EP3052402B1 - Measuring cap - Google Patents
Measuring cap Download PDFInfo
- Publication number
- EP3052402B1 EP3052402B1 EP14777696.7A EP14777696A EP3052402B1 EP 3052402 B1 EP3052402 B1 EP 3052402B1 EP 14777696 A EP14777696 A EP 14777696A EP 3052402 B1 EP3052402 B1 EP 3052402B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- neck
- line
- container
- break
- zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 230000002093 peripheral effect Effects 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 4
- 235000011837 pasties Nutrition 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 11
- 239000002775 capsule Substances 0.000 description 7
- 238000007789 sealing Methods 0.000 description 6
- 210000003323 beak Anatomy 0.000 description 5
- 125000006850 spacer group Chemical group 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 210000003679 cervix uteri Anatomy 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 208000031968 Cadaver Diseases 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D51/00—Closures not otherwise provided for
- B65D51/24—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes
- B65D51/28—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials
- B65D51/2807—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials the closure presenting means for placing the additional articles or materials in contact with the main contents by acting on a part of the closure without removing the closure, e.g. by pushing down, pulling up, rotating or turning a part of the closure, or upon initial opening of the container
- B65D51/2814—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials the closure presenting means for placing the additional articles or materials in contact with the main contents by acting on a part of the closure without removing the closure, e.g. by pushing down, pulling up, rotating or turning a part of the closure, or upon initial opening of the container the additional article or materials being released by piercing, cutting or tearing an element enclosing it
- B65D51/2842—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials the closure presenting means for placing the additional articles or materials in contact with the main contents by acting on a part of the closure without removing the closure, e.g. by pushing down, pulling up, rotating or turning a part of the closure, or upon initial opening of the container the additional article or materials being released by piercing, cutting or tearing an element enclosing it said element being provided with a preformed weakened line
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
- B65D41/02—Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
- B65D41/04—Threaded or like caps or cap-like covers secured by rotation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2217/00—Details of mixing containers or closures
Definitions
- the present invention relates to the field of plugs intended to be connected to the threaded neck of a bottle or container, in order to transfer into the contents of the bottle or container a liquid additive, pasty or powder, for example a supplement organoleptic, a mineral, a colorant, a taste additive or a chemical supplement, for example a catalyst, a reagent or a detergent.
- a liquid additive pasty or powder
- the content of the measuring cap is intended to be mixed with the contents of the container or bottle on which it is placed, or to reload this container.
- German patent DE102004013270 describing a screw-on accessory on the neck of a bottle, and having a lid.
- This lid is connected to the inner annular surface of the accessory by a peripheral annular area of lesser thickness.
- the frontal area of the neck comes into contact with the operculum - and not with the peripheral annular zone of lesser thickness, then exerts an axial force causing a tear in this annular zone. , in an uncontrolled way until provoking tear.
- the lid is then released and the neck enters the interior of the accessory.
- This solution has a seal at the bottom of the thread which is not adapted to retain the contents of the accessory during the various manipulations of the system.
- the bowl and the capsule have first latching means which cooperate in maintaining the bowl in the capsule in a first relative axial position with, between them, a sealed peripheral contact.
- a spacer extends inside the bowl skirt from the bottom thereof towards the bottom of the capsule to form a stop limiting the depression of the bowl in the capsule beyond this first position.
- This spacer is a means of breaking the bottom of the bowl when the depression of the latter in the capsule is forced beyond said first position by the neck drinking.
- the spacer occupies the useful volume and therefore reduces the capacity of the dosing cap. It can also deform during screwing, and thus not effectively fulfill its role of driving.
- the patent application US2007 / 0079895 discloses a container according to the preamble of claim 1, comprising a water reservoir, a threaded neck, and an upper reservoir.
- This upper reservoir has an upper part, a lower part removably attached to the upper part, a cylindrical coupling element projected downwards from the lower part and having internal threads fixed on the neck, and a formed seal in an upper part of the coupling element and above the opening.
- a hollow element pushes a seal, when the user presses the top of the elastomeric upper reservoir.
- the embodiment by plastic molding is complicated by this erect finger on the surface of the bottom of the cap.
- the devices comprise different parts in relative movement, which makes it difficult to obtain a good seal.
- the present invention relates to a device according to claim 1.
- the device engages around the neck of the bottle, and the transverse zone approaches the frontal surface of the cervix until this frontal area of the cervix comes into contact with the peripheral annular zone - and not with the operculum.
- the frontal surface of the neck exerts an axial stress, perpendicular to this transverse zone of increasing amplitude, to cause tearing along the rupture line, which releases the seal.
- the device has a stop, in particular of arcuate shape, whose median line has a radius R where R corresponds substantially to the median radius of the threaded neck of said container, said stop being configured to bear on the front surface of the neck of the bottle during the screwing of the skirt on the threaded neck of the container and a hinge zone whose median radius is greater than R.
- This device is a monolithic piece, molded in one piece without any insert (except possibly the bottom placed after filling the device). This solves the sealing problems encountered when assembling additional parts.
- This monolithic device is closed either by an attached bottom, or by a deformation of the portion opposite the lid, to seal, roll or close by any known method the filling end.
- the opening of the device is provided by the piercing of the cap when the stop comes into contact with the front surface of the neck of the bottle.
- the protrusion exerts a mechanical force on the lid causing tearing of the rupture line and the tilting of the lid towards the interior volume of the body, which allows the flow of the contents.
- This piece is also designed to be easily made in a simple plastic injection mold, not requiring drawers.
- said stop is located on the side diametrically opposite the middle of said breaking line.
- the lid is extended at its lower part by a striker extending perpendicular to the surface of the lid.
- the figures 1 and 2 illustrate a first embodiment.
- the metering device (1) is intended to be screwed onto the neck (2) of a bottle (3).
- the neck (2) presents in a known manner, or even in a standardized manner, an external thread, in particular of standardized diameter "28" according to the standards commonly used, such as GMP, MCA, ALCOA, 1716, LEIGHT-WEIGHT. These arrangements can also be taken for different diameters, such as diameters of "32" "38” "40” or other, depending on the type of container.
- the metering device (1) is manufactured by injection-molding a plastic material, preferably flexible, such as polyethylene or polypropylene.
- the dispenser (1) is constituted by a cylindrical body (4) forming at its lower part a tubular skirt (5) having on its inner surface a thread (6) complementary to the thread (16) of the neck (2) of the bottle.
- this thread of the neck (2) is provided on the outer surface of the neck.
- the skirt (5) has on its outer surface streaks (10) facilitating the exercise of a torque.
- This cylindrical body (4) is closed at its upper end by a bottom (7) clipped, welded, or glued.
- the cylindrical body (4) is closed by a sieve (8).
- this skirt (5) is, in the example described, configured to abut against the shoulder of the bottle or its neck, when the maximum screwing is reached. This solution limits the tightening stroke and prevent excessive depression of the neck in the body (4).
- the cylindrical body (4) defines a useful volume (9) completely available to receive a liquid, pasty or powdery content.
- the lid (8) has a central disc area (11) surrounded by an annular peripheral zone, a portion (13) is thinned to form a hinge.
- the thinned hinge portion (13) extends between the body (4) and the break line (12).
- This peripheral zone is not intended to tear, but to deform to move from a transverse initial position, to a conical position directed towards the bottom of the device, after tearing of the rupture line (12). It then forms a conical sealing lip fitting the upper part of the neck, up to its rim, without coming into contact with the thread.
- the radius of this peripheral annular zone is slightly greater than the outer radius of the neck (2) of the bottle, and less than the inner radius of the cylindrical body (4).
- the cover has a breaking line (12) with a radius smaller than the radius of the hinge zone (13).
- the radius of the rupture zone (12) is preferably also equal to or less than the median radius of the neck of the vial. In any event, the front surface of the neck does not come to rest on the seal formed inside this rupture line (12), so as to preserve the tightness of the connection zone between the device and the neck of the bottle. This sealing is ensured by the folding of the peripheral zone forming a conical sealing lip.
- the radius of the lid (8) is, at least partially, less than or equal to the median radius of the front surface of the neck (2) of the complementary bottle.
- the cover (8) has, at the hinge zone (13), a spout (14) extending below a segment of the break line (12), to avoid the tear at the point where the seal comes into contact first, during screwing, with the front surface of the neck (2) of the bottle.
- this beak (14) Before the face, this beak (14) has a tubular shape, perpendicular to the lid.
- this beak (14) is deformed taking a conical or annular shape, coming in circular support on the upper edge of the neck of the bottle.
- this arched beak (14) prevents tearing at this point, and creates a lever effect transmitting the forces in the opposite part of the lid.
- the tear then occurs along the break line (12) at a location diametrically opposed to the arcuate beak portion (14).
- the lid has at this beak (14) an extra thickness (15) avoiding an elastic deformation of the central disc area (11) and ensuring a good transfer of forces.
- the presence of this spout (14) locally protecting the rupture line (12) has the consequence that the mechanical stress which is exerted perpendicular to the surface of the cap (8) forces the tilting of the central disc zone (11) of the cap, which transmits the forces, especially because of the reinforced zone (15), towards the diametrically opposite portion. These constraints then cause tearing of the rupture line substantially on the opposite side to the spout (14). By continuing the screwing, it increases the deformation of the cover (8) which quickly takes a significant angle relative to the transverse plane.
- the disc area (11) of the cover (8) is further extended at its lower surface by a striker (18) erect in a perpendicular direction at rest in the transverse plane.
- This striker perforates the aluminum seal (or other material) that can seal some bottles, to allow the flow of the contents of the dispenser to the container.
- the dispenser can thus be used without any manipulation of the bottle other than the engagement and screwing on the neck of the bottle.
- the figure 2a describes in detail the hinge and sealing after screwing and tearing of the rupture zone.
- the thinned portion (13) of the hinged annular peripheral zone has been pushed back from a transverse initial position to a conical position, bearing against the upper tubular surface of the neck (2).
- the spout (14) has also been deformed to bear against the rim (or the upper outer edge) of the neck (2), before the threading.
- the deformation of the annular zone is facilitated on the one hand by the thinned annular zone (13) but not tearable forming hinge, and its extension - possibly of greater thickness - located inside the rupture line.
- the Figure 2B shows a view from below of the device.
- the figures 3 and 4 represents an alternative embodiment, wherein the body (4) of the dispenser (1) has in an eccentric zone a protruding index (20) whose lower end (21) comes into contact with the edge of the lid (8) when the screwing causes the front surface (16) of the neck of the bottle to come into contact with the spout (14) provided on the lower surface of the lid.
- This index (20) helps to prevent the undesirable tearing of the break line (12) and to ensure the transmission of the mechanical forces to the opposite side of the seal, where the break must occur.
- the figures 4 and 5 represent another variant embodiment in which the cover (8) has an outgrowth extending to the peripheral lower surface of the cover, at a radial distance less than the radius of the break line (12) and the radius of the hinge (13).
- the distance radial of this protrusion (14) substantially corresponds to the median radius of the front surface (16) of the neck (2) of the bottle (3).
- the figures 7 and 8 represent another embodiment where the cover (8) has a plurality of excrescences (22, 23) distributed circumferentially.
- the first (22) of these protrusions which comes into contact with the front surface (16) of the neck of the bottle transmits the mechanical forces which cause the tear at the diametrically opposite rupture zone.
- FIGS. 9 and 9A are detailed views of the seal and more particularly the piercing pin constituted, in this example, by a piercing pin (22) having an arcuate shape extending over approximately 30 °, with a width substantially corresponding to the the thickness of the front surface (16) of the neck of the bottle and a corresponding height sensitive to the pitch of the thread.
- This variant does not form a part of the present invention.
- the figures 10 and 11 respectively represent a sectional view of a measuring cap according to the invention, and a detailed view of the connection of the metering body with the bottom (25).
- This bottom has a disc transverse portion (29) extended by a tubular skirt (28) whose outer diameter corresponds to the inner diameter of the tubular body (4).
- This skirt (28) has an annular shoulder (26) forcibly engage in an annular groove (27) provided on the inner surface of the body (4).
Description
La présente invention concerne le domaine des bouchons destinés à se raccorder sur le col fileté d'une bouteille ou d'un récipient, afin de transférer dans le contenu de la bouteille ou du récipient un additif liquide, pâteux ou pulvérulent, par exemple un complément organoleptique, un minéral, un colorant, un additif gustatif ou encore un complément chimique, par exemple un catalyseur, un réactif ou un détergent. Le contenu du bouchon doseur est destiné à être mélangé au contenu du récipient ou de la bouteille sur laquelle il est placé, ou à recharger ce récipient.The present invention relates to the field of plugs intended to be connected to the threaded neck of a bottle or container, in order to transfer into the contents of the bottle or container a liquid additive, pasty or powder, for example a supplement organoleptic, a mineral, a colorant, a taste additive or a chemical supplement, for example a catalyst, a reagent or a detergent. The content of the measuring cap is intended to be mixed with the contents of the container or bottle on which it is placed, or to reload this container.
Pour permettre une utilisation aisée de ces bouchons doseurs, ils doivent réduire les manipulations et assurer une parfaite étanchéité tant pendant la phase de mise en place sur le récipient que pendant la phase de transfert de la dose contenue dans le bouchon doseur.To allow easy use of these dosing caps, they must reduce handling and ensure a perfect seal both during the placement phase on the container that during the transfer phase of the dose contained in the measuring cap.
On connaît, dans l'état de la technique, différentes solutions pour la réalisation de tels dispositifs, notamment pour la réalisation de bouchons doseurs.In the state of the art, various solutions are known for producing such devices, in particular for producing dosing plugs.
On connaît dans l'état de la technique le brevet allemand
Cette solution a une étanchéité en bas du filetage ce qui n'est pas adaptée pour retenir le contenu de l'accessoire au cours des différentes manipulations du système.This solution has a seal at the bottom of the thread which is not adapted to retain the contents of the accessory during the various manipulations of the system.
On connaît également dans l'état de la technique la demande de brevet américain
- une première pièce en forme de capsule possédant un fond et une jupe latérale dont l'extrémité opposée au fond est pourvue d'un filetage intérieur
- une seconde pièce en forme de cuvette avec un fond et une jupe latérale.
- a first capsule-shaped part having a bottom and a side skirt whose end opposite the bottom is provided with an internal thread
- a second bowl-shaped piece with a bottom and a side skirt.
La cuvette et la capsule possèdent des premiers moyens d'encliquetage qui coopèrent au maintien de la cuvette dans la capsule dans une première position axiale relative avec, entre elles, un contact périphérique étanche.The bowl and the capsule have first latching means which cooperate in maintaining the bowl in the capsule in a first relative axial position with, between them, a sealed peripheral contact.
Une entretoise s'étend à l'intérieur de la jupe cuvette depuis le fond de celle-ci en direction du fond de la capsule pour former une butée limitant l'enfoncement de la cuvette dans la capsule au-delà de cette première position. Cette entretoise constitue un moyen de rupture du fond de la cuvette lorsque l'enfoncement de cette dernière dans la capsule est forcé au-delà de ladite première position par le buvant du col.A spacer extends inside the bowl skirt from the bottom thereof towards the bottom of the capsule to form a stop limiting the depression of the bowl in the capsule beyond this first position. This spacer is a means of breaking the bottom of the bowl when the depression of the latter in the capsule is forced beyond said first position by the neck drinking.
Cette solution présente des difficultés d'étanchéité en raison du coulissement de la capsule par rapport à la cuvette.This solution has sealing difficulties because of the sliding of the capsule relative to the bowl.
Par ailleurs, l'entretoise occupe le volume utile et réduit donc la capacité du bouchon doseur. Elle peut aussi se déformer lors du vissage, et ainsi ne pas remplir efficacement son rôle d'enfoncement.Furthermore, the spacer occupies the useful volume and therefore reduces the capacity of the dosing cap. It can also deform during screwing, and thus not effectively fulfill its role of driving.
On connaît aussi le document
La demande de brevet
Beaucoup de solutions de l'art antérieur prévoient un doigt disposé dans le volume intérieur du doseur, venant exercer un effort sur un opercule lors du vissage du doseur sur le col du récipient.Many solutions of the prior art provide a finger disposed in the interior volume of the dispenser, coming to exert a force on a lid when screwing the dispenser on the neck of the container.
Ces solutions présentent plusieurs inconvénients. En premier lieu, le volume de ce doigt réduit le volume utile, et oblige d'augmenter l'encombrement du doseur pour compenser le volume mort occupé par le doigt.These solutions have several disadvantages. In the first place, the volume of this finger reduces the useful volume, and makes it necessary to increase the size of the dispenser to compensate for the dead volume occupied by the finger.
En second lieu, la réalisation par moulage plastique est compliquée par ce doigt en érection à la surface du fond du bouchon.Second, the embodiment by plastic molding is complicated by this erect finger on the surface of the bottom of the cap.
D'autres solutions prévoient un opercule entouré par une ligne de rupture déchirée lors de l'engagement du doseur sur le col de la bouteille et vissage.Other solutions include a lid surrounded by a broken tear line when the dispenser is engaged on the neck of the bottle and screwed.
Ces solutions ne sont pas non plus satisfaisantes car l'opercule est libéré après rupture, et peut pénétrer dans la bouteille, ou s'orienter dans une position où elle gêne l'écoulement du contenu du doseur vers la bouteille, de plus l'étanchéité n'est pas assurée au buvant ou au top de la bague de la bouteille, ce qui entraine une perte du contenu de l'accessoire au cours des différentes manipulations du système.These solutions are not satisfactory either because the cap is released after rupture, and can enter the bottle, or move in a position where it hinders the flow of the contents of the dispenser to the bottle, moreover the seal is not ensured at the rim or the top of the ring of the bottle, which causes a loss of the contents of the accessory during the various manipulations of the system.
Par ailleurs, les solutions de l'art antérieur présentent des configurations complexes nécessitant soit l'assemblage de plusieurs pièces, soit une production industrielle avec un outillage de moulage complexe, notamment des moules à tiroir.Furthermore, the solutions of the prior art have complex configurations requiring either the assembly of several parts or an industrial production with complex molding tools, including drawer molds.
Enfin, dans la plupart des solutions de l'art antérieur, les dispositifs comportent différentes pièces en mouvement relatif, ce qui rend difficile l'obtention d'une bonne étanchéité.Finally, in most solutions of the prior art, the devices comprise different parts in relative movement, which makes it difficult to obtain a good seal.
Afin de remédier à ces inconvénients, la présente invention concerne un dispositif selon la revendication 1. Ainsi, pendant le début de la rotation après que les deux filetages soient engagés, le dispositif s'engage autour du col de la bouteille, et la zone transversale se rapproche de la surface frontale du col jusqu'à ce que cette zone frontale du col vienne en contact avec la zone annulaire périphérique - et non pas avec l'opercule. En poursuivant le vissage, la surface frontale du col exerce une contrainte axiale, perpendiculaire à cette zone transversale d'amplitude croissante, jusqu'à provoquer la déchirure le long de la ligne de rupture, ce qui libère l'opercule.In order to overcome these drawbacks, the present invention relates to a device according to
Avantageusement, le dispositif présente une butée, notamment de forme arquée, dont la ligne médiane présente un rayon R où R correspond sensiblement au rayon médian du col fileté dudit récipient, ladite butée étant configurée pour venir en appui sur la surface frontale du col de la bouteille pendant le vissage de la jupe sur le col fileté du récipient et une zone charnière dont le rayon médian est supérieur à R.Advantageously, the device has a stop, in particular of arcuate shape, whose median line has a radius R where R corresponds substantially to the median radius of the threaded neck of said container, said stop being configured to bear on the front surface of the neck of the bottle during the screwing of the skirt on the threaded neck of the container and a hinge zone whose median radius is greater than R.
On entend par « pendant le vissage » au sens du présent brevet un stade d'engagement du vissage :
- postérieur à l'amorçage du vissage, où les deux éléments filetés entrent en contact, et
- et antérieur à l'arrivée en butée.
- after initiation of the screwing, where the two threaded elements come into contact, and
- and prior to arrival in abutment.
Ce dispositif est une pièce monolithique, moulée en une seule pièce sans aucune pièce rapportée (hormis éventuellement le fond placé après remplissage du dispositif). Cela permet de résoudre les problèmes d'étanchéité rencontrés lors de l'assemblage de pièces complémentaires.This device is a monolithic piece, molded in one piece without any insert (except possibly the bottom placed after filling the device). This solves the sealing problems encountered when assembling additional parts.
Ce dispositif monolithique est fermé soit par un fond rapporté, soit par une déformation de la partie opposée à l'opercule, pour sceller, rouler ou fermer par toute méthode connue l'extrémité de remplissage.This monolithic device is closed either by an attached bottom, or by a deformation of the portion opposite the lid, to seal, roll or close by any known method the filling end.
L'ouverture du dispositif est assuré par le perçage de l'opercule lorsque la butée vient en contact avec la surface frontale du col de la bouteille. En poursuivant le vissage, l'excroissance exerce un effort mécanique sur l'opercule provoquant la déchirure de la ligne de rupture et le basculement de l'opercule en direction du volume intérieur du corps, ce qui permet l'écoulement du contenu.The opening of the device is provided by the piercing of the cap when the stop comes into contact with the front surface of the neck of the bottle. By continuing the screwing, the protrusion exerts a mechanical force on the lid causing tearing of the rupture line and the tilting of the lid towards the interior volume of the body, which allows the flow of the contents.
Cette pièce est par ailleurs conçue pour être facilement réalisée dans un moule d'injection plastique simple, ne nécessitant pas de tiroirs.This piece is also designed to be easily made in a simple plastic injection mold, not requiring drawers.
Selon une première variante, ladite butée est située du coté diamétralement opposé au milieu de ladite ligne de rupture.According to a first variant, said stop is located on the side diametrically opposite the middle of said breaking line.
Selon une variante, l'opercule est prolongé à sa partie inférieure par un percuteur s'étendant perpendiculairement à la surface de l'opercule.According to a variant, the lid is extended at its lower part by a striker extending perpendicular to the surface of the lid.
La présente invention sera mieux comprise à la lecture de la description qui suit, concernant des exemples non limitatifs de réalisation illustrés par les dessins annexés où
- la
figure 1 représente une vue en coupe d'un premier exemple de dispositif selon l'invention, ainsi que d'une partie d'une bouteille - les
figures 2A et 2B représentent des vues respectivement en coupe en détail et de dessus de l'opercule - la
figure 3 et lafigure 4 représentent des vues en coupe d'un deuxième exemple de réalisation, respectivement en position intermédiaire de vissage et en position de vissage complet
- la
figure 5 et lafigure 6 représentent des vues en coupe d'un troisième exemple de réalisation, respectivement en position intermédiaire de vissage et en position de vissage complet - la
figure 7 et lafigure 8 représentent des vues en coupe d'un quatrième exemple de réalisation, respectivement en position intermédiaire de vissage et en position de vissage complet - les
figures 9 et 9A représentent des vues respectivement en coupe et de dessous d'un ergot de perçage qui ne forme pas une partie de la présente invention. - les
figures 10 et11 représentent respectivement une vue en coupe d'un bouchon doseur selon l'invention, et une vue en détail de la liaison du corps du doseur avec le fond.
- the
figure 1 represents a sectional view of a first example of a device according to the invention, as well as a portion of a bottle - the
Figures 2A and 2B represent views respectively in section in detail and from above of the operculum - the
figure 3 and thefigure 4 represent sectional views of a second exemplary embodiment, respectively in intermediate screwing position and in full screwing position
- the
figure 5 and thefigure 6 show sectional views of a third exemplary embodiment, respectively in intermediate screwing position and in full screwing position. - the
figure 7 and thefigure 8 show sectional views of a fourth embodiment, respectively in intermediate screwing position and in full screwing position - the
Figures 9 and 9A are views respectively in section and from below of a piercing pin which does not form a part of the present invention. - the
figures 10 and11 respectively represent a sectional view of a dosing cap according to the invention, and a detailed view of the connection of the doser body with the bottom.
Les
Le dispositif doseur (1) est destiné à être vissé sur le col (2) d'une bouteille (3).The metering device (1) is intended to be screwed onto the neck (2) of a bottle (3).
Le col (2) présente de façon connue, voire de façon normalisée, un filetage extérieur, notamment de diamètre normalisé "28" selon les normes couramment utilisées, telles que les normes BPF, MCA, ALCOA, 1716, LEIGHT-WEIGHT. Ces dispositions peuvent être également reprises pour des diamètres différents, tels que des diamètres de "32" "38" "40" ou autres, en fonction du type de contenant.The neck (2) presents in a known manner, or even in a standardized manner, an external thread, in particular of standardized diameter "28" according to the standards commonly used, such as GMP, MCA, ALCOA, 1716, LEIGHT-WEIGHT. These arrangements can also be taken for different diameters, such as diameters of "32" "38" "40" or other, depending on the type of container.
Le dispositif doseur (1) est fabriqué par injection-moulage d'une matière plastique, de préférence souple, telle que le polyéthylène ou polypropylène.The metering device (1) is manufactured by injection-molding a plastic material, preferably flexible, such as polyethylene or polypropylene.
Le doseur (1) est constitué par un corps cylindrique (4) formant à sa partie inférieure une jupe tubulaire (5) présentant à sa surface intérieure un filetage (6) complémentaire du filetage (16) du col (2) de la bouteille. Dans l'exemple décrit, ce filetage du col (2) est prévu sur la surface extérieure du col.The dispenser (1) is constituted by a cylindrical body (4) forming at its lower part a tubular skirt (5) having on its inner surface a thread (6) complementary to the thread (16) of the neck (2) of the bottle. In the example described, this thread of the neck (2) is provided on the outer surface of the neck.
La jupe (5) présente à sa surface extérieure des stries (10) facilitant l'exercice d'un couple de rotation.The skirt (5) has on its outer surface streaks (10) facilitating the exercise of a torque.
Ce corps cylindrique (4) est fermé à son extrémité supérieure par un fond (7) clipsé, soudé, ou collé.This cylindrical body (4) is closed at its upper end by a bottom (7) clipped, welded, or glued.
A l'autre extrémité, le corps cylindrique (4) est fermé par un opercule (8) percutable.At the other end, the cylindrical body (4) is closed by a sieve (8).
La hauteur de cette jupe (5) est, dans l'exemple décrit, configurée pour venir en butée contre l'épaulement du flacon ou de son col, lorsque le vissage maximum est atteint. Cette solution permet de limiter la course de vissage et empêcher un enfoncement excessif du col dans le corps (4).The height of this skirt (5) is, in the example described, configured to abut against the shoulder of the bottle or its neck, when the maximum screwing is reached. This solution limits the tightening stroke and prevent excessive depression of the neck in the body (4).
Entre ces deux extrémités bouchées, le corps cylindrique (4) définit un volume utile (9) totalement disponible pour recevoir un contenu liquide, pâteux ou pulvérulent.Between these two plugged ends, the cylindrical body (4) defines a useful volume (9) completely available to receive a liquid, pasty or powdery content.
L'opercule (8) présente une zone centrale discale (11) entourée par une zone périphérique annulaire dont une partie (13) est amincie pour former une charnière. La partie amincie (13) formant charnière s'étend entre le corps (4) et la ligne de rupture (12). Cette zone périphérique n'est pas destinée à se déchirer, mais à se déformer pour passer d'une position initiale transversale, à une position conique dirigée vers le fond du dispositif, après déchirure de la ligne de rupture (12). Elle forme alors une lèvre d'étanchéité conique épousant la partie supérieur du col, jusqu'à son buvant, sans venir en contact avec le filetage.The lid (8) has a central disc area (11) surrounded by an annular peripheral zone, a portion (13) is thinned to form a hinge. The thinned hinge portion (13) extends between the body (4) and the break line (12). This peripheral zone is not intended to tear, but to deform to move from a transverse initial position, to a conical position directed towards the bottom of the device, after tearing of the rupture line (12). It then forms a conical sealing lip fitting the upper part of the neck, up to its rim, without coming into contact with the thread.
Le rayon de cette zone annulaire périphérique est légèrement supérieur au rayon extérieur du col (2) de la bouteille, et inférieur au rayon intérieur du corps cylindrique (4). L'opercule présente une ligne de rupture (12) d'un rayon inférieur au rayon de la zone charnière (13). Le rayon de la zone de rupture (12) est de préférence également égal ou inférieur au rayon médian du col du flacon. En tout état de cause, la surface frontale du col ne vient pas s'appuyer sur l'opercule formé à l'intérieur de cette ligne de rupture (12), de façon à préserver l'étanchéité de la zone de raccordement entre le dispositif et le col du flacon. Cette étanchéité est assurée par le repliement de la zone périphérique formant une lèvre d'étanchéité conique.The radius of this peripheral annular zone is slightly greater than the outer radius of the neck (2) of the bottle, and less than the inner radius of the cylindrical body (4). The cover has a breaking line (12) with a radius smaller than the radius of the hinge zone (13). The radius of the rupture zone (12) is preferably also equal to or less than the median radius of the neck of the vial. In any event, the front surface of the neck does not come to rest on the seal formed inside this rupture line (12), so as to preserve the tightness of the connection zone between the device and the neck of the bottle. This sealing is ensured by the folding of the peripheral zone forming a conical sealing lip.
Le rayon de l'opercule (8) est, au moins partiellement, inférieur ou égal au rayon médian de la surface frontale du col (2) de la bouteille complémentaire.The radius of the lid (8) is, at least partially, less than or equal to the median radius of the front surface of the neck (2) of the complementary bottle.
Dans l'exemple décrit, l'opercule (8) présente, au niveau de la zone charnière (13), un bec (14) s'étendant en dessous d'un segment de la ligne de rupture (12), pour éviter la déchirure à l'endroit où l'opercule vient en contact en premier, lors du vissage, avec la surface frontale du col (2) de la bouteille. Avant le visage, ce bec (14) présente une forme tubulaire, perpendiculaire à l'opercule.In the example described, the cover (8) has, at the hinge zone (13), a spout (14) extending below a segment of the break line (12), to avoid the tear at the point where the seal comes into contact first, during screwing, with the front surface of the neck (2) of the bottle. Before the face, this beak (14) has a tubular shape, perpendicular to the lid.
Après vissage, ce bec (14) se déforme prenant une forme conique ou annulaire, venant en appui circulaire sur le bord supérieur du col du flacon.After screwing, this beak (14) is deformed taking a conical or annular shape, coming in circular support on the upper edge of the neck of the bottle.
De ce fait, lorsque le vissage se poursuit, ce bec arqué (14) empêche la déchirure à cet endroit, et crée un effet de levier transmettant les efforts dans la partie opposée de l'opercule. La déchirure se produit alors le long de la ligne de rupture (12), à un endroit diamétralement opposé à la partie comportant le bec arqué (14).Therefore, when the screwing continues, this arched beak (14) prevents tearing at this point, and creates a lever effect transmitting the forces in the opposite part of the lid. The tear then occurs along the break line (12) at a location diametrically opposed to the arcuate beak portion (14).
Pour améliorer cet effet de levier, l'opercule présente au niveau de ce bec (14) une surépaisseur (15) évitant une déformation élastique de la zone centrale discale (11) et assurant un bon transfert des efforts.To improve this leverage, the lid has at this beak (14) an extra thickness (15) avoiding an elastic deformation of the central disc area (11) and ensuring a good transfer of forces.
Le fonctionnement est le suivant :
- Le bouchon doseur (1) est engagé sur le col (2) de la bouteille (3). On procède alors de manière connue au vissage jusqu'à ce que la zone périphérique annulaire comprise entre la charnière (13) et la ligne de rupture (12) et entourant l'opercule (8), vienne en contact avec la surface frontale (16) du col (2) de la bouteille (3). Du fait de la forme hélicoïdale du filetage, ce contact débute en un point angulaire particulier, où se trouve le bec (14).
- The measuring cap (1) is engaged on the neck (2) of the bottle (3). The screwing is then done in known manner until the annular peripheral zone between the hinge (13) and the rupture line (12) and surrounding the cover (8) comes into contact with the front surface (16) of the neck (2) of the bottle (3). Due to the helical shape of the thread, this contact starts at a particular angular point where the spout (14) is located.
Selon une variante non limitative, la présence de ce bec (14) protégeant localement la ligne de rupture (12) a pour conséquence que la contrainte mécanique qui s'exerce perpendiculairement à la surface de l'opercule (8) force le basculement de la zone discale centrale (11) de l'opercule, qui transmet les efforts, notamment en raison de la zone renforcée (15), en direction de la partie diamétralement opposée. Ces contraintes provoquent alors la déchirure de la ligne de rupture sensiblement du côté opposé au bec (14). En poursuivant le vissage, on augmente la déformation de l'opercule (8) qui prend rapidement un angle important par rapport au plan transversal.According to a non-limiting variant, the presence of this spout (14) locally protecting the rupture line (12) has the consequence that the mechanical stress which is exerted perpendicular to the surface of the cap (8) forces the tilting of the central disc zone (11) of the cap, which transmits the forces, especially because of the reinforced zone (15), towards the diametrically opposite portion. These constraints then cause tearing of the rupture line substantially on the opposite side to the spout (14). By continuing the screwing, it increases the deformation of the cover (8) which quickly takes a significant angle relative to the transverse plane.
Dans cet exemple de réalisation, la zone discale (11) de l'opercule (8) est prolongée en outre à sa surface inférieure par un percuteur (18) en érection selon une direction perpendiculaire, au repos, au plan transversal. Ce percuteur perfore l'opercule en aluminium (ou autre matière) qui peut obturer certaines bouteilles, afin de permettre l'écoulement du contenu du doseur vers le récipient. Le doseur peut ainsi être utilisé sans aucune manipulation de la bouteille autre que l'engagement et le vissage sur le col de la bouteille.In this embodiment, the disc area (11) of the cover (8) is further extended at its lower surface by a striker (18) erect in a perpendicular direction at rest in the transverse plane. This striker perforates the aluminum seal (or other material) that can seal some bottles, to allow the flow of the contents of the dispenser to the container. The dispenser can thus be used without any manipulation of the bottle other than the engagement and screwing on the neck of the bottle.
La
La partie amincie (13) de la zone périphérique annulaire formant charnière a été repoussée pour passer d'une position initiale transversale à une position conique, en appui contre la surface tubulaire supérieure du col (2). Le bec (14) a également été déformé pour venir en appui contre le buvant (ou le bord supérieur extérieur) du col (2), avant le filetage. Ces deux parties (13 et 14) assurent ainsi l'étanchéité du raccordement entre le dispositif doseur et le col du flacon.The thinned portion (13) of the hinged annular peripheral zone has been pushed back from a transverse initial position to a conical position, bearing against the upper tubular surface of the neck (2). The spout (14) has also been deformed to bear against the rim (or the upper outer edge) of the neck (2), before the threading. These two parts (13 and 14) thus seal the connection between the metering device and the neck of the bottle.
La déformation de la zone annulaire est facilitée d'une part par la zone annulaire amincie (13) mais non déchirable formant charnière, et son prolongement - éventuellement de plus forte épaisseur - situé à l'intérieur de la ligne de rupture.The deformation of the annular zone is facilitated on the one hand by the thinned annular zone (13) but not tearable forming hinge, and its extension - possibly of greater thickness - located inside the rupture line.
La
Les
Cet index (20) contribue à empêcher la déchirure inopportune de la ligne de rupture (12) et à garantir la transmission des efforts mécanique vers le côté opposé de l'opercule, où la rupture doit se produire.This index (20) helps to prevent the undesirable tearing of the break line (12) and to ensure the transmission of the mechanical forces to the opposite side of the seal, where the break must occur.
Les
Les
Les
Les
Ce fond présente une partie transversale discale (29) prolongée par une jupe tubulaire (28) dont le diamètre extérieur correspond au diamètre intérieur du corps tubulaire (4). Cette jupe (28) présente un épaulement annulaire (26) venant s'engager de force dans une gorge annulaire (27) prévue à la surface intérieur du corps (4).This bottom has a disc transverse portion (29) extended by a tubular skirt (28) whose outer diameter corresponds to the inner diameter of the tubular body (4). This skirt (28) has an annular shoulder (26) forcibly engage in an annular groove (27) provided on the inner surface of the body (4).
Claims (8)
- A device consisting of a body (4) defining an effective interior volume (9) totally available for receiving a liquid or pulverulent or pasty composition intended to be transferred into a container having a threaded neck (2), with said device having a skirt (5) provided with a thread matching the thread of the neck (2) of said container, and a cap (8) connected to the inner wall of said body (4) by a peripheral zone having a generally annular shape and having a break-off line (12), with said cap (8) having a disc-shaped central area (11),
with said device being characterized in that said disc-shaped central area (11) is surrounded by an annular peripheral zone, a thinned part of which forms a hinge, with said disc-shaped central area extending between the body (4) and the break-off line (12), in that, during the screwing of the skirt (5) onto the threaded neck (2), such annular peripheral zone bears on the upper surface (16) of the neck (2) of the container and causes the at least partial breaking of said break-off line (12), and in that the body (4) is cylindrical. - A device according to claim 1, characterized in that said annular peripheral zone has a nose (14) with an initial tubular shape, in the vicinity of the break-off line (12), and in that said annular peripheral zone and said nose (14) are deformed after screwing to form conical lips bearing against the surface of the container neck.
- A device according to claim 1, characterized in that said annular peripheral zone has a hinge zone (13), the mid radius of which is greater than R, with R corresponding to the inner radius of the container neck (2).
- A device according to claim 1, 2 or 3 characterized in that said annular zone configured to bear against the front surface of the container neck consists of at least one stop (22), the mid line of which has a radius R, where R may substantially match the mid radius of the threaded neck of a container.
- A device according to claim 4, characterized in that said stop is provided on the side diametrically opposite the middle of said break-off line (12).
- A device according to claim 4, characterized in that said stop (22) is positioned in the middle of said break-off line (12).
- A device according to claim 1, 2 or 3, characterized in that said break-off line (12) extends over an arc of circle of less than 360-A°, with A ranging from 5 to 180°.
- A device according to any one of the preceding claims, characterized in that the lower part of the cap is extended by a spike (18) extending perpendicularly to the surface of the cap (8).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1359590A FR3011532B1 (en) | 2013-10-03 | 2013-10-03 | DOSING CAP |
PCT/FR2014/052175 WO2015049429A1 (en) | 2013-10-03 | 2014-09-03 | Measuring cap |
Publications (2)
Publication Number | Publication Date |
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EP3052402A1 EP3052402A1 (en) | 2016-08-10 |
EP3052402B1 true EP3052402B1 (en) | 2017-11-15 |
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ID=49998393
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP14777696.7A Active EP3052402B1 (en) | 2013-10-03 | 2014-09-03 | Measuring cap |
Country Status (10)
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US (1) | US9758283B2 (en) |
EP (1) | EP3052402B1 (en) |
JP (1) | JP6402946B2 (en) |
KR (1) | KR102227708B1 (en) |
CN (1) | CN105683056B (en) |
AU (1) | AU2014331018B2 (en) |
CA (1) | CA2925549C (en) |
FR (1) | FR3011532B1 (en) |
RU (1) | RU2660067C2 (en) |
WO (1) | WO2015049429A1 (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
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BE1023806B1 (en) * | 2016-06-28 | 2017-07-27 | R&O Lab Sprl | MIXING CONTAINER ADAPTABLE TO ANY RECEPTOR CONTAINER |
CN108116759A (en) * | 2016-11-30 | 2018-06-05 | 陈雷 | A kind of Packaging Bottle |
JP3225484U (en) * | 2017-03-15 | 2020-03-12 | ステアライフ・インディア・プライベート・リミテッド | Dozer cap for liquid container |
WO2024005521A2 (en) * | 2022-06-30 | 2024-01-04 | 이성재 | Mixing device |
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US4195730A (en) * | 1978-06-20 | 1980-04-01 | General Foods Corporation | Container having separate storage facilities for two materials |
US5246142A (en) * | 1991-09-26 | 1993-09-21 | Dipalma Elio | Device for storing two products separately and subsequently mixing them |
JP2004268930A (en) * | 2003-03-05 | 2004-09-30 | Oshima Minako | Lid structure of container |
US20050126632A1 (en) * | 2003-12-11 | 2005-06-16 | Farrell Steven H. | Beverage modification system |
DE102004013270A1 (en) * | 2004-03-18 | 2005-09-29 | Robert Schumacher | Liquid container with a closable pouring unit is provided with a connector piece for joining the container to the pouring unit of another liquid container |
CN101056800A (en) * | 2004-09-17 | 2007-10-17 | 创新基金有限责任公司 | Universal bottle cap |
JP4580726B2 (en) * | 2004-10-08 | 2010-11-17 | 日本高圧電気株式会社 | Beverage container cap structure |
US20060231428A1 (en) * | 2005-04-13 | 2006-10-19 | Peter Stern | Powder/liquid dispenser |
US20080289976A1 (en) * | 2005-06-27 | 2008-11-27 | Henry John R | Container attachable to another container for mixing ingredients |
US20070079895A1 (en) * | 2005-10-12 | 2007-04-12 | Jeng Fu J | Bottle head structure |
US7635012B2 (en) * | 2006-06-12 | 2009-12-22 | Jpro Dairy International, Inc. | Sealed storage container with a coupling assembly |
FR2916187B1 (en) * | 2007-05-14 | 2009-07-17 | Marguerite Deperrois | CAP FOR CONTAINER FORMING ADDITIVE TANK |
HRP20070312A2 (en) * | 2007-07-16 | 2009-01-31 | Cedevita D.O.O. | Bottle closure with container for powder material for beverage preparation |
KR200445282Y1 (en) * | 2007-11-15 | 2009-07-16 | 티에이치바이오제닉스주식회사 | Bottle with cap and separating film |
EP2096041A1 (en) * | 2008-02-26 | 2009-09-02 | Nestec S.A. | A closure with built-in storing compartment |
KR20130095356A (en) * | 2012-02-20 | 2013-08-28 | 이성재 | Protective cover structure of dissimilar material receiving device |
-
2013
- 2013-10-03 FR FR1359590A patent/FR3011532B1/en active Active
-
2014
- 2014-09-03 CN CN201480054624.XA patent/CN105683056B/en active Active
- 2014-09-03 KR KR1020167010937A patent/KR102227708B1/en active IP Right Grant
- 2014-09-03 RU RU2016112338A patent/RU2660067C2/en active
- 2014-09-03 WO PCT/FR2014/052175 patent/WO2015049429A1/en active Application Filing
- 2014-09-03 AU AU2014331018A patent/AU2014331018B2/en active Active
- 2014-09-03 US US15/026,345 patent/US9758283B2/en active Active
- 2014-09-03 JP JP2016519920A patent/JP6402946B2/en active Active
- 2014-09-03 CA CA2925549A patent/CA2925549C/en active Active
- 2014-09-03 EP EP14777696.7A patent/EP3052402B1/en active Active
Non-Patent Citations (1)
Title |
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WO2015049429A1 (en) | 2015-04-09 |
FR3011532B1 (en) | 2015-10-30 |
AU2014331018A1 (en) | 2016-04-21 |
AU2014331018B2 (en) | 2017-12-14 |
EP3052402A1 (en) | 2016-08-10 |
CN105683056B (en) | 2017-10-20 |
JP6402946B2 (en) | 2018-10-10 |
RU2016112338A (en) | 2017-11-10 |
RU2660067C2 (en) | 2018-07-04 |
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KR20160064169A (en) | 2016-06-07 |
RU2016112338A3 (en) | 2018-05-28 |
FR3011532A1 (en) | 2015-04-10 |
JP2016536225A (en) | 2016-11-24 |
CA2925549A1 (en) | 2015-04-09 |
US9758283B2 (en) | 2017-09-12 |
CN105683056A (en) | 2016-06-15 |
BR112016007285A2 (en) | 2017-09-12 |
CA2925549C (en) | 2021-10-12 |
KR102227708B1 (en) | 2021-03-15 |
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