EP2770286A1 - Method and apparatus for the production of high pressure oxygen and high pressure nitrogen - Google Patents
Method and apparatus for the production of high pressure oxygen and high pressure nitrogen Download PDFInfo
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- EP2770286A1 EP2770286A1 EP14000438.3A EP14000438A EP2770286A1 EP 2770286 A1 EP2770286 A1 EP 2770286A1 EP 14000438 A EP14000438 A EP 14000438A EP 2770286 A1 EP2770286 A1 EP 2770286A1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/04084—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
- F25J3/04193—Division of the main heat exchange line in consecutive sections having different functions
- F25J3/042—Division of the main heat exchange line in consecutive sections having different functions having an intermediate feed connection
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
- F25J3/04218—Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
- F25J3/04387—Details relating to the work expansion, e.g. process parameter etc. using liquid or hydraulic turbine expansion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
- F25J2240/10—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream the fluid being air
Definitions
- the invention relates to a method according to the preamble of patent claim 1.
- the basics of cryogenic separation of air in general and the construction of two-column systems in particular are described in the monograph " Cryogenics "by Hausen / Linde (2nd edition, 1985 ) and in one Review by Latimer in Chemical Engineering Progress (Vol. 63, No.2, 1967, page 35 ).
- the heat exchange relationship between the high-pressure column and the low-pressure column of a double column is generally realized by a main condenser, in which head gas of the high-pressure column is liquefied against vaporizing bottom liquid of the medium-pressure column.
- the distillation column system of the invention may be designed as a classical double column system, but also as a three or more column system. It may have, in addition to the columns for nitrogen-oxygen separation, other devices for obtaining other air components, in particular noble gases, for example an argon recovery.
- the main condenser is referred to as a "condenser-evaporator” is a heat exchanger in which a first, condensing fluid stream undergoes indirect heat exchange with a second, evaporating fluid stream.
- Each condenser-evaporator has a liquefaction space and an evaporation space, which consist of liquefaction passages or evaporation passages.
- the condensation (liquefaction) of a first fluid flow is performed, in the evaporation space the evaporation of a second fluid flow.
- Evaporation and liquefaction space are formed by groups of passages that are in heat exchange relationship with each other.
- the “main heat exchanger” is used to cool feed air under a first, subcritical pressure less than 1 bar above the operating pressure of the high pressure column, in indirect heat exchange with recycle streams from the distillation column system. It can be a single or multiple parallel and / or serial connected to heat exchanger sections, for example, from one or more plate heat exchanger blocks. When the heat exchanger sections are connected in parallel, an air feed stream flows below each of them below the first, subcritical pressure.
- wound heat exchanger In a "wound heat exchanger" several layers of tubes are wound onto a core tube. Through the individual tubes a medium is passed, which occurs in heat exchange with a flowing in the space between the tubes and a surrounding jacket medium. The tubes are brought together at the upper heat exchanger end in several groups and led out in the form of bundles from the outside.
- wound heat exchangers their preparation and their application are, for example, in Hausen / Linde, Tiefftemperaturtechnik, 2nd ed. 1985, p. 471-475 described.
- the invention has for its object to provide such a method and a corresponding device, which have a high efficiency at the same time relatively low expenditure on equipment and are particularly suitable for the supply of a coal gasification power plant (IGCC - Integrated Combined Cycle).
- IGCC coal gasification power plant
- the further increase in the energy efficiency of the process is the joint work-relaxing of the two parts of the second feed air flow in a liquid turbine (DLE - dense liquid expander).
- the mechanical energy generated at the liquid turbine can either be delivered directly to a compressor or converted into electrical energy via a generator.
- an equalizing flow (“third partial flow” of the second feed air stream) is taken from the high pressure heat exchanger system at an intermediate temperature and introduced into the main heat exchanger.
- the high-pressure heat exchanger system has at least two serially connected wound heat exchangers, between which the third partial flow is led out.
- These two serially connected coiled heat exchangers can be realized by two heat exchanger bundles in separate containers or by two serially connected heat exchanger bundles, which are arranged one above the other in the same container.
- the intermediate temperature at which the third partial flow is withdrawn from the high-pressure heat exchanger system and introduced into the main heat exchanger. is between 220 and 120 K, preferably between 190 and 150 K.
- the third partial flow can be conducted separately from the second partial flow through the high-pressure heat exchanger system; Preferably, however, it is guided together with the second partial flow through the warmer of the two wound heat exchanger.
- the high pressure heat exchanger system may also have three or more heat exchanger bundles.
- the first, subcritical pressure of the first feed air stream is preferably equal to the operating pressure of the high pressure column plus line losses and is for example between 5.0 and 6.0 bar, preferably between 5.3 and 5.7 bar.
- a third feed air stream may - optionally after recompression to a third pressure, which is between the first and the second pressure, be expanded in a gaseous state in an air turbine to perform cold work for the process; the inlet temperature of the air turbine is then at an intermediate level between the hot and cold end of the main heat exchanger.
- part of the air compressed to the second, supercritical pressure is released from an intermediate temperature to perform work.
- the total air is compressed to the first, subcritical pressure, pre-cooled and cleaned under this pressure and then divided into the first and second feed air stream. In principle, however, a completely separate compression of the first and the second feed air stream is possible.
- the total air is compressed in a main air compressor to a "first, subcritical pressure" of 6 bar and then pre-cooled and cleaned (not shown).
- the purified feed air 1 is divided into a first feed air stream 100, a second feed air stream 200 and a third feed air stream 300.
- the first feed air stream 100 is introduced under the first pressure in a main heat exchanger 2, flows through this completely from the warm to the cold end.
- the cooled to about dew point temperature first feed air stream 101 is introduced via line 3 in the high pressure column 4 of a distillation column system, which also has a low pressure column 5 and a main capacitor 6.
- the two columns as shown as a classic double column to be arranged one above the other; alternatively they stand side by side.
- the second feed air stream 200 is further compressed in a first after-compressor 7 with aftercooler 8 and further in a second after-compressor 9 with aftercooler 10 to a second, supercritical pressure of 85 bar and then branched again at 201.
- a first partial flow 210/211 of the second feed air stream 200 also flows through the main heat exchanger 2 completely from the hot to the cold end. Not at all through the main heat exchanger 2 flows a second feed air stream 220/221. This is completely cooled in a high-pressure heat exchanger system, which is formed in the embodiment of two coiled heat exchangers 11, 12, which are arranged in separate containers.
- the three sub-streams are reunited and then in a liquid turbine 13 to the operating pressure of the high-pressure column (about 6 bar) doing work relaxed.
- the liquid turbine is braked by a generator 14.
- the working expanded second feed air stream 205 is introduced into the high-pressure column 4 in a predominantly liquid state.
- a third partial stream 230 of the second feed air stream 200 is cooled together with the second partial stream 220 in the warm wound heat exchanger 11 to an intermediate temperature of 165 K and led out via line 203.
- they are further branched and the third substream 230 is fed to the main heat exchanger 2 at an intermediate location corresponding to its temperature and finally cooled there to the cold end.
- the fully cooled third substream 231 is combined at 204 with the remainder of the second feed air stream.
- a third feed air stream 300 is recompressed together with the second feed air stream 200 to a third pressure of 55 bar in the secondary compressor 7 and enters under this pressure in the warm end of the main heat exchanger. At a temperature which is slightly higher than the intermediate temperature of the second partial flow 230, it is removed again and expanded in an air turbine 15 to approximately the operating pressure of the high-pressure column 4 to perform work.
- the air turbine 15 drives the after-compressor 9.
- the expanded turbine air 303 is introduced in gaseous form into the high-pressure column 4 via line 3.
- a liquid oxygen stream 16 from the low-pressure column 5 is brought to a first product pressure in an oxygen pump 17 in the liquid state, which in the example is 115 bar, under this first product pressure in the high-pressure heat exchanger system 12/11 warmed to about ambient temperature and finally recovered as a high pressure oxygen product stream 18.
- the oxygen flows through the interior of the wound tubes of the heat exchangers 11 and 12, the feed air 202 or 206 through their outer space.
- a liquid nitrogen flow 19 from the high-pressure column 4 (it could also be taken from the main condenser 6) is brought in a nitrogen pump 20 in the liquid state to a second product pressure, which is in the embodiment at 80 bar, below this second product pressure to about ambient temperature warmed and finally recovered as a high pressure nitrogen product stream 21.
- a portion of the low-pressure nitrogen 23, 25 can be used for regeneration of the cleaning unit for the feed air (not shown).
- the warm pressure nitrogen can be used as a sealing gas 28 and / or medium-pressure product 29.
Abstract
Description
Die Erfindung betrifft ein Verfahren gemäß dem Oberbegriff des Patentanspruchs 1.The invention relates to a method according to the preamble of
Die Grundlagen der Tieftemperaturzerlegung von Luft im Allgemeinen sowie der Aufbau von Zwei-Säule-Anlagen im Speziellen sind in der Monografie "
Der Hauptkondensator ist als "Kondensator-Verdampfer " wird ein Wärmetauscher bezeichnet, in dem ein erster, kondensierender Fluidstrom in indirekten Wärmeaustausch mit einem zweiten, verdampfenden Fluidstrom tritt. Jeder Kondensator-Verdampfer weist einen Verflüssigungsraum und einen Verdampfungsraum auf, die aus Verflüssigungspassagen beziehungsweise Verdampfungspassagen bestehen. In dem Verflüssigungsraum wird die Kondensation (Verflüssigung) eines ersten Fluidstroms durchgeführt, in dem Verdampfungsraum die Verdampfung eines zweiten Fluidstroms. Verdampfungs- und Verflüssigungsraum werden durch Gruppen von Passagen gebildet, die untereinander in Wärmeaustauschbeziehung stehen.The main condenser is referred to as a "condenser-evaporator" is a heat exchanger in which a first, condensing fluid stream undergoes indirect heat exchange with a second, evaporating fluid stream. Each condenser-evaporator has a liquefaction space and an evaporation space, which consist of liquefaction passages or evaporation passages. In the liquefaction space, the condensation (liquefaction) of a first fluid flow is performed, in the evaporation space the evaporation of a second fluid flow. Evaporation and liquefaction space are formed by groups of passages that are in heat exchange relationship with each other.
Der "Hauptwärmetauscher" dient zur Abkühlung von Einsatzluft unter einem ersten, unterkritischen Druck, weniger als 1 bar über dem Betriebsdruck der Hochdrucksäule liegt, in indirektem Wärmeaustausch mit Rückströmen aus dem Destillationssäulen-System. Es kann aus einem einzelnen oder mehreren parallel und/oder seriell verbundenen Wärmetauscherabschnitten gebildet sein, zum Beispiel aus einem oder mehreren Plattenwärmetauscher-Blöcken. Sind die Wärmeaustauscherabschnitte parallel verbunden, strömt durch jeden von ihnen ein Einsatzluftstrom unter dem ersten, unterkritischen Druck.The "main heat exchanger" is used to cool feed air under a first, subcritical pressure less than 1 bar above the operating pressure of the high pressure column, in indirect heat exchange with recycle streams from the distillation column system. It can be a single or multiple parallel and / or serial connected to heat exchanger sections, for example, from one or more plate heat exchanger blocks. When the heat exchanger sections are connected in parallel, an air feed stream flows below each of them below the first, subcritical pressure.
Bei einem "gewickelten Wärmetauscher" sind mehrere Lagen von Rohren auf ein Kernrohr aufgewickelt. Durch die einzelnen Rohre wird ein Medium geleitet, welches in Wärmeaustausch mit einem in dem Raum zwischen den Rohren und einem umgebenden Mantel strömenden Medium tritt. Die Rohre werden am oberen Wärmetauscherende in mehreren Gruppen zusammengeführt und in Form von Bündeln aus dem Außenraum herausgeleitet. Derartige gewickelte Wärmetauscher, ihre Herstellung und ihre Anwendung sind beispielsweise in
Bei dem Prozess werden zwei flüssig auf Druck gebrachte Produktströme gegen einen Wärmeträger, insbesondere Einsatzluft unter besonders hohem Druck, verdampft und schließlich als gasförmiges Druckprodukt gewonnen. Diese Methode wird auch als "Innenverdichtung" bezeichnet. Sie dient zur Gewinnung von Drucksauerstoff und Druckstickstoff. Für den Fall eines überkritischen Drucks findet kein Phasenübergang im eigentlichen Sinne statt, der Produktstrom wird dann lediglich angewärmt; dies wird manchmal auch als "Pseudo-Verdampfung" bezeichnet.In the process, two fluidly pressurized product streams are vaporized against a heat transfer medium, in particular feed air under particularly high pressure, and finally recovered as a gaseous pressure product. This method is also called "internal compaction". It serves for the production of pressure oxygen and pressure nitrogen. In the case of a supercritical pressure, no phase transition takes place in the true sense, the product stream is then merely warmed; this is sometimes called "pseudo-evaporation".
Ein Verfahren der eingangs genannten Art ist aus
Der Erfindung liegt die Aufgabe zugrunde, ein derartiges Verfahren und eine entsprechende Vorrichtung anzugeben, die eine hohe Effizienz bei gleichzeitig relativ geringem apparativem Aufwand aufweisen und sich insbesondere für die Versorgung eines Kohlevergasungskraftwerks (IGCC - Integrated Combined Cycle) eignen.The invention has for its object to provide such a method and a corresponding device, which have a high efficiency at the same time relatively low expenditure on equipment and are particularly suitable for the supply of a coal gasification power plant (IGCC - Integrated Combined Cycle).
Diese Aufgabe wird durch die kennzeichnenden Merkmale des Patentanspruchs 1 gelöst.This object is solved by the characterizing features of
Zunächst erscheint es vernünftiger, durch den Hauptwärmetauscher nur die Niederdruckströme zu fahren, weil dieser dann besonders kostengünstig hergestellt werden kann. Im Rahmen der Erfindung hat sich jedoch überraschenderweise herausgestellt, dass es in vielen Fällen günstiger ist, den Hochdruckstickstoff in dem Hauptwärmetauscher zu verdampfen beziehungsweise zu pseudo-verdampfen. Vorzugsweise wird der gesamte flüssig auf Druck gebrachte Stickstoffstrom, der als Hochdruck-Stickstoff-Produktstrom gewonnen wird, in dem Hauptwärmetauscher in den Hauptwärmetauscher eingeleitet. Zwar wird dadurch tatsächlich der Aufwand am Hauptwärmetauscher größer, allerdings wird der Herstellungsaufwand für das entsprechend einfachere Hochdruck-Wärmetauscher-System überproportional geringer. Dies gilt sogar dann, wenn man den erhöhten Aufwand durch die Aufteilung des zweiten Einsatzluftstroms berücksichtigt.First, it seems more reasonable to drive through the main heat exchanger only the low pressure flows, because this can then be made particularly inexpensive. In the context of the invention, however, has surprisingly It has been found that in many cases it is more favorable to evaporate or pseudo-evaporate the high-pressure nitrogen in the main heat exchanger. Preferably, all of the liquid pressurized nitrogen stream recovered as the high pressure nitrogen product stream is introduced into the main heat exchanger in the main heat exchanger. Although this actually increases the complexity of the main heat exchanger, the production costs for the correspondingly simpler high-pressure heat exchanger system are disproportionately lower. This is true even when taking into account the increased effort by dividing the second feed air flow.
Der weiteren Erhöhung der energetischen Effizienz des Verfahrens dient die gemeinsame arbeitsleistende Entspannung der beiden Teile des zweiten Einsatzluftstroms in einer Flüssigturbine (DLE - dense liquid expander). Die an der Flüssigturbine erzeugte mechanische Energie kann entweder direkt an einen Verdichter abgegeben oder über einen Generator in elektrische Energie umgewandelt werden.The further increase in the energy efficiency of the process is the joint work-relaxing of the two parts of the second feed air flow in a liquid turbine (DLE - dense liquid expander). The mechanical energy generated at the liquid turbine can either be delivered directly to a compressor or converted into electrical energy via a generator.
Abweichend hiervon kann auch auf das Zusammenführen der beiden Teile des zweiten Einsatzluftstroms und/oder auf die Flüssigturbine verzichtet werden. Die beiden Teile werden dann beispielsweise getrennt oder gemeinsam in einem oder mehreren Drosselventilen auf den Druck des Destillationssäulen-Systems entspannt.Notwithstanding this, it is also possible to dispense with the merging of the two parts of the second feed air stream and / or on the liquid turbine. The two parts are then released, for example, separately or together in one or more throttle valves to the pressure of the distillation column system.
Bei der Erfindung wird ein Ausgleichsstrom ("dritter Teilstrom" des zweiten Einsatzluftstroms) bei einer Zwischentemperatur aus dem Hochdruck-Wärmetauscher-System entnommen und in den Hauptwärmetauscher eingeleitet. Durch diese Maßnahme können beide Wärmeaustauschprozesse stärker optimiert werden und arbeiten dadurch spürbar effizienter.In the invention, an equalizing flow ("third partial flow" of the second feed air stream) is taken from the high pressure heat exchanger system at an intermediate temperature and introduced into the main heat exchanger. As a result of this measure, both heat exchange processes can be optimized to a greater extent and thus work noticeably more efficiently.
Dazu weist das Hochdruck-Wärmetauscher-System mindestens zwei seriell verbundene gewickelte Wärmetauscher auf, zwischen denen der dritte Teilstrom herausgeführt wird. Diese zwei seriell verbundenen gewickelten Wärmetauscher können durch zwei Wärmetauscherbündel in separaten Behältern realisiert werden oder durch zwei seriell verbundene Wärmetauscherbündel, die übereinander im gleichen Behälter angeordnet sind.For this purpose, the high-pressure heat exchanger system has at least two serially connected wound heat exchangers, between which the third partial flow is led out. These two serially connected coiled heat exchangers can be realized by two heat exchanger bundles in separate containers or by two serially connected heat exchanger bundles, which are arranged one above the other in the same container.
Die Zwischentemperatur, bei welcher der dritte Teilstrom aus dem Hochdruck-Wärmetauscher-System abgezogen und in den Hauptwärmetauscher eingeleitet wird. liegt zwischen 220 und 120 K, vorzugsweise zwischen 190 und 150 K.The intermediate temperature at which the third partial flow is withdrawn from the high-pressure heat exchanger system and introduced into the main heat exchanger. is between 220 and 120 K, preferably between 190 and 150 K.
Der dritte Teilstrom kann separat vom zweiten Teilstrom durch das Hochdruck-Wärmetauscher-System geführt werden; vorzugsweise wird er jedoch gemeinsam mit dem zweiten Teilstrom durch den wärmeren der beiden gewickelten Wärmetauscher geführt. Selbstverständlich kann das Hochdruck-Wärmetauscher-System auch drei oder mehr Wärmetauscherbündel aufweisen.The third partial flow can be conducted separately from the second partial flow through the high-pressure heat exchanger system; Preferably, however, it is guided together with the second partial flow through the warmer of the two wound heat exchanger. Of course, the high pressure heat exchanger system may also have three or more heat exchanger bundles.
Vorzugsweise werden alle drei Teilströme des zweiten Einsatzluftstroms in der Flüssigturbine arbeitsleistend entspannt.
- Erster Produktdruck (Sauerstoff) höher als 100 bar, insbesondere höher als 110 bar, beispielsweise zwischen 105 und 135 bar.
- Zweiter Produktdruck niedriger als 100 bar, insbesondere niedriger als 90 bar, beispielsweise zwischen 30 und 80 bar.
- Zweiter, überkritischer Druck (oberes Luftdruckniveau) niedriger als der erste Produktdruck und insbesondere geringer als 100 bar, insbesondere geringer als 90 bar, beispielsweise zwischen 60 und 90 bar.
- First product pressure (oxygen) higher than 100 bar, in particular higher than 110 bar, for example between 105 and 135 bar.
- Second product pressure lower than 100 bar, in particular lower than 90 bar, for example between 30 and 80 bar.
- Second, supercritical pressure (upper air pressure level) lower than the first product pressure and in particular less than 100 bar, in particular less than 90 bar, for example between 60 and 90 bar.
Der erste, unterkritische Druck des ersten Einsatzluftstroms (Direktluft) ist vorzugsweise gleich dem Betriebsdruck der Hochdrucksäule plus Leitungsverlusten und liegt beispielsweise zwischen 5,0 und 6,0 bar, vorzugsweise zwischen 5,3 und 5,7 bar.The first, subcritical pressure of the first feed air stream (direct air) is preferably equal to the operating pressure of the high pressure column plus line losses and is for example between 5.0 and 6.0 bar, preferably between 5.3 and 5.7 bar.
Ein dritter Einsatzluftstrom kann - gegebenenfalls nach Nachverdichtung auf einen dritten Druck, der zwischen dem ersten und dem zweiten Druck liegt, in gasförmigem Zustand in einer Luftturbine arbeitsleistend entspannt werden, um Kälte für das Verfahren zu erzeugen; die Eintrittstemperatur der Luftturbine liegt dann auf einem Zwischenniveau zwischen warmem und kaltem Ende des Hauptwärmetauschers. Alternativ oder zusätzlich wird ein Teil der auf den zweiten, überkritischen Druck verdichteten Luft von einer Zwischentemperatur aus arbeitsleistend entspannt. Vorzugsweise wird bei dem Verfahren die Gesamtluft auf den ersten, unterkritischen Druck verdichtet, unter diesem Druck vorgekühlt und gereinigt und anschließend in den ersten und zweiten Einsatzluftstrom aufgeteilt. Grundsätzlich ist aber auch eine vollständig separate Verdichtung des ersten und des zweiten Einsatzluftstroms möglich.A third feed air stream may - optionally after recompression to a third pressure, which is between the first and the second pressure, be expanded in a gaseous state in an air turbine to perform cold work for the process; the inlet temperature of the air turbine is then at an intermediate level between the hot and cold end of the main heat exchanger. Alternatively or additionally, part of the air compressed to the second, supercritical pressure is released from an intermediate temperature to perform work. Preferably, in the method, the total air is compressed to the first, subcritical pressure, pre-cooled and cleaned under this pressure and then divided into the first and second feed air stream. In principle, however, a completely separate compression of the first and the second feed air stream is possible.
Die Erfindung sowie weitere Einzelheiten der Erfindung werden im Folgenden anhand eines in der Zeichnung schematisch dargestellten Ausführungsbeispiels näher erläutert.The invention and further details of the invention are explained in more detail below with reference to an embodiment schematically illustrated in the drawing.
Die Gesamtluft wird in einem Hauptluftverdichter auf einen "ersten, unterkritischen Druck" von 6 bar verdichtet und anschließend vorgekühlt und gereinigt (nicht dargestellt). Die gereinigte Einsatzluft 1 wird auf einen ersten Einsatzluftstrom 100, einen zweiten Einsatzluftstrom 200 und einen dritten Einsatzluftstrom 300 aufgeteilt.The total air is compressed in a main air compressor to a "first, subcritical pressure" of 6 bar and then pre-cooled and cleaned (not shown). The purified
Der erste Einsatzluftstrom 100 wird unter dem ersten Druck in einen Hauptwärmetauscher 2 eingeleitet, durchströmt diesen komplett vom warmen bis zum kalten Ende. Der auf etwa Taupunktstemperatur abgekühlte erste Einsatzluftstrom 101 wird über Leitung 3 in die Hochdrucksäule 4 eines Destillationssäulen-Systems eingeleitet, das außerdem eine Niederdrucksäule 5 und einen Hauptkondensator 6 aufweist. Die beiden Säulen wie dargestellt als klassische Doppelsäule übereinander angeordnet sein; alternativ stehen sie nebeneinander.The first
Der zweite Einsatzluftstrom 200 wird in einem ersten Nachverdichter 7 mit Nachkühler 8 und weiter in einem zweiten Nachverdichter 9 mit Nachkühler 10 weiter auf einen zweiten, überkritischen Druck von 85 bar verdichtet und anschließend bei 201 erneut verzweigt. Ein erster Teilstrom 210/211 des zweiten Einsatzluftstroms 200 durchströmt ebenfalls den Hauptwärmetauscher 2 komplett vom warmen bis zum kalten Ende. Überhaupt nicht durch den Hauptwärmetauscher 2 strömt ein zweiter Einsatzluftstrom 220/221. Dieser wird komplett in einem Hochdruck-Wärmetauscher-System abgekühlt, das in dem Ausführungsbeispiel aus zwei gewickelten Wärmetauschern 11, 12 gebildet wird, die in separaten Behältern angeordnet sind.The second
Bei 204 werden die drei Teilströme wieder vereinigt und anschließend in einer Flüssigturbine 13 auf den Betriebsdruck der Hochdrucksäule (etwa 6 bar) arbeitsleistend entspannt. Die Flüssigturbine wird von einem Generator 14 gebremst. Der arbeitsleistend entspannte zweite Einsatzluftstrom 205 wird in überwiegend flüssigem Zustand in die Hochdrucksäule 4 eingeleitet.At 204, the three sub-streams are reunited and then in a liquid turbine 13 to the operating pressure of the high-pressure column (about 6 bar) doing work relaxed. The liquid turbine is braked by a generator 14. The working expanded second
Ein dritter Teilstrom 230 des zweiten Einsatzluftstroms 200 wird gemeinsam mit dem zweiten Teilstrom 220 in dem warmen gewickelten Wärmetauscher 11 auf eine Zwischentemperatur von 165 K abgekühlt und über Leitung 203 herausgeführt. Bei 206 werden sie weiter verzweigt und der dritte Teilstrom 230 wird dem Hauptwärmtauscher 2 an einer Zwischenstelle zugeführt, die seiner Temperatur entspricht und schließlich dort bis zum kalten Ende abgekühlt. Der vollständig abgekühlte dritte Teilstrom 231 wird bei 204 mit dem Rest des zweiten Einsatzluftstroms vereinigt.A third
Ein dritter Einsatzluftstrom 300 wird gemeinsam mit dem zweiten Einsatzluftstrom 200 auf einen dritten Druck von 55 bar im Nachverdichter 7 nachverdichtet und tritt unter diesem Druck in das warme Ende des Hauptwärmtauschers ein. Bei einer Temperatur, die etwas höher als die Zwischentemperatur des zweiten Teilstroms 230 ist, wird er wieder entnommen und in einer Luftturbine 15 auf etwa den Betriebsdruck der Hochdrucksäule 4 arbeitsleistend entspannt. Die Luftturbine 15 treibt den Nachverdichter 9 an. Die entspannte Turbinenluft 303 wird über Leitung 3 gasförmig in die Hochdrucksäule 4 eingeleitet.A third
Ein flüssiger Sauerstoffstrom 16 aus der Niederdrucksäule 5 wird in einer Sauerstoffpumpe 17 in flüssigem Zustand auf einen ersten Produktdruck gebracht, der in dem Beispiel bei 115 bar liegt, unter diesem ersten Produktdruck in dem Hochdruck-Wärmetauscher-System 12/11 auf etwa Umgebungstemperatur angewärmt und schließlich als Hochdruck-Sauerstoff-Produktstrom 18 gewonnen. Der Sauerstoff strömt durch das Innere der gewickelten Rohre der Wärmetauscher 11 und 12, die Einsatzluft 202 beziehungsweise 206 durch deren Außenraum.A
Ein flüssiger Stickstoffstrom 19 aus der Hochdrucksäule 4 (er könnte auch aus dem Hauptkondensator 6 entnommen werden) wird in einer Stickstoffpumpe 20 in flüssigem Zustand auf einen zweiten Produktdruck gebracht wird, der in dem Ausführungsbeispiel bei 80 bar liegt, unter diesem zweiten Produktdruck auf etwa Umgebungstemperatur angewärmt und schließlich als Hochdruck-Stickstoff-Produktstrom 21 gewonnen.A
Außerdem werden die folgenden Gasströme im Hauptwärmetauscher 2 angewärmt:
- praktisch druckloser gasförmiger Reinstickstoff 22/23 vom
Kopf der Niederdrucksäule 5, - praktisch druckloser gasförmiger Unreinstickstoff 24/25 von einer Zwischenstelle der der
Niederdrucksäule 5 und gasförmiger Druckstickstoff 26/27 vomKopf der Hochdrucksäule 4.
- virtually pressureless gaseous
pure nitrogen 22/23 from the top of the low-pressure column 5, - practically non-pressurized gaseous
impure nitrogen 24/25 from an intermediate point of the low-pressure column 5 and -
gaseous pressure nitrogen 26/27 from the top of the high-pressure column 4.
Ein Teil des Niederdruckstickstoff 23, 25 kann zur Regenerierung der Reinigungseinheit für die Einsatzluft (nicht dargestellt) eingesetzt werden. Der warme Druckstickstoff kann als Dichtgas 28 und/oder als Mitteldruckprodukt 29 genutzt werden.A portion of the low-
Claims (7)
dadurch gekennzeichnet, dass
characterized in that
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marked by
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GB0422635D0 (en) * | 2004-10-12 | 2004-11-10 | Air Prod & Chem | Process for the cryogenic distillation of air |
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EP2770286B1 (en) | 2017-05-24 |
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