EP2925899B1 - Matériau en acier métallique - Google Patents

Matériau en acier métallique Download PDF

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Publication number
EP2925899B1
EP2925899B1 EP13795241.2A EP13795241A EP2925899B1 EP 2925899 B1 EP2925899 B1 EP 2925899B1 EP 13795241 A EP13795241 A EP 13795241A EP 2925899 B1 EP2925899 B1 EP 2925899B1
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EP
European Patent Office
Prior art keywords
weight
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content
vanadium
chromium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP13795241.2A
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German (de)
English (en)
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EP2925899A1 (fr
EP2925899B8 (fr
Inventor
Matthias Kuntz
Reinhold Ebner
Stefan Marsoner
Friedrich Muehleder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MATERIALS CENTER LEOBEN FORSCHUNG GmbH
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
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Publication of EP2925899B8 publication Critical patent/EP2925899B8/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/20—Isothermal quenching, e.g. bainitic hardening
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/002—Heat treatment of ferrous alloys containing Cr
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/008—Heat treatment of ferrous alloys containing Si
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/004—Dispersions; Precipitations

Definitions

  • the present invention relates to a metallic material.
  • the present invention further relates to a method for producing a metallic material and the use of a metallic material for producing a component in an internal combustion engine.
  • Metallic materials are used in a variety of applications.
  • metallic materials are known as components of an internal combustion engine.
  • high-strength materials such as metallic materials, for example, given by their mechanical properties, as well as by their machinability.
  • cyclic strength and economical workability such as formability, machinability, or weldability may be important.
  • the document US3291655 discloses a process for producing a high creep, ferritic Cr-Mo-V ferritic steel with improved time-break elongation by austenitizing annealing, quenching to form a predominantly bainite structure, and annealing at 620 to 760 ° C with the precipitation of vanadium carbides in finely divided form.
  • the present invention is a metallic steel material according to claim 1.
  • such a metallic material further comprises at least chromium (Cr), molybdenum (Mo) and vanadium (V).
  • Cr chromium
  • Mo molybdenum
  • V vanadium
  • the abovementioned metals may be present, for example, in the form of an alloy, at least partially as pure metals or at least partly as carbides, as explained below.
  • the material may contain other ingredients, which may be necessary for a suitable manufacturing process or for a specific field of application.
  • constituents may be mentioned, for example, in the steel production customary constituents, such as sulfur or phosphorus.
  • such a metallic material has a bainitic basic structure.
  • a bainitic ground structure may be understood to mean such a structure, which may in particular have ferrite phases and cementite phases (Fe 3 C).
  • a bainitic structure on carbon may have supersaturated ferrite crystals present with cubic body-centered crystal lattice.
  • a bainite structure can be recognized on a carbon-supersaturated ferritic mixed crystal optionally with other ingredients such as, in particular, chromium, molybdenum and vanadium, in combination with iron-rich metal carbides such as cementite, wherein a non-limiting typical iron content of the metallic constituents of the carbides is in a range greater than or equal to 50 atomic%.
  • the combination of the mixed crystal and the carbides can in principle be present next to each other, which, however, can often be difficult to recognize.
  • carbide phases are or are provided in the above-described material. These carbidic phases can be at least partially formed by carbide present as molybdenum, vanadium and / or chromium.
  • each of the abovementioned metals may be present as carbide, or individual or a suitable mixture of the abovementioned metals may be present as carbides. It is understood by those skilled in the art that the aforementioned metals need not be fully present as carbides, but also may be included in non-carbidic form in the material.
  • the carbide phases are present at least partially with a diameter which is in a range of less than or equal to 200 nm, in particular in a range of less than or equal to 100 nm.
  • Carbides in this size range are in particular molybdenum and / or vanadium as carbides , In particular, these carbides may be responsible for a hardness increase, as will be explained in detail later. In addition, other carbides may be present which have a larger diameter, for example carbides of iron and / or chromium.
  • the aforementioned material is thus a carbide-hardened steel.
  • the aforementioned steel allows in an especially advantageous manner an increase in the cyclic resistance, in particular an improved fatigue strength and higher toughness, at the same time low-calorific heat treatment.
  • the above-described carbide-hardened steel allows the possibility of combining soft-working with an increase in cyclic-strength.
  • the Carbidaushärtung offers the Possibility of a dimensionally stable strength increase of the steel structure by means of aging or heat treatment at moderate temperatures.
  • a soft bainitic ground structure such as having a hardness in a range of less than 37HRC (Rockwell hardness;
  • the Rockwell hardness of a material results from the penetration depth of a specimen in case of concern a certain fore- and Test load and can be determined, for example, according to DIN EN ISO 6508-1), and high strength increases of up to 10HRC or even more can be achieved via the following carbide precipitations.
  • the above-described material thus allows little effort in an optionally necessary post-processing in the hard state.
  • a post-processing in a hard state can be completely eliminated, which can allow a shortening of the value-added chain for setting the desired component property.
  • a particularly simple and cost-effective production process can be made possible.
  • the above-mentioned material is particularly inexpensive to produce and can also meet future requirements, with a dicheronia can also be given to the specific application requirements.
  • the above-described metallic material or the above-described carbide-hardened steel allows a particularly advantageous use in particularly harsh conditions, such as high temperatures, oxidative atmospheres and high pressures.
  • An advantageous application can be seen in internal combustion engines.
  • the above-described material can be used in injection systems, for example a diesel engine. Concrete application examples include the formation of nozzles or injectors, pressure accumulators or high-pressure pumps in injection systems. Because even in such applications occurring conditions, such as high Injection pressures of, for example, 3000 bar, the above-described material can easily withstand cost-effective manufacturability.
  • the above-described material allows the production of mechanically and / or cyclically highly stressable components, an adjustment of previously unavailable property combinations in steels, and thereby a particularly simple and cost-effective production process.
  • the steel material may further comprise at least one further constituent selected from the group consisting of silicon and manganese.
  • the properties of the material in particular with regard to the mechanical resistance or the cyclic resistance, can be further improved.
  • manganese for example, the hardenability, tensile strength and weldability and in principle the processability can be improved, which depending on the application or in particular depending on the production of great advantage. For example, a cooling occurring during the production can be improved due to an enlarged cooling window.
  • Silicon for example, can serve, in particular in the production of the material, to improve the processability and also to serve as a deoxidizer in order to protect the material from negative influence. Another advantage of providing silicon can be seen in that the tensile strength, yield strength and scale resistance of the material can be increased. In principle, silicon can further increase the strength. In addition, silicon as a mixed crystal hardener can further improve the mechanical properties.
  • the material may have a hardness of greater than or equal to 45HRC.
  • the material has a hardness that can not be achieved according to the prior art or only by much more complex manufacturing steps, as these are necessary for the described material.
  • the material in particular with such a high hardness, has a very high mechanical stability or cyclic resistance, so that a particularly wide field of application can be possible.
  • HRC in particular the hardness according to Rockwell can be understood.
  • the Rockwell hardness of a material results from the penetration depth of a test specimen when a given pre-test and test force and can be determined, for example, according to DIN EN ISO 6508-1.
  • the above-described metallic composition is therefore in particular a steel. It also has the potential for carbide precipitation by the elements carbon in combination with chromium, molybdenum and vanadium.
  • To form the material takes place in a further process step b) treating the metallic composition at elevated temperature.
  • the metallic composition can in particular be heated to or above its austenitizing temperature or austenite formation temperature.
  • heating takes place at a temperature in a range of greater than or equal to 950 ° C. up to a temperature in a range of less than or equal to 1100 ° C. This temperature may be maintained for a predetermined period of time, such as typically 15 to 120 minutes.
  • an austenite formation of the metallic composition thus takes place.
  • the metallic composition is cooled at a predetermined cooling rate.
  • the predetermined cooling rate can be selected, for example, as a function of the concrete metallic composition or its percentage composition. In principle, cooling rates which are in a range of greater than or equal to 0.2 K / s to less than or equal to 3 K / s may be suitable for the described metallic composition.
  • a bainitic ground structure is formed.
  • a steel having a hardness in the range of 32 to 40 HRC, for example 35HRC, can be obtained.
  • the further temperature treatment is carried out in particular by the provision of carbon and also chromium, molybdenum and vanadium, a formation of the corresponding metal carbides, in particular carbide or nanoscale Carbidausscheidungen in a range of less than or equal to 200nm, in particular in a range of 100nm.
  • the hardness can be further increased by a range of about 10HRC, so that a material having a hardness of 45HRC or even higher can be obtained.
  • the basic hardness of the bainitic microstructure and the increase in hardness or increase in strength can be adapted to the desired field of application in the method described above.
  • the material or its structure still has sufficient ductility even after curing, so that further strength-increasing technologies, such as autofrettage, can be used.
  • the subject matter of the present invention is furthermore a use of a material designed as described above or of a method configured as described above for producing a component for an internal combustion engine, in particular for producing an injection component.
  • an internal combustion engine can be understood in particular to mean a heat engine which converts the chemical energy of a fuel into mechanical energy via a combustion process.
  • Examples of internal combustion engines are in particular an internal combustion engine, such as a diesel engine or a gasoline engine.
  • injection components such as, for example, nozzles or injectors, high-pressure pumps or pressure accumulators, in particular for a diesel engine, may be mentioned as specific fields of application.
  • the subject of the present invention is furthermore an injection component for an internal combustion engine, comprising a material designed as described above.
  • the present invention is in particular an injection component, such as in particular a nozzle or an injector, a high-pressure pump or a pressure accumulator, which are at least partially, for example completely, formed from the material described above.
  • injection component according to the present invention a pressurized or pressure-loaded component of an injection system, in particular for a Diesel engine can be understood. Due to the outstanding properties of the above-described material in terms of mechanical stability and cyclic strength of the above-described material is particularly suitable for producing an injection component, in particular for a diesel engine.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)

Claims (10)

  1. Matériau métallique à base d'acier, comprenant au moins du fer, du carbone, du chrome, du molybdène et du vanadium, le matériau comprenant une structure de base bainitique et des phases carburiques étant en outre prévues, qui sont au moins partiellement formées par du molybdène, du vanadium et/ou du chrome présents sous la forme de carbures, les phases carburiques présentant au moins partiellement un diamètre dans une plage inférieure ou égale à 200 nm, le matériau comprenant :
    - du carbone en une teneur supérieure ou égale à 0,25 % en poids à inférieure ou égale à 0,4 % en poids ;
    - du chrome en une teneur supérieure ou égale à 0,3 % en poids à inférieure ou égale à 0,6 % en poids ;
    - du molybdène en une teneur supérieure ou égale à 1,5 % en poids à inférieure ou égale à 3,2 % en poids ;
    - du vanadium en une teneur supérieure ou égale à 0,2 % en poids à inférieure ou égale à 0,6 % en poids ;
    - du silicium en une teneur supérieure ou égale à 0 % en poids à inférieure ou égale à 0,35 % en poids ; et
    - du manganèse en une teneur supérieure ou égale à 0 % en poids à inférieure ou égale à 0,35 % en poids ;
    les constituants susmentionnés étant présents au total en une teneur inférieure à 100 % en poids, et les autres constituants étant répartis entre du fer et éventuellement du phosphore et éventuellement de l'azote.
  2. Matériau à base d'acier selon la revendication 1, dans lequel le matériau comprend en outre au moins un autre constituant du groupe constitué par le silicium et le manganèse.
  3. Matériau à base d'acier selon l'une quelconque des revendications 1 ou 2, dans lequel le matériau comprend :
    - du carbone en une teneur de 0,35 % en poids ;
    - du chrome en une teneur de 0,5 % en poids ;
    - du molybdène en une teneur de 3,0 % en poids ;
    - du vanadium en une teneur de 0,45 % en poids ;
    - du silicium en une teneur de 0,3 % en poids ; et
    - du manganèse en une teneur de 0,3 % en poids.
  4. Matériau à base d'acier selon l'une quelconque des revendications 1 à 3, dans lequel le matériau présente une dureté supérieure ou égale à 42 HRC, notamment supérieure ou égale à 45 HRC.
  5. Procédé de fabrication d'un matériau à base d'acier selon l'une quelconque des revendications 1 à 4, comprenant les étapes de procédé suivantes :
    a) la préparation d'une composition métallique comprenant au moins les constituants fer, carbone, chrome, molybdène, vanadium et éventuellement silicium et éventuellement manganèse, la composition comprenant :
    - du carbone en une teneur supérieure ou égale à 0,25 % en poids à inférieure ou égale à 0,4 % en poids ;
    - du chrome en une teneur supérieure ou égale à 0,3 % en poids à inférieure ou égale à 0,6 % en poids ;
    - du molybdène en une teneur supérieure ou égale à 1,5 % en poids à inférieure ou égale à 3,2 % en poids ;
    - du vanadium en une teneur supérieure ou égale à 0,2 % en poids à inférieure ou égale à 0,6 % en poids ;
    - du silicium en une teneur supérieure ou égale à 0 % en poids à inférieure ou égale à 0,35 % en poids ; et
    - du manganèse en une teneur supérieure ou égale à 0 % en poids à inférieure ou égale à 0,35 % en poids ;
    les constituants susmentionnés étant présents au total en une teneur inférieure à 100 % en poids, et les autres constituants étant répartis entre du fer et éventuellement du phosphore et éventuellement de l'azote ;
    b) le traitement de la composition métallique à une température qui est supérieure ou égale à la température d'austénisation ;
    c) le refroidissement de la composition métallique à un taux de refroidissement prédéterminé, une formation d'une structure de base bainitique ayant lieu ;
    d) le traitement du produit obtenu à l'étape de procédé c) à une température dans une plage supérieure ou égale à 400 °C, une formation de précipités de carbure dans une plage inférieure ou égale à 200 nm ayant lieu ; et
    e) le refroidissement du produit obtenu à l'étape de procédé d).
  6. Procédé selon la revendication 5, dans lequel l'étape de procédé b) est réalisée dans une plage de température supérieure ou égale à 950 °C à inférieure ou égale à 1 100 °C.
  7. Procédé selon la revendication 5 ou 6, dans lequel l'étape de procédé d) est réalisée dans une plage de température supérieure ou égale à 450 °C à inférieure ou égale à 600 °C.
  8. Procédé selon les revendications 5 à 7, dans lequel un taux de refroidissement dans une plage supérieure ou égale à 0,2 K/s à inférieure ou égale à 3 K/s est utilisé à l'étape de procédé c).
  9. Utilisation d'un matériau à base d'acier selon l'une quelconque des revendications 1 à 4 pour la fabrication d'un composant pour un moteur à combustion interne, notamment un composant d'injection.
  10. Composant d'injection pour un moteur à combustion interne, notamment pour un moteur diesel, comprenant un matériau à base d'acier selon l'une quelconque des revendications 1 à 4.
EP13795241.2A 2012-11-27 2013-11-25 Matériau en acier métallique Active EP2925899B8 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201210221607 DE102012221607A1 (de) 2012-11-27 2012-11-27 Metallischer Werkstoff
PCT/EP2013/074542 WO2014082945A1 (fr) 2012-11-27 2013-11-25 Matériau métallique

Publications (3)

Publication Number Publication Date
EP2925899A1 EP2925899A1 (fr) 2015-10-07
EP2925899B1 true EP2925899B1 (fr) 2019-02-06
EP2925899B8 EP2925899B8 (fr) 2019-04-17

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EP13795241.2A Active EP2925899B8 (fr) 2012-11-27 2013-11-25 Matériau en acier métallique

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US (1) US20150292066A1 (fr)
EP (1) EP2925899B8 (fr)
DE (1) DE102012221607A1 (fr)
WO (1) WO2014082945A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102016108633A1 (de) * 2016-05-10 2017-11-30 Benteler Steel/Tube Gmbh Kraftstoffeinspritzleitung und rohrförmiger Leitungskanal

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US3291655A (en) * 1964-06-17 1966-12-13 Gen Electric Alloys
US3806378A (en) * 1972-12-20 1974-04-23 Bethlehem Steel Corp As-worked bainitic ferrous alloy and method
UA59411C2 (uk) * 1997-07-28 2003-09-15 Ексонмобіл Апстрім Рісерч Компані Низьколегована конструкційна сталь (варіанти) та спосіб одержання листа сталі (варіанти)
DE10139620A1 (de) * 2001-08-11 2003-02-27 Bosch Gmbh Robert Kraftstoffeinspritzventil für Brennkraftmaschinen und ein Verfahren zur Härtung desselben
JP4609138B2 (ja) * 2005-03-24 2011-01-12 住友金属工業株式会社 耐硫化物応力割れ性に優れた油井管用鋼および油井用継目無鋼管の製造方法
WO2007058364A1 (fr) * 2005-11-21 2007-05-24 National Institute For Materials Science Acier pour écrouissage a chaud, procede d'écrouissage a chaud de l'acier, et materiau d'acier et piece en acier obtenus avec le procede
CN101578446B (zh) * 2007-11-12 2012-05-23 新日本制铁株式会社 共轨的制造方法以及局部强化的共轨
FR2931166B1 (fr) * 2008-05-15 2010-12-31 Arcelormittal Gandrange Acier pour forge a chaud a hautes caracteristiques mecaniques des pieces produites
JP5483859B2 (ja) * 2008-10-31 2014-05-07 臼井国際産業株式会社 焼入性に優れた高強度鋼製加工品及びその製造方法、並びに高強度かつ耐衝撃特性及び耐内圧疲労特性に優れたディーゼルエンジン用燃料噴射管及びコモンレールの製造方法

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Publication number Publication date
US20150292066A1 (en) 2015-10-15
EP2925899A1 (fr) 2015-10-07
DE102012221607A1 (de) 2014-05-28
EP2925899B8 (fr) 2019-04-17
WO2014082945A1 (fr) 2014-06-05

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