EP2975107A1 - Handgeschirrspülmittel mit verbesserten Schaumeigenschaften - Google Patents

Handgeschirrspülmittel mit verbesserten Schaumeigenschaften Download PDF

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Publication number
EP2975107A1
EP2975107A1 EP14002454.8A EP14002454A EP2975107A1 EP 2975107 A1 EP2975107 A1 EP 2975107A1 EP 14002454 A EP14002454 A EP 14002454A EP 2975107 A1 EP2975107 A1 EP 2975107A1
Authority
EP
European Patent Office
Prior art keywords
weight
foam
hand dishwashing
dishwashing composition
liquid hand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14002454.8A
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English (en)
French (fr)
Inventor
Fikret Koc
Ahmet Ergun
Murat Uzumcu
Serdar Soylemez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hayat Kimya Sanayi AS
Original Assignee
Hayat Kimya Sanayi AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hayat Kimya Sanayi AS filed Critical Hayat Kimya Sanayi AS
Priority to EP14002454.8A priority Critical patent/EP2975107A1/de
Priority to PCT/TR2015/000286 priority patent/WO2016010501A1/en
Publication of EP2975107A1 publication Critical patent/EP2975107A1/de
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the field of the present invention is liquid hand dishwashing compositions.
  • This application relates to dishwashing compositions with high foam duration capabilities. This application relates to liquid hand dishwashing compositions with high foaming height in presence of oil.
  • This application relates to liquid hand dishwashing compositions with high active agent content.
  • This application relates to effective and economically feasable liquid hand dish washing compositions.
  • this application relates to the specific compositions to fullfill all the said requirements and fullfill the need in this particular field.
  • compositions are more effective thus appealing more to the costumer due to desired long lasting foaming power and economic feasibility.
  • Aids for hand dishwashing are detergents of gel or mostly liquid form.
  • Hand dishwashing detergents remove food soils, hold soil in suspension and provide long lasting suds that indicate how much cleaning power is left in the wash water.
  • High foaming capacity of hand dishwashing detergents is a desired propertiy. Foaming is an indication of cleaning strength. High foaming properties show that detergent composition has still its cleaning capabilities especially with regard to soil and oil removing.
  • Another aspect of the foaming capability is the duration of the foam which influence cleaning effectiveness as well. Long duration of foam provides enhanced cleaning strength of the hand dishwashing cleaning composition.
  • WO9404640 Burdon Allan teaches use of high concentration of high loaded ethoxylated alkyl ether sulphonate which further comprise earth alkaline salts and alcohol. Very high content of actives is desadvantageous for aimed hand dishwashing compositions of present inventions.
  • compositions meet the by costumer desired hand dishwashing product owing high foam durability and high load properties.
  • the present invention relates to new dishwashing compositions which are superior to commercially available products on the market with regard to foaming potentcy.
  • compositions which have improved foaming properties By the search of favourable compositions, the present inventor encountered unexpectedly with compositions which have improved foaming properties.
  • liquid hand dishwashing compositions having foam of high duration.
  • LABSA Linear Alkyl Benzene Sulfonic Acid
  • This compound is used as its alkali metal salt prefferably as its sodium salt, belonging to the group of anionic surfactants with regard to its functionality and structure. It has good foaming capability with big bubbles. But their duration is of short period of time.
  • compositions with improved foaming properties there appeared to be necessary to apply not lone actives for this purpose but combinations of the ingredients.
  • the present inventor surprisingly found that anionic surfactant, foam booster compound, amphotheric surfactant, organic solvent and water comprising compositions show the desired long lasting foaming behaviour.
  • compositions show the desired long lasting foaming behaviour.
  • compositions show the desired long lasting foaming behaviour.
  • composition is unique, good working and superior to the marketed products with respect to foam durability.
  • compositions are superior to the existing LABSA or LAS, Long Alkyl Sulfonate containing marketed products with respect to skin compatibility.
  • LABSA and LAS are known skin irritants. They are replaced in the present invention with sodium lauryl sulphate ether which is less irritant. Additionally added cocoamido propyl betaine contribute to the dermatological improvement of the composition and decrease irritation. Additionally to that the combination of SLES with cocoamido propyl betaine decrease the amount of SLES necessary for the present invention which contributes to skin compatability additionally.
  • Surfactants are primary ingredients in a liquid hand dishwashing detergent. Often a combination of surfactants is used to produce good grease cutting capability, soil suspension and stable sud levels.
  • Stability and dispensing aids are added to keep the product homogeneous under varying storage conditions. Hydrotropes and salts are often used.
  • Preservatives are added if needed in small amounts to help prevent any microbiological growth in the product.
  • Suds generation is an important signal to the costumer that a hand dishwashing detergent is effective in removing soils and in particular, greasy oily residues.
  • LAS Lauryl Sulfate, SLS and Linear Alkyl Sulfate, LAS are primary surfactants added to classical dishwashing compositions but with decrease of foam height consequences.
  • Exemplarly LABSA containing compositions foam decrease according to the tests of inventor within less than 1 minute considerably, which is not desireable by the hand diswashing user. In comparison present invention compositions foam do not deflate before 3 minutes.
  • the present invention may contain following ingredients;
  • Anionic surfactants used in the dishwashing compositions of the present invention comprise sulfate surfactants, sulfosuccinate surfactants, alpha olefin sulfonate surfactants, sulfonate surfactants and mixtures thereof.
  • anionic surfactant of the present invention is comprising sodium lauryl ether sulfate, sodium alkyl glyceryl ether sulfonate, alcohol ether sulfate, alkyl ethoxy sulfonate.
  • anionic surfactant of the present invention is comprising of alkyl ethoxy sulfonate surfactants having average ethoxylation degree from 0.01 to 10, preferably from 0.02 to 4 and more preferably from 0.03 to 3.
  • anionic surfactant of the present invention is selected from sodium lauryl ether sulfonate with 1-6 ethoxy groups, more preferably with 1 ethoxy group.
  • compositions of the present invention comprise 10% to %30 preferably 12% to %24 of anionic surfactant.
  • Amphoteric surfactants used in the liquid hand dishwashing compositions of the present invention comprise alkyl dimethyl betaine, alkyl carbo betaine, alkyl sulfo betaine, alkyl hydroxysulfobetaine, alkylamideamine-type betaine and alkylimidazoline-type betaine.
  • amphoteric surfactant of the present invention is comprising alkyl amidopropylbetaine, N,N-dimethylacetic acid betaine, alkylamidepropyl-N,Ndimethyl-2-hydroxypropylsulfobetaine, alkylamidepropyl N, N-dimethylpropylsulfobetaine, lauramide propyl- N,N-dimethylacetic acid betaine, myristamidepropyl-N, N-dimethylacetic acid betaine, Cocamidepropyl-N,N-dimethylacetic acid betaine and the like.
  • amphoteric surfactant of the present invention is cocamidepropyl-N,N-dimethylacetic acid betaine.
  • Said betaines are particularly preferable in terms of detergency, foam producing ability and rinsing property.
  • amidobetaine-type amphoteric surfactants can be used singly or in combination of two or more. They are incorporated in amounts of 1% -15% by weight. When the amount of amidobetaine type amphoteric surfactant is less than 1%, sufficient detergency cannot be obtained. On the other hand, amounts exceeding 15% are not economical, because the effects of the amphoteric surfactants are saturated and cannot be enhanced any more.
  • compositions of the present invention comprise 1% to %15 prefferably 1% to %8 of said betaine compound(s).
  • Foam boosting compounds used in the present invention comprise amine oxide such as alkyl- or alkenyl- amine oxides having a linear or branched alkyl or alkenyl group having 1 to 24 carbon atoms.
  • amine oxide compounds used in the present invention is comprising, lauryl amido propyl amine oxide, myristal amido propyl amine oxide, lauryl dimethyl amine oxide, alkyl dimethyl amine oxides, cocodimethyl amine oxide, alkyl dihydroxyethyl amine oxide, coconut allyl dimethyl amine oxide, cocoamidopropyl amine oxide and cocoamide diethanolamide.
  • foam boosting compound of the present invention is cocodimethyl amine oxide.
  • Said compounds add foam enhancement and stability, emulsification and viscosity building properties to the compositions of present invention.
  • compositions of the present invention comprise 1% to %15 prefferably 2% to %12 of amine oxide compound.
  • Solvents are needed for preventing phasing out the composition and to dissolve some ingredients. Additionally by hand dishwashing compositions they add to the rinsing properties of the composition by dripping out the water from surface of dishes, avoiding water and mineral stains on dishes and providing short drying times.
  • Organic solvents are the main solvents used for this purpose and comprise for the present invention ethanol, propanol, isopropanol, butoxy propoxy propanol, butoxy propanol, butoxy ethanol, , butyl diglycoether, benzyl alcohol, propoxy propoxy propanol, polypropylene glycol, ethers and diethers, alkoxylated glycols, C6-C16 glycol ethers, aliphatic branched alcohols, alkoxylated aliphatic alcohols, alkoxylated linear C1-C5 alcohols, linear C1-C5 alcohols and mixtures thereof.
  • Preffered solvents of the present invention are ethanol, isopropanol, glycol, glycerin, polyethylene glycol, most prefferable ethanol.
  • Used solvent amounts in the present invention may vary between 0.01% to 25% prefferably 1% to 10%.
  • Surfactants interact with skin by binding to skin protein and causing swelling.
  • An example is sodium lauryl sulfate SLS which is limiting its use by hand dishwashing detergents.
  • a solution to this problem constitute use of mild surfactants, use of ethoxylated alcohols and skin compatibility agents which is provided by the present invention.
  • compositions at a concentration of 0 % to 3 % weight percentage comprise benzalkonium chloride, benzethonium chloride, sodium benzoate, 5-bromo-5-nitro-1,3 dioxane, 2-bromo-2-nitropropane-1, 3-diol, alkyl trimethyl ammonium bromide; N- (hydroxymethyl)-N- (1, 3-dihydroxy methyl-2, 5-dioxo-4-imidaxolidinyl-N'- (hydroxy methyl) urea; 1-3-dimethyol- 5, 5-dimethyl hydantoin; formaldehyde; iodopropynl butyl carbamate, butyl paraben; ethyl paraben; methyl paraben; propyl paraben, mixture of methyl isothiazolinone/methyl-chloroisothiazoline; mixture of phenoxythanol/buty
  • Prefered preservative of the present invention is mixture of 5-chloro-2-methyl-4-isothiazol-3-one and 2-methyl-4-isothiazol- 3-one.
  • compositions of the present invention may contain builder which act as a complexation agent as well, such as ethylene diamine tetra acetic acid (EDTA) and its salts.
  • EDTA ethylene diamine tetra acetic acid
  • Prefered salts are alkali salts most prefered tetrasodium salt of EDTA.
  • Polycarboxylated organic acids like citric acid and its salts may be used for complexation purposes as well beside polyphosphate and polyacrylate among others.
  • PH adjusting agents of basic nature such as sodium hydroxide, potassium hydroxide, alkali metal hydroxide, alkali metal carbonate, bicarbonate may be added to the present invention compositions.
  • organic acids such as citric acid, fumaric acid, inorganic acids such as hydrochloric acid and sulfuric acid may be added to the present invention compositions.
  • salts may be added to the compositions of the present invention.
  • Said salts may be organic or inorganic nature such as sodium chloride, magnesium sulfate, calcium chloride, sodium citrate, sodium sulfate among others.
  • fragrance perfume, hydrotropes, dye, thickening agents among others may be added to the present invention compositions.
  • Foam height of aqueous solution of respective hand dishwashing compositions are indicative for improved foaming properties thereby for improved cleaning capabilities.
  • cleaning composition is mixed with 500ml of tap water of 22 FR of water hardness, whereby 1 FR is corresponding to 10mg Ca in 1 LT water. 50 ml of this mixture is taken and placed into holding cylinder of KRUSS DFA 100 device. Holding cylinder has the dimensions of 250mm height and 40mm diameter with a propeller at the bottom of the cylinder. This test mixture is stirred 120 seconds with 4000 rpm , stopped, waited 60 seconds and foam height is measured via light transmittance.
  • Example 1 which is the prefered composition of present invention ,has highest foam height which is indicative for foaming strength.
  • Example 2 lacks of amine oxide compound which is specific for foam enhancement therefore resulting as low foam height.
  • Example 3 lacks of organic solvent, apart from that very similar to Ex 1. Considering very similar foam height, organic solvents, in this case ethanol seems not to have an impact on foam height in absence of oil.
  • Comparative Example 1 comprising LABSA which is a good foaming agent but its foam has big bubbles with low duration. This agent is an irritant as well which makes it less desirable.
  • Conclusively composition of present invention has high foam height compared to prior art compositions. With regard to foam height which is related to cleaning strength as well, presence of amine oxide compounds seems to be the most crucial.
  • Example 1 which is the prefered composition of present invention ,has greatest foam height which is indicative for foaming strength in dishwashings with oil presence.
  • Example 2 lacks of amine oxide compound which is specific for reduced foam, therefore resulting as low foam height in dishwashings with oil presence.
  • Example 3 lacks of organic solvent, apart from that very similar to Ex 1 composition. Considering low foam height,organic solvents, in this case ethanol seems to have a positive impact in dishwashings with oil prersence with regard to foam height consequently foam strength.
  • Comparative Example 1 comprising LABSA which is a good foaming agent but its foam has big bubbles with short duration in case of dishwashings with oil presence as well.
  • Conclusively compositions of present invention has elevated foam height compared to prior art compositions in dishwashings containing oil.
  • Amine oxide has crucial share on foaming performance.
  • organic solvent addition has a positive impact on foaming capability in presence of oily soil.
  • cleaning composition 0.4 gram is mixed with 500ml of tap water of 22 FR of water hardness, whereby 1 FR is corresponding to 10mg Ca in 1 LT water. 50 ml of this mixture is taken and placed into holding cylinder of KRUSS DFA 100 device. This test mixture is stirred 120 seconds with 4000 rpm , stopped, and waited until a drop in foam height occurs which is observable from time -foam height curve as the sustained line becomes a curve downwards.
  • Example 1 which is the prefered composition of present invention ,has longest foam resistance which is indicative for foaming strength.
  • Example 2 lacks of amine oxide compound which is specific for foam enhancement therefore resulting as short foam resistance.
  • Example 3 lacks of organic solvent apart from that very similar to Ex 1 composition. Considering moderately lower foam resistance with regard to ethanol comprising Ex 1 composition ,organic solvents, in this case ethanol seems to have a positive impact with regard to foam resistance.
  • Comparative Example 1 comprising LABSA as a good foaming agent but with low duration, additionally lacking of amine oxide seems to lead to decreased foam resistance.
  • compositions of present invention has late foam breaking point which is indicative for foam resistance and high cleaning performance.
  • 0.4 gramm of cleaning composition is mixed with 500ml of tap water of 22 FR of water hardness, whereby 1 FR is corresponding to 10mg Ca in 1 LT water. 50 ml of this mixture is taken and placed into holding cylinder of KRUSS DFA 100 device. This test mixture is stirred 120 seconds with 4000 rpm , stopped, waited for 10 seconds and foam height is measured against time via light transmittance.
  • Foam height decrease in % 130 sec height - 250 sec height/ 130 second height x 100
  • 130 sec is corresponding to 120 sec stirring+ 10 sec waiting
  • 250 sec is corresponding to 120 sec waiting after 120 sec stirring +10 sec waiting
  • Example 1 which is the prefered composition of the present invention , has the most persistent foam height. With %1.6 foam height decrease it is by far the best composition with respect of foam duration which is indicative for better cleaning performance as well.
  • Example 2 lacks of amine oxide compound which is specific for foam enhancement therefore resulting as short foam resistance and drop of %42 height vs time.
  • Example 3 lacks of organic solvent apart from that very similar to Ex 1 composition. Considering moderate foam duration with regard to ethanol comprising Ex 1 composition ,organic solvents, in this case ethanol seems to have a positive impact with regard to foam duration.
  • Comparative Example 1 comprising LABSA as a good foaming agent but with low duration, additionally lacking of amine oxide seems to lead to decreased foam duration.
  • compositions of present invention has better foam duration properties in comparison with prior art compositions.
  • LABSA containing prior art compositions has low foam duration.
  • amine oxides can be considered as essential for foam duration. Presence of organic solvent has a moderate influence for foam duration.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP14002454.8A 2014-07-14 2014-07-16 Handgeschirrspülmittel mit verbesserten Schaumeigenschaften Withdrawn EP2975107A1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP14002454.8A EP2975107A1 (de) 2014-07-16 2014-07-16 Handgeschirrspülmittel mit verbesserten Schaumeigenschaften
PCT/TR2015/000286 WO2016010501A1 (en) 2014-07-14 2015-07-24 Hand dishwashing composition with improved foaming properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14002454.8A EP2975107A1 (de) 2014-07-16 2014-07-16 Handgeschirrspülmittel mit verbesserten Schaumeigenschaften

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EP2975107A1 true EP2975107A1 (de) 2016-01-20

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3243897B1 (de) 2016-05-09 2019-02-13 The Procter & Gamble Company Reinigungsmittelzusammensetzung umfassend ein fettsäure transformierendes enzym
EP3511402A1 (de) * 2018-01-16 2019-07-17 The Procter & Gamble Company Reinigungsmittel mit einer umgekehrten behälteranordnung und eine viskose reinigungszusammensetzung
EP3511405A1 (de) * 2018-01-16 2019-07-17 The Procter & Gamble Company Reinigungsprodukt mit einem umgekehrten und viskoelastischen reinigungsmittel
EP4134419A1 (de) * 2021-08-11 2023-02-15 Henkel AG & Co. KGaA Verfahren zum gleichzeitigen maximieren der mildheit und der reinigungsleistung einer flüssigen spülmittelzusammensetzung
DE102023203548A1 (de) 2023-04-18 2024-10-24 Henkel Ag & Co. Kgaa Fettlösende Handgeschirrspülmittel mit optimierter Tenisdkombination

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017140472A1 (en) * 2016-02-17 2017-08-24 Unilever N.V. Dishwash composition comprising rinse-activatable antifoam
CN115948205B (zh) * 2022-12-29 2024-08-16 广州立白企业集团有限公司 一种洗碗巾及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994004640A1 (en) 1992-08-21 1994-03-03 The Procter & Gamble Company Concentrated liquid detergent composition comprising an alkyl ether sulphate and a process for making the composition
CA2237694A1 (en) 1995-11-16 1997-05-22 Amway Corporation Liquid dishwashing detergent
US5990065A (en) 1996-12-20 1999-11-23 The Procter & Gamble Company Dishwashing detergent compositions containing organic diamines for improved grease cleaning, sudsing, low temperature stability and dissolution
US20040005991A1 (en) * 2000-11-29 2004-01-08 The Procter & Gamble Company Hand dishwashing composition containing a suds suppresser and a method of use therefor
US20040029757A1 (en) * 2002-08-08 2004-02-12 Ecolab Inc. Hand dishwashing detergent composition and methods for manufacturing and using
DE102009005791A1 (de) * 2009-01-22 2010-07-29 Henkel Ag & Co. Kgaa Handgeschirrspülmittel mit antibakterieller Wirkung
EP2420558A1 (de) * 2010-08-17 2012-02-22 The Procter & Gamble Company Stabile nachhaltige Handspülmittel

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994004640A1 (en) 1992-08-21 1994-03-03 The Procter & Gamble Company Concentrated liquid detergent composition comprising an alkyl ether sulphate and a process for making the composition
CA2237694A1 (en) 1995-11-16 1997-05-22 Amway Corporation Liquid dishwashing detergent
US5990065A (en) 1996-12-20 1999-11-23 The Procter & Gamble Company Dishwashing detergent compositions containing organic diamines for improved grease cleaning, sudsing, low temperature stability and dissolution
US20040005991A1 (en) * 2000-11-29 2004-01-08 The Procter & Gamble Company Hand dishwashing composition containing a suds suppresser and a method of use therefor
US20040029757A1 (en) * 2002-08-08 2004-02-12 Ecolab Inc. Hand dishwashing detergent composition and methods for manufacturing and using
DE102009005791A1 (de) * 2009-01-22 2010-07-29 Henkel Ag & Co. Kgaa Handgeschirrspülmittel mit antibakterieller Wirkung
EP2420558A1 (de) * 2010-08-17 2012-02-22 The Procter & Gamble Company Stabile nachhaltige Handspülmittel

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3243897B1 (de) 2016-05-09 2019-02-13 The Procter & Gamble Company Reinigungsmittelzusammensetzung umfassend ein fettsäure transformierendes enzym
EP3243897B2 (de) † 2016-05-09 2022-02-16 The Procter & Gamble Company Reinigungsmittelzusammensetzung umfassend einen fettsäure transformierendes enzym
EP3511402A1 (de) * 2018-01-16 2019-07-17 The Procter & Gamble Company Reinigungsmittel mit einer umgekehrten behälteranordnung und eine viskose reinigungszusammensetzung
EP3511405A1 (de) * 2018-01-16 2019-07-17 The Procter & Gamble Company Reinigungsprodukt mit einem umgekehrten und viskoelastischen reinigungsmittel
WO2019143653A1 (en) * 2018-01-16 2019-07-25 The Procter & Gamble Company Cleaning product comprising an inverted container assembly and a viscous cleaning composition
US11427793B2 (en) 2018-01-16 2022-08-30 The Procter & Gamble Company Cleaning product comprising an inverted container assembly and a viscous cleaning composition
EP4134419A1 (de) * 2021-08-11 2023-02-15 Henkel AG & Co. KGaA Verfahren zum gleichzeitigen maximieren der mildheit und der reinigungsleistung einer flüssigen spülmittelzusammensetzung
DE102023203548A1 (de) 2023-04-18 2024-10-24 Henkel Ag & Co. Kgaa Fettlösende Handgeschirrspülmittel mit optimierter Tenisdkombination

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