Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
  • A61K8/27—Zinc; Compounds thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
  • A61K8/0241—Containing particulates characterized by their shape and/or structure
  • A61K8/027—Fibers; Fibrils
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/73—Polysaccharides
  • A61K8/731—Cellulose; Quaternized cellulose derivatives
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/88—Polyamides
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q19/00—Preparations for care of the skin
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/60—Particulates further characterized by their structure or composition
  • A61K2800/61—Surface treated

Definitions

• the present invention relates to compositions and methods for improving the appearance of keratin fibers, and in particular eyebrows, through the use of magnetically- oriented cosmetic fibers.
• the eyebrow is an area of thick, delicate hairs above the eye that typically follows the shape of the lower margin of the brow ridges.
• the main function of eyebrows is to protect the eye, but they are also important to human communication and facial expression. Furthermore, it is not uncommon for people to modify their eyebrows by means of hair addition or removal, and/or to enhance the appearance of their eyebrows with make up.
• the present invention thus provides, in one aspect, a product for creating or enhancing the appearance of keratin fibers on an individual's face or head, as well as methods for making the product and methods for applying the product to an individual's face or head.
• a product for creating or enhancing the appearance of keratin fibers comprising: (a) a matrix composed of one or more water-dissolvable polymers; and (b) a plurality of magnetic responsive fibers oriented in a non-random direction and embedded in said matrix.
• It is another aspect of the invention to provide a method for preparing a product for creating or enhancing the appearance of keratin fibers comprising: (a) applying an external magnetic field to an aqueous mixture of one or more water-dissolvable polymers and plurality of magnetic responsive fibers so as to orient the fibers in a non-random manner; and (b) removing the aqueous solvent to form a solid or semi-solid film.
• It is a further aspect of the invention to provide a method for applying a keratin fiber enhancing film comprising: (a) wetting the surface of an area on an individual's face or head to which the film will be applied; (b) positioning the film on the wetted surface; and (c) allowing the film to dissolve; wherein said film includes a plurality of non-randomly oriented fibers that are adhered to said individual's face or head by a water-dissolvable polymer.
• the application of the magnetic force to the magnetic responsive fibers orients the fibers in a non-random manner when applied to an individual's eyebrows, face or head.
• the present invention contemplates a dissolvable polymer film matrix comprising cosmetic fibers, such as nylon fibers, such that the polymer film may be applied to an individual's face or head and wherein upon dissolution of the film, the fibers remain and simulate the appearance of the individual's own hair.
• cosmetic fibers such as nylon fibers
• the nylon fibers ideally have the color and overall appearance of the individual's eyebrows or other surrounding hair depending upon where the fibers are applied.
• the fibers are magnetic responsive fibers and are oriented in a non- random direction and embedded in the matrix.
• orientation in a non-random direction is meant that the orientation is non- random with respect to at least one, two or three perpendicular axes.
• the fibers may have some degree of orientation along one or more planes, preferably including the plane containing the dissolvable film.
• the polymer film matrix is composed of one or more water-dissolvable polymers.
• water-dissolvable polymers contemplated by the present invention includes: water-soluble hydroxypropylmethyl cellulose (e.g., Methocel E50®, The Dow Chemical Company, Midland, MI), hydroxyethyl cellulose, hydroxypropyl cellulose, polyvinyl pyrrolidone, carboxymethyl cellulose, sodium carboxy methyl cellulose, methyl cellulose, polyvinyl alcohol, sodium alginate, polyethylene glycol, xanthan gum, tragacantha, guar gum, acacia gum, arabic gum, carrageenan, puUulan, chitosan, polyacrylic acid, methylmethacrylate copolymer, carboxyvinyl copolymers, and/or mixtures thereof.
• water-soluble hydroxypropylmethyl cellulose e.g., Methocel E50®, The Dow Chemical Company, Midland, MI
• the polymer film matrix may also comprise film formers which may be water soluble/dispersible or oil soluble/dispersible. Film formers may be hydrophilic or hydrophobic depending on the solvent system in the cosmetic gel. Suitable film formers include, but are not limited to, the following: one or more aery late copolymers such as acrylate/octylacrylamide copolymers and acrylate/vinyl acetate copolymers; ethylene/acrylic acid copolymer; polyacrylic acid; C 1 to C 5 alkyl galactomannan; adipic acid/diethylene glycol glycerin crosspolymer; trimethylpentanediol adipic acid copolymer; trimethylpentanediol/adipic acid/isononanoic acid; polyimides; alpha olefin/isopropyl maleate/maleic anhydride polymer; acrylates C 10 to C 30 alkyl acrylate crosspol
• the polyurethane resins include Polyurethane- 1, Polyurethane-2, Polyurethane-4, Polyurethane-5, and mixtures thereof. Additional film formers include those set forth in U.S. Pat. No. 5,916,541, which is incorporated herein by reference. [0019] To match the fibers in the matrix with those on an individual's face to which the matrix will be applied, the fibers may be pigmented (i.e., colored) to provide a reasonably close match with the color of the individual's natural, existing hair.
• Iron oxides are well known in the art to yield pigments and as such are also widely used in the cosmetic field. Iron oxides are considered to be nontoxic, moisture resistant, and nonbleeding. Iron oxides graded safe for cosmetic use are produced synthetically in order to avoid the inclusion of ferrous or ferric oxides, and impurities normally found in naturally occurring iron oxides. Typically, the iron (II) oxide pigment is black, while the iron (III) oxide is red or rust-colored. (Iron compounds other than oxides can have other colors.)
• Iron (11,111) oxide is found in nature as the mineral magnetite (and is commonly known as black iron oxide) and has the chemical formula Fe 3 O 4 . It contains both Fe 2+ and Fe 3+ ions and is sometimes formulated as FeO.Fe 2 O 3 . It is encountered in the laboratory as a black powder. It exhibits permanent magnetism and is ferrimagnetic, but is sometimes incorrectly described as ferromagnetic. It's most extensive use is as a black pigment which is synthesized rather than being extracted from the naturally occurring mineral as the particle size and shape can be varied by the method of production.
• the fibers are coated with a magnetic iron oxide such as black iron oxide (magnetite) and maghemite.
• a magnetic iron oxide such as black iron oxide (magnetite) and maghemite.
• the invention is not limited to these magnetic iron oxides and other magnetic minerals, including magnetic metal oxides, are contemplated by the present invention.
• Other magnetic pigments, including magnetic iron sulfides, such as pyrrhotite, and magnetic nickel flakes and other pigments are also contemplated to by useful.
• Magnetic particle (e.g., iron oxide) coated nylon fibers have a preferred length in the range of approximately 0.75mm to approximately 20mm, more preferably from approximately 0.5mm to approximately 10mm and most preferably from approximately 0.1mm to approximately 5mm, with a diameter in the range of approximately 1-30D (denier), and preferably comparable to human hair or eyelashes.
• iron oxide coated nylon fibers have a preferred length in the range of approximately 0.75mm to approximately 20mm, more preferably from approximately 0.5mm to approximately 10mm and most preferably from approximately 0.1mm to approximately 5mm, with a diameter in the range of approximately 1-30D (denier), and preferably comparable to human hair or eyelashes.
• Magnetic (e.g., iron oxide) fibers as described may be over coated with brown, grey, or blonde matching shades to keep the magnetic strength while providing a more versatile shade palette.
• the magnetic particle (e.g., iron oxide) coated fiber may comprise other polymers as a core, such as polyethylene (PE), polyethylene terephthalate (PET), cellulose, polypropylene (PP), acrylate, and polyurethane (PUR).
• the magnetic particle (e.g., iron oxide) coated fibers may also be provided without core and comprise, for example, hydrous iron oxides such as those described in U.S.
• Patent 6,599,493 which is incorporated by reference fully herein.
• the keratin-like fibers are magnetic responsive fibers and are advantageously nylon fibers, though other fibers may be used without detracting from the invention.
• Exemplary magnetic responsive nylon fibers contemplated by the embodiments disclosed herein may be obtained from KOBO Products, Inc. (South Plainfield, New Jersey) and have the following trade names: NFBL-10D-2R; NFBR-10D-2R; NFBR- 10D-2T, although the invention is not limited to the aforementioned fibers only.
• the aforementioned fibers are colored nylon fibers and are commercially available in length 2 mm and a thickness of 10 Denier.
• Nylon fibers obtainable from KOBO products include "Nylon Cut Fiber 6D” which includes nylon-66 plus titanium dioxide and silica is available having a length of 2 mm and a thickness of 6 Denier; "Nylon-66 Fiber 20D” which includes nylon-66 and titanium dioxide and has a fiber length of 2mm and a thickness of 20 Denier; and “Nylon-66 Fiber 3D” which includes nylon-66 and titanium dioxide and has a fiber length of 2mm and a thickness of 3 Denier.
• KOBO's KNY-1.7 fiber includes nylon-6 plus silica and titanium dioxide and has a fiber length of 1mm and a thickness of 15 Denier.
• the invention further encompasses cellulose fibers, polypropylene fibers and polyethylene terephthalate fibers.
• fibers may be made from cellulose.
• Cellulose is a natural polymer and the fibers may be fabricated to vary in length from 20 ⁇ to 750 ⁇ m.
• Cellulose fibers are hydrophilic and disperse easily in the initial water phase of an emulsion.
• Cellulose Fibers obtainable from KOBO Products Inc. are sold under the tradename "Cell-U-Lash" and are available in lengths ranging from 20 ⁇ to 750 ⁇ .
• Polypropylene fibers available from KOBO Products Inc. are sold under the tradename "PP Fiber” and incorporate silica.
• the propylene fibers available from KOBO Products are available in two lengths and thicknesses.
• PP Fiber 6D05 is provided in length 0.5mm and 5.6 Denier thickness and PP Fiber 6D2 is available in length 2 mm and 5.6 Denier thickness.
• Prismatic Powder BB35C30 is available in particle 20 ⁇ m x 30 ⁇ m
• Prismatic Powder BB35C150 is available in particle size 20 ⁇ m x 150 ⁇ m
• the invention also contemplates other pigments commonly utilized in the cosmetic art such as, but not limited to, colored pigments including organic and/or inorganic pigments, such as inorganic red pigments such as iron oxide, iron hydroxide, and iron titanate, inorganic brown pigments such as ⁇ -iron oxide, inorganic yellow pigments such as iron oxide yellow and loess, inorganic black pigments such as iron oxide black and carbon black, inorganic violet pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide, and cobalt titanate, in organic blue pigments such as Prussian blue
• a method for preparing a product for creating or enhancing the appearance of keratin fibers comprises (a) applying an external magnetic field to an aqueous mixture of one or more water-dissolvable polymers and plurality of magnetic responsive fibers so as to orient the fibers in a non- random manner; and (b) removing the aqueous solvent to form a solid or semi-solid film.
• the method for preparing the product may also include additional steps of pre- coating the magnetic responsive fibers with a magnetic particle (e.g., iron oxide) as described above and additionally with other pigments to impart further coloration to the fibers.
• a magnetic particle e.g., iron oxide
• the method for preparing the dissolvable film matrix product for creating or enhancing the appearance of keratin fibers includes the steps of mixing one or more water dissolvable polymers with water; adding the magnetic responsive fibers to the polymer mixture; pouring the resulting mixture into a dish, preferably a flat one and applying a magnetic field to the mixture to orient the fibers in a non-random manner.
• the mixture is then heated at approximately 60 C for approximately 6 hours until the mixture becomes a film. After drying, the film can then be cut into desired shapes for application to an individual's eyebrows or other areas where the fibers are to be applied.
• the magnetic field utilized in accordance with the present invention may be any conventional magnetic field as known in the art.
• a magnet in the preparation of the dissolvable polymer film matrix, a magnet may be positioned in proximity to the mixture such that the magnet exerts its forces upon the magnetic responsive fibers in the dissolvable polymer film matrix.
• the magnetic force causes the magnetic responsive fibers to be oriented along a plane so that when the matrix is applied to an individual, the fibers simulate the appearance of the individual's natural hair.
• the magnetic field may be applied using a magnetic stir plate or magnetic mixer.
• Magnetic stirrers often include a hot plate or some other means for heating the liquid, which may be used to facilitate removal of solvent.
• the invention is not limited to the use of a magnetic stir plate and the magnetic field may be applied using other methods and apparatuses know to those of skill in the art.
• the magnetic field applied is measured in "Gauss.”
• the magnetic field applied in accordance with the present invention is typically within the range of 1-250 Gauss, although the invention is not limited in this respect and stronger or weaker magnetic fields are contemplated and may be applied without detracting for the present invention.
• the polymer matrix film optionally may include one or more of the following additional ingredients to modify aesthetics and/or adhesion strength: anesthetics, anti- allergenics, antifungals, antimicrobials, anti-inflammatories, antiseptics, chelating agents, colorants, depigmenting agents, emollients, fragrances, humectants, lubricants, moisturizers, pharmaceutical agents, preservatives, skin protectants, skin penetration enhancers, stabilizers, surfactants, and vitamins apart from the colored fibers to provide additional color and/or visual effects.
• anesthetics anesthetics, anti- allergenics, antifungals, antimicrobials, anti-inflammatories, antiseptics, chelating agents, colorants, depigmenting agents, emollients, fragrances, humectants, lubricants, moisturizers, pharmaceutical agents, preservatives, skin protectants, skin penetration enhancers, stabilizers, surfactants, and vitamins
• the polymer matrix film may also optionally include bioactive compounds that promote and/or restore hair growth such as, for example, Allergan's Latisse® product (bimatoprost) for treating inadequate or lack of eyelashes.
• bioactive compounds contemplated that promote and/or restore hair growth include minoxidil (Rogaine®), finasteride (Propecia®), dutasteride, ketoconazole, saw palmetto extract, various retinoids, lecithin, and the like.
• keratin conditioning agents Any keratin conditioning agent known to the art as cosmetically acceptable, may be employed, for example: algae extracts (for example, BIOSTRUCTURER and BIOENERGIZER from Secma), wheat amino acids, wheat protein, hydrolyzed vegetable protein, hydrolyzed vegetable protein derivatives (for example hydrolyzed vegetable protein propylene glycol-propyl silanetriol (KERAVIS from Croda Chemicals)), keratin amino acids, serum protein, yeast extract, hydrolyzed mucopolysaccharides (for example, OLIGOQUAT M from Arch Chemicals), hydrolyzed animal protein, chitosan, phytantriol, hydrolyzed corn protein, hydrolyzed soy protein, hydrolyzed silk, silk amino acids, and mixtures thereof.
• algae extracts for example, BIOSTRUCTURER and BIOENERGIZER from Secma
• wheat amino acids for example, wheat protein, hydrolyzed vegetable protein, hydrolyzed vegetable protein derivatives (for example hydrolyzed vegetable protein
• antioxidants such as, rosemary extract, tocopherol, a derivative of tocopherol including a tocotriene, carotene, a carotenoid, a phenolic antioxidant including a phenolic acid, a bioflavonoid, a plant extract, curcumin, tetrahydrocurcumin, camphorol, quercetine, epigenine, and any mixtures thereof.
• keratolytic agents such as, salicylic acid, resorcinol, peroxide of an organic acid, and any mixtures thereof;
• Filler powders are contemplated that can be physically or chemically coated with a moisturizing agent and used in the compositions of this invention.
• Such filler powders include, but are not limited to, mineral silicate, starch, kaolin, nylon, zinc oxide, titanium oxide, precipitated calcium carbonate, synthetic polymer powder, as well as other fillers known in the art, or any combinations thereof.
• the fillers may have hydrophobic or hydrophilic surfaces.
• the most preferred fillers are mineral silicates, such as mica and talc.
• the invention provides methods for applying the polymer matrix to an individual's face or head.
• the method provides that steps of: (a) wetting the surface of an area on an individual's face or head to which the film will be applied; (b) positioning the film on the wetted surface; and (c) allowing the film to dissolve; wherein said film includes a plurality of non-randomly oriented fibers that are adhered to said individual's face or head by a water-dissolvable polymer.
• the matrix film applied to an individual's eyebrows is typically pre-cut in a shape that complements the shape of the eyebrows upon which the film will be applied.
• the matrix of water dissolvable polymers may be coated or disposed on to a backing or carrier sheet or substrate to provide structural support, to facilitate handling, storage, etc.
• Backing or carrier sheets are well known in the art and may include, without limitation, sheet stock, wax paper, cellophane, Teflon®, non-absorbent plastics such as lexan or polystyrene, and the like.
• the matrix may include a peelable, top or cover sheet upon the matrix film. This will protect the film during storage and transport.
• the top or cover sheet can be easily peeled from the matrix prior to application of the matrix to the wetted surface of the individual's face as described above.
• a slurry is typically prepared that comprises the water-dissolvable polymers and fibers.
• back injection equipment may be used to scale-up and commercialize production and manufacture.
• the slurry is typically pumped into a plastic form from the back into a pan which is then exposed to a magnetic field, the film would be partially dried with an absorbent paper wicking off the water and the remaining film is dried in an oven.
• An absorbent paper placed on top of the fiber film could serve as the substrate for the film to be laid down on the skin once the fibers are orientated. In the oven the fiber containing film could be peeled off the absorbent paper to provide a dissolvable product to deliver the fibers.
• Example 1 Cosmetic formulation for enhancing the appearance of hair, particularly eyebrows or hair of the scalp, are provided in Tables 1-6.
• the magnetic fiber is a nylon fiber coated with magnetic iron oxide particles.
• the formulations provided in Tables 1-6 may be prepared by the method of Example 2.
• One or more water-dissolvable polymers are mixed with water
• magnetic responsive fibers are added into the polymer mixture
• the mixture is subjected to an external magnetic field to orient the fibers
• the mixture is heated in the flat dish at approximately 60 °C for approximately six hours until the mixture becomes a film;
• the film is cut into an eyebrow-like shape (e.g., arcuate) for application to a wearer's eyebrows (or other suitable shapes depending upon where the film will be applied).
• an eyebrow-like shape e.g., arcuate
• Example 3 Method for applying the eyebrow lay down film product
• the film of magnetically-oriented fibers is then positioned on the treated (i.e., wetted) surface to enhance the attachment and adhesion of the film to the surface;
• the fibers incorporated in the film are adhered in place on said individual's eyebrows, beard or head.

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• Health & Medical Sciences (AREA)
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• 2010
  • 2010-06-22 US US12/820,696 patent/US9192550B2/en active Active
• 2011
  • 2011-06-09 CA CA2791341A patent/CA2791341A1/en not_active Abandoned
  • 2011-06-09 CN CN2011800163817A patent/CN102869333A/zh active Pending
  • 2011-06-09 JP JP2013516594A patent/JP2013531144A/ja active Pending
  • 2011-06-09 WO PCT/US2011/039740 patent/WO2011162967A1/en active Application Filing
  • 2011-06-09 EP EP11798606.7A patent/EP2585026A1/en not_active Withdrawn

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