CN109463807A - A kind of Anti-bacterium, antiskid socks - Google Patents
A kind of Anti-bacterium, antiskid socks Download PDFInfo
- Publication number
- CN109463807A CN109463807A CN201811499661.8A CN201811499661A CN109463807A CN 109463807 A CN109463807 A CN 109463807A CN 201811499661 A CN201811499661 A CN 201811499661A CN 109463807 A CN109463807 A CN 109463807A
- Authority
- CN
- China
- Prior art keywords
- parts
- socks
- minutes
- nano
- mof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
- A41B11/008—Hosiery with an anti-slip coating
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
- A41B11/02—Reinforcements
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/22—Breathability, i.e. being vapour permeable and waterproof
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/80—Friction or grip reinforcement
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Anti-bacterium, antiskid socks, it includes toe, heel, stocking blank and socks ontology, and the toe and heel surface bonding have anti-slip layer, and the inner layer of the socks is all stained with nano anti-biotic material.The present invention it include toe, heel, stocking blank and socks ontology, toe and heel surface bonding have anti-slip layer, with extraordinary antiskid effect, the inner layer of the socks is all stained with nano anti-biotic material, using special nano anti-biotic material, good anti-bacterial effect, the socks ontology is equipped with several air holes, it is ventilative, comfortably.
Description
The original applying number of the application be 201711032346X, the applying date be on October 29th, 2017, entitled " one
Kind Anti-bacterium, antiskid socks ".
Technical field
The present invention relates to a kind of Anti-bacterium, antiskid socks.
Background technique
Socks are indispensable daily necessities in people's life, either walk, move and still stroll Shi Douhui use
It arrives, due to the relationship of part socks poor air permeability, foot is generated often in moist, air-locked microenvironment, bacterium easy to breed
Tinea pedis etc. endangers foot, and general socks are substantially and are knitted, and coefficient of friction is small and road holding is not high, antiskid effect
Difference.
Summary of the invention
In view of the above problems, the present invention provides a kind of Anti-bacterium, antiskid socks, has anti-skidding and anti-microbial property.
To achieve the goals above, present invention provide the technical scheme that a kind of Anti-bacterium, antiskid socks, it includes toe, socks
With, stocking blank and socks ontology,
The toe and heel surface bonding has anti-slip layer,
The inner layer of the socks is all stained with nano anti-biotic material.
The stocking blank surface is coated with fluorescent material,
The socks ontology is equipped with several air holes.
Matcoveredn is bonded on the inside of the stocking blank, protective layer is sponge material.
The nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3 nano material, Ethyl formate, polylactic acid, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are primary raw material preparation.
It includes toe, heel, stocking blank and socks ontology to the present invention, and toe and heel surface bonding have anti-slip layer, is had non-
Often good antiskid effect, the inner layer of the socks are all stained with nano anti-biotic material, using special nano anti-biotic material,
Good anti-bacterial effect, the socks ontology are equipped with several air holes, breathe freely, comfortably.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention；
In figure: 1, socks ontology, 2, toe, 3, heel, 4, stocking blank.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Referring to Fig. 1, a kind of Anti-bacterium, antiskid socks, it includes toe 2, heel 3, stocking blank and socks ontology 1,
The stocking blank uses elasticity material,
The toe and heel surface bonding has anti-slip layer,
The inner layer of the socks is all stained with nano anti-biotic material.
The stocking blank surface is coated with fluorescent material,
The socks ontology is equipped with several air holes.
Matcoveredn is bonded on the inside of the stocking blank, protective layer is sponge material.
It includes toe, heel, stocking blank and socks ontology to the present invention, and toe and heel surface bonding have anti-slip layer, is had non-
Often good antiskid effect, the inner layer of the socks are all stained with nano anti-biotic material, using special nano anti-biotic material,
Good anti-bacterial effect, the socks ontology are equipped with several air holes, breathe freely, comfortably.
The nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3 nano material, Ethyl formate, polylactic acid, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are primary raw material preparation.
The inner layer of socks of the present invention is all stained with nano anti-biotic material, and the material use porous aluminas and Cu-MOF are in situ
It is cross-linked to form the matrices of composite material with network structure, and the copper ion in basis material forming process, in basis material
It may be homogenously dispersed in the network structure of matrix crosslinking, improve the antibacterial stability of material；MOF organic ligand constructs double-layer structure
Platform will be hidden under " clean " surface of a stable against biological contamination on polyethylene, under dry conditions, outermost molecular brush
Surface dehydration is collapsed, and internal antibacterial polymer is made to kill bacterium in a manner of contact sterilization, equal to Escherichia coli and staphylococcus
With preferable antibacterial effect.
More specifically the preparation method is as follows:
The preparation method of anti-biotic material, method includes the following steps:
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
1.5 parts of antioxidant BHTs and 1.3 parts of aid anti-oxidants DLTP are added in the head product that step 1 obtains by step 2, in temperature
Degree is uniformly mixed under the conditions of being 80 DEG C, and mixing speed is 200 revs/min, and mixing time is 30 minutes；
Step 3, the mixture for obtaining step 2 squeeze out in double screw extruder, and extrusion condition is after twin screw extruder barrel
Duan Wendu divides three stage control, is controlled respectively at 180 DEG C, 185 DEG C and 190 DEG C, and barrel front-end temperature divides three stage control, controls respectively
At 195 DEG C, 200 DEG C and 210 DEG C, head temperature is divided to two sections of controls, is controlled respectively in 230 DEG C and 236 DEG C, finally obtains medical receive
Nano antibacterial composite material.
The Cu-MOF-Al2O3Preparation method of nano material is as follows:
Step 1, by 10 parts of alumina powders, 0.3 part of Sodium Polyacrylate, 19.4 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yttrium oxide
Mixing is put into flask, and the uniform stirring at 75 DEG C obtains slurry；
Step 2 pours into slurry in mold, places at -16 DEG C, obtains being shaped to columnar aluminum oxide porous particle preform；
Aluminum oxide porous particle preform is first placed 12h by step 3 at -16 DEG C, then put it into freeze drier -
Dry 6h under the conditions of 60 DEG C finally carries out high temperature sintering with the speed heating of 4 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h, cooling
After obtain porous oxidation aluminum substrate；
Step 4 takes 4.2 parts of trimesic acids, is added in the ethanol solution of 25 parts of mass fractions 95%, waits for as ligand solution
With；
The porous oxidation aluminum substrate prepared is impregnated 5h in enough above-mentioned ligand solutions by step 5；
Step 6 will be put into the nitric acid that enough concentration is 0.5 mol/L after above-mentioned impregnated porous oxidation aluminum substrate filtering
In copper solution, 22h is reacted in 80 DEG C of oil baths and under the conditions of condensing reflux, is filtered, it is dry (dry temperature is 100 DEG C),
The dry time be 12h) after obtain Cu-MOF-Al2O3Nano material.
Embodiment 2
Step 1, by 50 parts of polyethylene, 16 parts of Cu-MOF-Al2O3Nano material, 4 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 3
Step 1, step 1, by 45 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 6 parts of Ethyl formates and 5 parts of polylactic acid
It is added in reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate is molten
It in 30 parts of water, is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the stirring speed being uniformly mixed
Degree is 150 revs/min, and incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes,
It is warming up to 130 DEG C again, is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 4
Step 1, by 38 parts of polyethylene, 19 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 5
Step 1, by 17 parts of polyethylene, 3 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to instead
It answers in kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate is dissolved in 30 parts of water
In, it is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is 150
Rev/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then heat up
To 130 DEG C, it is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 6
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 5 parts of Ethyl formates and 1 part of polylactic acid are added to
In reaction kettle, 4 parts of sodium carbonate, 3 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 7
Step 1, by 34 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 8 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 8
Step 1, by 34 parts of polyethylene, 17 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 4 parts of sodium xylene sulfonates are dissolved in 30 parts of water
In, it is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is 150
Rev/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then heat up
To 130 DEG C, it is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 9
Step 1, by 65 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 3 parts of sodium carbonate, 1 part of lauryl betaine, 1 part of sodium tripolyphosphate and 2.1 parts of sodium xylene sulfonates are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 10
Step 1, by 75 parts of polyethylene, 37 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 8 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 11
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 8 parts of modified carbon fibers, 3 parts of Ethyl formates and 5
Part polylactic acid is added in reaction kettle, by 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of dimethylbenzene
Sodium sulfonate is dissolved in 30 parts of water, is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein being uniformly mixed
Mixing speed be 150 revs/min, incorporation time be 30 minutes, then vacuum degree be 0.01MPa under be warming up to 80 DEG C, stir
It mixes 20 minutes, then is warming up to 130 DEG C, be stirred to react 30 minutes, obtain head product；
Remaining preparation and embodiment 1 are identical.
The modified carbon fiber the preparation method is as follows:
Carbon fiber is placed in acetone soln and impregnates 12h, is filtered, deionized water is washed 3 times, dry in 120 DEG C of blast driers
4h, with 60% nitric acid reflux oxidation carbon fiber 7h, filtering, deionized water washs PH=6, dries extremely in 120 DEG C of blast driers
Constant weight；The carbon fiber of nitric acid oxidation is placed in polyvinylpyrrolidone, lauryl sodium sulfate and is equivalent to its total weight parts
In the solution of 12 times of deionized water configuration, ultrasonic 50min, 60 DEG C of dryings obtain the modified carbon fiber in surface.
Reference examples 1
It is with 1 difference of embodiment: in the step 2 of antimicrobial nano material, by 2 parts of antioxidant BHTs and 0.3 part of aid anti-oxidants
DLTP is added in the head product that step 1 obtains, remaining step is identical with embodiment 1.
Reference examples 2
It is with 1 difference of embodiment: in the step 2 of antimicrobial nano material, by 0.3 part of antioxidant BHT and 2 parts of aid anti-oxidants
DLTP is added in the head product that step 1 obtains, remaining step is identical with embodiment 1.
Reference examples 3
It is with 1 difference of embodiment: in the step 3 of antimicrobial nano material, three sections of controls of twin screw extruder barrel back segment temperature point
System, controls respectively at 150 DEG C, 155 DEG C and 160 DEG C, remaining step is identical with embodiment 1.
Reference examples 4
It is with 1 difference of embodiment: in the step 3 of antimicrobial nano material, three sections of controls of twin screw extruder barrel back segment temperature point
System, controls respectively at 190 DEG C, 195 DEG C and 200 DEG C, remaining step is identical with embodiment 1.
Reference examples 5
It is with 1 difference of embodiment: Cu-MOF-Al2O3In the step 1 of nano material preparation, 8 parts of alumina powders, 3 parts are gathered
Sodium acrylate, 14 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yttrium oxide mixing are put into flask, and the uniform stirring at 75 DEG C obtains
To slurry, remaining step is identical with embodiment 1.
Reference examples 6
It is with 1 difference of embodiment: Cu-MOF-Al2O3In the step 1 of nano material preparation, by 16 parts of alumina powders, 0.1
Part Sodium Polyacrylate, 6 parts of camphenes, 9 parts of tert-butyl alcohols and 3 parts of yttrium oxides mixing are put into flask, and the uniform stirring at 75 DEG C obtains
Slurry, remaining step are identical with embodiment 1.
Reference examples 7
It is with 1 difference of embodiment: Cu-MOF-Al2O3Nano material preparation step 3 in, be put into freeze drier-
Dry 6h under the conditions of 60 DEG C finally carries out high temperature sintering with the speed heating of 15 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h,
Remaining step is identical with embodiment 1.
Reference examples 8
It is with 1 difference of embodiment: Cu-MOF-Al2O3Nano material preparation step 3 in, be put into freeze drier-
Dry 6h under the conditions of 60 DEG C finally carries out high temperature sintering with the speed heating of 25 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h,
Remaining step is identical with embodiment 1.
Reference examples 9
It is with 1 difference of embodiment: Cu-MOF-Al2O3It, will be above-mentioned impregnated porous in the step 3 of nano material preparation
It is put into after alumina substrate filtering in the copper nitrate solution that enough concentration is 0.01mol/L, remaining step and embodiment 1 are complete
It is exactly the same.
Reference examples 10
It is with 1 difference of embodiment: Cu-MOF-Al2O3It, will be above-mentioned impregnated porous in the step 3 of nano material preparation
It is put into after alumina substrate filtering in the copper nitrate solution that enough concentration is 1.0mol/L, remaining step and embodiment 1 are complete
It is exactly the same.
The anti-biotic material that above embodiments and reference examples are prepared is tested for the property, and test the 100th day after its
Antibacterial effect, it is as a result as follows；
Test result
The experimental results showed that the anti-biotic material inside socks body of the present invention has good antibacterial effect, material is in standard test condition
Under, Bacteria suppression rate is lower, illustrates good anti-bacterial effect, conversely, effect is poorer；Embodiment 1 arrives embodiment 10, staphylococcus and big
Enterobacteria inhibiting rate changes the proportion of each raw material composition in anti-biotic material more than 85% respectively, equal to the anti-microbial property of material
There are different degrees of influence, polyethylene and Cu-MOF-Al2O3Nano material quality proportioning is 5:1, when other ingredient dosages are fixed,
Antibacterial effect is best；It is worth noting that modified carbon fiber is added in embodiment 11, antibacterial effect is significantly improved, and antibacterial is stablized
Property keep unusual outstanding, illustrate modified carbon fiber to Cu-MOF-Al2O3The anti-microbial property of nanometer insulation layer structure and steady
It is qualitative to have better optimization function；Reference examples 1 to reference examples 2 change antimicrobial nano material against oxidative agent dosage, and antibacterial effect is bright
Aobvious decline, illustrates that the dosage of antioxidant and pro-oxidant has an important influence on the antibiotic property of material；Reference examples 3 and reference examples
4, change the height of three stage control temperature, the material bacteria inhibiting rate of synthesis is still very low, and anti-microbial property is bad；Reference examples 5 arrive
Reference examples 8 change Cu-MOF-Al2O3The raw material proportioning and heating rate of nano material, effect is also bad, illustrates the composition of raw material
With temperature-rise period to Cu-MOF-Al2O3Nano material obtains compound have a major impact；Reference examples 9 and example 10 change nitre in dipping process
The concentration of sour copper solution, antibacterial effect are substantially reduced, illustrate copper nitrate it is excessive it is very few all can the Bacteria suppression rate on material influence
It is very big；Therefore there is inside socks body good antibacterial effect using anti-biotic material.
Claims (3)
1. a kind of Anti-bacterium, antiskid socks, it includes toe, heel, stocking blank and socks ontology,
The toe and heel surface bonding has anti-slip layer,
The inner layer of the socks is all stained with nano anti-biotic material.
2. a kind of Anti-bacterium, antiskid socks according to claim 1, which is characterized in that the stocking blank surface is coated with phosphor
Material,
The socks ontology is equipped with several air holes.
3. a kind of Anti-bacterium, antiskid socks according to claim 1, which is characterized in that be bonded with protection on the inside of the stocking blank
Layer, protective layer is sponge material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811499661.8A CN109463807A (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811499661.8A CN109463807A (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
| CN201711032346.XA CN107594645B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711032346.XA Division CN107594645B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109463807A true CN109463807A (en) | 2019-03-15 |
Family
ID=61080374
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711032346.XA Active CN107594645B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
| CN201811499661.8A Pending CN109463807A (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711032346.XA Active CN107594645B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN107594645B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107518440B (en) * | 2017-10-29 | 2019-01-22 | 上海东北亚新纺织科技有限公司 | A kind of Anti-bacterium, antiskid socks increasing the stocking leg |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014143039A1 (en) * | 2013-03-15 | 2014-09-18 | Crosstex International, Inc. | A facemask having one or more nanofiber layers |
| CN205456097U (en) * | 2016-04-01 | 2016-08-17 | 浙江希望之星针织有限公司 | Novel antiskid antibacterial socks |
| CN206025230U (en) * | 2016-08-17 | 2017-03-22 | 海宁市越立袜业有限公司 | Running socks |
| CN106268656B (en) * | 2016-09-28 | 2019-03-19 | 中国石油大学(北京) | Porous alumina ceramic loaded Cu-MOF adsorbent and preparation method thereof |
| CN106937763A (en) * | 2017-05-21 | 2017-07-11 | 盐城巧丽袜业有限公司 | A kind of multi-functional short legging |
| CN107142538B (en) * | 2017-06-27 | 2020-01-21 | 陕西科技大学 | Preparation method of metal organic framework composite antibacterial cellulose fiber filler |
-
2017
- 2017-10-29 CN CN201711032346.XA patent/CN107594645B/en active Active
- 2017-10-29 CN CN201811499661.8A patent/CN109463807A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN107594645A (en) | 2018-01-19 |
| CN107594645B (en) | 2019-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2019101531A4 (en) | Nano-oxide/kaolin composite hemostatic antibacterial material, hemostatic healing-promoting dressing and preparation method thereof | |
| CN107326470A (en) | A kind of processing method of the lasting modified polyester fiber of antibacterial | |
| CN102121174A (en) | Nonwovens containing antibacterial and antiviral master batches and method and device for producing same | |
| CN104963028A (en) | Antibacterial polyester fibers and preparation method for same | |
| CN107652518A (en) | A kind of preparation method of novel antibacterial material | |
| CN106954636A (en) | A kind of graphene nano silver composite material and its preparation method and application | |
| CN104206418A (en) | Preparation method and application of discoloration-preventing powdery silver-containing anti-bacterial agent | |
| CN107518440B (en) | A kind of Anti-bacterium, antiskid socks increasing the stocking leg | |
| CN108126231A (en) | A kind of preparation method of the antibacterial hospital gauze of high intensity | |
| CN108914247A (en) | A kind of high antibacterial non-woven fabric and preparation method thereof | |
| CN107594645B (en) | A kind of Anti-bacterium, antiskid socks | |
| CN108385202A (en) | A kind of resistance to discoloration antibacterial nylon fiber | |
| CN109337481A (en) | A kind of nano heat-insulating antibiotic paint and preparation method thereof | |
| US20170114191A1 (en) | Method for producing polymer latex particle coated with silver nanoparticles | |
| WO2017092234A1 (en) | Mesoporous zirconium-phosphate loaded nano-silver antibacterial polyester fiber and method for preparation thereof | |
| CN109777163A (en) | A kind of scrubbing resistance shell powder paint | |
| CN108295298A (en) | A kind of calcium alginate perforated membrane of the basic zirconium phosphate containing carrying metal ion and preparation method thereof | |
| CN112409777A (en) | Medical antibacterial breathable TPU film and preparation method thereof | |
| CN104161044A (en) | Preparation method and application of organic/inorganic compound antibacterial agent | |
| CN106978000A (en) | Far infrared health care inner wall putty powder and preparation method thereof | |
| CN103360731A (en) | Microencapsulated polyester fragrant masterbatch and preparation method thereof | |
| KR20170028852A (en) | A method for preparing antibacterial fiber | |
| CN106189400A (en) | A kind of preparation method of the photochromic inorganic coating of aqueous | |
| CN109337280A (en) | Fitness equipment novel antibacterial ABS material and preparation method thereof | |
| CN108300012A (en) | Antimicrobial form art coatings |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190315 |
|
| WD01 | Invention patent application deemed withdrawn after publication |