EP2721130A1 - Installation and method for extraction of oil from olive paste - Google Patents

Installation and method for extraction of oil from olive paste

Info

Publication number
EP2721130A1
EP2721130A1 EP12732559.5A EP12732559A EP2721130A1 EP 2721130 A1 EP2721130 A1 EP 2721130A1 EP 12732559 A EP12732559 A EP 12732559A EP 2721130 A1 EP2721130 A1 EP 2721130A1
Authority
EP
European Patent Office
Prior art keywords
conveyor
paste
installation
olive paste
olive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP12732559.5A
Other languages
German (de)
French (fr)
Other versions
EP2721130B1 (en
Inventor
Gennaro Pieralisi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PIERALISI MAIP SpA
Original Assignee
PIERALISI MAIP SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PIERALISI MAIP SpA filed Critical PIERALISI MAIP SpA
Priority to EP12732559.5A priority Critical patent/EP2721130B1/en
Publication of EP2721130A1 publication Critical patent/EP2721130A1/en
Application granted granted Critical
Publication of EP2721130B1 publication Critical patent/EP2721130B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00—Production of fats or fatty oils from raw materials
    • C11B1/06—Production of fats or fatty oils from raw materials by pressing
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00—Production of fats or fatty oils from raw materials
    • C11B1/10—Production of fats or fatty oils from raw materials by extracting
    • C11B1/102—Production of fats or fatty oils from raw materials by extracting in counter-current; utilisation of an equipment wherein the material is conveyed by a screw

Definitions

  • the present patent application for industrial invention relates to an installation and method for extraction of oil from olive paste.
  • GB 917 638 discloses a system for oil and fat extraction from animal or vegetal products that provides for alternate crushing and heating of the product, which is then pressed to extract oil. Heating is obtained with a tubular heat exchanger provided with air space wherein steam flows. The product is fed into the heat exchanger by means of a worm conveyor. In order to favor the transfer of product inside the exchanger, water is added to the product to make it more fluid. It appears evident that the addition of water considerably degrades the quality of the oil and produces emulsion during the following operations (especially during crushing in the disintegrator), impairing the extraction output.
  • EP2248880 in the name of the same applicant, which discloses a conveyor device composed of a heat exchanger with air space with circulation of hot water and worm conveyor.
  • a pressure rotary pump is used to maintain the conveyor device under pressure, so that the conveyor device is filled with olive paste during the passage of the olive paste.
  • the above guarantees a contact between the olive paste and the entire heating wall of the exchanger, in order to optimize the heat exchange efficiency.
  • the heat exchange efficiency improves for the continuous scraping of the internal surface of the heat exchanger caused by the olive paste moved by the worm conveyor.
  • such a system avoids the use of water to transport the olive paste, it does not consider the variable nature of different types of olive paste. In fact, some of them, being especially dehydrated, are difficult to be moved and tend to stagnate and deposit along the walls of the heat exchanger, thus impairing the quality of the oil.
  • ES 2 327 308 discloses a system that uses ultrasounds to achieve quicker and more uniform heating of a mass of olives during the extraction process of olive oil. Such a process uses the heating effect of ultrasounds on olive paste until it reaches a temperature of approximately 28-35 °C. However, experimental tests have shown that the heating effect of ultrasounds does not achieve a significant temperature increase.
  • the purpose of the present invention is to eliminate the drawbacks of the prior art by disclosing an installation and method for extraction of olive oil that considerably reduces kneading time, while improving the quality of the oil without impairing the extraction output.
  • the installation for extraction of olive from olives comprises:
  • said conveyor disposed between crushing station and centrifugation station, said conveyor comprising a cylindrical tubular structure with a worm conveyor axially disposed inside said cylindrical tubular structure in such a way to generate an auger conveyor with product inlet and outlet,
  • a piston pump disposed in said inlet of the conveyor to generate a pulsating effect on feeding of olive paste into said conveyor.
  • the piston pump of pulsating type, creates a pressure wave (a sequence of implosions and explosions of cellular membranes that favors the liberation of oil) that propagates in time and space to all the paste contained inside the worm conveyor. It can be defined as "milking" of olive paste, an alternate pressing of sinusoidal type as transmitted by a piston pump.
  • the linear motion of the piston is sinusoidal, in terms of space, speed and acceleration.
  • the installation of the invention may be optionally provided with a kneading station. It must be considered that preparation processes of the paste to oil separation occur during kneading. Oil is contained in olives in small cellular bags (vacuoles) with wall consisting in a cellular membrane. Crushing is not effective in terms of oil separation, because it breaks olives, but only a very few cellular membranes.
  • Coalescence is the coming together of microdrops to form large drops that become separable. It is caused by the slow mixing of the mass in kneading. Therefore, coalescence is a physical effect (due to the slow movement of the paste that favors coalescence, not emulsion, of the oil).
  • the delivery of the pump is higher than the delivery of the auger conveyor (pump and auger push the olive paste in series, one after the other). Therefore, a forced pushing action on the paste is generated in the air space between the revolving auger and the thermal exchange surface, thus keeping the surface of the conveyor clean, meaning that the product (olive paste) does not stagnate on the surface, favoring thermal exchange and avoiding local overheating of the olive paste.
  • the above improves the extraction output without impairing the quality of the oil.
  • ultrasounds can be applied in direct contact with the olive paste.
  • the synergetic effect of the ultrasound treatment that causes the breakage of the membranes and favors the coming out of oil, and of the conveyor allows for a considerable reduction of kneading time, thus guaranteeing high extraction output without impairing the quality of the oil.
  • the ultrasound treatment device can be installed upstream the conveyor.
  • the application of ultrasounds to the olive paste favors the breakage of the pulp cells, thus favoring the coming out of oil from the vacuoles.
  • the above makes the paste more oily and slicker, thus reducing friction on the internal walls of the conveyor. Therefore, the synergetic effect of the ultrasound treatment and the piston pump favors the passage of the olive paste in the conveyor, avoiding possible deposits of paste on the internal walls that may overheat and damage the quality of the extracted oil.
  • Fig. 1 is a block diagram of the installation for extraction of oil according to the invention ;
  • Fig. 2 is a cross-sectional view of a kneading tank of the installation of Fig.
  • Fig. 3 is a side view, partially in axial section, that shows the conveyor and piston pump of the installation of Fig. 1 ;
  • Fig. 4 is a diagrammatic perspective view of an ultrasound device of the installation of Fig. 1 ;
  • Fig. 5 is a side view of a ultrasound generator of the device of Fig. 4.
  • FIG. 1 the installation of the invention is disclosed, generally indicated with numeral (1 00).
  • Said installation (1 00) comprises:
  • An auger conveyor (4) is disposed between crushing station (1 ) and centrifugation station to transport the olive paste (P).
  • a piston pump (3) is connected to the conveyor (4) to feed the olive paste in the conveyor (4) in a pulsating way.
  • a first collection tank (7) is disposed upstream the piston pump.
  • a second collection tank (7') is disposed upstream the centrifugation station (6).
  • a volumetric pump (8) for example a single screw pump, is disposed between second collection tank (7') and centrifugation station (6) to feed olive paste to the centrifugation station (6).
  • the conveyor (4) can be optionally heated and, in such a case, it is defined as heater-conveyor (4).
  • a kneading station (5) can be optionally provided downstream the conveyor (4) to knead the paste (P).
  • the kneading station (5) is generally provided with a tank and a volumetric pump; therefore the second tank (7') and the volumetric pump (8) shown in Fig. 1 can be omitted.
  • the first tank (7) used to collect and transfer the paste, disposed upstream the piston pump (3) may comprise a bottom screw to feed the piston pump (3).
  • the first tank (7) may also be provided with kneading blades.
  • the installation (100) comprises at least one ultrasound generator device (2) to apply ultrasounds to the olive paste (P).
  • the ultrasound device or devices (2) may be disposed in any position of the installation, downstream the crushing station (1 ) and upstream the centrifugation station (6).
  • an ultrasound application device is disposed upstream the heater-conveyor (4).
  • the devices installed between crushing station and centrifugation station, in addition to the kneading station, are designed to reduce the thermal and oxidative stress of the olive paste, while exalting the quality of the extracted oil and improving the extraction output. It is known that, if too long, kneading tends to cause the development of aliphatic alcohols, in addition to other compounds, which degrade the quality of the oil.
  • the crushing station (1 ) is of traditional type and may comprise a hammer crusher.
  • the kneading station (5) is of traditional type and, as shown in Fig. 2, comprises at least one basically cylindrical tank (50) with rotating blades (51 , 51 ') supported by a shaft (52) disposed in axial position in the tank.
  • the blades (51 , 51 ') have a different radial length.
  • the longest blade (51 ) brushes the semi-cylindrical internal profile concentric to the shaft of the kneading tank, whereas the shortest blade (51 ') does not.
  • the shortest blade (51 ') has helicoidal direction opposite to the longest blade (51 ') in order to give the fundamental relative motion between adjacent parts of the paste contained in the tank.
  • the peripheral speed of the blades has a higher limit that depends on the variety of olives, being the limit beyond which emulsion is developed.
  • the blades create a relative motion between adjacent parts of the paste (P) that remains inside the tank (50) to allow for mechanical scratching- breaking action of the cellular membranes.
  • the movement of the paste also favors the thermal exchange with the heating surface and the enzyme action at a temperature of approximately 27 - 35 °C.
  • the speed of the blades must not be excessive not to impair the natural aggregation action of the oil (coalescence), which is crucial for the following centrifugation station.
  • the tank (50) generally has external diameter of about 60 cm and length of about 2-3 m.
  • the heater-conveyor (4) is adapted to convey the olive paste (P) and heat it uniformly to guarantee rapid kneading.
  • the heater-conveyor (4) comprises a cylindrical tubular structure (40) internally housing an auger (41 ) with bearing shaft (42), actuated by a suitable gear motor (43) to generate an auger conveyor.
  • the heater-conveyor (4) comprises an inlet (44) to load the olive paste (P) coming from the crushing station (1 ) and an outlet (45) to unload the olive paste (P) towards the kneading station (5).
  • the lateral walls of the cylindrical tubular structure (40) of the heater- conveyor are provided with air space (46) to allow for hot water circulation (A) by means of an inlet conduit (47) and an outlet conduit (48) provided at the ends of the air space (46).
  • the hot water circulation (A) guarantees a hot water temperature of about 35-40 °C. In fact, a higher temperature would cause an excessive thermal shock of the olive paste (P).
  • the air space (46) is provided with helicoidal partitions (49).
  • the shaft (42) of the auger has an internally empty tubular structure and is crossed by hot water in order to heat also the central part of the flow of paste (P) moved by the heater-conveyor (4).
  • the internal diameter ( ⁇ ) of the tubular structure (40) of the heater is lower than half of the internal diameter of the kneading tank (50), preferably being one third of the diameter of the kneading tank.
  • the length (L) of the tubular structure (40) of the heater is higher than four meters, preferably six meters, to provide for suitable heating of the paste (P) inside the heater, with a temperature difference of about 1 0 °C from the inlet to the outlet of the heater, in a very short transit time, such as 1 -2 minutes. So, the paste (P) reaches the kneading station (5) at a temperature of about 20-30 °C and kneading has a reduced length of 1 0-20 minutes, thus saving on time and energy.
  • the function of the kneading station is reduced because its effect is compensated by the effects of other devices installed between crushing station and centrifugation station. Certainly, with the same general effect, the useful volume of the kneading station is reduced.
  • the installation (1 00) provides for a piston pump (3) disposed upstream the heater-conveyor (4) to generate a pulsating effect on feeding of olive paste into the heater (4).
  • the piston pump (3) comprises a cylindrical chamber (30) where a piston (31 ) slides.
  • the piston (31 ) is connected to a connecting rod (33).
  • the connecting rod (33) is connected to a crank (34) that is driven into rotation by a drive shaft (35).
  • the pumping chamber (30) is connected to an inlet conduit (36) and an outlet conduit (37).
  • the outlet conduit (37) is directly connected to the inlet conduit (44) of the heater.
  • One-way valves (38, 39) are disposed in the inlet (36) and outlet (37) conduits of the piston pump to allow for correct direction of the flow of olive paste (P) towards the heater-conveyor.
  • the delivery of the piston pump (3) is higher than the delivery of the auger conveyor (41 ).
  • the pulsating action of the piston pump is of sinusoidal type because of its constructive configuration.
  • the ultrasound treatment device (2) comprises at least one ultrasound generator (20).
  • each ultrasound generator (20) comprises a transducer (21 ) to transform electricity into mechanical vibration at ultrasound frequency.
  • the transducer (21 ) comprises an enclosure that contains piezo- electrical crystals.
  • the transducer (21 ) is connected to an ultrasound emitter (22) that protrudes axially from the transducer.
  • the transducer (21 ) is provided with electrical contacts (23) connected to electrical wires (24) (Fig. 4). As shown in Fig. 4, the electrical wires (24) are connected to electricity generators (G).
  • the piezo-electric crystals of the transducer (21 ) when they are powered with electricity, they determine a high-frequency mechanical vibration that expands radially from the ultrasound emitter (22).
  • the ultrasound emitter (22) is inserted in a conduit (25) inserted in pipes (26, 27, 28) that transfer the olive paste from crushing station (1 ) to centrifugation station (6).
  • the olive paste passing through the conduits (26, 27, 28) comes in direct contact with the ultrasound emitter (22).
  • Low frequency ultrasounds are used, from 20 KHz to 100KHz, preferably at 20 KHz frequency.
  • the ultrasound treatment can be made for a variable time from 5 to 60 seconds. To that end, the transfer speed of the olive paste is suitably adjusted.
  • the power of the ultrasounds and the transit speed of the olive paste are chosen in order to prevent ultrasounds from heating the olive paste excessively, thus causing oil deterioration.
  • Such an ultrasound treatment causes heating of olive paste lower than 5 °C.
  • Processing in the experimental installation was carried out with two varieties of olives, with constant olive delivery to the installation, changing the temperature of processed paste (by means of the heater-conveyor (4)) and the kneading time in kneading station (5).
  • the delivery of the experimental installation (100) is basically the same as each line of the industrial installation, the kneading time and temperature used in the industrial installation are the typical kneading time and temperature of the oil mill.
  • Each of the industrial lines used as reference is characterized by three kneading tanks in series (in overflow configuration) of 6,000 l/each, with single shaft and two-phase decanter (SPI 99 model), i.e. with only one subproduct.
  • the crusher and piston pump used in the lines of the industrial installation are identical to the experimental installation.
  • the parameters that were changed with experimental methodicalness (in the experimental installation) were kneading time and temperature (measured in the inlet of the decanter or horizontal centrifugation station).
  • a practically null kneading time was obtained by making the paste pass rapidly (without stopping) in the kneading tank (5).
  • the worm screw acts as a pump with lower delivery than the piston pump.
  • the worm screw is a conveyor that guarantees the sealing (outwards) of the paste, because during its travel the paste is subject to a certain pressure basically due to the pumping effect of the piston pump.
  • the kneading station is a heat exchanger with low heat output because of the large size of the tank (large distances between heating surface and center of heated mass).
  • the kneading station is a heat exchanger with low heat output because of the large size of the tank (large distances between heating surface and center of heated mass).
  • a great amount of heat is dissipated by the kneading station because of the large surfaces involved, contrary to the conveyor (4) when used as heater. This is evidently caused by the different ratio between heating surface and heated mass.
  • the operating system is more continuous.
  • the large volumes of the kneading tanks contribute to high operating discontinuity.
  • Transit time of the processed product through the installation is reduced, with lower possibility of oil oxidation (higher quality).
  • Processing time is reduced (permanence in the kneading station is reduced or eliminated).
  • the equipment of the installation is exploited in a more efficient way (optimization).
  • the space necessary in the oil mill is reduced (the kneading section is the bulkiest section of the installation).
  • the organization of the installation is improved.
  • This method has the advantages of cold processing (without oil oxidation caused by temperature and long kneading time), and enhances the quality of oil, which is normally associated with low temperature, without the contraindication of low extraction output of oil, as it normally occurs with traditional cold processing methods.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Fats And Perfumes (AREA)
  • Disintegrating Or Milling (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

The present invention relates to a high-efficiency installation and process for extraction of oil, which provides for transportation of olive paste from a crushing station (1) by a piston pump and a conveyor (4) towards a centrifugation station (6) where oil is extracted. The piston pump (3) feeds the olive paste to the conveyor (4) in a pulsating way.

Description

Description
Installation and method for extraction of oil from olive paste
The present patent application for industrial invention relates to an installation and method for extraction of oil from olive paste.
As it is known, olive processing for oil production is traditionally composed of three operations, defined as crushing, kneading and oil extraction. Within the prior art numerous attempts have been made to heat olive paste before oil extraction in order to improve the efficiency of the installation.
GB 917 638 discloses a system for oil and fat extraction from animal or vegetal products that provides for alternate crushing and heating of the product, which is then pressed to extract oil. Heating is obtained with a tubular heat exchanger provided with air space wherein steam flows. The product is fed into the heat exchanger by means of a worm conveyor. In order to favor the transfer of product inside the exchanger, water is added to the product to make it more fluid. It appears evident that the addition of water considerably degrades the quality of the oil and produces emulsion during the following operations (especially during crushing in the disintegrator), impairing the extraction output.
The above drawbacks are partially remedied in EP2248880 in the name of the same applicant, which discloses a conveyor device composed of a heat exchanger with air space with circulation of hot water and worm conveyor. A pressure rotary pump is used to maintain the conveyor device under pressure, so that the conveyor device is filled with olive paste during the passage of the olive paste. The above guarantees a contact between the olive paste and the entire heating wall of the exchanger, in order to optimize the heat exchange efficiency. As a matter of fact, the heat exchange efficiency improves for the continuous scraping of the internal surface of the heat exchanger caused by the olive paste moved by the worm conveyor. Although such a system avoids the use of water to transport the olive paste, it does not consider the variable nature of different types of olive paste. In fact, some of them, being especially dehydrated, are difficult to be moved and tend to stagnate and deposit along the walls of the heat exchanger, thus impairing the quality of the oil.
ES 2 327 308 discloses a system that uses ultrasounds to achieve quicker and more uniform heating of a mass of olives during the extraction process of olive oil. Such a process uses the heating effect of ultrasounds on olive paste until it reaches a temperature of approximately 28-35 °C. However, experimental tests have shown that the heating effect of ultrasounds does not achieve a significant temperature increase.
The purpose of the present invention is to eliminate the drawbacks of the prior art by disclosing an installation and method for extraction of olive oil that considerably reduces kneading time, while improving the quality of the oil without impairing the extraction output.
These purposes are achieved according to the invention with the characteristics disclosed in the attached independent claims.
Advantageous embodiments appear from the dependent claims.
The installation for extraction of olive from olives according to the invention comprises:
- a crushing station to crush olives in such a way to obtain a paste composed of pulp and crushed olive pit,
- a centrifugation station wherein oil is extracted from olive paste,
- a conveyor disposed between crushing station and centrifugation station, said conveyor comprising a cylindrical tubular structure with a worm conveyor axially disposed inside said cylindrical tubular structure in such a way to generate an auger conveyor with product inlet and outlet,
- a piston pump disposed in said inlet of the conveyor to generate a pulsating effect on feeding of olive paste into said conveyor.
The piston pump, of pulsating type, creates a pressure wave (a sequence of implosions and explosions of cellular membranes that favors the liberation of oil) that propagates in time and space to all the paste contained inside the worm conveyor. It can be defined as "milking" of olive paste, an alternate pressing of sinusoidal type as transmitted by a piston pump. The linear motion of the piston is sinusoidal, in terms of space, speed and acceleration.
The installation of the invention may be optionally provided with a kneading station. It must be considered that preparation processes of the paste to oil separation occur during kneading. Oil is contained in olives in small cellular bags (vacuoles) with wall consisting in a cellular membrane. Crushing is not effective in terms of oil separation, because it breaks olives, but only a very few cellular membranes.
The various actions that occur during kneading are:
• Thermal action. The temperature increase reduces the viscosity of the oil, thus favoring the coming out of the oil from the vacuole.
• Mechanical action. The kneading movement creates friction between olive pulp and crushed pit. The sharp corners of the pit scratch the membrane. Consequently, the membrane is broken and the oil comes out. However, oil comes out as microdrops that are strongly dispersed in the mass and therefore in emulsion form (not in "separable phase" not even by means of centrifugation).
· Coalescence. Obviously, oil would not be separable and would remain in emulsion without the effect of coalescence. Coalescence is the coming together of microdrops to form large drops that become separable. It is caused by the slow mixing of the mass in kneading. Therefore, coalescence is a physical effect (due to the slow movement of the paste that favors coalescence, not emulsion, of the oil).
• Enzymatic action. Because of pulp breakage, diffuse distribution and prolonged dynamic contact with the membrane, the enzymes contained in the pulp - but not in the vacuoles - cause an enzymatic attack of the membrane, also favored by temperature, with consequent enzymatic breakage of the membrane. "Milking" of the paste is an additional effect that cannot take place in the kneading phase, but in the conveyor before kneading.
With the introduction of the pulsating pump (for instance, sinusoidally) upstream the conveyor, alternate pressure stress of the vacuole is obtained, with additional breakage effect of the membrane. Such additional breakage effect of the membrane corresponds to higher efficacy and efficiency of the process (productivity of the device is increased in terms of process speed, volumes of the kneading station in downstream position, if any, are reduced, and output of oil is increased).
Advantageously, the delivery of the pump is higher than the delivery of the auger conveyor (pump and auger push the olive paste in series, one after the other). Therefore, a forced pushing action on the paste is generated in the air space between the revolving auger and the thermal exchange surface, thus keeping the surface of the conveyor clean, meaning that the product (olive paste) does not stagnate on the surface, favoring thermal exchange and avoiding local overheating of the olive paste. The above improves the extraction output without impairing the quality of the oil.
In order to additionally accelerate the oil extraction process, ultrasounds can be applied in direct contact with the olive paste. The synergetic effect of the ultrasound treatment that causes the breakage of the membranes and favors the coming out of oil, and of the conveyor allows for a considerable reduction of kneading time, thus guaranteeing high extraction output without impairing the quality of the oil.
Advantageously, the ultrasound treatment device can be installed upstream the conveyor. In such a case, the application of ultrasounds to the olive paste favors the breakage of the pulp cells, thus favoring the coming out of oil from the vacuoles. The above makes the paste more oily and slicker, thus reducing friction on the internal walls of the conveyor. Therefore, the synergetic effect of the ultrasound treatment and the piston pump favors the passage of the olive paste in the conveyor, avoiding possible deposits of paste on the internal walls that may overheat and damage the quality of the extracted oil. Further characteristics of the invention will become clearer from the detailed description below, which refers to a merely illustrative, not limiting, embodiment, wherein :
Fig. 1 is a block diagram of the installation for extraction of oil according to the invention ;
Fig. 2 is a cross-sectional view of a kneading tank of the installation of Fig.
1 ;
Fig. 3 is a side view, partially in axial section, that shows the conveyor and piston pump of the installation of Fig. 1 ;
Fig. 4 is a diagrammatic perspective view of an ultrasound device of the installation of Fig. 1 ;
Fig. 5 is a side view of a ultrasound generator of the device of Fig. 4.
Referring to Fig. 1 , the installation of the invention is disclosed, generally indicated with numeral (1 00).
Said installation (1 00) comprises:
- a crushing station (1 ) to crush olives in such a way to obtain a paste (P) composed of pulp and crushed olive pit,
- a centrifugation station (6) to extract oil from olive paste.
An auger conveyor (4) is disposed between crushing station (1 ) and centrifugation station to transport the olive paste (P). A piston pump (3) is connected to the conveyor (4) to feed the olive paste in the conveyor (4) in a pulsating way.
A first collection tank (7) is disposed upstream the piston pump. A second collection tank (7') is disposed upstream the centrifugation station (6). A volumetric pump (8), for example a single screw pump, is disposed between second collection tank (7') and centrifugation station (6) to feed olive paste to the centrifugation station (6).
The conveyor (4) can be optionally heated and, in such a case, it is defined as heater-conveyor (4).
A kneading station (5) can be optionally provided downstream the conveyor (4) to knead the paste (P). In such a case, the kneading station (5) is generally provided with a tank and a volumetric pump; therefore the second tank (7') and the volumetric pump (8) shown in Fig. 1 can be omitted.
The first tank (7) used to collect and transfer the paste, disposed upstream the piston pump (3) may comprise a bottom screw to feed the piston pump (3). The first tank (7) may also be provided with kneading blades.
Optionally, the installation (100) comprises at least one ultrasound generator device (2) to apply ultrasounds to the olive paste (P). The ultrasound device or devices (2) may be disposed in any position of the installation, downstream the crushing station (1 ) and upstream the centrifugation station (6). Advantageously, an ultrasound application device is disposed upstream the heater-conveyor (4). Actually, the devices installed between crushing station and centrifugation station, in addition to the kneading station, are designed to reduce the thermal and oxidative stress of the olive paste, while exalting the quality of the extracted oil and improving the extraction output. It is known that, if too long, kneading tends to cause the development of aliphatic alcohols, in addition to other compounds, which degrade the quality of the oil.
The crushing station (1 ) is of traditional type and may comprise a hammer crusher.
The kneading station (5) is of traditional type and, as shown in Fig. 2, comprises at least one basically cylindrical tank (50) with rotating blades (51 , 51 ') supported by a shaft (52) disposed in axial position in the tank. The blades (51 , 51 ') have a different radial length. The longest blade (51 ) brushes the semi-cylindrical internal profile concentric to the shaft of the kneading tank, whereas the shortest blade (51 ') does not. Although not shown in Fig. 2, the shortest blade (51 ') has helicoidal direction opposite to the longest blade (51 ') in order to give the fundamental relative motion between adjacent parts of the paste contained in the tank. The peripheral speed of the blades has a higher limit that depends on the variety of olives, being the limit beyond which emulsion is developed.
The blades create a relative motion between adjacent parts of the paste (P) that remains inside the tank (50) to allow for mechanical scratching- breaking action of the cellular membranes. Of course, the movement of the paste also favors the thermal exchange with the heating surface and the enzyme action at a temperature of approximately 27 - 35 °C. The speed of the blades must not be excessive not to impair the natural aggregation action of the oil (coalescence), which is crucial for the following centrifugation station. To allow for correct kneading, the tank (50) generally has external diameter of about 60 cm and length of about 2-3 m.
The heater-conveyor (4) is adapted to convey the olive paste (P) and heat it uniformly to guarantee rapid kneading.
Referring to Fig. 3, the heater-conveyor (4) comprises a cylindrical tubular structure (40) internally housing an auger (41 ) with bearing shaft (42), actuated by a suitable gear motor (43) to generate an auger conveyor.
The heater-conveyor (4) comprises an inlet (44) to load the olive paste (P) coming from the crushing station (1 ) and an outlet (45) to unload the olive paste (P) towards the kneading station (5).
The lateral walls of the cylindrical tubular structure (40) of the heater- conveyor are provided with air space (46) to allow for hot water circulation (A) by means of an inlet conduit (47) and an outlet conduit (48) provided at the ends of the air space (46). The hot water circulation (A) guarantees a hot water temperature of about 35-40 °C. In fact, a higher temperature would cause an excessive thermal shock of the olive paste (P).
Such a continuous circulation of hot water inside the air space (46) of the heater-conveyor (4) guarantees the desired heating of the olive paste that moves inside it. Advantageously, the air space (46) is provided with helicoidal partitions (49).
Advantageously, the shaft (42) of the auger has an internally empty tubular structure and is crossed by hot water in order to heat also the central part of the flow of paste (P) moved by the heater-conveyor (4).
Advantageously, the internal diameter (Φ) of the tubular structure (40) of the heater is lower than half of the internal diameter of the kneading tank (50), preferably being one third of the diameter of the kneading tank. The length (L) of the tubular structure (40) of the heater is higher than four meters, preferably six meters, to provide for suitable heating of the paste (P) inside the heater, with a temperature difference of about 1 0 °C from the inlet to the outlet of the heater, in a very short transit time, such as 1 -2 minutes. So, the paste (P) reaches the kneading station (5) at a temperature of about 20-30 °C and kneading has a reduced length of 1 0-20 minutes, thus saving on time and energy.
Therefore, the function of the kneading station is reduced because its effect is compensated by the effects of other devices installed between crushing station and centrifugation station. Certainly, with the same general effect, the useful volume of the kneading station is reduced.
The installation (1 00) provides for a piston pump (3) disposed upstream the heater-conveyor (4) to generate a pulsating effect on feeding of olive paste into the heater (4).
The piston pump (3) comprises a cylindrical chamber (30) where a piston (31 ) slides. The piston (31 ) is connected to a connecting rod (33). The connecting rod (33) is connected to a crank (34) that is driven into rotation by a drive shaft (35).
The pumping chamber (30) is connected to an inlet conduit (36) and an outlet conduit (37). The outlet conduit (37) is directly connected to the inlet conduit (44) of the heater. One-way valves (38, 39) are disposed in the inlet (36) and outlet (37) conduits of the piston pump to allow for correct direction of the flow of olive paste (P) towards the heater-conveyor.
Advantageously, the delivery of the piston pump (3) is higher than the delivery of the auger conveyor (41 ).
Preferably, the pulsating action of the piston pump is of sinusoidal type because of its constructive configuration.
Referring to Fig. 5, the ultrasound treatment device (2) comprises at least one ultrasound generator (20).
Referring to Fig. 5, each ultrasound generator (20) comprises a transducer (21 ) to transform electricity into mechanical vibration at ultrasound frequency. The transducer (21 ) comprises an enclosure that contains piezo- electrical crystals. The transducer (21 ) is connected to an ultrasound emitter (22) that protrudes axially from the transducer. The transducer (21 ) is provided with electrical contacts (23) connected to electrical wires (24) (Fig. 4). As shown in Fig. 4, the electrical wires (24) are connected to electricity generators (G).
So, when the piezo-electric crystals of the transducer (21 ) are powered with electricity, they determine a high-frequency mechanical vibration that expands radially from the ultrasound emitter (22). The ultrasound emitter (22) is inserted in a conduit (25) inserted in pipes (26, 27, 28) that transfer the olive paste from crushing station (1 ) to centrifugation station (6).
The olive paste passing through the conduits (26, 27, 28) comes in direct contact with the ultrasound emitter (22). Low frequency ultrasounds are used, from 20 KHz to 100KHz, preferably at 20 KHz frequency. The ultrasound treatment can be made for a variable time from 5 to 60 seconds. To that end, the transfer speed of the olive paste is suitably adjusted.
The power of the ultrasounds and the transit speed of the olive paste are chosen in order to prevent ultrasounds from heating the olive paste excessively, thus causing oil deterioration. Such an ultrasound treatment causes heating of olive paste lower than 5 °C.
Experimental tests were carried out in an installation (100) similar to the one of Fig. 1 , but not provided with ultrasound generators (2).
Processing in the experimental installation was carried out with two varieties of olives, with constant olive delivery to the installation, changing the temperature of processed paste (by means of the heater-conveyor (4)) and the kneading time in kneading station (5).
The experimental installation (100) was compared with two processing lines of an industrial oil mill, which were equivalent and alternative for comparison with the experimental installation, operating with fixed parameters:
- the delivery of the experimental installation (100) is basically the same as each line of the industrial installation, the kneading time and temperature used in the industrial installation are the typical kneading time and temperature of the oil mill.
Each of the industrial lines used as reference is characterized by three kneading tanks in series (in overflow configuration) of 6,000 l/each, with single shaft and two-phase decanter (SPI 99 model), i.e. with only one subproduct. The crusher and piston pump used in the lines of the industrial installation are identical to the experimental installation. The parameters that were changed with experimental methodicalness (in the experimental installation) were kneading time and temperature (measured in the inlet of the decanter or horizontal centrifugation station).
The results obtained with the experimental installation (with variable kneading time and temperature) were compared with the results of the lines of the industrial installation used as reference, which operated throughout the oil campaign with kneading time of 90-100 min and temperature of 27-35 °C of the paste at the end of kneading.
The following tests were carried out:
The quality of the oil (obtained in the two installations) was tested with a sensorial analysis of the finished product (outlet of centrifugation separator).
It was observed that extraction yield increased when kneading time was reduced from 90 min to 60, 30, 15 min, down to 0 and when temperature was reduced from 50 °C to 30 °C, 20 °C, and 15°C. Therefore, yield is significantly higher with lower kneading time and temperature.
A practically null kneading time was obtained by making the paste pass rapidly (without stopping) in the kneading tank (5).
This result demonstrates that the presence of kneading tanks (5) and the heating of the conveyor (4) can be reduced or avoided, because of the presence of the piston pump (3) in association with the worm screw (4). The worm screw (4) was not heated for the temperature values with the best results. Therefore the effect can be entirely ascribed to the "milking" effect obtained by the piston pump (3) in the presence of the worm screw (4) that carries out a braking (contrast) action during passage of the paste pumped by the piston pump (3).
This occurs because the worm screw acts as a pump with lower delivery than the piston pump. For its entire length the worm screw is a conveyor that guarantees the sealing (outwards) of the paste, because during its travel the paste is subject to a certain pressure basically due to the pumping effect of the piston pump.
Between the periphery of the screw of the worm screw and the tubular channel, the radial "clearance" that is necessary for the relative motion between the two parts must be minimized to avoid the formation of a "static" layer of paste in such space, which causes difficulties in the cleaning of tubular walls and in the heat exchange, if necessary, from the heating water to the paste to be heated. Evidently, in order for the contrast action to occur, the delivery transmitted by the screw of the worm screw must be lower than the delivery of the piston pump.
The installation and method of the present invention have the following advantages:
Energy (heat) is saved in the kneading station (5) and/or the heater conveyor (4). In any case, it must be noted that the kneading station is a heat exchanger with low heat output because of the large size of the tank (large distances between heating surface and center of heated mass). In addition to the heat used to heat the paste, a great amount of heat is dissipated by the kneading station because of the large surfaces involved, contrary to the conveyor (4) when used as heater. This is evidently caused by the different ratio between heating surface and heated mass.
The operating system is more continuous. In fact, the large volumes of the kneading tanks contribute to high operating discontinuity. Transit time of the processed product through the installation is reduced, with lower possibility of oil oxidation (higher quality). Processing time is reduced (permanence in the kneading station is reduced or eliminated). The equipment of the installation is exploited in a more efficient way (optimization).
Operating costs are reduced (faster amortization) because of the reduction or elimination of the kneading stations.
The space necessary in the oil mill is reduced (the kneading section is the bulkiest section of the installation). The organization of the installation is improved.
The quality of the oil is improved and increased (as clearly, yet unexpectedly, demonstrated). This method has the advantages of cold processing (without oil oxidation caused by temperature and long kneading time), and enhances the quality of oil, which is normally associated with low temperature, without the contraindication of low extraction output of oil, as it normally occurs with traditional cold processing methods.

Claims

Claims
1 ) Installation (100) for extraction of oil from olives comprising:
- a crushing station (1 ) to crush olives in such a way to obtain a paste (P) composed of pulp and crushed olive pit,
- a centrifugation station (6) wherein oil is extracted from olive paste
- a conveyor (4) disposed between crushing station (1 ) and centrifugation station (6), said conveyor comprising a cylindrical tubular structure (40) with a worm conveyor (41 ) axially disposed inside said cylindrical tubular structure, in such a way to generate an auger conveyor (40,41 ) with inlet (44) and outlet (45) of product,
characterized in that it also comprises
a piston pump (3) disposed in said inlet (44) of the conveyor to generate a pulsating effect on feeding of olive paste into said conveyor (4).
2) Installation as claimed in claim 1 , characterized in that the delivery of said piston pump (3) is higher than the delivery of said auger conveyor (40, 41 ).
3) Installation as claimed in claim 1 or 2, characterized in that the pulsating action of said piston pump (3) is of alternate type related to the sinusoidal motion of the piston.
4) Installation as claimed in any one of the preceding claims, characterized in that it comprises a kneading station (5) comprising at least one tank (50) with basically cylindrical shape, where blades (51 ) rotate, being supported by a shaft (52) arranged axially in the tank to knead the paste (P).
5) Installation as claimed in any one of the previous claims, characterized in that said conveyor (4) comprises a space (46) with circulation of hot water to heat the olive paste passing in the conveyor (4).
6) Installation as claimed in any one of the preceding claims, characterized in that it also comprises at least one ultrasound generator device (2) disposed downstream said crushing station (1 ) and/or upstream said centrifugation station (6), provided with ultrasound generator (22) in direct contact with olive paste (P) to break the cells of olive paste and favor the coming out of oil from vacuoles.
7) Installation as claimed in claim 6, characterized in that the power of said ultrasounds and transit time of olive paste in contact with said ultrasound generator (22) are chosen in such a way to cause heating of olive paste by ultrasounds lower than 5°C.
8) Installation as claimed in claim 6 or 7, characterized in that said ultrasound generator (22) is disposed upstream said piston pump (3).
9) Installation as claimed in any one of the preceding claims, characterized in that it comprises a tank (7') disposed upstream said centrifugation station and a volumetric pump (8) disposed between said tank (7') and centrifugation station.
10) Method for extraction of oil from olives comprising the following steps:
- crushing to crush olives in order to obtain a paste (P) composed of pulp and crushed olive pits,
- centrifugation of olive paste to extract oil,
- transportation of olive paste to centrifugation station by means of a conveyor (4) with tubular cylindrical structure (40) with a worm screw (41 ) disposed axially inside said tubular cylindrical structure, in such manner to generate a worm screw (40, 41 ) with product inlet (44) and outlet (45),
characterized in that it comprises the generation of a pulsing effect on the delivery of olive paste inside said conveyor (4) by means of a piston pump
(3) disposed in said inlet (44) of the conveyor.
1 1 ) Method as claimed in claim 10, characterized in that the delivery of said piston pump (3) is higher than the delivery of said screw conveyor (40,
41 ).
12) Method as claimed in claim 10 or 1 1 , characterized in that the pulsing action of said piston pump (3) is of alternate type related with the sinusoidal motion of the piston.
13) Method as claimed in any one of claims 10 to 12, characterized in that it comprises kneading of olive paste before centrifugation. 14) Method as claimed in any one of claims 1 0 to 1 3, characterized in that it comprises heating of olive paste before centrifugation.
1 5) Method as claimed in any one of claims 1 0 to 14, characterized in that it comprises the application of ultrasounds to olive paste (P) to break the cells of olive paste and favor the coming out of oil from vacuoles.
1 6) Method as claimed in claim 1 5, characterized in that the power of said ultrasounds and transit time of olive paste in contact with ultrasounds are selected in order to cause heating of olive paste by ultrasounds lower than
EP12732559.5A 2011-06-15 2012-06-06 Installation and method for extraction of oil from olive paste Active EP2721130B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12732559.5A EP2721130B1 (en) 2011-06-15 2012-06-06 Installation and method for extraction of oil from olive paste

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20110425159 EP2535399B1 (en) 2011-06-15 2011-06-15 Installation for extraction of oil from olive paste
PCT/EP2012/060735 WO2012171843A1 (en) 2011-06-15 2012-06-06 Installation and method for extraction of oil from olive paste
EP12732559.5A EP2721130B1 (en) 2011-06-15 2012-06-06 Installation and method for extraction of oil from olive paste

Publications (2)

Publication Number Publication Date
EP2721130A1 true EP2721130A1 (en) 2014-04-23
EP2721130B1 EP2721130B1 (en) 2014-09-03

Family

ID=46458443

Family Applications (2)

Application Number Title Priority Date Filing Date
EP20110425159 Not-in-force EP2535399B1 (en) 2011-06-15 2011-06-15 Installation for extraction of oil from olive paste
EP12732559.5A Active EP2721130B1 (en) 2011-06-15 2012-06-06 Installation and method for extraction of oil from olive paste

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP20110425159 Not-in-force EP2535399B1 (en) 2011-06-15 2011-06-15 Installation for extraction of oil from olive paste

Country Status (6)

Country Link
EP (2) EP2535399B1 (en)
ES (1) ES2525105T3 (en)
MA (1) MA35265B1 (en)
PT (1) PT2721130E (en)
TN (1) TN2013000496A1 (en)
WO (1) WO2012171843A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITFI20130104A1 (en) * 2013-05-08 2014-11-09 Insono S R L "REACTOR ACTIVES TO INCREASE THE QUANTITY OF POLYPHENOLS AND / OR THE STABILITY OF THE TORBIDO OF OLIVE OIL, PLANT AND METHOD THAT USE THE REACTOR"
ES2710395T3 (en) * 2015-09-02 2019-04-24 Alfa Laval Corp Ab Procedure for the production of virgin olive oil
CN106354176B (en) * 2016-08-31 2018-08-07 青岛长寿食品有限公司 One cultivates peanut cold pressing control method and system
WO2018206827A1 (en) * 2017-05-10 2018-11-15 Gea Westfalia Separator Ibérica, S.A. Device and method for continuous treatment of a food product
IT201800006084A1 (en) * 2018-06-06 2019-12-06 PLANT AND PROCEDURE FOR THE PRODUCTION OF A SEASONING BASED ON OLIVES AND TOMATOES NATURALLY RICH IN ANTIOXIDANTS
IT202100013064A1 (en) * 2021-05-20 2022-11-20 Clemente S R L Separating machine for processing material.
US20220404084A1 (en) * 2021-06-10 2022-12-22 Glacia, Inc. Methods, systems, devices, and formulations for cryogenic fluids
CN117681480B (en) * 2024-02-02 2024-04-23 西南林业大学 Olive oil extraction equipment and extraction process thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB917638A (en) 1960-06-18 1963-02-06 George Scott & Son London Ltd Process and apparatus for rendering oils and fats from solid oil-bearing materials
US4522119A (en) * 1980-12-23 1985-06-11 Fps Development Partnership Olive oil recovery
ITRE20040147A1 (en) * 2004-12-03 2005-03-03 Bonfiglioli Ing Spa SYSTEM FOR THE EXTRACTION OF THE LIQUID COMPONENT FROM DRUPE MOUNTED ON THE FLOOR OF A ROTABLE VEHICLE WITH DIRECT POWER SUPPLY
ES2327308B1 (en) 2007-12-26 2010-07-26 Instituto Andaluz De Investigacion Y Formacion Agraria, Pesquera, Alimentaria Y De La Produccion E. APPARATUS AND PROCEDURE FOR CONTINUOUS AND UNIFORM HEATING OF MASSED OLIVE MASS BY ULTRASOUNDS.
IT1394287B1 (en) 2009-05-08 2012-06-06 Nuova Maip Macchine Agric PROCEDURE AND PLANT AT HIGH EFFICIENCY FOR THE EXECUTION OF THE OLIVE GRAM.

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2012171843A1 *

Also Published As

Publication number Publication date
EP2535399A1 (en) 2012-12-19
TN2013000496A1 (en) 2015-03-30
EP2721130B1 (en) 2014-09-03
EP2535399B1 (en) 2014-04-16
ES2525105T3 (en) 2014-12-17
PT2721130E (en) 2014-12-12
WO2012171843A1 (en) 2012-12-20
MA35265B1 (en) 2014-07-03

Similar Documents

Publication Publication Date Title
EP2721130B1 (en) Installation and method for extraction of oil from olive paste
Clodoveo et al. Engineering design and prototype development of a full scale ultrasound system for virgin olive oil by means of numerical and experimental analysis
US1949374A (en) Heat transfer apparatus for semisolid products
Amirante et al. Acoustic cavitation by means ultrasounds in the extra virgin olive oil extraction process
JP2014112009A (en) Scraper-type heat exchanger
US1735392A (en) Apparatus for cooking materials
CN109173809B (en) Multifunctional efficient heat exchange system of emulsification equipment
EP2248880A1 (en) High-efficiency kneading system for olives
CN203676018U (en) Stewing device for processing preserved fruit
KR20150126149A (en) Sludge drying apparatus
CN208218775U (en) Compact recycles sump oil soil pretreatment unit
CN105349242A (en) Antarctic krill heating coagulation equipment
CN215906168U (en) Small-size animal fat refining equipment
RU2340383C1 (en) Device for dispergation and extraction of fruit raw material
CN213643150U (en) Distillation plant is used in bromine nitre alcohol production
CN208555469U (en) Thermal cycle utilizes sump oil soil pretreatment unit
CN205018200U (en) Evaporimeter of horizontal boil out machine
CN204107063U (en) Fish protein water vacuum decker
CN113275358A (en) Kitchen garbage washs integrative device of grease solid-liquid separation conveying
CN105053099A (en) Forming machine for instant noodles
CN111109631A (en) Cooling and heating cylinder device for food additive
CN104772090A (en) Apparatus for manufacturing clean fuel through papermaking waste
RU162754U1 (en) OIL FORMER FOR PRODUCTION OF CREAMY OIL AND SPREADS
CN210314307U (en) Deoxidation tank for fruit and grape pulp production
US1956141A (en) Apparatus for processing material

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20131213

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

DAX Request for extension of the european patent (deleted)
INTG Intention to grant announced

Effective date: 20140602

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: AT

Ref legal event code: REF

Ref document number: 685620

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140915

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602012002981

Country of ref document: DE

Effective date: 20141016

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20141202

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2525105

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20141217

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 685620

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140903

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20141203

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20140903

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

REG Reference to a national code

Ref country code: GR

Ref legal event code: EP

Ref document number: 20140402412

Country of ref document: GR

Effective date: 20150128

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150103

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602012002981

Country of ref document: DE

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

26N No opposition filed

Effective date: 20150604

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602012002981

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150606

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20160229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150630

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150606

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150630

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20160606

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160606

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20120606

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20140903

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230508

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20230721

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GR

Payment date: 20240619

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20240606

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20240606

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20240610

Year of fee payment: 13