CN107594645B - A kind of Anti-bacterium, antiskid socks - Google Patents
A kind of Anti-bacterium, antiskid socks Download PDFInfo
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- CN107594645B CN107594645B CN201711032346.XA CN201711032346A CN107594645B CN 107594645 B CN107594645 B CN 107594645B CN 201711032346 A CN201711032346 A CN 201711032346A CN 107594645 B CN107594645 B CN 107594645B
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- 239000000463 material Substances 0.000 claims abstract description 40
- 230000003115 biocidal effect Effects 0.000 claims abstract description 21
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 19
- 229940088710 antibiotic agent Drugs 0.000 claims abstract description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 31
- 239000002086 nanomaterial Substances 0.000 claims description 31
- 229910052593 corundum Inorganic materials 0.000 claims description 27
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 27
- 238000002360 preparation method Methods 0.000 claims description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 23
- -1 polyethylene Polymers 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 19
- 238000010792 warming Methods 0.000 claims description 18
- 239000004698 Polyethylene Substances 0.000 claims description 16
- 229920000573 polyethylene Polymers 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- WBJINCZRORDGAQ-UHFFFAOYSA-N ethyl formate Chemical class CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000010410 layer Substances 0.000 claims description 14
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 14
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 13
- 239000004626 polylactic acid Substances 0.000 claims description 13
- 238000010348 incorporation Methods 0.000 claims description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 12
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 11
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 11
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 11
- 241000894006 Bacteria Species 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 235000006708 antioxidants Nutrition 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 4
- 125000002382 camphene group Chemical group 0.000 claims description 4
- 239000003446 ligand Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000005245 sintering Methods 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 150000003639 trimesic acids Chemical class 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 7
- 230000000845 anti-microbial effect Effects 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 229940094506 lauryl betaine Drugs 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- WJEIYVAPNMUNIU-UHFFFAOYSA-N [Na].OC(O)=O Chemical compound [Na].OC(O)=O WJEIYVAPNMUNIU-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 210000002683 foot Anatomy 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 239000013084 copper-based metal-organic framework Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 208000021302 gastroesophageal reflux disease Diseases 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012621 metal-organic framework Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000003244 pro-oxidative effect Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 201000004647 tinea pedis Diseases 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
- A41B11/008—Hosiery with an anti-slip coating
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
- A41B11/02—Reinforcements
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/22—Breathability, i.e. being vapour permeable and waterproof
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/80—Friction or grip reinforcement
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Anti-bacterium, antiskid socks, it includes toe, heel, stocking blank and socks ontology, and the stocking blank uses elasticity material, and the toe and heel surface bonding have anti-slip layer, and the inner layer of the socks is all stained with nano anti-biotic material.The present invention it include toe, heel, stocking blank and socks ontology, toe and heel surface bonding have anti-slip layer, with extraordinary antiskid effect, the inner layer of the socks is all stained with nano anti-biotic material, using special nano anti-biotic material, good anti-bacterial effect, the socks ontology is equipped with several air holes, it is ventilative, comfortably.
Description
Technical field
The present invention relates to a kind of Anti-bacterium, antiskid socks.
Background technique
Socks are indispensable daily necessities in people's life, either walk, move and still stroll Shi Douhui use
It arrives, due to the relationship of part socks poor air permeability, foot is generated often in moist, air-locked microenvironment, bacterium easy to breed
Tinea pedis etc. endangers foot, and general socks are substantially and are knitted, and coefficient of friction is small and road holding is not high, antiskid effect
Difference.
Summary of the invention
In view of the above problems, the present invention provides a kind of Anti-bacterium, antiskid socks, has anti-skidding and anti-microbial property.
To achieve the goals above, present invention provide the technical scheme that a kind of Anti-bacterium, antiskid socks, it include toe,
Heel, stocking blank and socks ontology,
The stocking blank uses elasticity material,
The toe and heel surface bonding has anti-slip layer,
The inner layer of the socks is all stained with nano anti-biotic material.
The stocking blank surface is coated with fluorescent material,
The socks ontology is equipped with several air holes.
Matcoveredn is bonded on the inside of the stocking blank, protective layer is sponge material.
The nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3Nano material, Ethyl formate, polylactic acid, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are primary raw material preparation.
It includes toe, heel, stocking blank and socks ontology to the present invention, and toe and heel surface bonding have anti-slip layer, is had non-
Often good antiskid effect, the inner layer of the socks are all stained with nano anti-biotic material, using special nano anti-biotic material,
Good anti-bacterial effect, the socks ontology are equipped with several air holes, breathe freely, comfortably.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention；
In figure: 1, socks ontology, 2, toe, 3, heel, 4, stocking blank.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Referring to Fig. 1, a kind of Anti-bacterium, antiskid socks, it includes toe 2, heel 3, stocking blank and socks ontology 1,
The stocking blank uses elasticity material,
The toe and heel surface bonding has anti-slip layer,
The inner layer of the socks is all stained with nano anti-biotic material.
The stocking blank surface is coated with fluorescent material,
The socks ontology is equipped with several air holes.
Matcoveredn is bonded on the inside of the stocking blank, protective layer is sponge material.
It includes toe, heel, stocking blank and socks ontology to the present invention, and toe and heel surface bonding have anti-slip layer, is had non-
Often good antiskid effect, the inner layer of the socks are all stained with nano anti-biotic material, using special nano anti-biotic material,
Good anti-bacterial effect, the socks ontology are equipped with several air holes, breathe freely, comfortably.
The nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3Nano material, Ethyl formate, polylactic acid, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are primary raw material preparation.
The inner layer of socks of the present invention is all stained with nano anti-biotic material, and the material use porous aluminas and Cu-MOF are in situ
It is cross-linked to form the matrices of composite material with network structure, and the copper ion in basis material forming process, in basis material
It may be homogenously dispersed in the network structure of matrix crosslinking, improve the antibacterial stability of material；MOF organic ligand constructs double-layer structure
Platform will be hidden under " clean " surface of a stable against biological contamination on polyethylene, under dry conditions, outermost molecular brush
Surface dehydration is collapsed, and internal antibacterial polymer is made to kill bacterium in a manner of contact sterilization, equal to Escherichia coli and staphylococcus
With preferable antibacterial effect.
More specifically the preparation method is as follows:
The preparation method of anti-biotic material, method includes the following steps:
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
1.5 parts of antioxidant BHTs and 1.3 parts of aid anti-oxidants DLTP are added in the head product that step 1 obtains by step 2,
It is uniformly mixed under the conditions of temperature is 80 DEG C, mixing speed is 200 revs/min, and mixing time is 30 minutes；
Step 3, the mixture for obtaining step 2 squeeze out in double screw extruder, and extrusion condition is double screw extruder
Cylinder back segment temperature divides three stage control, is controlled respectively at 180 DEG C, 185 DEG C and 190 DEG C, and barrel front-end temperature divides three stage control, respectively
At 195 DEG C, 200 DEG C and 210 DEG C, head temperature is divided to two sections of controls, is controlled respectively in 230 DEG C and 236 DEG C, finally obtains doctor for control
Use nano-antibacterial composite material.
The Cu-MOF-Al2O3Preparation method of nano material is as follows:
Step 1, by 10 parts of alumina powders, 0.3 part of Sodium Polyacrylate, 19.4 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of oxygen
Change yttrium mixing to be put into flask, the uniform stirring at 75 DEG C obtains slurry；
Step 2 pours into slurry in mold, places at -16 DEG C, obtains being shaped to columnar aluminum oxide porous particle modeling
Base；
Aluminum oxide porous particle preform is first placed 12h by step 3 at -16 DEG C, is then put it into freeze drier
Dry 6h under the conditions of -60 DEG C finally carries out high temperature sintering with the speed heating of 4 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h,
Porous oxidation aluminum substrate is obtained after cooling；
Step 4 takes 4.2 parts of trimesic acids, is added in the ethanol solution of 25 parts of mass fractions 95%, molten as ligand
Liquid is stand-by；
The porous oxidation aluminum substrate prepared is impregnated 5h in enough above-mentioned ligand solutions by step 5；
Step 6 will be put into enough concentration after above-mentioned impregnated porous oxidation aluminum substrate filtering as 0.5 mol/L's
In copper nitrate solution, 22h is reacted in 80 DEG C of oil baths and under the conditions of condensing reflux, is filtered, dry (dry temperature is 100
DEG C), the dry time be 12h) after obtain Cu-MOF-Al2O3Nano material.
Embodiment 2
Step 1, by 50 parts of polyethylene, 16 parts of Cu-MOF-Al2O3Nano material, 4 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 3
Step 1, step 1, by 45 parts of polyethylene, 23 parts of Cu-MOF-Al2O3The poly- cream of nano material, 6 parts of Ethyl formates and 5 parts
Acid is added in reaction kettle, by 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate
It is dissolved in 30 parts of water, is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the stirring being uniformly mixed
Speed is 150 revs/min, and incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 points
Clock, then 130 DEG C are warming up to, it is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 4
Step 1, by 38 parts of polyethylene, 19 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 5
Step 1, by 17 parts of polyethylene, 3 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 6
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 5 parts of Ethyl formates and 1 part of polylactic acid are added
Into reaction kettle, 4 parts of sodium carbonate, 3 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 0.8 part of sodium xylene sulfonate are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 7
Step 1, by 34 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 8 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 8
Step 1, by 34 parts of polyethylene, 17 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 4 parts of sodium xylene sulfonates are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 9
Step 1, by 65 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 3 parts of sodium carbonate, 1 part of lauryl betaine, 1 part of sodium tripolyphosphate and 2.1 parts of sodium xylene sulfonates are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 10
Step 1, by 75 parts of polyethylene, 37 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added
Into reaction kettle, 1 part of sodium carbonate, 8 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30
In part water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 11
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 8 parts of modified carbon fibers, 3 parts of Ethyl formates
It is added in reaction kettle with 5 parts of polylactic acid, by 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part two
Toluenesulfonic acid sodium salt is dissolved in 30 parts of water, is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein being stirred
Uniform mixing speed is 150 revs/min, and incorporation time is 30 minutes, is then warming up to 80 in the case where vacuum degree is 0.01MPa
DEG C, it stirs 20 minutes, then be warming up to 130 DEG C, is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
The modified carbon fiber the preparation method is as follows:
Carbon fiber is placed in acetone soln and impregnates 12h, is filtered, deionized water is washed 3 times, in 120 DEG C of blast driers
Dry 4h, with 60% nitric acid reflux oxidation carbon fiber 7h, filtering, deionized water washs PH=6, does in 120 DEG C of blast driers
It is dry to constant weight；The carbon fiber of nitric acid oxidation is placed in polyvinylpyrrolidone, lauryl sodium sulfate and is equivalent to its total weight
In the solution of 12 times of the deionized water configuration of part, ultrasonic 50min, 60 DEG C of dryings obtain the modified carbon fiber in surface.
Reference examples 1
It is with 1 difference of embodiment: in the step 2 of antimicrobial nano material, 2 parts of antioxidant BHTs and 0.3 part is helped anti-
Oxygen agent DLTP is added in the head product that step 1 obtains, remaining step is identical with embodiment 1.
Reference examples 2
It is with 1 difference of embodiment: in the step 2 of antimicrobial nano material, 0.3 part of antioxidant BHT and 2 parts is helped anti-
Oxygen agent DLTP is added in the head product that step 1 obtains, remaining step is identical with embodiment 1.
Reference examples 3
It is with 1 difference of embodiment: in the step 3 of antimicrobial nano material, twin screw extruder barrel back segment temperature point three
Section control, controls respectively at 150 DEG C, 155 DEG C and 160 DEG C, remaining step is identical with embodiment 1.
Reference examples 4
It is with 1 difference of embodiment: in the step 3 of antimicrobial nano material, twin screw extruder barrel back segment temperature point three
Section control, controls respectively at 190 DEG C, 195 DEG C and 200 DEG C, remaining step is identical with embodiment 1.
Reference examples 5
It is with 1 difference of embodiment: Cu-MOF-Al2O3In the step 1 of nano material preparation, by 8 parts of alumina powders, 3
Part Sodium Polyacrylate, 14 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yttrium oxide mixing are put into flask, are uniformly stirred at 75 DEG C
It mixes, obtains slurry, remaining step is identical with embodiment 1.
Reference examples 6
It is with 1 difference of embodiment: Cu-MOF-Al2O3Nano material preparation step 1 in, by 16 parts of alumina powders,
0.1 part of Sodium Polyacrylate, 6 parts of camphenes, 9 parts of tert-butyl alcohols and 3 parts of yttrium oxide mixing are put into flask, the uniform stirring at 75 DEG C,
Slurry is obtained, remaining step is identical with embodiment 1.
Reference examples 7
It is with 1 difference of embodiment: Cu-MOF-Al2O3In the step 3 of nano material preparation, it is put into freeze drier
Dry 6h under the conditions of -60 DEG C finally carries out high temperature sintering with the speed heating of 15 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h,
Remaining step is identical with embodiment 1.
Reference examples 8
It is with 1 difference of embodiment: Cu-MOF-Al2O3In the step 3 of nano material preparation, it is put into freeze drier
Dry 6h under the conditions of -60 DEG C finally carries out high temperature sintering with the speed heating of 25 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h,
Remaining step is identical with embodiment 1.
Reference examples 9
It is with 1 difference of embodiment: Cu-MOF-Al2O3It, will be above-mentioned impregnated more in the step 3 of nano material preparation
It is put into after the filtering of porous aluminum oxide matrix in the copper nitrate solution that enough concentration is 0.01mol/L, remaining step and embodiment 1
It is identical.
Reference examples 10
It is with 1 difference of embodiment: Cu-MOF-Al2O3It, will be above-mentioned impregnated more in the step 3 of nano material preparation
It is put into after the filtering of porous aluminum oxide matrix in the copper nitrate solution that enough concentration is 1.0mol/L, remaining step and embodiment 1
It is identical.
The anti-biotic material that above embodiments and reference examples are prepared is tested for the property, and test the 100th day after its
Antibacterial effect, it is as a result as follows；
Test result
The experimental results showed that the anti-biotic material inside socks body of the present invention has good antibacterial effect, material is in standard testing
Under the conditions of, Bacteria suppression rate is lower, illustrates good anti-bacterial effect, conversely, effect is poorer；Embodiment 1 arrives embodiment 10, grape ball
Bacterium and Escherichia coli inhibiting rate change the proportion of each raw material composition in anti-biotic material, to the antibacterial of material more than 85% respectively
Performance has different degrees of influence, polyethylene and Cu-MOF-Al2O3Nano material quality proportioning is 5:1, other ingredient dosages
When fixed, antibacterial effect is best；It is worth noting that modified carbon fiber is added in embodiment 11, antibacterial effect is significantly improved, and
Antibacterial stability keeps unusual outstanding, illustrates modified carbon fiber to Cu-MOF-Al2O3The antibiotic property of nanometer insulation layer structure
Energy and stability have better optimization function；Reference examples 1 to reference examples 2 change antimicrobial nano material against oxidative agent dosage, resist
Bacterium effect is decreased obviously, and illustrates that the dosage of antioxidant and pro-oxidant has an important influence on the antibiotic property of material；Reference examples 3
With reference examples 4, change the height of three stage control temperature, the material bacteria inhibiting rate of synthesis is still very low, and anti-microbial property is bad；It is right
5 change Cu-MOF-Al to reference examples 8 as usual2O3The raw material proportioning and heating rate of nano material, effect is also bad, illustrates raw material
Composition and temperature-rise period to Cu-MOF-Al2O3Nano material obtains compound have a major impact；Reference examples 9 and the change of example 10 impregnated
The concentration of copper nitrate solution, antibacterial effect are substantially reduced in journey, illustrate copper nitrate it is excessive it is very few all can be to the Bacteria suppression of material
Rate influences very big；Therefore there is inside socks body good antibacterial effect using anti-biotic material.
Claims (3)
1. a kind of Anti-bacterium, antiskid socks, it includes toe, heel, stocking blank and socks ontology,
The stocking blank uses elasticity material,
The toe and heel surface bonding has anti-slip layer,
The inner layer of the socks is all stained with nano anti-biotic material；The nano anti-biotic material preparation method includes following step
It is rapid:
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to instead
It answers in kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate is dissolved in 30 parts of water
In, it is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is 150
Rev/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then heat up
To 130 DEG C, it is stirred to react 30 minutes, obtains head product；
1.5 parts of antioxidant BHTs and 1.3 parts of aid anti-oxidants DLTP are added in the head product that step 1 obtains by step 2, in temperature
Degree is uniformly mixed under the conditions of being 80 DEG C, and mixing speed is 200 revs/min, and mixing time is 30 minutes；
Step 3, the mixture for obtaining step 2 squeeze out in double screw extruder, and extrusion condition is after twin screw extruder barrel
Duan Wendu divides three stage control, is controlled respectively at 180 DEG C, 185 DEG C and 190 DEG C, and barrel front-end temperature divides three stage control, controls respectively
At 195 DEG C, 200 DEG C and 210 DEG C, head temperature is divided to two sections of controls, is controlled respectively in 230 DEG C and 236 DEG C, and it is anti-to finally obtain nanometer
Bacterium material；
The Cu-MOF-Al2O3Preparation method of nano material is as follows:
Step 1, by 10 parts of alumina powders, 0.3 part of Sodium Polyacrylate, 19.4 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yttrium oxide
Mixing is put into flask, and the uniform stirring at 75 DEG C obtains slurry；
Step 2 pours into slurry in mold, places at -16 DEG C, obtains being shaped to columnar aluminum oxide porous particle preform；
Aluminum oxide porous particle preform is first placed 12h by step 3 at -16 DEG C, then put it into freeze drier -
Dry 6h under the conditions of 60 DEG C finally carries out high temperature sintering with the speed heating of 4 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h, cooling
After obtain porous oxidation aluminum substrate；
Step 4 takes 4.2 parts of trimesic acids, is added in the ethanol solution of 25 parts of mass fractions 95%, waits for as ligand solution
With；
The porous oxidation aluminum substrate prepared is impregnated 5h in enough above-mentioned ligand solutions by step 5；
Step 6 will be put into the nitric acid that enough concentration is 0.5mol/L after above-mentioned impregnated porous oxidation aluminum substrate filtering
In copper solution, react 22h in 80 DEG C of oil baths and under the conditions of condensing reflux, filter, it is dry, after obtain Cu-MOF-Al2O3It receives
Rice material.
2. a kind of Anti-bacterium, antiskid socks according to claim 1, which is characterized in that the stocking blank surface is coated with phosphor
Material,
The socks ontology is equipped with several air holes.
3. a kind of Anti-bacterium, antiskid socks according to claim 1, which is characterized in that be bonded with protection on the inside of the stocking blank
Layer, protective layer is sponge material.
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| CN201811499661.8A CN109463807A (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
| CN201711032346.XA CN107594645B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
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| EP2969040A4 (en) * | 2013-03-15 | 2016-11-09 | Crosstex International Inc | A facemask having one or more nanofiber layers |
| CN205456097U (en) * | 2016-04-01 | 2016-08-17 | 浙江希望之星针织有限公司 | Novel antiskid antibacterial socks |
| CN206025230U (en) * | 2016-08-17 | 2017-03-22 | 海宁市越立袜业有限公司 | Running socks |
| CN106268656B (en) * | 2016-09-28 | 2019-03-19 | 中国石油大学(北京) | Porous alumina ceramic loaded Cu-MOF adsorbent and preparation method thereof |
| CN106937763A (en) * | 2017-05-21 | 2017-07-11 | 盐城巧丽袜业有限公司 | A kind of multi-functional short legging |
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