EP2655567A1 - Système de distribution de vapeur pour le traitement de la biomasse - Google Patents

Système de distribution de vapeur pour le traitement de la biomasse

Info

Publication number
EP2655567A1
EP2655567A1 EP11811158.2A EP11811158A EP2655567A1 EP 2655567 A1 EP2655567 A1 EP 2655567A1 EP 11811158 A EP11811158 A EP 11811158A EP 2655567 A1 EP2655567 A1 EP 2655567A1
Authority
EP
European Patent Office
Prior art keywords
steam
bar
heating
biomass
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11811158.2A
Other languages
German (de)
English (en)
Inventor
Henrik Boye JØRGENSEN
Henning Andersen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inbicon AS
Original Assignee
Inbicon AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inbicon AS filed Critical Inbicon AS
Publication of EP2655567A1 publication Critical patent/EP2655567A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • F22B1/1861Waste heat boilers with supplementary firing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K17/00Using steam or condensate extracted or exhausted from steam engine plant
    • F01K17/06Returning energy of steam, in exchanged form, to process, e.g. use of exhaust steam for drying solid fuel or plant
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K17/00Using steam or condensate extracted or exhausted from steam engine plant
    • F01K17/02Using steam or condensate extracted or exhausted from steam engine plant for heating purposes, e.g. industrial, domestic
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K7/00Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating
    • F01K7/34Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being of extraction or non-condensing type; Use of steam for feed-water heating
    • F01K7/40Use of two or more feed-water heaters in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/08Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being steam
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/14Combined heat and power generation [CHP]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the field of the invention relates to delivery of steam produced by an electrical power generation plant to a lignocellulosic biomass refinery.
  • second generation bioethanol produced from lignocellulosic biomass such as crop wastes (stalks, cobs, pits, stems, shells, husks, etc.), grasses, straws, wood chips, waste paper and the like.
  • fermentable 6-carbon sugars, and potentially fermentable 5-carbon sugars are liberated from biomass polysaccharide polymer chains by enzymatic hydrolysis or, in some cases, by pure chemical hydrolysis.
  • the fermentable sugars obtained from biomass conversion can be used to produce fuel ethanol or, alternatively, other fuels such as butanol, or lactic acid monomers for use in synthesis of bioplastics, or many other products.
  • hydrothermal pretreatments are especially attractive. These utilize pressurized steam/liquid hot water at temperatures on the order of 160 - 230 o C to gently melt hydrophobic lignin that is intricately associated with cellulose strands, to solubilize a major component of hemicellulose, rich in 5 carbon sugars, and to disrupt cellulose strands so as to improve accessibility to productive enzyme binding. Hydrothermal pretreatment does not require any added industrial chemicals and can be conveniently integrated with existing coal- and biomass-fired electrical power generation plants to efficiently utilize turbine steam and "excess" power production capacity.
  • steam supply for the biomass refinery is produced first by pressurizing comparatively low temperature water ( ⁇ 100 o C) to a desired final pressure then heating the pressurized water to a final steam temperature by means of a series of heat exchangers fed by turbine steam.
  • Power generation plants are typically configured so as to provide discrete extraction points where turbine steam may be extracted for other purposes. However these extraction points typically extract steam having a definite pressure. It can occur that a power generation plant is configured to provide extraction steam at pressures that do not correspond to the steam pressure requirements of the biomass refinery. Accordingly, where steam is provided directly by the power generation plant to the biomass refinery, there can often be
  • At least one compressor for pressurizing low temperature water to pressures of at least 5 bar
  • FIG. 1 shows a schematic illustration of one preferred embodiment of a system according to the invention.
  • Two separate pre-heating trains are used to provide steam at two different final pressures of 10 and 20 bar.
  • a compressor (1 ) compresses low temperature water to a final pressure of 10 bar.
  • compressed low temperature water is then heated by series of three counter-current heat exchangers (2) supplied with heat by extracted turbine steam (3) from an associated power generation plant.
  • the pre-heated, pressurized water is then conveyed as steam to biomass processing devices such as distillation units, dryers and evaporators by means of steam pipeline (4).
  • biomass processing devices such as distillation units, dryers and evaporators by means of steam pipeline (4).
  • a compressor (5) compresses low temperature water to a final pressure of 20 bar.
  • compressed low temperature water is then heated by series of three counter-current heat exchangers (6) supplied with heat by extracted turbine steam (7) from an associated power generation plant.
  • the pre-heated, pressurized water is then conveyed as steam to biomass processing devices such as hydrothermal pretreatment reactors by means of steam pipeline (8).
  • pre-heating trains may be configured in a variety of different ways, depending on the level of turbine steam pressure that is available for extraction from the power generation plant.
  • a steam delivery system according to the invention may be used in combination with an additional heat source.
  • 10 bar steam from a pre-heating train fed by turbine steam can be further super-heated to 20 bar steam using a gas-fired boiler.
  • methane gas for such a boiler can be provided by anaerobic digestion of waste water produced by the biomass refinery.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

L'invention concerne la distribution de la vapeur produite par une centrale électrique à une raffinerie de biomasse lignocellulosique.
EP11811158.2A 2010-12-21 2011-12-21 Système de distribution de vapeur pour le traitement de la biomasse Withdrawn EP2655567A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201061425251P 2010-12-21 2010-12-21
PCT/IB2011/055852 WO2012085860A1 (fr) 2010-12-21 2011-12-21 Système de distribution de vapeur pour le traitement de la biomasse

Publications (1)

Publication Number Publication Date
EP2655567A1 true EP2655567A1 (fr) 2013-10-30

Family

ID=45509584

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11811158.2A Withdrawn EP2655567A1 (fr) 2010-12-21 2011-12-21 Système de distribution de vapeur pour le traitement de la biomasse

Country Status (6)

Country Link
US (1) US20130269631A1 (fr)
EP (1) EP2655567A1 (fr)
CN (1) CN103339237A (fr)
BR (1) BR112013015640A2 (fr)
CA (1) CA2822423A1 (fr)
WO (1) WO2012085860A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9440163B2 (en) 2011-09-14 2016-09-13 Aquasource Technologies Corporation System and method for water treatment
EP3333312B1 (fr) 2016-12-08 2019-09-18 Valmet AB Procédé et système de traitement de biomasse
EP3333313B1 (fr) 2016-12-08 2019-10-16 Valmet AB Procédé de traitement de biomasse et dispositif de traitement de biomasse
EP3333311B1 (fr) 2016-12-08 2019-09-25 Valmet AB Procédé d'imprégnation de biomasse et dispositif d'imprégnation de biomasse

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006022687A2 (fr) * 2004-08-03 2006-03-02 The Regents Of The Universtiy Of California Procede de pyrolyse de vapeur ameliorant l'hydro-gazeification de matieres carbonees

Family Cites Families (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2802114A (en) * 1955-06-15 1957-08-06 Foster Wheeler Corp Method and apparatus for the generation of power
US4004947A (en) * 1975-02-12 1977-01-25 United Technologies Corporation Pressurized fuel cell power plant
US3982962A (en) * 1975-02-12 1976-09-28 United Technologies Corporation Pressurized fuel cell power plant with steam powered compressor
US4001041A (en) * 1975-02-12 1977-01-04 United Technologies Corporation Pressurized fuel cell power plant
US3976506A (en) * 1975-02-12 1976-08-24 United Technologies Corporation Pressurized fuel cell power plant with air bypass
IT1038112B (it) * 1975-05-13 1979-11-20 Sir Soc Italiana Resine Spa Procedimento per la conversione il trasporto e la utilizzazione di energia
US4239603A (en) * 1978-02-22 1980-12-16 Dan Egosi Fuel-efficient generation of ejecting steam
US4212652A (en) * 1978-04-05 1980-07-15 Dupont Anthony A Apparatus and system for producing coal gas
US4282070A (en) * 1978-05-30 1981-08-04 Dan Egosi Energy conversion method with water recovery
US4240259A (en) * 1979-02-15 1980-12-23 Vincent Ogden W Boiler steam engine with steam recovery and recompression
DE3240745A1 (de) * 1982-11-04 1984-05-10 Kraftwerk Union AG, 4330 Mülheim Verfahren und anlage zur gewinnung von kohlenwasserstoffen aus oelhaltigem sand oder gestein
SU1521284A3 (ru) * 1985-02-02 1989-11-07 Проф.Др.-Инж.Др.-Инж. Е.Х.Клаус Книциа (Фирма) Энергетическа установка
GB8526055D0 (en) * 1985-10-22 1985-11-27 Ici Plc Electricity production
US5375151A (en) * 1991-12-09 1994-12-20 General Electric Company Reactor water cleanup system
US5346592A (en) * 1993-08-11 1994-09-13 Madani Anas A Combined water purification and power of generating plant
US5733941A (en) * 1996-02-13 1998-03-31 Marathon Oil Company Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid
US5861441A (en) * 1996-02-13 1999-01-19 Marathon Oil Company Combusting a hydrocarbon gas to produce a reformed gas
GB2351323A (en) * 1999-06-21 2000-12-27 Newtonville Ltd Heat and power generation plant.
US6419788B1 (en) * 2000-08-16 2002-07-16 Purevision Technology, Inc. Method of treating lignocellulosic biomass to produce cellulose
US6562105B2 (en) * 2001-09-27 2003-05-13 Praxair Technology, Inc. Combined method of separating oxygen and generating power
US6564579B1 (en) * 2002-05-13 2003-05-20 Black & Veatch Pritchard Inc. Method for vaporizing and recovery of natural gas liquids from liquefied natural gas
US8631657B2 (en) * 2003-01-22 2014-01-21 Vast Power Portfolio, Llc Thermodynamic cycles with thermal diluent
WO2004065763A2 (fr) * 2003-01-22 2004-08-05 Vast Power Systems Inc. Cycles thermodynamiques faisant intervenir un diluant thermique
US8579999B2 (en) * 2004-10-12 2013-11-12 Great River Energy Method of enhancing the quality of high-moisture materials using system heat sources
US7909895B2 (en) * 2004-11-10 2011-03-22 Enertech Environmental, Inc. Slurry dewatering and conversion of biosolids to a renewable fuel
EP2520609A1 (fr) * 2005-07-19 2012-11-07 Inbicon A/S Procédé et appareil de conversion de matériau cellulosique en éthanol
SE531872C2 (sv) * 2006-01-24 2009-09-01 Bengt H Nilsson Med Ultirec Fa Förfarande för stegvis energiomvandling
US20070291939A1 (en) 2006-02-15 2007-12-20 Samsung Electronics Co., Ltd. Method and system for transmission of uncompressed video over wireless channels
US8968515B2 (en) * 2006-05-01 2015-03-03 Board Of Trustees Of Michigan State University Methods for pretreating biomass
DE602007009980D1 (de) 2006-05-26 2010-12-02 Dong Energy Power As Verfahren zur syngasproduktion aus verflüssigter biomasse
US8065879B2 (en) * 2007-07-19 2011-11-29 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Thermal integration of oxygen plants
US20090208402A1 (en) * 2008-02-20 2009-08-20 Rossi Robert A Process and system for producing commercial quality carbon dioxide from fine particle limestone
CA2684817C (fr) * 2008-12-12 2017-09-12 Maoz Betzer-Zilevitch Procede de production de vapeur et installation de recuperation amelioree de petrole
US8057639B2 (en) * 2008-02-28 2011-11-15 Andritz Inc. System and method for preextraction of hemicellulose through using a continuous prehydrolysis and steam explosion pretreatment process
WO2009129233A2 (fr) * 2008-04-15 2009-10-22 Combined Solar Technologies, Llc Système et procédé de récupération d’eau
DE102008064321A1 (de) * 2008-09-19 2010-04-01 Ecoenergy Gesellschaft Für Energie- Und Umwelttechnik Mbh Externe Frischluftvorwärmung bei Feststofffeuerungen
CN101402983B (zh) * 2008-11-18 2012-08-29 华北电力大学 纤维生产乙醇和生物质燃烧发电的耦合工艺
US8500868B2 (en) * 2009-05-01 2013-08-06 Massachusetts Institute Of Technology Systems and methods for the separation of carbon dioxide and water
DE102009032537A1 (de) * 2009-07-10 2011-01-13 Hitachi Power Europe Gmbh Kohlekraftwerk mit zugeordneter CO2-Wäsche und Wärmerückgewinnung
US20110100005A1 (en) * 2009-10-30 2011-05-05 Sampson Glenn A Water reclamation in a concentrated solar power-enabled power plant
US8663364B2 (en) * 2009-12-15 2014-03-04 L'Air Liquide, Société Anonyme pour l'Étude et l'Éxploitation des Procédés Georges Claude Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture
US8617292B2 (en) * 2009-12-15 2013-12-31 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture
US8734569B2 (en) * 2009-12-15 2014-05-27 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture
US8880202B2 (en) * 2010-07-09 2014-11-04 Emerson Process Management Power & Water Solutions, Inc. Optimization system using an iteratively coupled expert engine
WO2012018542A1 (fr) * 2010-07-24 2012-02-09 Matthew Rosenfeld Techniques pour le stockage indirect d'énergie thermique à température froide
GB201104975D0 (en) * 2011-03-24 2011-05-11 Dow Corning Generation of vapour for use in an industrial process
AU2012266929B2 (en) * 2011-06-10 2017-11-23 Steeper Energy Aps Process and apparatus for producing liquid hydrocarbon
WO2014127913A2 (fr) * 2013-02-21 2014-08-28 Faramarz Bairamijamal Procédé haute pression de capture de co2, utilisation pour la récupération de chaleur, cycle de puissance, production super efficace d'énergie fossile à base d'hydrogène et conversion de co2 liquide avec de l'eau en gaz de synthèse et oxygène
MA38480B1 (fr) * 2013-03-15 2018-10-31 Mecs Inc Récupération de la chaleur d'absorption de trioxyde de soufre

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006022687A2 (fr) * 2004-08-03 2006-03-02 The Regents Of The Universtiy Of California Procede de pyrolyse de vapeur ameliorant l'hydro-gazeification de matieres carbonees

Also Published As

Publication number Publication date
WO2012085860A1 (fr) 2012-06-28
US20130269631A1 (en) 2013-10-17
BR112013015640A2 (pt) 2016-10-11
CN103339237A (zh) 2013-10-02
CA2822423A1 (fr) 2012-06-28

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