EP2713788B1 - Laminé multicouche - Google Patents

Laminé multicouche Download PDF

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Publication number
EP2713788B1
EP2713788B1 EP12729375.1A EP12729375A EP2713788B1 EP 2713788 B1 EP2713788 B1 EP 2713788B1 EP 12729375 A EP12729375 A EP 12729375A EP 2713788 B1 EP2713788 B1 EP 2713788B1
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EP
European Patent Office
Prior art keywords
outer layer
maximum
laminate
layer comprises
laminate according
Prior art date
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EP12729375.1A
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German (de)
English (en)
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EP2713788A1 (fr
Inventor
Franz Ziegler
Michele Stinco
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Individual
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Individual
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    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D15/00—Convertible garments
    • A41D15/005—Convertible garments reversible garments
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
    • A41D31/102—Waterproof and breathable

Definitions

  • the invention relates to a multi-ply laminate, which is particularly suitable for garments, as well as a garment with a multi-ply laminate.
  • Multi-layer laminates are basically known and of interest for various fields of application. Thus, several times multi-layer laminates have recently been used in the clothing industry.
  • the typical construction of multi-layer laminates in garments, especially for so-called outdoor garments, consists of an outer layer or layer which is durable, a membrane with appropriate functional properties such as impermeability to water and / or vapor permeability, and inner lining or lining an inner layer that is comfortable to wear on the skin.
  • the functional clothing should be functional, for example, during a mountain hike both in the early morning ascent in the shade and in the midday heat. Accordingly, the functional clothing should be worn during high performance (for example, in the Ascent) as well as in peace (for example with a windy summit rest) provide a high wearing comfort.
  • US 2008/127395 discloses a helical laminate having a first, light-absorbing outer layer, an opposing second, outer-layer reflective light, and a diaphragm disposed therebetween, which represents the closest prior art.
  • the first outer layer gives a laminate garment a discreet appearance when worn outside.
  • the second outer layer makes the garment clearly visible when worn outside.
  • Other laminates are in the DE 20 2004 009287 , of the EP 1 810 824 and the U.S. 4,569,874 disclosed.
  • the present invention has the object to provide a multi-layer laminate which is functional in a very wide range of applications and provides a high wearing comfort. This object is achieved by a laminate according to claim 1 or a garment according to claim 12. Preferred embodiments are described in the dependent claims.
  • the invention is based on the idea of providing a turn-over laminate which has two outer layers and a membrane arranged therebetween.
  • the two outer layers have different optical properties, so that a first outer layer absorbs light, in particular sunlight or the visible spectrum, and a second, opposite outer layer reflects light, in particular sunlight and / or infrared radiation.
  • a first outer layer absorbs light, in particular sunlight or the visible spectrum
  • a second, opposite outer layer reflects light, in particular sunlight and / or infrared radiation.
  • the second outer layer points outward, incoming solar radiation is reflected in order to prevent overheating of the body and does not reflect back from radiated heat radiation from the body.
  • the second state is well suited for exposure to sunlight, while the first state is intended to adequately warm the body, for example, during a windy rest in sunlight or with appropriate UV radiation.
  • an "outer layer” is understood to mean a layer that forms the outermost layer in each case (that is, inwards or outwards, respectively). In other words, the respective outer layer of the laminate or of a garment is not covered by further layers.
  • the membrane disposed between the two outer layers is preferably substantially waterproof, the membrane preferably having a water column of at least 5000 mm, more preferably at least 10000 mm, and most preferably at least 15000 mm (measured to ISO 811) withstands.
  • the membrane is substantially waterproof in both directions.
  • the laminate should be substantially preferably water vapor permeable, the laminate preferably has a vapor permeability of at least 10,000 g / m 2 in 24 hours, more preferably of at least 20000 g / m 2 within 24 hours, even more preferably of at least 25,000 g / m 2 in 24 hours and more preferably of at least 30,000 g / m 2 in 24 hours.
  • the laminate is substantially permeable to water vapor in two directions, so that a functional clothing made of the laminate according to the invention, regardless of which outer layer is directed outwards, keeps out rain and transports body sweat. It is further preferred that the laminate is substantially windproof.
  • the second, light-reflective outer layer has a diffuse reflection of at least 15%, preferably at least 20%, more preferably at least 22%, most preferably at least 24%, for all wavelengths between 300 nm and 1100 nm.
  • the diffuse reflection is measured by means of a so-called integrating sphere and a so-called white standard. An ideal white sample gives 100% reflection at all wavelengths in this method, and a perfectly black sample gives 0% reflection.
  • the second outer ply at a wavelength of 500 nm has a diffuse reflection of at least 15%, preferably at least 20%, more preferably at least 22%, most preferably at least 24%, and at a wavelength of 700 nm a diffuse reflection of at least 15%, preferably at least 20%, more preferably at least 23%, most preferably at least 25%.
  • the first outer layer has a diffuse reflection of at most 20%, preferably at most 18%, particularly preferably at most 15%, for all wavelengths between 400 nm and 900 nm, preferably between 350 nm and 1000 nm. It is furthermore preferred that the first outer layer has a diffuse reflection of not more than 12%, preferably not more than 10%, more preferably not more than 8%, particularly preferably not more than 6%, for all wavelengths between 400 nm and 700 nm.
  • the first outer ply at a wavelength of 500 nm has a diffuse reflection of at most 10%, preferably at most 5%, more preferably at most 3%, particularly preferably at most 2%, and at a wavelength of 700 nm diffuse reflection of at most 12%, preferably at most 10%, more preferably at most 8%, particularly preferably at most 6%.
  • the first outer layer for all wavelengths between 400 nm and 650 nm, preferably between 350 nm and 700 nm, a diffuse reflection of at most 30%, preferably at most 25%, particularly preferably at most 20% of the diffuse reflection of the second Outer layer has.
  • the membrane of the laminate according to the invention all known membranes are suitable, which are suitable in the sense of the functions discussed above.
  • the membrane may comprise one or a combination of the following materials: polyester, polyurethane, polytetrafluoroethylene, ceramic, carbon, aluminum.
  • first and second outer layer are in principle materials in question, which also came as a conventional outer layer for such laminates used.
  • both the first outer layer and the second outer layer are suitable for being worn on the skin or for the skin correspondingly comfortably.
  • both outer sides are preferably sufficiently stable in terms of their turning function, abrasion resistant and / or hard-wearing.
  • the first and / or second outer layer preferably comprises one or a combination of the following materials: polyamide, polyester, polyacrylic, polyurethane, cotton, wool, silk, bamboo, spandex, silver, ceramic, carbon, aluminum.
  • the preferred optical properties of the two outer layers can be achieved by a corresponding surface finish.
  • first light-absorbing outer layer in particular dark, preferably black, matt materials are suitable, which preferably have a rough surface finish.
  • second, light-reflecting outer layer particularly bright, for example white, or reflective, for example silvery or metal-colored, materials with a preferably smooth and / or shiny surface are suitable.
  • the first outer layer has a Schlnchiere according to ISO 12947-1 of at least 40000 Martindale, preferably of at least 50,000 Martindale, more preferably of at least 60,000 Martindale.
  • the second outer layer preferably has a Schl containiere according to ISO 12947-1 of at least 30,000 Martindale, preferably of at least 35,000 Martindale, more preferably of at least 40,000 Martindale.
  • the item of clothing is preferably intended to be worn on both sides, so that, depending on requirements, the first or second outer layer faces outward.
  • the item of clothing is not only basically suitable for being turned to the left, but that the item of clothing is explicitly designed so that the inside can also point outwards.
  • both outer sides should be correspondingly abrasion-resistant, the processing of the seams should be such that both outer sides can be carried outwards, and preferably one or more reversible pockets be provided which are suitable for being able to be used on both sides.
  • the garment is a reversible jacket.
  • the laminate according to the invention can also be used for other clothing, in particular for jackets, pants, T-shirts, pullovers, shirts, functional underwear, headgear such as caps or hats, gloves and swimwear.
  • the laminate according to the invention can also be used for tent fabrics, blankets, insulating mats or the like. In the case of the latter as well, there are in each case an outwardly directed side and a side directed toward the body, so that here too the turning properties described above can be of advantage.
  • the laminate described above has the advantage that it warms when it is to warm and cools when it is supposed to cool.
  • the laminate of the present invention with minimum weight, provides heat-cold-regulating comfort in various life and stress situations.
  • Functional clothing made of the laminate according to the invention saves weight, without sacrificing comfort, and combines the functions of three garments by providing protection against the cold, rain protection and heat protection.
  • a reversible jacket according to the invention which consists of the laminate according to the invention.
  • the reversible jacket according to the invention has a first, light-absorbing, black outer layer and a second light-reflecting, white or silver-colored outer layer.
  • the reversible jacket is made in such a way that both outer layers can be worn to the outside, without compromises in terms of comfort and design would have to be made.
  • two turning pockets can be seen, which are used on both sides, that can be opened and closed or filled from both sides.
  • the reference jacket consists of a 3-layer laminate. Upper (outer) and lower (inner layer) are made of 100% polyamide. The membrane is made of 100% polyurethane.
  • the reference jacket "Makalu" from the company Mammut has a black outer layer and a so-called DRYtech membrane, which withstands a water column of 20,000 mm and has a vapor permeability of 20,000 g / m 2 in 24 hours. The investigation was in the climate chamber at the University of Innsbruck at an ambient temperature of 5 ° C and a humidity of 60%.
  • the subject was fitted with sensors for measuring skin temperature and air humidity on the scapula just behind the armpit (latissimus dorsi muscle). These were attached to the running apparel (Löffler C-TEX compression shirt and pants) outside. The sensors recorded the ambient temperature and humidity (between underwear and jacket) every 8 seconds and were turned off only after the test protocol was completed.
  • test person had to with both jackets in FIG. 7 go through the measurement protocol shown schematically. To do this, the subject first had to sit quietly for 7 minutes to acclimatize.
  • the subject then had to walk for 15 minutes at a rate of 17.5% and a speed of 4 km / h, corresponding to a climb speed of 700 meters per hour.
  • the first black outer layer was worn outwards during the acclimatization phase and the first loading phase, and the reversible jacket was then turned between the two loading phases and worn outwards during the second loading phase with the second, white outer layer.
  • the jacket was turned again and worn during both periods of rest with the first, black outer layer to the outside.
  • the reference jacket was worn outward during the entire measurement protocol with the usual outer layer.
  • FIG. 8 The result of the temperature measurement during this measurement protocol is in FIG. 8 to see.
  • the solid line shows the temperature profile during the measurement protocol under the reversible jacket according to the invention ("poly"), the dashed line those of the reference jacket ("reference").
  • poly the temperature profile during the measurement protocol under the reversible jacket according to the invention
  • reference those of the reference jacket
  • both jackets cause a slight increase in temperature. This was due to the increased To expect heat production under load.
  • the advantage of the reversible jacket according to the invention shows in the second load phase, during which the temperature rises strongly under the reference jacket, whereas the reversible jacket according to the invention keeps the temperature reasonably constant. The latter is based as out FIG.
  • the temperature drop which is caused by the turning (at minute 22), as well as by a reduced temperature increase during the second loading phase.
  • the temperature under the reference jacket is significantly higher than the temperature under the reversible jacket of the invention (see, minute 37).
  • the subject thus experiences under load with the reversible jacket according to the invention a cooling effect, which is positive for performance and circulatory system to evaluate.
  • minute 38 and minute 40 the reversible jacket of the invention is turned back, which can explain the renewed temperature drop.
  • the reference jacket leads to higher temperatures under load and infrared radiation (see Minute 38) and relative to lower temperatures in the recovery phase under infrared radiation (see the development between the minutes 38 and 45).
  • the temperature balance of the subject is better regulated by the reversible jacket of the invention, since the jacket during performance cools and warms in the subsequent rest phase, so that overheating during performance prevented and shivering after the end of the exercise can be delayed.
  • the result of the humidity measurement during the measurement protocol is in FIG. 9 to see.
  • the solid line shows the course during the measurement protocol under the reversible jacket according to the invention ("poly"), the dashed line those of the reference jacket ("reference").
  • poly the reversible jacket according to the invention
  • reference the reference jacket
  • the turn of the jacket at minute 22 leads to a strong drop in humidity, but in the long run, the value is similar to that the referee jacket (compare Minte 37).
  • the effect of heating under infrared radiation may also cause an increase in humidity.
  • the turning of the jacket according to the invention leads, at least for a short time, to reduced air humidity under clothing, which was also confirmed by the subjects as part of a sensitivity survey. These stated that they had felt "less wet” during the measurement with the reversible jacket.
  • the athlete / user can, after strenuous activity, simply turn the jacket over on the dry side without sacrificing the functionality of the non-wearable jacket.
  • the advantage of turning the jacket after effort is the much better evaporation of body moisture on the textile. Unpleasant shivering and creeping cold danger is thus actively counteracted.
  • the reversible jacket can make the body climate positive in all situations of athletic active life in favor of the wearer by a high reflection characteristic and smart ventilation.
  • the wearer no longer has to fear the dreaded heat build-up and the associated loss of performance or discomfort, as the wearer can always have the right jacket at the right moment.
  • this product can be used in extreme sun, especially with the hood.
  • FIGS. 1 to 6 illustrated embodiment of the reversible jacket also has almost invisible “seam tapes" on the silver side (tapes, which make the jacket even more waterproof) and the possibility of biregulatable underarm ventilation.

Claims (12)

  1. Stratifié avec une première couche extérieure absorbant la lumière, une deuxième couche extérieure opposée réfléchissant la lumière et une membrane intermédiaire, caractérisé en ce que le stratifié présente une perméabilité à la vapeur d'au moins 10000 g/m2/24h, en ce que pour toutes les longueurs d'ondes entre 400 nm et 900 nm, la première couche extérieure présente une réflexion diffuse de 20 % maximum, de préférence de 18 % maximum, de façon particulièrement préférée de 15 % maximum, et en ce que pour toutes les longueurs d'ondes entre 300 nm et 1100 nm, la deuxième couche extérieure présente une réflexion diffuse d'au moins 15 %, de préférence d'au moins 20 %, de façon particulièrement préférée d'au moins 22 %, et plus préférentiellement encore, d'au moins 24 %.
  2. Stratifié selon la revendication 1, caractérisé en ce que la membrane est essentiellement étanche à l'eau, de préférence dans les deux directions, la membrane résistant à une colonne d'eau d'au moins 5000 mm, de préférence d'au moins 10000 mm, de façon particulièrement préférée d'au moins 15000 mm (mesurée selon ISO 811), de préférence dans deux directions.
  3. Stratifié selon l'une des revendications précédentes, caractérisé en ce que le stratifié est essentiellement perméable à la vapeur d'eau, de préférence dans deux directions, le stratifié présentant de préférence une perméabilité à la vapeur d'eau d'au moins 20000 g/m2/24h, de préférence d'au moins 25000 g/m2/24h, de façon particulièrement préférée d'au moins 30000 g/m2/24h, de préférence dans deux directions.
  4. Stratifié selon l'une des revendications précédentes, caractérisé en ce que pour une longueur d'onde de 500 nm, la deuxième couche extérieure présente une réflexion diffuse d'au moins 15 %, de préférence d'au moins 20 %, de façon particulièrement préférée d'au moins 22 % et plus préférentiellement encore d'au moins 24 %.
  5. Stratifié selon l'une des revendications précédentes, caractérisé en ce que pour une longueur d'onde de 700 nm, la deuxième couche extérieure présente une réflexion diffuse d'au moins 15 %, de préférence d'au moins 20 %, de façon particulièrement préférée d'au moins 23 % et plus préférentiellement encore d'au moins 25 %.
  6. Stratifié selon l'une des revendications précédentes, caractérisé en ce que pour toutes les longueurs d'ondes entre 400 nm et 700 nm, la première couche extérieure présente une réflexion diffuse de 12 % maximum, de préférence de 10 % maximum, de façon particulièrement préférée de 8 % maximum, et plus préférentiellement encore de 6 % maximum.
  7. Stratifié selon l'une des revendications précédentes, caractérisé en ce que pour une longueur d'onde de 500 nm, la première couche extérieure présente une réflexion diffuse de 10 % maximum, de préférence de 5 % maximum, de façon particulièrement préférée de 3 % maximum, et plus préférentiellement encore de 2 % maximum.
  8. Stratifié selon l'une des revendications précédentes, caractérisé en ce que pour une longueur d'onde de 700 nm, la première couche extérieure présente une réflexion diffuse de 12 % maximum, de préférence de 10 % maximum, de façon particulièrement préférée de 8 % maximum, et plus préférentiellement encore de 6 % maximum.
  9. Stratifié selon l'une des revendications précédentes, caractérisé en ce que pour toutes les longueurs d'ondes entre 400 nm et 700 nm, la première couche extérieure présente une réflexion diffuse de 30 % maximum, de préférence de 25 % maximum, de façon particulièrement préférée de 20 % maximum de la réflexion diffuse de la deuxième couche extérieure.
  10. Stratifié selon l'une des revendications précédentes, caractérisé en ce que la membrane présente l'un des matériaux suivants ou une combinaison de ceux-ci : polyester, polyuréthane, polytétrafluoréthylène, céramique, la première couche extérieure présentant l'un des matériaux suivants ou une combinaison de ceux-ci : polyamide, polyester, polyacrylique, polyuréthane, coton, laine, soie, bambou, élasthanne, argent, céramique, carbone, aluminium, la deuxième couche extérieure présentant l'un des matériaux suivants ou une combinaison de ceux-ci : polyamide, polyester, polyacrylique, polyuréthane, coton, laine, soie, bambou, élasthanne, argent, céramique, carbone, aluminium.
  11. Stratifié selon l'une des revendications précédentes, caractérisé en ce que la première couche extérieure présente une abrasivité selon ISO 12947-1 d'au moins 40000 Martindales, de préférence d'au moins 50000 Martindales, de façon particulièrement préférée d'au moins 60000 Martindales, la deuxième couche extérieure présentant une abrasivité selon ISO 12947-1 d'au moins 30000 Martindales, de préférence d'au moins 35000 Martindales, de façon particulièrement préférée d'au moins 40000 Martindales.
  12. Vêtement caractérisé par un stratifié selon l'une des revendications précédentes.
EP12729375.1A 2011-05-24 2012-05-24 Laminé multicouche Active EP2713788B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12729375.1A EP2713788B1 (fr) 2011-05-24 2012-05-24 Laminé multicouche

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP11167348 2011-05-24
EP11173274A EP2526795A1 (fr) 2011-05-24 2011-07-08 Laminé multicouche
PCT/EP2012/059730 WO2012160144A1 (fr) 2011-05-24 2012-05-24 Laminé multicouche
EP12729375.1A EP2713788B1 (fr) 2011-05-24 2012-05-24 Laminé multicouche

Publications (2)

Publication Number Publication Date
EP2713788A1 EP2713788A1 (fr) 2014-04-09
EP2713788B1 true EP2713788B1 (fr) 2016-07-13

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Family Applications (2)

Application Number Title Priority Date Filing Date
EP11173274A Withdrawn EP2526795A1 (fr) 2011-05-24 2011-07-08 Laminé multicouche
EP12729375.1A Active EP2713788B1 (fr) 2011-05-24 2012-05-24 Laminé multicouche

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP11173274A Withdrawn EP2526795A1 (fr) 2011-05-24 2011-07-08 Laminé multicouche

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EP (2) EP2526795A1 (fr)
WO (1) WO2012160144A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104188225A (zh) * 2014-08-14 2014-12-10 江苏箭鹿毛纺股份有限公司 一种抗静电保健复合羊毛呢
CN104382244A (zh) * 2014-10-30 2015-03-04 常熟市长生针织服饰有限公司 一种竹炭纤维羊毛复合内衣面料
CN104997215A (zh) * 2015-08-03 2015-10-28 安徽创荣服装辅料有限公司 一种复合羊毛面料

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2044599A (en) * 1979-03-28 1980-10-22 Heath & Son Ltd G High visibility garments
GB8507335D0 (en) * 1985-03-21 1985-05-01 Compton Webb Career Wear Ltd Reversible textile articles
US4569874A (en) * 1985-04-17 1986-02-11 Lawrence Kuznetz Sportswear fabric for cold climates
US5029344A (en) * 1990-09-06 1991-07-09 Shannon Thomas D Double-reversible garments
DE102004024075B4 (de) * 2004-05-13 2010-12-23 BLüCHER GMBH Adsorptionsfiltermaterial, seine Verwendung und Schutzmaterialien
KR20070068417A (ko) * 2004-10-25 2007-06-29 스미토모덴코파인폴리머 가부시키가이샤 다공질 복합재료의 제조방법 및 다공질 복합재료
US20080127395A1 (en) * 2006-12-01 2008-06-05 Blauer Manufacturing Company, Inc. Front closure for reversible outerwear

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EP2713788A1 (fr) 2014-04-09
EP2526795A1 (fr) 2012-11-28
WO2012160144A1 (fr) 2012-11-29

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