EP2598693B1 - Structure de sécurité incorporant des compositions phosphorescente et fluorescente - Google Patents
Structure de sécurité incorporant des compositions phosphorescente et fluorescente Download PDFInfo
- Publication number
- EP2598693B1 EP2598693B1 EP11749537.4A EP11749537A EP2598693B1 EP 2598693 B1 EP2598693 B1 EP 2598693B1 EP 11749537 A EP11749537 A EP 11749537A EP 2598693 B1 EP2598693 B1 EP 2598693B1
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- EP
- European Patent Office
- Prior art keywords
- compositions
- composition
- security
- phosphorescent
- fluorescent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
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- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/387—Special inks absorbing or reflecting ultraviolet light
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/42—Ribbons or strips
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/48—Elements suited for physical verification, e.g. by irradiation
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
- G07D7/1205—Testing spectral properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24322—Composite web or sheet
- Y10T428/24331—Composite web or sheet including nonapertured component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2935—Discontinuous or tubular or cellular core
Definitions
- the present invention relates to security structures intended to combat counterfeiting of identity or valuable documents.
- the invention relates more particularly to security structures comprising luminescent substances.
- luminescent substance should be understood to mean a fluorescent or phosphorescent substance.
- Requirement FR 2 866 036 discloses a flat security element which may incorporate a fluorescent or phosphorescent substance.
- Requirement EP 2 028 017 discloses a security structure comprising two openwork opaque layers, a first fluorescent layer being located between the first and second openwork opaque layers and a second fluorescent layer being located so as to be separated from the first fluorescent layer by one of the openwork opaque layers .
- Requirement US 2006/0014045 describes the possibility of applying a mixture of a fluorescent substance and a phosphorescent substance on a polymer layer of a security film.
- Requirement EP 0 303 725 discloses a security thread having an at least partial superposition of phosphorescent and / or fluorescent substances.
- the lights emitted by fluorescence and phosphorescence can combine or juxtapose according to the configurations of the security structure, and produce an optical effect which is different from that observable after extinction of the illuminant, where only the light emitted by phosphorescence is likely to be perceived by the observer.
- one of the first and second compositions forms at least one pattern which, when the lighting is switched off by the predefined illuminant, appears or disappears, or which changes appearance from a positive to negative pattern or from one color to another.
- the contrast of the pattern with respect to its immediate environment can be modified between the state in which the first and second compositions are illuminated by the predefined illuminant and that in which they are no longer, the modification of the contrast resulting for example from a change in color of the pattern and / or of its immediate environment, or of the light intensity of the pattern and of its immediate environment.
- the first and second compositions can be deposited by printing or by depositing a varnish, one for example completely covering the other or one being placed next to the other without covering it. One can still be arranged with partial superposition only on the other.
- the first and second compositions can emit by luminescence the same color, with substantially the same intensity or with different intensities.
- the phosphorescent and fluorescent compositions emit by luminescence the same color but at different intensities.
- the predefined illuminant it is possible to make a pattern appear in positive and this pattern becomes negative after extinction of the illuminant, this is the case for example if the fluorescent composition forms a pattern and is of greater intensity than the composition phosphorescent which surrounds the pattern, or conversely the pattern appears in negative under the illuminant then in positive after extinction of the illuminant.
- the phosphorescent composition is located on the fluorescent composition.
- the change in appearance of a pattern from positive to negative, or vice versa means that the pattern is still discernible but that its interior color or intensity is modified compared to the background, that is to say by relative to the color or intensity that surrounds the pattern.
- the phosphorescent and luminescent compositions can still luminescently emit different colors.
- the first and second compositions can be applied to the mark on the safety structure, in particular when they are juxtaposed.
- the first composition can form at least one positive unit and the second composition at least one negative unit, preferably complementary to the positive unit, placed at the mark.
- the arrangement at the reference point for the compositions can be done on the same face of a support of the structure or on either side of this support, which is then at least partially transparent.
- the first and second compositions can be juxtaposed and do not overlap, in particular in the case of mark printing.
- the security structure may include an opaque perforated layer and the first and second compositions may be located respectively on either side of this layer.
- the perforated opaque layer can be defined for example by at least one layer of locally demetallized metal or by a selective metallization or by a opacifying printing which is not necessarily metallic, for example comprising a black pigment or TiO 2 .
- the presence of the perforated opaque layer can allow, in the aperture (s), the light emitted by the second composition to be added at least partially to the light emitted by the first, therefore to observe a light under the predefined illuminant. resultant function of the luminescence colors present. Furthermore, the openings of the perforated opaque layer can also form patterns, which further enhances the safety of the structure.
- the security structure comprises a perforated opaque layer, with on one side thereof the first and second respectively fluorescent and phosphorescent compositions, and on the other side of this perforated opaque layer at least another luminescent, phosphorescent or fluorescent composition, preferably third and fourth respectively fluorescent and phosphorescent compositions.
- first, second, third and fourth compositions are possible, in particular in order to play on the nature of the compositions which are superimposed through the openings of the openwork opaque layer.
- the first and third compositions are shifted when the structure is observed from the first face.
- the second composition is also offset from the fourth.
- the first and third compositions can be superimposed at least partially with an openwork. The same can be done with the second and fourth compositions.
- the first and fourth compositions can be superimposed at the level of an openwork. The same can be true of the second and third compositions.
- the first and second compositions can be juxtaposed, without being superimposed; the same applies, for example, to the third and fourth compositions.
- the first and third compositions can be the same or different, as can the second and fourth compositions.
- the first composition can emit by luminescence, in one example, the color of the fourth and the second composition that of the third.
- the structure comprises two openwork opaque layers, these opaque layers possibly being perforated differently.
- the first composition can be located between the two openwork opaque layers and one of the openwork opaque layers can be located between the two compositions.
- the openings of the perforated opaque layer can also form patterns, which further enhances the safety of the structure.
- carrier is meant that the element or the layer prevents the passage of UV radiation for at least a certain range of wavelength values.
- the “barrier” function can make it possible to avoid the effects of subtractive combination of fluorescence and phosphorescence.
- the element and / or the barrier layer can be applied in the form of a pattern, for example a symbol, an alphanumeric character, a logo, among others.
- the pattern can be reproduced identically on the security document comprising the security structure.
- the layer and / or the barrier element to UV radiation can make it possible to prevent the passage of UV radiation whose wavelength is less than or equal to 400 nm.
- At least one of the compositions can be introduced into the security structure other than by printing.
- at least one of the layers of the security structure is a film of extruded thermoplastic material or a coating, which incorporates a pigment or a fluorescent or phosphorescent dye, or even which consists of a fluorescent or phosphorescent compound.
- composition should thus be understood broadly as encompassing both a solid film and a deposit which has solidified, such as an ink deposit for example or a varnish.
- the fluorescent composition and / or the phosphorescent composition may comprise a mixture of iridescent substances exhibiting an interference effect.
- the iridescent substances which can be used according to the invention mention may in particular be made of mother-of-pearl extracts, lead salts and micas.
- the preferred substances are micas, because mother-of-pearl extracts are very expensive, and lead salts, because of their toxicity, require compliance with very strict hygiene and safety rules.
- micas coated with at least one metal oxide are recommended, and in particular the products marketed by the company Merck AG under the name IRIODINE®, these products being micas coated with T i O 2 with, where appropriate, at least one other metal oxide.
- the security structure may be in the form of a security element intended to be integrated into any security document, in particular a paper document comprising natural and / or synthetic fibers, in particular cellulose fibers.
- the security structure can advantageously be in the form of a security thread or of a patch or of a security film.
- the security structure may merge with the security document, when the latter comprises a substrate on which the first and second compositions are applied directly, for example by printing, on the substrate of the entire document or in a strip.
- the security structure in the form of a wire the latter can be integrated into a paper mass during the formation of the sheet, for example in a machine with a round shape or with a flat table.
- the sheet can be formed so as to be equipped with windows, constituting openings allowing the security thread or the patch to appear at least partially.
- Another subject of the invention is a security document incorporating a security structure as defined above.
- the security structure may be observable from both sides of the document or from only one of the sides, depending on the variants.
- the security structure may possibly merge with the document, for example when the latter comprises a paper or other substrate which is printed with the first and second compositions.
- the security document can be chosen from identity documents and valuable documents, for example banknotes, tickets for shows or sporting events, checks, identity cards, passports, tickets. transport, among others.
- each of the fluorescent and phosphorescent compositions spans less than the full extent of one side of the document.
- the fluorescent composition preferably emits a red, green, blue or yellow color under UV illuminant at 365 nm. The same is true of the phosphorescent composition.
- the security document may include one or more additional security elements as defined below.
- security elements some are detectable by eye, in daylight or in artificial light, without using a particular device.
- These security elements include, for example, colored fibers or planchettes, fully or partially printed or metallized threads. These security elements are said to be first level.
- Additional security features are detectable only with a relatively simple device, such as an ultraviolet (UV) or infrared (IR) emitting lamp.
- UV ultraviolet
- IR infrared
- These security elements include, for example, fibers, boards, bands, threads or particles. These security elements may or may not be visible to the naked eye, for example being luminescent under lighting from a Wood lamp emitting in a wavelength of 365 nm. These security elements are said to be second level.
- Additional security elements require a more sophisticated detection device for their detection.
- These security elements are for example capable of generating a specific signal when they are subjected, simultaneously or not, to one or more external excitation sources. The automatic detection of the signal makes it possible to authenticate the document, if necessary.
- These security elements include, for example, tracers in the form of active materials, particles or fibers, capable of generating a specific signal when these tracers are subjected to optronic, electrical, magnetic or electromagnetic excitation. These security elements are said to be third level.
- the additional security element (s) present within the security document, or the security structure that it comprises, may have first, second or third level security characteristics.
- the fluorescent composition may contain at least one fluorescent compound chosen from a copolymer of acrylic styrene from the company ARJOWIGGINS and a magnesium doped with zinc sulfide from the company GLOWBUG.
- a subject of the invention is also a method of manufacturing a security structure as defined above, in which first and second compositions, respectively fluorescent and phosphorescent, are deposited on a support, in particular under UV illuminant at 365 nm, the deposition taking place in such a way that the two compositions are simultaneously excitable from the same face of the structure.
- the deposition of the compositions can be carried out by printing, in particular a marked printing of one of the compositions with respect to the other.
- the compositions can be deposited on one side of the structure or as a variant on both sides of the structure.
- the phosphorescent and fluorescent compositions for example each have a thickness of between 1 and 6 ⁇ m.
- a further subject of the invention is a method for manufacturing a security document in which a security structure according to the invention, as defined above, is incorporated into a paper substrate.
- one face of the structure is observed under UV illuminant and after extinction of the UV illuminant, and information relating to the authenticity of the document is deduced from the comparison of the observations.
- This comparison can be carried out automatically within a device responsible for this comparison, if necessary.
- both the light emitted by the fluorescent composition and the light emitted by the phosphorescent composition and / or an additive combination of the latter are observed.
- After extinction of the UV illuminant only the light emitted by the phosphorescent composition is observable. According to the combinations described above, it is thus possible to make the patterns formed by the first and / or second compositions appear / disappear which, by comparison between the presence of UV illuminant and after its extinction, makes it possible to authenticate the document.
- the structure 10 comprises a support 11 which is for example with a single-layer or multilayer structure, the support 11 preferably comprising at least one layer of a thermoplastic material, preferably transparent, for example of PET.
- phosphorescent 12 and fluorescent 13 compositions which emit different colors by luminescence.
- the two compositions 12 and 13 emit different lights which, by additive synthesis where the compositions are superimposed, give patterns 15 which appear of a first color, on a colored background 16 which appears of another color, which is that of fluorescence of the fluorescent composition 13 in the example illustrated in figure 3c .
- the patterns 15 appear in white, by additive synthesis where the compositions are superimposed, while the background 16 appears in blue.
- the UV excitation is turned off, the patterns 15 appear in yellow for the duration of the persistence of the phosphorescent composition 12, as illustrated in 3d figure .
- phosphorescent and fluorescent compositions which emit the same color, but at different intensities.
- the pattern (s) will appear with a different contrast from the background compared to the absence of UV, due to the addition of the intensities luminous of the phosphorescent composition and of the fluorescent composition. After extinction of the UV source, only the units defined by the phosphorescent composition appear positive.
- a pattern defined by the phosphorescent composition is superimposed on a solid area of fluorescent composition, the phosphorescent composition emitting with a lower intensity than the fluorescent composition.
- the fluorescent composition 13 is deposited in the form of a solid on the face 14 of the support 11, while the phosphorescent composition 12 is deposited in the form of patterns in positive or negative writing, depending on the variants.
- the term “flat” should be understood to mean a homogeneous deposit of sufficient extent to extend around the pattern at least.
- the fluorescent composition 13 is deposited on the face 14 of the support 11 in the form of patterns, in positive writing or negative, and the phosphorescent composition 12 is deposited in the form of a solid which covers the fluorescent composition 13.
- the phosphorescent composition 12 is deposited in the form of a solid on the face 14 of the support 11, while the fluorescent composition 13 is deposited so as to define patterns in positive or negative writing, on the phosphorescent composition 12.
- the phosphorescent 12 and fluorescent 13 compositions are located on the same side of the support 11.
- the phosphorescent 12 and fluorescent 13 compositions respectively on either side of the support 11, the fluorescent composition 13 being for example deposited on the face 14 and the phosphorescent composition 12 on the surface. opposite face 17, as shown in figure 8 , the support 11 being at least partially transparent where the compositions 12 and 13 are superimposed and / or where it is superimposed with the composition deposited on the face 17.
- the support 11 can be only partially transparent, which can include opaque zones 18, for example metallizations, and openings 19, as illustrated in figure 11 .
- Example 1 Lighting under UV maintained with the phosphorescent composition 12 which emits a blue light and the fluorescent composition 13 a yellow light
- Example 3 After extinction of the UV lighting with the side of face A, the phosphorescent composition emits in yellow and the fluorescent composition emits in blue and on the side of the face B the phosphorescent composition emits in blue and the fluorescent composition emits in yellow
- the figure 14 represents an alternative embodiment of a security structure 10 according to the invention.
- the support 11 is completely transparent and comprises on each of its opposite faces elements 20 forming a barrier to ultraviolet (UV) radiation, applied for example in the form of layers respectively on the surface.
- the barrier elements 20 can be placed on either side of the support 11 without being superimposed on each other.
- the elements 20 forming a barrier to ultraviolet radiation are transparent to visible radiation so that the pattern they form is visible only under a predefined excitation and invisible under visible radiation, which further adds to the safety of the light. structure.
- the barrier elements 20 can correspond to prints and / or coatings made on the support 11.
- the barrier elements 20 can form a pattern, which can appear under a predefined excitation to allow authentication of the security structure 10.
- the formation of the barrier elements 20 on the support 11, in particular by printing and / or coating, can be carried out after the manufacture of the support 11 coated with fluorescent 13 and phosphorescent 12 compositions, thus making it possible to personalize the security structure 10, for example under in the form of a security thread, with the aid of the barrier elements 20 arranged in the form of patterns.
- the barrier elements 20 can be printed at the mark on each of the faces of the support 11, coated respectively with the fluorescent composition 13 and the phosphorescent composition 12. Areas are thus observed where the compositions 12 and 13 located on either side of the support 11 are superimposed on one another, which is the case with zones S1 and S3, and zones where compositions 12 and 13 located on either side of support 11 are both at least partially superimposed with a same barrier element 20 , which is the case with areas S0, S2 and S4.
- Example 4 Lighting under UV maintained with the phosphorescent composition 12 which emits a blue light and the fluorescent composition 13 a yellow light
- the support 11 of the figure 14 may include opaque areas, as described above, for example in the form of metallizations, and / or UV radiation barrier elements arranged for example between openings 19 as described above.
- a support 11 comprising barrier elements 20 can be produced using two films, in particular made of polyester, the first film serving as a support for the printing and / or coating of barrier elements 20, which constitute a second film on which the fluorescent and / or phosphorescent compositions are deposited.
- the security structure comprises only a first fluorescent composition and a second phosphorescent composition in the form of a solid, respectively arranged on either side of the perforated support.
- FIG. 12 One represented on the figure 12 an alternative embodiment in which the structure 10 comprises two transparent layers 11a and 11b.
- the structure 10 When the structure 10 is observed under UV illuminant from the face 14 of the layer 11a, by illuminating the structure from this face, the lights emitted by luminescence by the compositions 12 and 13 are added where the openings 19b allow the light emitted by the fluorescent composition 13 to reach the face 14, while where this light is blocked by the opaque zones 18b, the patterns formed by the openings 19a are only observable with the light produced by the fluorescent composition 13.
- FIG. 13 We represented at the figure 13 an example of a security document 30 incorporating a security structure 10 in accordance with the invention. This is in the form of a security thread incorporated into windows, and extending from one edge of the document to the other.
Landscapes
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Finance (AREA)
- Accounting & Taxation (AREA)
- Business, Economics & Management (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Credit Cards Or The Like (AREA)
- Printing Methods (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
- Luminescent Compositions (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RS20201464A RS61167B1 (sr) | 2010-07-29 | 2011-07-26 | Sigurnosna konstrukcija koja obuhvata fosforescentna i fluorescentna jedinjenja |
PL11749537T PL2598693T3 (pl) | 2010-07-29 | 2011-07-26 | Struktura zabezpieczająca zawierająca kompozycje fosforyzujące i fluorescencyjne |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1056284A FR2963356B1 (fr) | 2010-07-29 | 2010-07-29 | Structure de securite incorporant des compositions phosphorescente et fluorescente |
PCT/IB2011/053323 WO2012014151A1 (fr) | 2010-07-29 | 2011-07-26 | Structure de sécurité incorporant des compositions phosphorescente et fluorescente |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2598693A1 EP2598693A1 (fr) | 2013-06-05 |
EP2598693B1 true EP2598693B1 (fr) | 2020-09-30 |
Family
ID=43033064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11749537.4A Active EP2598693B1 (fr) | 2010-07-29 | 2011-07-26 | Structure de sécurité incorporant des compositions phosphorescente et fluorescente |
Country Status (12)
Country | Link |
---|---|
US (1) | US10011141B2 (ko) |
EP (1) | EP2598693B1 (ko) |
KR (2) | KR101889526B1 (ko) |
CN (1) | CN103038418B (ko) |
BR (1) | BR112013002005B1 (ko) |
ES (1) | ES2835182T3 (ko) |
FR (1) | FR2963356B1 (ko) |
HU (1) | HUE052330T2 (ko) |
PL (1) | PL2598693T3 (ko) |
RS (1) | RS61167B1 (ko) |
RU (1) | RU2578316C2 (ko) |
WO (1) | WO2012014151A1 (ko) |
Cited By (1)
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EP3166798B1 (en) | 2014-07-07 | 2020-08-19 | Security Fibres UK Limited | Improvements in and relating to security documents |
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US8872818B2 (en) | 2013-03-15 | 2014-10-28 | State Farm Mutual Automobile Insurance Company | Methods and systems for capturing the condition of a physical structure |
US11542080B2 (en) * | 2013-05-07 | 2023-01-03 | BBB Holding Company | Track and trace packaging and systems |
FR3014017B1 (fr) * | 2013-12-03 | 2018-12-07 | Hid Global Cid Sas | Structure de securite |
FR3020595B1 (fr) * | 2014-05-02 | 2016-05-06 | Oberthur Fiduciaire Sas | Bandeau de securite et document de securite qui l'integre |
FR3020596B1 (fr) * | 2014-05-02 | 2017-03-10 | Oberthur Fiduciaire Sas | Document de securite impregne d'un agent desopacifiant et procede de traitement d'un document |
CN104988798B (zh) * | 2015-07-24 | 2017-06-06 | 中国人民银行印制科学技术研究所 | 一种防伪纤维及其制备方法 |
JP2017053663A (ja) * | 2015-09-08 | 2017-03-16 | 株式会社東芝 | 画像読取装置、及び紙葉類処理装置 |
EP3390065B1 (en) * | 2015-12-17 | 2021-06-16 | Sicpa Holding Sa | Security element formed from at least two inks applied in overlapping patterns, articles carrying the security element, and authentication methods |
EP3390066B1 (en) * | 2015-12-17 | 2021-03-10 | Sicpa Holding Sa | Security element formed from at least two materials present in partially overlapping areas, articles carrying the security element, and authentication methods |
GB2547045A (en) * | 2016-02-08 | 2017-08-09 | De La Rue Int Ltd | Improvements in security devices |
JP6658166B2 (ja) * | 2016-03-18 | 2020-03-04 | コニカミノルタ株式会社 | 読取装置、読取方法、および読取プログラム |
CN106240190B (zh) * | 2016-07-18 | 2018-12-21 | 中国人民银行印制科学技术研究所 | 防伪元件及其制作方法、安全物品、物品检测方法和装置 |
AU2017330350B2 (en) * | 2016-09-23 | 2023-07-27 | Crown Packaging Technology, Inc. | Can imprinting device and associated methods |
CN106996057A (zh) * | 2017-04-24 | 2017-08-01 | 上海先幻新材料科技有限公司 | 一种防伪纸张添加物及其制备方法 |
KR102355877B1 (ko) | 2017-12-27 | 2022-01-26 | 한국조폐공사 | 보안잉크가 인쇄된 보안 인쇄물 |
DE102018129365A1 (de) * | 2018-11-21 | 2020-05-28 | Bundesdruckerei Gmbh | Codierungssystem zum Ausbilden eines Sicherheitsmerkmals in oder an einem Sicherheits- oder Wertdokument oder einer Mehrzahl von Sicherheits- oder Wertdokumenten |
KR102446998B1 (ko) * | 2020-10-05 | 2022-09-26 | 한국과학기술원 | 그래핀 양자점 기반의 보안 인쇄용 잉크 조성물 및 이를 이용한 보안 표지 |
GB202017778D0 (en) * | 2020-11-11 | 2020-12-23 | Security Fibres Uk Ltd | Authentication of security documents |
KR20230076650A (ko) | 2021-11-24 | 2023-05-31 | 한국조폐공사 | 보안 잉크가 인쇄된 보안문서의 위변조 판별 시스템 |
DE102022000101A1 (de) | 2022-01-12 | 2023-07-13 | Giesecke+Devrient Currency Technology Gmbh | Optisch variables Sicherheitselement |
CN118219689B (zh) * | 2024-05-24 | 2024-07-12 | 广东工业大学 | 一种隐藏图案信息的防伪标签及其制作方法和图案显现方法 |
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GB2375078A (en) | 2001-04-30 | 2002-11-06 | Rue De Int Ltd | Security substrate with indicia only viewable in transmitted light |
FR2866036B1 (fr) | 2004-02-11 | 2007-06-15 | Arjo Wiggins Secutity Sas | Elements de securite de format relativement petit et leur procede de fabrication, feuille et document de securite les comportant |
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FR2877609B1 (fr) * | 2004-11-08 | 2007-03-09 | Arjowiggins Security Soc Par A | Structure de securite et article incorporant une telle structure |
DE102005007749A1 (de) * | 2005-02-18 | 2006-08-31 | Giesecke & Devrient Gmbh | Sicherheitselement und Verfahren zu seiner Herstellung |
US7654581B2 (en) * | 2005-05-06 | 2010-02-02 | Canadian Bank Note Company, Limited | Security document with ultraviolet authentication security feature |
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FR2901286B1 (fr) * | 2006-05-19 | 2011-08-19 | Arjowiggins | Procede de fabrication d'un materiau en feuille comprenant au moins une couche fibreuse et des elements de securite et/ou decoratifs |
GB2452078B (en) * | 2007-08-23 | 2009-12-23 | Rue De Int Ltd | Security devices for security substrates |
US20100194093A1 (en) * | 2009-12-23 | 2010-08-05 | Bank Of Canada | Security devices, their production and use |
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2010
- 2010-07-29 FR FR1056284A patent/FR2963356B1/fr active Active
-
2011
- 2011-07-26 BR BR112013002005-9A patent/BR112013002005B1/pt active IP Right Grant
- 2011-07-26 US US13/813,103 patent/US10011141B2/en active Active
- 2011-07-26 KR KR1020137002796A patent/KR101889526B1/ko active IP Right Grant
- 2011-07-26 EP EP11749537.4A patent/EP2598693B1/fr active Active
- 2011-07-26 RU RU2013107741/05A patent/RU2578316C2/ru active
- 2011-07-26 KR KR1020187023226A patent/KR102059764B1/ko active IP Right Grant
- 2011-07-26 HU HUE11749537A patent/HUE052330T2/hu unknown
- 2011-07-26 PL PL11749537T patent/PL2598693T3/pl unknown
- 2011-07-26 WO PCT/IB2011/053323 patent/WO2012014151A1/fr active Application Filing
- 2011-07-26 CN CN201180037043.1A patent/CN103038418B/zh active Active
- 2011-07-26 RS RS20201464A patent/RS61167B1/sr unknown
- 2011-07-26 ES ES11749537T patent/ES2835182T3/es active Active
Non-Patent Citations (1)
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Publication number | Priority date | Publication date | Assignee | Title |
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EP3166798B1 (en) | 2014-07-07 | 2020-08-19 | Security Fibres UK Limited | Improvements in and relating to security documents |
Also Published As
Publication number | Publication date |
---|---|
WO2012014151A1 (fr) | 2012-02-02 |
RU2013107741A (ru) | 2014-09-10 |
EP2598693A1 (fr) | 2013-06-05 |
KR20130132390A (ko) | 2013-12-04 |
CN103038418B (zh) | 2016-08-03 |
US20130147181A1 (en) | 2013-06-13 |
FR2963356B1 (fr) | 2014-08-22 |
RS61167B1 (sr) | 2021-01-29 |
ES2835182T3 (es) | 2021-06-22 |
HUE052330T2 (hu) | 2021-04-28 |
KR20180093135A (ko) | 2018-08-20 |
RU2578316C2 (ru) | 2016-03-27 |
PL2598693T3 (pl) | 2021-03-08 |
BR112013002005B1 (pt) | 2020-12-15 |
US10011141B2 (en) | 2018-07-03 |
BR112013002005A2 (pt) | 2016-05-31 |
FR2963356A1 (fr) | 2012-02-03 |
KR101889526B1 (ko) | 2018-08-17 |
KR102059764B1 (ko) | 2019-12-26 |
CN103038418A (zh) | 2013-04-10 |
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