EP2995674A1 - Utilisation d'un sulfate et procede pour la production d'un élément en acier par formage dans une machine de formage - Google Patents
Utilisation d'un sulfate et procede pour la production d'un élément en acier par formage dans une machine de formage Download PDFInfo
- Publication number
- EP2995674A1 EP2995674A1 EP14184415.9A EP14184415A EP2995674A1 EP 2995674 A1 EP2995674 A1 EP 2995674A1 EP 14184415 A EP14184415 A EP 14184415A EP 2995674 A1 EP2995674 A1 EP 2995674A1
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- European Patent Office
- Prior art keywords
- sulfate
- forming
- flat steel
- steel product
- coating
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
- C10M103/06—Metal compounds
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/53—Treatment of zinc or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/18—Ammonia
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/06—Groups 3 or 13
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/14—Group 7
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/16—Groups 8, 9, or 10
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/08—Solids
Definitions
- the invention relates to a use of a sulfate from the group "aluminum sulfate, ammonium sulfate, iron sulfate, magnesium sulfate".
- the invention relates to a method for producing a component by forming a flat steel product in a forming machine.
- the steel flat product to be formed in each case is placed in a forming machine and then shaped by the machine into the respective component.
- the transformation can be carried out as cold forming, that is to say as forming at temperatures below the recrystallization temperature of the respective steel of the flat steel products, or as hot forming, that is to say as forming at working temperatures which are above the recrystallization temperature.
- a typical example of such a forming process is deep-drawing, in which the flat steel product to be formed is pressed by means of a punch into a die.
- the shape of die and punch determine the shape that the flat steel product receives through the forming process.
- This friction can be very different locally, especially during the forming of flat steel products, because the material of the flat steel product is deformed differently in sections as part of the forming and thus the material of the flat steel product flows locally as differently at the deformation. It is therefore precisely in the production of complex-shaped components by deep drawing or comparable cold forming processes, which are usually achieved in large degrees of deformation and complex shapes are displayed, dynamically changing frictional conditions in which static and sliding friction can occur alternately.
- the frictional forces occurring in particular during cold forming can be so high that they cause the Interrupt continuous flow of the molding process and can cause a faulty impression of each component to be molded. At the same time, the unavoidable friction causes considerable tool wear.
- flat steel products in which a protective coating based on zinc or aluminum, which protects against corrosion or other environmental influences, prove particularly critical in the case of the actual flat steel product.
- the surfaces coming into contact with one another during the forming process are coated with lubricants.
- the forming tools can be protected and thus significantly increase tool life.
- the lubricant can be applied both to the flat steel product to be formed and to the surfaces of the tool which come into contact with the flat steel product.
- cold-working coating compositions based on mineral oil or similar hydrocarbons are disclosed in U.S.P. DE 101 15 696 A1 described. These coating agents include paraffinic or naphthenic based lubricants or vegetable or animal based ester oils.
- Coating agents based on carbonic acid esters are known.
- the coating compositions contain one or more components selected from the group of mono- and / or diesters of mono- or oligophosphoric acids, triglycerides and fatty acid methyl esters. These components are intended to serve primarily as a substitute for hydrocarbons of mineral oil or other petroleum distillates.
- the layer is applied as a solution to the flat steel product whose pH is greater than or equal to 12 but less than 13.
- the solution is made by anodic polarization of the surface applied to the galvanized surface of the flat steel product.
- the layer thus produced consists of zinc hydroxysulfate, also called "basic zinc sulfate".
- the object of the invention was to provide coating compositions which, with minimized lubricant requirement, on the one hand enable optimized tribological conditions in the forming of flat steel products and on the other hand are harmless in terms of their effect on the environment.
- this object is achieved by the use of a sulfate selected from the group consisting of "aluminum sulfate, ammonium sulfate, iron sulfate, magnesium sulfate" as a coating agent for improving the tribological behavior of a flat steel product Forming has been solved in a forming machine.
- the sulfates provided according to the invention as coating agents for flat steel products lead to a significant improvement of the tribological conditions during the forming of flat steel products.
- the sulfates selected according to the invention for use as coating compositions it is possible to achieve lubricating properties which are equivalent to the properties achieved with conventional lubricants of the type described above. This effect is fundamentally independent of whether the forming is carried out as cold or hot forming. Particularly effective prove the invention as Coating agents used sulfates in the cold forming of flat steel products.
- the sulfates used according to the invention as a coating material to improve the friction conditions during forming are distinguished by a good environmental compatibility and can be applied in a simple manner to the respective flat steel product.
- the sulfates used according to the invention can be removed just as easily from the steel components obtained after the forming process after the deformation. In the process, coating residues remaining on the steel component interfere at most insignificantly with the processes usually carried out after the forming in the further processing of steel components.
- concrete sulfate according to the invention particularly suitable for practical use are the sulfates from the group "aluminum-III-sulfate, ammonium sulfate, ferrous sulfate, ferric sulfate, magnesium sulfate".
- the sulfates provided according to the invention for use as coating agents in a process of the type according to the invention are suitable for coating the surfaces of the respective tool with which the flat steel product to be formed comes into contact during the forming process.
- the sulfates used in the invention can be sprayed as an aqueous solution to the respective critical surfaces of the forming tool, painted or applied in other already known in practice for this purpose manner.
- the respective Flat steel product is coated in the course of its production with the coating agent.
- the ease of application and the good adhesion of the sulfates used according to the invention have a particularly positive effect on the surface of the flat steel product to be coated.
- the sulfates which are proposed according to the invention for use as lubricants can also be applied to the respective flat steel product to be shaped using conventional coating systems, such as are commonly available for applying organic or inorganic layers to flat steel products of the type in question.
- the respective sulfate can be applied as a coating agent by dipping, spraying, coating or brushing on the flat steel product.
- the order of the sulfates according to the invention used as a coating agent to improve the state of friction in the deformation of flat steel products is particularly simple, that these sulfates wet well each surface to be coated and form correspondingly uniform layers, without requiring special precautions.
- the application of the sulfates used according to the invention as coating agents is particularly simple when they are applied as an aqueous solution. After a subsequent drying process, there is a dense, uniformly distributed thin sulfate layer on the respective flat steel product, which ensures optimum deformation behavior during a forming process, in particular a cold forming operation.
- the aqueous solution consists of two components, of which one component is water as a solvent and the other component is the respective sulfate as a tribologically active ingredient. If distilled water is used as the solvent, this has the advantage that it can not interfere with the function of the coating by foreign ions.
- a sufficiently thick and dense tribologically effective coating for the purposes of the invention on the respective surface to be coated of flat steel products or forming tools results when the content of the tribologically active sulfate component in the aqueous solution 0.2 to 1 mol / l (based on the SO 4 2- ion concentration) is, with good effective coatings in practice then arise reliable, if the content of the present invention provided sulphate component of the aqueous solution 0.4 to 0.7 mol / l (based on the SO 4 2 - ion concentration) is.
- the layer formed from the respective coating agent on the flat steel product or the surface of the forming tool to be coated can be applied with a coating weight of 5 to 50 mg / m 2 .
- Optimal effects occur when the occupational weight is 10 - 30 mg / m 2 .
- the surface in question can be cleaned alkaline prior to application of the coating composition.
- the coefficient of friction of the respective coated surface is markedly improved.
- the friction coefficient of the respective coated surface is regularly reduced to ⁇ 0.15.
- the Zn-based coating can be applied in a conventional manner as a pure zinc layer, as a zinc alloy layer containing Mg, Al or Si, for example electrolytically or by hot dip coating on the respective steel substrate. It is also possible to coat flat steel products with Al-based coatings in accordance with the invention in order to improve their forming behavior during cold or hot forming.
- coatings produced by the coating compositions selected according to the invention thus achieve frictional properties which are certainly consistent with the frictional properties of coatings consist of conventional, commonly used to improve the tribological properties means.
- an aqueous solution was prepared in which 90 g of ammonium sulfate ((NH 4 ) 2 SO 4 ) in 1 l of water (dist.) was dissolved, so that the ammonium sulfate content of the aqueous solution at 90 g / l was.
- the native pH of the resulting solution was 5.3.
- aqueous solution thus obtained has been applied at room temperature to the previously alkaline-cleaned steel flat product sheet by means of a so-called "chemcoater" which is customary in industry.
- a "chemcoater” is a part of the plant used in the steel industry for applying chemical substances to be applied as an aqueous solution to galvanized flat carbon steel.
- coaters are used for the application of water-soluble media, which serve for the pretreatment of the respective flat steel product for a subsequent coating or film coating or to improve the corrosion protection.
- Various treatment chemicals can be applied via rollers to the flat steel product to be coated in each case. Subsequently, the coated steel flat product passes through an oven in which the coating is dried.
- ferrous sulfate FeSO 4
- 1 1 of fully demineralized water so that the iron sulfate content of the aqueous solution was 189 g / l.
- the native pH of the resulting solution was 2.2.
- the aqueous solution was applied as in Experiment 1 at room temperature by means of the coater already described above to the previously alkaline-cleaned steel flat product.
- the application parameters are also given in Table 1.
- a conventional flat steel product also in the form of a Zn-coated thin sheet metal strip, has been coated with a tribologically active aluminum sulphate layer.
- the aqueous solution has also been applied in this case at room temperature by means of the coater already described above on the previously alkaline-cleaned steel flat product.
- the application parameters are also given in Table 1.
- the term "setting dipping and application roller” designates the extent to which the nip between the dipping and the application roller is smaller than the thickness of the processed flat steel product. With “PMT” at the same time the so-called “peak metal temperature” is designated.
- the tribologically active layers which consist of the sulfates proposed according to the invention for use, thus achieve the same effect as the conventional coatings consisting for example of ZnSO 4 .
- Table 1 attempt Operation of the coater peripheral speeds Setting dipping and application roller Thickness of steel product Gap width between dipping and application roller bearing weight drying oven PMT applicator roll dipping roller transport roller temperature dwell [M / min] [M / min] [M / min] [.Mu.m] [Mm] [.Mu.m] [mg / m 2 ] [° C] [S] [° C] 1 Reverse 30 10 25 -400 1 0.9 30 100 100 71 2 Reverse 25 10 23 -500 1 0.9 30 100 100 100 71 3 Mit pleasant 30 10 40 -400 1 0.9 30 100 35 71
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14184415.9A EP2995674B1 (fr) | 2014-09-11 | 2014-09-11 | Utilisation d'un sulfate et procede pour la production d'un élément en acier par formage dans une machine de formage |
KR1020177009712A KR102472493B1 (ko) | 2014-09-11 | 2015-08-19 | 황산염의 사용 및 성형 기계에서 성형에 의한 강 부품의 제조 방법 |
CN201580049081.7A CN106687571B (zh) | 2014-09-11 | 2015-08-19 | 硫酸盐的用途及通过在成型机中的成型制造钢构件的方法 |
JP2017513483A JP6694876B2 (ja) | 2014-09-11 | 2015-08-19 | 硫酸塩の使用、および成形機における成形により鋼部品を製造するための方法 |
US15/509,524 US10072229B2 (en) | 2014-09-11 | 2015-08-19 | Use of a sulphate, and method for producing a steel component by forming in a forming machine |
PCT/EP2015/069018 WO2016037814A1 (fr) | 2014-09-11 | 2015-08-19 | Utilisation d'un sulfate et procédé de fabrication d'une pièce en acier par formage sur une machine de formage |
CA2958500A CA2958500C (fr) | 2014-09-11 | 2015-08-19 | Utilisation d'un sulfate et procede de fabrication d'une piece en acier par formage sur une machine de formage |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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EP14184415.9A EP2995674B1 (fr) | 2014-09-11 | 2014-09-11 | Utilisation d'un sulfate et procede pour la production d'un élément en acier par formage dans une machine de formage |
Publications (2)
Publication Number | Publication Date |
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EP2995674A1 true EP2995674A1 (fr) | 2016-03-16 |
EP2995674B1 EP2995674B1 (fr) | 2020-07-15 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP14184415.9A Active EP2995674B1 (fr) | 2014-09-11 | 2014-09-11 | Utilisation d'un sulfate et procede pour la production d'un élément en acier par formage dans une machine de formage |
Country Status (7)
Country | Link |
---|---|
US (1) | US10072229B2 (fr) |
EP (1) | EP2995674B1 (fr) |
JP (1) | JP6694876B2 (fr) |
KR (1) | KR102472493B1 (fr) |
CN (1) | CN106687571B (fr) |
CA (1) | CA2958500C (fr) |
WO (1) | WO2016037814A1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018215236A1 (fr) * | 2017-05-23 | 2018-11-29 | Thyssenkrupp Steel Europe Ag | Amélioration de l'aptitude au formage à froid d'un revêtement à base d'aluminium par addition par alliage de métaux alcalinoterreux |
DE102018209737A1 (de) * | 2018-06-18 | 2019-12-19 | Thyssenkrupp Ag | Trennschicht für die Warmumformung |
WO2021074388A1 (fr) * | 2019-10-18 | 2021-04-22 | Thyssenkrupp Steel Europe Ag | Procédé de production d'un produit d'acier plat et procédé de production d'un composant à partir de celui-ci |
US11078573B2 (en) | 2016-01-19 | 2021-08-03 | Thyssenkrupp Ag | Method for producing a steel product with a Zn coating and a tribologically active layer deposited on the coating, and a steel product produced according to said method |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016218957A1 (de) | 2016-09-30 | 2018-04-05 | Thyssenkrupp Ag | Temporäre Korrosionsschutzschicht |
WO2019073273A1 (fr) | 2017-10-12 | 2019-04-18 | Arcelormittal | Procédé de traitement de feuille métallique et feuille métallique traitée avec ce procédé |
WO2019073274A1 (fr) * | 2017-10-12 | 2019-04-18 | Arcelormittal | Procédé de traitement de feuille métallique et feuille métallique traitée à l'aide de ce procédé |
EP3620502A1 (fr) * | 2018-09-10 | 2020-03-11 | Carl Bechem Gmbh | Composition destiné à la production d'une composition lubrifiante |
WO2021074672A1 (fr) | 2019-10-16 | 2021-04-22 | Arcelormittal | Procédé de traitement de feuille métallique et feuille métallique traitée à l'aide de ce procédé |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB166949A (en) * | 1920-04-21 | 1921-07-21 | Rustproofing Syndicate Ltd | New or improved process for the prevention of black oxide of iron on ferrous metal forgings and the like |
GB739313A (en) * | 1952-11-08 | 1955-10-26 | Pyrene Co Ltd | Improvements relating to the production of oxalate coatings on metals |
US4168241A (en) * | 1978-03-14 | 1979-09-18 | Aichi Steel Works, Limited | Lubricant and method for non-chip metal forming |
SU1204283A1 (ru) * | 1983-11-05 | 1986-01-15 | Предприятие П/Я М-5481 | Состав дл нанесени на поверхность стальных листов перед гор чей прокаткой |
US6194357B1 (en) * | 1996-06-21 | 2001-02-27 | Henkel Corporation | Waterborne lubricant for the cold plastic working of metals |
DE10007625A1 (de) | 2000-02-18 | 2001-08-23 | Henkel Kgaa | Schmiermittel zur Umformung von Metallen |
DE10115696A1 (de) | 2001-03-29 | 2002-10-10 | Henkel Kgaa | Schmierstoffmischung und ihre Verwendung |
DE69906555T2 (de) | 1998-09-15 | 2004-03-04 | Sollac S.A. | Verzinkte, mit einer hydroxysulfat-schmierschicht überzogene stahlbleche und verfahren zur herstellung |
US20040255818A1 (en) * | 2003-06-23 | 2004-12-23 | Pawloski David Roy | Lubricating chemical coating for metalworking |
DE102008016348A1 (de) | 2008-03-29 | 2009-10-15 | Stefan Graichen | Hochtemperaturschmiermittel, insbesondere Gesenkschmiermittel, enthaltend mindestens einen Oxidationskatalysator |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2864552B1 (fr) * | 2003-12-24 | 2006-07-21 | Usinor | Traitement de surface par hydroxysulfate |
DE102006039307B3 (de) * | 2006-08-22 | 2008-02-21 | Thyssenkrupp Steel Ag | Verfahren zum Beschichten eines 6-30 Gew.% Mn enthaltenden warm- oder kaltgewalzten Stahlbands mit einer metallischen Schutzschicht |
EP2802682B1 (fr) * | 2012-01-10 | 2020-09-23 | ArcelorMittal | Utilisation d'une solution contenant des ions sulfates pour réduire le noircissement ou le ternissement d'une tôle lors de son stockage et tôle traitée par une telle solution |
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2014
- 2014-09-11 EP EP14184415.9A patent/EP2995674B1/fr active Active
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2015
- 2015-08-19 CN CN201580049081.7A patent/CN106687571B/zh active Active
- 2015-08-19 KR KR1020177009712A patent/KR102472493B1/ko active IP Right Grant
- 2015-08-19 US US15/509,524 patent/US10072229B2/en not_active Expired - Fee Related
- 2015-08-19 WO PCT/EP2015/069018 patent/WO2016037814A1/fr active Application Filing
- 2015-08-19 CA CA2958500A patent/CA2958500C/fr active Active
- 2015-08-19 JP JP2017513483A patent/JP6694876B2/ja active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB166949A (en) * | 1920-04-21 | 1921-07-21 | Rustproofing Syndicate Ltd | New or improved process for the prevention of black oxide of iron on ferrous metal forgings and the like |
GB739313A (en) * | 1952-11-08 | 1955-10-26 | Pyrene Co Ltd | Improvements relating to the production of oxalate coatings on metals |
US4168241A (en) * | 1978-03-14 | 1979-09-18 | Aichi Steel Works, Limited | Lubricant and method for non-chip metal forming |
SU1204283A1 (ru) * | 1983-11-05 | 1986-01-15 | Предприятие П/Я М-5481 | Состав дл нанесени на поверхность стальных листов перед гор чей прокаткой |
US6194357B1 (en) * | 1996-06-21 | 2001-02-27 | Henkel Corporation | Waterborne lubricant for the cold plastic working of metals |
DE69906555T2 (de) | 1998-09-15 | 2004-03-04 | Sollac S.A. | Verzinkte, mit einer hydroxysulfat-schmierschicht überzogene stahlbleche und verfahren zur herstellung |
DE10007625A1 (de) | 2000-02-18 | 2001-08-23 | Henkel Kgaa | Schmiermittel zur Umformung von Metallen |
DE10115696A1 (de) | 2001-03-29 | 2002-10-10 | Henkel Kgaa | Schmierstoffmischung und ihre Verwendung |
US20040255818A1 (en) * | 2003-06-23 | 2004-12-23 | Pawloski David Roy | Lubricating chemical coating for metalworking |
DE102008016348A1 (de) | 2008-03-29 | 2009-10-15 | Stefan Graichen | Hochtemperaturschmiermittel, insbesondere Gesenkschmiermittel, enthaltend mindestens einen Oxidationskatalysator |
Non-Patent Citations (3)
Title |
---|
DATABASE WPI Week 198633, Derwent World Patents Index; AN 1986-217980, XP002736455 * |
FRITZ KLOCKE; WILFRIED KÖNIG: "Fertigungsverfahren 4", vol. 4, 2006, SPRINGER-VERLAG |
PROF. DR.-ING. FRITZ KLOCKE; PROF. EM. DR.-ING. DR. H.C. MULT; WILFRIED KÖNIG: "Fertigungsverfahren", vol. 4, 2006, SPRINGER-VERLAG, article "Umformen" |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11078573B2 (en) | 2016-01-19 | 2021-08-03 | Thyssenkrupp Ag | Method for producing a steel product with a Zn coating and a tribologically active layer deposited on the coating, and a steel product produced according to said method |
WO2018215236A1 (fr) * | 2017-05-23 | 2018-11-29 | Thyssenkrupp Steel Europe Ag | Amélioration de l'aptitude au formage à froid d'un revêtement à base d'aluminium par addition par alliage de métaux alcalinoterreux |
DE102018209737A1 (de) * | 2018-06-18 | 2019-12-19 | Thyssenkrupp Ag | Trennschicht für die Warmumformung |
WO2021074388A1 (fr) * | 2019-10-18 | 2021-04-22 | Thyssenkrupp Steel Europe Ag | Procédé de production d'un produit d'acier plat et procédé de production d'un composant à partir de celui-ci |
Also Published As
Publication number | Publication date |
---|---|
WO2016037814A1 (fr) | 2016-03-17 |
US10072229B2 (en) | 2018-09-11 |
US20170260471A1 (en) | 2017-09-14 |
CN106687571A (zh) | 2017-05-17 |
JP6694876B2 (ja) | 2020-05-20 |
KR102472493B1 (ko) | 2022-12-01 |
JP2017534700A (ja) | 2017-11-24 |
CN106687571B (zh) | 2019-09-13 |
CA2958500C (fr) | 2019-01-15 |
CA2958500A1 (fr) | 2016-03-17 |
KR20170052670A (ko) | 2017-05-12 |
EP2995674B1 (fr) | 2020-07-15 |
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