EP2562272A9 - Methode zur Herstellung eines Stahlproduktes mit exzellenten mechanischen Eigenschaften, das Stahlprodukt gerfertigt nach dieser Methode sowie sein Gebrauch - Google Patents

Methode zur Herstellung eines Stahlproduktes mit exzellenten mechanischen Eigenschaften, das Stahlprodukt gerfertigt nach dieser Methode sowie sein Gebrauch Download PDF

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Publication number
EP2562272A9
EP2562272A9 EP12181887.6A EP12181887A EP2562272A9 EP 2562272 A9 EP2562272 A9 EP 2562272A9 EP 12181887 A EP12181887 A EP 12181887A EP 2562272 A9 EP2562272 A9 EP 2562272A9
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Prior art keywords
steel
steel product
rate
product
cooling
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English (en)
French (fr)
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EP2562272A2 (de
EP2562272B1 (de
EP2562272A3 (de
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Tuomo Saarinen
Pasi Peura
Petteri Steen
Juha Rajala
Jussi Minkkinen
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Rautaruukki Oyj
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Rautaruukki Oyj
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00—Modifying the physical properties of iron or steel by deformation
    • C21D7/02—Modifying the physical properties of iron or steel by deformation by cold working
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/10—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/34—Methods of heating
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/84—Controlled slow cooling
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    • C21D6/00—Heat treatment of ferrous alloys
    • C—CHEMISTRY; METALLURGY
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    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
    • C—CHEMISTRY; METALLURGY
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    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
    • C—CHEMISTRY; METALLURGY
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • C—CHEMISTRY; METALLURGY
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
    • C—CHEMISTRY; METALLURGY
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    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the invention relates to a method for producing a steel product having excellent mechanical properties and to a steel product produced by the method and used, in particular, for manufacturing components, more precisely steel components, for automotive industry, inter alia.
  • the invention relates to the use of a strain hardened steel pipe and to the manufacture of said component.
  • the object of the present invention is to provide such an improvement in the known heat treatment and/or forming processes that gives a steel product better mechanical properties than before, or enables simplification of the process over the known techniques.
  • a strain hardened steel pipe of independent claim 16 which is characterized by using the strain hardened steel pipe in an extremely rapid heat treatment method which comprises:
  • the invention is based on the idea that in the micro structure of the steel pipe to be heated very rapidly there is provided a strain hardened structure that is not soft annealed prior to the rapid heating.
  • the strain hardened structure may refer to a structure that is not recrystallized after moulding, i.e. it may refer to a non-recrystallized structure.
  • the strain hardened structure such as full hard structure, is provided by cold forming, such as cold rolling a steel strip, for instance.
  • the invention is characterized in that the rapid heating is followed by immediate cooling.
  • the micro structure provided in the steel product comprises at least 30 percent martensite and/or bainite by volume.
  • the steel is heated in an accelerated manner after obtaining a strain hardened structure and hardened immediately after the rapid heating.
  • Hardening may also be performed by air cooling, in case the composition of the steel is suitable therefor.
  • cooling or hardening is provided in a mould, in which moulding into a component is also carried out.
  • the method of the invention provides an extremely fine micro structure in steel, and as a consequence the steel will have progressive mechanical properties.
  • the invention has significant advantages regarding as well a production chain as mechanical properties of the product.
  • the heat treatment may be implemented very quickly, and consequently, when needed, it may be applied on some continuously-operating production lines, arranged in immediate connection with the forming of a steel product.
  • the duration of the heat treatment step of the method may be less than one minute, even less than 30 seconds.
  • Particularly shaped products such as steel pipes are produced by the method.
  • Steel components may also be provided by the method.
  • the method allows higher R m *A values to be provided as compared to steel products manufactured by a conventional slow method. Further, the production of a steel product does not require annealing after cold forming, and therefore this step need not restrict the throughput of production.
  • the method it is possible to provide strong and formable steel products, such as steel pipes, whereby the use of a ready-tempered, yet well cold-mouldable, steel pipe is cost effective in the manufacture of cold-mouldable components, because the final component made of steel pipe need not be hardened separately as pipe material is already hardened, at least partly.
  • Figure 1 shows the main steps of the method according to the invention, wherein in the first step a steel strip is cold formed 1, such as cold rolled, in such a manner that a strain hardened structure will be formed in the steel of the steel strip.
  • Cold forming 1 is performed on a suitable steel preform, such as a hot-rolled or moulded steel strip/plate/shaped product. In cold forming 1 the steel typically becomes thinner, at least partly.
  • the effectiveness of cold forming may be assessed roughly, for instance, through reduction, which refers to a change in the thickness of steel after cold forming in relation to the original thickness.
  • a strain hardened structure refers to a steel structure whose reduction used in cold forming exceeds 15%. Preferably the reduction used in cold forming is more than 30%, most preferably more than 40%. According to an embodiment, the strain hardened structure refers to a full hard structure, in which the reduction used is at least 50%, such as 60%.
  • the cold forming means that the steel is cold rolled to a thin sheet having a thickness of 0.4 to 5 mm, for instance.
  • cold rolling is performed to a thickness of 0.8 to 3 mm.
  • the steel having strain hardened structure is cold formed into a shaped product 2.
  • the cold forming step 2 of the shaped product may comprise cold forming of a pipe and longitudinal seam welding to obtain a closed pipe profile.
  • the degree of strain hardening of the steel further increases.
  • a highly strain hardened steel pipe which is still unusable as such.
  • the shaped steel product, such as steel pipe, having a strain hardened structure is heated 2 very quickly, preferably at least at a rate of HR ⁇ 100 °C/s to a temperature of A c3 ⁇ 100 °C.
  • the grain structure of austenite is very fine due to heating 3.
  • Figure 3 further illustrates steps "rapid heating 3" and "cooling 4" of the method according to the invention.
  • the rapid heating 3 is preferably carried out at least at a mean heating rate of 100 °C/s. In this manner it is possible to make sure that during heating the grain size will not have time to grow excessively.
  • high heating rates require a considerable amount of energy and they may deteriorate the uniform quality of mechanical properties of a steel product.
  • heating is implemented as induction heating, which may be readily performed on closed steel pipes, for instance. Other heating methods of high heating rate are also possible.
  • the abbreviation HR stands for heating rate.
  • Rapid heating 3 of the steel having strain hardened structure is carried out to a temperature of A c3 ⁇ 100 °C.
  • heating is carried out rapidly 3 above the temperature A c3 .
  • heating 3 starts substantially at room temperature.
  • cooling 4 is started in at least 10 seconds from the termination of heating 3, most preferably the cooling is started in at least 2 seconds from the termination of heating. In other words, the time spent in the austenite range, or in proximity thereto, is as short as possible.
  • a rapidly heated steel pipe is hot-formed, such as hot-stamped, immediately after the rapid heating 3, whereby there will be no longer need to form the cooled steel product.
  • After hot-stamping it is possible to perform cooling in a mould, preferably tempering in a mould.
  • the embodiment may provide an improvement in the mechanical properties of a hot-stamped steel component, when the steel pipe to be heated and tempered is made of strain hardened steel strip.
  • the steel pipe of the invention may also be more robust to some hot-stamping process parameters because of the strongly strain hardened initial structure.
  • the density of occurrence of small austenite grains formed in the rapi heating 3 is high, which results in a very fine micro structure in a steel product of the invention having excellent mechanical properties.
  • the rapid heating 3 the austenite grain size will have no time to grow large, whereby, as a result of heating 3, the micro structure comprises very densely formed, small-sized austenite grains. The end result, after cooling, will be a stronger steel product the tensile strain of which is still substantially at the same or higher level than that of a steel product in rapid heating of which soft annealed steel is employed.
  • the A c3 temperature is higher at high heating rates in comparison to the A c3 temperature at low heating rates.
  • the A c3 temperature is understood to be a possibly elevated A c3 temperature as a consequence of a higher heating rate.
  • Cooling 5 from the austenitic range, or from the vicinity thereof, may be implemented in a variety of ways so as to obtain a desired end result. It is essential, however, that the cooling 5 is provided in a manner known per se such that the micro structure formed in the steel structure comprises 30% by volume martensite and/or bainite. In other words, in cooling 4, the steel is tempered in a manner fully known per se. The rest of the micro structure may consist of ferrite and possibly residual austenite.
  • the desired micro structure may be obtained in a manner known per se, for instance, such that cooling 4 is performed at a mean cooling rate of at least 5 °C/s. Further, in a manner known per se there is used steel the hardenability of which is sufficient to provide 30 % by volume martensite and/or bainite in the cooling.
  • the hardenability of steel may be determined in various ways, such as by using a hardenability index DI, which is based on a modification of ASTM standard A255-89.
  • the composition is expressed in percentages by weight (%) and DI is millimetres (mm).
  • the hardenability index DI of the steel product is at least 3mm.
  • the hardenability index DI of the steel product is at least 15mm.
  • Cooling may be implemented in a manner known per se, for instance as water vapour or water cooling, depending particularly on the steel composition used and the thickness of the steel.
  • An element providing cooling may also be a mould.
  • the cooling 4 is provided in such a manner that the formed micro structure comprises at least 70 % by volume martensite and/or bainite, the rest being ferrite and possibly residual austenite.
  • the cooling is implemented as water vapour or water cooling or as cooling in a mould in such a manner that a mean cooling rate is at least 20 °C/s, preferably at least 35 °C/s.
  • the final temperature of accelerated cooling is preferably below a bainite start temperature (B s temperature), most preferably below a martensite start temperature (M s temperature), i.e. the temperature at which a bainite transformation, and correspondingly, a martensite transformation start. In this manner it is made sure that the micro structure of the steel will be as desired.
  • the steel product may be cut to desired dimensions, when the steel product is a steel pipe.
  • the invention also relates to a steel product produced by the method and described in the following.
  • the steel product obtained by the method possesses high strength and ductility.
  • the steel product has excellent mechanical properties.
  • the steel product is also well formable, and thanks to low alloyage, its weldability is good.
  • the product of breaking strength and breaking elongation is at least 12000, i.e. R m * A ⁇ 12000.
  • the breaking strength of the steel product obtained by the method is at least 800 MPa.
  • An advantage of the method is also that by using the method, with the same steel composition, it is possible to provide 1) high-strength steel of excellent ductility (Rm ⁇ 1500 MPa and A ⁇ 10%) or 2) strong and particularly ductile steel (Rm ⁇ 800 MPa and A ⁇ 18%).
  • the products to be produced by the method may be roughly divided into two categories:
  • Steels in this category possess very high breaking strength and well retained breaking elongation A as follows: R m ⁇ 1500 MPa and A ⁇ 10%. These steels are thus very strong, yet the ductility is of good level thanks to the method of the invention. This is indicated by exemplary steels 1, 4, 5, 10 and 11 of Table 2.
  • the steel product produced by the method advantageously also possesses relatively high uniform elongation Ag ⁇ 3%, despite the substantially hardened micro structure and high breaking strength of the steel produced by the method.
  • Steels in this category possess relatively high breaking strength (Rm ⁇ 800 MPa) and very high elongation (A ⁇ 18%, preferably up to A ⁇ 18% and Ag>8%). These steels are thus relatively strong and the elongation has become very high, thanks to the method of the invention.
  • the steel product produced by the method contains iron Fe and unavoidable residuals and comprises in percentages by weight C: 0.04-0.32 %, Si: 0.00-2.5% Mn: 0.2-2.5% Al: 0.00-2.5% such that the hardenability index DI of the steel product is at least 3mm, preferably at least 15mm.
  • the steel product produced by the method contains iron Fe and unavoidable residuals and comprises in percentages by weight C: 0.04-0.32 %, Si: 0.00-2.5% Mn: 0.2-2.5% Al: 0.00-0.5% Ti: ⁇ 0.15% Nb: ⁇ 0.1 % V: ⁇ 0.17% Nb+Ti+V ⁇ 0.22 % such that the hardenability index DI of the steel product is at least 3mm, preferably at least 15mm.
  • the steel product produced by the method contains iron Fe and unavoidable residuals and comprises in percentages by weight C: 0.05-0.25 % Si: 0 - 2.5 % Mn: 0.8 - 3.0 % Al: 0 - 2.5 % Mo: ⁇ 1.5 %, preferably 0.1-0.8% Cr: ⁇ 1.5 %, preferably 0.2 - 1.5% Cu ⁇ 1.00 % Ti: ⁇ 0.15 % Nb: ⁇ 0.09 % V: ⁇ 0.17 % preferably 0.015 % ⁇ Ti+Nb+V ⁇ 0.22 % such that the hardenability index DI of the steel product is at least 3mm, preferably at least 15mm.
  • the steel product produced by the method contains iron Fe and unavoidable residuals and comprises in percentages by weight C: 0.10-0.40 %, Si: 0 - 2.5 % Mn: 0.2 - 3.0 % Al: 0 - 2.5 % Cu 0 - 1.0% B: 0.0005 - 0.009 % Cr 0-1.5% Mo 0 - 1.5 % Ti: ⁇ 0.15 % Nb: ⁇ 0.09 % V: ⁇ 0.17 % such that the hardenability index DI of the steel product is at least 3mm, preferably at least 15mm.
  • Prior austenite grain size formed in the heating 3 of the steel product produced by the method of the invention is very small, preferably less than 10 micrometres and most preferably less than 3 micrometres. Further the grain size of ferrite and/or bainite possibly formed in the steel product in the cooling 4 is also very small, preferably less than 5 micrometres and most preferably less than 3 micrometres. Also martensite formed in hardening will be fine and tough thanks to the invention.
  • Material thickness in the steel product may be 0.4 to 5mm, preferably 1 to 3mm.
  • the steel product may be a cold-formed shaped product.
  • Most preferably the steel product is a steel pipe used, for instance, for manufacture of components in automotive industry.
  • the steel product may thus be a hollow section, such as a circular or rectangular steel pipe.
  • the steel product may also be a stamped steel component.
  • Table 1 shows the mechanical properties and process parameters of steel samples 10a and 8a produced in laboratory conditions by the method of the invention. Additionally, Table 1 shows as reference the mechanical properties and process parameters of steel samples ref8a and ref10a whose heating rate is low, 4 °C/s, i.e. the heating rate is clearly lower than the heating rate used in the method of the invention. Further, Table 1 shows as reference the mechanical properties of a test sample ref that is not heat treated in accordance with the method of the invention. For the sake of clarity, the references are depicted in grey in Table 1. Correspondingly, Figure 4 shows the corresponding stress-strain curves 10a, 8a, ref8a, ref10a and ref. All the results in the table and the graph concern strain hardened steel CP800 the composition of which is shown in Table 3. The results shown in Table 1 and Figure 4 are not comparable with those in Table 2, but they are mutually comparable.
  • yield strength and breaking strength (R p0.2 and R m ) of the air-cooled steel sample 8a increased significantly thanks to the high heating rate as compared to the steel sample ref8a produced at a low heating rate.
  • the uniform elongation A g surprisingly remained the same and the breaking elongation A weakened only slightly.
  • Table 2 presents the mechanical properties and dimensions of steel products obtained in full-scale tests 1 - 15 as well as process parameters used.
  • the table gives as reference values the tests 3, 6, 9, 12 and 15, in the heat treatment of which there was not used steel having strain hardened structure, i.e. after cold forming the steel was soft annealed in a known manner.
  • X in column FH indicates that in said test there was used steel that is not soft annealed.
  • Table 2 presents as reference the tests 16 to 21, in which there was used a heating rate significantly lower than that in the method of the invention. For the sake of clarity, the references are depicted in grey in Table 2.
  • the pipe diameter (D) was 48 - 49mm and the thickness of material (T) 1.7 - 2.1 mm.
  • the steel to be heated rapidly comprises a strongly strain hardened structure.
  • Heating rates 300, 500 and 1000 °C/s were used in the tests of the method according to the invention in Table 2. It is seen in the table that the objects of the invention are also achieved at the heating rate of 300 °C/s. A lower heating rate is advantageous because of a lower power requirement in the apparatus, and consequently it is advisable to use a lower heating rate when sufficient. In many cases the heating rate of at least 100 °C/s will suffice to achieve the objects of the invention.
  • heating rates of at least 160 °C/s are used, whereby it is made sure that the austenite grain size formed in the heating does not grow excessively and excellent mechanical properties will be achieved.
  • Table 1 presents results which show that the invention works also at heating rates of 192 and 197 °C/s.
  • heating rates used in hot stamping may be lower, even as low as 15 to 100 °C/s, because the strain hardened steel pipe in itself improves the component's mechanical properties to be achieved in said hot stamping process, or it is more robust to use in said process than the prior art solutions. Further, a higher heating rate may provide advantages in this process as well.
  • the heating and cooling rates are mean cooling rates.
  • the method uses heating rates, such as 160 to 500 °C/s, because generation of a lower heating rate requires less energy and may contribute to controlling the uniformity of results.
  • the heating temperature used is indicated in column HT.
  • An appropriate heating temperature depends on the composition of steel, yet it is selected such that the heating temperature is A c3 ⁇ 100 °C.
  • the heating is performed to a temperature slightly above A c3 .
  • Said temperature refers to a temperature at which the steel austenitizes completely. It is important, however, that due to heating the steel is not maintained excessively long above the temperature A c3 or in the vicinity thereof. It is preferable to start cooling 4 in at least 10 seconds from the termination of heating 3, most preferably in at least 2 seconds from the termination of heating.
  • Table 3 shows some steel compositions to which the method of the invention is applicable.
  • Table 3 Contents of test steels in percentages by weight C Si Mn Al Nb V Cu Cr Ni Mo Ti B steel % % % % % % % % % % % DP800 0,13 0,20 1,46 0,05 0,02 0,01 0,01 0,05 0,05 0,02 0,002 0,000 355 0,07 0,15 1,43 0,04 0,02 0,01 0,02 0,03 0,04 0,00 0,013 0,000 CP 800 full hard 0,17 0,18 1,74 0,03 0,01 0,01 0,04 0,33 0,06 0,15 0,002 0,000 HSF420 0,06 0,20 0,80 0,03 0,01 0,01 0,28 0,04 0,04 0,00 0,068 0,000 CP800 0,16 0,21 1,74 0,04 0,00 0,01 0,02 0,31 0,07 0,15 0,002 0,000 B24 0,24 0,26 1,21 0,04 0,00 0,01 0,03 0,32 0,05 0,01 0,040 0,002

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  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
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EP12181887.6A 2011-08-26 2012-08-27 Methode zur Herstellung eines Stahlproduktes oder einer Stahlkomponente mit exzellenten mechanischen Eigenschaften, das Stahlprodukt gerfertigt nach dieser Methode sowie der Gebrauch als Stahlrohr gefertigt aus kaltgehärtetem Stahl Active EP2562272B1 (de)

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PL12181887T PL2562272T3 (pl) 2011-08-26 2012-08-27 Sposób wytwarzania produktu stalowego lub elementu stalowego o doskonałych właściwościach mechanicznych, produktu stalowego wytworzonego tym sposobem i zastosowania rury stalowej wykonanej ze stali umacnianej przez zgniot

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CN103266272A (zh) * 2013-04-16 2013-08-28 安徽省宁国市宁沪钢球有限公司 一种球磨机筒体衬板的制备方法
US9850553B2 (en) 2014-07-22 2017-12-26 Roll Forming Corporation System and method for producing a hardened and tempered structural member
CN104451407B (zh) * 2014-11-25 2016-08-24 东北大学 一种低碳热轧超高强高韧钢及其制备方法
CN105483531A (zh) * 2015-12-04 2016-04-13 重庆哈工易成形钢铁科技有限公司 用于冲压成形的钢材及其成形构件与热处理方法
CN105714189B (zh) * 2016-04-28 2017-09-15 北京科技大学 一种铌、钒复合添加的具有高强塑积汽车用钢及制造方法
JP2020059880A (ja) * 2018-10-09 2020-04-16 日本製鉄株式会社 鋼材およびその製造方法
JP7218533B2 (ja) * 2018-10-09 2023-02-07 日本製鉄株式会社 鋼材およびその製造方法
US11739866B2 (en) * 2018-10-12 2023-08-29 Nippon Steel Corporation Electric resistance welded steel pipe for torsion beam
CN110273054A (zh) * 2019-06-28 2019-09-24 机械科学研究总院集团有限公司 一种热处理成形工艺

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US20060169368A1 (en) * 2004-10-05 2006-08-03 Tenaris Conncections A.G. (A Liechtenstein Corporation) Low carbon alloy steel tube having ultra high strength and excellent toughness at low temperature and method of manufacturing the same
JP5194878B2 (ja) * 2007-04-13 2013-05-08 Ｊｆｅスチール株式会社 加工性および溶接性に優れる高強度溶融亜鉛めっき鋼板およびその製造方法

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ES2881667T3 (es) 2021-11-30
FI20115832A0 (fi) 2011-08-26
FI20115832L (fi) 2013-02-27

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