EP2879882B1 - Flat screen material and screen - Google Patents
Flat screen material and screen Download PDFInfo
- Publication number
- EP2879882B1 EP2879882B1 EP13728975.7A EP13728975A EP2879882B1 EP 2879882 B1 EP2879882 B1 EP 2879882B1 EP 13728975 A EP13728975 A EP 13728975A EP 2879882 B1 EP2879882 B1 EP 2879882B1
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- European Patent Office
- Prior art keywords
- screen material
- screen
- threads
- filling
- flat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F15/00—Screen printers
- B41F15/14—Details
- B41F15/34—Screens, Frames; Holders therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/24—Stencils; Stencil materials; Carriers therefor
- B41N1/247—Meshes, gauzes, woven or similar screen materials; Preparation thereof, e.g. by plasma treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F15/00—Screen printers
- B41F15/14—Details
- B41F15/34—Screens, Frames; Holders therefor
- B41F15/36—Screens, Frames; Holders therefor flat
Definitions
- the invention relates to a sieve material with the preamble features of claim 1 and a sieve with the preamble features of claim 8.
- the square mesh When used in the field of filtration, the square mesh is the usual embodiment. For the printing application, this mesh has been adopted. With the available photo layers and the well-known application methods, a reasonable image resolution can only be achieved with a large number of "supports". Therefore, increasingly high mesh fabrics are being used.
- the solar cell coating requires a high paste application and a precise and fine image resolution. For example, for applying printed conductors as current fingers with the smallest possible coverage of the solar cells, in order to ensure a high efficiency of the solar cells.
- the screens or fabrics used for electronic printing are very expensive and delicate to process, making them unsuitable for the production of screen printing plates for rotary screen printing.
- the lack of suitability is also due to the fact that the screen fabric in the rotary screen can be stretched in one direction only, namely the cylinder longitudinal axis, in flat screen printing, however, in two dimensions.
- the color is transported through the screen by the hydrodynamic pressure generated by the rotation of the screen and by the squeegee in front of the squeegee.
- the hydrodynamic pressure generated by the rotation of the screen and by the squeegee in front of the squeegee.
- Such a rotary screen printing unit is for example in the WO 99/19146 A1 described.
- the state of the art for nickel plating is that preferably sulphamate nickel baths or chemical nickel processes (external powerless) are used.
- the advantage of this method is a uniform geometric layer distribution in all spatial planes.
- the disadvantage of this method is that at the crossing point a so-called angle weakness, hereinafter also referred to as an undercut, arises.
- the undercut has the property that the flow behavior, for example in cleaning processes and of ink in the print, as well as the stability of the metallized fabric are adversely affected.
- the Watt's nickel sulphate baths are mixed with a wide variety of, preferably organic, additives.
- the additives are subdivided into gloss additives (so-called glossy carrier) first (primary) and second (secondary) class.
- gloss additives so-called glossy carrier
- Primary glossy supports which incidentally may also have properties of second-class luster carriers, are used to achieve homogeneous metal deposition with a specific base luster over as wide a current density range as possible.
- Secondary glosses have a large influence on the leveling and gloss level.
- first and second class gloss supports have, in combination, other effects on the deposited nickel layer: gloss, ductility, hardness, flattening behavior and electrochemical potential of the deposited layers with each other.
- US 3,482,300 describes a screen for a screen printing machine which is electrolytically coated with metal for reinforcement.
- US 4,285,274 describes a seamless screen printing cylinder and a manufacturing method therefor.
- the described screen-printing cylinder has a metal net substrate, in which the crossing points are provided with a galvanic coating.
- the object of the present invention is therefore to provide a sieve material and a sieve which do not have the disadvantages of the screening materials and sieves known from the prior art and which are particularly suitable for rotary screen printing.
- the screen materials in particular steel mesh, should have a higher stability and a longer service life for use in rotary screen printing.
- the flat screen material according to the invention is used in screen printing, in particular in rotary screen printing.
- the screen material has strands arranged at an angle to one another and crossing at points of intersection, which form a woven screen structure, the invention being independent of the weave and the stitch form.
- the strands form undercuts, wherein undercuts mean the inner edges of adjacent surfaces of the intersecting strands, for example of warp threads and weft threads.
- the strands are arranged so that a screen structure is formed with openings. Throughout their surfaces, the strands have a coating of approximately constant thickness of metal, particularly nickel, which has been deposited on the strands in a plating process.
- the areal sieve material is designed in such a way that, in the region of crossing points of the strands, their undercuts, in addition to the coating, at least partially have a filling of the metal applied in a plating process. In other words, the undercuts were reduced or eliminated by the plating process by depositing additional metal in the area of the undercuts. This creates a surface without sharp edges and chamfers.
- Such a flat screen material has the advantage that flow resistances and turbulences are reduced by the metallic fillings when using the screen material for the screen printing, which leads to a better flow behavior of the paint. Furthermore, no ink can dry in the undercut. It also further simplifies the cleaning process by permitting a direct flow of cleaning fluid, which contributes to a shorter cleaning time and a lower consumption of cleaning fluid. Another advantage is the increased stability of the flat screen material, since the notch effect of the undercuts is reduced by the metallic filling.
- a respective filling forms an inner edge transition with a rounding.
- the metal filling is thus designed so that there are no sharp edges or chamfers in the area of the undercuts. It is particularly advantageous if the fillings have a radius of at least 1 ⁇ m or at least one tenth of the mean radius of the strands (mean value of radius warp thread and radius weft thread). This ensures that in screen-printing applications, the ink can easily flow through the screen material and there are no significant deposits in the area of the undercuts, and the screen material is easy to clean, with high stability.
- a curve along the surface of the sieve material - viewed in a sectional plane perpendicular to the sieve material and viewed through one of the strands - describes a smooth curve.
- a smooth curve is understood to mean a smooth curve in the mathematical sense, i. a curve that is continuous and differentiable, ie a curve without corners or abrupt turns.
- a curve along the surface of the sieve material - in a sectional plane parallel to the sieve material and viewed through all the strands - describes a smooth curve.
- a smooth curve is understood to be a smooth curve in the mathematical sense, ie a curve which is continuous and differentiable, ie a curve without corners or abrupt turns.
- the undercuts at the top and / or at the bottom of the screen material each have a metallic padding.
- the undercuts in the plane of the screen material each have a metallic filling.
- the curve along the surface of the screen material has two
- a turning point is meant a turning point in the mathematical sense, i. a point on the surface curve in which a sign change of the second derivative takes place.
- the turning points may in particular have a distance from each other of at least 1 micron and a maximum of a distance corresponding to the pitch. By division, the distance between the center axes of two adjacent, mutually parallel strands is called. In particular, however, the inflection points are 10 to 20 microns apart. Fillings that fall into this area, on the one hand production technology well produced and meet the other hand, the expectations of higher stability and better flow properties of the sheet material.
- a parabolic filling which in each case has an undercut itself.
- the sieve material in the region of a respective undercut is filled up to a particularly high degree and reinforced.
- the fillings are designed in such a way that the surfaces of the fillings on the surface and / or on the underside of the sieve material are in each case almost in one plane.
- the metal fill causes the strands to be completely embedded in the metallic padding.
- the screen material has a screen structure with calendered surfaces that has been diluted in a calendering process.
- a calendering process also referred to as a calendering process, is understood to mean a process which generally rolls and which causes a flattening of the sieve structure.
- Such a calendering process is used for example in the DE 691 08 040 T2 described.
- the flat screen material is formed by a tissue, for. B. by a plastic fabric or a metal wire mesh.
- the structure has the form of so-called meshes, e.g. B. of rectangular mesh or square mesh.
- the strands are made of metal at their surfaces, with nickel being particularly advantageous and therefore preferred.
- the metal was deposited on the strands in a galvanization process.
- a fabric structure with one or more, in particular nickel-containing, layers of only one electrolyte bath is preferably metallized, it being possible to purposefully add organic additives to the electrolyte bath to reinforce the crossing points.
- the formation of the nickel layer is further influenced by the tissue is moved past the non-anode side of the fabric on non-conductive bodies, ie insulators, which change the field and thus influence the nickel deposition. During the passage, the fabric structure rests on the insulator.
- the anodes can be arranged so that they have a different distance to the tissue over their extent.
- the nickel layer distribution in the crossing points on the front and back of the fabric can be optimized.
- depolarized pure nickel plates or nickel pellets can be used in baskets.
- the electric field current lines can be influenced so that specifically more nickel can be deposited on the anode-facing side of the fabric in the crossing points.
- a single strand of the fabric is nickel-plated eccentrically, with a stronger coating also taking place here on the side facing away from the anode.
- the coating can be carried out in a single process step. This is particularly advantageous when applying thin nickel layers of a few micrometers.
- the tissue can be cleaned between.
- the invention also relates to a screen for rotary screen printing, which is made of a flat screen material, as described above, and wherein the screen has the shape of a cylindrical sleeve.
- the planar sieve material is provided on one side with a polymer layer, in particular with a photopolymer layer, so that imaging is made possible by methods known to the person skilled in the art.
- brightener additives are preferably added, so-called secondary luster agents, e.g. Butynediol derivatives, quaternary pyridinium derivatives, propargyl alcohol, propynol propoxylates, especially butynediol, and primary brighteners, e.g. Benzenesulfonic acids, alkylsulfonic acids, Alylsulfonklaren, sulfonimides, sulfonamides or Benzoeklaresulfimid.
- secondary luster agents e.g. Butynediol derivatives, quaternary pyridinium derivatives, propargyl alcohol, propynol propoxylates, especially butynediol
- primary brighteners e.g. Benzenesulfonic acids, alkylsulfonic acids, Alylsulfonklaren, sulfonimides, sulfonamides
- Secondary brighteners are used in this application for the defined reinforcement of the crossing points 10, these being added depending on the desired reinforcement in a content of 0 to 0.15 g / l, primary brightener between 0 and 8 g / l.
- the fabric structure 5, which is pretreated as usual in electroplating, is nickel-plated with the bath described above.
- the fabric 5 is transported in the nickel bath via an electrical non-conductive support surface.
- the electrically non-conductive support surface can be provided transversely to the transport direction of the fabric 5 with segments which are also filled with electrolyte during operation and ensure a permanent exchange of electrolyte.
- the metal deposit 3 additionally concentrates specifically into the points of intersection 10.
- deposition also takes place on the back of the fabric.
- the nickel deposition 3 can be distributed over the crossing points or the entire back.
- the deposition rate on the tissue is reduced on the anode side. It has been shown in this arrangement that an increased deposition can take place on the side facing away from the anode.
- An ideal anode distance is between 1 cm and 40 cm to the cathode. This distance is advantageous in that the tissue 5 can still be flowed through sufficiently strongly with fresh electrolyte, but the electrical voltage losses due to the increased anode distance remain at a tolerable level.
- the nickel plating can basically take place in a single nickel cell. However, it is also conceivable to arrange several nickel cells one behind the other.
- Fig. 1 shows an inventive sheet-like screen material 1, which is provided on one side with a photo-polymer coating 2 (direct template).
- a photo-polymer coating 2 direct template
- an already imaged film can be applied to the screen structure 1 (indirect template).
- the nickel-plated planar screen material 1 is constructed from a fabric.
- Fig. 2a is a sheet-like material 1 shown, which is formed from interwoven strands 5.
- the strands 5 are arranged at right angles to each other and at a distance, so that openings 6 are formed in the flat screen material 1.
- the region in which the strands 5 arranged at right angles to one another meet or push against one another is referred to as the intersection point 10.
- a metal coating 3, z. As nickel, which is applied in a galvanic process on the strands 5, the strands 5 are connected to each other in the crossing points 10. Since the metal coating 3 is applied substantially evenly to the surface of the strands 5, so-called undercuts 11 occur where the surfaces of the strands 5 meet.
- the adjoining surfaces of the strands 5, for example of warp thread 5.1 and weft thread 5.2 form inside edges in their lines of contact.
- This has an inner edge weakness, also referred to as an angle weakness, the result, which has a negative effect on stability, flow properties and cleanability of the flat screen material 1.
- Fig. 2a is given a Cartesian coordinate system xyz, wherein the flat screen material 1 is in the xy plane.
- the z-axis is oriented orthogonal to this plane.
- Fig. 2b shows the flat screen material 1 from Fig. 2a ,
- the undercuts 11 were provided in the intersection points 10 according to the invention by selective deposition each with a padding 12.
- the targeted deposition can be carried out in particular in the context of the galvanic production of the metal coating 3.
- Fig. 3a is a section through the flat screen material 1 in the xz plane or in the yz plane shown: the warp threads 5.1 and weft threads 5.2 are each provided with a metal coating 3.
- the layer thickness of the metal coating a, b, c on the upper surface (top 28) and the lower surface (bottom 29) of warp yarns 5.1 and weft yarns 5.2 may be uniform or different.
- the properties of the flat screen material 1 can be influenced.
- the diameters 26, 27 of warp yarns 5.1 and weft yarns 5.2 can be either of the same size or of different sizes.
- Fig. 3a the neutral fiber 20 is represented by the wire longitudinal section and the division 21, which describes the distance between two central axes of strands 5 (here 5.1).
- the undercuts 11, which were in Fig. 3c can still be seen, according to Fig. 3a provided by selective deposition with a padding 12.
- Inner edges, chamfers, cuts or undercuts were thus eliminated and the surface has a smooth transition between the strands 5 on.
- the fillings 12 of the undercuts 11 can be seen more clearly: in the embodiment according to FIG Fig. 3b the curve along the surface of the screen material 1, so two turning points 22 can be seen in the region of a respective filling 12, which are turning points in the mathematical understanding. Stated another way: between the turning points 22 there is a filling 12 of the undercut 11, outside the turning points 22, however, the warp thread is 5.1 or the weft 5.2 with the usual metal coating 3 of layer thickness a, b, c provided.
- the filling 12 produced by targeted deposition has - approximately in the middle between the two turning points 22 - the largest filling strength 24, which is measured between the surface of the filling 12 and the theoretical vertex of the undercut 11.
- Fig. 4a are shown alternative galvanic coatings i, ii, iii, iv.
- the padding 12 is parabolic (not according to the invention).
- the Auf colllbine the padding 12 in the region of the original undercut 11 is particularly large.
- the padding 12 is designed such that through the filling further has an undercut, which is formed by the filling of an inner edge.
- a particularly strong galvanic coating was applied to fill 12 of the undercut 11.
- the padding 12 is so extensive that the surface of the padding 12 lies in a plane 30 and the warp threads 5.1 and the weft threads 5.2 completely into the metal coating. 3 , 12 are embedded.
- a flat screen material 1 is created, which has a flat surface which lies in the plane 30.
- the undercut 11 was provided with a particularly strong padding 12.
- the padding 12 has an inner edge transition with rounding 12.1.
- the rounding has a particularly large radius.
- the coating alternative iv can be used alternatively or in combination with the previously described coating alternatives.
- a reinforced metal coating 3 takes place, so that the metal coating 3 has a particularly high layer thickness on one side, that is, the coating is applied eccentrically.
- Fig. 4b is a heavily calendered sheet sieve material 1 shown.
- the fabric was rolled and thus flattened. This calendered surfaces 5.3, ie flattened areas were created. Since even with a calendered fabric after the metal coating 3 undercuts 11 result in the region of the crossing points 10, For example, the previously described alternatives to electroplating can be used equally here. As shown, the undercuts 11 were leave on the bottom 29 of the sheet material 1 in its original state, while at the top 28 of the flat screen material 1, the undercuts 11 were each provided with a padding 12.
- Fig. 5 shows a section through the flat screen material 1 in the xy plane, ie in the plane of the flat screen material 1.
- the flat screen material 1 in the region of the intersections 10 of warp yarns 5.1 and weft yarns 5.2 also undercuts 11.
- the fillings 12 may have an inner edge transition with rounding 12.1, wherein the padding 12 may be limited by two turning points 22 and may have a radius 25.
- Fig. 6 is a sieve 4 indicated with a flat screen material 1 in a cylindrical sleeve shape for rotary screen printing.
- the screen material 1 is held by unspecified tails in its cylindrical shape.
- Inside the screen 4 is a - not visible here - squeegee to squeeze paint through the screen material.
- the orientation of the doctor blade may be parallel to the axis of rotation of the screen 4.
- the rotation U of the screen 4 during printing is indicated by a double arrow.
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- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
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- Printing Plates And Materials Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
- Screen Printers (AREA)
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Description
Die Erfindung betrifft ein Siebmaterial mit den oberbegrifflichen Merkmalen von Anspruch 1 und ein Sieb mit den oberbegrifflichen Merkmalen von Anspruch 8.The invention relates to a sieve material with the preamble features of
Die industrielle Anwendung von Sieben und Geweben ist aus verschiedenen Fachgebieten bekannt.The industrial application of fabrics and fabrics is known from various fields.
Bei der Anwendung im Bereich der Filtration ist die quadratische Maschenform die übliche Ausführungsform. Für die Druckanwendung hat man diese Maschenform übernommen. Mit den verfügbaren Fotoschichten und den bekannten Auftragsverfahren lässt sich eine vernünftige Bildauflösung nur mit einer großen Zahl von "Abstützungen" erreichen. Deshalb werden zunehmend Gewebe mit hohen Maschenzahlen verwendet.When used in the field of filtration, the square mesh is the usual embodiment. For the printing application, this mesh has been adopted. With the available photo layers and the well-known application methods, a reasonable image resolution can only be achieved with a large number of "supports". Therefore, increasingly high mesh fabrics are being used.
Beim Elektronikdruck werden möglichst dünne Siebe bzw. Gewebe mit möglichst dünnem Draht eingesetzt um einen guten Durchfluss der Pasten zu gewährleisten und um allerfeinste Bildmotive zu ermöglichen.When electronic printing as thin as possible sieves or fabrics are used with the thinnest possible wire to ensure a good flow of pastes and to allow the finest of fine images.
Bei der Solarzellenbeschichtung werden ein hoher Pastenauftrag und eine präzise und feine Bildauflösung gefordert. Z.B. zum Auftragen von Leiterbahnen als Stromfinger mit möglichst geringer Abdeckung der Solarzellen, um so einen hohen Wirkungsgrad der Solarzellen sicherzustellen.The solar cell coating requires a high paste application and a precise and fine image resolution. For example, for applying printed conductors as current fingers with the smallest possible coverage of the solar cells, in order to ensure a high efficiency of the solar cells.
Die für den Elektronikdruck verwendeten Siebe bzw. Gewebesorten sind sehr teuer und empfindlich in der Verarbeitung, so dass sie für die Herstellung von Siebdruckplatten für den rotativen Siebdruck ungeeignet sind. Die fehlende Eignung wird auch dadurch bedingt, dass die Siebgewebe beim Rotationssieb nur in einer Richtung, nämlich der Zylinderlängsachse gespannt werden können, im Flachsiebdruck hingegen jedoch in zwei Dimensionen.The screens or fabrics used for electronic printing are very expensive and delicate to process, making them unsuitable for the production of screen printing plates for rotary screen printing. The lack of suitability is also due to the fact that the screen fabric in the rotary screen can be stretched in one direction only, namely the cylinder longitudinal axis, in flat screen printing, however, in two dimensions.
Beim Rotationssiebdruck wird die Farbe durch den hydrodynamischen Druck, welcher bei der Rotation des Siebes und bei angestellter Rakel vor der Rakelbrust entsteht, durch das Sieb transportiert. Konstruktionsbedingt lassen sich nur offene oder halboffene Rakelsysteme einsetzen, so dass der dynamische Druck von vielen Faktoren beeinflusst wird wie Viskosität, Füllmenge und Rotationsgeschwindigkeit. Durch eine Erhöhung der Rotationsgeschwindigkeit oder der Farbmenge kann der hydrodynamische Druck einfach verstärkt werden.In rotary screen printing, the color is transported through the screen by the hydrodynamic pressure generated by the rotation of the screen and by the squeegee in front of the squeegee. By design, only open or semi-open squeegee systems can be used, so that the dynamic pressure is influenced by many factors such as viscosity, filling quantity and rotational speed. By increasing the speed of rotation or the amount of ink, the hydrodynamic pressure can be easily increased.
Ein solches Rotationssiebdruckwerk ist beispielsweise in der
Als Grundstrukturen für Siebmaterialien werden nach dem Stand der Technik Edelstahlgewebe mit Leinenbindung verwendet. Das Verhältnis von Sieböffnung, Kontaktfläche und Gewebedicke hat sich als geeignet erwiesen. Die Dicke der Struktur, also die Gewebedicke (Ausgangsmaß vor Kalandrieren) entspricht in etwa der zweifachen Drahtstärke. Die Grundstruktur wird einem weiteren Schritt in einem Kalandrierprozess, auch als Kalanderprozess bezeichnet, bearbeitet und so auf die gewünschte Rohgewebedicke gebracht. Auch wird so eine höhere Glätte des Siebes und damit ein geringerer Sieb- und Rakelverschleiß erreicht. Im sich anschließenden Vemickelungsvorgang wird das Gewebe zwecks einer höheren Verschleißfestigkeit in der Regel gleichmäßig, also symmetrisch zur Achse der Gewebefäden, verstärkt und die Abstützungspunkte im Bereich der Kreuzungspunkte vergrößert. Es sind jedoch auch Verfahren zum gezielten Abscheiden nur in einer Richtung, senkrecht zur Fläche des Gewebes bekannt. So wird gemäß der
Ein Komplettverfahren zur Herstellung solcher Siebmaterialien ist beispielsweise in der
Aus dem Stand der Technik ist bekannt, dass rostfreie Stahlgewebe, z.B. für den Rotationssiebdruck mittels galvanischer Verfahren metallisiert werden.It is known from the prior art that stainless steel fabrics, e.g. be metallized for the rotary screen printing by means of galvanic processes.
Stand der Technik für die Vernickelung ist, dass dabei vorzugsweise Sulphamat-Nickelbäder oder Chemisch-Nickel Verfahren (außenstromlos) eingesetzt werden. Der Vorteil dieser Verfahren ist eine gleichmäßige geometrische Schichtverteilung in allen räumlichen Ebenen. Der Nachteil dieser Verfahren liegt darin, dass im Kreuzungspunkt eine sogenannte Winkelschwäche, nachfolgend auch als Hinterschnitt bezeichnet, entsteht. Der Hinterschnitt hat die Eigenschaft, dass das Strömungsverhalten, z.B. bei Reinigungsprozessen und von Farbe im Druck, und auch die Stabilität des metallisierten Gewebes nachteilig beeinflusst werden.The state of the art for nickel plating is that preferably sulphamate nickel baths or chemical nickel processes (external powerless) are used. Of the The advantage of this method is a uniform geometric layer distribution in all spatial planes. The disadvantage of this method is that at the crossing point a so-called angle weakness, hereinafter also referred to as an undercut, arises. The undercut has the property that the flow behavior, for example in cleaning processes and of ink in the print, as well as the stability of the metallized fabric are adversely affected.
Weiter bekannt ist, dass Mehrfachnickelschichten als Korrosionsschutz und / oder zu dekorativen Zwecken mit Wattschen Nickelsulphatelektrolyten abgeschieden werden. Diese Verfahren können in einem breiten Anwendungsspektrum zum veredeln diversester Bauteile in unterschiedlichen Branchen angewandt werden.It is also known that multiple nickel layers are deposited as corrosion protection and / or for decorative purposes with Watt's nickel sulphate electrolytes. These methods can be applied in a wide range of applications for refining various components in different industries.
Den Wattschen Nickelsulphatbädern werden verschiedenartigste, bevorzugt organische Zusätze beigegeben. Die Zusätze werden unterteilt in Glanzzusätze (sog. Glanzträger) erster (primäre) und zweiter (sekundäre) Klasse. Primäre Glanzträger, welche nebenbei auch Eigenschaften von Glanzträgern zweiter Klasse haben können, werden eingesetzt um eine homogene Metallabscheidung mit einem spezifischen Grundglanz über einen möglichst großen Stromdichtebereich zu erzielen. Sekundäre Glanzträger beeinflussen im großen Maß Einebnungsverhalten und Glanzgrad.The Watt's nickel sulphate baths are mixed with a wide variety of, preferably organic, additives. The additives are subdivided into gloss additives (so-called glossy carrier) first (primary) and second (secondary) class. Primary glossy supports, which incidentally may also have properties of second-class luster carriers, are used to achieve homogeneous metal deposition with a specific base luster over as wide a current density range as possible. Secondary glosses have a large influence on the leveling and gloss level.
Desweiteren haben die Glanzträger erster und zweiter Klasse in Kombination noch andere Auswirkungen auf die abgeschiedene Nickelschicht: Glanz, Duktilität, Härte, Einebnungsverhalten und elektrochemisches Potential der abgeschiedenen Schichten untereinander.Furthermore, the first and second class gloss supports have, in combination, other effects on the deposited nickel layer: gloss, ductility, hardness, flattening behavior and electrochemical potential of the deposited layers with each other.
Auf dem Markt erhältliche Mixturen organischer Zusätze müssen eine Vielzahl von technischen Anforderungen erfüllen. Diese Mixturen und Nickelbäder sind im Wesentlichen auf die Metallisierung von Stückgut in Trommelanlagen abgestimmt.Mixtures of organic additives available on the market must meet a variety of technical requirements. These mixtures and nickel baths are mainly adapted to the metallization of general cargo in drum systems.
Für die Vernicklung von Gewebe können diese Bäder in Reel to Reel Anlagen (Rolle-zu-Rolle) nur beschränkt eingesetzt werden. Üblich bei der Metallisierung ist, dass die zu veredelnde Oberfläche während dem Metallisierungsprozess der Anode zugewandt wird (z.B. in Trommelanlagen durch Drehen).For the nickel-plating of tissue, these baths can only be used to a limited extent in Reel to Reel systems (roll-to-roll). A common feature of metallization is that the surface to be refined faces the anode during the metallization process (eg in drum systems by turning).
Dies ermöglicht in Kombination mit der Beigabe von Zusätzen eine gleichmäßige Schichtverteilung.This, in combination with the addition of additives, allows a uniform layer distribution.
In einer Reel to Reel Anlage könnte dies theoretisch durch eine Bandführung zwischen zwei Anoden erzielt werden. Gewebe, insbesondere Feinstgewebe, hat jedoch die Eigenschaft, sich auf Grund von Stromeinspeisung und seiner geringen Masse extrem schnell auszudehnen, was zu Wellenbildung und inneren Spannungen führt. Zudem sind die oben aufgeführten Mixturen so abgestimmt, dass entweder ein Hinterschnitt im Kreuzungspunkt bestehen bleibt oder die Maschenöffnungen zu stark Verschließen.In a reel to reel system, this could theoretically be achieved by a tape guide between two anodes. Tissue, in particular micro-fabric, however, has the property of expanding extremely rapidly due to power supply and its low mass, which leads to wave formation and internal stresses. In addition, the mixtures listed above are tuned so that either an undercut remains in the crossing point or close the mesh openings too much.
Um die Stabilität des Siebmaterials sicherzustellen wird eine engmaschige Struktur mit vielen Abstützpunkten gewählt. Diese aus dem Stand der Technik bekannten Siebmaterialien und Siebe weisen folgende Nachteile auf:
In den Kreuzungspunkten der Gewebefäden liegen Winkelschwächen, also Hinterschnitte vor. In anderen Worten: Die Stabilität von gewebten Sieben wird durch die Kerbwirkung im Bereich der Kreuzungspunkte der Gewebefäden beschränkt.In order to ensure the stability of the screening material, a close-meshed structure with many support points is chosen. These screen materials and screens known from the prior art have the following disadvantages:
In the crossing points of the fabric threads are angle weaknesses, ie undercuts. In other words, the stability of woven fabrics is limited by the notch effect in the region of the crossing points of the fabric threads.
Ein verstärktes Beschichten durch den allgemein bekannten galvanischen Beschichtungsprozess ist keine Lösung, da die Öffnungen des Gewebes dabei zuwachsen und es beim Einsatz im Siebdruck zum Verstopfen der Öffnungen durch Farbpartikel kommen kann. Dies beeinträchtigt dann die Druckqualität.Increased coating by the well-known galvanic coating process is not a solution, since the openings of the tissue grow in the process and when used by screen printing, clogging of the openings by color particles can occur. This will affect the print quality.
Aufgabe der vorliegenden Erfindung ist es daher, ein Siebmaterial und ein Sieb zu schaffen, welche die Nachteile der aus dem Stand der Technik bekannten Siebmaterialien und Siebe nicht aufweisen und besonders für den rotativen Siebdruck geeignet sind. Die Siebmaterialien, insbesondere Stahlgewebe, sollten für die Anwendung im rotativen Siebdruck eine höhere Stabilität und eine größere Lebensdauer aufweisen.The object of the present invention is therefore to provide a sieve material and a sieve which do not have the disadvantages of the screening materials and sieves known from the prior art and which are particularly suitable for rotary screen printing. The screen materials, in particular steel mesh, should have a higher stability and a longer service life for use in rotary screen printing.
Gelöst wird diese Aufgabe durch ein Siebmaterial mit den Merkmalen von Anspruch 1 und durch ein Sieb mit den Merkmalen von Anspruch 8. Diese sind besonders vorteilhaft, da sie den spezifischen Anforderungen des rotativen Siebdrucks Rechnung tragen und eine größere Stabilität im Vergleich zu herkömmlichen Siebmaterialien und Sieben aufweisen. Das erfindungsgemäße flächige Siebmaterial dient der Anwendung im Siebdruck, insbesondere im Rotationssiebdruck. Das Siebmaterial besitzt winklig zueinander angeordnete und sich in Kreuzungspunkten kreuzende Stränge, welche eine gewebte Siebstruktur bilden, wobei die Erfindung unabhängig ist von der Webart und der Maschenform. In den Kreuzungspunkten bilden die Stränge Hinterschnitte, wobei unter Hinterschnitten die Innenkanten von angrenzenden Oberflächen der sich kreuzenden Stränge verstanden werden, beispielsweise von Kettfäden und Schussfäden. Diese weisen somit eine Winkelschwäche auf, welche auch als Innenkantenschwäche bezeichnet wird. Die Stränge sind dabei so angeordnet, dass eine Siebstruktur mit Öffnungen gebildet wird. Überall an ihren Oberflächen besitzen die Stränge einen Überzug in etwa konstanter Dicke aus Metall, insbesondere aus Nickel, welcher in einem Galvanisierungsprozess auf den Strängen abgeschieden wurde. Erfindungsgemäß ist das flächige Siebmaterial derart ausgeführt, dass im Bereich von Kreuzungspunkten der Stränge deren Hinterschnitte zusätzlich zu dem Überzug zumindest teilweise eine in einem Galvanisierungsprozess aufgebrachte Auffüllung aus dem Metall besitzen. In anderen Worten: durch den Galvanisierungsprozess wurden die Hinterschnitte reduziert, bzw. beseitigt, indem zusätzliches Metall gezielt im Bereich der Hinterschnitte abgeschieden wurde. Dadurch entsteht eine Oberfläche ohne scharfe Kanten und ohne Fasen.This object is achieved by a sieve material with the features of
Ein derartiges flächiges Siebmaterial hat den Vorteil, dass durch die metallischen Auffüllungen beim Einsatz des Siebmaterials für den Siebdruck Strömungswiderstände und Turbulenzen reduziert werden, was zu einem besseren Fließverhalten der Farbe führt. Weiterhin kann keine Druckfarbe in dem Hinterschnitt eintrocknen. Auch wird er Reinigungsprozess weiter vereinfacht, da eine direkte Anströmung mit Reinigungsflüssigkeit ermöglicht wird, was zu einer kürzeren Reinigungszeit und einem geringeren Verbrauch an Reinigungsflüssigkeit beiträgt. Ein weiterer Vorteil ist die vergrößerte Stabilität des flächigen Siebmaterials, da die Kerbwirkung der Hinterschnitte durch die metallische Auffüllung reduziert wird.Such a flat screen material has the advantage that flow resistances and turbulences are reduced by the metallic fillings when using the screen material for the screen printing, which leads to a better flow behavior of the paint. Furthermore, no ink can dry in the undercut. It also further simplifies the cleaning process by permitting a direct flow of cleaning fluid, which contributes to a shorter cleaning time and a lower consumption of cleaning fluid. Another advantage is the increased stability of the flat screen material, since the notch effect of the undercuts is reduced by the metallic filling.
In einer besonders vorteilhaften und daher bevorzugten Weiterbildung des erfindungsgemäßen Siebmaterials bildet eine jeweilige Auffüllung einen Innenkanten-Übergang mit Rundung. Die Metallauffüllung ist also derart ausgeführt, dass im Bereich der Hinterschnitte keine scharfen Kanten oder Fasen vorliegen. Besonders vorteilhaft ist es, wenn die Auffüllungen einen Radius von mindestens 1 µm oder von mindestens einem Zehntel des mittleren Radius der Stränge (Mittelwert aus Radius Kettfaden und Radius Schussfaden) aufweisen. Dadurch wird sichergestellt, dass bei den Anwendungen im Siebdruck die Farbe das Siebmaterial problemlos durchfließen kann und es keine wesentlichen Ablagerungen im Bereich der Hinterschnitte gibt, das Siebmaterial gut zu reinigen ist und dabei eine hohe Stabilität aufweist.In a particularly advantageous and therefore preferred development of the screening material according to the invention, a respective filling forms an inner edge transition with a rounding. The metal filling is thus designed so that there are no sharp edges or chamfers in the area of the undercuts. It is particularly advantageous if the fillings have a radius of at least 1 μm or at least one tenth of the mean radius of the strands (mean value of radius warp thread and radius weft thread). This ensures that in screen-printing applications, the ink can easily flow through the screen material and there are no significant deposits in the area of the undercuts, and the screen material is easy to clean, with high stability.
In einer ersten erfindungsgemäßen Ausführungsvariante des erfindungsgemäßen flächigen Siebmaterials beschreibt eine Kurve entlang der Oberfläche des Siebmaterials - in einer Schnittebene senkrecht zum Siebmaterial und durch einen der Stränge betrachtet - eine glatte Kurve. Unter einer glatten Kurve wird dabei eine glatte Kurve im mathematischen Sinn verstanden, d.h. eine Kurve, welche stetig ist und differenzierbar, also eine Kurve ohne Ecken oder abrupte Wendungen.In a first variant of the inventive planar sieve material according to the invention, a curve along the surface of the sieve material - viewed in a sectional plane perpendicular to the sieve material and viewed through one of the strands - describes a smooth curve. A smooth curve is understood to mean a smooth curve in the mathematical sense, i. a curve that is continuous and differentiable, ie a curve without corners or abrupt turns.
In einer zweiten erfindungsgemäßen Ausführungsvariante des erfindungsgemäßen flächigen Siebmaterials beschreibt eine Kurve entlang der Oberfläche des Siebmaterials - in einer Schnittebene parallel zum Siebmaterial und durch alle Stränge betrachtet - eine glatte Kurve. Unter einer glatten Kurve wird dabei eine glatte Kurve im mathematischen Sinn verstanden, d.h. eine Kurve, welche stetig und differenzierbar ist, d.h. eine Kurve ohne Ecken oder abrupte Wendungen. Für die erste Variante besitzen die Hinterschnitte an der Oberseite und/oder an der Unterseite des Siebmaterials jeweils eine metallische Auffüllung. Für die zweite Variante hingegen besitzen die Hinterschnitte in der Ebene des Siebmaterials jeweils eine metallische Auffüllung. In einer vorteilhaften erfindungsgemäßen Weiterbildung werden beide erfindungsgemäße Ausführungsvarianten miteinander kombiniert, so dass ein besonders stabiles und durchflussoptimiertes flächiges Siebmaterial gebildet wird.In a second variant of the inventive planar sieve material according to the invention, a curve along the surface of the sieve material - in a sectional plane parallel to the sieve material and viewed through all the strands - describes a smooth curve. A smooth curve is understood to be a smooth curve in the mathematical sense, ie a curve which is continuous and differentiable, ie a curve without corners or abrupt turns. For the first variant, the undercuts at the top and / or at the bottom of the screen material each have a metallic padding. For the second variant, however, the undercuts in the plane of the screen material each have a metallic filling. In an advantageous development of the invention, both embodiments of the invention are combined with each other, so that a particularly stable and flow-optimized planar sieve material is formed.
In vorteilhafter Weiterbildung des flächigen Siebmaterials mit glatten Kurven zwischen zwei Kreuzungspunkten weist die Kurve entlang der Oberfläche des Siebmaterials zweiIn an advantageous embodiment of the flat screen material with smooth curves between two crossing points, the curve along the surface of the screen material has two
Wendepunkte auf, wobei die Wendepunkte die Auffüllung begrenzen. Unter einem Wendepunkt wird dabei ein Wendepunkt im mathematischen Sinn verstanden, d.h. ein Punkt auf der Oberflächenkurve, in welchem ein Vorzeichenwechsel der zweiten Ableitung stattfindet. Die Wendepunkte können dabei insbesondere einen Abstand voneinander von mindestens 1 µm und maximal einen Abstand aufweisen, welcher der Teilung entspricht. Mit Teilung wird der Abstand der Mittelachsen zweier benachbarter, zueinander paralleler Stränge bezeichnet. Insbesondere sind die Wendepunkte jedoch 10 bis 20 µm voneinander beabstandet. Auffüllungen, welche in diesen Bereich fallen, sind einerseits fertigungstechnisch gut herstellbar und erfüllen andererseits die Erwartungen an eine höhere Stabilität und an bessere Durchflusseigenschaften des flächigen Siebmaterials.Turning points on, with the turning points limit the replenishment. By a turning point is meant a turning point in the mathematical sense, i. a point on the surface curve in which a sign change of the second derivative takes place. The turning points may in particular have a distance from each other of at least 1 micron and a maximum of a distance corresponding to the pitch. By division, the distance between the center axes of two adjacent, mutually parallel strands is called. In particular, however, the inflection points are 10 to 20 microns apart. Fillings that fall into this area, on the one hand production technology well produced and meet the other hand, the expectations of higher stability and better flow properties of the sheet material.
In einer nicht erfindungsgemäßen, alternativen Ausführungsform zur Auffüllung mit Rundung wird eine parabelförmige Auffüllung vorgesehen, welche jeweils selbst einen Hinterschnitt aufweist. Bei der parabelförmigen Auffüllung wird das Siebmaterial im Bereich eines jeweiligen Hinterschnitts besonders stark aufgefüllt und verstärkt.In a non-inventive, alternative embodiment for filling with rounding a parabolic filling is provided, which in each case has an undercut itself. In the case of the parabolic filling, the sieve material in the region of a respective undercut is filled up to a particularly high degree and reinforced.
In einer weiteren alternativen Ausführungsform sind die Auffüllungen derart ausgestaltet, dass die Oberflächen der Auffüllungen an der Oberfläche und/ an der Unterseite des Siebmaterials jeweils nahezu in einer Ebene liegen. In anderen Worten: die metallische Auffüllung bewirkt, dass die Stränge komplett in die metallische Auffüllung eingebettet sind.In a further alternative embodiment, the fillings are designed in such a way that the surfaces of the fillings on the surface and / or on the underside of the sieve material are in each case almost in one plane. In other words, the metal fill causes the strands to be completely embedded in the metallic padding.
In Weiterbildung dieses oder der zuvor beschriebenen Siebmaterialien weist das Siebmaterial eine in einem Kalandrierprozess verdünnte Siebstruktur mit kalandrierten Flächen auf. Unter einem Kalandrierprozess, auch als Kalanderprozess bezeichnet, wird dabei ein in der Regel walzender Vorgang verstanden, welcher eine Abplattung der Siebstruktur bewirkt.In a further development of this or of the screen materials described above, the screen material has a screen structure with calendered surfaces that has been diluted in a calendering process. A calendering process, also referred to as a calendering process, is understood to mean a process which generally rolls and which causes a flattening of the sieve structure.
Ein solcher Kalandrierprozess wird beispielsweise in der
Das flächige Siebmaterial wird durch ein Gewebe gebildet, z. B. durch ein Kunststoffgewebe oder ein Metalldrahtgewebe. Die Struktur hat die Form von sogenannten Maschen, z. B. von Rechteckmaschen oder Quadratmaschen.The flat screen material is formed by a tissue, for. B. by a plastic fabric or a metal wire mesh. The structure has the form of so-called meshes, e.g. B. of rectangular mesh or square mesh.
Die Stränge bestehen an ihren Oberflächen aus Metall, wobei Nickel besonders vorteilhaft und daher bevorzugt ist. Das Metall wurde in einem Galvanisierungsprozess auf den Strängen abgeschieden.The strands are made of metal at their surfaces, with nickel being particularly advantageous and therefore preferred. The metal was deposited on the strands in a galvanization process.
Zur Herstellung des obenstehend beschriebenen erfindungsgemäßen Siebmaterials wird bevorzugt eine Gewebestruktur mit einer oder mehreren insbesondere nickelhaltigen Schichten aus nur einem Elektrolytbad metallisiert, wobei dem Elektrolytbad zur Verstärkung der Kreuzungspunkte gezielt organische Zusätze beigegeben werden können. Die Ausbildung der Nickelschicht wird weiter beeinflusst indem das Gewebe an der anodenabgewandten Gewebeseite an nichtleitenden Körpern, also Isolatoren, vorbeibewegt wird, welche das Feld verändern und damit die Nickelabscheidung beeinflussen. Während der Vorbeibewegung liegt die Gewebestruktur auf dem Isolator auf. Auch können die Anoden so angeordnet sein, dass diese über ihre Erstreckung einen unterschiedlichen Abstand zum Gewebe haben. Damit kann die Nickelschichtverteilung in den Kreuzungspunkten auf Vorder- und Rückseite des Gewebes optimiert werden. Als Anoden können dabei depolarisierte Reinnickelplatten oder Nickelpellets in Körben eingesetzt werden.To produce the sieve material according to the invention described above, a fabric structure with one or more, in particular nickel-containing, layers of only one electrolyte bath is preferably metallized, it being possible to purposefully add organic additives to the electrolyte bath to reinforce the crossing points. The formation of the nickel layer is further influenced by the tissue is moved past the non-anode side of the fabric on non-conductive bodies, ie insulators, which change the field and thus influence the nickel deposition. During the passage, the fabric structure rests on the insulator. Also, the anodes can be arranged so that they have a different distance to the tissue over their extent. Thus, the nickel layer distribution in the crossing points on the front and back of the fabric can be optimized. As anodes, depolarized pure nickel plates or nickel pellets can be used in baskets.
Mittels einem derartigen Verfahren und der Kombination von aufliegenden Vernicklungsprozess , spezifische Dosierung von Glanzbildnern erster und zweiter Klasse sowie gezielter Anströmung durch das Elektrolyt können die Stromlinien des elektrischen Feldes so beeinflusst werden, dass auf der anodenabgewandten Gewebeseite in den Kreuzungspunkten gezielt mehr Nickel abgeschieden werden kann.By means of such a method and the combination of overlying nickel plating process, specific dosage of brighteners first and second class and targeted flow through the electrolyte, the electric field current lines can be influenced so that specifically more nickel can be deposited on the anode-facing side of the fabric in the crossing points.
Dadurch kann weiterhin erreicht werden, dass ein einzelner Strang des Gewebes exzentrisch vernickelt wird, wobei auch hier auf der anodenabgewandten Seite eine stärkere Beschichtung erfolgt.As a result, it can furthermore be achieved that a single strand of the fabric is nickel-plated eccentrically, with a stronger coating also taking place here on the side facing away from the anode.
Bei idealer Abstimmung aller Komponenten kann die Beschichtung in einem einzigen Prozessschritt erfolgen. Dies ist insbesondere beim Aufbringen von dünnen Nickelschichten von wenigen Mikrometern vorteilhaft.With ideal coordination of all components, the coating can be carried out in a single process step. This is particularly advantageous when applying thin nickel layers of a few micrometers.
Müssen dickere Schichten über 2 µm abgeschieden werden, so ist es von Vorteil den Schichtauftrag in mehrere Prozessschritte zu unterteilen, wobei jedoch auf unterschiedliche Elektrolytbäder verzichtet werden kann.If thicker layers over 2 microns must be deposited, so it is advantageous to Subdivide layer order into several process steps, but can be dispensed with different electrolyte baths.
Zwischen der Abscheidung der einzelnen Nickelschichten kann das Gewebe zwischengereinigt werden.Between the deposition of the individual nickel layers, the tissue can be cleaned between.
Die Erfindung betrifft auch ein Sieb für den Rotationssiebdruck, welches aus einem flächigen Siebmaterial, wie oben beschrieben, hergestellt ist und wobei das Sieb die Form einer zylindrischen Hülse besitzt.The invention also relates to a screen for rotary screen printing, which is made of a flat screen material, as described above, and wherein the screen has the shape of a cylindrical sleeve.
In einer vorteilhaften Weiterbildung des erfindungsgemäßen Siebs ist das flächige Siebmaterial einseitig mit einer Polymerschicht, insbesondere mit einer Fotopolymerschicht, versehen, sodass eine Bebilderung nach dem Fachmann bekannten Verfahren ermöglicht wird.In an advantageous development of the sieve according to the invention, the planar sieve material is provided on one side with a polymer layer, in particular with a photopolymer layer, so that imaging is made possible by methods known to the person skilled in the art.
Die beschriebene Erfindung und die beschriebenen vorteilhaften Weiterbildungen der Erfindung stellen auch in beliebiger Kombination miteinander vorteilhafte Weiterbildungen der Erfindung dar.The described invention and the described advantageous developments of the invention are also in any combination with each other advantageous developments of the invention.
Hinsichtlich weiterer Vorteile und in konstruktiver und funktioneller Hinsicht vorteilhafter Ausgestaltungen der Erfindung wird auf die Unteransprüche sowie die Beschreibung von Ausführungsbeispielen unter Bezugnahme auf die beiliegenden Zeichnungen verwiesen.With regard to further advantages and constructive and functional aspects of advantageous embodiments of the invention, reference is made to the dependent claims and the description of embodiments with reference to the accompanying drawings.
Die Erfindung soll an Hand eines Ausführungsbeispiels noch näher erläutert werden. Es zeigen in schematischer Darstellung
- Fig.1
- ein erfindungsgemäße Sieb
- Fig. 2a
- ein Siebmaterial vor Vernickelung
- Fig. 2b
- ein Siebmaterial nach Vernickelung
- Fig. 3a
- eine Schnittdarstellung mit einem Schnitt senkrecht zum Siebmaterial
- Fig. 3b
- eine Detaildarstellung der
Fig. 3a - Fig. 3c
- eine Detaildarstellung der
Fig. 3a vor Auffüllung - Fig. 4a
- Alternative Auffüllungen der Hinterschnitte
- Fig. 4b
- Auffüllungen der Hinterschnitte eines kalandrierten Gewebes
- Fig. 5
- eine Schnittdarstellung mit einem Schnitt in der Ebene des Siebmaterials
- Fig. 6
- ein Sieb für den Rotationssiebdruck
- Fig.1
- a sieve according to the invention
- Fig. 2a
- a screen material before nickel plating
- Fig. 2b
- a screen material after nickel plating
- Fig. 3a
- a sectional view with a section perpendicular to the screen material
- Fig. 3b
- a detailed view of the
Fig. 3a - Fig. 3c
- a detailed view of the
Fig. 3a before replenishment - Fig. 4a
- Alternative fillings of the undercuts
- Fig. 4b
- Fillings of the undercuts of a calendered fabric
- Fig. 5
- a sectional view with a section in the plane of the screen material
- Fig. 6
- a screen for rotary screen printing
Einander entsprechende Elemente und Bauteile sind in den Figuren mit gleichen Bezugszeichen versehen.Corresponding elements and components are provided in the figures with the same reference numerals.
Nachfolgend wird beispielhaft ein Verfahren zu Herstellung des erfindungsgemäßen Siebmaterials 1 und beispielhaft eine erforderlichen Badzusammensetzung beschrieben. Es wird dabei davon ausgegangen, dass bei der Galvanisierung Nickel 3 auf die Gewebestruktur 5 aufgebracht werden soll.In the following, a method for producing the
Als Basis zur Vernicklung kann ein Wattsches Nickelelektrolytbad dienen, welchem vorzugsweise primäre und sekundäre Glanzmittel zugegeben werden:
- Nickel 60 - 90 g/l
- Chlorid 12 - 45 g/l
- Borsäure 30 - 50 g/l
- Badtemperatur 45 - 70°C,
- pH Wert 3.5 bis 4.8,
- Nickel 60 - 90 g / l
- Chloride 12-45 g / l
- Boric acid 30 - 50 g / l
- Bath temperature 45 - 70 ° C,
- pH value 3.5 to 4.8,
Zur Abscheidung werden vorzugsweise Glanzzusätze zugegeben, sogenannte Sekundärglanzbildner, wie z.B. Butindiolderivate, quarternäre Pyridiniumderivate, Propargylalkohol, Propynolpropoxylate, insbesondere Butindiol, sowie Primärglanzbildner wie z.B. Benzolsulfonsäuren, Alkylsulfonsäuren, Alylsulfonsäuren, Sulfonimide, Sulfonamide oder Benzoesäuresulfimid.For deposition, brightener additives are preferably added, so-called secondary luster agents, e.g. Butynediol derivatives, quaternary pyridinium derivatives, propargyl alcohol, propynol propoxylates, especially butynediol, and primary brighteners, e.g. Benzenesulfonic acids, alkylsulfonic acids, Alylsulfonsäuren, sulfonimides, sulfonamides or Benzoesäuresulfimid.
Sekundäre Glanzmittel werden bei dieser Anwendung zur definierten Verstärkung der Kreuzungspunkte 10 eingesetzt, wobei diese je nach gewünschter Verstärkung in einem Gehalt von 0 bis 0.15 g/l, primäre Glanzmittel zwischen 0 und 8 g/l zugegeben werden.Secondary brighteners are used in this application for the defined reinforcement of the crossing points 10, these being added depending on the desired reinforcement in a content of 0 to 0.15 g / l, primary brightener between 0 and 8 g / l.
Die wie in der Galvanotechnik üblich vorbehandelte Gewebestruktur 5 wird mit dem oben beschriebenen Bad vernickelt.The
Das Gewebe 5 wird im Nickelbad über eine elektrische nichtleitende Auflagefläche transportiert.The
Die elektrisch nichtleitende Auflagefläche kann quer zur Transportrichtung des Gewebes 5 mit Segmenten versehen werden, welche im Betrieb ebenfalls mit Elektrolyt befüllt sind und einen permanenten Elektrolytaustausch sicherstellen.The electrically non-conductive support surface can be provided transversely to the transport direction of the
Auf der aufliegenden Fläche wird durch nichtvorhandenen Elektrolyt die Nickelabscheidung 3 behindert.On the surface lying on the
Durch entsprechende Zugabe von Sekundärem Glanzträger konzentriert sich die Metallabscheidung 3 zusätzlich gezielt in die Kreuzungspunkte 10.By appropriate addition of secondary gloss support, the
In der mit Segmenten versehenen Zone findet eine Abscheidung auch auf der Geweberückseite statt. Durch eine geschickte Verteilung der Segmente zur aufliegenden Fläche, kombiniert mit der entsprechenden Menge an Sekundärem Glanzträger kann die Nickelabscheidung 3 auf die Kreuzungspunkte oder die gesamte Rückseite verteilt erfolgen.In the segmented zone, deposition also takes place on the back of the fabric. By a clever distribution of the segments to the resting surface, combined with the corresponding amount of secondary gloss carrier, the
Durch eine ideale Elektrolytströmung zwischen Anode und der Gewebestruktur als Katode wird anodenseitig die Abscheidungsgeschwindigkeit auf dem Gewebe reduziert. Es hat sich bei dieser Anordnung gezeigt, dass eine verstärkte Abscheidung auf der anodenabgewandten Seite erfolgen kann.Due to an ideal electrolyte flow between the anode and the tissue structure as the cathode, the deposition rate on the tissue is reduced on the anode side. It has been shown in this arrangement that an increased deposition can take place on the side facing away from the anode.
Ein idealer Anodenabstand liegt zwischen 1 cm und 40 cm zur Katode. Dieser Abstand ist insofern von Vorteil, da das Gewebe 5 noch genügend stark mit frischem Elektrolyt angeströmt werden kann, die elektrischen Spannungsverluste durch den erhöhten Anodenabstand jedoch auf einem erträglichen Niveau bleiben.An ideal anode distance is between 1 cm and 40 cm to the cathode. This distance is advantageous in that the
Die Vernicklung kann grundsätzlich in einer einzigen Nickelzelle erfolgen. Es ist jedoch auch denkbar mehrere Nickelzellen, hintereinander anzuordnen.The nickel plating can basically take place in a single nickel cell. However, it is also conceivable to arrange several nickel cells one behind the other.
In
In
In
In der Detaildarstellung von
In
Gemäß der Alternative ii wurde eine besonders starke galvanische Beschichtung aufgebracht zur Auffüllung 12 des Hinterschnitts 11. Die Auffüllung 12 ist dabei so umfangreich, dass die Oberfläche der Auffüllung 12 in einer Ebene 30 liegt und die Kettfäden 5.1 und die Schussfäden 5.2 komplett in die Metallbeschichtung 3, 12 eingebettet sind. Dadurch wird ein flächiges Siebmaterial 1 geschaffen, welches eine ebene Oberfläche besitzt, welche in der Ebene 30 liegt.According to the alternative ii, a particularly strong galvanic coating was applied to fill 12 of the undercut 11. The
Auch gemäß der Variante iii wurde der Hinterschnitt 11 mit einer besonders starken Auffüllung 12 versehen. Wie auch bereits anhand von
Die Beschichtungsalternative iv kann alternativ oder in Kombination mit den zuvor beschriebenen Beschichtungsalternativen genutzt werden. Dabei erfolgt im Bereich eines jeweiligen Kettfadens 5.1 bzw. Schussfadens 5.2 eine verstärkte Metallbeschichtung 3, so dass die Metallbeschichtung 3 einseitig eine besonders hohe Schichtdicke aufweist, d.h., dass die Beschichtung exzentrisch aufgetragen wird.The coating alternative iv can be used alternatively or in combination with the previously described coating alternatives. In this case, in the region of a respective warp thread 5.1 or weft thread 5.2, a reinforced
In
In
- 11
- Flächiges SiebmaterialFlat screen material
- 22
- Polymerbeschichtungpolymer coating
- 33
- Metallbeschichtung (z.B. Nickel)Metal coating (e.g., nickel)
- 44
- Sieb in zylindrischer HülsenformSieve in cylindrical sleeve shape
- 55
- Strangstrand
- 5.15.1
- Kettfadenwarp
- 5.25.2
- Schussfadenweft
- 5.35.3
- kalandrierte Flächecalendered area
- 66
- Öffnungopening
- 1010
- Kreuzungspunktintersection
- 1111
- Hinterschnittundercut
- 1212
- Auffüllung (gezielte Abscheidung)Replenishment (targeted separation)
- 12.112.1
- Innenkantenübergang mit RundungInner edge transition with rounding
- 2020
- neutrale Faser durch Drahtlängsschnittneutral fiber by wire-cutting
- 2121
- Teilungdivision
- 2222
- Wendepunktturning point
- 2323
- Abstand WendepunkteDistance turning points
- 2424
- AuffüllstärkeAuffüllstärke
- 2525
- Radiusradius
- 2626
- Radius KettfadenRadius warp thread
- 2727
- Radius SchussfadenRadius weft
- 2828
- Oberseitetop
- 2929
- Unterseitebottom
- 3030
- Ebenelevel
- i, ii, iii, ivi, ii, iii, iv
- Alternative galvanische BeschichtungenAlternative galvanic coatings
- x,y,zx, y, z
- Achsen eines KoordinatensystemsAxes of a coordinate system
- a,b,cABC
- Schichtdicken der MetallbeschichtungLayer thickness of the metal coating
- UU
- Rotation des SiebsRotation of the sieve
Claims (8)
- Flat screen material (1) for use in screen printing, in particular in rotary screen printing, including threads (5, 5.1, 5.2) forming a woven screen structure, arranged at angles relative to one another, and intersecting at intersections (10) where said threads (5, 5.1, 5.2) form undercuts (11), said threads forming a screen structure with openings and the surfaces of said threads (5, 5.1, 5.2) having a coating of approximately constant thickness and made of a metal (3), in particular nickel, that has been deposited on the threads (5, 5.1, 5.2) in an electroplating process,
wherein in the region of intersections of the threads (5, 5.1, 5.2), in addition to the coating, the undercuts (11) at least partly have a filling (12) made of the metal and applied in the electroplating process, and
wherein the respective filling (12) does not have any sharp edges and ridges on its surface,
characterized in
that - as viewed in a section plane (xz, xy) perpendicular to the screen material (1) and through one of the threads (5, 5.1, 5.2) - a curve along the surface of the screen material (1) describes a smooth curve and/or that - as viewed in a section plane (xy) parallel with the screen material (1) and through all threads (5, 5.1, 5.2) - a curve along the surface of the screen material (1) describes a smooth curve. - Flat screen material according to claim 1,
characterized in
that a respective filling (12) forms an inner edge transition with a rounding (12.1). - Flat screen material according to any one of the preceding claims,
characterized in
that the filling (12) has a radius (25) of at least 1 µm or of 1/10 of the average radius (26, 27) of the threads (5, 5.1, 5.2). - Flat screen material according to any one of the preceding claims,
characterized in
that between two intersections (10), the curve along the surface of the screen material (1) has two (22) inflection points, said inflection points (22) limiting the filling (12). - Flat screen material according to claim 4,
characterized in
that the inflection points (22) are spaced apart from one another by a distance (23) of 1 µm at the minimum and of the pitch (21) at the maximum, preferably of 10 to 20 µm. - Flat screen material according to any one of the preceding claims,
characterized in
that the undercuts (11) have a respective filling (12) at the top side (28) and/or at the bottom side (29) of the screen material (1) and/or in the plane (xy) of the screen material (1). - Flat screen material according to any one of the preceding claims,
characterized in
that the surfaces of the filling (12) at the top side (28) and/or at the bottom side (29) of the screen material (1) respectively are (ii) approximately in one plane (30) and/or that the screen material (1) has a screen structure (1) that has been thinned in a calendering process. - Screen (4) for rotary screen printing made of a flat screen material (1) according to at least one of claims 1 to 7, wherein the screen has the form of a cylindrical sleeve and wherein the flat screen material (1), in particular one side thereof, is coated with a polymer layer (2), e.g. a photopolymer layer.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012011901A DE102012011901A1 (en) | 2012-06-14 | 2012-06-14 | Flat screen material and sieve |
PCT/EP2013/001723 WO2013185916A2 (en) | 2012-06-14 | 2013-06-12 | Flat screen material and screen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2879882A2 EP2879882A2 (en) | 2015-06-10 |
EP2879882B1 true EP2879882B1 (en) | 2018-12-19 |
Family
ID=48626407
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13728975.7A Active EP2879882B1 (en) | 2012-06-14 | 2013-06-12 | Flat screen material and screen |
Country Status (8)
Country | Link |
---|---|
US (1) | US9333740B2 (en) |
EP (1) | EP2879882B1 (en) |
JP (1) | JP6157604B2 (en) |
CN (1) | CN104364088B (en) |
DE (1) | DE102012011901A1 (en) |
DK (1) | DK2879882T3 (en) |
ES (1) | ES2711556T3 (en) |
WO (1) | WO2013185916A2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110214088A (en) * | 2016-12-06 | 2019-09-06 | 株式会社Nbc纱网技术 | Silk-screen plate and its manufacturing method |
CN108121862B (en) * | 2017-12-13 | 2021-04-27 | 武汉益模科技股份有限公司 | Automatic engineering drawing labeling method based on three-dimensional geometric features |
TWI759109B (en) * | 2021-02-18 | 2022-03-21 | 倉和股份有限公司 | Printing screen plate with graphics and method of making the same |
CN115008883B (en) * | 2021-03-05 | 2024-03-26 | 仓和精密制造(苏州)有限公司 | Printing screen plate matched with graph and manufacturing method |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3482300A (en) * | 1966-10-31 | 1969-12-09 | Screen Printing Systems Inc | Printing screen and method of making same |
US3759799A (en) * | 1971-08-10 | 1973-09-18 | Screen Printing Systems | Method of making a metal printing screen |
JPS5333933A (en) * | 1976-09-11 | 1978-03-30 | Kouji Doi | Method of producing mesh cylinder for rotary screennprint by aligning metallic filaments* etc* to cross one another and plating them to secure cross points |
JPS54156880A (en) * | 1978-05-04 | 1979-12-11 | Kenseido Kagaku Kogyo Kk | Production of sleeve for rotary screen printing |
JPS5613196A (en) * | 1979-07-05 | 1981-02-09 | Toshin Kogyo Kk | Seamless tubular screen for printing and production thereof |
NL8005427A (en) | 1980-09-30 | 1982-04-16 | Veco Beheer Bv | METHOD FOR MANUFACTURING SCREEN MATERIAL, SCREENING MATERIAL OBTAINED AND APPARATUS FOR CARRYING OUT THE METHOD |
DE3441593A1 (en) | 1984-11-14 | 1986-05-22 | Ferd. Rüesch AG, St. Gallen | METHOD AND DEVICE FOR PRODUCING SCREEN PRINTING FABRICS FOR SCREEN PRINTING CYLINDERS |
DE8511549U1 (en) * | 1985-04-18 | 1986-06-19 | Ferd. Rüesch AG, St. Gallen | Screen printing stencil |
DE4020046A1 (en) * | 1990-06-23 | 1992-01-09 | Messerschmitt Elmar | Screen for silk-screen printing - has straight longitudinal threads with transverse threads passing over and under them |
US5365840A (en) | 1990-10-03 | 1994-11-22 | Newman Donald E | Screen material for and method of screen printing |
ES2183401T3 (en) | 1997-10-14 | 2003-03-16 | Gallus Ferd Ruesch Ag | SERIGRAPHY MECHANISM. |
JP2005199604A (en) * | 2004-01-16 | 2005-07-28 | Ngk Insulators Ltd | Screen printing plate and method for manufacturing multiple layer film body using this screen printing plate |
JP2007210219A (en) * | 2006-02-10 | 2007-08-23 | Komori Corp | Plate material of rotary screen equipment and manufacturing method thereof |
NL2003627C2 (en) * | 2009-10-12 | 2011-04-13 | Stork Prints Bv | Screen printing. |
DE102010021062A1 (en) * | 2010-05-19 | 2011-11-24 | Gallus Ferd. Rüesch AG | Flat screen material and sieve |
-
2012
- 2012-06-14 DE DE102012011901A patent/DE102012011901A1/en active Pending
-
2013
- 2013-06-12 ES ES13728975T patent/ES2711556T3/en active Active
- 2013-06-12 CN CN201380031494.3A patent/CN104364088B/en active Active
- 2013-06-12 EP EP13728975.7A patent/EP2879882B1/en active Active
- 2013-06-12 WO PCT/EP2013/001723 patent/WO2013185916A2/en active Application Filing
- 2013-06-12 JP JP2015516507A patent/JP6157604B2/en active Active
- 2013-06-12 DK DK13728975.7T patent/DK2879882T3/en active
-
2014
- 2014-12-15 US US14/569,991 patent/US9333740B2/en active Active
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
WO2013185916A2 (en) | 2013-12-19 |
JP6157604B2 (en) | 2017-07-05 |
CN104364088A (en) | 2015-02-18 |
CN104364088B (en) | 2016-07-06 |
US9333740B2 (en) | 2016-05-10 |
WO2013185916A3 (en) | 2014-02-20 |
DE102012011901A1 (en) | 2013-12-19 |
US20150096451A1 (en) | 2015-04-09 |
ES2711556T3 (en) | 2019-05-06 |
EP2879882A2 (en) | 2015-06-10 |
JP2015527215A (en) | 2015-09-17 |
DK2879882T3 (en) | 2019-03-18 |
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