EP2737960A1 - Screw and method for manufacturing the same - Google Patents

Screw and method for manufacturing the same Download PDF

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Publication number
EP2737960A1
EP2737960A1 EP13172449.4A EP13172449A EP2737960A1 EP 2737960 A1 EP2737960 A1 EP 2737960A1 EP 13172449 A EP13172449 A EP 13172449A EP 2737960 A1 EP2737960 A1 EP 2737960A1
Authority
EP
European Patent Office
Prior art keywords
segment
screw
screw body
further characterized
head portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13172449.4A
Other languages
German (de)
French (fr)
Inventor
Ming-Feng Hu
Chih-Chun Hsieh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sol Full International Ltd
Original Assignee
Sol Full International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sol Full International Ltd filed Critical Sol Full International Ltd
Publication of EP2737960A1 publication Critical patent/EP2737960A1/en
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B33/00—Features common to bolt and nut
    • F16B33/008—Corrosion preventing means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00—Metallic substrate
    • B05D2202/10—Metallic substrate based on Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2258/00—Small objects (e.g. screws)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B05D3/0272—After-treatment with ovens
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B25/00—Screws that cut thread in the body into which they are screwed, e.g. wood screws
    • F16B25/10—Screws performing an additional function to thread-forming, e.g. drill screws or self-piercing screws
    • F16B25/103—Screws performing an additional function to thread-forming, e.g. drill screws or self-piercing screws by means of a drilling screw-point, i.e. with a cutting and material removing action

Definitions

  • the invention relates to a screw and a method for manufacturing the same, more particularly to a bimetal screw and a method for manufacturing the same.
  • a conventional screw includes a screw body 11 and a protecting layer 21 formed on an outer surface of the screw body 11.
  • the screw body 11 includes a head portion 12 and a shank portion 13 extended from the head portion 12.
  • the shank portion 13 has a first segment 131 which is connected to the head portion 12 and a second segment 132 which is connected to the first segment 131.
  • the head portion 12 and the first segment 131 of the shank portion 13 are made of austenitic stainless steel which provides a superior anti-corrosion capability, and the second segment 132 of the shank portion 13 is made of low carbon steel which provides a superior drilling ability.
  • the protective layer 21 can be coated on the outer surface of the screw body 11 by electroplating or by painting, so as to increase the anti-corrosion ability of the conventional screw.
  • a carburizing process is usually performed on a surface of the second segment 132 for improving the surface hardness thereof.
  • a baking process is required to be conducted under a temperature ranging from 200°C to 220°C.
  • the high temperature results in re-annealing of the steel material and adversely affects the hardness and drilling ability thereof.
  • the conventional screw only has ability to drill through a steel plate that has a thickness less than 5mm, and cannot be used to drill through a stainless steel plate.
  • the electroplating or painting process causes massive environmental pollution and increases the production cost of the conventional screw.
  • the inaccuracy of the carburizing process often results in the surface carburization of the first segment 131 instead of merely the second segment 132, thereby affecting the anti-corrosion ability of the first segment 131.
  • the object of the present invention is to provide a screw that may alleviate the aforesaid drawbacks of the prior art.
  • a method for manufacturing a screw includes the following steps of:
  • a screw includes:
  • the preferred embodiment of a method for manufacturing a screw according to the present invention is shown to include steps 51 to 57.
  • a screw body 3 is provided.
  • the screw body 3 has an outer surface and includes a head portion 31 and a shank portion 32 that extends from the head portion 31 and that has a first segment 321 which is connected to the head portion 31, and a second segment 322 which is connected to the first segment 321.
  • the head portion 31 and the first segment 321 of the shank portion 32 are made of an austenitic stainless steel, and the second segment 322 of the shank portion 32 is made of a Cr-Mo alloy steel.
  • the head portion 31 and the first segment 321 of the shank portion 32 are made of one of SUS304 stainless steel and SUS3016 stainless steel, and the second segment 322 of the shank portion 32 is made of one of SCM435 Cr-Mo alloy steel and SCM440 Cr-Mo alloy steel. Due to the material property of each of the first and second segments 321 and 322 of the shank portion 32, the surface color of the second segment 322 is darker than that of the first segment 321.
  • a surface of the second segment 322 of the shank portion 32 is hardened by a high frequency induction hardening method. Since the high frequency induction hardening method has higher accuracy than a conventional carburizing method and is suitable for the Cr-Mo alloy steel, it is easier to precisely perform the hardening method on the second segment 322 of the screw body 3 without affecting the first segment 321.
  • the outer surface of the screw body 3 is washed with acid.
  • the screw body 3 is immersed into an acid solution with a pH value ranging from 1 to 2 for 3 to 5 minutes.
  • the acid solution can be a nitric acid solution, a hydrochloric acid solution, and so forth.
  • the screw body 3 is removed from the acid solution and washed with water to remove the acid solution and impurities, followed by drying the screw body 3 at a temperature under 80°C.
  • the screw body 3 is immersed into a solution at room temperature for 10 to 20 seconds, wherein the solution is composed of diethylene glycol monobutyl ether acetate, water borne organic-inorganic copolymer resin, and water.
  • the weight percentage of diethylene glycol monobutyl ether acetate ranges from 10 wt% to 20 wt%
  • the weight percentage of water borne organic-inorganic copolymer resin ranges from 15 wt% to 30 wt%
  • the weight percentage of water ranges from 50 wt% to 75 wt%.
  • the weight percentage of diethylene glycol monobutyl ether acetate is 15 wt%
  • the weight percentage of water borne organic-inorganic copolymer resin is 22 wt%
  • the weight percentage of water is 63 wt%.
  • the screw body 3 is removed from the solution, followed by centrifuging and baking the screw body 3 at a temperature ranging from 80°C to 110°C for 20 minutes, so as to form a uniform first transparent layer 41 on the outer surface of the screw body 3.
  • a temperature ranging from 80°C to 110°C for 20 minutes is lower than the conventional annealing temperature for steels or alloy steels and does not lower the hardness of the second segment 322 of the screw body 3 so as to achieve a higher production yield of the screw of the present invention.
  • the screw body 3 with the first transparent layer 41 is immersed into the same solution at room temperature for 10 to 20 seconds.
  • the screw body 3 is removed from the solution, followed by centrifuging and baking at a temperature ranging from 80°C to 110°C for 20 minutes, so as to form a uniform second transparent layer 42 on the first transparent layer 41.
  • the resultant screw according to the present invention includes the screw body 3, the first transparent layer 41, and the second transparent layer 42.
  • Each of the first and second transparent layers 41 and 42 is composed of diethylene glycol monobutyl ether acetate and water borne organic-inorganic copolymer resin.
  • the first and second transparent layers 41 and 42 of the screw have good lubricity and low friction due to the compositions thereof. Therefore, the first and second transparent layers 41 and 42 of the screw are capable of not only protecting the screw body 3 from corrosion but also increasing the drilling ability of the screw. Further, no electroplating or painting process is needed, thereby reducing the environmental pollution and the production cost of the screw, while maintaining the hardness of the second segment 322 and the production yield of the screw. In practical testing, the actual cost of the screw of the present invention is 16% lower than that of the conventional screw and is capable of drilling through a steel plate that has a thickness less than 17mm or through a stainless steel plate that has a thickness less than 6mm.

Abstract

A method for manufacturing a screw includes the following steps of: providing a screw body (3) having an outer surface and including a head portion (31) and a shank portion (32) that extends from the head portion (31); immersing the screw body (3) into a solution composed of diethylene glycol monobutyl ether acetate, water borne organic-inorganic copolymer resin and water; and removing the screw body (3) from the solution, followed by baking the screw so as to form a transparent layer (41) on the screw body (3).

Description

  • The invention relates to a screw and a method for manufacturing the same, more particularly to a bimetal screw and a method for manufacturing the same.
  • Referring to Figure 1, a conventional screw includes a screw body 11 and a protecting layer 21 formed on an outer surface of the screw body 11. The screw body 11 includes a head portion 12 and a shank portion 13 extended from the head portion 12. The shank portion 13 has a first segment 131 which is connected to the head portion 12 and a second segment 132 which is connected to the first segment 131. The head portion 12 and the first segment 131 of the shank portion 13 are made of austenitic stainless steel which provides a superior anti-corrosion capability, and the second segment 132 of the shank portion 13 is made of low carbon steel which provides a superior drilling ability. The protective layer 21 can be coated on the outer surface of the screw body 11 by electroplating or by painting, so as to increase the anti-corrosion ability of the conventional screw. A carburizing process is usually performed on a surface of the second segment 132 for improving the surface hardness thereof.
  • During electroplating or painting the protective layer 21, a baking process is required to be conducted under a temperature ranging from 200°C to 220°C. The high temperature results in re-annealing of the steel material and adversely affects the hardness and drilling ability thereof. In practical testing, the conventional screw only has ability to drill through a steel plate that has a thickness less than 5mm, and cannot be used to drill through a stainless steel plate. Moreover, the electroplating or painting process causes massive environmental pollution and increases the production cost of the conventional screw. Furthermore, the inaccuracy of the carburizing process often results in the surface carburization of the first segment 131 instead of merely the second segment 132, thereby affecting the anti-corrosion ability of the first segment 131.
  • Therefore, the object of the present invention is to provide a screw that may alleviate the aforesaid drawbacks of the prior art.
  • According to one aspect of the present invention, a method for manufacturing a screw includes the following steps of:
    1. (a) providing a screw body that has an outer surface and that includes a head portion and a shank portion extending from the head portion;
    2. (b) immersing the screw body into a solution that is composed of diethylene glycol monobutyl ether acetate, water borne organic-inorganic copolymer resin, and water; and
    3. (c) removing the screw body from the solution, followed by drying and baking the screw body so as to form a transparent layer on the outer surface of the screw body.
  • According to another aspect of the present invention, a screw includes:
    • a screw body having an outer surface and including a head portion and a shank portion that extends from the head portion; and
    • a transparent layer formed on an outer surface of the screw body and composed of diethylene glycol monobutyl ether acetate and water borne organic-inorganic copolymer resin.
  • Other features and advantages of the present invention will become apparent in the following detailed description of the preferred embodiment with reference to the accompanying drawings, of which:
    • Figure 1 is a partly sectional view of a conventional screw;
    • Figure 2 is a flow chart illustrating the preferred embodiment of a method for manufacturing a screw according to the present invention; and
    • Figure 3 is a partly sectional view of the preferred embodiment of a screw according to the present invention.
  • Referring to Figures 2 and 3, the preferred embodiment of a method for manufacturing a screw according to the present invention is shown to include steps 51 to 57.
  • At Step 51, a screw body 3 is provided. The screw body 3 has an outer surface and includes a head portion 31 and a shank portion 32 that extends from the head portion 31 and that has a first segment 321 which is connected to the head portion 31, and a second segment 322 which is connected to the first segment 321. The head portion 31 and the first segment 321 of the shank portion 32 are made of an austenitic stainless steel, and the second segment 322 of the shank portion 32 is made of a Cr-Mo alloy steel. Preferably, the head portion 31 and the first segment 321 of the shank portion 32 are made of one of SUS304 stainless steel and SUS3016 stainless steel, and the second segment 322 of the shank portion 32 is made of one of SCM435 Cr-Mo alloy steel and SCM440 Cr-Mo alloy steel. Due to the material property of each of the first and second segments 321 and 322 of the shank portion 32, the surface color of the second segment 322 is darker than that of the first segment 321.
  • At Step 52, a surface of the second segment 322 of the shank portion 32 is hardened by a high frequency induction hardening method. Since the high frequency induction hardening method has higher accuracy than a conventional carburizing method and is suitable for the Cr-Mo alloy steel, it is easier to precisely perform the hardening method on the second segment 322 of the screw body 3 without affecting the first segment 321.
  • At Step 53, the outer surface of the screw body 3 is washed with acid. In this embodiment, the screw body 3 is immersed into an acid solution with a pH value ranging from 1 to 2 for 3 to 5 minutes. The acid solution can be a nitric acid solution, a hydrochloric acid solution, and so forth. The screw body 3 is removed from the acid solution and washed with water to remove the acid solution and impurities, followed by drying the screw body 3 at a temperature under 80°C.
  • At Step 54, the screw body 3 is immersed into a solution at room temperature for 10 to 20 seconds, wherein the solution is composed of diethylene glycol monobutyl ether acetate, water borne organic-inorganic copolymer resin, and water. Preferably, based on the total weight of the solution, the weight percentage of diethylene glycol monobutyl ether acetate ranges from 10 wt% to 20 wt%, the weight percentage of water borne organic-inorganic copolymer resin ranges from 15 wt% to 30 wt%, and the weight percentage of water ranges from 50 wt% to 75 wt%. In this embodiment, the weight percentage of diethylene glycol monobutyl ether acetate is 15 wt%, the weight percentage of water borne organic-inorganic copolymer resin is 22 wt%, and the weight percentage of water is 63 wt%.
  • At Step 55, the screw body 3 is removed from the solution, followed by centrifuging and baking the screw body 3 at a temperature ranging from 80°C to 110°C for 20 minutes, so as to form a uniform first transparent layer 41 on the outer surface of the screw body 3. Such temperature is lower than the conventional annealing temperature for steels or alloy steels and does not lower the hardness of the second segment 322 of the screw body 3 so as to achieve a higher production yield of the screw of the present invention.
  • At Step 56, the screw body 3 with the first transparent layer 41 is immersed into the same solution at room temperature for 10 to 20 seconds.
  • At Step 57, the screw body 3 is removed from the solution, followed by centrifuging and baking at a temperature ranging from 80°C to 110°C for 20 minutes, so as to form a uniform second transparent layer 42 on the first transparent layer 41.
  • The resultant screw according to the present invention includes the screw body 3, the first transparent layer 41, and the second transparent layer 42. Each of the first and second transparent layers 41 and 42 is composed of diethylene glycol monobutyl ether acetate and water borne organic-inorganic copolymer resin.
  • The first and second transparent layers 41 and 42 of the screw have good lubricity and low friction due to the compositions thereof. Therefore, the first and second transparent layers 41 and 42 of the screw are capable of not only protecting the screw body 3 from corrosion but also increasing the drilling ability of the screw. Further, no electroplating or painting process is needed, thereby reducing the environmental pollution and the production cost of the screw, while maintaining the hardness of the second segment 322 and the production yield of the screw. In practical testing, the actual cost of the screw of the present invention is 16% lower than that of the conventional screw and is capable of drilling through a steel plate that has a thickness less than 17mm or through a stainless steel plate that has a thickness less than 6mm.

Claims (14)

  1. A method for manufacturing a screw, characterized by the following steps of:
    (a) providing a screw body (3) that has an outer surface and that includes a head portion (31) and a shank portion (32) extending from the head portion (31);
    (b) immersing the screw body (3) into a solution that is composed of diethylene glycol monobutyl ether acetate, water borne organic-inorganic copolymer resin, and water; and
    (c) removing the screw body (3) from the solution, followed by drying and baking the screw body (3) so as to form a first transparent layer (41) on the outer surface of the screw body (3).
  2. The method as claimed in Claim 1, further characterized in that, in step (a), the shank portion (32) of the screw body (3) has a first segment (321) which is connected to the head portion (31), and a second segment (322) which is connected to the first segment (321), the head portion (31) and the first segment (321) of the shank portion (32) being made of an austenitic stainless steel, the second segment (322) of the shank portion (32) being made of a Cr-Mo alloy steel.
  3. The method as claimed in any one of Claims 1 and 2, further characterized by repeating steps (b) and (c) so as to form a second transparent layer (42) on the first transparent layer (41).
  4. The method as claimed in any one of Claims 1 to 3, further characterized in that, in step (b), based on the total weight of the solution, the percentage of diethylene glycol monobutyl ether acetate ranges from 10 wt% to 20 wt%, the percentage of water borne organic-inorganic copolymer resin ranges from 15 wt% to 30 wt%, and the percentage of water ranges from 50 wt% to 75 wt%.
  5. The method as claimed in Claim 4, further characterized in that, in step (b), based on the total weight of the solution, the percentage of diethylene glycol monobutyl ether acetate is 15 wt%, the percentage of water borne organic-inorganic copolymer resin is 22 wt%, and the percentage of water is 63 wt%.
  6. The method as claimed in any one of Claims 1 to 5, further characterized in that, in step (b), the temperature of the solution ranges from 20 °C to 30 °C, and the immersion time for the screw body (3) in the solution ranges from 10 seconds to 20 seconds.
  7. The method as claimed in any one of Claims 1 to 6, further characterized in that, in step (c), the screw body (3) is baked for 20 minutes at a temperature ranging from 80°C to 110°C.
  8. The method as claimed in Claim 2, further characterized by a step (a1) of hardening a surface of the second segment (322) of the shank portion (32) by high frequency induction hardening prior to step (b).
  9. The method as claimed in Claim 8, further characterized by a step (a2) of washing the outer surface of the screw body (3) with acid after step (a1) and before step (b).
  10. The method as claimed in any one of Claims 2, 8, and 9, further characterized in that, in step (a), the austenitic stainless steel is one of SUS304 stainless steel and SUS316 stainless steel, and the Cr-Mo alloy steel is one of SCM435 alloy steel and SCM440 alloy steel.
  11. A screw including a screw body (3) that has an outer surface and that includes a head portion (31) and a shank portion (32) which extends from said head portion (31),
    characterized by a first transparent layer (41) formed on said outer surface of said screw body (3) and composed of diethylene glycol monobutyl ether acetate and water borne organic-inorganic copolymer resin.
  12. The screw as claimed in Claim 11, further characterized in that said shank portion (31) has a first segment (321) that is connected to said head portion (31), and a second segment (322) that is connected to said first segment (321), said head portion (31) and said first segment (321) being made of an austenitic stainless steel, said second segment (322) of said shank portion (32) being made of a Cr-Mo alloy steel.
  13. The screw as claimed in any one of Claims 11 and 12, further characterized by a second transparent layer (42) formed on said first transparent layer (41) and composed of diethylene glycol monobutyl ether acetate and water borne organic-inorganic copolymer resin.
  14. The screw as claimed in any one of Claims 12 and 13, further characterized in that the austenitic stainless steel is one of SUS304 stainless steel and SUS316 stainless steel, and the Cr-Mo alloy steel is one of SCM435 alloy steel and SCM440 alloy steel.
EP13172449.4A 2012-12-03 2013-06-18 Screw and method for manufacturing the same Withdrawn EP2737960A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW101145249A TW201422844A (en) 2012-12-03 2012-12-03 Manufacturing method for composite screw and products thereof

Publications (1)

Publication Number Publication Date
EP2737960A1 true EP2737960A1 (en) 2014-06-04

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EP13172449.4A Withdrawn EP2737960A1 (en) 2012-12-03 2013-06-18 Screw and method for manufacturing the same

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EP (1) EP2737960A1 (en)
JP (1) JP2014109382A (en)
TW (1) TW201422844A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104178601A (en) * 2014-08-17 2014-12-03 成都亨通兆业精密机械有限公司 Surface hardening method for bolt

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7437114B2 (en) * 2018-12-26 2024-02-22 日東精工株式会社 flow drill screw

Citations (1)

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Publication number Priority date Publication date Assignee Title
DE10308237A1 (en) * 2003-02-25 2004-09-09 Chemetall Gmbh Aqueous composition imparting improved corrosion resistance to metal surfaces contains a hydrolyzable silane and a metal chelate and optionally also an organic film-former and film-forming aid

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JPS5266143A (en) * 1975-11-28 1977-06-01 Japan Gasoline Holder for fixation of backing furnace material in heating furnace
JPS5517772A (en) * 1978-07-25 1980-02-07 Nippon Pillar Packing Insulated bolt and its manufacturing method
TW306046B (en) * 1996-07-09 1997-05-21 Vanguard Int Semiconduct Corp Manufacturing method of bit line over capacitor array of memory cell
AR057940A1 (en) * 2005-11-30 2007-12-26 Tenaris Connections Ag THREADED CONNECTIONS WITH HIGH AND LOW FRICTION COATINGS
JP2007262498A (en) * 2006-03-28 2007-10-11 National Institute Of Advanced Industrial & Technology Color-controlled titanium alloy bolt and nut

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
DE10308237A1 (en) * 2003-02-25 2004-09-09 Chemetall Gmbh Aqueous composition imparting improved corrosion resistance to metal surfaces contains a hydrolyzable silane and a metal chelate and optionally also an organic film-former and film-forming aid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104178601A (en) * 2014-08-17 2014-12-03 成都亨通兆业精密机械有限公司 Surface hardening method for bolt

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TW201422844A (en) 2014-06-16
JP2014109382A (en) 2014-06-12

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