CN109259335A - A kind of antimicrobial socks - Google Patents
A kind of antimicrobial socks Download PDFInfo
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- CN109259335A CN109259335A CN201811439295.7A CN201811439295A CN109259335A CN 109259335 A CN109259335 A CN 109259335A CN 201811439295 A CN201811439295 A CN 201811439295A CN 109259335 A CN109259335 A CN 109259335A
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- socks
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- stocking leg
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Classifications
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
- A41B11/008—Hosiery with an anti-slip coating
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H15/00—Massage by means of rollers, balls, e.g. inflatable, chains, or roller chains
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H39/00—Devices for locating or stimulating specific reflex points of the body for physical therapy, e.g. acupuncture
- A61H39/04—Devices for pressing such points, e.g. Shiatsu or Acupressure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H7/00—Devices for suction-kneading massage; Devices for massaging the skin by rubbing or brushing not otherwise provided for
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2300/00—Details of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2300/30—Closures
- A41B2300/322—Closures using slide fasteners
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/32—Therapeutic use
- A41B2400/322—Massage
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B2400/00—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass
- A41B2400/34—Functions or special features of shirts, underwear, baby linen or handkerchiefs not provided for in other groups of this subclass antimicrobial or antibacterial
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H2205/00—Devices for specific parts of the body
- A61H2205/12—Feet
- A61H2205/125—Foot reflex zones
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- Health & Medical Sciences (AREA)
- Rehabilitation Therapy (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Pain & Pain Management (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Textile Engineering (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of antimicrobial socks, it includes the stocking leg and socks ontology, and the socks body bottom portion has several spaced tread plates；Also have on the stocking leg and removably increase set, the set of increasing is fixedly connected with the stocking leg by zipper, and the inner layer of the sock body is all stained with nano anti-biotic material.
Description
The original applying number of the application be 2017110323347, the applying date be on October 29th, 2017, entitled " one
Kind can increase the Anti-bacterium, antiskid socks of the stocking leg ".
Technical field
The present invention relates to a kind of antimicrobial socks.
Background technique
Socks are indispensable daily necessities in people's life, either walk, move and still stroll Shi Douhui use
It arrives, due to the relationship of part socks poor air permeability, foot is generated often in moist, air-locked microenvironment, bacterium easy to breed
Tinea pedis etc. endangers foot, and general socks are substantially and are knitted, and coefficient of friction is small and road holding is not high, antiskid effect
Difference.
Summary of the invention
In view of the above problems, the present invention provides a kind of antimicrobial socks, can independently increase the stocking leg, has antibiotic property
Energy.
To achieve the goals above, present invention provide the technical scheme that one kind can increase the Anti-bacterium, antiskid socks of the stocking leg,
It includes the stocking leg and socks ontology, and the socks body bottom portion has several spaced tread plates；
Also having on the stocking leg and removably increases set, the set of increasing is fixedly connected with the stocking leg by zipper,
The inner layer of the sock body is all stained with nano anti-biotic material.
Massage convex is additionally provided between the adjacent tread plate, the massage convex is pasted in sock body table
Face.
The nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3Nano material, Ethyl formate, polylactic acid, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are primary raw material preparation.
It includes the stocking leg and socks ontology to the present invention, and the socks body bottom portion has several spaced tread plates,
With extraordinary antiskid effect, also have on the stocking leg and removably increase set, the set of increasing passes through machine for zipper with the stocking leg
Structure is fixedly connected, and can easily increase or reduce stocking leg height, and suitable environment needs, and the inner layer of the socks all adheres to
There is nano anti-biotic material, using special nano anti-biotic material, good anti-bacterial effect is additionally provided with massage between adjacent tread plate
Protrusion, the massage convex are pasted on sock body surface, are had effects that massage for sole and are dredged muscle.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention；
Fig. 2 is socks body bottom portion schematic diagram；
In figure: 1, socks ontology, 2, the stocking leg, 3, increase set, 4, zipper, 5, tread plate, 6, massage convex.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Fig. 1 and 2 is please referred to, a kind of Anti-bacterium, antiskid socks, it includes the stocking leg 2 and socks ontology 1, the socks body bottom portion tool
There are several spaced tread plates 5；
Also have on the stocking leg and removably increase set 3, increase set and the stocking leg connect by the way that zipper 4 is fixed
It connects,
The inner layer of the sock body is all stained with nano anti-biotic material.
Massage convex 6 is additionally provided between the adjacent tread plate, the massage convex is pasted in sock body table
Face.
It includes the stocking leg and socks ontology to the present invention, and the socks body bottom portion has several spaced tread plates,
With extraordinary antiskid effect, also have on the stocking leg and removably increase set, the set of increasing passes through machine for zipper with the stocking leg
Structure is fixedly connected, and can easily increase or reduce stocking leg height, and suitable environment needs, and the inner layer of the socks all adheres to
There is nano anti-biotic material, using special nano anti-biotic material, good anti-bacterial effect is additionally provided with massage between adjacent tread plate
Protrusion, the massage convex are pasted on sock body surface, are had effects that massage for sole and are dredged muscle.
The nano anti-biotic material is with polyethylene, Cu-MOF-Al2O3Nano material, Ethyl formate, polylactic acid, carbonic acid
Sodium, lauryl betaine, sodium tripolyphosphate and sodium xylene sulfonate are primary raw material preparation.
The inner layer of socks of the present invention is all stained with nano anti-biotic material, and the material use porous aluminas and Cu-MOF are in situ
It is cross-linked to form the matrices of composite material with network structure, and the copper ion in basis material forming process, in basis material
It may be homogenously dispersed in the network structure of matrix crosslinking, improve the antibacterial stability of material；MOF organic ligand constructs double-layer structure
Platform will be hidden under " clean " surface of a stable against biological contamination on polyethylene, under dry conditions, outermost molecular brush
Surface dehydration is collapsed, and internal antibacterial polymer is made to kill bacterium in a manner of contact sterilization, equal to Escherichia coli and staphylococcus
With preferable antibacterial effect.
More specifically the preparation method is as follows:
The preparation method of anti-biotic material, method includes the following steps:
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
1.5 parts of antioxidant BHTs and 1.3 parts of aid anti-oxidants DLTP are added in the head product that step 1 obtains by step 2, in temperature
Degree is uniformly mixed under the conditions of being 80 DEG C, and mixing speed is 200 revs/min, and mixing time is 30 minutes；
Step 3, the mixture for obtaining step 2 squeeze out in double screw extruder, and extrusion condition is after twin screw extruder barrel
Duan Wendu divides three stage control, is controlled respectively at 180 DEG C, 185 DEG C and 190 DEG C, and barrel front-end temperature divides three stage control, controls respectively
At 195 DEG C, 200 DEG C and 210 DEG C, head temperature is divided to two sections of controls, is controlled respectively in 230 DEG C and 236 DEG C, finally obtains medical receive
Nano antibacterial composite material.
The Cu-MOF-Al2O3Preparation method of nano material is as follows:
Step 1, by 10 parts of alumina powders, 0.3 part of Sodium Polyacrylate, 19.4 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yttrium oxide
Mixing is put into flask, and the uniform stirring at 75 DEG C obtains slurry；
Step 2 pours into slurry in mold, places at -16 DEG C, obtains being shaped to columnar aluminum oxide porous particle preform；
Aluminum oxide porous particle preform is first placed 12h by step 3 at -16 DEG C, then put it into freeze drier -
Dry 6h under the conditions of 60 DEG C finally carries out high temperature sintering with the speed heating of 4 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h, cooling
After obtain porous oxidation aluminum substrate；
Step 4 takes 4.2 parts of trimesic acids, is added in the ethanol solution of 25 parts of mass fractions 95%, waits for as ligand solution
With；
The porous oxidation aluminum substrate prepared is impregnated 5h in enough above-mentioned ligand solutions by step 5；
Step 6 will be put into the nitric acid that enough concentration is 0.5 mol/L after above-mentioned impregnated porous oxidation aluminum substrate filtering
In copper solution, 22h is reacted in 80 DEG C of oil baths and under the conditions of condensing reflux, is filtered, it is dry (dry temperature is 100 DEG C),
The dry time be 12h) after obtain Cu-MOF-Al2O3Nano material.
Embodiment 2
Step 1, by 50 parts of polyethylene, 16 parts of Cu-MOF-Al2O3Nano material, 4 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 3
Step 1, step 1, by 45 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 6 parts of Ethyl formates and 5 parts of polylactic acid
It is added in reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate is molten
It in 30 parts of water, is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the stirring speed being uniformly mixed
Degree is 150 revs/min, and incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes,
It is warming up to 130 DEG C again, is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 4
Step 1, by 38 parts of polyethylene, 19 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 5
Step 1, by 17 parts of polyethylene, 3 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to instead
It answers in kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate is dissolved in 30 parts of water
In, it is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is 150
Rev/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then heat up
To 130 DEG C, it is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 6
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 5 parts of Ethyl formates and 1 part of polylactic acid are added to
In reaction kettle, 4 parts of sodium carbonate, 3 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 7
Step 1, by 34 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 8 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 8
Step 1, by 34 parts of polyethylene, 17 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 5 parts of lauryl betaines, 6 parts of sodium tripolyphosphates and 4 parts of sodium xylene sulfonates are dissolved in 30 parts of water
In, it is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is 150
Rev/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then heat up
To 130 DEG C, it is stirred to react 30 minutes, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 9
Step 1, by 65 parts of polyethylene, 23 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 3 parts of sodium carbonate, 1 part of lauryl betaine, 1 part of sodium tripolyphosphate and 2.1 parts of sodium xylene sulfonates are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 10
Step 1, by 75 parts of polyethylene, 37 parts of Cu-MOF-Al2O3Nano material, 3 parts of Ethyl formates and 5 parts of polylactic acid are added to
In reaction kettle, 1 part of sodium carbonate, 8 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of sodium xylene sulfonate are dissolved in 30 parts
In water, then it is added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein the mixing speed being uniformly mixed is
150 revs/min, incorporation time is 30 minutes, is then warming up to 80 DEG C in the case where vacuum degree is 0.01MPa, stirs 20 minutes, then rise
Temperature is stirred to react 30 minutes to 130 DEG C, obtains head product；
Remaining preparation and embodiment 1 are identical.
Embodiment 11
Step 1, by 65 parts of polyethylene, 13 parts of Cu-MOF-Al2O3Nano material, 8 parts of modified carbon fibers, 3 parts of Ethyl formates and 5
Part polylactic acid is added in reaction kettle, by 1 part of sodium carbonate, 5 parts of lauryl betaines, 1 part of sodium tripolyphosphate and 0.8 part of dimethylbenzene
Sodium sulfonate is dissolved in 30 parts of water, is then added in reaction kettle, is uniformly mixed under the conditions of 50 DEG C, wherein being uniformly mixed
Mixing speed be 150 revs/min, incorporation time be 30 minutes, then vacuum degree be 0.01MPa under be warming up to 80 DEG C, stir
It mixes 20 minutes, then is warming up to 130 DEG C, be stirred to react 30 minutes, obtain head product；
Remaining preparation and embodiment 1 are identical.
The modified carbon fiber the preparation method is as follows:
Carbon fiber is placed in acetone soln and impregnates 12h, is filtered, deionized water is washed 3 times, dry in 120 DEG C of blast driers
4h, with 60% nitric acid reflux oxidation carbon fiber 7h, filtering, deionized water washs PH=6, dries extremely in 120 DEG C of blast driers
Constant weight；The carbon fiber of nitric acid oxidation is placed in polyvinylpyrrolidone, lauryl sodium sulfate and is equivalent to its total weight parts
In the solution of 12 times of deionized water configuration, ultrasonic 50min, 60 DEG C of dryings obtain the modified carbon fiber in surface.
Reference examples 1
It is with 1 difference of embodiment: in the step 2 of antimicrobial nano material, by 2 parts of antioxidant BHTs and 0.3 part of aid anti-oxidants
DLTP is added in the head product that step 1 obtains, remaining step is identical with embodiment 1.
Reference examples 2
It is with 1 difference of embodiment: in the step 2 of antimicrobial nano material, by 0.3 part of antioxidant BHT and 2 parts of aid anti-oxidants
DLTP is added in the head product that step 1 obtains, remaining step is identical with embodiment 1.
Reference examples 3
It is with 1 difference of embodiment: in the step 3 of antimicrobial nano material, three sections of controls of twin screw extruder barrel back segment temperature point
System, controls respectively at 150 DEG C, 155 DEG C and 160 DEG C, remaining step is identical with embodiment 1.
Reference examples 4
It is with 1 difference of embodiment: in the step 3 of antimicrobial nano material, three sections of controls of twin screw extruder barrel back segment temperature point
System, controls respectively at 190 DEG C, 195 DEG C and 200 DEG C, remaining step is identical with embodiment 1.
Reference examples 5
It is with 1 difference of embodiment: Cu-MOF-Al2O3In the step 1 of nano material preparation, 8 parts of alumina powders, 3 parts are gathered
Sodium acrylate, 14 parts of camphenes, 2.9 parts of tert-butyl alcohols and 0.5 part of yttrium oxide mixing are put into flask, and the uniform stirring at 75 DEG C obtains
To slurry, remaining step is identical with embodiment 1.
Reference examples 6
It is with 1 difference of embodiment: Cu-MOF-Al2O3In the step 1 of nano material preparation, by 16 parts of alumina powders, 0.1
Part Sodium Polyacrylate, 6 parts of camphenes, 9 parts of tert-butyl alcohols and 3 parts of yttrium oxides mixing are put into flask, and the uniform stirring at 75 DEG C obtains
Slurry, remaining step are identical with embodiment 1.
Reference examples 7
It is with 1 difference of embodiment: Cu-MOF-Al2O3Nano material preparation step 3 in, be put into freeze drier-
Dry 6h under the conditions of 60 DEG C finally carries out high temperature sintering with the speed heating of 15 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h,
Remaining step is identical with embodiment 1.
Reference examples 8
It is with 1 difference of embodiment: Cu-MOF-Al2O3Nano material preparation step 3 in, be put into freeze drier-
Dry 6h under the conditions of 60 DEG C finally carries out high temperature sintering with the speed heating of 25 DEG C/min, is warming up to 1000 DEG C, keeps the temperature 3h,
Remaining step is identical with embodiment 1.
Reference examples 9
It is with 1 difference of embodiment: Cu-MOF-Al2O3It, will be above-mentioned impregnated porous in the step 3 of nano material preparation
It is put into after alumina substrate filtering in the copper nitrate solution that enough concentration is 0.01mol/L, remaining step and embodiment 1 are complete
It is exactly the same.
Reference examples 10
It is with 1 difference of embodiment: Cu-MOF-Al2O3It, will be above-mentioned impregnated porous in the step 3 of nano material preparation
It is put into after alumina substrate filtering in the copper nitrate solution that enough concentration is 1.0mol/L, remaining step and embodiment 1 are complete
It is exactly the same.
The anti-biotic material that above embodiments and reference examples are prepared is tested for the property, and test the 100th day after its
Antibacterial effect, it is as a result as follows；
Test result
The experimental results showed that the anti-biotic material inside socks body of the present invention has good antibacterial effect, material is in standard test condition
Under, Bacteria suppression rate is lower, illustrates good anti-bacterial effect, conversely, effect is poorer；Embodiment 1 arrive embodiment 10, staphylococcus and
Escherichia coli inhibiting rate changes the proportion of each raw material composition in anti-biotic material, to the anti-microbial property of material more than 85% respectively
There are different degrees of influence, polyethylene and Cu-MOF-Al2O3Nano material quality proportioning is 5:1, other ingredient dosages are fixed
When, antibacterial effect is best；It is worth noting that modified carbon fiber is added in embodiment 11, antibacterial effect is significantly improved, and antibacterial
Stability keeps unusual outstanding, illustrates modified carbon fiber to Cu-MOF-Al2O3Nanometer insulation layer structure anti-microbial property with
And stability has better optimization function；Reference examples 1 to reference examples 2 change antimicrobial nano material against oxidative agent dosage, antibacterial effect
Fruit is decreased obviously, and illustrates that the dosage of antioxidant and pro-oxidant has an important influence on the antibiotic property of material；Reference examples 3 and right
As usual 4, change the height of three stage control temperature, the material bacteria inhibiting rate of synthesis is still very low, and anti-microbial property is bad；Reference examples
5 change Cu-MOF-Al to reference examples 82O3The raw material proportioning and heating rate of nano material, effect is also bad, illustrates the group of raw material
At with temperature-rise period to Cu-MOF-Al2O3Nano material obtains compound have a major impact；Reference examples 9 and example 10 change in dipping process
The concentration of copper nitrate solution, antibacterial effect are substantially reduced, illustrate copper nitrate it is excessive it is very few all can Bacteria suppression rate shadow to material
Sound is very big；Therefore there is inside socks body good antibacterial effect using anti-biotic material.
Claims (4)
1. a kind of antimicrobial socks, it includes the stocking leg and socks ontology, and the socks body bottom portion has several spaced anti-
Draw runner；
Also having on the stocking leg and removably increases set, the set of increasing is fixedly connected with the stocking leg by zipper,
The inner layer of the sock body is all stained with nano anti-biotic material.
2. massage convex is additionally provided between adjacent tread plate described in, the massage convex is pasted on sock body surface.
3. a kind of antimicrobial socks according to claim 1, which is characterized in that the socks ontology is equipped with several air holes.
4. a kind of antimicrobial socks according to claim 1, which is characterized in that matcoveredn is bonded on the inside of the stocking blank,
Protective layer is sponge material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811439295.7A CN109259335A (en) | 2017-10-29 | 2017-10-29 | A kind of antimicrobial socks |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811439295.7A CN109259335A (en) | 2017-10-29 | 2017-10-29 | A kind of antimicrobial socks |
| CN201711032334.7A CN107518440B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks increasing the stocking leg |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711032334.7A Division CN107518440B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks increasing the stocking leg |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109259335A true CN109259335A (en) | 2019-01-25 |
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ID=60685504
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711032334.7A Active CN107518440B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks increasing the stocking leg |
| CN201811439295.7A Pending CN109259335A (en) | 2017-10-29 | 2017-10-29 | A kind of antimicrobial socks |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711032334.7A Active CN107518440B (en) | 2017-10-29 | 2017-10-29 | A kind of Anti-bacterium, antiskid socks increasing the stocking leg |
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| CN108451057A (en) * | 2018-05-25 | 2018-08-28 | 海宁市红枫针织有限责任公司 | A kind of silk stocking with buffering sole pressure |
| CN112516828A (en) * | 2020-11-28 | 2021-03-19 | 浙江千禧龙纤特种纤维股份有限公司 | Ultrahigh molecular polyethylene fiber varicose vein socks and production equipment thereof |
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| CN107518440A (en) | 2017-12-29 |
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