EP3006591A1 - Procédé de fabrication d'un composant revêtu et composant revêtu - Google Patents

Procédé de fabrication d'un composant revêtu et composant revêtu Download PDF

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Publication number
EP3006591A1
EP3006591A1 EP14188479.1A EP14188479A EP3006591A1 EP 3006591 A1 EP3006591 A1 EP 3006591A1 EP 14188479 A EP14188479 A EP 14188479A EP 3006591 A1 EP3006591 A1 EP 3006591A1
Authority
EP
European Patent Office
Prior art keywords
layer
ceramic material
base body
fiber
coated component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14188479.1A
Other languages
German (de)
English (en)
Other versions
EP3006591B1 (fr
Inventor
Christian Steffens
Viktor Bauder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INOMETA GmbH
Original Assignee
Inometa & Co KG GmbH
Inometa & Co KG GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inometa & Co KG GmbH, Inometa & Co KG GmbH filed Critical Inometa & Co KG GmbH
Priority to PL14188479T priority Critical patent/PL3006591T3/pl
Priority to EP14188479.1A priority patent/EP3006591B1/fr
Publication of EP3006591A1 publication Critical patent/EP3006591A1/fr
Application granted granted Critical
Publication of EP3006591B1 publication Critical patent/EP3006591B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/134Plasma spraying
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • C23C4/11Oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/129Flame spraying

Definitions

  • the invention relates to a method for producing a coated component and a coated component.
  • the document DE 93 05 806 U1 relates to a method for producing a pressure roller.
  • a layer of copper or a copper alloy is produced on a base body made of a thermoplastic fiber-reinforced plastic by means of plasma spraying.
  • the document EP 0 514 640 A1 discloses a method for applying a ceramic coating to a body by a thermal spraying method.
  • a main body has a synthetic resin layer contained particulate material.
  • the resin layer is treated before another layer is applied by thermal spraying.
  • the document EP 0 273 298 A2 discloses an erosion-resistant coating which adheres to a plastic by means of a binder.
  • the task is to specify improved technologies for coating components.
  • a corrosion-free primer for a coating should be provided.
  • a method of making a coated component comprises the following steps.
  • a base made of a fiber-reinforced plastic is provided.
  • a layer of a ceramic material is applied directly to the base body.
  • An area between the base body and the layer of ceramic material is free of an intermediate layer. In particular, the area is free of an adhesive.
  • a coated component is formed with a base body made of a fiber-reinforced plastic and a layer of a ceramic material arranged directly on the base body.
  • Avoiding the application of an adhesive results in fewer process steps, which makes the process faster and less expensive.
  • the properties of the component are improved. Corrosion of the adhesive, which has often occurred in the prior art, is avoided.
  • a fiber-reinforced plastic (also: fiber-plastic composite or fiber composite plastic) is a material that contains reinforcing fibers that are embedded in a plastic matrix. The matrix surrounds the reinforcing fibers bonded to the matrix by adhesive or cohesive forces.
  • the main body may for example consist of a glass fiber reinforced plastic (GRP).
  • GRP glass fiber reinforced plastic
  • CFRP carbon fiber reinforced plastic
  • PA fiber reinforced polyamide
  • EP fiber reinforced epoxy resin
  • the layer of ceramic material can lead to a breakdown strength of the component of up to 40 kV. Furthermore, the layer of ceramic material allows thermal insulation of the underlying body. For example, it protects against great heat. The layer of ceramic material is also resistant to wear, very hard, pressure resistant and has a high layer strength.
  • the layer of ceramic material can be applied to the base body in one or more layers. It may further be provided to apply a plurality of layers of different ceramic materials to the base body.
  • the layer of ceramic material can be applied with a layer thickness of 100 .mu.m to 3 mm.
  • the layer of ceramic material may have an adhesive tensile strength of greater than or equal to 10 N / mm 2 after curing. In another embodiment, the layer of ceramic material after curing may have an adhesive tensile strength of greater than or equal to 5 N / mm 2 .
  • the base body is provided on a substrate.
  • the substrate may contain a metal, for example aluminum, a metal alloy, for example steel, or a nonmetal.
  • the substrate may consist entirely of one of the abovementioned materials or material classes.
  • the layer of ceramic material is sprayed onto the base body.
  • the layer of ceramic material is applied to the base body by means of thermal spraying.
  • thermal spraying filler materials, so-called spray additives, inside or outside of a spray burner, are fused, melted or melted.
  • the filler metals are accelerated in a gas stream in the form of spray particles and onto the surface of the coated Applied body.
  • a layer formation can take place.
  • Suitable thermal spraying methods include, for example, high speed flame spraying (HVOF), vacuum plasma spraying (VPS) and atmospheric plasma spraying (APS).
  • As operating gases for the atmospheric plasma spraying argon, hydrogen, nitrogen or a combination thereof can be used.
  • nitrogen, a nitrogen-argon mixture, an argon-hydrogen mixture or argon can be used as conveying gas. Cooling may be by compressed air, carbon dioxide (CO2) or a combination thereof.
  • the layer of ceramic material is formed from an oxide-ceramic material, for example titanium dioxide (TiO 2), chromium oxide (Cr 2 O 3) or aluminum oxide (Al 2 O 3).
  • the layer of ceramic material may be formed from engineering ceramics or engineering ceramics.
  • the layer of a ceramic material in powder form is applied to the base body, for example by means of thermal spraying.
  • the powder may have a purity of more than 95%, preferably from 98% to 99.95%.
  • the powder may be provided in the form of powder forms as follows: mixed ceramic material, water atomized ceramic material, gas atomized ceramic material, coated ceramic material, chemically coated ceramic material, agglomerated ceramic material, agglomerated and sintered ceramic material, agglomerated and hollow spherical ceramic material, agglomerated and compacted ceramic material, molten and crushed ceramic material , molten and broken and mixed ceramic material as well as sintered and broken ceramic material.
  • Grains of the powder may have the following particle sizes: 10/5 ⁇ m, 22/5 ⁇ m, 45/16 ⁇ m, 25/5 ⁇ m, 45/20 ⁇ m and 30/10 ⁇ m. Grains of the powder may also have grain sizes in any combination of the aforementioned grain sizes. If the powder is applied by thermal spraying onto the base body, an internal axial powder feed, an internal radial powder feed or an external powder feed can take place.
  • the layer of ceramic material may be applied in the form of a suspension, for example as a water-based suspension or as an alcohol-based suspension.
  • the main body may contain a resin material.
  • the resin material may be, for example, an armin resin, a phenol resin, a polyester resin, a vinyl ester resin, a polyamide resin, an epoxy resin, an anhydride resin, and a bismaleimite-triazine resin.
  • the main body may further contain any combination of the aforementioned resins.
  • the component that is, both the base body and the layer of ceramic material, is formed free of an electrically conductive material.
  • the component may be free of metallic materials and / or metallic alloys.
  • the component can be formed free of a metallic adhesive. The component can thus be formed as a corrosion-free component.
  • the main body is provided with fibers in cross-layers.
  • the fibers can be wound and / or laid in cross-layers.
  • the cross layers may be formed with final circumferential positions.
  • the main body may have a fiber content between 20% by volume and 80% by volume, between 20% by volume and 60% by volume, between 30% by volume and 60% by volume or between 30% by volume. and 50% by volume.
  • the fibers can be made of glass, carbon, ceramic, plastic and / or natural fibers. Glass fibers may for example consist of R glass, E glass, C glass, D glass and S glass.
  • the component may be a rotationally symmetrical component, for example a roller with a cylindrical base body, on which a layer of ceramic material is arranged directly.
  • the component can be, for example, an anilox roller or a raster adapter or a raster sleeve for flexographic printing, a treatment roller or a treatment adapter or a treatment sleeve for a corona treatment.
  • Fig. 1 shows a schematic representation of a roller with a tubular substrate 1, a layer of a fiber-reinforced material 2 and a layer of a ceramic material 3. At both ends of the roller pins 4 are arranged.
  • the substrate 1 may be made of steel or aluminum, for example.
  • the layer of fiber-reinforced plastic 2 serves as an insulation barrier. It may comprise various types of fibers, for example glass fibers, carbon fibers, ceramic fibers, synthetic fibers and / or natural fibers.
  • the fibers are embedded in an Armin resin and applied to the tubular substrate 1 in wound cross-layers.
  • the layer of a ceramic material 3 is applied directly.
  • the ceramic layer 3 provides thermal insulation.
  • an oxide ceramic is provided in this embodiment.
  • Fig. 2 shows a further embodiment of a roller.
  • the tubular substrate 1 is shortened, so that an intermediate region 5 is formed between the ends of the substrate 1 and the pin 4.
  • a roller with a continuous tubular substrate 1 is shown.
  • Fig. 4 shows a roller with a fiber-reinforced layer 2, on which a ceramic layer 3 is arranged directly.
  • the fiber-reinforced layer is applied to a substrate 6 of a solid material, for example of steel or aluminum.
  • Fig. 5 shows a roller with a shortened tubular substrate 1, a fiber-reinforced layer 2 and a ceramic layer 3. At both ends of the roller, a receptacle 7 is formed.
  • FIG. 6 and 7 show schematic representations for components with arbitrary shapes.
  • a layer of a ceramic material 8 is arranged, for example, an oxide ceramic.
  • the fiber-reinforced base body 9 is arranged on a substrate 10.
  • Fig. 8 shows a schematic representation of an adapter or a sleeve.
  • a layer of a ceramic material 23 is arranged directly, for example of an oxide ceramic.
  • an intermediate layer 21 is arranged, which is formed with a compressible covering material.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Rolls And Other Rotary Bodies (AREA)
EP14188479.1A 2014-10-10 2014-10-10 Procédé de fabrication d'un rouleau revêtu et rouleau revêtu Active EP3006591B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL14188479T PL3006591T3 (pl) 2014-10-10 2014-10-10 Sposób wytwarzania powlekanego walca i powlekany walec
EP14188479.1A EP3006591B1 (fr) 2014-10-10 2014-10-10 Procédé de fabrication d'un rouleau revêtu et rouleau revêtu

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14188479.1A EP3006591B1 (fr) 2014-10-10 2014-10-10 Procédé de fabrication d'un rouleau revêtu et rouleau revêtu

Publications (2)

Publication Number Publication Date
EP3006591A1 true EP3006591A1 (fr) 2016-04-13
EP3006591B1 EP3006591B1 (fr) 2019-12-25

Family

ID=51743281

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14188479.1A Active EP3006591B1 (fr) 2014-10-10 2014-10-10 Procédé de fabrication d'un rouleau revêtu et rouleau revêtu

Country Status (2)

Country Link
EP (1) EP3006591B1 (fr)
PL (1) PL3006591T3 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8532300U1 (de) * 1985-11-15 1986-01-02 Felten & Guilleaume Energietechnik GmbH, 5000 Köln Walzenrohr für Druckmaschinen mit einem auswechselbaren Mantelrohr
EP0273298A2 (fr) 1986-12-23 1988-07-06 Mtu Motoren- Und Turbinen-Union MàœNchen Gmbh Procédé de revêtement de parts et pièces
US4997704A (en) 1989-06-02 1991-03-05 Technetics Corporation Plasma-arc ceramic coating of non-conductive surfaces
EP0514640A1 (fr) 1991-05-22 1992-11-25 SIGRI GREAT LAKES CARBON GmbH Procédé pour le revêtement d'un article en plastique renforcé par des fibres
DE9305806U1 (de) 1993-04-19 1993-06-09 Hoechst Ag, 6230 Frankfurt Druckwalze mit einer Hülse aus thermisch gewickelten faserverstärkten Thermoplasten und einer plasmagespritzten Kupfer- oder Kupferlegierungsbeschichtung
WO2007090707A2 (fr) * 2006-02-07 2007-08-16 Forschungszentrum Jülich GmbH Procédé de pulvérisation thermique faisant appel à une suspension colloïdale
DE102009048709A1 (de) 2009-10-08 2011-04-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verbundbauteil aus Metall und Faserverbundwerkstoff und Verfahren zur Herstellung
WO2012113426A1 (fr) * 2011-02-25 2012-08-30 Daimler Ag Procédé d'assemblage d'un élément constitué d'un matériau composite renforcé par des fibres de carbone à un élément en métal et système de liaison de tels éléments
DE102011120197A1 (de) * 2011-12-05 2013-06-06 Technische Universität Chemnitz Spindel,insbesondere Gewindespindel,und Verfahren zu deren Herstellung

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8532300U1 (de) * 1985-11-15 1986-01-02 Felten & Guilleaume Energietechnik GmbH, 5000 Köln Walzenrohr für Druckmaschinen mit einem auswechselbaren Mantelrohr
EP0273298A2 (fr) 1986-12-23 1988-07-06 Mtu Motoren- Und Turbinen-Union MàœNchen Gmbh Procédé de revêtement de parts et pièces
US4997704A (en) 1989-06-02 1991-03-05 Technetics Corporation Plasma-arc ceramic coating of non-conductive surfaces
EP0514640A1 (fr) 1991-05-22 1992-11-25 SIGRI GREAT LAKES CARBON GmbH Procédé pour le revêtement d'un article en plastique renforcé par des fibres
DE9305806U1 (de) 1993-04-19 1993-06-09 Hoechst Ag, 6230 Frankfurt Druckwalze mit einer Hülse aus thermisch gewickelten faserverstärkten Thermoplasten und einer plasmagespritzten Kupfer- oder Kupferlegierungsbeschichtung
WO2007090707A2 (fr) * 2006-02-07 2007-08-16 Forschungszentrum Jülich GmbH Procédé de pulvérisation thermique faisant appel à une suspension colloïdale
DE102009048709A1 (de) 2009-10-08 2011-04-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verbundbauteil aus Metall und Faserverbundwerkstoff und Verfahren zur Herstellung
WO2012113426A1 (fr) * 2011-02-25 2012-08-30 Daimler Ag Procédé d'assemblage d'un élément constitué d'un matériau composite renforcé par des fibres de carbone à un élément en métal et système de liaison de tels éléments
DE102011120197A1 (de) * 2011-12-05 2013-06-06 Technische Universität Chemnitz Spindel,insbesondere Gewindespindel,und Verfahren zu deren Herstellung

Also Published As

Publication number Publication date
PL3006591T3 (pl) 2020-06-29
EP3006591B1 (fr) 2019-12-25

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