EP2802235B1 - Contenant en plastique pour un déodorant à bille - Google Patents

Contenant en plastique pour un déodorant à bille Download PDF

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Publication number
EP2802235B1
EP2802235B1 EP12797718.9A EP12797718A EP2802235B1 EP 2802235 B1 EP2802235 B1 EP 2802235B1 EP 12797718 A EP12797718 A EP 12797718A EP 2802235 B1 EP2802235 B1 EP 2802235B1
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EP
European Patent Office
Prior art keywords
plastic container
roll cage
roll
receptacle
deodorant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12797718.9A
Other languages
German (de)
English (en)
Other versions
EP2802235A1 (fr
Inventor
Johann KÜNZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alpla Werke Alwin Lehner GmbH and Co KG
Original Assignee
Alpla Werke Alwin Lehner GmbH and Co KG
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Filing date
Publication date
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Application filed by Alpla Werke Alwin Lehner GmbH and Co KG filed Critical Alpla Werke Alwin Lehner GmbH and Co KG
Priority to PL12797718T priority Critical patent/PL2802235T3/pl
Publication of EP2802235A1 publication Critical patent/EP2802235A1/fr
Application granted granted Critical
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Classifications

    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
    • A45D34/041—Appliances specially adapted for applying liquid, e.g. using roller or ball using a roller, a disc or a ball
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D33/00—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances
    • A45D33/02—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances with dispensing means, e.g. sprinkling means
    • A45D33/12—Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances with dispensing means, e.g. sprinkling means with rollers
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/26—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
    • A45D40/261—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball using a ball, a roller or the like
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball

Definitions

  • the invention relates to a plastic container for a deodorant roller according to the preamble of patent claim 1.
  • plastic containers made of white or stained, glass or ceramic are increasingly being replaced by plastic containers.
  • plastic containers are used for the packaging of fluid substances, such as beverages, household products, care products, etc.
  • the low weight and the lower costs certainly play a significant role in this substitution.
  • the use of recyclable plastic materials and the overall more favorable overall energy balance in their production also contribute to the consumer's acceptance of plastic containers, in particular of plastic bottles.
  • the usual glass containers are increasingly replaced by those made of plastic.
  • a Deoroller consists of a receptacle for a deodorant, which has at its upper, provided with the outlet opening a roller cage for an application ball. The ball is rotatably held in the cage.
  • screwing the closure usually a rotary closure, on the receptacle, the ball is pressed against an annular peripheral sealing area and prevents leakage of the deodorant contained inside.
  • the closure is removed between the spherical surface and the sealing area remains a narrow gap.
  • the gap makes it possible for the portion of the ball wetted with the deodorant to pass to the body site to be treated, for example the armpit, during the rotation of the ball, where it emits a thin deodorant film. Because of the double function, on the one hand sealing, on the other hand dispensing deodorant, there are relatively high demands on the dimensional accuracy of the cage and the ball.
  • the roll cages are therefore manufactured in an injection molding process, which ensures the required accuracy.
  • the receptacles were often made of glass, to which the injection-molded plastic roll cage was pressed or screwed.
  • the application ball is pressed after filling the deodorant in the receptacle in the roll cage and is held there rotatable and captive.
  • a number of deo scooters are known, which have a receptacle made of plastic.
  • the plastic container can be produced in a stretch blow molding process or in an extrusion blow molding process.
  • the injection-molded roller cage is in turn pressed onto the neck of the receptacle or screwed and welded, for example, additionally for fixing and sealing.
  • the roller cage and the receptacle must have exactly matched tying sections, so that tightness problems can be avoided.
  • the known Deoroller usually consist of four components, the receptacle, the roll cage, the application ball and the cap, which are each made separately and must be coordinated with each other in terms of dimensional accuracy.
  • the logistical effort for the production, storage and merging of the coordinated components of the Deoroller is not insignificant.
  • the production of the roller cage by injection molding is relatively complicated and expensive because of the necessary for the rotatable and captive holding the application ball undercut.
  • the tool costs for the injection mold for the roller cage and the tool costs for the tool for the production of the receptacle play a significant role.
  • even a separate assembly and fixation of the roll cage on the plastic container is required, which increases the cost and cost of the production of deo scooters.
  • the document WO2009 / 006713A2 discloses a plastic container with a sealing membrane. There is therefore a desire to reduce the cost of manufacturing, storage and merging of the individual components and for the installation of deodorant scooters. The tool costs should be reduced.
  • the invention proposes a plastic container for a deodorant roller which has a receptacle and a roller cage for the captive rotatable mounting of an application ball.
  • the roll cage is formed in an extrusion blown from an extruded tube integral with the receptacle. This eliminates the need for separate tools for the production of the roll cage and for the production of the receptacle.
  • For the integrally formed plastic container only a single tool is required, which has an advantageous effect on the tool costs.
  • the integrally formed roller cage at a transition to the receiving container forming portion of the plastic container on an annular peripheral sealing area.
  • the roller cage is provided at least in this sealing area with an inner layer which is softer than an outer layer of the roll cage.
  • the application ball inserted into the roller cage which usually consists of a harder material, for example polypropylene, polyamide, polyethylene terephthalate (PET), etc.
  • the adjacent surface of the roll cage is HDPE, for example.
  • the entire roll cage can be designed in one layer and consist of HDPE.
  • the inner layer of the roll cage is made by coextrusion. Coextrusion is particularly used in the extrusion blow molding process to produce multilayer containers or articles. It allows a very exact arrangement and dosing of the additional layer (s) to adjust their wall thickness accurately.
  • the roll cage is formed integrally with the receptacle for the deodorant, eliminates the assembly step for a separate roll cage. Leakage problems at Anbindeabêten the receptacle and the roller cage can not occur at all.
  • the one-piece design also increases the degrees of freedom in terms of the design of the receptacle forming portion of the plastic container and designed as a roll cage section, since not two separately manufactured components must be equipped with coordinated tethers.
  • the simplified production and the simplified handling also reduces the costs for producing the plastic container for the deodorant.
  • the production of the plastic container with one piece with each other trained receptacle and roll cage in an extrusion blow molding of an extruded plastic tube is very convenient and inexpensive.
  • the extrusion blow molding process in which a single-layer or multi-layer plastic hose is extruded, inserted into a blow mold and finally inflated by a blowing medium introduced with excess pressure according to the blow mold cavity, has been tried and tested, can be carried out inexpensively and permits short production cycles.
  • the plastic container with integrally formed receptacle and roll cage can be inflated from a continuously or discontinuously extruded plastic tube.
  • a continuously extruded plastic tube since the equipment required for this purpose are simpler in construction. For example, eliminates a jam head in the continuous extrusion of the plastic tube.
  • the sealing area is formed as a circumferential annular shoulder, already a relatively small contact pressure is sufficient to achieve a sufficient seal. Due to the formation of a facet or the like in the sealing area, a surface seal between the application ball and the ring cage can be achieved.
  • a further embodiment of the invention provides that the plastic container is formed in the region of the roller basket at least two layers.
  • the inner layer of the roll cage is softer than its outer layer.
  • the inner layer of the roll cage expediently has a hardness which is about 35 Shore to 90 Shore, according to ASTM test D-2240 (or to ISO 868 or DIN53505). These hardness values for the inner layer ensure that it is in any case softer than the surface of the application balls used in deo rollers.
  • the materials used for the inner layer of the roll cage are all extrudable and expandable in a blow molding plastics, such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, copolymers and material mixtures containing the above materials are used.
  • the hardness properties of the materials used can be adjusted by the addition of plasticizers to the desired extent.
  • the plastic container is expediently designed to be multi-layered overall.
  • the outer layer are also all extrudable and expandable in a blown plastic materials, such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, co-polymers and material mixtures containing the above materials are used.
  • the hardness properties of the materials used can be adjusted to the desired extent by the addition of plasticizers.
  • the outer layer has a greater hardness than the inner layer of the roll cage.
  • the invention also provides a deodorant roller comprising a plastic container according to the invention as claimed in claim 1, which has a roller cage formed integrally with the receptacle.
  • An application ball is rotatable and captive mounted inside the roller cage.
  • the deodorant has a closure cap, the height of which is dimensioned such that an extension projecting from an inner side of a cover surface of the closure cap presses against the application ball when it is fastened to the plastic container and seals the receptacle.
  • the deodorant roller according to the invention has a smaller number of components, namely the plastic container with receptacle section and roller cage section, the application ball and the closure cap.
  • the Deoroller is simpler and cheaper to manufacture.
  • the closure cap of Deoreollers is conveniently designed as a rotary closure.
  • the rotary closure is designed such that when screwing The cap must be overcome before reaching the end position increased resistance. Due to the increased resistance that he has to overcome when screwing, the user of the Deoroller is signaled that he has sufficiently sealed this.
  • the closure cap and / or the plastic container are designed such that for sealing sealing of the plastic container with the cap a minimum torque of 30 Nm to 250 Nm, preferably 60 Nm to 140 Nm, must be applied.
  • the cap can also be connected via a bayonet connection with the plastic container.
  • the invention also extends to a Deoroller according to claim 10 which contains a deodorant.
  • the plastic container formed according to the invention is in each case provided with the reference numeral 1 in its entirety.
  • the plastic container 1 has a receptacle 2 and an integrally molded roller cage 3.
  • the section forming the receptacle 2 extends up to a constriction 4.
  • the roller cage 3 adjoins the constriction 4 and has an approximately spherical segment-shaped or toroidal outer contour.
  • At the transition from the roll cage 3 to the constriction 4 is on the inner wall 6 of the rolling cage 3 is an annular circumferential Shoulder 7 formed.
  • the shoulder 7 bounds an opening 8 in the receptacle 2 and forms a sealing area in cooperation with an application ball held in the roll cage 3 (US Pat. Fig. 3 ).
  • the plastic container 1 with an integrally formed receptacle 2 and roll cage 3 is produced in an extrusion blow molding process.
  • a single-layer or multi-layer plastic hose is preferably extruded continuously, inserted into a blow molding tool and finally inflated and demolded by a blowing medium introduced with excess pressure according to the blow mold cavity.
  • the production of the roll cage 3 takes place with advantage in a so-called "lost-head process”.
  • an excess plastic portion in the area of the roll cage 3 is cut by the extrusion blown method by cutting. This ensures that the critical for the holder of an application ball portion of the rolling cage 3 has the required tolerances in terms of dimensional accuracy, wall thickness and rigidity.
  • a layer is provided on the inner wall of the roller cage, which has a lower hardness than the usually usable application balls.
  • the entire roll cage 3 and optionally also the receptacle 2 has an inner layer which is usually softer than an outer layer of the plastic container 1.
  • a hardness of the inner layer measured according to ASTM Standard D-2240 is about 35 Shore to 90 Shore ,
  • materials for the inner layer of the roll cage 3 are all extrudable and expandable in a blow molding plastics, such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, copolymers and material mixtures containing the above materials are used.
  • the hardness properties of the materials used can be adjusted by the addition of plasticizers to the desired extent.
  • the plastic container 1 is expediently designed to be multi-layered overall.
  • For the outer layer are also all extrudable and expandable in a blown plastic materials, such as polyolefins, thermoelastic elastomers, HDPE, LDPE, polyamides, co-polymers and material mixtures containing the above materials are used.
  • the hardness properties of the materials used are by the addition of plasticizers in the desired Circumference adjustable.
  • the outer layer usually has a greater hardness than the inner layer of the roll cage 3.
  • Fig. 3 shows an axially sectioned view of a deodorant roller
  • the overall reference numeral 10 carries.
  • the deodorant roller 10 according to the invention consists only of three individual components, namely the plastic container 1 with integrally formed receptacle 2 and roller cage 3, an application roller 13 which is rotatably and captively held in the roller cage 3 is, and a closure cap 14, whose internal thread 15 cooperates with the external thread 5 of the plastic container 1.
  • the plastic container 1 with integrally formed receptacle 2 and roll cage 3 is manufactured in an extrusion blow molding technology.
  • the closure cap 14 embodied as a rotary closure has a height which is dimensioned such that when the closure cap 14 is screwed on, an extension 16 protruding from an inside of a top surface of the closure cap 14 presses against the application ball 13.
  • the application ball 13 is pressed against the annular peripheral shoulder 7 and the receptacle is sealed.
  • the sealing is also assisted by the fact that the roller cage 3 has a surface or layer at least in the region of the annular peripheral shoulder 7, which is softer than the material of the application ball 13, which is usually made of a harder material, for example polypropylene, polyamide, Polyethylene terephthalate or a polyamide exists.
  • the receptacle 2 is reliably sealed against leakage of the content contained, for example, a deodorant.
  • the plastic container 1 and / or the closure cap 14 embodied as a rotary closure are designed such that an increased resistance must be overcome when the closure cap 14 is screwed on before reaching the end position.
  • an increased resistance must be overcome when the closure cap 14 is screwed on before reaching the end position.
  • one or more oversized areas are provided which must be overcome. This gives the user a feedback signal that indicates that the deodorant is now correctly and leak-proof.
  • a minimum torque of 30 Nm to 250 Nm, preferably 60 Nm to 140 Nm, must be applied to overcome the increased resistance.

Landscapes

  • Containers Having Bodies Formed In One Piece (AREA)
  • Closures For Containers (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Packages (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Pens And Brushes (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)

Claims (13)

  1. Contenant en matière plastique destiné à un déodorant à bille, comprenant un récipient (2) et une cage de roulement (3) pour le maintien rotatif imperdable d'une bille d'application (13), la cage de roulement (3) étant réalisée d'une seule pièce avec le récipient (2) et étant fabriquée par un procédé d'extrusion-soufflage, à partir d'un tube extrudé en matière plastique, caractérisé en ce que la cage de roulement (3) formée d'une seule pièce présente, à sa transition vers le récipient (2), une zone d'étanchéité périphérique circulaire, et en ce que la cage de roulement (3) présente, au moins dans cette zone d'étanchéité, une couche interne qui est réalisée par coextrusion et est plus souple qu'une couche externe de la cage de roulement (3).
  2. Contenant en matière plastique selon la revendication 1, caractérisé en ce que le récipient (2) et la cage de roulement (3) sont réalisés d'une seule pièce à partir d'un tube de matière plastique extrudé en continu.
  3. Contenant en matière plastique selon la revendication 2, caractérisé en ce que le récipient (2) et la cage de roulement (3) réalisée d'une seule pièce avec celui-ci sont fabriqués selon un procédé « à tête perdue », lors duquel une portion de matière plastique excédentaire située dans la région de la cage de roulement (3) est séparée par coupe à la fin du procédé d'extrusion-soufflage.
  4. Contenant en matière plastique selon une des revendications précédentes, caractérisé en ce que la zone d'étanchéité est un épaulement annulaire (7) ou un chanfrein périphérique ou un élément analogue.
  5. Contenant en matière plastique selon une des revendications précédentes, caractérisé en ce que la cage de roulement (3) est réalisée au moins avec deux couches, une couche interne (6) de la cage de roulement (3) étant plus souple qu'une couche externe de celle-ci.
  6. Contenant en matière plastique selon une des revendications précédentes, caractérisé en ce que la couche interne (6) présente une dureté qui est comprise entre environ 35 Shore et 90 Shore.
  7. Contenant en matière plastique selon une des revendications précédentes, caractérisé en ce que la couche interne (6) présente des matières plastiques pouvant être extrudées et dilatées au cours d'un procédé de soufflage, par exemple des polyoléfines, des élastomères thermoplastiques, HDPE, LDPE, des polyamides, des copolymères ainsi que des mélanges de matières contenant les matières précitées, dont les caractéristiques de dureté peuvent être réglées de la manière souhaitée, par l'ajout de plastifiants.
  8. Contenant en matière plastique selon une des revendications précédentes, caractérisé en ce qu'il est réalisé en plusieurs couches, sa couche externe comprenant une matière plastique pouvant être extrudée et pouvant être dilatée au cours d'un procédé de soufflage, dont les caractéristiques de dureté peuvent être réglées par l'ajout de plastifiants.
  9. Contenant selon la revendication 8, dans la mesure où il se réfère aux revendications 5 à 7, caractérisé en ce que la couche externe est plus dure que la couche interne (6) de la cage de roulement (3).
  10. Déodorant à bille comprenant un contenant en matière plastique (1) avec une cage de roulement (3) réalisée d'une seule pièce avec un récipient (2) selon une des revendications 1 à 9, ainsi qu'une bille d'application (13) qui est tenue avec possibilité de rotation et de façon imperdable dans la cage de roulement (3), et un capuchon de fermeture (14) dont la hauteur est prévue avec des dimensions telles que lors de la fixation sur le contenant en matière plastique (1), une saillie (16) s'étendant à partir d'une face interne d'une surface de recouvrement du capuchon de fermeture (14) soit en appui contre la bille d'application (13) et que celle-ci ferme de manière étanche le récipient.
  11. Déodorant à bille selon la revendication 10, caractérisé en ce que le capuchon de fermeture (14) est une fermeture à vis qui est réalisée de manière à ce que, lors du vissage du capuchon de fermeture (14) sur le contenant en matière plastique (1), une résistance accrue doive être surmontée avant d'atteindre la position finale.
  12. Déodorant à bille selon la revendication 10 ou 11, caractérisé en ce que le capuchon de fermeture (14) et/ou le contenant en matière plastique (1) sont réalisés de manière telle que, pour la fermeture étanche du récipient en matière plastique (1), un couple minimal de 30 Nm à 250 Nm, de préférence de 60 Nm à 140 Nm soit nécessaire.
  13. Déodorant à bille selon une des revendications 10 à 12, contenant un déodorant.
EP12797718.9A 2012-01-11 2012-12-03 Contenant en plastique pour un déodorant à bille Active EP2802235B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL12797718T PL2802235T3 (pl) 2012-01-11 2012-12-03 Pojemnik z tworzywa sztucznego na dezodorant w kulce

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH00053/12A CH706012A1 (de) 2012-01-11 2012-01-11 Kunststoffbehälter für einen Deoroller.
PCT/EP2012/004985 WO2013104385A1 (fr) 2012-01-11 2012-12-03 Contenant en plastique pour un déodorant à bille

Publications (2)

Publication Number Publication Date
EP2802235A1 EP2802235A1 (fr) 2014-11-19
EP2802235B1 true EP2802235B1 (fr) 2018-07-25

Family

ID=47297103

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12797718.9A Active EP2802235B1 (fr) 2012-01-11 2012-12-03 Contenant en plastique pour un déodorant à bille

Country Status (12)

Country Link
US (1) US9456677B2 (fr)
EP (1) EP2802235B1 (fr)
CN (1) CN104203040B (fr)
AR (1) AR089689A1 (fr)
BR (1) BR112014016955B8 (fr)
CH (1) CH706012A1 (fr)
ES (1) ES2688810T3 (fr)
IN (1) IN2014DN05798A (fr)
MX (1) MX347809B (fr)
PL (1) PL2802235T3 (fr)
RU (1) RU2608293C2 (fr)
WO (1) WO2013104385A1 (fr)

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DE102020113258A1 (de) 2020-05-15 2021-11-18 QOIS GmbH Flüssigkeitsdosierroller

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JP5905297B2 (ja) * 2012-02-27 2016-04-20 株式会社パイロットコーポレーション 筆記具
CN103462347A (zh) * 2013-10-08 2013-12-25 苏州新区华士达工程塑胶有限公司 多功能便利化妆瓶
US20170173314A1 (en) * 2015-12-17 2017-06-22 Shanna NELSON Nasal applicator
USD859527S1 (en) * 2016-11-15 2019-09-10 Crayola Llc Rollerball marker
CN109892693A (zh) * 2017-12-07 2019-06-18 上海新型烟草制品研究院有限公司 一种口服烟烟具
US11957229B2 (en) * 2019-12-09 2024-04-16 Ball Corporation Metallic roll-on container
RU199827U1 (ru) * 2020-02-04 2020-09-22 Федеральное государственное бюджетное образовательное учреждение высшего образования "Астраханский государственный технический университет" (ФГБОУ ВО "АГТУ") Роликовый контейнер для пищевого ароматизатора
DE102021108267A1 (de) * 2021-03-31 2022-10-06 Nussbaum Matzingen Ag Behältnis mit einem Gewinde
KR102511951B1 (ko) * 2021-12-29 2023-03-20 주식회사 태을 롤온 형식의 화장품 용기

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US4948641A (en) * 1987-06-01 1990-08-14 Olin Corporation Multiple layer container for storage of high purity chemicals
WO1997001427A1 (fr) * 1995-06-26 1997-01-16 Valyi Emery I Recipient pour aliments et boissons en plastique moule et procede correspondant
WO2003065842A2 (fr) * 2002-02-08 2003-08-14 Contreras Huerta Benjamin Recipient a sphere rotative pour l'application de liquides et son procede d'obtention
US20070040306A1 (en) * 2003-04-02 2007-02-22 Sabrina Morel Method for carrying out ventilation in a multi-walled container
US20070071547A1 (en) * 2005-09-27 2007-03-29 Graham Packaging Company, L.P. Tube with ball socket
US20100094245A1 (en) * 2008-10-10 2010-04-15 Daniel Py Co-extrusion blow molding apparatus and method, and sealed empty devices

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102020113258A1 (de) 2020-05-15 2021-11-18 QOIS GmbH Flüssigkeitsdosierroller

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US9456677B2 (en) 2016-10-04
US20140321898A1 (en) 2014-10-30
ES2688810T3 (es) 2018-11-07
MX347809B (es) 2017-05-15
MX2014008368A (es) 2014-10-14
CN104203040B (zh) 2017-08-04
CN104203040A (zh) 2014-12-10
RU2608293C2 (ru) 2017-01-17
PL2802235T3 (pl) 2018-12-31
BR112014016955A8 (pt) 2017-07-04
RU2014132704A (ru) 2016-02-27
IN2014DN05798A (fr) 2015-05-15
AR089689A1 (es) 2014-09-10
CH706012A1 (de) 2013-07-15
WO2013104385A1 (fr) 2013-07-18
BR112014016955B1 (pt) 2021-04-06
BR112014016955B8 (pt) 2022-12-13
EP2802235A1 (fr) 2014-11-19
BR112014016955A2 (pt) 2017-06-13

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