EP2948658B1 - Method and device for gasifying feedstock - Google Patents

Method and device for gasifying feedstock Download PDF

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Publication number
EP2948658B1
EP2948658B1 EP13873081.7A EP13873081A EP2948658B1 EP 2948658 B1 EP2948658 B1 EP 2948658B1 EP 13873081 A EP13873081 A EP 13873081A EP 2948658 B1 EP2948658 B1 EP 2948658B1
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EP
European Patent Office
Prior art keywords
gasifier
grate
zone
feedstock
oxidation
Prior art date
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EP13873081.7A
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German (de)
English (en)
French (fr)
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EP2948658A4 (en
EP2948658A1 (en
Inventor
Deon John Potgieter
Billy Freeman Hopper
Jeffrey Scott BROWN
Mark Oliver LOFTIN
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Aries Gasification LLC
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Aries Gasification LLC
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Priority claimed from US13/752,021 external-priority patent/US8546636B1/en
Priority claimed from US13/751,983 external-priority patent/US8721748B1/en
Application filed by Aries Gasification LLC filed Critical Aries Gasification LLC
Publication of EP2948658A1 publication Critical patent/EP2948658A1/en
Publication of EP2948658A4 publication Critical patent/EP2948658A4/en
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/24—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
    • F23G5/26—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber having rotating bottom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/22—Arrangements or dispositions of valves or flues
    • C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
    • C10J3/26—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/34—Grates; Mechanical ash-removing devices
    • C10J3/40—Movable grates
    • C10J3/42—Rotary grates
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/002—Incineration of waste; Incinerator constructions; Details, accessories or control therefor characterised by their grates
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/24—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
    • F23G5/245—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber with perforated bottom or grate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00—Special features of, or arrangements for incinerators
    • F23G2900/50002—Burning with downwards directed draft through the waste mass

Definitions

  • the invention relates to thermochemical technology and equipment, in particular, to processes and apparatuses for gasifying solid biomass, household and industrial waste, fossil fuels as well as other carbon-containing feedstock using downdraft gasification.
  • Gasification is a continuous thermal decomposition process in which solid organic or carbonaceous materials (feedstock) break down into a combustible gas mixture.
  • the combustible gas components formed are primarily carbon monoxide (CO), hydrogen (H 2 ), and methane (CH 4 ).
  • Other non-combustible gases such as nitrogen (N 2 ), steam (H 2 O), and carbon dioxide (CO 2 ) are also present in various quantities.
  • the process of gasification involves pyrolysis followed by partial oxidation, which is controlled by injecting air or other oxygen containing gases into the partially pyrolysed feedstock. More specifically, biomass gasification is a sequence of reactions including water evaporation, lignin decomposition, cellulosic deflagration and carbon reduction.
  • An external heat source begins the reaction, but partial oxidation provides heat to maintain the thermal decomposition of the feedstock. If concentrated oxygen is used, the resulting gas mixture is called syngas. If air (which includes nitrogen) is used as the oxidant, the resulting gas mixture is called producer gas.
  • the term "Producer Gas” as used herein shall include both syngas and producer gas. Both gas mixtures are considered a "fuel gas” and can be used as a replacement for natural gas in many processes. They can also be used as a precursor to generate various industrial chemicals and motor fuels. When biomass is used as the feedstock, gasification and combustion of the Producer Gas is considered to be a source of renewable energy.
  • gasification offers a more efficient, cost effective and environmentally friendly alternative for extracting potential energy from solid feedstock as compared to combustion.
  • the feedstock's potential energy can be converted to Producer Gas, which is cleaner burning, compressible and more portable.
  • Producer Gas may be burned directly in some engines and burners, purified to produce methanol and hydrogen, or converted via the Fischer-Tropsch and other methods and processes into synthetic liquid fuel.
  • fluidized bed gasification There are three common gasification processes: fluidized bed gasification, updraft gasification and downdraft gasification.
  • the present invention is an improved downdraft gasifier. Therefore only a brief description of fluidized bed gasification and updraft gasification are provided and followed by a fuller discussion of current downdraft gasification.
  • the counter-current fixed bed (“updraft”) gasifier consists of a fixed bed of feedstock on top of a large grate through which steam, oxygen and/or air flow upward. Updraft gasifiers typically require feedstock that is hardy and not prone to caking or clumping so that it will form a permeable bed.
  • the updraft gasifier consists of a feedstock bed through which the oxidant (steam, oxygen and/or air) flows in from the bottom and exits through the top as gas. Updraft gasifiers are thermally efficient because the ascending gases pyrolyze and dry the incoming biomass, transferring heat so that the exiting Producer Gas is cooled when it exits the gasifier.
  • the updraft gasifier has been the standard of coal gasification for 150 years and it is also popular in biomass cooking stoves.
  • oxidant is blown through a bed of solid particles at a sufficient velocity to keep the solid particles in a state of suspension.
  • the feedstock is introduced to the gasifier, very quickly mixed with the bed material and almost instantaneously heated to the bed temperature either externally or using a heat transfer medium.
  • Most of these fluidized-bed gasifiers are equipped with an internal cyclone in order to minimize char (carried over into the Producer Gas stream) and remove fluidizing media from the Producer Gas.
  • the major advantages include feedstock flexibility and the ability to easily control the reaction temperature, which allows for gasification of fine grained materials (sawdust, etc.) without the need of pre-processing. Fluidized-bed gasifiers also scale very well to large sizes.
  • downdraft gasification In downdraft gasification, all feedstock, air and gases flow in the same direction - from top to bottom. Although updraft gasification is typically favored for processing of biomass feedstock and fluid bed gasification is typically used in gasification of coal, downdraft gasification process has a number of advantages.
  • One advantage of downdraft gasification is low levels of tar in the resulting Producer Gas because the tars generated during pyrolysis must pass through the Oxidation Zone (defined below) and the char bed in the Reduction Zone (defined below) before exiting the gasifier.
  • the high temperature of the Oxidation Zone and the top of the char bed breaks down the tars (i.e., thermal cracking).
  • the result is a Producer Gas that may be cooled and more easily cleaned for use in reciprocating engines, gas-fired turbines and catalytic reforming processes.
  • a Pyrolysis Zone there are three zones: a Pyrolysis Zone, an Oxidation Zone and a Reduction Zone (each defined below).
  • the residence time of feedstock could be controlled in the Oxidation Zone (relative to the flow of feedstock through the rest of the gasifier) to allow the maximum amount of feedstock to undergo gasification before passing out of the Oxidation Zone into the Reduction Zone and (2) the Reduction Zone would be designed to cause the hot gas produced in the Oxidation Zone to mix with the char in the Reduction Zone as quickly and as thoroughly as possible to promote thorough gasification.
  • the restriction area in current gasifiers greatly impedes the overall volume of feedstock that can be moved through such a gasifier and disrupts the overall flow and output of Producer Gas.
  • throat and hearth The restriction areas found in prior art gasifiers are commonly referred to as the throat and hearth, which are an intentional design in current downdraft gasifiers as dictated by the prevailing theory, Superficial Velocity Theory.
  • the objective of the invention is solved by a gasifier according to claim 1 and a method according to claim 8.
  • the invention disclosed is a gasifier comprising a plurality of conjoined and vertically positioned tubes.
  • the tubes have an interior wall and exterior wall and a proximal and distal end wherein the proximal end provides an inlet and the distal end provides an outlet.
  • the gasifier has three separate reaction zones: (1) a Pyrolysis Zone; (2) an Oxidation Zone beneath the Pyrolysis Zone; and (3) a Reduction Zone beneath the Oxidation Zone.
  • a rotating and vertically adjustable grate is located below, but not attached to, the Reduction Zone. Unlike other gasifiers, this is a partially open core gasifier without an airtight seal on the distal end of the gasifier.
  • a Drying Zone is placed above the Pyrolysis Zone so the heat of the gasifier can be used to dry feedstock before it enters the gasifier.
  • feedstock is fed into the Pyrolysis Zone (either directly or by way of the Drying Zone).
  • Gravity causes the feedstock to move downward through the three reaction zones, with the Producer Gas and carbon ash and residue by-product formed after a biomass feedstock has been gasified (“Biochar") exiting through the grate at the bottom of the gasifier into collection chutes.
  • Biochar is separated from the Producer Gas by gravity.
  • the Producer Gas also exits through the grate and is collected by collection vents on the sides of the collection chutes.
  • the pressure within the collection chutes is a function of pipelines connected to the gas collection vents and machinery attached to those pipelines downstream of the gasifier (i.e., engines, collection chambers, etc.)
  • the pressure of the gasifier is not dependent on the pressure of the collection chutes.
  • Bed Oxidant Stream or " Bed Air” means the Oxidant Stream entering the gasifier through inlets (i.e., non Plano Air Inlets) positioned at the top of the Pyrolysis Zone (or the optional Drying Zone).
  • inlets i.e., non Plano Air Inlets
  • Biochar means the carbon ash and residue by-product formed after a biomass feedstock has been gasified.
  • Bypass means the “gap” between the top of the grate located underneath the gasifier and the opening at the bottom of the Reduction Zone, which may also be referred to as the grate pitch.
  • Control System means an operating system, which includes multiple control mechanisms and coordinated software for a user/operator to adjust variables of a gasifier such as grate rotation and height, input of feedstock and Oxidant Streams.
  • Drying Zone with regard to the gasifier, means an area where feedstock is dried prior to entering a Pyrolysis Zone, said Drying Zone being a container of sorts or extension of the gasifier above the Pyrolysis Zone, but alternatively it may be an area and/or component/unit separate from the gasifier.
  • the "Drying Zone” means the phase where feedstock is dried.
  • Gasifier Flow Lane means the path, generally toward the middle of a gasifier, where feedstock moves the fastest, is gasified, and the resulting Producer Gas and Biochar continue to move into a Reduction Zone and out of gasifier through a grate.
  • Oxidant Stream means air or other oxygen containing gases.
  • Oxidation Band with regard to a gasifier, means the location where the primary gasification reaction occurs.
  • the Oxidation Band is where the Oxidant Streams converge and, together with the heat from the gasifier and the presence of feedstock, the gasifier quickly oxidizes the feedstock in a narrow band of white hot gas that extends across the diameter of a gasifier.
  • the "Oxidation Band” means the hottest phase of the gasification reaction.
  • Oxidation Zone with regard to the gasifier, means a zone of a gasifier leading up to and away from an Oxidation Band.
  • the overall shape of the Oxidation Zone is of a hollow tube, the tube having an inlet and an outlet of approximately the same size but is dilated in the middle.
  • the "Oxidation Zone” means a phase where feedstock changes to a gas.
  • Plano Air Inlets means pressurized air inlets used to inject pressurized Oxidant Streams into a gasifier. In existing gasifiers, tuyeres are used to allow air to passively enter a gasifier, but Plano Air Inlets are instead pressurized to inject Oxidant Streams into the gasifier.
  • Plano Oxidant Stream or " Plano Air” means an Oxidant Stream entering a gasifier through Plano Air Inlets.
  • Pressure Lock means a pressure lock assembly with a valve at its top and another valve at its bottom, the pressure lock being located at the top of a gasifier.
  • Pressure Wave means the differential pressure between the center of the Oxidation Band and the Oxidation Zone wall, which pushes feedstock toward the wall of a gasifier forming an induced gradient of feedstock above the Oxidation Band ("Induced Feedstock Gradient") and an entrained gradient of Biochar below the Oxidation band ("Entrained Biochar Gradient”).
  • Producer Gas means the combustible gas mixture created by gasification of feedstock and includes both syngas and producer gas.
  • Purge Oxidant Stream or "Purge Air” means the Oxidant Stream mixed with feedstock prior to the feedstock entering the Pyrolysis Zone (or the optional Drying Zone).
  • Pyrolysis Zone with regard to a gasifier, means the zone of the gasifier where the feedstock begins to fluidize and decompose before passing into the Oxidation Zone.
  • the overall shape of the Pyrolysis Zone may range from a hollow tube to an inverted hollow cone.
  • the "Pyrolysis Zone” means the phase where feedstock begins to fluidize and decompose.
  • Reduction Zone with regard to a gasifier, means the zone of the gasifier where Producer Gas mixes with Biochar, cools and produces additional Producer Gas.
  • the overall shape of the Reduction Zone is that of a hollow tube, being wider than the outlet of the Oxidation Zone.
  • the "Reduction Zone” means the phase where Producer Gas mixes with Biochar.
  • the present invention relates to a method and apparatus for gasifying carbon-containing biomass feedstock.
  • the gasifier comprises a plurality of conjoined and vertically positioned tubes.
  • the tubes have an interior wall and exterior wall and a proximal and distal end wherein the proximal end provides an inlet and the distal end provides an outlet.
  • the gasifier has three separate sequential reaction zones: (1) a Pyrolysis Zone; (2) an Oxidation Zone beneath the Pyrolysis Zone; and (3) a Reduction Zone beneath the Oxidation Zone.
  • a rotating and vertically adjustable grate is located below, but not attached to, the Reduction Zone. Unlike other gasifiers, this is a partially open core gasifier; there is no airtight bottom wall sealing the Reduction Zone or the bottom of the gasifier itself.
  • FIGS 1 and 2 show a cutaway front view of a gasifier.
  • This downdraft gasifier is a sequential, co-current flow, gravity-assisted, thermo-chemical phase change gasifier having at least three zones: a Pyrolysis Zone 20, an Oxidation Zone 30 and a Reduction Zone 40.
  • the gasifier partially oxidizes a portion of the feedstock, which releases enough heat activation energy to start a thermo-chemical solid-to-gas phase change reaction of the remaining feedstock into Producer Gas.
  • the process of gasification is a sequence of reactions including water evaporation, lignin decomposition, cellulosic deflagration and carbon reduction and is controlled by injecting Oxidant Streams into the partially pyrolysed feedstock.
  • the interior of the entire gasifier is lined with silica carbide, silica oxide, aluminum oxide, refractory alloys, other ceramics or another material having similar properties that is stable at high temperatures.
  • Non-volatile and ungasified materials are separated from the Producer Gas by gravity as these materials fall to the bottom of the gasifier.
  • This high efficiency gasifier converts the chemical potential energy of feedstock into Producer Gas, with the average amount of Biochar generated being about 1%-10% by weight of the original feedstock.
  • FIGS 3 and 4 show the exterior front and side views of a gasifier.
  • Feedstock moves downward in the gasifier as gasification takes place.
  • a steady operating state i.e., the state wherein each zone of the gasifier has reached a steady and sustained temperature
  • a vertical temperature gradient forms inside the gasifier and the feedstock stratifies into a sequence of layers or zones roughly corresponding to the Pyrolysis Zone 20, the Oxidation Zone 30 and the Reduction Zone 40 based on the steps in the gasification process.
  • a steady operating state i.e., the state wherein each zone of the gasifier has reached a steady and sustained temperature
  • the feedstock stratifies into a sequence of layers or zones roughly corresponding to the Pyrolysis Zone 20, the Oxidation Zone 30 and the Reduction Zone 40 based on the steps in the gasification process.
  • feedstock pyrolysis may begin in the Drying Zone 10 and oxidation may begin in the Pyrolysis Zone 20 ).
  • Feedstock is maintained at a level above the Pyrolysis Zone 20 and pulled down through the Pyrolysis Zone 20 by gravity so that descending feedstock replaces feedstock that has been gasified. Gases and feedstock flow in a downward direction inside the gasifier. Solid materials flow through the gasifier by gravity. Gases move downward through the gasifier by pressure differential.
  • Solids e.g., feedstock and Biochar
  • a vertically adjustable, rotating grate 50 located just below the Reduction Zone 40 of the gasifier, as shown in Figures 1, 2 , 3 and 4 .
  • the residence time of solids within the gasifier is controlled by the rotational speed of the grate 50, the vertical position of the grate 50, and the rate of gasification (i.e., phase change) within the gasifier.
  • the Biochar accumulates on top of the grate 50 and acts as a pseudo-seal for the bottom of the gasifier, which then allows the gasifier to pressurize, and maintain pressurization even as Biochar continuously leaves the gasifier.
  • Biochar falls from the bottom of the gasifier through the rotating grate 50 or out the Bypass 49. Once the Biochar falls from the grate 50 or the Bypass 49, it falls into one or more collection chutes 60 below the grate 50 and then into a residue box 90, where it is removed from the gasifier by an auger 91.
  • the zones of the gasifier include: the Drying Zone 10, the Pyrolysis Zone 20, the Oxidation Zone 30, the Reduction Zone 40 with a grate 50 located underneath the gasifier. Below the gasifier are gas collection vents 70, Biochar collection chutes 60 and a Biochar residue box 90.
  • Figures 5 and 6 show a cutaway front and side view of a gasifier with dimensions.
  • the Drying Zone 10 moisture within the feedstock is evaporated as it is exposed to radiant heat emitting from the Oxidation Zone 30.
  • the water vapor flows downward through the Pyrolysis Zone 20 toward the Oxidation Zone 30 along with the Bed Oxidant Stream and the Purge Oxidant Stream being fed into the gasifier.
  • Temperatures in the Drying Zone 10 can vary extensively depending on how the gasifier is operated. By way of example, for woodchips with 25% moisture content, the normal range of temperature in the Drying Zone 10 is about 100 to 300° F (approximately 40°C to 150°C).
  • the depth of the Drying Zone 10 in one embodiment may be between zero and six feet tall (about 180cm).
  • This depth may increase with the moisture content of the feedstock, the size of the gasifier and the embodiment of the gasifier used. Radiant heat from the Oxidation Zone 30 drives the evaporative processes. However, preheating the Bed Oxidant Stream and the Purge Oxidant Stream can accelerate the drying process.
  • Drying the feedstock inside the gasifier is an endothermic process, and so energy (i.e., heat) is required to dry and release water from the feedstock as steam, which steam assists the reactions occurring below.
  • energy i.e., heat
  • the wetter the feedstock the more energy the Drying Zone 10 requires.
  • a Pressure Lock may be used to bring feedstock into the gasifier while maintaining the gasifier's pressure.
  • a top valve of the Pressure Lock opens to admit feedstock into the Pressure Lock and then closes.
  • the interior of the Pressure Lock pressurizes to match the air pressure of the Pyrolysis Zone 20 (or optional Drying Zone 10 ), which may be controlled by a user through the Control Systems, before a bottom valve opens allowing the feedstock to leave the Pressure Lock and enter the gasifier at the adjusted air pressure.
  • the Pressure Lock may be fabricated from materials such as Schedule 40 seamless carbon steel pipe, 150 pound class steel flanges and standard 150 pound class slide gate valves, such as knife-gate valves.
  • This Pressure Lock assembly may be integrated into the equipment design and use a pair of standard industrial knife-gate valves with a pipe between them.
  • the pipe in one embodiment may be 18" schedule 40 pipe orientated vertically.
  • the length of the pipe may be adjusted depending on the feedstock delivery method and desired volume.
  • An example of a Pressure Lock is 72" (about 180cm) in length, which will provide 100-120 pounds (about 45 - 54 kg) of feedstock per feedstock dump into the Drying Zone 10 (if applicable) or the Pyrolysis Zone 20.
  • attached to the pipe are threaded couplings for receiving (1) a level switch, such as a rotary level switch, limit switch, photon switch, or a laser switch, and (2) a pressure transmitter, and (3) a pressurized air supply line.
  • the end user may automate the gasifier feedstock filling process with a timer or by using a microwave sensor or another suitable fill level indicator, to detect the presence of feedstock at the fill level in the gasifier and also in the Pressure Lock ("Fill Level Indicators").
  • the Drying Zone 10 of the gasifier may have one or more Fill Level Indicators 12 capable of functioning in high temperature environments. Once the Fill Level Indicator 12 detects that the feedstock level is low, the automatic feed mechanism begins.
  • One gasifier design with multiple Fill Level Indicators 12 allows more options in choosing the height of the feedstock bed when using an automatic filling system.
  • the top valve of the Pressure Lock opens and a bucket loading mechanism dumps feedstock into the Pressure Lock until a Fill Level Indicator in the Pressure Lock detects that it is full.
  • the top valve of the Pressure Lock closes and the Pressure Lock pressurizes to match the pressure of the Drying Zone 10 (if applicable) or the Pyrolysis Zone 20.
  • the bottom valve of the Pressure Lock opens and deposits the feedstock onto a pressurized auger that is connected to the Drying Zone 10 (if applicable) or the Pyrolysis Zone 20.
  • the auger deposits the feedstock into the top of the gasifier.
  • the gasifier's control systems determine when to initiate each feedstock fill cycle based on the signals, such as temperature or pressure changes, received from various sensors and indicators on the gasifier.
  • the Pyrolysis Zone 20 is directly below the Drying Zone 10 (if a Drying Zone 10 is included) within the gasifier.
  • the Pyrolysis Zone 20 may be increased or decreased in height based on the properties of the predominant type of anticipated feedstock. A taller Pyrolysis Zone 20 will accommodate wetter and/or more complex materials that require more drying and longer pyrolysis times.
  • the Pyrolysis Zone 20 vapors, oils, and constituent gases are distilled and moved downward by the effects of gravity, pressure differences and steam created in the Drying Zone 10 and the Pyrolysis Zone 20.
  • the Pyrolysis Zone 20 is endothermic at the top and relies on heat released from below.
  • the feedstock begins to spontaneously break down as it becomes chemically unstable at the elevated temperatures. Therefore, the decomposition of feedstock occurring in the lower section of the Pyrolysis Zone 20 is exothermic and releases heat.
  • the Pyrolysis Zone 20 is four to six feet deep.
  • Oxygen is present in the Pyrolysis Zone 20 from the Oxidant Streams being fed into the gasifier, oxidation may occur as feedstock approaches the bottom of the Pyrolysis Zone 20.
  • the Oxidation Zone 30 is the zone in the gasifier leading up to and away from the Oxidation Band 350 or the general step of the method including formation of the Oxidation Band 350.
  • the Oxidation Zone 30 is where the Oxidation Band 350 forms and represents the hottest step in the gasification process and is where the cellulosic fraction of the feedstock converts from a solid to a gas.
  • the First Gradient (The Induced Feedstock Gradient)
  • this Induced Feedstock Gradient is an increasing and differential density of feedstock becoming denser toward the perimeter of the gasifier wall and above the Oxidation Band 350 (the "Densest Portion") formed by at least four factors acting in concert: (1) the Pressure Wave from the Oxidation Band 350 pressing feedstock against the interior wall of the gasifier; (2) the geometry of the Pyrolysis Zone 20 and the Oxidation Zone 30 (i.e., angles of the walls); (3) the total volume of the Oxidant Stream flowing into the Pyrolysis Zone 20 and the Oxidation Zone 30; and (4) the relative volume of the Oxidant Stream flowing into each of the Pyrolysis Zone 20 and the Oxidation Zone 30.
  • the Densest Portion of the Induced Feedstock Gradient is illustrated at 200.
  • Feedstock travels through the gasifier at different velocities. Some of the feedstock is steadily progressing down the gasifier in the Gasifier Flow Lane 203, while other feedstock may pause or slow at various points in the gasifier. Feedstock moves more slowly and/or is suspended within the Induced Feedstock Gradient 200.
  • the Densest Portion of the Induced Feedstock Gradient 200 is denser and slower moving feedstock than the feedstock in the Gasifier Flow Lane.
  • the Densest Portion of the Induced Feedstock Gradient 200 ends at the lower Plano Air Inlets 32 where the Oxidation Zone 30 dilates to a wider diameter.
  • this dilation is designed to be a Kline-Fogelman step in order to direct and control the rate of flow of gases and solids moving down the gasifier.
  • the Induced Feedstock Gradient may also change allowing for movement of the Oxidation Band 350 and the Gasifier Flow Lane 203 inside the gasifier. This is not possible in other gasifiers where the Gasifier Flow Lane 203 would be formed against the immovable outer wall of the gasifier.
  • the feedstock in the Gasifier Flow Lane 203 travels down through the gasifier into the Oxidation Band 350.
  • the Oxidation Band 350 is the point where significant heat is liberated by the deflagration of the cellulose matter in the feedstock. Once initiated during start-up, the Oxidation Band 350 is sustained by the addition of Oxidant Streams from the Plano Air Inlets 31, 32 and feedstock descending from above.
  • the Oxidation Band 350 partially oxidizes the feedstock into Biochar and constituent gases of Producer Gas. Tar vapors generated in the Pyrolysis Zone 20 are further decomposed in the presence of steam under the high temperatures of the Oxidation Band 350 into additional Producer Gas.
  • the overall shape of the Oxidation Zone 30 is of a hollow tube, the tube having an inlet 301 and an outlet 303 of approximately the same size but is dilated in the middle 302. This is the opposite of traditional downdraft gasifiers where the Oxidation Zone narrows into a restriction point according to Superficial Velocity Theory.
  • the inlet 301 and the outlet 303 of the Oxidation Zone 30 are half the diameter of the dilated section 302 of the Oxidation Zone 30.
  • a higher ring 31 being approximately 11 inches (about 30cm) above the lower ring 32 and a lower ring of Piano Air Inlets 32 being at the widest part of the dilated section 302 of the Oxidation Zone 30.
  • the extremely high temperatures generated by this Oxidation Band 350 produce the heat that drives the chemical and physical reactions in the Pyrolysis Zone 20 and Drying Zone 10 above (if applicable).
  • the Oxidation Band 350 naturally tends to move upward in the gasifier toward the unconsumed feedstock and the Oxidant Stream supply above.
  • Below the Oxidation Band 350 is a mixture of Biochar, which is relatively stable at high temperatures.
  • the gasifier is designed to allow the Oxidation Band 350 to move up and down within the gasifier.
  • the Oxidation Band 350 may be held in place in the gasifier by using a grate 50 (located below the Reduction Zone 40 ) to remove the Biochar beneath the Oxidation Band 350, counteracting the tendency of the Oxidation Band 350 to move upward. Whenever the grate 50 stops rotating, the Oxidation Band 350 starts rising.
  • a higher ring of Piano Air Inlets 31 positioned above the lower set of Piano Air Inlets 32 allows additional Oxidant Streams to be injected to the feedstock just before it enters the Oxidation Band 350.
  • the Oxidation Band 350 can be held at any desired location within the gasifier. In one embodiment, the Oxidation Band 350 is held just below the lower ring of Piano Air Inlets 32.
  • the partial oxidation of feedstock is also complex but can be simplified into the following expressions: Feedstock-Bound C + 1 ⁇ 2 O 2 ⁇ CO + Heat Feedstock-Bound C + O2 ⁇ CO2 + Heat Feedstock-Bound H + O2 ⁇ H2O + Heat Feedstock-Bound H ⁇ H 2 CO + 3H 2 ⁇ CH 4 + H 2 O + Heat CO 2 + 4H 2 ⁇ CH 4 + 2H 2 O + Heat Solid C Residue + 2H 2 ⁇ CH 4 + Heat CO + H 2 O ⁇ CO 2 + H 2 + Heat
  • the reactions in the Oxidation Zone 30 are exothermic and release the heat that operates the entire gasifier.
  • the beginning of a second gradient of Biochar forms (1) vertically, beginning just below the lower ring of Plano Air Inlets 32 in the Oxidation Zone 30 and extending down along the wall of the Oxidation Zone 30 into the Reduction Zone 40 (2) horizontally, from the center of the gasifier to the wall of the gasifier (the "Entrained Biochar Gradient").
  • the diameter of the Oxidation Zone 30 narrows to approximately the same size as the inlet 301 to the Oxidation Zone 30.
  • the Pressure Wave from the Oxidation Band pushes the Biochar against the narrowing wall of the Oxidation Zone.
  • the Densest Portion of the Entrained Biochar Gradient is illustrated at 300.
  • the Pressure Wave slows the movement of the Densest Portion of the Biochar in the Entrained Biochar Gradient 300 relative to Biochar in the Gasifier Flow Lane 203.
  • the Gasifier Flow Lane 203 remains intact even though the feedstock has changed phase, and Producer Gas and Biochar are now moving downward instead of feedstock.
  • the Densest Portion of the Entrained Biochar Gradient 300 runs down along the wall of the Oxidation Zone 30 into the Reduction Zone 40.
  • the entrance to the Reduction Zone 40 forms another step.
  • the angled of the wall of the Oxidation Zone 30 and the inlet to the Reduction Zone 40 form a Kline-Fogleman step.
  • an eddy forms in the Reduction Zone 40. This eddy encourages mixing between the Producer Gas and Biochar in the Reduction Zone 40.
  • this downdraft gasifier does not have a restriction zone in the Oxidation Zone 30, but instead the Oxidation Zone 30 increases in size. Nearly all current downdraft gasifiers apply the Superficial Velocity Theory and are, therefore, constructed with a restriction in the Oxidation Zone 30 in order to achieve a useable quality Producer Gas. Additionally, most current downdraft gasifiers use a vacuum to pull Producer Gas through the gasifier.
  • the two gradients that are formed in this gasifier, the Induced Feedstock Gradient above the Oxidation Band 350 and the Entrained Biochar Gradient below the Oxidation Band 350 work together to simulate a throat and hearth inside the gasifier.
  • the advantages of this approach are that the Oxidation Band 350 can move up or down in the gasifier without damaging or possibly destroying the gasifier itself, and the inside of the gasifier can adapt to different types and mixtures of feedstock.
  • Other gasifiers with a fixed throat and hearth must be calibrated to a small range of feedstock, cannot be easily adjusted to accommodate other feedstock types, and cannot be adjusted during operation to accommodate changes.
  • the Reduction Zone 40 of the gasifier is equal to or greater in diameter than the outlet 303 of the Oxidation Zone 30.
  • the two primary functions of the Reduction Zone 40 are to gasify residual carbon from the Biochar and to cool the Producer Gas. Both functions occur by the same mechanism, namely the endothermic reactions of Producer Gas constituents and the solid carbon contained within the Biochar.
  • the Reduction Zone 40 of the gasifier maintains about a 2 to 6 foot bed of Biochar above the grate 50.
  • Producer Gas exits typical downdraft gasifiers at temperatures around 1,500° F (approximately 820°C) or higher. Producer Gas exits this gasifier at temperatures less than 1,500° F (approximately 820°C). In one embodiment, it exits at temperatures less than 1,000° F(approximately 540°C). Also, the thick bed of Biochar allows about 90 to 99% of the fuel carbon to exit this gasifier as Producer Gas, depending on the feedstock.
  • the grate 50 of the gasifier may be made of stainless steel or another suitable material that is both durable, heat resistant and non-reactive such as silica carbide, silica oxide, aluminum oxide, refractory alloys or other ceramics, the grate having a top and a bottom face.
  • the bottom face of the grate and shaft may be mounted on an elevating platform 80 that moves up and down and is controlled by variable control systems.
  • the top face of the grate 50 is positioned below the lower edge of the Reduction Zone 40.
  • the Bypass is a gap of .25 to 2 inches (about 0.64 to 5cm) between the Reduction Zone 40 and the top face of the grate 50.
  • Figure 11 shows the gasifier grate 50 which provides support for all of the solids in the gasifier.
  • the grate 50 has a frame 505 and two faces, a top face and a bottom face.
  • Figures 11 and 12 show the top face of the grate 50 has a spiral groove 501.
  • the spiral groove 501 is oriented in the gasifier so that it faces the Reduction Zone 40.
  • the spiral groove 501 has a starting point at the center of the grate and a tail continuing outward to the edge of the grate 50. Therefore in one embodiment the spiral grove spans the entire top face of the grate.
  • the purpose of the spiral groove 501 is that it naturally moves Biochar outward from the center of the grate 50 to the edge of the grate 50 as the grate 50 rotates opposite the direction of the spiral groove 501.
  • the Biochar follows the tail of the spiral groove 501 as the grate 50 turns in the opposite direction until the Biochar is forced from the Reduction Zone 40 through the Bypass.
  • silica carbide, silica oxide, aluminum oxide, a refractory alloy, other ceramics or some other heat resistant, high density, course material lines the walls of the Reduction Zone 40.
  • This heat resistant, high density, course material acts as file to grind away at any Biochar that is pressed against and dragged along the outer wall of the Reduction Zone 40 by the rotating grate 50.
  • This combination of having a spiral groove 501 in the grate forcing Biochar toward and along the course wall of the Reduction Zone 40 assists in grinding large chunks of char into small enough pieces that they escape the Bypass.
  • a person having ordinary skill in the art will recognize that different types of spirals may be used (e.g., Archimedean, logarithmic, etc.).
  • the spiral groove 501 in the grate is a "v" shaped Archimedean groove 502, where the outer edge of one groove in the spiral meets the inner edge of the adjacent groove to form a raised edge.
  • a purpose of the "v" shaped groove is to avoid having any 90° angles, which would otherwise create hot spots or thermally unstable sections of the grate 50.
  • the grate 50 can be raised and lowered to create a higher or lower Bypass, allowing larger items that have inadvertently entered the gasifier and/or materials that have not gasified to be removed without shutting the gasifier down (e.g., brick, rocks, etc.).
  • these foreign bodies will be forced to the wall of the Reduction Zone 40, and then the grate 50 can be lowered to allow them to be discharged through the Bypass.
  • This design allows for the gasifier to remain in service and still remove large, ungasified objects from the Reduction Zone 40.
  • the ability to raise and lower the grate 50 can also be used if maintenance is ever required inside the gasifier.
  • the Bypass 49 functions to control Producer Gas flow out of the Reduction Zone 40, the Bypass 49 acting similar to a valve. For example, a short Bypass increases resistance to Producer Gas flow through the grate 50 and causes pressure to build in the gasifier.
  • Figures 13 and 14 show the assembled grate.
  • Figures 15 and 16 show the grate "pie slice" segments 502.
  • Figures 13 and 14 show a perspective and front view of an assembled grate having elliptical holes 503.
  • the elliptical holes 503, such as kidney-shaped or oval-shaped holes are distributed symmetrically across the grate 50 (except there are no holes in the center of the grate above the mechanical shaft that lifts and rotates the grate).
  • the purpose of the holes 503 is both to allow Biochar and Producer Gas to pass through the grate into the Biochar collection chute 60 below.
  • the "pie slice" segments 502, 504 sit on a frame 505 of the grate 50. When each of the segments 504 is inserted into the frame 505, the grate is formed. This embodiment allows for replacement of a segment 504 rather than the entire grate 50 in the event part of the grate 50 becomes damaged, and also allows the gasifier to be fitted with customized segments 504 designed for particular types of feedstock.
  • Figure 15 shows a perspective view of removable segment of a grate.
  • the grate 50 also has a spiral groove 501 cut as a "v" 502 and elliptical, kidney or oval-shaped holes 503 cut through the spiral groove 501.
  • Figure 16 shows a top view of a removable segment of a grate.
  • the shaft supporting and rotating the grate 50 can be formed of one or more pieces, depending on the size of the grate 50.
  • the rotational speed of the grate 50 may be calibrated by a Control System, but typically ranges from 0.0001 RPM to 1 RPM, depending on the non-volatile components of the feedstock and the rate of production of Producer Gas. Since the Oxidation Band 350 effectively rides on top of the bed of Biochar in the Reduction Zone 40, if the bed of Biochar in Reduction Zone 40 gets too thick, the Oxidation Band 350 will rise into the Pyrolysis Zone 20.
  • the gasifier's Control System discussed below can be programmed to speed up the rotation of the grate 50 and remove Biochar at a higher rate, which reduces the height of the Biochar bed and lowers the Oxidation Band 350 back to appropriate locations. Conversely, the gasifier's Control System can slow the grate 50 if the bed of Biochar becomes too shallow and, consequently, the Oxidation Band 350 moves too close to the grate.
  • Biochar collection chute 60 Shown in Figures 1, 2 , 5 and 6 , below the gasifier is a Biochar collection chute 60, which may be made of steel, stainless steel or another strong, thermally stable, nonporous material. As Biochar exits the bottom or sides of the grate 50, it falls down the Biochar collection chute 60 below the gasifier.
  • the Biochar collection chute 60 is arranged at an angle from the direction of the flow of Biochar in the Gasifier Flow Lane 203. In one embodiment, the angle is less than 90°, measured from the direction of Biochar flow in the Gasifier Flow Lane 203. In one embodiment, the angle is 45° to 80°, measured from the direction of Biochar flow in the Gasifier Flow Lane 203. In one embodiment, at least two Biochar collection chutes 60 are symmetrically arranged with respect to center axis of the gasifier.
  • two or more Producer Gas collection vents 70 are positioned within the Biochar collection chute 60 symmetrically around the axis of the grate 50.
  • the opening to the Producer Gas collection vents 70 faces downward so the Biochar does not fall directly into them as the Biochar falls from the grate 50.
  • the Biochar separates from the Producer Gas by gravity, and the Producer Gas exits through the Producer Gas collection vents 70.
  • the Biochar residue boxes 90 are at the bottom of the Biochar collection chutes 60.
  • the Biochar falls down a Biochar collection chute 60 into a Biochar residue box 90.
  • the Biochar residue box has a tube-style auger 91 called the "Residue Auger.”
  • the Residue Auger 91 moves the Biochar into a pocket valve 92 that is bolted to the end of a cross pipe spool, which is bolted to the Residue Auger 91.
  • the pocket valve 92 is a standard, air-actuated 8" or 10" ball valve where the ball is sealed on one end. When in the "up” position, the ball forms a bucket.
  • the Residue Auger 91 is controlled by the gasifier's Control System so that while the pocket valve 92 is in the up position, the Residue Auger 91 deposits Biochar into the pocket valve 92.
  • the Residue Auger 91 stops and the pocket valve 92 rotates to the "down" position, dumping its contents into an external collection bin or some other secondary removal system. Because the ball on the pocket valve 92 is closed on one end, the pocket valve 92 remains sealed at all times and prevents Producer Gas from leaking out of the Biochar residue box 90. A small amount of Producer Gas does escape, but can be vented safely by a high-point vent pipe or drawn out by vacuum pump.
  • the gasifier can gasify a very broad range of feedstock. To determine whether a given feedstock or blend of materials will gasify effectively, the feedstock must be porous enough to allow Oxidant Stream to flow through it, have a suitable calorific density (btu/ft3), have a suitable bulk density and a suitable chemical makeup. A person having ordinary skill in the art would recognize a suitable feedstock.
  • a suitable feedstock may be: (1) 25% or more chemically-bound oxygen content (molecular basis), (2) 10% or less ash content, (3) 30% or less moisture content, and (4) greater than 15 lbs/ft 3 bulk density. There is some interaction between these variables.
  • the gasifier On start-up, the gasifier is filled up to the middle of the Oxidation Zone 30 with feedstock. A layer of hot charcoal (in one embodiment a layer just a few inches (about 7.5cm) in height) is added to the top of the feedstock through the top of the Pyrolysis Zone 20 or Drying Zone 10 (if applicable). The gasifier is then filled with feedstock to the gasifier's Fill Level Indicator and the gasifier's Control System is started.
  • a layer of hot charcoal in one embodiment a layer just a few inches (about 7.5cm) in height
  • the gasifier Over the next several hours, the gasifier will begin to heat up, and a thermal gradient will start forming. Some low quality gas will be made almost immediately and Producer Gas production will gradually increase and improve as the gasifier heats up.
  • the gasifier If the gasifier is operated for an adequate period of time, the lining inside the gasifier will become saturated with heat and the gasifier can be restarted without additional hot charcoal even after several hours of downtime. This is referred to as a "warm-start". In many cases, the gasifier can be shut down for more than 2-3 days and still retain enough internal heat for a warm start simply by restarting the Oxidant Streams. Producer Gas flow from the gasifier stops when the Oxidant Streams stop.
  • Optimizing the gasifier's operation requires precise real-time adjustments to control the location of the Oxidation Band 350. For example, if a mechanical device were inserted in the Oxidation Band 350 to adjust the rate of the materials leaving or entering, the 3,000° F (about 1600°C) temperatures (approximate) in the Oxidation Band 350 would destroy the mechanical device. Therefore, a grate 50 is used to control the removal of Biochar from the gasifier as it can be placed adjacent to the much cooler Reduction Zone 40. The changes to the height of the Biochar bed caused by increasing the rate of removal of Biochar from the Reduction Zone 40 induce some of the necessary changes to adjust the vertical location of the Oxidation Band 350. The variables mentioned below may each be adjusted to induce changes in the Oxidation Band 350.
  • the Control System uses various algorithms to monitor and adjust the gasifier.
  • the Control System may include subsystems capable of real-time adjustments and account for other methods that may only be adjusted while the gasifier is offline. Adjustments while the gasifier is offline may include: (1) adjusting the physical size and height of the Drying Zone 10 (or removing it); (2) adjusting the size of the holes 503 in the grate 50 (in one embodiment, by replacing its interchangeable segments 504 ).
  • the Control System may include subsystems to implement real-time adjustments during operation of the gasifier related to: (a) the type of feedstock entering the gasifier; (b) the rate that feedstock enters the gasifier; (c) the fill level of the feedstock in the Drying Zone 10, if applicable; (d) the temperature of the Drying Zone 10, if applicable; (e) the volume, speed and pressure of Oxidant Stream delivered through the inlets at the top of the Pyrolysis Zone 20 (or Drying Zone 10, if applicable); (f) the volume, speed and pressure of Oxidant Stream delivered through the rings of Plano Air Inlets 31, 32; (g) the overall pressure of the gasifier; (h) the differential pressure between the various zones of the gasifier; (i) the location of the Oxidation Band 350 in the gasifier; (j) adjusting the rotational speed of the grate 50; (k) the vertical position of the grate 50 (i.e., adjusting height of the Bypass); (1) the thickness of the Biochar bed in the Reduction
  • the Control System can gradually increase or decrease a Variable or start or stop any changes to the Variable entirely.
  • the Control System may need to slightly slow the rotational speed of the grate 50 at one time and then completely stop it at another point.
  • VFDs variable frequency drives
  • a VFD is therefore attached to an on/off timer and used to control the rotational speed of the grate 50. By starting and stopping the VFD, the Control System may simulate a slow grate 50 rotation while maintaining sufficient torque from the VFD to rotate the grate 50.
  • the VFD may be used without an on/off timer.
  • the Control System adjusts the rotational velocity of the grate 50 to adjust several of the Variables, including the differential pressure between the Oxidation Zone 30 and the Reduction Zone 40.
  • An example of the latter is that the differential pressure of the Reduction zone may be maintained by simply controlling the RPM setting of the grate 50.
  • the rate at which Biochar leaves the gasifier also controls the vertical differential pressure across the gasifier (the thickness of the Biochar bed partly determines the pressure of the gasifier because the Biochar forms a pseudo-seal at the bottom of the gasifier).
  • the vertical differential pressure across the gasifier, from the top of the Drying Zone 10 through to the bottom of the grate 50 is therefore controlled, in part, simply by increasing or decreasing the rotational speed of the grate 50, which ejects Biochar from the Reduction Zone 40. Described another way, if Biochar is not ejected fast enough from the gasifier it accumulates in the Reduction Zone 40 and the decreased remaining volume increases the pressure of the Producer Gas in the Reduction Zone 40 and the Oxidation Zone 30.
  • the vertical differential pressure of the gasifier is controlled by the height of the Bypass; as the height of the Bypass increases (i.e., by lowering the grate 50 ) the greater the flow of Producer Gas and Biochar from the gasifier.
  • the rate of Producer Gas generation is proportional to the concentration of Oxygen in the Oxidant Streams and the flow rate of the Oxidant Streams being introduced to the gasifier.
  • the Control System measures and regulates the Oxidant Streams using standard methods known in the art.
  • Figure 17 shows a cutaway side view of a gasifier with arrows depicting the gasification process.
  • Three types of Oxidant Streams enter the gasifier through three separate, corresponding inlet points: Purge Oxidant Streams, Bed Oxidant Streams and Plano Oxidant Streams.
  • the Purge Oxidant Stream is the Oxidant Stream that is introduced to the feedstock and enters the gasifier with the feedstock through the Pressure Lock.
  • the Purge Oxidant Stream also prevents tarry gases from back-flowing into the Pressure Lock.
  • the Bed Oxidant Stream enters the gasifier through inlets 11 located at the top of the gasifier.
  • the Plano Oxidant Streams enter the gasifier through the Plano Air Inlets 31, 32 located in rings around the perimeter of the Oxidation Zone 30.
  • the Control System monitors and adjusts each of these Oxidant Streams to control the total amount of Oxygen in each zone of the gasifier and the rate of Producer Gas being generated.
  • the Control System can adjust the volume and velocity of this Oxidant Stream to adjust for feedstock having differing moisture contents, bulk densities, or even because of changes in the BTU value of a feedstock.
  • the Control System allows for the changes to be made while the gasifier is in operation, so that it does not need to be shut down or be reconfigured.
  • an effective control method is to monitor the thermal gradient, or profile, as indicated by the temperatures of each zone. These temperatures are obtained by way of embedded thermocouples inside of the lined wall of the gasifier. This temperature gradient, or profile, is a very good indicator of where each zone is and where it is moving toward within the gasifier.
  • the Control System uses this information to change the balance of Oxidant Stream at any given zone or to physically change the height of the bed of Biochar in the Reduction Zone 40 by way of the grate 50 rotation and bypass to help maintain and/or sustain each zone above it.
  • One embodiment improves the consistency of the Producer Gas by lining the entire gasifier with silica carbide, silica oxide, aluminum oxide, refractory alloy, other ceramics or another material that is stable at high temperatures. This lining helps to evenly distribute and conduct heat out from the Oxidation Band 350 and allows the use of thermocouples while protecting them from the reactions occurring inside the gasifier.
  • the Control System may use all of the different methods and combine said methods into an algorithmic controller.
  • the latter does not only allow for redundancy throughout the Control System but also ensures much greater reliability and efficiency. It furthermore ensures that the Producer Gas is of constant and high quality.
  • the application and method of gasification described above also provides an effective way of controlling the height of the Reduction Zone 40.
  • a problem in other gasifiers is that the Oxidation Band 350 is limited to one location within the gasifier, and moving it disrupts the function of the process substantially or destroys the gasifier.
  • the Oxidation Band 350 can move up into the Pyrolysis Zone 20 or down into the Reduction Zone 40 and still be controlled and/or maintained by way of where the Control System allows the Oxidant Stream to be placed and amount of Biochar being removed. Disruption to the height of the feedstock, or the differential pressure across the gasifier can therefore be controlled by way of the grate 50 rotation without risking the Oxidation Band's 350 collapse.
  • the gasifier will create Producer Gas having a calorific density of 125 to 145 btu/ft 3 (about 4660 to 5400 kJ/m 3 ). This quality of Producer Gas will continue to be produced for so long as sufficient Oxidant Stream and suitable feedstock are made available to the gasifier. In one embodiment, the gasifier converts between 12 and 120 tons of feedstock per day.
EP13873081.7A 2013-01-28 2013-01-29 Method and device for gasifying feedstock Active EP2948658B1 (en)

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US13/752,021 US8546636B1 (en) 2013-01-28 2013-01-28 Method for gasifying feedstock
US13/751,983 US8721748B1 (en) 2013-01-28 2013-01-28 Device with dilated oxidation zone for gasifying feedstock
PCT/US2013/023606 WO2014116267A1 (en) 2013-01-28 2013-01-29 Method and device for gasifying feedstock

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106345408A (zh) * 2016-09-23 2017-01-25 北京甸甸丰生物科技有限公司 一种含有植物提取物带有除臭剂的制剂
JP6633563B2 (ja) * 2017-03-24 2020-01-22 ヤンマー株式会社 ガス化装置
JP6668283B2 (ja) * 2017-03-24 2020-03-18 ヤンマー株式会社 ガス化装置
CN107142127B (zh) * 2017-06-30 2023-03-31 商丘市恒盛机械制造有限公司 自动搅拌式料位控制装置
DE102017213195A1 (de) * 2017-07-31 2019-01-31 Entrade Energiesysteme Ag Rosteinrichtung für einen Festbettvergaser zum Erzeugen eines Produktgases aus schüttbaren kohlenstoffhaltigen Einsatzstoffen, Festbettvergaser mit einer solchen Rosteinrichtung und Verwendung eines solchen Festbettvergasers
CN108192667B (zh) * 2017-12-29 2020-04-10 扬州大学 一种生物质气化炉及其气化操作方法
JP7386813B2 (ja) * 2018-02-08 2023-11-27 ソチエタ・ペル・アツィオーニ・クルティ－コストルツィオーニ・メッカーニケ ガス化プラント
JP7161051B2 (ja) * 2018-11-28 2022-10-25 アフリカン レインボー ミネラルズ リミテッド 供給原料のガス化及び／又は溶融のための反応炉及びプロセス
JP2020105451A (ja) * 2018-12-28 2020-07-09 ユア・エネルギー開発株式会社 バイオマス原料を用いたガス化炉
CN111826172A (zh) * 2020-06-29 2020-10-27 中冶天工集团天津有限公司 一种焦炉煤气埋管安装方法
CN113587103A (zh) * 2021-07-28 2021-11-02 中国铁建重工集团股份有限公司 一种热解气化炉
GB2622377A (en) * 2022-09-13 2024-03-20 Gasification Consultancy Ltd Gasification

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2516141A (en) * 1949-07-01 1950-07-25 Louis L Newman Apparatus and method for gasifying carbonaceous material
SE453670C (sv) * 1986-07-08 1989-06-20 Waste Gas Energy Ab Wge Anordning foer framstaellning av gas ur fasta braenslen
US4764185A (en) * 1987-10-28 1988-08-16 Mayer Edward F Gasifier apparatus
US5226927A (en) * 1991-02-13 1993-07-13 Southern California Edison Wood gasifier
WO1994016038A1 (en) * 1992-12-30 1994-07-21 Combustion Engineering, Inc. Circular slag tap for a gasifier
US6112677A (en) * 1996-03-07 2000-09-05 Sevar Entsorgungsanlagen Gmbh Down-draft fixed bed gasifier system and use thereof
DE19608826C2 (de) * 1996-03-07 1998-03-26 Walter Kuntschar Gleichstrom-Vergasungsreaktor
GB9811415D0 (en) * 1998-05-28 1998-07-22 Dedar Limited Gasifiers
DK174582B1 (da) * 2001-11-05 2003-06-30 Biosynergi Proces Aps Fremgangsmåde og generator til forgasning af fast biobrændsel
GB0325668D0 (en) * 2003-11-04 2003-12-10 Dogru Murat Intensified and minaturized gasifier with multiple air injection and catalytic bed
ES2420805T3 (es) * 2005-06-28 2013-08-26 Afognak Native Corporation Metodo y aparato para generación de energía de biomasa, modular, automatizada
US7569204B2 (en) * 2006-02-27 2009-08-04 Zeropoint Clean Tech, Inc. Apparatus and method for controlling the gas composition produced during the gasification of carbon containing feeds
JP2008081635A (ja) * 2006-09-28 2008-04-10 Tsukishima Kikai Co Ltd 木質バイオマスのガス化方法
US8105401B2 (en) * 2007-07-10 2012-01-31 Refill Energy, Inc. Parallel path, downdraft gasifier apparatus and method
ITTO20090125A1 (it) * 2009-02-20 2010-08-21 Socoges S R L Gassificatore dotato di camera di combustione perfezionata
ES2935058T3 (es) * 2010-08-16 2023-03-01 Singularity Energy Tech Llc Procedimiento de gasificación en sándwich para la conversión de combustibles carbonáceos de alta eficiencia en gas de síntesis limpio con cero descarga de carbono residual

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

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BR112015017918A2 (pt) 2017-07-11
MX2015009729A (es) 2015-11-13
ES2727960T3 (es) 2019-10-21
WO2014116267A1 (en) 2014-07-31
EP2948658A1 (en) 2015-12-02
AU2013375286A1 (en) 2015-08-13
CA2899123C (en) 2017-08-15
SG11201505847QA (en) 2015-08-28
CR20150415A (es) 2016-04-08
IL240175B (en) 2018-08-30
SG10201706842YA (en) 2017-10-30
CN105026725A (zh) 2015-11-04
PH12015501856B1 (en) 2015-12-07
CN105026725B (zh) 2017-03-08
JP2016508526A (ja) 2016-03-22
AU2013375286B2 (en) 2017-03-02
IL240175A0 (en) 2015-09-24
JP2017186565A (ja) 2017-10-12
DOP2015000179A (es) 2015-09-30
JP6179041B2 (ja) 2017-08-16
MX365196B (es) 2019-05-27
JP6402419B2 (ja) 2018-10-10
PH12015501856A1 (en) 2015-12-07
CA2899123A1 (en) 2014-07-31
MY175172A (en) 2020-06-12

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