CN107594645A - A kind of Anti-bacterium, antiskid socks - Google Patents
A kind of Anti-bacterium, antiskid socks Download PDFInfo
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- CN107594645A CN107594645A CN201711032346.XA CN201711032346A CN107594645A CN 107594645 A CN107594645 A CN 107594645A CN 201711032346 A CN201711032346 A CN 201711032346A CN 107594645 A CN107594645 A CN 107594645A
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- socks
- bacterium
- nano
- stocking blank
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Links
- 239000000463 material Substances 0.000 claims abstract description 37
- 230000003115 biocidal effect Effects 0.000 claims abstract description 20
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 19
- 229940088710 antibiotic agent Drugs 0.000 claims abstract description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 31
- 239000002086 nanomaterial Substances 0.000 claims description 30
- 229910052593 corundum Inorganic materials 0.000 claims description 25
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 24
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 14
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 6
- 229940094506 lauryl betaine Drugs 0.000 claims description 4
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 claims description 2
- BFHYAOOZWLJQEP-UHFFFAOYSA-N sodium;1,2-xylene Chemical compound [Na].CC1=CC=CC=C1C BFHYAOOZWLJQEP-UHFFFAOYSA-N 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 7
- 238000003756 stirring Methods 0.000 description 26
- -1 polyethylene Polymers 0.000 description 18
- 238000010792 warming Methods 0.000 description 16
- 239000004698 Polyethylene Substances 0.000 description 15
- 238000002156 mixing Methods 0.000 description 15
- 229920000573 polyethylene Polymers 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 229920000747 poly(lactic acid) Polymers 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000010348 incorporation Methods 0.000 description 11
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 10
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 10
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 10
- 230000000845 anti-microbial effect Effects 0.000 description 9
- 239000003963 antioxidant agent Substances 0.000 description 7
- 235000006708 antioxidants Nutrition 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
- 239000004917 carbon fiber Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 4
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
- 125000002382 camphene group Chemical group 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000191940 Staphylococcus Species 0.000 description 2
- WJEIYVAPNMUNIU-UHFFFAOYSA-N [Na].OC(O)=O Chemical compound [Na].OC(O)=O WJEIYVAPNMUNIU-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 239000013084 copper-based metal-organic framework Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000002683 foot Anatomy 0.000 description 1
- 208000021302 gastroesophageal reflux disease Diseases 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000012621 metal-organic framework Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000003244 pro-oxidative effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 201000004647 tinea pedis Diseases 0.000 description 1
- 150000003639 trimesic acids Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
- A41B11/008—Hosiery with an anti-slip coating
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
- A41B11/02—Reinforcements
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/22—Breathability, i.e. being vapour permeable and waterproof
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/80—Friction or grip reinforcement
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of Anti-bacterium, antiskid socks, and it includes toe, heel, stocking blank and socks body, and described stocking blank uses elasticity material, and described toe and heel surface bonding have skid resistant course, and the nexine of described socks is all stained with nano anti-biotic material.The present invention it include toe, heel, stocking blank and socks body, toe and heel surface bonding have skid resistant course, with extraordinary skidproof effect, the nexine of described socks is all stained with nano anti-biotic material, using special nano anti-biotic material, its good anti-bacterial effect, described socks body is provided with some air-vents, it is ventilative, comfortably.
Description
Technical field
The present invention relates to a kind of Anti-bacterium, antiskid socks.
Background technology
Socks are indispensable daily necessitiess in people's life, either walk, move and still stroll Shi Douhui uses
Arrive, due to the relation of part socks poor air permeability, pin easy breed bacteria, produces often in moist, air-locked microenvironment
Tinea pedis etc. endangers foot, and general socks are substantially knitting and formed, and coefficient of friction is small and earth-grasping force is not high, skidproof effect
Difference.
The content of the invention
For above-mentioned problem, the present invention provides a kind of Anti-bacterium, antiskid socks, has anti-skidding and anti-microbial property.
To achieve these goals, technical scheme provided by the invention is：A kind of Anti-bacterium, antiskid socks, it include toe,
Heel, stocking blank and socks body,
Described stocking blank uses elasticity material,
Described toe and heel surface bonding has skid resistant course,
The nexine of described socks is all stained with nano anti-biotic material.
Described stocking blank surface scribbles fluorescent material,
Described socks body is provided with some air-vents.
Bonding matcoveredn on the inside of described stocking blank, protective layer is sponge material.
Described nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3Nano material, Ethyl formate, PLA, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are prepared for primary raw material.
It includes toe, heel, stocking blank and socks body to the present invention, and toe and heel surface bonding have skid resistant course, has non-
Often good skidproof effect, the nexine of described socks are all stained with nano anti-biotic material, using special nano anti-biotic material, its
Good anti-bacterial effect, described socks body are provided with some air-vents, breathe freely, comfortably.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention；
In figure：1st, socks body, 2, toe, 3, heel, 4, stocking blank.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made
Embodiment, belong to the scope of protection of the invention.
Referring to Fig. 1, a kind of Anti-bacterium, antiskid socks, it includes toe 2, heel 3, stocking blank and socks body 1,
Described stocking blank uses elasticity material,
Described toe and heel surface bonding has skid resistant course,
The nexine of described socks is all stained with nano anti-biotic material.
Described stocking blank surface scribbles fluorescent material,
Described socks body is provided with some air-vents.
Bonding matcoveredn on the inside of described stocking blank, protective layer is sponge material.
It includes toe, heel, stocking blank and socks body to the present invention, and toe and heel surface bonding have skid resistant course, has non-
Often good skidproof effect, the nexine of described socks are all stained with nano anti-biotic material, using special nano anti-biotic material, its
Good anti-bacterial effect, described socks body are provided with some air-vents, breathe freely, comfortably.
Described nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3Nano material, Ethyl formate, PLA, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are prepared for primary raw material.
The nexine of socks of the present invention is all stained with nano anti-biotic material, and the material use Woelm Alumina is in situ with Cu-MOF
The matrices of composite material with network structure is cross-linked to form, and in matrix material forming process, the copper ion in matrix material
It may be homogenously dispersed in the network structure of matrix crosslinking, improve the antibacterial stability of material；MOF organic ligands build double-decker
Platform, it will be hidden on polyethylene under " clean " surface of a stable against biological contamination, under dry conditions, outermost molecular brush
Surface dehydration is caved in, and the antibacterial polymer of inside is killed bacterium in a manner of contact sterilization, equal to Escherichia coli and staphylococcus
With preferable antibacterial effect.
More specifically preparation method is as follows：
The preparation method of anti-biotic material, this method comprise the following steps：
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of PLAs are added to
In reactor, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then rise
Temperature stirring reaction 30 minutes, obtains head product to 130 DEG C；
Step 2,1.5 parts of antioxidant BHTs and 1.3 parts of aid anti-oxidants DLTP are added in the head product that step 1 obtains, in temperature
Spend to be uniformly mixed under the conditions of 80 DEG C, mixing speed is 200 revs/min, and mixing time is 30 minutes；
Step 3, the mixture for obtaining step 2 are extruded in double screw extruder, and extrusion condition is after twin screw extruder barrel
Duan Wendu divides three stage control, controls respectively at 180 DEG C, 185 DEG C and 190 DEG C, barrel front-end temperature divides three stage control, controls respectively
At 195 DEG C, 200 DEG C and 210 DEG C, head temperature is divided to two sections of controls, controls respectively in 230 DEG C and 236 DEG C, finally gives medical receive
Nano antibacterial composite.
Described Cu-MOF-Al2O3Preparation method of nano material is as follows：
Step 1, by 10 parts of alumina powders, 0.3 part of Sodium Polyacrylate, 19.4 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yittrium oxide
Mixing is put into flask, the uniform stirring at 75 DEG C, obtains slurry；
Step 2, slurry poured into mould, placed at -16 DEG C, obtain being shaped to the aluminum oxide porous particle preform of column；
Step 3, by aluminum oxide porous particle preform first 12h is placed at -16 DEG C, then put it into freeze drier -
6h is dried under the conditions of 60 DEG C, high temperature sintering is finally carried out with 4 DEG C/min speed heating, is warming up to 1000 DEG C, is incubated 3h, cooling
After obtain porous oxidation aluminum substrate；
Step 4,4.2 parts of trimesic acids are taken, be added in the ethanol solution of 25 parts of mass fractions 95%, treated as ligand solution
With；
Step 5, the porous oxidation aluminum substrate prepared impregnated into 5h in enough above-mentioned ligand solutions；
Step 6, the nitric acid that enough concentration is 0.5 mol/L will be put into after the good porous oxidation aluminum substrate filtering of above-mentioned dipping
In copper solution, 22h is reacted in 80 DEG C of oil baths and under the conditions of condensing reflux, is filtered, is dried（Dry temperature is 100 DEG C）,
The dry time is 12h）After obtain Cu-MOF-Al2O3Nano material.
Embodiment 2
Step 1, by 50 parts of polyethylene, 16 parts of Cu-MOF-Al2O3Nano material, 4 parts of Ethyl formates and 5 parts of PLAs are added to
In reactor, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then rise
Temperature stirring reaction 30 minutes, obtains head product to 130 DEG C；
Remaining is prepared and embodiment 1 is identical.
Embodiment 3
Step 1, step 1, by 45 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 6 parts of Ethyl formates and 5 parts of PLAs
It is added in reactor, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate is molten
In 30 parts of water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the stirring speed being uniformly mixed
To spend for 150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes,
130 DEG C are warming up to again, stirring reaction 30 minutes, obtain head product；
Remaining is prepared and embodiment 1 is identical.
Embodiment 4
Step 1, by 38 parts of polyethylene, 19 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of PLAs are added to
In reactor, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then rise
Temperature stirring reaction 30 minutes, obtains head product to 130 DEG C；
Remaining is prepared and embodiment 1 is identical.
Embodiment 5
Step 1, by 17 parts of polyethylene, 3 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of PLAs are added to instead
Answer in kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts of water
In, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is 150
Rev/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then heat up
To 130 DEG C, stirring reaction 30 minutes, head product is obtained；
Remaining is prepared and embodiment 1 is identical.
Embodiment 6
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 5 parts of Ethyl formates and 1 part of PLA are added to
In reactor, 4 parts of sodium carbonate, 3 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then rise
Temperature stirring reaction 30 minutes, obtains head product to 130 DEG C；
Remaining is prepared and embodiment 1 is identical.
Embodiment 7
Step 1, by 34 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 8 parts of Ethyl formates and 5 parts of PLAs are added to
In reactor, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then rise
Temperature stirring reaction 30 minutes, obtains head product to 130 DEG C；
Remaining is prepared and embodiment 1 is identical.
Embodiment 8
Step 1, by 34 parts of polyethylene, 17 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of PLAs are added to
In reactor, 1 part of sodium carbonate, 5 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 4 parts of sodium xylene sulfonates are dissolved in 30 parts of water
In, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is 150
Rev/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then heat up
To 130 DEG C, stirring reaction 30 minutes, head product is obtained；
Remaining is prepared and embodiment 1 is identical.
Embodiment 9
Step 1, by 65 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of PLAs are added to
In reactor, 3 parts of sodium carbonate, 1 part of lauryl betaine, 1 part of sodium tripolyphosphate and 2.1 parts of sodium xylene sulfonates are dissolved in 30 parts
In water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then rise
Temperature stirring reaction 30 minutes, obtains head product to 130 DEG C；
Remaining is prepared and embodiment 1 is identical.
Embodiment 10
Step 1, by 75 parts of polyethylene, 37 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of PLAs are added to
In reactor, 1 part of sodium carbonate, 8 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then add in reactor, be uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum is 0.01MPa, stirs 20 minutes, then rise
Temperature stirring reaction 30 minutes, obtains head product to 130 DEG C；
Remaining is prepared and embodiment 1 is identical.
Embodiment 11
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 8 parts of modified carbon fibers, 3 parts of Ethyl formates and 5
Part PLA is added in reactor, by 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of dimethylbenzene
Sodium sulfonate is dissolved in 30 parts of water, is then added in reactor, is uniformly mixed under the conditions of 50 DEG C, wherein being uniformly mixed
Mixing speed be 150 revs/min, incorporation time be 30 minutes, then vacuum be 0.01MPa under be warming up to 80 DEG C, stir
Mix 20 minutes, then be warming up to 130 DEG C, stirring reaction 30 minutes, obtain head product；
Remaining is prepared and embodiment 1 is identical.
Described modified carbon fiber preparation method is as follows：
Carbon fiber is placed in acetone soln and soaks 12h, is filtered, deionized water is washed 3 times, is dried in 120 DEG C of blast driers
4h, with 60% nitric acid reflux oxidation carbon fiber 7h, filtering, deionized water washing PH=6, dried extremely in 120 DEG C of blast driers
Constant weight；The carbon fiber of nitric acid oxidation is placed in polyvinylpyrrolidone, lauryl sodium sulfate and equivalent to its total weight parts
In the solution of 12 times of deionized water configuration, ultrasonic 50min, 60 DEG C of dryings, the carbon fiber of surface modification is obtained.
Reference examples 1
It is with the difference of embodiment 1：In the step 2 of antimicrobial nano material, by 2 parts of antioxidant BHTs and 0.3 part of aid anti-oxidants
DLTP is added in the head product that step 1 obtains, and remaining step is identical with embodiment 1.
Reference examples 2
It is with the difference of embodiment 1：In the step 2 of antimicrobial nano material, by 0.3 part of antioxidant BHT and 2 parts of aid anti-oxidants
DLTP is added in the head product that step 1 obtains, and remaining step is identical with embodiment 1.
Reference examples 3
It is with the difference of embodiment 1：In the step 3 of antimicrobial nano material, the three sections of controls of twin screw extruder barrel back segment temperature point
System, is controlled at 150 DEG C, 155 DEG C and 160 DEG C, remaining step is identical with embodiment 1 respectively.
Reference examples 4
It is with the difference of embodiment 1：In the step 3 of antimicrobial nano material, the three sections of controls of twin screw extruder barrel back segment temperature point
System, is controlled at 190 DEG C, 195 DEG C and 200 DEG C, remaining step is identical with embodiment 1 respectively.
Reference examples 5
It is with the difference of embodiment 1：Cu-MOF-Al2O3In step 1 prepared by nano material, 8 parts of alumina powders, 3 parts are gathered
PAA, 14 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yittrium oxide mixing are put into flask, the uniform stirring at 75 DEG C, are obtained
It is identical with embodiment 1 to slurry, remaining step.
Reference examples 6
It is with the difference of embodiment 1：Cu-MOF-Al2O3In step 1 prepared by nano material, by 16 parts of alumina powders, 0.1
Part Sodium Polyacrylate, 6 parts of camphenes, 9 parts of tert-butyl alcohols and 3 parts of yittrium oxide mixing are put into flask, the uniform stirring at 75 DEG C, are obtained
Slurry, remaining step are identical with embodiment 1.
Reference examples 7
It is with the difference of embodiment 1：Cu-MOF-Al2O3Nano material prepare step 3 in, be put into freeze drier-
6h is dried under the conditions of 60 DEG C, high temperature sintering is finally carried out with 15 DEG C/min speed heating, 1000 DEG C is warming up to, is incubated 3h, its
Remaining step is identical with embodiment 1.
Reference examples 8
It is with the difference of embodiment 1：Cu-MOF-Al2O3Nano material prepare step 3 in, be put into freeze drier-
6h is dried under the conditions of 60 DEG C, high temperature sintering is finally carried out with 25 DEG C/min speed heating, 1000 DEG C is warming up to, is incubated 3h, its
Remaining step is identical with embodiment 1.
Reference examples 9
It is with the difference of embodiment 1：Cu-MOF-Al2O3In step 3 prepared by nano material, by good porous of above-mentioned dipping
It is put into after alumina substrate filtering in the copper nitrate solution that enough concentration is 0.01mol/L, remaining step and embodiment 1 are complete
It is exactly the same.
Reference examples 10
It is with the difference of embodiment 1：Cu-MOF-Al2O3In step 3 prepared by nano material, by good porous of above-mentioned dipping
It is put into after alumina substrate filtering in the copper nitrate solution that enough concentration is 1.0mol/L, remaining step and embodiment 1 are complete
It is exactly the same.
The anti-biotic material that above example and reference examples are prepared carries out performance test, and its antibacterial after testing the 100th day
Effect is as a result as follows；
Test result
Test result indicates that the anti-biotic material inside socks body of the present invention has good antibacterial effect, material is in standard test condition
Under, Bacteria suppression rate is lower, illustrates good anti-bacterial effect, conversely, effect is poorer；Embodiment 1 arrives embodiment 10, staphylococcus and
Escherichia coli inhibiting rate changes the proportioning of each raw material composition in anti-biotic material, to the anti-microbial property of material respectively more than 85%
There are different degrees of influence, polyethylene and Cu-MOF-Al2O3Nano material quality proportioning is 5：1, other dispensing dosages are fixed
When, antibacterial effect is best；It is worth noting that embodiment 11 adds modified carbon fiber, antibacterial effect significantly improves, and antibacterial
Stability keeps unusual outstanding, illustrates modified carbon fiber to Cu-MOF-Al2O3Nanometer insulation layer structure anti-microbial property with
And stability has more preferable optimization function；Reference examples 1 to reference examples 2 change antimicrobial nano material against oxidative agent dosage, antibacterial effect
Fruit is decreased obviously, and illustrates that the dosage of antioxidant and pro-oxidant produces material impact to the antibiotic property of material；Reference examples 3 and right
As usual 4, change the height of three stage control temperature, the material bacteria inhibiting rate of synthesis is still very low, and anti-microbial property is bad；Reference examples
5 change Cu-MOF-Al to reference examples 82O3The raw material proportioning and heating rate of nano material, effect is also bad, illustrates the group of raw material
Into with temperature-rise period to Cu-MOF-Al2O3Nano material obtains compound have a major impact；Reference examples 9 and example 10 change in dipping process
The concentration of copper nitrate solution, antibacterial effect substantially reduce, illustrate copper nitrate it is excessive it is very few all can be to the Bacteria suppression rate shadow of material
Sound is very big；Therefore there is good antibacterial effect inside socks body using anti-biotic material.
Claims (4)
1. a kind of Anti-bacterium, antiskid socks, it includes toe, heel, stocking blank and socks body,
Described stocking blank uses elasticity material,
Described toe and heel surface bonding has skid resistant course,
The nexine of described socks is all stained with nano anti-biotic material.
2. a kind of Anti-bacterium, antiskid socks according to claim 1, it is characterised in that described stocking blank surface scribbles phosphor
Material,
Described socks body is provided with some air-vents.
3. a kind of Anti-bacterium, antiskid socks according to claim 1, it is characterised in that be bonded with protection on the inside of described stocking blank
Layer, protective layer is sponge material.
4. a kind of Anti-bacterium, antiskid socks according to claim 1, it is characterised in that described nano anti-biotic material is with poly- second
Alkene, Cu-MOF-Al2O3Nano material, Ethyl formate, PLA, sodium carbonate, lauryl betaine, sodium tripolyphosphate and dimethylbenzene
Sodium sulfonate is prepared for primary raw material.
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| CN201711032346.XA CN107594645B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
| CN201811499661.8A CN109463807A (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107518440A (en) * | 2017-10-29 | 2017-12-29 | 宁波科邦华诚技术转移服务有限公司 | A kind of Anti-bacterium, antiskid socks for increasing the stocking leg |
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| CN105246552A (en) * | 2013-03-15 | 2016-01-13 | 克洛斯泰克斯国际公司 | Facemask having one or more nanofiber layers |
| CN205456097U (en) * | 2016-04-01 | 2016-08-17 | 浙江希望之星针织有限公司 | Novel antiskid antibacterial socks |
| CN106268656A (en) * | 2016-09-28 | 2017-01-04 | 中国石油大学(北京) | Porous alumina ceramic loaded Cu MOF adsorbent and preparation method thereof |
| CN206025230U (en) * | 2016-08-17 | 2017-03-22 | 海宁市越立袜业有限公司 | Socks of running |
| CN106937763A (en) * | 2017-05-21 | 2017-07-11 | 盐城巧丽袜业有限公司 | A kind of multi-functional short legging |
| CN107142538A (en) * | 2017-06-27 | 2017-09-08 | 陕西科技大学 | A kind of preparation method of metal organic frame composite antibacterial fibre cellulose fiber filler |
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| CN105246552A (en) * | 2013-03-15 | 2016-01-13 | 克洛斯泰克斯国际公司 | Facemask having one or more nanofiber layers |
| CN205456097U (en) * | 2016-04-01 | 2016-08-17 | 浙江希望之星针织有限公司 | Novel antiskid antibacterial socks |
| CN206025230U (en) * | 2016-08-17 | 2017-03-22 | 海宁市越立袜业有限公司 | Socks of running |
| CN106268656A (en) * | 2016-09-28 | 2017-01-04 | 中国石油大学(北京) | Porous alumina ceramic loaded Cu MOF adsorbent and preparation method thereof |
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| CN107518440A (en) * | 2017-10-29 | 2017-12-29 | 宁波科邦华诚技术转移服务有限公司 | A kind of Anti-bacterium, antiskid socks for increasing the stocking leg |
| CN107518440B (en) * | 2017-10-29 | 2019-01-22 | 上海东北亚新纺织科技有限公司 | A kind of Anti-bacterium, antiskid socks increasing the stocking leg |
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| CN107594645B (en) | 2019-02-15 |
| CN109463807A (en) | 2019-03-15 |
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