EP2787964A1 - Composition à base de poudre de plante(s) produisant de l'indigo et d'huile(s) et/ou de beurre(s), et procédé de teinture de cheveux à l'aide de ladite composition - Google Patents

Composition à base de poudre de plante(s) produisant de l'indigo et d'huile(s) et/ou de beurre(s), et procédé de teinture de cheveux à l'aide de ladite composition

Info

Publication number
EP2787964A1
EP2787964A1 EP12795827.0A EP12795827A EP2787964A1 EP 2787964 A1 EP2787964 A1 EP 2787964A1 EP 12795827 A EP12795827 A EP 12795827A EP 2787964 A1 EP2787964 A1 EP 2787964A1
Authority
EP
European Patent Office
Prior art keywords
composition
butter
oil
weight
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12795827.0A
Other languages
German (de)
English (en)
Inventor
Chrystel POURILLE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR1161384A external-priority patent/FR2983725B1/fr
Priority claimed from FR1161383A external-priority patent/FR2983724B1/fr
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP2787964A1 publication Critical patent/EP2787964A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/31—Anhydrous

Definitions

  • the invention relates to a composition A, which is preferably compact and/or anhydrous, comprising at least 20% of a powder of indigo-yielding plant(s) and at least one oil and/or at least one butter, and also to an aqueous composition B derived from A for dyeing keratin fibres, to the process for dyeing keratin fibres using composition A or B, and to the use of composition A or B for dyeing keratin fibres.
  • a composition A which is preferably compact and/or anhydrous, comprising at least 20% of a powder of indigo-yielding plant(s) and at least one oil and/or at least one butter
  • an aqueous composition B derived from A for dyeing keratin fibres to the process for dyeing keratin fibres using composition A or B, and to the use of composition A or B for dyeing keratin fibres.
  • the first known as oxidation dyeing or permanent dyeing, consists in using one or more oxidation dye precursors, more particularly one or more oxidation bases, optionally combined with one or more couplers.
  • Oxidation bases are usually selected from ortho- or para-phenylenediamines, ortho- or para-aminophenols, and heterocyclic compounds. These oxidation bases are colourless or weakly coloured compounds, which, when combined with oxidizing products, can give rise via a process of oxidative condensation to coloured species, which remain trapped within the fibre.
  • Couplers are chosen especially from aromatic meta- diamines, meta-aminophenols, meta-diphenols and certain heterocyclic compounds, such as indole compounds.
  • the second dyeing method comprises the application of direct dyes, which are coloured and colouring molecules that have an affinity for the fibres. Given the nature of the molecules used, they rather remain on the surface of the fibre and penetrate relatively little into the fibre, when compared with the small molecules of oxidation dye precursors.
  • the main advantages of this type of dyeing are that it does not require any oxidizing agent, which limits the degradation of the fibres, and that it does not use any dyes that have a particular reactivity, resulting in limitation of the intolerance risks.
  • the first hair dyes were semi-permanent.
  • One of the most widely known natural dyes is indigo (see Ullmann's Encyclopedia of Industrial Chemistry, “Hair Preparations", point 5.2.3, 2006 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim; 10.1002/14356007.a12 571 .pub2).
  • Indigo continues to be used for making women more attractive by dyeing the hair or colouring the nails, or for dyeing fabrics (jeans), leather, silk and wool, etc.
  • Indigo [482-89-3] is a natural dye, originating in particular from the indigo plant, which has the empirical formula: Ci6H 10 N 2 O2: it has the structure:
  • Indigo is derived from indican, which can be prepared from various "indigo-yielding" plants such as Indigofera tinctoria, Indigo suffraticosa, Isatis tinctoria etc. (see Kirk-Othmer Encyclopedia of Chemical Technology, updated on 17/04/2009, DOI: 10.1002/0471238961.0425051903150618.a01.pub2).
  • the indigo-yielding plants are generally cut up and soaked in hot water, heated, fermented and air-oxidized so as to release the mauve-blue-coloured indigo (see Chem. Rev. , 201 1 , 111 , 2537-2561 , pp. 2537- 2561 ).
  • Indigo is the result of the fermentation and then oxidation of indican (glycosylated precursor).
  • Indigo as a molecule is water-insoluble.
  • the leave-on time is long. It may vary from several tens of minutes to several hours (overnight) depending on the desired intensity, with no ability to control the result.
  • the result varies as a function of the fibres to be dyed and of the indigo raw material used.
  • indigo powder optionally in the presence of excipients, in fine-powder form (DE 195 48 291 ).
  • these powders are packaged in sachets or blister packs (DE 101 31 385). If the packaging of the indigo powder happens to become broken, a large quantity of raw material is lost into the air and cannot be recovered. Added to the problem of the loss of raw material is additionally that linked to the fineness of the particles for users or clients. Indeed, in suspension, the particles in the atmosphere can cause respiratory problems or allergies such as rhinitis for the clients, sellers of extracts or natural dyeing professionals (Allergy, J. Scibilia, E. Galdi, G. Biscaldi and G. Moscato, 52, 231 -232, (1997)).
  • the solid compositions do not always readily disintegrate in water.
  • the poultices derived from the compositions of the prior art are not always creamy and/or easy to apply. They do not make it possible, moreover, to obtain a palette of colours in the ashen and deep purple range. There is thus a real need to develop dyeing processes which make it possible to obtain powerful colourations using indigo, while at the same time being friendly to the cosmetics of keratin fibres.
  • an indigo-based dyeing product that does not have the drawbacks mentioned above, especially a dust-free product, that is easy to store, that is readily miscible (rapid disintegration) in water, and that can especially produce colourations that are less aggressive to the hair and at the same time that are resistant to external agents (light, bad weather or shampooing), and that are fast and homogeneous, while remaining powerful and chromatic.
  • the colour uptake on the keratin fibers, especially hair, treated with indigo and potentially henna must be satisfactory.
  • This aim is achieved by the present invention, a subject of which is a composition, preferably in compact and/or anhydrous form, more preferentially in compact and anhydrous form, comprising:
  • this composition which is usually in the form of a poultice, is prepared from composition A defined above and an aqueous composition C, preferentially water, in proportions ranging from 1 part by weight of composition A per 1 part by weight of an aqueous composition C and preferentially water (1/1 ) to 1 part by weight of composition A per 3 parts by weight of an aqueous composition C and preferentially water (1/3), preferentially 1 part by weight of composition per A 2 parts by weight of an aqueous composition C and preferentially water (1/2).
  • composition and poultice according to the invention have the advantage of dyeing keratin fibres, in particular human keratin fibres, with strong and chromatic dyeing results that are resistant to washing, perspiration, sebum and light, and that are moreover long-lasting, without impairing said fibres. Furthermore, the colourations obtained using the composition or the poultice give uniform colours from the root to the end of a fibre (little colouration selectivity). Furthermore, the application of the composition or of the poultice does not give off any raw material dust (dust-free). The composition or the poultice is easy to use, in total safety and with no risk of staining. In addition, the composition and the active agent remain stable on storage. The treated keratin fibres have a very pleasant aesthetic appearance and their integrity is respected.
  • the composition of the invention even in compact form, is very water- miscible even in cold water (especially between 10°C and ambient temperature, 25°C), and the poultice then formed is particularly creamy and/or shows excellent adhesion to the hair.
  • the time for and/or ease of disintegration of the composition when it is in compact and preferably anhydrous form is faster or easier, for an equivalent amount, than for the compact compositions on the market.
  • composition according to the invention comprises, as first ingredient, powder of an indigo-yielding plant.
  • Indigofera such as Indigofera tinctoria, Indigo suffraticosa, Indigofera articulata, Indigofera arrecta, Indigofera gerardiana, Indigofera argenta, Indigofera indica, Indigofera longiracemosa;
  • Isatis such as Isatis tinctoria
  • Persicaria such as Polygonum tinctorium (Persicaria tinctoria);
  • Calanthe such as Calanthe veratrifolia
  • Baphicacanthus such as Baphicacanthus cusia.
  • the indigo-yielding plant is of the Indigofera genus and is more particularly Indigofera tinctoria.
  • All or part (in particular the leaves, especially for Indigofera tinctoria) of the indigo- yielding plant can be used.
  • the powder of an indigo-yielding plant may be screened to obtain particles with upper limit sizes corresponding to the orifices or mesh sizes of the screen, particularly between 35 and 80 mesh (US).
  • the size of particles the powder of an indigo-yielding plant is fine.
  • a particle size of less than or equal to 500 ⁇ is more particularly intended.
  • the powder consists of fine particles inclusively between 50 and 300 ⁇ in size and more particularly between 10 and 200 ⁇ in size.
  • Composition A comprises powder of indigo-yielding plant(s) in an amount particularly inclusively between 20 % and 99 % by weight relative to the total weight of the composition, more particularly between 30 % and 95 % by weight, preferentially between 40% and 90% by weight, more preferentially between 50 % and 85 % by weight and even more preferentially between 60 % and 80 % by weight.
  • the composition of the invention comprises as second ingredient ii) one or more oils, which may be identical or different, free of butter(s).
  • the term "o/T is intended to mean a "fatty substance" which is liquid at ambient temperature (25°C) and at atmospheric pressure (760 mmHg); the viscosity at 25°C is preferably less than 1200 cPs and better still less than 500 cPs (defined, for example, from the Newtonian plateau determined using an ARG2 rheometer from TA Instruments equipped with a spindle with cone-plate geometry, with a diameter of 60 mm and with an angle of 2 degrees, over a shear stress range of from 0.1 Pa to 100 Pa).
  • fatty substances are generally soluble in organic solvents under the same temperature and pressure conditions, such as, for example, chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran (THF), liquid petroleum jelly or decamethylcyclopentasiloxane.
  • organic solvents such as, for example, chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran (THF), liquid petroleum jelly or decamethylcyclopentasiloxane.
  • non-silicone o/T is intended to mean an oil not containing any silicon (Si) atoms and the term “silicone o/T is intended to mean an oil containing at least one silicon atom.
  • the oils are chosen from non-silicone oils and in particular hydrocarbons which are C 6 -Ci 6 hydrocarbons or which contain more than 16 carbon atoms and in particular alkanes; oils of animal origin; triglyceride oils of plant origin; essential oils; fluoro oils or glycerides of synthetic origin; fatty alcohols; fatty acid and/or fatty alcohol esters other than triglycerides; and silicone oils.
  • the oils do not comprise any C 2 -C 3 oxyalkylene units or any glycerol units.
  • the oils are not fatty acids which, in salified form, give water-soluble soaps.
  • the oils that may be used as second ingredient ii) in the composition in accordance with the invention may be silicones.
  • the silicones may be volatile or non-volatile and cyclic, linear or branched silicones, which are unmodified or modified with organic groups, having a viscosity from 5x10 "6 to 2.5 m 2 /s at 25°C, and preferably from 1 *10 "5 to 1 m 2 /s.
  • the silicone is chosen from polydialkylsiloxanes, especially polydimethylsiloxanes (PDMSs), and organomodified polysiloxanes comprising at least one functional group chosen from poly(oxyalkylene) groups, amino groups and alkoxy groups.
  • PDMSs polydimethylsiloxanes
  • organomodified polysiloxanes comprising at least one functional group chosen from poly(oxyalkylene) groups, amino groups and alkoxy groups.
  • Organopolysiloxanes are defined in more detail in Walter Noll's "Chemistry and Technology of Silicones” (1968), Academic Press. They can be volatile or non-volatile.
  • the silicones are more particularly chosen from those having a boiling point of between 60°C and 260°C, and more particularly still from: (i) (i) cyclic polydialkylsiloxanes comprising from 3 to 7 and preferably from 4 to 5 silicon atoms. They are, for example, octamethylcyclotetrasiloxane, sold in particular under the name Volatile Silicone ® 7207 by Union Carbide or Silbione ® 70045 V2 by Rhodia, decamethylcyclopentasiloxane, sold under the name Volatile Silicone ® 7158 by Union Carbide and Silbione ® 70045 V5 by Rhodia, and their mixtures .
  • octamethylcyclotetrasiloxane sold in particular under the name Volatile Silicone ® 7207 by Union Carbide or Silbione ® 70045 V2 by Rhodia
  • decamethylcyclopentasiloxane sold under the name Volatile Silicone ® 7158
  • linear volatile polydialkylsiloxanes containing from 2 to 9 silicon atoms and having a viscosity of less than or equal to 5x10 "6 m 2 /s at 25°C.
  • An example is decamethyltetrasiloxane sold in particular under the name SH 200 by the company Toray Silicone. Silicones coming within this category are also described in the paper published in Cosmetics and Toiletries, Vol. 91 , Jan. 76, pp. 27-32, Todd & Byers, "Volatile Silicone Fluids for Cosmetics”.
  • Use is preferably made of non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above organofunctional groups, and mixtures thereof.
  • silicones are more particularly chosen from polydialkylsiloxanes, among which mention may be made mainly of polydimethylsiloxanes having trimethylsilyl end groups.
  • the viscosity of the silicones is measured at 25°C according to Standard
  • oils of the 200 series from Dow Corning such as DC200 having a viscosity of 60 000 mm 2 /s;
  • CTFA dimethiconol
  • the alcohols and esters that may be used as second ingredient ii) in the composition in accordance with the invention are in the form of oils.
  • the fatty alcohols, esters and acids more particularly have at least one linear or branched and saturated or unsaturated hydrocarbon-based group comprising 6 to 30 carbon atoms, which is optionally substituted, in particular with one or more hydroxyl groups (in particular 1 to 4). If they are unsaturated, these compounds can comprise from one to three conjugated or non-conjugated carbon- carbon double bonds.
  • C 6 -Ci 6 alkanes they are linear, branched or possibly cyclic. Mention may be made, by way of example, of hexane, dodecane or isoparaffins, such as isohexadecane or isodecane.
  • the linear or branched hydrocarbons containing more than 16 carbon atoms may be chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, polydecenes and hydrogenated polyisobutene such as Parleam®.
  • liquid fatty acid triglycerides containing from 6 to 30 carbon atoms for instance heptanoic or octanoic acid triglycerides, or alternatively, for example, sunflower oil, maize oil, soybean oil, marrow oil, grapeseed oil, sesame seed oil, hazelnut oil, apricot oil, macadamia oil, arara oil, castor oil, avocado oil, caprylic/capric acid triglycerides, for instance those sold by the company Stearineries Dubois or those sold under the names Miglyol ® 810, 812 and 818 by the company Dynamit Nobel, jojoba oil or shea butter oil.
  • fluoro oils mention may be made of perfluoromethylcyclopentane and perfluoro-1 ,3-dimethylcyclohexane, sold under the names Flutec ® PC1 and Flutec ® PC3 by the company BNFL Fluorochemicals; perfluoro-1 ,2-dimethylcyclobutane; perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names PF 5050 ® and PF 5060 ® by the company 3M, or bromoperfluorooctyl sold under the name Foralkyl ® by the company Atochem; nonafluoromethoxybutane and nonafluoroethoxyisobutane; perfluoromorpholine derivatives such as 4-(trifluoromethyl) perfluoromorpholine sold under the name PF 5052 ® by the company 3M.
  • Flutec ® PC1 and Flutec ® PC3 by
  • the oil(s) is (are) chosen from C 6 -Ci 6 alkanes, polydecenes, liquid esters of a fatty acid and/or of a fatty alcohol, liquid fatty alcohols or mixtures thereof.
  • the fatty substance is chosen from liquid petroleum jelly, C 6 -Ci 6 alkanes or polydecenes.
  • the oil(s) is (are) chosen from mineral oils such as liquid petroleum jelly.
  • oils of plant origin are chosen from avocado oil, olive oil, coconut oil, copra oil, argan oil and sunflower oil.
  • Composition A according to the invention may comprise one or more oils in an amount particularly inclusively between 1 % and 80% by weight, relative to the total weight of the composition, more particularly between 2% and 50% by weight, preferentially between 3% and 40% by weight and more preferentially between 5% and 25% by weight.
  • the term “butter” (also referred to as “pasty fatty substance”) is intended to mean a lipophilic fatty compound with a reversible solid/liquid change of state, comprising, at a temperature of 25°C and at atmospheric pressure (760 mmHg), a liquid fraction and a solid fraction.
  • the starting melting point of the pasty compound can be less than 25°C.
  • the liquid fraction of the pasty compound measured at 25°C can represent from 9% to 97% by weight of the compound. This fraction that is liquid at 25°C preferably represents between 15% and 85% and more preferably between 40% and 85% by weight.
  • the butter(s) has (have) an end melting point of less than 60°C.
  • the butter(s) has (have) a hardness of less than or equal to 6 MPa.
  • the butters or pasty fatty substances have, in the solid state, an anisotropic crystal organization, which is visible by X-ray observation.
  • the measurements are performed on the abovementioned calorimeter.
  • the oven is flushed with nitrogen. Cooling is provided by an RCS 90 heat exchanger.
  • the sample is then subjected to the following protocol: it is first of all placed at a temperature of 20°C, and then subjected to a first temperature rise passing from 20°C to 80°C, at a heating rate of 5°C/minute, then is cooled from 80°C to -80°C at a cooling rate of 5°C/minute and finally subjected to a second temperature rise passing from -80°C to 80°C at a heating rate of 5°C/minute.
  • the variation in the difference in power absorbed by the empty crucible and by the crucible containing the sample of butter is measured as a function of the temperature.
  • the melting point of the compound is the value of the temperature corresponding to the top of the peak of the curve representing the variation in the difference in power absorbed as a function of the temperature.
  • the end melting point corresponds to the temperature at which 95% of the sample has melted.
  • the liquid fraction by weight of the butter at 25°C is equal to the ratio of the heat of fusion consumed at 25°C to the heat of fusion of the butter.
  • the heat of fusion of the pasty compound is the heat consumed by the compound in order to pass from the solid state to the liquid state.
  • the butter is said to be in the solid state when all of its mass is in crystalline solid form.
  • the butter is said to be in the liquid state when all of its mass is in liquid form.
  • the heat of fusion of the butter is equal to the integral of the entire melting curve obtained using the abovementioned calorimeter, with a temperature rise of 5 or 10°C/rminute, according to Standard ISO 1 1357-3:1999.
  • the heat of fusion of the butter is the amount of energy required to make the compound change from the solid state to the liquid state. It is expressed in J/g.
  • the heat of fusion consumed at 25°C is the amount of energy absorbed by the sample to change from the solid state to the state that it has at 25°C, consisting of a liquid fraction and a solid fraction.
  • the liquid fraction of the butter measured at 32°C is equal to the ratio of the heat of fusion consumed at 32°C to the heat of fusion of the pasty compound.
  • the heat of fusion consumed at 32°C is calculated in the same way as the heat of fusion consumed at 23°C.
  • sample preparation and measurement protocols are as follows:
  • composition according to the invention or the butter is placed in a mould 75 mm in diameter, which is filled to about 75% of its height.
  • the mould is placed in a Votsch VC0018 programmable oven, where it is first of all placed at a temperature of 80°C for 60 minutes, then cooled from 80°C to 0°C at a cooling rate of 5°C/minute, then left at the stabilized temperature of 0°C for 60 minutes, and then subjected to a temperature rise passing from 0°C to 20°C, at a heating rate of 5°C/minute, and then left at the stabilized temperature of 20°C for 180 minutes.
  • the compressive force measurement is taken using a TA/TX2i texturometer from Swantech.
  • the spindle used is chosen according to the texture:
  • the measurement comprises three steps:
  • the hardness value measured during the first step corresponds to the maximum compressive force measured in newtons divided by the area of the texturometer cylinder expressed in mm 2 in contact with the butter or the composition according to the invention.
  • the hardness value obtained is expressed in megapascals or MPa.
  • the particular butter(s) is (are) of plant origin, such as those described in Ullmann's Encyclopedia of Industrial Chemistry ("Fats and Fatty Oils", A. Thomas, Published Online: 15 JUN 2000, DOI: 10.1002/14356007.a10_173, point 13.2.2.2. Shea Butter, Borneo Tallow, and Related Fats (Vegetable Butters)).
  • the weight content of Ci 6 fatty acids of the triglycerides, in the butter(s) according to the invention, expressed relative to the total content of fatty acids of the triglycerides, is less than 23%.
  • the composition does not contain any cacao butter.
  • the butter(s) according to the invention is (are) chosen from murumuru butter, ucuuba butter, shorea butter, illipe butter, shea butter and cupuacu butter, and even more preferentially from murumuru butter and ucuuba butter.
  • Composition A according to the invention comprises one or more butters in an amount particularly inclusively between 1 % and 80% by weight relative to the total weight of the composition, more particularly inclusively between 2% and 50% by weight, preferentially inclusively between 3% and 40% by weight and more preferentially inclusively between 5% and 25% by weight.
  • Composition A according to the invention may comprise one or more oils and one or more butters, the [oil(s) + butter(s)] amount of which is inclusively between 1 % and 80% by weight, relative to the total weight of the composition, particularly between 2% and 50% by weight, preferentially between 3% and 40% by weight and more preferentially between 5% and 25% by weight.
  • At least one fatty substance other than oils and butters waxes or resins
  • composition of the invention may also comprise one or more fatty substances other than the oil(s) as defined previously and other than the butter(s) as defined previously.
  • the composition comprises as third constituent one or more waxes, preferably of plant origin.
  • the fatty alcohols that are suitable for use in the invention are more particularly chosen from saturated linear alcohols comprising from 6 to 30 carbon atoms and preferably from 8 to 30 carbon atoms. Mention may be made, for example, of cetyl alcohol, stearyl alcohol and their mixture (cetearyl alcohol).
  • esters of fatty acids and/or fatty alcohols mention may preferably be made of esters of saturated linear fatty acids and of saturated linear fatty alcohols, such as cetyl palmitate, stearyl stearate or cetyl stearate.
  • the composition comprises as third constituent one or more waxes, other than the fatty alcohols and fatty esters mentioned above, preferably of plant origin.
  • the (non-silicone) wax(es) is (are) chosen in particular from carnauba wax, candelilla wax, esparto wax, paraffin wax, ozokerite, plant waxes, such as olive tree wax, rice wax, hydrogenated jojoba wax or absolute flower waxes, such as the blackcurrant blossom essential wax sold by Bertin (France), or animal waxes, such as beeswaxes or modified beeswaxes (cerabellina); other waxes or waxy starting materials that can be used according to the invention are in particular marine waxes, such as that sold by Sophim under the reference M82, polyethylene waxes or polyolefin waxes in general.
  • the composition comprises one or more silicone waxes, resins or gums.
  • the silicone gums that may be used in accordance with the invention are especially polydialkylsiloxanes and preferably polydimethylsiloxanes with high number-average molecular weights of between 200 000 and 1 000 000, used alone or as a mixture in a solvent.
  • This solvent can be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures.
  • Products which can be used more particularly in accordance with the invention are mixtures, such as:
  • CTFA dimethiconol
  • CFA cyclic polydimethylsiloxane
  • the product SF 1236 is the mixture of a gum SE 30 defined above having a viscosity of 20 m 2 /s and of an oil SF 96 with a viscosity of 5x10 "6 m 2 /s. This product preferably comprises 15% of gum SE 30 and 85% of an oil SF 96.
  • organopolysiloxane resins which can be used in accordance with the invention are crosslinked siloxane systems including the following units:
  • R represents an alkyl having from 1 to 16 carbon atoms.
  • R denotes a lower d-C 4 alkyl group, more particularly methyl.
  • the fatty substance(s) does (do) not comprise any C 2 -C 3 oxyalkylene units or any glycerol units.
  • Composition A according to the invention preferably comprises a content of fatty substances other than the oil(s) and butter(s) as defined previously ranging from 0.5% to 50% by weight, better still from 1 % to 30% by weight and even better still from 1 % to 20% by weight relative to the total weight of the composition.
  • Composition A of the invention is cosmetic, i.e. it is cosmetically acceptable and therefore suitable for use for application to keratin fibres.
  • the composition of the invention does not contain any "mordants”, i.e. metal salts conventionally used in "mordanting” (see for example Ullmann's Encyclopedia of Industrial Chemistry ("Textile Dyeing", Herbert Leube et al., DOI: 10.1002/14356007.a26_351 , and in particular point 4.8.2, p. 72 ; ibid, "Metal-complex dyes", Klaus Gryschtol et al., DOI: 10.1002/14356007.a16_299).
  • compositions may comprise water or a mixture of water and of one or more organic solvents or a mixture of organic solvents.
  • Composition A according to the invention preferably comprises less than 3% by weight and preferably less than 2% by weight of water relative to the total weight of the composition, or even is free of water.
  • the composition according to the invention does not comprise any water other than the water associated with the starting materials included in its composition. It is then referred to as an anhydrous composition.
  • Composition A according to the invention is preferentially in compact form. As emerges from the foregoing, the compact composition according to the invention is "solid".
  • solid means the state of the composition at ambient temperature (25°C) and at atmospheric pressure (760 mmHg), i.e. a composition of high consistency, which retains its form during storage. In contrast to “fluid” compositions, it does not flow under its own weight. It is advantageously characterized by a hardness as defined below.
  • the term "compact composition” means that the composition consists of a mixture of products whose cohesion is at least partly provided by compacting or pressing during manufacture.
  • the compact powder according to the invention can advantageously exhibit a resistance to pressure of between 0.2 and 2.5 kg and in particular between 0.8 and 1 .5 kg, with respect to the surface area of the spindle used (in the case in point, 7.07 mm 2 ).
  • the measurement of this resistance is performed by moving an SMS P/3 flat-ended cylindrical spindle in contact with the powder over a distance of 1 .5 mm and at a speed of 0.5 mm/second.
  • composition A is in compact form and in different forms as a function of the desired compacting, especially in the form of pebbles, in the form of discs, in the form of soaps, in the form of pyramids, in the form of bricks or in the form of platelets.
  • composition comprises one or more oils, it is in compact form.
  • the cosmetic composition A of the invention may also be in non-compact galenical forms, such as a lotion, a mousse, a cream or a gel, or in any other form that is suitable for dyeing keratin fibres. It may also be packaged in a propel lant-free pump-dispenser bottle or under pressure in an aerosol container in the presence of a propellant and can form a foam.
  • Aqueous composition B Aqueous composition B
  • composition B derived from the mixture between composition A, which is preferably compact and/or anhydrous, and an aqueous composition C and preferably water (only water). It is thus possible to use, in this composition B, the powder of indigo-yielding plant(s) i) as defined previously and optionally other natural dyes as defined below, combined with the oil(s) and/or with the butter(s) ii) as defined previously and optionally iii) one or more fatty substances other than the oil(s) or the butters ii).
  • composition B is in the form of a poultice.
  • composition A according to the invention preferably in compact and/or anhydrous form, comprising the ingredients i), ii) and optionally iii) as defined previously is mixed with an aqueous composition, and preferentially mixed with water, to obtain a poultice in order to obtain a creamy and pleasant consistency.
  • the composition is compact, it is crumbled into the aqueous composition C and the compact composition is preferentially crumbled into water.
  • the ratios of composition A according to the invention and an aqueous composition C and preferentially water preferably range from 1 part by weight of composition A per 1 part by weight of aqueous composition C and preferentially water (1/1 ) to 1 part by weight of composition A per 3 parts by weight of aqueous composition and preferentially water (1 /3), more preferentially 1 part by weight of composition A per 2 parts of aqueous composition C and preferentially water (1 /2).
  • composition B comprises only ingredients of natural origin.
  • one or more identical or different clays may be added.
  • composition B has a neutral pH close to 7 (preferably ranging from 6 to 8 and better still from 6.5 to 7.5).
  • the organic solvents are present in proportions preferably of between 0.1 % and 20% by weight approximately and even more preferentially between 0.5% and 10% by weight approximately relative to the total weight of the composition under consideration.
  • compositions A and/or B and/or C of the invention may also contain various adjuvants conventionally used in hair dyeing compositions, such as anionic, cationic, non- ionic, amphoteric or zwitterionic surfactants or mixtures thereof, anionic, cationic, non-ionic, amphoteric or zwitterionic polymers or mixtures thereof, mineral or organic thickeners, and in particular anionic, cationic, non-ionic and amphoteric polymeric associative thickeners, antioxidants, penetrants, sequestrants, fragrances, buffers, dispersants, conditioning agents other than the butters of the invention, for instance ceramides, film-forming agents, preserving agents, opacifiers and mineral or organic thickeners such as clays.
  • compositions A and/or B are not in emulsion form.
  • compositions A and/or B do not contain any surfactants.
  • the above adjuvants are generally present in an amount for each of them of between 0.01 % and 40% by weight relative to the weight of the composition, and preferably between 0.1 % and 20% by weight relative to the weight of the composition under consideration.
  • compositions A and/or B and/or C of the invention comprising the ingredients i) and ii) and optionally iii) as defined previously may also contain iv) one or more additional direct dyes other than the powder of indigo-yielding plant(s) i).
  • direct dyes are chosen, for example, from those conventionally used in direct dyeing, and among which mention may be made of any commonly used aromatic and/or non-aromatic dye such as neutral, acidic or cationic nitrobenzene direct dyes, neutral, acidic or cationic azo direct dyes, natural direct dyes, neutral, acidic or cationic quinone and in particular anthraquinone direct dyes, azine, triarylmethane, indoamine, methine, styryl, porphyrin, metalloporphyrin, phthalocyanine or methine cyanine direct dyes, and fluorescent dyes.
  • aromatic and/or non-aromatic dye such as neutral, acidic or cationic nitrobenzene direct dyes, neutral, acidic or cationic azo direct dyes, natural direct dyes, neutral, acidic or cationic quinone and in particular anthraquinone direct dyes, azine, triarylmethane, indoamine
  • compositions A and/or B and/or C of the invention comprise one or more natural dyes other than indigo i) as defined previously.
  • natural direct dyes mention may be made of juglone, lawsone, isatin, curcumin, spinulosin, apigenidin, orceins and pure indigo.
  • These natural dyes can be added in the form of defined compounds, from extracts or from plant parts.
  • Said defined compounds from extracts or from plant parts are preferably in the form of powders, in particular fine powders, the particles of which have sizes identical to that of the powder of indigo-yielding plant(s) as defined previously.
  • compositions A and/or B and/or C comprise also a red henna in powder form.
  • composition A contains red henna.
  • the size of the henna powder particles is fine.
  • a particle size of less than or equal to 500 ⁇ is more particularly intended.
  • the powder consists of fine particles with sizes inclusively between 50 and 300 ⁇ and more particularly between 10 and 200 ⁇ .
  • the said henna particles preferentially have a moisture content of between 0 and 10% by weight relative to the total weight of the powders.
  • the red henna is the same amount in weight than of the indigo-yielding plant amount.
  • the natural or non-natural direct dye(s), other than the powder of indigo-yielding plant(s) i) and red henna, of the composition according to the invention particularly represent(s) from 0.001 % to 10% by weight of the total weight of the composition and even more preferentially from 0.05% to 5% by weight relative to the total weight of the composition under consideration.
  • composition of the invention does not contain any synthetic direct dyes, i.e. dyes that do not occur in nature.
  • Compositions A and/or B comprising the ingredients i) and ii) as defined previously, and also composition C according to the invention, may also comprise one or more oxidation bases and/or one or more couplers conventionally used for the dyeing of keratin fibres.
  • oxidation bases mention may be made of para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, bis-para-aminophenols, ortho- aminophenols and heterocyclic bases, and the addition salts thereof.
  • composition A and/or B and/or C of the invention does not contain any para-phenylenediamine(s).
  • couplers Mention may in particular be made, among these couplers, of meta- phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene couplers, heterocyclic couplers and their addition salts.
  • the oxidation base(s) present in the composition(s) are each generally present in an amount of between 0.001 % and 10% by weight of the total weight of the dyeing composition(s).
  • compositions A and/or B and/or C do not contain any oxidation dyes.
  • composition A and/or composition B and/or composition C comprise iv) one or more additional direct dyes other than the powder of indigo-yielding plant(s) i), chosen from red henna; preferentially, composition A, B and/or C also comprise(s) iv) red henna, preferably in powder form, in particular in the form of fine particles, it being understood that the particle size of the powder is as defined previously for the powder of indigo-yielding plant(s)
  • composition A, B and/or C contain(s) a content of red henna which is equivalent to that of the indigo, which particularly represents from 0.001 % to 70% by weight of the total weight of the composition and more particularly from 0,05% to 50% by weight, more particularly from 0.5% to 40% by weight, relative to the total weight of the composition under consideration. pH of compositions B and C
  • the pH of aqueous composition B containing the ingredients i), ii) and optionally iii) and also the pH of aqueous composition C are neutral, i.e. they have a pH of about 7 (preferably ranging from 6 to 8 and better still from 6.5 to 7.5).
  • composition B of the invention and/or composition C is acidic and preferably has a pH ranging from 3 to 6.5.
  • composition B and/or C may be adjusted to the desired value by means of acidifying or basifying agents usually used in the dyeing of keratin fibres or alternatively with the aid of standard buffer systems, or of clays as defined previously present in composition A or in the aqueous composition mixed with composition A to give composition B and/or in composition C.
  • acidifying agents for the compositions used in the invention examples that may be mentioned include inorganic or organic acids, for instance hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids, for instance acetic acid, tartaric acid, citric acid or lactic acid, or sulfonic acids; the acid is preferably an organic acid such as citric acid.
  • inorganic or organic acids for instance hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids, for instance acetic acid, tartaric acid, citric acid or lactic acid, or sulfonic acids
  • the acid is preferably an organic acid such as citric acid.
  • composition A is added to composition A or to the poultice, or to composition C according to the invention.
  • this alkaline agent is chosen from aqueous ammonia, alkali metal carbonates, alkanolamines such as monoethanolamine, diethanolamine or triethanolamine, and also derivatives thereof, sodium hydroxide, potassium hydroxide and the compounds of formula (I) below:
  • W is a propylene residue optionally substituted with a hydroxyl group or a C1-C4 alkyl radical
  • R a , R b , R c and R d which may be identical or different, represent a hydrogen atom or a C1-C4 alkyl or C1-C4 hydroxyalkyl radical.
  • composition A, B and/or C of the invention that is at a neutral pH.
  • composition of the invention may be obtained in the following manner:
  • the ingredients i), ii) and optionally iii) as defined are mixed by hand or with a standard mixer and/or an extruder.
  • the dyeing process is performed in several steps:
  • the first step consists in preparing composition B of the invention, in particular in the form of a creamy poultice, as defined previously, using composition A of the invention;
  • the keratin fibres are rinsed with water until the poultice has disappeared, preferably without shampooing;
  • the keratin fibres may then be dried or left to dry naturally, without a hairdryer.
  • the dyeing process is performed in several steps:
  • the first step consists in preparing composition B of the invention as described previously;
  • composition B is left to stand for several hours, preferably 24 hours, and composition B is then applied and left on said fibres preferably for a minimum time of 30 minutes (preferably ranging from minutes to 24 hours and better still from 1 hour to 12 hours);
  • the keratin fibres are rinsed with water until the poultice has disappeared, preferably without shampooing;
  • the keratin fibres may then be dried or left to dry naturally, without a hairdryer.
  • the aqueous composition mixed with composition A, preferably water, used in the first step may be at ambient temperature or at a higher temperature, in particular at a temperature ranging from 40°C to 98°C.
  • the composition is mixed with or crumbled into an aqueous composition, preferably water, at a temperature below 40°C, in particular between 10°C and 40°C.
  • the ratio amount by weight of composition of the invention/amount by weight of aqueous composition and preferably water ranges from 1/1 to 1/3 and is preferably 1/2.
  • Use may be made, both as means for heating and straightening the head of hair, of a heating iron at a temperature ranging from 60°C to 220°C and preferably from 120°C to 200°C.
  • One particular mode of the invention relates to a dyeing process which is carried out at ambient temperature (25°C).
  • compositions (A) to (C) were prepared:
  • Indigo plant (Indigofera tinctoria) leaf powder 75 g%
  • Indigo plant (Indigofera tinctoria) leaf powder 75 g%
  • Indigo plant (Indigofera tinctoria) leaf powder 70 g%
  • Indigo plant (Indigofera tinctoria) leaf powder 65 g%
  • compositions (A), ( ⁇ '), (A"), (B), ( ⁇ '), (B"), (C), and (C) were conventionally compacted.
  • the compositions of the invention, even compacted, are easy to split by hand, while not being pulverulent.
  • the mixing is performed easily, and the compositions, even compacted, disintegrate rapidly in water.
  • the poultice obtained is very creamy and is easy to apply to the keratin fibres, totally impregnating the keratin fibres from the root to the end.
  • the poultice is applied to dry natural grey hair containing 90% white hairs, with a leave-on time of 60 minutes.
  • the hair is rinsed carefully.
  • the hair is dried.
  • the hair is soft and smooth to the touch.
  • the colouration is very persistent with regard to washing operations and light.
  • Colorimetric results The colouration of the hair is evaluated visually and read on a Minolta spectrocolorimeter (CM3600d, illuminant D65, angle 10°, SCI values) for the L * , a * , b * colorimetric measurements.
  • CM3600d Minolta spectrocolorimeter
  • L * represents the intensity of the colour
  • a * indicates the green/red colour axis
  • b * indicates the blue/yellow colour axis.
  • the lower the value of L the darker or more vivid the colour.
  • the higher the value of a * the redder the shade and, the higher the value of b * , the yellower the shade.
  • L * , a * and b * represent the values measured after dyeing natural hair containing 90% white hairs
  • L 0 * , a 0 * and b 0 * represent the values measured for untreated natural/permanent-waved hair containing 90% white hairs.
  • Composition (A) 32.53 7.18 -9.3 1 1.75 30.68
  • Composition (B) 43.16 8.36 13.77 16.1 1 22.4

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition A, qui est de préférence compacte et/ou anhydre, comprenant au moins 20 % de poudre de plante(s) produisant de l'indigo et au moins une huile et/ou un beurre, ainsi qu'une composition aqueuse B, de préférence sous la forme de cataplasme, pour la teinture de fibres kératiniques, le procédé de teinture de fibres kératiniques par le traitement desdites fibres avec ladite composition, et l'utilisation de la composition et d'un cataplasme pour teinter des fibres kératiniques. Les compositions A et B selon l'invention permettent la teinture de fibres kératiniques avec des résultats de teinture forts et chromatiques qui résistent au lavage, à la transpiration, au sébum et à la lumière, et qui de plus durent longtemps, sans abîmer lesdites fibres. En outre, l'utilisation des compositions A et B ne dégage aucune poussière de matière première (sans poussière). Ces compositions sont faciles à utiliser, en toute sécurité et sans risque de se tâcher. En plus, la composition A et l'agent actif de teinture restent stables en stockage. Les fibres kératiniques traitées peuvent présenter un aspect esthétique très plaisant et leur intégrité est respectée.
EP12795827.0A 2011-12-09 2012-12-06 Composition à base de poudre de plante(s) produisant de l'indigo et d'huile(s) et/ou de beurre(s), et procédé de teinture de cheveux à l'aide de ladite composition Withdrawn EP2787964A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
FR1161384A FR2983725B1 (fr) 2011-12-09 2011-12-09 Composition a base de poudres de plante(s) indigofere(s) et de beurres, procede de coloration capillaire mettant en oeuvre cette composition
FR1161383A FR2983724B1 (fr) 2011-12-09 2011-12-09 Composition a base de poudre de plante(s) indigofere(s) et d'huiles, procede de coloration capillaire mettant en oeuvre cette composition
US201161581156P 2011-12-29 2011-12-29
US201161581177P 2011-12-29 2011-12-29
PCT/EP2012/074654 WO2013083699A1 (fr) 2011-12-09 2012-12-06 Composition à base de poudre de plante(s) produisant de l'indigo et d'huile(s) et/ou de beurre(s), et procédé de teinture de cheveux à l'aide de ladite composition

Publications (1)

Publication Number Publication Date
EP2787964A1 true EP2787964A1 (fr) 2014-10-15

Family

ID=48573604

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12795827.0A Withdrawn EP2787964A1 (fr) 2011-12-09 2012-12-06 Composition à base de poudre de plante(s) produisant de l'indigo et d'huile(s) et/ou de beurre(s), et procédé de teinture de cheveux à l'aide de ladite composition

Country Status (3)

Country Link
EP (1) EP2787964A1 (fr)
IN (1) IN2014KN01259A (fr)
WO (1) WO2013083699A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3004943B1 (fr) 2013-04-26 2015-05-15 Oreal Composition comprenant du henne et/ou de l'indigo, une huile et un saccharide, et procede de coloration capillaire la mettant en œuvre
FR3097760B1 (fr) * 2019-06-28 2022-04-01 Oreal Procédé de coloration des fibres kératiniques comprenant l’application d’un mélange extemporané d’un colorant direct etd’une composition comprenant un corps gras liquide, un corps gras solide et un tensioactif.
FR3098118B1 (fr) * 2019-07-05 2021-06-11 Oreal Composition comprenant un colorant naturel, un colorant direct cationique anthraquinonique et un composé aromatique
FR3098116B1 (fr) * 2019-07-05 2021-06-18 Oreal Composition comprenant un colorant naturel, un colorant direct triarylméthane et un composé aromatique
FR3098114B1 (fr) * 2019-07-05 2022-11-11 Oreal Composition comprenant un colorant naturel, un colorant direct synthétique cationique hydrazono et/ou azoïque et un composé aromatique
WO2023139349A2 (fr) * 2022-01-18 2023-07-27 Cosmetic Warriors Limited Composition
FR3134518A1 (fr) * 2022-04-15 2023-10-20 Farevacare Composition cosmetique solide pour le soin et la coloration semi-permanente des fibres keratiniques

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE20100721U1 (de) * 2001-01-16 2001-04-12 Wella Ag Mittel zum Färben keratinischer Fasern

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3609962A1 (de) * 1985-12-14 1987-06-19 Hartmut Panke Haarfaerbemittel
DE19548291A1 (de) 1995-12-22 1997-06-26 Henkel Kgaa Färbeverfahren und Färbemittel auf natürlicher Basis
DE19600225A1 (de) * 1996-01-05 1997-07-10 Henkel Kgaa Staubarme Färbemittel auf natürlicher Basis
EP0806200A3 (fr) * 1996-05-09 2000-08-16 Wella Aktiengesellschaft Composition et procédé de coloration des fibres kératiniques
EP0806199A3 (fr) 1996-05-09 2000-08-16 Wella Aktiengesellschaft Composition et procédé de teinture des fibres kératiniques
GB2369995B (en) 2000-12-15 2004-06-16 Lush Ltd Henna product
DE10131385A1 (de) 2001-06-25 2003-01-30 Real Chemical Co Ltd Haarfärbemittel und Haarfärbemethode unter Verwendung desselben

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE20100721U1 (de) * 2001-01-16 2001-04-12 Wella Ag Mittel zum Färben keratinischer Fasern

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2013083699A1 *

Also Published As

Publication number Publication date
WO2013083699A1 (fr) 2013-06-13
IN2014KN01259A (en) 2015-10-16

Similar Documents

Publication Publication Date Title
EP2787965B1 (fr) Composition à base de poudre de henné rouge et d'une ou plusieurs huiles et procédé de coloration de cheveux utilisant cette composition
JP6831410B2 (ja) ポリマーを含んでなる粒子を含有する分散物および組成物
WO2013083699A1 (fr) Composition à base de poudre de plante(s) produisant de l'indigo et d'huile(s) et/ou de beurre(s), et procédé de teinture de cheveux à l'aide de ladite composition
WO2014174114A2 (fr) Procédé de coloration de cheveux utilisant du henné puis de l'indigo et une huile et/ou un beurre
US11986549B2 (en) Method for treating keratin fibers using a composition comprising at least one silicone acrylic copolymer and at least one pigment
WO2015082482A1 (fr) Procédé de coloration de matériaux kératiniques en utilisant une poudre de plantes produisant de l'indigo et un (des) agent(s) alcalins
EP2988722A2 (fr) Composition comprenant du henné et/ou de l'indigo, une huile et un saccharide, et procédé de coloration des cheveux l'utilisant
US20140102467A1 (en) Aqueous wax dispersions for altering the color of keratinous substrates
CN110327224A (zh) 压实粉末形式的固体化妆品组合物
EP3989915A1 (fr) Dispersion huileuse comprenant une particule polymère et un stabilisant renfermant un groupe alkyle en c9-c22 et procédé de traitement de matières kératiniques à l'aide de la dispersion huileuse
FR3004944A1 (fr) Composition comprenant du henne et/ou de l'indigo, un corps gras, un (bi)carbonate, et un acide, et procede de coloration capillaire la mettant en œuvre
WO2013083702A1 (fr) Composition à base de poudre de henné rouge et de beurre(s), et procédé de teinture de cheveux à l'aide de ladite composition
WO2019122332A1 (fr) Procédé en plusieurs étapes pour teinter des fibres de kératine à l'aide d'une poudre de plantes produisant de l'indigo, et pour un traitement de colorant alcalin
EP3727304A1 (fr) Procédé en plusieurs étapes pour colorer des fibres kératiniques au moyen d'une poudre de plante produisant de l'indigo, et traitement acide comprenant un colorant particulier
WO2016097248A1 (fr) Procédé de coloration de fibres de kératine à l'aide de henné pré-hydrolysé et décontaminé
WO2014174116A2 (fr) Composition basée sur une poudre de henné ou d'indigo ayant une prédispersion d'huile, et procédé de coloration de cheveux utilisant cette composition
FR2983725A1 (fr) Composition a base de poudres de plante(s) indigofere(s) et de beurres, procede de coloration capillaire mettant en oeuvre cette composition
WO2020126773A1 (fr) Composition de coloration de fibres de kératine, comprenant au moins un copolymère acrylique de silicone, au moins une résine de silicone et au moins un pigment
FR2983724A1 (fr) Composition a base de poudre de plante(s) indigofere(s) et d'huiles, procede de coloration capillaire mettant en oeuvre cette composition
US11534387B2 (en) Method for treating keratin fibers using a composition comprising at least one cationic acrylic copolymer and at least one pigment
CN117042748A (zh) 包含至少一种脂肪醇、非离子糖酯、乙基纤维素的反相乳液及采用该反相乳液的方法
FR3004945A1 (fr) Procede de coloration capillaire mettant en œuvre de du henne et/ou de l'indigo et une source de chaleur

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20140709

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

RIN1 Information on inventor provided before grant (corrected)

Inventor name: POURILLE, CHRYSTEL

DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20170320

RIC1 Information provided on ipc code assigned before grant

Ipc: A61K 8/92 20060101AFI20190403BHEP

Ipc: A61Q 5/06 20060101ALI20190403BHEP

Ipc: A61K 8/97 20170101ALI20190403BHEP

RIC1 Information provided on ipc code assigned before grant

Ipc: A61K 8/9789 20170101ALI20190405BHEP

Ipc: A61Q 5/06 20060101ALI20190405BHEP

Ipc: A61K 8/92 20060101AFI20190405BHEP

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20191029