EP2969040A1 - A facemask having one or more nanofiber layers - Google Patents
A facemask having one or more nanofiber layersInfo
- Publication number
- EP2969040A1 EP2969040A1 EP13878371.7A EP13878371A EP2969040A1 EP 2969040 A1 EP2969040 A1 EP 2969040A1 EP 13878371 A EP13878371 A EP 13878371A EP 2969040 A1 EP2969040 A1 EP 2969040A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- facemask
- wearer
- stiffening member
- layer
- mask
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
- A41D13/1107—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape
- A41D13/1115—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape with a horizontal pleated pocket
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
- A41D13/1192—Protective face masks, e.g. for surgical use, or for use in foul atmospheres with antimicrobial agent
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B23/00—Filters for breathing-protection purposes
- A62B23/02—Filters for breathing-protection purposes for respirators
- A62B23/025—Filters for breathing-protection purposes for respirators the filter having substantially the shape of a mask
Definitions
- present medical facemasks have a high pressure drop between the interior and exterior of the mask because the filter material prohibits the passage of air. This high pressure drop is uncomfortable for the wearer because the interior of the mask increases in temperature. Also, a large portion of the exhaled air of the wearer is forced to deflect above and below the wearers face without passing through the facemask. The more exhaled air that deflects out of the facemask instead of passing through the facemask results in a surrounding environment having more pathogens, which originate from the wearer's exhaled breath.
- the facemask provided allows for reduced deflection of inhaled or exhaled air, which enhances filtration efficiency for air that passes through the mask.
- the facemask provided allows consistent pressure and comfortable and consistent temperatures within the mask for the user when the mask is worn.
- the facemask comprises a bend portion (e.g., crimp, concave portion, etc.) in a malleable stiffening member (e.g., metal strip) of the facemasks, so that the user can properly identify the front, back, nose and cheek area of the mask, and properly wear the mask to reduce potential risk of contamination and effectively filter either inhaled or exhaled air from the nostrils or the mouth of the wearer.
- a bend portion e.g., crimp, concave portion, etc.
- a malleable stiffening member e.g., metal strip
- a malleable stiffening member e.g., metal strip
- the user can pinch the malleable stiffening members to obtain a secure and comfortable fit to the mask and, therefore, have the mask custom fit to his/her face.
- a facemask comprising: an inner layer comprising nonwoven fiber material configured to contact a wearer's nose and mouth; a middle layer disposed on or attached to the inside of the outer layer or on the inner layer and comprising a nanofiber material; an outer layer disposed on the middle layer and comprising nonwoven fiber material, the outer layer configured to contact an external environment, the facemask having upper and lower edges and at least one pleat disposed between at least the upper and lower edges and configured to fit over a chin of the wearer when unfolded, the at least one pleat configured for folding and unfolding the facemask such that when folded the facemask is configured to assume a generally flat storage configuration and when unfolded the facemask is configured to cover at least the nose and mouth of the wearer.
- a method of reducing pressure differential between inside and outside (ambient) spaces in a facemask comprising: providing an inner layer comprising nonwoven fiber material configured to contact a wearer's nose and mouth; a middle layer disposed on the inner layer and comprising a nanofiber material; an outer layer disposed on the middle layer and comprising nonwoven fiber material, the outer layer configured to contact an external environment, the facemask having upper and lower edges and at least one pleat disposed between at least the upper and lower edges and configured to fit over a chin of the wearer when unfolded, the at least one pleat configured for folding and unfolding the facemask such that when folded the facemask is configured to assume a generally flat storage configuration and when unfolded the facemask is configured to cover at least the nose and mouth of the wearer.
- the nanofibers are integrally adhered to or applied to the inside of the outer layer.
- there is a method of enhancing filtration of airborne particles in a facemask by reducing deflection and differential pressure gradients within and external to the face mask comprising: providing an inner layer comprising nonwoven fiber material configured to contact a wearer's nose and mouth; a middle layer disposed on the inner side of the outer layer and comprising a nanofiber material; an outer layer disposed on the middle layer and comprising nonwoven fiber material, the outer layer configured to contact an external environment, the facemask having upper and lower edges and at least one pleat disposed between at least the upper and lower edges and configured to fit over a chin of the wearer when unfolded, the at least one pleat configured for folding and unfolding the facemask such that when folded the facemask is configured to assume a generally flat storage configuration and when unfolded the facemask is configured to cover at least the nose and mouth of the wearer.
- a method of making a facemask comprising providing an inner layer comprising nonwoven fiber material configured to contact a wearer' s nose and mouth; disposing a middle layer on the inner side of an outer layer, the middle layer comprising a nanofiber material; disposing an outer layer on the middle layer, the outer layer comprising nonwoven fiber material, the outer layer configured to contact an external environment; and forming at least one pleat disposed between upper and lower edges of the facemask, the at least one pleat configured to fit over a chin of the wearer when unfolded, the at least one pleat configured for folding and unfolding the facemask such that when folded the facemask is configured to assume a generally flat storage configuration and when unfolded the facemask is configured to cover at least the nose and mouth of the wearer.
- each face mask comprising: an inner layer comprising nonwoven fiber material configured to contact a wearer's nose and mouth; a middle layer disposed on the inner side of an outer layer and comprising a nanofiber material; an outer layer disposed on the middle layer and comprising nonwoven fiber material, the outer layer configured to contact an external environment, the facemask having upper and lower edges and at least one pleat disposed between at least the upper and lower edges and configured to fit over a chin of the wearer when unfolded, the at least one pleat configured for folding and unfolding the facemask such that when folded the facemask is configured to assume a generally flat storage configuration and when unfolded the facemask is configured to cover at least the nose and mouth of the wearer.
- the mask allows bidirectional air flow.
- a facemask comprising: an inner layer comprising nonwoven fiber material configured to contact a wearer's nose and mouth; a middle layer disposed on the inner layer and comprising a nanofiber material; an outer layer disposed on the middle layer and comprising nonwoven fiber material, the outer layer configured to contact an external environment, the facemask having upper and lower edges and at least one pleat disposed between at least the upper and lower edges and configured to fit over a chin of the wearer when unfolded, the at least one pleat configured for folding and unfolding the facemask such that when folded the facemask is configured to assume a generally flat storage configuration and when unfolded the facemask is configured to cover at least the nose and mouth of the wearer.
- Figure 1 illustrates an embodiment of an outside sectional view of the facemask in a folded configuration prior to the facemask being installed upon a wearer's face.
- the bend portion or crimp causes a projection, convex projection, or peak visible from the outside of the mask and a recesses or trough visible from the inside of the mask that the wearer places against the face.
- the rest of the facemask is flat.
- Figure 2A illustrates an embodiment of a top view of the malleable stiffening member (e.g., metal strip) having a bend portion shown as a crimp, concave recess, or crease that causes a recess or trough or cavity visible from the inside of the mask in the nose section.
- the malleable stiffening member e.g., metal strip
- Figure 2B illustrates an embodiment of a top view of the malleable stiffening member (e.g., metal strip) having a bend portion shown as it would bend further around the nose if the facemask was unfolded and the user pinched the malleable stiffening member.
- the malleable stiffening member e.g., metal strip
- Figure 3 illustrates a cross-sectional exploded view of an embodiment of a facemask installed upon a wearer's face.
- Figure 4 illustrates a perspective view of an embodiment of a facemask installed upon a wearer's face.
- Figure 5 illustrates an embodiment of the inner surface of a facemask.
- Figure 6 illustrates an embodiment of the outer surface of the facemask as the mask is installed upon a wearer's face and having a visual indicator of temperature, moisture, and/or if a pathogen contacts the mask.
- Figure 7 illustrates an embodiment of the indicator as a strip.
- Figure 8 is a graphic illustration showing different mask filtration.
- the nanofiber masks had greater filtration than other masks.
- Figure 9 is a graphic illustration showing different pressure differentials with various masks. The pressure differentials were lower with the nanofiber masks indicating reduced deflection and better filtration.
- the present disclosure includes a face mask containing nanofiber material.
- the facemask provided allows for reduced airflow resistance and thereby reduced deflection of inhaled or exhaled air and associated particles, which enhances filtration efficiency for airborne particles that pass through the mask.
- the face mask provided allows consistent pressure and comfortable and consistent temperatures within the mask for the user when the mask is worn.
- the materials to make the mask comprise hydrophobic materials, e.g., hydrophobic polymers, hydrophobic fluoropolymers, or polymers having a hydrophobic surfactants, or the like.
- Suitable hydrophobic materials include polyolefins (polyethylene, polypropylene and combinations thereof) or polyesters that are free of hydrophilic materials.
- the hydrophobic polymer can comprise fluoro surfactants.
- fluoro surfactants are the perfluoroalkyl acrylic copolymers sold under the tradename Zonyl 8300 or Zonyl 7040, supplied by Ciba Geigy.
- the face mask provided allows for reduced pressure differential (internal to ambient air) and enhanced filtration of airborne particles.
- the face mask provided improves filtration and/or reduces breathing resistance (e.g., provides wearer comfort) while protecting the wearer from airborne particles as small as 0.05 microns (e.g., including viruses, bacteria, spores, mold, dust and diffuse airborne chemical pollutants, etc.).
- the face mask can be comfortably worn by the source of the airborne contaminants (e.g., patient).
- Nanofiber filtration media will enable high filtration and limit differential pressure within the mask allowing for greater comfort and perceived breathability. This discomfort level may also be measured by temperature readings within the worn mask. Nanofiber masks show low temperature reading within the space between the mask and the wearer; an indication of greater comfort. Likewise, healthcare personnel are required to wear masks in clinical settings to either protect themselves from large airborne droplets or to protect other patients from their potentially infectious respiratory emissions. Nanofiber masks will contribute to higher mask-wearing compliance as well as the wearing of masks with more proper fit. In association with MOF (Metal Organic Frameworks) chemistries, nanofiber masks may also serve to protect the wearer from specific airborne gaseous chemical threats.
- MOF Metal Organic Frameworks
- Discrete integrated or detachable nanofiber strips placed within the nanofiber masks may enable the capture of exhaled particles for subsequent analysis and detection of wearer illness/infection.
- Including a discrete nanofiber layer between two discrete nonwoven fiber layers provides for enhanced filtration of airborne particles, such as, for example, pathogens, and reduced pressure drop.
- Figure 1 illustrates an embodiment of an outside sectional view of the face mask 10 in a folded configuration 11 prior to the facemask being installed upon a wearer's face.
- this side of the facemask 10 would face the outside environment and not touch the wearer' s nose, cheeks, jaw and/or chin.
- the facemask 10 may have application in healthcare, industrial, domestic, public, or other settings.
- the embodiment shown is an N95 respirator, which is a lightweight, nose-and-mouth respirator that provides protection for the wearer from microorganisms (e.g., bacteria, fungi, yeast, molds and viruses).
- the facemask 10 is generally configured so as to provide a secure fit which reduces or prevents gaps and passage of material between the nostrils and mouth and the surrounding environment except through the filter material 13.
- the makeup of the filter material 13, and the pleating 20 used in connection with the facemask 10 will be explained in detail shortly.
- the facemask 10 has the particular advantage of allowing a secure fit to be created and to be maintained upon installation of the facemask 10 on the face with the use of two ear loops 28 and 30.
- the facemask 10 may be constructed of a wide variety of materials and is preferably disposable.
- the inner, outer, and filtration materials 13 used to fabricate the facemask 10 may vary according to the particular application of the facemask 10. For example, when the facemask 10 is to be used in a medical application, such as on members of a surgical team, it is common to use a three layer filter material that will provide blood (or other) fluid resistance to prevent penetration of fluids to the inner lining of the mask.
- appropriate inner, outer, and filtration materials may be of a single or multiple layer design.
- Multi-layer material may be readily purchased in a precollated form, that is with the three layers already arranged, or the materials may be obtained separately and the filter material 13 formed in part of the process for forming the facemask 10.
- a three or four layer filter medium might include an outer layer of a relatively porous paper-like or spunbond polypropylene material which provides durability and resistance against abrasion and/or fluid penetration.
- the outer layer may also be generally stiff er than the other layers. By using a stiff er outer layer, the effectiveness of the various pleating arrangements is increased.
- the pleats 20 are disposed between the upper edge 12 and lower edge 25 and side edges 21 and 29 and may be incorporated in the body of the filter material 13 to hold the facemask 10 in a cup-like shape when installed.
- the inner layer or layers of the filter material generally contain polyethylene or polypropylene, or other material, which exhibits the proper filtration characteristics.
- the middle layer comprises nanofiber material that is coated onto either the outer side of the inner layer or the inner side of the outer layer. Glass fiber based materials may also have applications as the middle filtration layer.
- the innermost layer of the filter material is to be worn next to or against the face and generally comprises a soft material for providing a soft, non-irritating surface against which the facial skin will make contact.
- the combined mask materials 13 also provide bacterial filtration efficiency (BFE) in accord.
- BFE bacterial filtration efficiency
- the BFE of a filter material is generally determined by the percentage of bacteria, such as Staphylococcus aureus or Bacillus stearothermophilus, that is able to migrate through the filter material under normal conditions. The fewer bacteria which are able to pass through the filter material 13, the higher the BFE.
- a BFE of 100% is desirable; however, efficiencies of as low as 25% are not uncommon among some types of prior art disposable facemasks. However, materials are available which provide BFE's of between 90 and 99%.
- a filter material having as high a BFE it is generally desirable to utilize a filter material having as high a BFE as possible so as to prevent release of nasopharyngeal organisms into the environment.
- the considerations that provide for a high BFE are the same considerations which provide that a filter material would be desirable in applications in industry and domestic use.
- a filter material which inhibits the migration of nearly all bacteria would generally also prevent inhalation of dust and dirt particles in industrial applications.
- those materials providing a high BFE are often also those materials which provide the least resistance to passage of gases through the filter material.
- the easy passage of gases through the filter material is important in maintaining the comfort of the wearer and reduce or inhibit deflection of air and the particles it carries out of any openings created by imperfect sealing of the face mask to the face, thereby bypassing the particle filtration process intended. It should be realized by one of ordinary skill in the art, however, that many applications might require greater or lesser standards of filtration than is commonly required in the medical environment. Therefore, while filter materials having an efficiency suitable for use with the present application available in the art, the best filter material is of little use if the air inhaled and exhaled by the wearer is allowed or facilitated to escape the face mask 10 without passing through the filter material 13.
- the present application provides a unique secure fit which reduces or prevents inhaled and exhaled air from leaking around the edges 12, 25, 21, and 29 of the facemask 10 by finding the combination of air flow patterns caused by pressure differentials, and an route of escape, all while providing a superior fit on a wider range of facial sizes and shapes.
- the maintenance of such a secure fit greatly improves the overall efficiency of the face mask 10.
- the structure of the face mask 10 is generally prepared as a rectangular piece of flat filter material 13. However, it will be understood by those of ordinary skill in the art that other shapes of the face mask can be made in order to cover additionally both the eyes, hair, and throat of the user. As such, the present application includes face masks 10 that cover areas above and beyond simply the nose and mouth of the user.
- the facemask may also incorporate any combination of known face mask 10 features, such as visors or shields, sealing films, beard covers, etc.
- the face mask 10 may be from about 5.5 inches to 7 inches across in length to cover the user's nose and mouth.
- the mask is shown as it would be packaged in its folded and flat configuration, except for the convex outside by the malleable stiffening member 14, where the outside surface is viewed.
- the facemask 10 comprises a malleable stiffening member 14 attached to or imbedded in the mask material 13 at the masks upper edge 12.
- the malleable stiffening member 14 is configured to conform the filter material 13 to at least a nose portion and a cheek portion of the face of the wearer. It will cause a portion of the mask to be convex and have, in some embodiments a curved projection on the outer layer to indicate the nose and cheek area.
- a second malleable stiffening member 24 is attached to or within lower edge 25 of the filter material 13, as illustrated in Figure 1.
- the second malleable stiffening member is configured to conform the mask material to at least a chin portion and a jaw portion of the face of the wearer.
- the second malleable member does not include a bend portion.
- it can include a bend portion that is different from the bend portion 15 in the nose and cheek portion of the mask provided that they can be distinguished (e.g., the bend portion 15 at the nose section can be creased at a larger angle than the optional bend portion in the chin piece).
- the portion of the mask that has the second malleable stiffening member will also have, in some embodiments, a convex projection on the outer layer.
- malleable stiffener or “malleable stiffening member” herein is meant to include the use of both malleable and flexible stiffeners. It is preferred that the malleable stiffeners 14 and 24 be placed adjacent to the upper 12 and lower edges 25 of the mask material 13, respectively. Alternatively, the malleable stiffeners 14, and 24 may be placed somewhere along the upper 12 and lower edges 25 of the mask material 13. The important property of the malleable stiffeners 14 and 24 is that the material be pliant enough to be bent to a shape that conforms to the face of the wearer, and then retain that shape.
- the face mask 10 also has ear loop 30 attached to edges of the mask at attachment points 16 and 22 and ear loop 28 to edges of the mask at attachment points 18 and 26 used in donning the mask.
- the ear loops are attached to the outside surface of the mask.
- the loops can be attached to the inside surface of the mask.
- the mask can be a mask that is not folded, e.g., a cone shaped mask that has the nanofiber disposed on the inner layer or the inside of the outer layer.
- the mask of the current application is not an N95 mask, but other mask type like a cone-shaped mask.
- the upper portion of the facemask 10 will refer to that portion which contacts the nose and cheek areas of the wearer while the lower portion of the facemask 10 will be that portion which is in proximity to the lower jaw and chin of the wearer.
- the malleable stiffeners 14 and 24 can comprise any pliant material, such as a malleable metal or alloy, plastic, or the like. In some embodiments, the malleable stiffeners comprise aluminum or other binding material which exhibits stiffening characteristics.
- the malleable stiffeners 14 and 24 can be attached to or imbedded within the inside or outside surface of the filter material.
- the malleable stiffening members can be attached to the facemask and then covered with the same or different material used to make the mask.
- the malleable stiffening members can be attached to the mask by covering it with spunbonded polypropylene and ultrasonically sealing it to the outer surface of the mask.
- the malleable stiffening members can be attached to the mask by adhesive or other means for holding the malleable stiffening members to the mask.
- first malleable stiffener 14 used for the nose portion of the mask may be from about 3 to 6 inches in length and from about 0.025 or 0.125 or 0.25 or 0.5 inches in height and from about 0.01 or 0.02 or 0.05 or 0.125 or 0.25 inches thick.
- second malleable stiffener 24 used for the chin portion of the mask may be from about 1.5 to 5 inches in length and from about 0.025 or 0.125 or 0.25 or 0.5 inches in height and from about 0.01 or 0.02 or 0.05 or 0.125 or 0.25 inches thick.
- the first malleable stiffener 14 used in the nose portion is a length that is larger or the same size as the length of second malleable stiffener 24 that is used in the chin portion of the facemask.
- the second malleable stiffener 24 is smaller than the first malleable stiffener 14.
- the malleable stiffening member 14 has a bend portion 15 indicating at least the inner surface, outer surface, center and/or the nose portion of the facemask.
- the bend portion or crimp includes an angular or rounded shape made by pinching, folding, punching or bending the malleable stiffening member 14 to cause a cavity, indentation, recess, crease, concave recess, or trough on the inside surface of the mask (not shown) and a projection, convex projection, peak, protrusion, elevation or ridge on the outside surface of the mask (shown). At these portions of the facemask, it will not be flat on storage.
- the bend portion 15 includes making a ridge or fold by pinching the malleable stiffening member 14 by hand or machine. Although the bend portion 15 is shown generally in the center of the malleable stiffening member 14, it will be understood that the bend portion 15 can be disposed to the left, or right of center.
- the bend portion 15 or crimp may be located by the nose portion of the mask on the outer or inner surface and be angled or crimped in the direction away from the nose so that the user can bend it further for a custom fit around the nose and check area. In this way, the bend portion can be "pre-bent” or "pre-crimped” by the manufacturer.
- the bend portion will cause the inner surface of the mask that is to be placed against the user's nose to have a cavity, indentation, recess, crease, or trough on the inside surface of the mask and as the malleable stiffening member 14 is further pinched, bent or folded (as shown by the arrows in Figure 2A), a cavity, indentation, recess, crease, or trough becomes larger to accommodate the nose.
- the user will have a visual indication of where the top of the mask is, where the nose section of the mask is and/or where the center of the mask is for those embodiments where the bend portion is disposed within the center or generally within the center of the malleable stiffening member 14.
- the bend portion 15 allows the user to identify the outside of the mask, the inside of the mask, top of the mask, and/or center of the mask. In some embodiments, the bend portion 15 is packaged (not shown) at least partially bent so that the cavity, indentation, recess, crease, or trough is visible on the interior of the mask.
- the bend portion 15 or crimp is typically formed from the same material as the malleable stiffening member. However, the same or different material may be used as long as the bend portion will cause a crease or fold in the filter material and allow the user to identify the top, center, inside and/or outside of the mask.
- the bend portion may be formed from any suitable material, such as an elastic material (e.g., a polymer), inelastic material, a nonwoven, knit, ribbon, cloth, wire, metal or the like.
- the bend portion may be bent before use by the manufacturer by about 1 to about 5 degrees, by about 1 to about 10 degrees, or by about 5 to about 20 degrees. In some embodiments, the bend portion may be bent before use by the manufacturer so that the bend portion projects out of the inner or outer surface of the mask by about 0.25 mm to about 0.5 mm, or by about 1 mm to about 5 mm or by about 1 mm to about 10mm or by about 5 mm to about 20 mm, or by about 10 mm to about 30 mm or by about 35 mm to about 60 mm. Therefore, the facemask will not be flat when stored or in the package as a stack before it is worn.
- the bend portion is designed for easy bending around the ridge of the nose.
- the bend portion like the malleable stiffening member, may be substantially deformable so that a wearer is able to bend, pinch or fold the bend portion and/or the malleable stiffening member between two or more fingers when gripping it as it is put around the ridge of the nose.
- each face mask comprising: an inner layer comprising nonwoven fiber material configured to contact a wearer's nose and mouth; a middle layer disposed on the inner layer and comprising a nanofiber material; an outer layer disposed on the middle layer and comprising nonwoven fiber material, the outer layer configured to contact an external environment, the facemask having upper and lower edges and at least one pleat disposed between at least the upper and lower edges and configured to fit over a chin of the wearer when unfolded, the at least one pleat configured for folding and unfolding the facemask such that when folded the facemask is configured to assume a generally flat storage configuration and when unfolded the facemask is configured to cover at least the nose and mouth of the wearer.
- the facemasks are positioned in a nestled relation to one another (e.g., masks that are close or one on top of the other in the package), the inner surface of at least one mask being apposed to the outside surface of an adjacent mask, thereby forming a stack.
- the facemask comprises bent malleable stiffening members
- the concave portions can be stacked one on top of the other and parallel to each other for ease of packaging.
- Figure 2A illustrates a top side view of the malleable stiffening member 31 (e.g., metal strip) having a bend portion shown as a crimp or crease.
- the bend portion has a projection, peak, protrusion, elevation, convex surface or ridge 32A that extends out and is visible on the outside surface of the mask (not shown).
- the bend portion has a cavity, concave surface, indentation, recess, crease, or trough 32B on the inside of the mask that is visible on the inside surface of the mask.
- the stiffening member 31 would have this configuration when attached to the mask.
- the mask would be in a flat and/or folded configuration, except for the bend portion(s).
- the bend portion may be substantially deformable so that a wearer is able to bend or fold the bend portion and/or the malleable stiffening member in the direction of the arrows shown using two or more fingers when gripping it as it is put around the ridge of the nose.
- the wearer By employing a bend portion in the malleable stiffening member 31, which is placed in the center of the facemask, the wearer will see a projection, peak, protrusion, elevation, convex surface, or ridge or other marker visible on the outside surface of the mask, or a cavity, concave surface, indentation, recess, crease, or trough or other marker visible on the inside surface of the mask and know where the top inside or outside, and/or center of the mask is and where the nose portion of the mask is to be placed on the face.
- the bend portion can be any shape (e.g., circular, square, rectangular, regular, irregular, symmetrical or asymmetrical shape).
- the bend portion causes a projection, peak, protrusion, elevation, or ridge or other marker on the top front, outside and/or center portion of the mask so that the wearer will know these portions of the mask and know the right side of the mask should be facing the outside environment and not the wearer's nose or face.
- the facemask of the present application reduces the risk that the wearer will wear the mask incorrectly.
- Figure 2B illustrates a top view of the malleable stiffening member 31 having a bend portion shown as it would start to bend around the nose if the facemask (not shown) was unfolded.
- the bend portion has a projection, peak, protrusion, elevation or ridge 32A that extends out and is visible on the outside surface of the mask (not shown).
- the projection increases as the malleable stiffening member 31 is further bent or pinched.
- the bend portion has a cavity, indentation, recess, crease, or trough 32B on the inside of the mask that is visible on the inside surface of the mask and gets bigger as the malleable stiffening member is further bent, pinched or folded.
- the stiffening member 31 would have this configuration when attached to or in the unfolded mask.
- the bend portion like the malleable stiffening member 31 may be substantially deformable so that a wearer is able to bend or fold the bend portion and/or the malleable stiffening member using two or more fingers when gripping it as it is put around the ridge of the nose. It will be understood that the one or more malleable members once bent will cause the mask to be elevated where the bend is, while the other portions of the mask that do not have a bend portion will remain flat.
- the bend is in a vertical direction relative to the one or more pleats.
- the bend portion 32 is crimped, bent, creased, folded, or angled toward the inner surface or outer surface of the facemask by about 1 to 10 degrees or by 0.5 mm to about 50 mm.
- the crimp can be from 1 mm, 10 mm, 15 mm, 20 mm, 30 mm, 35 mm, 40 mm, 45 mm, 50 mm, 55 mm, 60 mm, or 65 mm.
- the facemask may be attached to the user by a securing means that can attach the mask to the user.
- the securing means may be a pair of manual tie straps that are wrapped around the head of the user and are connected to one another, or the securing means may be ear loops (28 and 30 in Figure 1), elastic bands wrapped around the head of the user, a hook and loop type fastener arrangement (e.g. VELCRO® fasteners), or a connection directly attaching the face mask to a hair cap.
- the ear loops (28 and 30 in Figure 1) can be attached to the inner or outer surface of the mask at upper edges 16 and 18 and lower edges 22 and 26.
- the attachment points may be in from the edge by, for example, from about 1/8* of an inch to 1 inch. The closer together the ear loops are, the tighter the fit and the mask will reduce gaps and leakage of inhaled and exhaled air.
- the loop is positioned so as to be balanced in the wearer's hand, thereby stabilizing the mask for donning.
- the loop may be formed from any suitable material, such as an elastic material (e.g. a polymer), inelastic material, a nonwoven, knit, ribbon, cloth, wire, and so forth.
- the term “elastic” refers to the ability of a material to recover its size and shape after deformation.
- the term “inelastic” refers to the inability of a material to recover its size and shape after deformation.
- the loop is formed from the same material selected to form the outside surface of the mask. The loop may be bonded or otherwise affixed to the outside surface or inside surface of the mask. Examples of suitable techniques include adhesive bonding, thermal bonding, stitching, and so forth.
- the term “adhesive” refers to the property of any material that allows the material to bond together substrates by surface attachment.
- the loop is generally sized and positioned to facilitate gripping by a wearer, both prior to, during, and after donning.
- the loop 30 may be more or less than about 80 mm (0.08 m) in length as measured from the first end 16 to the second end 22 along the length of the loop. In other embodiments, the loop 30 may be less than about 60 mm (0.06 m) in length. In yet other embodiments, the loop 30 may be less than about 40 mm (0.04 m) in length. Where, in some embodiments, the loop is formed from an elastic material, the loop may have a fully extended length of 200 mm (0.200 m) or more. In some embodiments, the loop is from about 4 to 10 inches in length.
- the loop generally extends inwardly from the outside surface or inside surface a sufficient distance so that the wearer of the mask may grip the loop between two or more fingers of a single hand.
- the loop may extend outwardly from the inside or outside surface at least 5 mm (0.005 m).
- the loop may extend outwardly from the outside or inside surface at least about 8 mm (0.008 m).
- the loop may extend outwardly from the outside or inside surface at least about 10 mm (0.01 m) from the outside surface.
- Fiber diameter and density is the main variable responsible for maintaining a balance between filtration efficiency and pressure differentials (inside the mask on the face in relation to ambient pressures outside the mask). Greater diameter and density of fibers provide for less fiber surface area and thereby less space between fibers through which gaseous particles may pass. When such a dense-fiber mask is sealed to the face through a tight fit, upon wearer exhalation pressure within the mask is elevated creating a pressure differential between the inside of the mask and the ambient air.
- the pressurized gas will seek equivalence to ambient (lower) air pressures through the pathway of least resistance, namely any opening or unintended leak around the mask, rather than through the dense filtration material. This creates a condition whereby airflows are deflected off of the mask material (inner, and filter layers) rather than passing through it. Likewise, upon inhalation of a mask with high(er) density filtration material and a tight seal, inhalation will produce a negative pressure within the mask chamber. This pressure differential will resolve itself in the same fashion, namely, with higher ambient (external) air flows seeking entry into the mask via the path of least resistance; through any mask leaks, rather than through the filter material.
- nanofiber material with ⁇ 150x smaller diameter and far greater surface area will result in significant improvements in filtration efficiency, lower pressure differentials, and less mask leakage and filter bypass.
- Efficiency increases are attributed to the enormous specific surface of the nanofiber filter media. Less inward to outward leakage, higher filtration efficiency, and lower pressure differential will enhance the respiratory source control (inward to outward filtration/capture of potentially infectious particles) efficacy of the mask.
- the nanofiber layer while chemically inert, can be modified to incorporate specific functional characteristics.
- the nanofiber can be modified with silver, copper, or gold nanoparticles for antimicrobial functionality or application of Metal Organic Frameworks (MOFs) that can be functionalized for capture of specific gaseous airborne threats.
- MOFs Metal Organic Frameworks
- the nanofibers can be any suitable type of nanofiber, including electrospun fibers, protein nanofibers, cellulose nanofibers, hollow nanofibers, bacterial nanofibers, inorganic nanofibers, hybrid nanofibers, splittable nanofibers or combinations thereof.
- the nanofibers can be coated on or adhered to the inside of the outer layer, middle layer inside or outside of it, or on or adhered to the inside or outside of the inner layer of the mask.
- nanofibers refers to very small diameter fibers having an average diameter not greater than about 1500 nanometers (nm). Nanofibers are generally understood to have a fiber diameter range of about 10 to about 1500 nm, more specifically from about 10 to about 1000 nm, more specifically still from about 20 to about 500 nm, and most specifically from about 20 to about 400 nm. Other exemplary ranges include from about 50 to about 500 nm, from about 100 to 500 nm, or about 40 to about 200 nm.
- the average diameter of a nanofiber can be measured using known techniques (e.g., image analysis tools coupled with electro microscopy), but excluding the portions of a fiber that are substantially enlarged by the presence of added particles relative to the particle free portions of the fiber.
- Nanofibers ranging from 10 nm to 1000 nm can be used in filtration medium to capture submicron particles below 1000 nm.
- the ability of nanofibers to capture particles is believed to be due to a combination of interception of submicron particles by the fibers as well as the Brownian motion or "random walk" of submicron particles, both of which facilitate the particles to be captured by the large surface/mass ratio of the nanofibers.
- Further increase of capture capability may be obtained by increasing the nanofiber surface area such as by reducing the fiber diameter and/or by increasing the packing density of the nanofibers, as measured in terms of grams of nanofibers per square meter.
- the facemask configuration of the present application may offer many advantages: the nanofibers may maintain a low solid volume fraction (or equivalently a higher porosity) in each nanofiber layer, the total thickness of the nanofiber layers in the filter may well exceed the single nanofiber layer having the same total polymer packing density (i.e. same grams per square meter or "gsm"), a high particle capture efficiency may be attained with submicron particles, a lower pressure drop may be achieved when compared to the single layer with the same packing density (i.e. same gsm), the substrate layer may act as a support providing mechanical stress (tensile) for the filtration medium, and the substrate layer may serve as a filter medium.
- the nanofibers may maintain a low solid volume fraction (or equivalently a higher porosity) in each nanofiber layer
- the total thickness of the nanofiber layers in the filter may well exceed the single nanofiber layer having the same total polymer packing density (i.e. same grams per square meter or "gsm")
- gsm grams per
- the nanofibers can be in a discrete layer(s) sandwiched between the outer and inner layer. In some embodiments, the nanofibers can make up the middle layer or can be disposed on the middle layer of the facemask. In some embodiments, the nanofiber can be disposed on the inner, middle and/or outer layer by electrospinning.
- electrospun fibers refers to a technology which produces nano-sized fibers referred to as electrospun fibers from a solution using interactions between fluid dynamics and charged surfaces.
- formation of the electrospun fiber involves providing a solution to an orifice in a body in electric communication with a voltage source, wherein electric forces assist in forming fine fibers that are deposited on a surface that may be grounded or otherwise at a lower voltage than the body.
- electrospinning a polymer solution or melt provided from one or more needles, slots or other orifices is charged to a high voltage relative to a collection grid. Electrical forces overcome surface tension and cause a fine jet of the polymer solution or melt to move towards the grounded or oppositely charged collection grid.
- the jet can splay into even finer fiber streams before reaching the target and is collected as an interconnected web of small fibers.
- the dried or solidified fibers can have diameters of about 40 nm, or from about 10 to about 100 nm, although 100 to 500 nm fibers are commonly observed.
- Various forms of electrospun nanofibers include branched nanofibers, tubes, ribbons and split nanofibers, nanofiber yarns, surface-coated nanofibers (e.g., with carbon, metals, etc.), nanofibers produced in a vacuum, and so forth.
- the production of electrospun fibers is illustrated in many publication and patents, including, for example, P. W. Gibson et al, "Electrospun Fiber Mats: Transport Properties," AIChE Journal, 45(1): 190-195 (January 1999), which is hereby incorporated by reference.
- the nanofibers can be in the mask to create a gradient in the mask.
- the gradient can be a multi-component material in which nano-sized fibers of at least two different "types" which have been produced by electrospinning are present and non-uniformly distributed to create one or more gradients or heterogeneity in one or more directions.
- the gradient in a "gradient electrospun material” provides discrete areas having measurable differences in surface chemistry (e.g., wicking, contact angle, etc.) or other material properties, including, but not limited to, density, pore size, surface charge, zeta potential, and so forth, resulting from the presence of fibers of different types, i.e., of substantially different material composition.
- the nanofibers can be coated on the mask in the inner, middle and/or outer layer.
- the inner layer is the most porous
- the middle layer is less porous than the middle layer and the outer layer is the least porous.
- the porosity of the inner and middle layer is the same and the outer layer is the least porous.
- the medical facemask has a first discrete nonwoven fiber layer 33 (inner layer) disposed adjacent a wearer's face.
- First layer 33 has an inner surface 34, which is at least partially contacting the wearer's face.
- First layer also has an outer surface 35.
- a second discrete nonwoven fiber layer 36 (middle layer) is disposed adjacent to outer surface 35 of first layer 33.
- Second layer 36 can be spaced apart from first layer 33 or can be disposed in contact with first layer 33.
- Second layer 36 has an inner surface 37 facing direction A as shown in FIG. 3.
- Second layer 36 includes an outer surface 38 facing direction B as shown in FIG. 3 opposite inner surface 34.
- a third discrete nonwoven fiber layer 39 is disposed adjacent second layer 36 such that second layer 36 is disposed between first and second layers 33, 36.
- Third layer 39 (outer layer) has an inner surface 40 facing direction A as shown in FIG. 3 disposed adjacent outer surface 38 of second layer 36.
- Third layer 39 (outer layer) also includes an outer surface 41 exposed to the surrounding environment opposite inner surface 40 of third layer 39.
- Nanofiber material is layered or coated onto surfaces of first, second and/or third fiber layers 33 (inner layer), 36 (middle layer), 39 (outer layer).
- the nanofiber layer can replace the outer, middle, or inner layer.
- the nanofiber layers are discrete layers, separate from and coated on first, second and third fiber layers 33, 36, 39.
- the discrete nanofiber layers are not interwoven into the nonwoven fiber layers nor are they composites of the nonwoven fiber layers.
- Discrete nanofiber layers can be coated on one or a plurality of the surfaces of the first, second and third fiber layers 33, 36, 39.
- second layer 36 is replaced with a first discrete nanofiber layer 42 coated on outer surface 35 of first layer 33 and a second nanofiber layer 43 coated onto inner surface 40 of third layer 39.
- discrete nanofiber layers are coated onto outer surface 35 of first layer 33, inner and outer surfaces 37, 38 of second layer 36, and inner surface 40 of third layer 39 forming a facemask having four discrete nanofiber layers for enhanced filtration of airborne pathogens.
- a discrete nanofiber layer is coated on inner surface 34 of first layer 33 and/or inner surface 40 of third layer 39.
- the nanofiber layer density and the combination of non-woven/nanofiber layers will vary according to specific performance objectives for each mask version. For example, one mask version may incorporate a more dense nanofiber layer as a replacement for the non-woven filtration layer in order to achieve similar filtration efficacy while reducing pressure differentials (increasing breathability). Another version may incorporate a less dense nanofiber layer onto an existing layer to achieve greater filtration efficiency. Additionally, the hydrophilic or hydrophilic nature of the incorporated nanofibers may vary. For example, a highly hydrophobic outer layer would be used to improve the fluid barrier properties of the mask.
- a highly hydrophilic nanofiber layer may be used to draw moisture in (wick) towards a subsequent layer in order to draw moisture away from the wearer's face and/or to draw potentially infectious moisture droplets toward an anti-microbial layer where the pathogen would be neutralized.
- the nanofiber layers may incorporate antimicrobial nanoparticles, metal organic frameworks, moisture sensors and/or an integrated flu diagnostic nano-strip.
- the materials to make the mask comprise hydrophobic materials, e.g., hydrophobic polymers, hydrophobic fluoropolymers, or polymers having a hydrophobic surfactants, or the like.
- the facemask is a continuous loop of fabric that is stretched over the wearer' s head covering the neck. Approximately half of the fabric will comprise nano-filter material and the other half will comprise fabric having elastic properties. The front filter portion will be pulled over the bridge of the nose. It is contemplated that the facemask has a tear-away perforation for removal and safety purposes, and will not require any metal pieces or ties in order to secure the facemask to the wearer.
- discrete nanofiber layer 42 is hydrophilic to draw moisture away from first layer 33.
- the discrete nanofiber layers increase in hydrophilicity from inner surface 34 of first layer 33 to inner surface 40 of third layer 39 such that a moisture concentration gradient is formed between first and third layers 33, 39.
- First layer 33 has the lowest moisture content and third layer 39 has the highest moisture content given that moisture will be constantly drawn away from the wearer' s face in direction B as shown in FIG. 3.
- the moisture concentration gradient reduces the amount of moisture in an interior cavity 27 of facemask 10, thus enhancing comfort for the wearer.
- first, second and third layers 33, 36, 39 comprise material increasing in hydrophilicity, respectively.
- Figure 4 illustrates a perspective view of an embodiment of a facemask 44 installed upon a wearer's face.
- the outer surface 58 of the facemask 44 is shown facing the outside or external environment that the wearer 64 is exposed to.
- the facemask 44 is shown in its unfolded position and secured to the wearer's face to provide the secure and comfortable fit by securing the ear loops (one shown as 62) around the wearer's ears.
- the ear loops are preferably formed of elastic such that they will secure the facemask 44 in the proper position on the wearer's face. Use of elastic ear loops allows the facemask 44 to be easily installed by the wearer and avoids the difficulty of tying a string tie behind the head.
- the ear loops are elastic, there is not the risk of the ear loops becoming untied at an inopportune moment which accompanies the use of ordinary tie strings. Furthermore, the elasticity of the ear loops may be chosen so as to allow the facemask 44 to be easily repositioned on the face while only using one hand.
- the facemask 44 comprises one or more pleats (shown in the unfolded position are three pleats that have been unfolded 48, 50 and 52).
- the one or more pleats are disposed between at least the upper, lower, and/or side edges of the mask.
- the term "pleat” refers to a relatively flat double-fold formed in the facemask 44 when the facemask 20 is in the flat storage configuration (as illustrated in Figure 1).
- the pleats in the filter material can be any known in the art and include, for example, Z shaped pleats, standard pleats, omega pleats, secondary pleats, reverse pleats or the like.
- the one or more pleats are disposed between the upper, lower and side edges (60) of the mask. It will be understood by those of ordinary skill in the art that the mask may have one, two, three, four, five, six, seven, eight or more pleats, each of which can be the same or different sizes and/or shapes.
- the facemask 44 comprises in its upper section, an upper malleable stiffener 46, which when pinched, folded or twisted pulls the filter material including its top and side edges against the nose and cheeks.
- the facemask also comprises lower malleable stiffener 54 in the lower section of the facemask, which when pinched, folded or twisted pulls the side and lower edges into the side of the face and lower jaw area to provide a secure facial fit.
- the pleats 48, 50, and 52 allow the creation of a pocket-like shape by which the inner surface of the filter material is held tightly against the lower jaw area of the wearer.
- the upper and lower malleable stiffeners (46 and 54) are attached to or imbedded in the mask material, typically on or in the inside or outside of the mask. These malleable stiffeners increase the secure fit formed around the nose and cheek area and the chin and jaw portion of the face of the wearer.
- Figure 5 illustrates an embodiment of the inner surface 68 of a facemask that the wearer would place against his/her face.
- the mask is shown in the unfolded or partially unfolded position.
- the upper malleable stiffener 67 imbedded or attached to the mask has been folded, crimped, pinched, bent, creased, and/or angled around the wearer's nose and/or cheek area and causes a cavity 66 in the filter material that conforms and pulls it closer to a portion of the nose and/or cheek.
- the lower malleable stiffener 70 imbedded or attached to the mask has been crimped, bent, creased, folded, pinched, and/or angled around or under the wearer's chin and/or jaw area and causes a cavity 69 in the filter material that conforms and pulls it closer to a portion of the wearer's chin and/or jaw area.
- the cavity 69 will be located under the chin so that the user can rest it on it.
- the mask provides a secure and comfortable fit for the user by simply pinching the malleable stiffeners. It will be understood by those of ordinary skill in the art that the cavities in the inside of the mask 66 and 69 can be aligned vertically with each other or be substantially parallel to each other so that projection 66 and 69 line up.
- Figure 6 illustrates an embodiment of the outer surface 73 of the facemask installed upon a wearer's face.
- the mask is shown in the unfolded or partially unfolded position.
- the upper malleable stiffener 71 imbedded or attached to the mask has been folded, crimped, pinched, bent, creased, and/or angled around the wearer's nose and/or cheek area and causes a projection 72 in the filter material that conforms it to a portion of the nose and/or cheek.
- the lower malleable stiffener 74 imbedded or attached to the mask has been crimped, bent, creased, folded, pinched, and/or angled around or under the wearer's chin and/or jaw area and causes a projection 75 in the filter material that conforms to a portion of the wearer's chin and/or jaw area.
- the projection 75 will be located under the chin so that the user can rest it on it.
- the mask provides a secure and comfortable fit for the user by simply pinching the malleable stiffeners. In this way, the mask reduces leakage of material around the top, bottom and edges of the masks.
- the projections in the outside of the mask 72 and 75 can be aligned vertically with each other or be substantially parallel to each other so that projection 72 and 75 line up and the masks can be stacked one on top of the other.
- the facemask may be thermally molded or heat set to increase stiffness. In other embodiments, binder chemicals may be added to the materials prior to formation of the mask.
- the facemask can be disposable and/or for single use.
- the outer surface 73 of the facemask comprises a temperature, moisture, and/or pathogen indicator. Although shown on the outer surface, it will be understood by those of ordinary skill in the art that this indicator can be disposed on or in the outer, inner, and/or middle layer.
- the indicator provides a visual indication when a certain temperature, and/or moisture is reached and/or when a pathogen is detected.
- the indicator can have for example, a thermochromic dye, such as for example, that disclosed in U.S. Pat. No. 4,826,550, the entire disclosure is herein incorporated by reference, to provide the indication of a temperature change in the mask.
- a thermochromic dye such as for example, that disclosed in U.S. Pat. No. 4,826,550, the entire disclosure is herein incorporated by reference, to provide the indication of a temperature change in the mask.
- the temperature threshold When the temperature threshold is reached, it results in a visual indication.
- the visual indication of a change in temperature threshold is a change in color. This can signal the user to change the mask.
- the indicator can be a label, strip, film, and/or tape that can change between two colors, or between a colored condition and colorless condition.
- a thermochromic material can have an activation temperature, which is the temperature at which the material has reached its final color (or clear) state.
- a thermochromic material can be provided in the form of microcapsules which contain crystal violet lactone, a weak acid, and a dissociable salt dissolved in a non-polar or slightly polar solvent liquid crystal solvent such as dodecanol or another suitable liquid crystal solvent. When the temperature is room tempertaure, the dye exists in its lactone leuco form.
- thermochromic dyes can be based on mixtures of leucodyes with suitable other chemicals, which display a color change (usually between a colorless leuco form and the colored form of the dye) dependent on the temperature.
- Thermochromic materials which can be used in the current application also include, but are not limited to, spirolactones, fluorans, spiropyrans, or fulgides.
- Weak acids that can be used as proton donors include bisphenol A, parabens, 1,2,3-triazole derivatives, and 4-hydroxycoumarin. These weak acids can function as a proton donor to cause a dye molecule to change between its leuco form and its protonated colored form. Stronger Bronsted acids (better proton donors) can also be used but they tend to make the color change irreversible.
- thermosensitive dyes that can be used include an oxazine- based leuco thermosensitive dye (such as that sold under the trade mark CSB-12 by Hodogaya Chemicals Co), a spiropyran-based leuco thermosensitive dye (such as that sold under the trade mark CSR-13 by Hodogaya Chemicals Co), a quinoline-based thermosensitive dye (such as that sold under the trade mark CSY-13 by Hodogaya Chemicals Co) or the like.
- an oxazine- based leuco thermosensitive dye such as that sold under the trade mark CSB-12 by Hodogaya Chemicals Co
- a spiropyran-based leuco thermosensitive dye such as that sold under the trade mark CSR-13 by Hodogaya Chemicals Co
- a quinoline-based thermosensitive dye such as that sold under the trade mark CSY-13 by Hodogaya Chemicals Co
- thermosensitive dyes that can be used in the thermochromic material are non- toxic and are known to activate at temperatures in the range of 21 to 51 °C and which are available from SICPA Securink Corporation of Springfield, Va. These dyes include 744020TC (thermochromic blue), 744010TC (thermochromic turquoise), 744027TC (thermochromic yellow), 734010TC (thermochromic rose), 724010TC (thermochromic orange), 754027TC (thermochromic green). There are also thermochromic dyes which lose color when heated, so that they change from a color towards clear.
- These dyes include 178002TC (black/clear) which is active at 80 to 97 degrees C and 128001TC (orange/clear), 1384175TC (rose/clear), 150015TC (green/clear), 148003TC (blue/clear), 17800TC (black/clear), 14001TCBR (blue/red), or 128001TCY (orange/yellow), or combinations thereof.
- the indicator can comprise an agent that changes colors based on pH such as, for example, bromophenol blue. For example, as moisture from respiration or sweat occurs in the mask, the pH will decrease and the color will be indicated so the user can change the mask.
- Figure 7 illustrates an embodiment of the indicator shown as a strip 77.
- the strip at one end has a section 81 that can be held and used to pull the strip from the mask. This embodiment is useful for example when the strip is going to be used to test a pathogen.
- the strip can be pulled from the mask and the strip can be cultured to see what pathogen can grow (bacteria, virus, mold, etc.).
- the strip can be attached to the mask by velcro, adhesive, glue, or other attachment means.
- the strip comprises an indicator region 83 disposed on the strip that gives a visual indication (certain color, color change, or turn colorless, etc.) when a certain threshold temperature, moisture, and/or pathogen is present so that the mask can be changed or used only for a certain period of time.
- the strip can comprise a region 85 that does not contain any visual indication.
- the strip can comprise the same material as the mask, for example, nanofibers and non-nanofibers.
- the indicator comprises a collector that can capture microbes and they can be sent to the laboratory for identification or in some embodiments, the collector can capture the microbe and have an indicator to identify the microbe (e.g., gram positive or gram negative bacteria, etc.).
- the collector allows immobilization of the microbes that can be sent to the lab.
- the mask can have certain colors for the malleable member (e.g., strip) so the user can know how to wear the mask.
- the nose piece can be a certain color of the malleable member and the malleable member of the chin piece can be a different color than the nose piece.
- the outside of the mask can be marked with a different color to indicate the part of the mask to be worn on the nose and that part of the mask to be worn on the mouth.
- the facemask may be formed from a variety of materials and fabrics, such as woven reusable fabrics and nonwoven disposable fabrics or webs.
- nonwoven fabric or “nonwoven web” or “nonwoven material” means a web having a structure of individual fibers or threads that are randomly interlaid, but not in an identifiable manner or pattern as in a knitted fabric.
- Nonwoven fabrics or webs have been formed from many processes, for example, meltblowing processes, spunbonding processes, and bonded carded web processes.
- spunbond or "spunbond fibers” or “spunbonded fibers” refers to small diameter fibers that are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced, for example, as in U.S. Pat. No. 4,340,563 to Appel et al., and U.S. Pat. No. 3,692,618 to Dorschner et al., U.S. Pat. No. 3,802,817 to Matsuki et al., U.S. Pat. Nos. 3,338,992 and 3,341,394 to Kinney, U.S. Pat. No. 3,502,763 to Hartman, and U.S. Pat. No. 3,542,615 to Dobo et al.
- meltblown or “meltblown fibers” means fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity, usually hot, gas (e.g. air) streams that attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly disbursed meltblown fibers.
- gas e.g. air
- the facemask may be formed from a single layer or multiple layers of material or a composite of multiple layers.
- the layers are generally positioned in a juxtaposed or surface-to-surface relationship and all or a portion of the layers may be bound to adjacent layers.
- the multiple layers of a composite may be joined to form a multilayer laminate by various methods, including but not limited to adhesive bonding, thermal bonding, or ultrasonic bonding.
- SMS laminate is a spunbond/meltblown/spunbond (SMS) laminate.
- SMS laminate may be made by sequentially depositing onto a moving forming belt first a spunbond fabric layer, then a meltblown fabric layer and last another spunbond layer and then bonding the laminate in a manner described below.
- the fabric layers may be made individually, collected in rolls, and combined in a separate bonding step.
- Multilayer laminates may have multiple meltblown layers or multiple spunbond layers in many different configurations and may include materials other than nonwovens. Examples of such other materials include wovens, films, foam/film laminates and combinations thereof, for example, a spunbond/film/spunbond (SFS) laminate.
- SFS spunbond/film/spunbond
- Examples of other composite materials suitable for use in the present invention include, but are not limited to, those described in U.S. Pat. No. 4,041,203 to Brock et al., U.S. Pat. No. 5,169,706 to Collier, et al., U.S. Pat. No. 5,145,727 to Potts et al., U.S. Pat. No. 5,178,931 to Perkins et al., U.S. Pat. No. 4,374,888 to Bornslaeqer, and U.S. Pat. No. 5,188,885 to Timmons et al., which are all incorporated herein by reference.
- the facemask of the present application may include a layer of material, for example, a nonwoven material, suitable for filtration.
- the filtration material may be made from a meltblown nonwoven web and, in some embodiments, may be subject to electret treating.
- electret or “electret treating” refers to a treatment that imparts a charge to a dielectric material, such as a polyolefin.
- the charge includes layers of positive or negative charges trapped at or near the surface of the polymer, or charge clouds stored in the bulk of the polymer.
- the charge also includes polarization charges that are frozen in alignment of the dipoles of the molecules. Methods of subjecting a material to electret treating are well known by those skilled in the art.
- the mask may include a layer of expanded polytetrafluoroethylene (PTFE) membrane for filtration, such as those manufactured by W. L. Gore & Associates.
- PTFE polytetrafluoroethylene
- the facemask comprises one or more layers individually or combined made of medical grade tissue, spun bound polypropylene, cellulose material, meltblown polypropylene, spun bound high density polyethylene, and/or low density polyethylene.
- one or more layers of the mask may be impervious or substantially impervious to liquid (e.g., spun bound polypropylene, and/or meltblown polypropylene layer(s)), which may cause liquid to bead on one or more surfaces or layers of the mask.
- liquid e.g., spun bound polypropylene, and/or meltblown polypropylene layer(s)
- the facemask can be made by providing the filter material and inserting or attaching the malleable stiffening members to the mask, where at least one malleable stiffening member is partially bent, crimped, creased, folded, and/or angled and attached to or in the nose portion of the mask, either on the inside of the mask or outside of it and then attaching a second malleable stiffening member to the lower portion of the mask for the chin and/or jaw area; and attaching securing members to the mask, either on the inside of the mask or outside of it.
- the bend portion is pinched, crimped, bent, creased, folded, or angled toward the inner surface or outer surface of the facemask by about 1 to 10 degrees or by 1 mm to about 20 mm by hand or machine, before, during or after it is attached or imbedded in the mask.
- crimping machines having stops, posts, or the like that allow the bend portion to be formed.
- Tables 1-3 below display the differential pressure or pressure drop between the interior of the facemask and the surrounding environment using a facemask of the present disclosure having nanofiber layers. Tables 1-3 also display the differential pressures measured using a facemask without a discrete nanofiber layer and a three layer melt-blown nonwoven fiber facemask without a discrete nanofiber layer. Three separate trials runs were performed for each facemask as represented by Tables 1, 2 and 3, respectively. Air was directed through an inner surface of the mask representing the flow of a wearer's breath during exhalation. Differential pressure drop was measured for air flows of 25, 125, 250 and 500 liters per minute. The results are displayed below.
- the differential pressures measured for the facemask of the present disclosure is as much as approximately 18 times lower than the differential pressures measured for facemasks without discrete nanofiber layers.
- the differential pressure is directly related to the amount of air that gets deflected above and below the facemask. Therefore, a lower differential drop associated with the use of the facemask of the present disclosure results in a reduced amount of air deflection and an increased amount of air that passes through the facemask rather than around the facemask.
- Facemasks without discrete nanofiber layer(s) demonstrated higher air deflection and therefore less airflow through the facemask.
- the nanofiber coating can have a thickness from between 0.03 grams per square meter (gsm) to about 1.0 gsm, or 1-60 gsm. Further, each surface of the filter material can have multiple coatings of nanofiber layers to increase the thickness of the nanofiber coating. The length of each nanofiber can be below approximately 0.01 deniers.
- Figure 8 is a graphic illustration showing different mask filtration. Those marked with "T" were taped to the face; those not marked with a T were not taped. The nanofiber masks had greater filtration than other masks.
- Figure 9 is a graphic illustration showing different pressure differentials with various masks. The pressure differentials were lower with the nanofiber masks indicating reduced deflection and better filtration.
- the nanofibers By having the nanofibers on the inside surface of the outer layer or on the middle layer or inner layer or in place of the middle layer, there is low pressure differential between layers and there is enhanced filtration efficiency. There is also enhanced bidirectional flow of air.
- the nanofibers can be integrally adhered (e.g., applied) to the inside of the outer layer material.
Abstract
Description
Claims
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/US2013/032518 WO2014143039A1 (en) | 2013-03-15 | 2013-03-15 | A facemask having one or more nanofiber layers |
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EP2969040A1 true EP2969040A1 (en) | 2016-01-20 |
EP2969040A4 EP2969040A4 (en) | 2016-11-09 |
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EP13878371.7A Withdrawn EP2969040A4 (en) | 2013-03-15 | 2013-03-15 | A facemask having one or more nanofiber layers |
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EP (1) | EP2969040A4 (en) |
CN (1) | CN105246552B (en) |
AU (1) | AU2013381874B2 (en) |
NZ (1) | NZ712238A (en) |
WO (1) | WO2014143039A1 (en) |
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-
2013
- 2013-03-15 EP EP13878371.7A patent/EP2969040A4/en not_active Withdrawn
- 2013-03-15 WO PCT/US2013/032518 patent/WO2014143039A1/en active Application Filing
- 2013-03-15 NZ NZ712238A patent/NZ712238A/en not_active IP Right Cessation
- 2013-03-15 US US14/775,420 patent/US20160015098A1/en not_active Abandoned
- 2013-03-15 AU AU2013381874A patent/AU2013381874B2/en not_active Ceased
- 2013-03-15 CN CN201380075761.7A patent/CN105246552B/en not_active Expired - Fee Related
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WO2014143039A1 (en) | 2014-09-18 |
US20160015098A1 (en) | 2016-01-21 |
CN105246552A (en) | 2016-01-13 |
NZ712238A (en) | 2017-12-22 |
CN105246552B (en) | 2018-11-06 |
AU2013381874B2 (en) | 2018-03-01 |
AU2013381874A1 (en) | 2015-10-01 |
EP2969040A4 (en) | 2016-11-09 |
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