemithermomechanical pulp added into the pulp mixture was maintained at 25 wt.-% of the pulp mixture. The observed change in the transparency level was from 49.9% to 46.7%, which means over 6% change over the measurement period.
  • bleached chemithermomechanical pulp made of hardwood may introduce difficulties in the process control when continued longer, such as over one day or over two days.
  • these bleached chemithermomechanical pulp threshold values have been discovered to be problematic with bleached chemithermomechanical pulp made of aspen.
  • a pulp mixture comprising equal to or more than 10 wt.-% of bleached chemithermomechanical pulp made of aspen lead to reduced retention capability of fine particles on the forming section of the paper machine.
  • Glassine paper comprising BCTMP of hardwood and softwood
  • softwood may be used to improve the compatibility of the bleached chemithermomechanical pulp to the paper manufacturing process.
  • Different wood species have different chemical composition, and a different average fiber length in a pulpwood.
  • the wood material used to produce cellulose fibers is traditionally divided into two groups based on the average cellulose fiber length.
  • Hardwood typically denotes wood wherein the average fiber length of cellulose fibers in a pulp is less than 2 millimetres, such as in the range of 0.7 to 1.8 millimetres, whereas softwood denotes species having a longer average fiber length of cellulose fibers in a pulp compared to the hardwood, such as in the range of 2 to 3 millimetres.
  • a suitable softwood may be, for example a coniferous wood species, preferably spruce.
  • Spruce has an average fiber length typically in the range of 2.2 to 2.5 millimetres in a pulpwood.
  • the use of bleached chemithermomechanical pulp made of hardwood and softwood in glassine paper was tested on a paper machine.
  • the pulp mixture used to manufacture the paper comprised bleached chemical pulp of hardwood and softwood and 25 wt.-% of bleached chemithermomechanical pulp made of aspen and spruce.
  • the paper grade manufactured had a grammage of 57g/m 2 and was calendared into a final thickness of 53 micrometers ( ⁇ m).
  • the paper was measured to have a density of 1082 kg/m 3 . Measurements were taken from the paper manufacturing process over several days, up to a time period of 62 hours, during which the content of bleached chemithermomechanical pulp added into the pulp mixture was maintained at 25 wt.-% of the pulp mixture.
  • Figures 4a, 4b and 4c are trend diagrams representing by way of examples the development of paper transparency (%), top side roughness (PPS) and back side water absorptiveness (CobbA60) as a function of time in a paper manufacturing process, wherein the pulp suspension comprises 25 wt.-% of bleached chemithermomechanical pulp made of aspen and spruce. From Figure 4a it can be observed, that the transparency of the paper has a relatively small decrease in the manufacturing process as a function of time, when the content of bleached chemithermomechanical pulp added into the pulp mixture was maintained at 25 wt.-% of the pulp mixture.
  • the observed change in the transparency level was from 48.6% to 46.5 %, which means less than 4.4% change over the measurement period of several days. From Figure 4b it can be observed, that the roughness of the paper decreased to some extent in the manufacturing process as a function of time, when the content of bleached chemithermomechanical pulp added into the pulp mixture was maintained at 25 wt.-% of the pulp mixture.
  • the observed change in the roughness (PPS) from top side of the paper started from a value of 1.33 and ended in a value of 1.39.
  • the standard deviation of the values measured over several days was 6%.
  • the example 2 indicated, that the presence of softwood in the bleached chemithermomechanical pulp improves the runnability of the manufacturing process.
  • the results also indicate, that the presence of softwood in the bleached chemithermomechanical pulp improves the fiber length distribution of the bleached chemithermomechanical pulp such that the retention of fine particles in the paper web is higher.
  • the results also indicate, that the presence of softwood in the bleached chemithermomechanical pulp improves the fiber length distribution of the bleached chemithermomechanical pulp such that the average fiber length is longer.
  • Table 1 below is an example of two papers, wherein the first paper p1 has been manufactured using an amount of 25% of bleached chemithermomechanical pulp (BCTMP) comprising both aspen and spruce, and the second paper p2 has been manufactured using only bleached chemical pulp.
  • Table 1 Comparative quality data of yellow paper p1 comprising 25 wt.-% of bleached chemithermomechanical pulp comprising both aspen and spruce and of yellow paper p2 comprising only bleached chemical pulp.
  • Table 1 discloses comparative quality data of papers p1 and p2. The columns are numbered from 1 to 8 and refer to following parameters:
  • Paper p1 comprises 75 wt.-% of bleached chemical pulp and 25 wt.-% of bleached chemithermomechanical pulp comprising both aspen and spruce.
  • Paper p2 comprises only bleached chemical pulp. Both papers p1 and p2 were calendared to the same thickness of 53 micrometers. As can be determined from the table 1, the density of the paper p1 is only ca. 94% of the density of paper p2.
  • the bulk of paper p1 is 0.925 cm 3 /g
  • the bulk of paper p2 is 0.877 cm 3 /g, the bulk denoting the inverse of density, and expressed in cubic centimeters per gram (cm 3 /g).
  • the ratio of bulk to the grammage (g/m 2 ) in paper p1 is 1.016
  • the ratio of bulk to the grammage (g/m 2 ) in paper p2 is 1.014. Therefore, the ratio of bulk to the grammage in paper p1 comprising bleached chemithermomechanical pulp is more than 11% higher than the ratio of bulk to the grammage in paper p2, comprising only bleached chemical pulp.
  • the ratio of grammage (g/m 2 ) to thickness in micrometers in both papers p1 and p2 is above 1.0.
  • the ratio of grammage to thickness in micrometers is 1.07.
  • the ratio of grammage to thickness in micrometers is 1.13. Therefore, the paper p1 comprising 25 wt.-% of bleached chemithermomechanical pulp has a lighter grammage in the same thickness.
  • the water absorptiveness level of the paper p1 comprising 25 wt.-% of bleached chemithermomechanical pulp is only 96% of the water absorptiveness level of paper p2, which reflects a moderate refining of the fibers, and is an indication of sufficient surface density of for release coating purposes.
  • the transparency of both papers p1 and p2 is above 45%. Considering that the papers have been manufactured to comprise a yellow colour, which typically reduces the transparency value, the measured transparency of the papers p1 and p2 is very good.
  • Table 2 below is an example of papers p3 and p4, wherein paper p3 has been manufactured using an amount of 10% of bleached chemithermomechanical pulp (BCTMP) comprising both aspen and spruce, and paper p4 has been manufactured using an amount of 25% of bleached chemithermomechanical pulp (BCTMP) comprising both aspen and spruce.
  • the paper colour type in papers p3 and p4 was "Brilliant", denoting non-coloured, white paper with high transparency level.
  • the paper type in both papers p3 and p4 is glassine paper. Table 2.
  • the columns are numbered from 1 to 8, referring to same parameters as in table 1 above.
  • the difference between the papers p3 and p4 is in the content of bleached chemithermomechanical pulp added into the pulp mixture.
  • Both papers p3 and p4 were calendared to the same thickness of 61 micrometers. As can be determined from the table 2, the transparency of both papers is similar. In fact, paper p4 having a higher content of bleached chemithermomechanical pulp has a slightly higher transparency level. The density of the paper p4 is ca. 95% of the density of paper p3. Therefore, the bulk of the paper has been increased by increasing the content of the bleached chemithermomechanical pulp added into the pulp mixture.
  • the bulk of paper p3 is 0.887 cm 3 /g, and the bulk of paper p2 is 0.916 cm 3 /g, the bulk denoting the inverse of density, and expressed in cubic centimeters per gram (cm 3 /g).
  • the ratio of bulk to the grammage in paper p3 is 1.012, whereas the ratio of bulk to the grammage in paper p4 is 1.013. This indicates, that the ratio of bulk to the grammage may be increased by providing a higher amount of bleached chemithermomechanical pulp. An increase from 10 wt.-% to 25 wt.-% of bleached chemithermomechanical pulp added into the pulp mixture provided higher than 6% increase in the ratio of bulk to the grammage.
  • the ratio of grammage to thickness in micrometers in both papers p3 and p4 is above 1.0. In paper p3, the ratio of grammage to thickness in micrometers is 1.12. In paper p4, the ratio of grammage to thickness in micrometers is 1.09. Therefore, the paper p4 comprising 25 wt.-% of bleached chemithermomechanical pulp has a lighter grammage in the same thickness, when compared to the paper p3 comprising 10 wt.-% of bleached chemithermomechanical pulp. The ratio of grammage to thickness in micrometers may therefore also be reduced, by means of increasing the content of the bleached chemithermomechanical pulp added into the pulp mixture.
  • the water absorptiveness level of the paper p4 comprising 25 wt.-% of bleached chemithermomechanical pulp is only 96% of the water absorptiveness level of paper p3. It is likely, therefore, that the increase in the content of bleached chemithermomechanical pulp has improved the process of pulp mixture refining, such that the fibers have reduced swelling characteristics. This is a positive indication of the bleached chemithermomechanical pulp promoting the formation of sufficient surface density of the paper.
  • the transparency of both papers p3 and p4 is above 40 %. Considering that the papers have been manufactured to a thickness of 61 micrometers, the measured transparency of the papers p3 and p4 is very good.
  • Table 3 below represents by way of an example of papers p5, p6, p7 and p8, wherein paper p5 has been manufactured using only bleached chemical pulp, paper p6 has been manufactured using bleached chemical pulp and an amount of 10% of bleached chemithermomechanical pulp comprising both aspen and spruce, paper p7 has been manufactured using bleached chemical pulp and an amount of 25% of bleached chemithermomechanical pulp comprising both aspen and spruce and paper p8 has been manufactured using bleached chemical pulp and an amount of 35% of bleached chemithermomechanical pulp comprising both aspen and spruce.
  • the data values of papers p5, p6, p7 and p8 are average values of multiple measurements in each paper p5, p6, p7 and p8.
  • the average values in the columns 2 to 8 are based on the measurement results of multiple rolls of papers produced on a paper machine, to enhance the representativeness of the value.
  • Each average value represents the mean value of paper from a manufacturing process over several kilometers of produced paper.
  • Table 3 Comparative quality data of papers p5 to p8 having thickness in the range of 51 to 53 micrometers, and manufactured using either only bleachedchemical pulp as in p5 or an amount of bleached chemithermomechanical pulp comprising both aspen and spruce in the range of 10 to 35 wt.% as in p6 to p8.
  • the columns are numbered from 1 to 8, referring to same parameters as in table 1 above.
  • the density of the paper decreases as a function of the bleached chemithermomechanical pulp content, wherein a higher bleached chemithermomechanical pulp content corresponds to a lower density in paper.
  • a paper comprising bleached chemithermomechanical pulp in the range of 10 to 35 wt.-% has a density in the range of 1139.5 kg/m 3 to 1063 kg/m 3 , respectively.
  • the density of paper p6 having a content of 10 wt.-% of bleached chemithermomechanical pulp is about 98% of the density of paper p5 comprising only bleached chemical pulp.
  • the density of paper p7 having a content of 25 wt.-% of bleached chemithermomechanical pulp is about 95% of the density of paper p5 comprising only bleached chemical pulp.
  • the density of paper p8 having a content of 35 wt.-% of bleached chemithermomechanical pulp is about 93% of the density of paper p5 comprising only bleached chemical pulp.
  • the specific volume or bulk which is inverse of the density of the paper, increases as a function of the bleached chemithermomechanical pulp content, wherein a higher bleached chemithermomechanical pulp content corresponds to a higher specific volume. The results indicate, that the specific volume of the paper may be configured to increase as a function of the bleached chemithermomechanical pulp content.
  • the Bekk porosity (sec/min) of the paper decreases as a function of the bleached chemithermomechanical pulp content, wherein a higher bleached chemithermomechanical pulp content corresponds to a lower Bekk porosity.
  • a paper comprising bleached chemithermomechanical pulp in the range of 10 to 35 wt.-% has a Bekk porosity in the range of 177 to 101 sec/min, respectively. This indicates, that the surface integrity is very good in paper comprising bleached chemithermomechanical pulp, and that the surface fibers are sufficiently bonded to fibers beneath the surface towards the interior of the paper, which provides a good support for a primer layer coating.
  • the top side roughness of the paper (PPS) of the paper increases as a function of the bleached chemithermomechanical pulp content, wherein a higher bleached chemithermomechanical pulp content corresponds to a higher top side roughness of the paper.
  • a paper comprising bleached chemithermomechanical pulp in the range of 10 to 35 wt.-% has a top side roughness in the range of 1.4 to 1.8 PPS, respectively. This indicates, that the surface roughness in paper comprising bleached chemithermomechanical pulp increases as a function of the bleached chemithermomechanical pulp content.
  • top side roughness is also an indication of paper retention level, wherein a higher top side roughness may correspond to a higher amount of fine particles flowing through the formed paper web and through the wire into the short circulation, which may lead to accumulation of the particles in the pulp suspension.
  • bleached chemithermomechanical pulp comprising both aspen and spruce is beneficial in preventing the rate of increase of the top side roughness.
  • paper comprising 25 wt.-% of bleached chemithermomechanical pulp made of aspen has a top side roughness, which increases linearly as a function of time in a manufacturing process.
  • Figure 4b shows the effect of a softwood fraction as a function of time in a manufacturing process in a paper web comprising 25 wt.-% of bleached chemithermomechanical pulp made of aspen and spruce.
  • the back side water absorptiveness of the paper (Cobb A60) of the paper increases as a function of the bleached chemithermomechanical pulp content, wherein a higher bleached chemithermomechanical pulp content corresponds to a higher back side water absorptiveness of the paper.
  • a paper comprising bleached chemithermomechanical pulp in the range of 10 to 35 wt.-% has a back side water absorptiveness in the range of 21 to 25 PPS, respectively. This indicates, that the back side water absorptiveness in paper comprising bleached chemithermomechanical pulp increases as a function of the bleached chemithermomechanical pulp content.
  • back side water absorptiveness is also an indication of paper refining level, wherein a higher back side water absorptiveness may correspond to a higher amount of fine particles, which may flow through the formed paper web and through the wire into the short circulation, which may further lead to accumulation of the particles in the pulp suspension.
  • bleached chemithermomechanical pulp comprising both aspen and spruce is beneficial in moderating the rate of increase of the top side roughness.
  • paper comprising 25 wt.-% of bleached chemithermomechanical pulp made of aspen has a water absorptiveness, which increases rapidly as a function of time in a manufacturing process.
  • softwood such as spruce also present in the bleached chemithermomechanical pulp
  • the water absorptiveness in the manufacturing process may be controlled.
  • Figure 4c shows the effect of a softwood fraction as a function of time in a manufacturing process in a paper web comprising 25 wt.-% of bleached chemithermomechanical pulp made of aspen and spruce.
  • the grammage of the paper decreases as a function of the bleached chemithermomechanical pulp content, such that a higher bleached chemithermomechanical pulp content corresponds to a lower grammage of the paper.
  • the grammage of the paper decreases as a function of the paper density, such that a lower paper density corresponds to a lower grammage of the paper.
  • the grammage of paper p6 having a content of 10 wt.-% of bleached chemithermomechanical pulp is about 96% of the grammage of paper p5 comprising only bleached chemical pulp.
  • the grammage of paper p7 having a content of 25 wt.-% of bleached chemithermomechanical pulp is about 95% of the grammage of paper p5 comprising only bleached chemical pulp.
  • the grammage of paper p8 having a content of 35 wt.-% of bleached chemithermomechanical pulp is about 91% of the grammage of paper p5 comprising only bleached chemical pulp.
  • a paper comprising bleached chemithermomechanical pulp in the range of 10 to 35 wt.-% may be configured to have a high transparency equal to higher than 40%, such as in the range of 45 to 52%, and a reduction in the grammage equal to or higher than 10%, such as from ca. 60 g/m 2 to ca. 54 g/m 2 , while maintaining the thickness of the paper.
  • Bleached chemithermomechanical pulp may therefore be used to reduce the grammage of the paper, while maintaining the thickness of the paper, such that the surface density and transparency of the paper remain suitable for release coating purposes.
  • the higer amount of fine particles i.e. cellulose fibers of short average fiber length present in the bleached chemithermomechanical pulp, may be one reason for the high surface density of the paper.
  • the presence of the softwood fraction in the bleached chemithermomechanical pulp may enable a higher retention level of the fine particles on the paper web surface, such that the surface density of the paper may be improved, when bleached chemithermomechanical pulp made of aspen and spruce is used.
  • the ratio of grammage to thickness has been decreased from 1.138 in a paper comprising only bleached chemical pulp to 1.062 in a paper comprising 35 wt.-% of bleached chemithermomechanical pulp.
  • the ratio of bulk to grammage has increased more than 5% in a paper comprising 10 wt.-% of bleached chemithermomechanical pulp, more than 10% in a paper comprising 25 wt.-% of bleached chemithermomechanical pulp, and more than 18% in a paper comprising 35 wt.-% of bleached chemithermomechanical pulp, when compared to the ratio of bulk to grammage in a paper comprising only bleached chemical pulp.
  • the ratio of grammage to thickness has decreased less than 1.5% in a paper comprising 10 wt.-% of bleached chemithermomechanical pulp, equal to or less than 5% in a paper comprising 25 wt.-% of bleached chemithermomechanical pulp, and less than 7% in a paper comprising 35 wt.-% of bleached chemithermomechanical pulp, when compared to the ratio of grammage to thickness in a paper comprising only bleached chemical pulp.
  • bleached chemithermomechanical pulp may be arranged to have a composition configured to optimize the process conditions of a paper manufacturing process, where said bleached chemithermomechanical pulp is used.
  • Typical characteristics of bleached chemithermomechanical pulp are bulk, absorbency, internal bond and stiffness.
  • the bulk may be used to reduce grammage.
  • the high amount of short fibers in bleached chemithermomechanical pulp may also be used to improve the density of the paper surface, while increasing the bulk.
  • increased absorbency is not desired, as this increases the need for paper web pressing and drying, as well as reduces dimensional stability of the paper web.
  • Bleached chemithermomechanical pulp used in paper manufacturing can made of hardwood, such as aspen. Aspen wood has a relatively low lignin content compared to other pulped hardwoods which makes the pulp easier to bleach.
  • Typical properties of aspen fiber in a chemical pulp are a fiber length in the range of 1.0 to 1.3 mm, fiber width in the range of 18 to 19 ⁇ m and fiber wall thickness in the range of 2.0 to 3.0 ⁇ m.
  • the strength compared to pulp made of longer fibers, such as birch pulp, is less.
  • the easy reduction of the cellulose fiber length by refining may also lead to difficulties in the paper manufacturing, as described above.
  • Due to the fiber behavior in refining the cellulose fiber length distribution of bleached chemithermomechanical pulp made of aspen comprises a large amount of fine particles, such as cellulose fibers having a fiber length less than the original fiber length of aspen.
  • the increase of fine particles has been noticed to reduce the retention capability of fine particles on the forming section of the paper machine, such that the paper manufacturing process is difficult to control.
  • the manufactured paper has reduced quality.
  • Tables 5 and 6 below are examples of characteristic values of bleached chemithermomechanical pulp made of aspen and spruce, refined to different freeness levels.
  • the parameters in the tables refer to values obtained by Metso Fiber Image Analyzer (Metso FS5), using defined standards.
  • the average length Lc(l) (mm) refers to length weighted average length in millimeters of cellulose fibers in a sample.
  • the fiber mass per length (mg/m) refers to mass of fiber per length unit in a sample in milligrams per meter.
  • the kink of the sample is given as an inverse of length (1/m).
  • the fiber content refers to the percentage of fibers in a given length range in a sample; for example "fiber content 0-0.2 mm” refers to number weighted average amount of fibers having a measured length less than 0.2 millimeters in a sample, and “fiber content 0.2-0.6 mm” refers to number weighted average amount of fibers having a measured length equal to or higher than 0.2 millimeters and less than 0.6 millimeters in a sample.
  • the fiber content 0-0.2 mm" is equal to the amount of fine particles in a sample.
  • the series of samples S10, S11, S12 and S13 represent bleached chemithermomechanical pulp made of aspen and spruce, refined to Canadian standard freeness (CSF) 330 ml, 270 ml, 240 ml and 189 ml, respectively.
  • the series of samples S20, S21, S22 and S23 represent bleached chemithermomechanical pulp made of aspen and spruce, refined to Canadian standard freeness 140 ml, 127 ml, 108 ml and 91 ml, respectively.
  • the Canadian Standard Freeness value of 90 ml is approximately equal to a Schopper-Riegler value of 70. Table 5.
  • the number weighted average amount of fine particles i.e. the cellulose fiber content in the range of 0 to 0.2 mm fiber length, in bleached chemithermomechanical pulp made of aspen was 21%. From Tables 5 and 6 it may be observed, that in the sample series S10-S13 and S20-S23 made of aspen and spruce, the number weighted average amount of fine particles in bleached chemithermomechanical pulp is less than 20 %, in the range of 14.6 to 19.1 %.
  • the number weighted average amount of fine particles in bleached chemithermomechanical pulp made of hardwood and softwood is less than the number weighted average amount of fine particles in bleached chemithermomechanical pulp made of hardwood only.
  • the number weighted average amount of fine particles in bleached chemithermomechanical pulp is higher than 14 %. Therefore, the number weighted average amount of fine particles in bleached chemithermomechanical pulp made of hardwood and softwood is less than the number weighted average amount of fine particles in bleached chemical pulp made of hardwood only.
  • the number weighted average amount of fine particles in bleached chemical pulp made of aspen was 14%. Therefore, by varying the amount of softwood in the bleached chemithermomechanical pulp, the composition may be used to optimize the process conditions of a paper manufacturing process, where said bleached chemithermomechanical pulp is used. In particular, the amount of cellulose fibers in a specific volume of the paper may be increased by the composition of the bleached chemithermomechanical pulp. As can be observed from the results of the sample series S10-S13 and S20-S23, the amount of fine particles and particle amounts is proportional to the extent of refining. By refining more, the amount of amount of fine particles increases.
  • the manufacturing method has a role in determining the properties of the bleached chemithermomechanical pulp.
  • the characteristics and compatibility of the bleached chemithermomechanical pulp for use in a paper for a release liner may be, at least to some extent, be determined by the way of manufacturing the bleached chemithermomechanical pulp.
  • the bleached chemithermomechanical pulp preferably is chemically compatible with the paper manufacturing process.
  • the fine particles may comprise other compounds, which originate from the wood species used in manufacturing the bleached chemithermomechanical pulp.
  • the wood material of aspen for example, may comprise compounds which promote foaming in amounts, which when accumulating in the short circulation of the paper machine, may lead to foaming of the pulp suspension.
  • the composition of spruce pulp comprises compounds, such as coniferous resins, which appear to facilitate the manufacturing process of chemithermomechanical pulp, in particular the washing of the chemithermomechanical pulp.
  • Measured pH of aqueous extracts from bleached chemithermomechanical pulp have indicated that chemithermomechanical pulp comprising both aspen and spruce may have a higher pH value than chemithermomechanical pulp comprising only aspen.
  • a softwood component may be arranged to protect the hardwood component of chemithermomechanical pulp or bleached chemithermomechanical pulp during mechanical refining.
  • chemithermomechanical pulp comprising both aspen and spruce
  • the manufacturing process of bleached chemithermomechanical pulp may also be improved by adjusting the pH and extent of refining, such that bleached chemithermomechanical pulp having a desired water absorptiveness and fiber length distribution is obtained. After refining the bleached chemithermomechanical pulp may have for example,
  • Chemithermomechanical pulp may be manufactured by a hybrid process wherein wood chips are first pretreated with chemicals, heated for a short period and subsequently refined by mechanical means.
  • the wood chips are pretreated in a higher pH, preferably by impregnating the wood chips with chemicals, the internal bonding of the cellulose fibers may be reduced, such that the specific volume of the formed chemithermomechanical pulp may be increased.
  • the pH during the chemical impregnation treatment is typically an alkaline treatment, wherein the chemical solution raises the pH environment experienced by the wood chips to above pH level 7.
  • the pH environment experienced by the wood chips may be, for example in the range of pH 7 to 11, advantageously in the range of pH 7 to 9.
  • the bulkiness of the formed chemithermomechanical pulp may be increased such that less amount of refining may be required for providing the desired water absorptiveness and fiber length distribution.
  • the amount of short fibers, such as fine particles, in the bleached chemithermomechanical pulp may be increased, which in a pulp suspension are suitable for increasing the specific volume of a paper web formed from the pulp suspension, while providing means to reduce the grammage of a paper formed from the paper web.
  • the foaming tendency of the formed bleached chemithermomechanical pulp may also be reduced, such that the runnability of a further manufacturing process of paper comprising bleached chemithermomechanical pulp may be improved.
  • sample S10, S12 and S20 are bleached chemithermomechanical pulp manufactured according to an embodiment of the invention and refined to initial Canadian standard freeness levels of 330 ml and 140 ml, respectively.
  • Sample S12 has been obtained by further refining sample S10 from Canadian standard freeness level of 330 ml to Canadian standard freeness level of 240 ml.
  • Sample S12 and sample S20 both have the same average fiber length of 0.84mm.
  • the fiber content in the range of 0-0.2mm denoting the amount of fine particles in sample S20 is 17.9%, whereas the fiber content in the range of 0-0.2mm denoting the amount of fine particles in sample S12 is 15.8%. Therefore, by adjusting the manufacturing process conditions, bleached chemithermomechanical pulp having a desired water absorptiveness and fiber length distribution may be obtained.
  • Spruce is a coniferous wood, of which a typical example is Picea abies.
  • Coniferous woods from genus Picea, Abies, Larix or Pinus are softwoods, which have a long cellulose fiber length compared to aspen.
  • the cellulose fibers of spruce are thin walled and collapse to thin bands upon drying.
  • the chemical composition of pulp made of spruce is easy to bleach.
  • Typical fiber length of spruce in a chemical pulp is in the range of 2.2 to 2.5 mm.
  • the chemical characteristics of spruce is well suited for manufacturing glassine paper and other papers for release liner.
  • a bleached chemithermomechanical pulp is typically manufactured into a dry product, such as into a sheet or bale.
  • the pH of aqueous extracts may be measured from a manufactured bleached chemithermomechanical pulp product according to the standard DIN 53124 (ISO 6588-1 or ISO 6588-2), as described above.
  • a modified version of the standard ISO 6588-2 may be used.
  • An amount of 2 grams of pulp sample is cut into pieces, such that each piece has a maximum dimension of 1 centimeter.
  • the cut pieces of pulp sample are mixed with 100 millilitres of deionised water to disperse the pulp with the water such that a dispersed pulp sample having a pulp concentration of 2 wt.-% of water is obtained.
  • the dispersed pulp sample is heated to a boiling point and boiled for 60 minutes.
  • the dispersed pulp sample is cooled down, such that the temperature of the pulp sample is in the range of 20 to 25°C, and the pulp sample is filtrated through a filter having a 200 mesh grid, for example by means of a Buchner-funnel, thereby obtaining a filtrate separated from the bleached chemithermomechanical pulp.
  • the pH is measured from the filtrate thus obtained.
  • the pH may be measured from the filtrate by means of a pH meter, using two buffer solutions having pH4 and pH7, respectively. Suitable pH meters are, for example, pH-meter CG 840 with electrode N 1042A, Knick pH-meter 766 Calimatic with electrode SE 103 or Mettler-Toledo MP 120, used according to the manufacturer's instructions.
  • a modified version of the standard ISO 6588-1 may be used, wherein the pH of aqueous extracts is measured directly from such sample having a volume of at least 25 ml.
  • a modified version of the standard ISO 6588-1 may be used, wherein a sample having a volume of at least 25 ml is filtrated through a filter having a 200 mesh grid, for example by means of a Büchner-funnel, and the pH of aqueous extracts is measured from the thus obtained filtrate.
  • the pH of aqueous extracts from a bleached chemithermomechanical pulp suspension sample is measured after disintegrating the sample by heating to a boiling point and boiling the sample for 60 minutes, and cooling the sample down to a temperature in the range of 20 to 25°C, before performing the pH measurement.
  • bleached chemithermomechanical pulp BCTMP11, BCTMP12, BCTMP13, BCTMP14 having a desired water absorptiveness and fiber length distribution.
  • the bleached chemithermomechanical pulp BCTMP11, BCTMP12, BCTMP13, BCTMP14 may be further used in manufacturing of a release liner support layer PAP1 comprising bleached chemithermomechanical pulp BCTMP, as shown in Figure 1 b.
  • the bleached chemithermomechanical pulp BCTMP refers to bleached chemithermomechanical pulp manufactured according to any of the variations presented in Figures 5 , 6 , 7 or 8 below.
  • the bleached chemithermomechanical pulp BCTMP11, BCTMP12, BCTMP13, BCTMP14 may be used, for example, in manufacturing of a glassine paper or a baking paper, such that the glassine paper or the baking paper comprises bleached chemithermomechanical pulp BCTMP.
  • the bleached chemithermomechanical pulp BCTMP11, BCTMP12, BCTMP13, BCTMP14 may be used for example, in manufacturing of a release liner support layer.
  • the variations differ from each other in the order of the step, where the mixing of the hardwood component and the softwood component is performed.
  • the method above may further comprise
  • Figure 5 shows, by way of an example a method for manufacturing bleached chemithermomechanical pulp comprising hardwood and softwood.
  • the amount of softwood SW1 in the bleached chemithermomechanical pulp may be equal to or less than 50 wt.-%, such as in the range of 1 to 50 wt.-%.
  • the amount of softwood SW1 in the bleached chemithermomechanical pulp BCTMP11 may be equal to or more than 5 wt.-%, such as equal to or more than 10 wt.-%, preferably equal to or more than 25 wt.-%, most preferably equal to or more than 35 wt.-%.
  • the amount of softwood SW1 in the bleached chemithermomechanical pulp may be, for example in the range of 5 to 45 wt.-%, or in the range of 10 to 35 wt.-%.
  • wood chips from hardwood HW1 and softwood SW1 may be produced by debarking and chipping wood.
  • the debarked and chipped hardwood HW1 and softwood SW1 may be mixed 21 in a mixer, thereby forming a wood chip mixture MIX11 comprising the debarked and chipped hardwood HW1 and softwood SW1.
  • the mixing of the wood chips may be done prior to adding a chemical solution CH1 on the wood chips.
  • a chemical solution CH1 may be applied 20 on the wood chips, for example in the mixer.
  • impregnation of the chemical solution CH1 is used to improve the absorption of the chemicals into the wood chips, such that a more homogenous absorption profile of the chemicals inside the wood chips may be obtained.
  • the even distribution of the chemicals into the wood chips reduces the amount of non-fibrillated material in the chemithermomechanical pulp, such as small splinters of wood chips.
  • An example of chemical used in the chemical solution is sodium sulphite.
  • the chemical solution CH1 may comprise sodium sulphite for example in the range of 2% to 5% by weight.
  • the impregnation of the wood chips may be used to control the extent of the defibrillation of the cellulose fibers, such that the ratio of bulk to tensile strength may be adjusted.
  • the chemical solution may have an alkaline pH value, such as a pH equal to or higher than pH 7, preferably equal to or higher than pH 7.5.
  • a chemical solution CH1 having a higher pH value may be used.
  • the impregnated wood chips are subsequently treated 23 by thermomechanical means.
  • the treatment 23 comprises heating of the impregnated wood chips by steam.
  • the temperature and duration of the heating step may be varied.
  • the impregnated wood chips may be heated for at least 2 minutes at a temperature in the range of 120 to 130°C, or even higher such as up to 150°C.
  • the heating time may be longer, for example in the range of 2 to 5 minutes, or longer, in order to allow the chemical solution to soften the wood chips such that the defibrillation of the cellulose fibers by refining is improved.
  • the softened fibers are separated from each other by mechanical means.
  • the separation process may comprise, for example refiners, wherein the average fiber length of the material is also reduced.
  • the formed chemithermomechanical pulp CTMP11 may be washed. Washing of the chemithermomechanical pulp with water, removes aqueous extracts from the material. Washing also helps to remove the compounds of the chemical solution CH1 used in impregnating the wood chips.
  • the formed chemithermomechanical pulp CTMP11 may be bleached 24, for example by using hydrogen peroxide and sodium hydroxide, to form bleached chemithermomechanical pulp.
  • the formed bleached chemithermomechanical pulp BCTMP11 advantageously has a Canadian Standard Freeness value in the range of 90 to 350 ml, preferably in the range of 130 to 330 ml, and a pH of aqueous extracts measured from the formed bleached chemithermomechanical pulp BCTMP11 above pH 7.0, preferably above pH 7.2 such as in the range of pH 7.0 to 9.0, preferably in the range of pH 7.4 to 8.0.
  • the temperature and duration of the thermomechanical treatment 23 are configured such that the amount of refining needed after the thermomechanical treatment 23 is as small as possible, such that the formed bleached chemithermomechanical pulp BCTMP11 has a Canadian Standard Freeness value equal to or more than 90 ml, preferably equal to or more than 180 ml, such as in the range of 90 to 500 ml and the pH of aqueous extracts equal to or above pH 7.0, such as in the range of pH 7.0 to 9.0.
  • the formed bleached chemithermomechanical pulp BCTMP11 has a Canadian Standard Freeness value equal to or more than 130 ml, such as in the range of 130 to 425 ml and the pH of aqueous extracts equal to or above pH 7.1, such as in the range of pH 7.1 to 8.9.
  • the formed bleached chemithermomechanical pulp BCTMP11 has a Canadian Standard Freeness value equal to or more than 325 ml, such as in the range of 325 to 435 ml and the pH of aqueous extracts equal to or above pH 7.3, in the range of pH 7.3 to 8.8.
  • FIG. 6 shows, by way of an example a variation of the method described above, for manufacturing bleached chemithermomechanical pulp comprising hardwood and softwood.
  • bleached chemithermomechanical pulp BCTMP12 comprising cellulose fibers from hardwood HW1 and softwood SW1 may be manufactured such that the wood chips are impregnated 30a, 30b with the chemical solution CH1 prior to forming an impregnated wood chip mixture MIX12, such that the composition and amount of the chemical solution CH1 may be separately applied to the cellulose fibers from hardwood HW1 and softwood SW1.
  • This enables a different chemical treatment to be applied to each wood type, which may be used in optimizing the composition of the bleached chemithermomechanical pulp BCTMP12.
  • chemithermomechanical pulp CTMP12 After applying the chemical solution CH1, the wood chips are mixed 31, and subjected to a thermomechanical treatment 32 as described above, such that chemithermomechanical pulp CTMP12 is obtained.
  • chemithermomechanical pulp CTMP12 By bleaching 33 the chemithermomechanical pulp CTMP12, bleached chemithermomechanical pulp BCTMP12 may be obtained, which has a Canadian Standard Freeness value equal to or more than 90 ml, preferably equal to or more than 180 ml, such as in the range of 90 to 500 ml and the pH of aqueous extracts equal to or above pH 7.0, such as in the range of pH 7.0 to 9.0.
  • the formed bleached chemithermomechanical pulp BCTMP12 has a Canadian Standard Freeness value equal to or more than 130 ml, such as in the range of 130 to 425 ml and the pH of aqueous extracts equal to or above pH 7.1, such as in the range of pH 7.1 to 8.9.
  • the formed bleached chemithermomechanical pulp BCTMP12 has a Canadian Standard Freeness value equal to or more than 325 ml, such as in the range of 325 to 435 ml and the pH of aqueous extracts equal to or above pH 7.3, in the range of pH 7.3 to 8.8.
  • FIG 7 shows, by way of an example a variation of the method described above, for manufacturing bleached chemithermomechanical pulp comprising hardwood and softwood.
  • bleached chemithermomechanical pulp BCTMP12 comprising cellulose fibers from hardwood HW1 and softwood SW1 may be manufactured such that the wood chips are impregnated 40a, 40b with the chemical solution CH1 separately, as in Figure 6 .
  • thermomechanical treatments 41 a, 41 b such that chemithermomechanical pulp CTMP1 made of hardwood HW1 and chemithermomechanical pulp CTMP2 made of softwood SW1 is obtained, wherein the different chemical 40a, 40b and thermomechanical 41a, 41b treatments may be used in optimizing the composition of the bleached chemithermomechanical pulp BCTMP12.
  • chemithermomechanical pulp CTMP1 comprising hardwood HW1
  • chemithermomechanical pulp CTMP2 comprising softwood SW1
  • a chemithermomechanical pulp mixture MIX13 comprising hardwood HW1 and softwood SW1 may be formed.
  • bleached chemithermomechanical pulp BCTMP13 may be obtained, which has a Canadian Standard Freeness value equal to or more than 90 ml, preferably equal to or more than 180 ml, such as in the range of 90 to 500 ml and the pH of aqueous extracts equal to or above pH 7.0, such as in the range of pH 7.0 to 9.0.
  • the formed bleached chemithermomechanical pulp BCTMP13 has a Canadian Standard Freeness value equal to or more than 130 ml, such as in the range of 130 to 425 ml and the pH of aqueous extracts equal to or above pH 7.1, such as in the range of pH 7.1 to 8.9.
  • the formed bleached chemithermomechanical pulp BCTMP13 has a Canadian Standard Freeness value equal to or more than 325 ml, such as in the range of 325 to 435 ml and the pH of aqueous extracts equal to or above pH 7.3, in the range of pH 7.3 to 8.8.
  • FIG 8 shows, by way of an example a variation of the method described above, for manufacturing bleached chemithermomechanical pulp comprising hardwood and softwood.
  • bleached chemithermomechanical pulp BCTMP14 comprising cellulose fibers from hardwood HW1 and softwood SW1 may be manufactured such that the wood chips are impregnated 50a, 50b with the chemical solution CH1 separately, as in Figure 6 .
  • the wood chips are subjected to separate thermomechanical treatments 51 a, 51 b, such that chemithermomechanical pulp CTMP1 made of hardwood HW1 and chemithermomechanical pulp CTMP2 made of softwood SW1 is obtained.
  • bleaching 52a, 52b the chemithermomechanical pulp CTMP1 made of hardwood HW1 and chemithermomechanical pulp CTMP2 made of softwood SW1 separately, bleached chemithermomechanical pulp comprising hardwood BCTMP1 and bleached chemithermomechanical pulp comprising softwood BCTMP2 may be obtained separately, wherein the different chemical 50a, 50b, thermomechanical 51 a, 51 b and bleaching 52a, 52b treatments may be used in optimizing the composition of the bleached chemithermomechanical pulps BCTMP1, BCTMP2.
  • the bleached chemithermomechanical pulps may further be mixed 53, thereby forming bleached chemithermomechanical pulp BCTMP14 comprising hardwood HW1 and softwood SW1, and which bleached chemithermomechanical pulp BCTMP14 has a Canadian Standard Freeness value equal to or more than 90 ml, preferably equal to or more than 180 ml, such as in the range of 90 to 500 ml and the pH of aqueous extracts equal to or above pH 7.0, such as in the range of pH 7.0 to 9.0.
  • the formed bleached chemithermomechanical pulp BCTMP14 has a Canadian Standard Freeness value equal to or more than 130 ml, such as in the range of 130 to 425 ml and the pH of aqueous extracts equal to or above pH 7.1, such as in the range of pH 7.1 to 8.9.
  • the formed bleached chemithermomechanical pulp BCTMP14 has a Canadian Standard Freeness value equal to or more than 325 ml, such as in the range of 325 to 435 ml and the pH of aqueous extracts equal to or above pH 7.3, in the range of pH 7.3 to 8.8.
  • the temperature and duration of the thermomechanical treatment 23, 32, 41 a, 41 b, 51 a, 51 b is configured such that the amount of refining needed after the thermomechanical treatment is reduced, such that the formed bleached chemithermomechanical pulp BCTMP11, BCTMP12, BCTMP13, BCTMP14 has a Canadian Standard Freeness value equal to or higher than 90, preferably equal to or higher than 130 ml, most preferably equal to or higher than 325 ml and pH value of aqueous extracts equal to or higher than 7.0, preferably equal to or higher than 7.2, most preferably equal to or higher than 7.3.
  • the methods described above enable forming bleached chemithermomechanical pulp BCTMP11, BCTMP12, BCTMP13, BCTMP14, wherein the bulk of the bleached chemithermomechanical pulp is advantageously equal to or higher than 1.8 cm 3 /g, preferably at least 2.0 cm 3 /g, such as in the range of 1.8 to 3.2 cm 3 /g.
  • the methods described above further enable forming bleached chemithermomechanical pulp BCTMP11, BCTMP12, BCTMP13, BCTMP14, wherein the brightness of the bleached chemithermomechanical pulp may be equal to or higher than 60%, preferably equal to or higher than 80%, most preferably equal to or higher than 85%, such as in the range of 60 to 85% .

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WO2020020503A1 (fr) * 2018-07-27 2020-01-30 Delfortgroup Ag Papier de base de séparation léger
CN112593453A (zh) * 2020-12-10 2021-04-02 牡丹江恒丰纸业股份有限公司 一种液晶基板保护纸制造方法
US20220380980A1 (en) * 2018-12-11 2022-12-01 Suzano S.A. Fibre composition, use of said composition and article comprising said composition
EP4293159A1 (fr) * 2022-06-13 2023-12-20 Ahlstrom Oyj Ruban transparent à base de fibres, son procédé de fabrication et ses utilisations
WO2024141707A1 (fr) * 2022-12-30 2024-07-04 Upm-Kymmene Corporation Papier sck comprenant de la bctmp et de la pâte recyclée
WO2024141706A1 (fr) * 2022-12-30 2024-07-04 Upm-Kymmene Corporation Papier sck doté d'une composition de fibres courtes et d'une durabilité améliorée

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WO2024141707A1 (fr) * 2022-12-30 2024-07-04 Upm-Kymmene Corporation Papier sck comprenant de la bctmp et de la pâte recyclée
WO2024141706A1 (fr) * 2022-12-30 2024-07-04 Upm-Kymmene Corporation Papier sck doté d'une composition de fibres courtes et d'une durabilité améliorée

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