EP2553132A1 - Steel product with improved weathering characteristics in saline environment - Google Patents
Steel product with improved weathering characteristics in saline environmentInfo
- Publication number
- EP2553132A1 EP2553132A1 EP10712049A EP10712049A EP2553132A1 EP 2553132 A1 EP2553132 A1 EP 2553132A1 EP 10712049 A EP10712049 A EP 10712049A EP 10712049 A EP10712049 A EP 10712049A EP 2553132 A1 EP2553132 A1 EP 2553132A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel product
- steel
- weathering
- product
- niobium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 34
- 239000010959 steel Substances 0.000 title claims abstract description 34
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title description 12
- 239000011780 sodium chloride Substances 0.000 title description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 14
- 229910052802 copper Inorganic materials 0.000 claims abstract description 13
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 12
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 12
- 239000010955 niobium Substances 0.000 claims abstract description 12
- 239000010936 titanium Substances 0.000 claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000011572 manganese Substances 0.000 claims abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 5
- 239000005864 Sulphur Substances 0.000 claims abstract description 4
- 239000004411 aluminium Substances 0.000 claims abstract description 4
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010703 silicon Substances 0.000 claims abstract description 4
- 229910052718 tin Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 abstract description 13
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 6
- 229910000870 Weathering steel Inorganic materials 0.000 abstract description 3
- 239000002436 steel type Substances 0.000 abstract description 3
- 230000001747 exhibiting effect Effects 0.000 abstract description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052598 goethite Inorganic materials 0.000 description 9
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 9
- 229910052804 chromium Inorganic materials 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 4
- -1 Fe2+ ions Chemical class 0.000 description 2
- 229910000074 antimony hydride Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- OUULRIDHGPHMNQ-UHFFFAOYSA-N stibane Chemical compound [SbH3] OUULRIDHGPHMNQ-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910002588 FeOOH Inorganic materials 0.000 description 1
- 238000004813 Moessbauer spectroscopy Methods 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000005290 antiferromagnetic effect Effects 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
Definitions
- the present invention is related to steel types and products made thereof, which exhibit an increase in corrosion resistance when exposed to a chlorine-rich environment. These steels are known as weathering steels. State of the art
- the weathering capability in saline environment is mainly obtained by the presence of Sb and/or Sn, which stabilize the amount of Fe2+ ions when the steel is in a wet and saline environment, by reacting with Fe3+ ions, produced by oxidation of Fe2+.
- Sn and/or Sb is disadvantageous for various reasons :
- the present invention aims to provide a weathering steel with a Ni-content in the same order of magnitude as in traditional weathering steels, and with an increased corrosion resistance in marine or seaside conditions, as well as with excellent mechanical properties .
- the invention is related to a steel product as disclosed in the appended claims.
- the invention is in particular related to a steel product as disclosed in the main independent claim, suitable for use in outdoor environments, in particular in saline conditions.
- the steel product of the invention may be any type of construction element such as a steel sheet or beam.
- the invention is related to a steel composition characterized by the following contents (in wt%) :
- the balance being Fe and accidental impurities, and wherein the sum of the Al and Si levels is higher than about 0.85wt% .
- the steel product according to the invention comprises no Sn and no Sb .
- the present invention is related to a steel product of the weathering steel type, i.e. a product exhibiting increased corrosion resistance after having been exposed to the outside environment for a given time.
- the steel product is defined by a composition consisting of (in wt%) :
- the amounts of Cu, Ti, Cr, Ni and Nb are as follows (in wt%) :
- This embodiment combines good weathering behaviour in saline conditions with excellent mechanical properties, due to the minimum amounts of the abovenamed elements (Cu, Ti, Cr, Ni, Nb) .
- the present invention reveals that the inventive steel compositions favour the formation of fine grained goethite (a-FeOOH) in the corrosion layer forming on the surface of a steel product having these compositions, due to the specific combined Al and Si content.
- a-FeOOH fine grained goethite
- x fine grained goethite' is meant goethite with grain sizes from about 8nm to about 15nm.
- the formation of such fine grained goethite is beneficial for the stability of the oxide layer in saline conditions.
- inventive compositions do not necessarily include an addition of significant amounts of the traditional elements regarded as beneficial for weathering resistance in saline conditions, such as Ni .
- inventive compositions do not comprise Sn and Sb above an accidental impurity level.
- the steel product of the invention comprises no Sb or Sn.
- Elements such as Nb, Ti, Cu, Cr may be added for improving the mechanical properties of the steel, but are not required for ensuring the weathering behaviour in saline conditions .
- the invention is related to any type of steel product having the composition as claimed, e.g. steel sheets or beams, obtained by any standard steel-making process, e.g. hot-rolled or cold-rolled sheets or beams.
- Table 1 shows the compositions of 3 test samples SI to S3 having Al and Si contents according to the invention, as well as 2 comparative samples CI and C2 having Al and Si contents falling outside the claimed ranges and/or wherein the combined Al and Si content is less than 0.85wt%.
- test samples have been obtained by standard steel processing methods, involving at least a hot rolling step, possibly followed by a cold rolling step.
- the samples were subjected to a dip-dry test during 60 days, using a 0.05M NaCl solution, in order to test weatherability behaviour in saline conditions.
- oxide layers were formed on the samples.
- the composition of these oxide layers was investigated by Mossbauer spectroscopy, used in particular to measure the relative area of superparamagnetic goethite in the oxide layer.
- Superparamagnetic goethite has a particle size between 8 and 15nm, as opposed to antiferromagnetic goethite, having particle sizes above 15nm.
- Table 2 clearly shows that the combined Al and Si contents according to the present invention give rise to a considerable increase in the relative area of fine-grained goethite in the oxide layer.
- Table 1 example compositions (in wt%)
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10712049T PL2553132T3 (en) | 2010-03-29 | 2010-03-29 | Steel product with improved weathering characteristics in saline environment |
HRP20150826TT HRP20150826T1 (en) | 2010-03-29 | 2015-07-30 | Steel product with improved weathering characteristics in saline environment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2010/054086 WO2011120550A1 (en) | 2010-03-29 | 2010-03-29 | Steel product with improved weathering characteristics in saline environment |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2553132A1 true EP2553132A1 (en) | 2013-02-06 |
EP2553132B1 EP2553132B1 (en) | 2015-05-06 |
Family
ID=43302026
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20100712049 Active EP2553132B1 (en) | 2010-03-29 | 2010-03-29 | Steel product with improved weathering characteristics in saline environment |
Country Status (12)
Country | Link |
---|---|
US (1) | US20130078135A1 (en) |
EP (1) | EP2553132B1 (en) |
CN (1) | CN102884214B (en) |
BR (1) | BR112012024642B1 (en) |
CA (1) | CA2793294C (en) |
DK (1) | DK2553132T3 (en) |
ES (1) | ES2544576T3 (en) |
HR (1) | HRP20150826T1 (en) |
PL (1) | PL2553132T3 (en) |
PT (1) | PT2553132E (en) |
WO (1) | WO2011120550A1 (en) |
ZA (1) | ZA201207137B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020084332A1 (en) | 2018-10-23 | 2020-04-30 | Arcelormittal | Hot-rolled steel plate and a method of manufacturing thereof |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102650015A (en) * | 2012-05-29 | 2012-08-29 | 江苏省沙钢钢铁研究院有限公司 | Economical-type fine-grain high-flexibility weather-proof medium steel plate and production method thereof |
US20140170015A1 (en) * | 2012-12-17 | 2014-06-19 | Grzegorz Jan Kusinski | Corrosion resistant steel composition |
CN103074548B (en) * | 2013-01-24 | 2016-02-24 | 宝山钢铁股份有限公司 | A kind of high corrosion resistant type high strength is containing Al weather-resistant steel plate and manufacture method thereof |
JP6180956B2 (en) * | 2014-02-13 | 2017-08-16 | 株式会社神戸製鋼所 | Painted steel with excellent corrosion resistance |
JP6405910B2 (en) * | 2014-11-10 | 2018-10-17 | 新日鐵住金株式会社 | Corrosion resistant steel |
CN104878322B (en) * | 2015-05-14 | 2017-01-04 | 中天钢铁集团有限公司 | A kind of production technology of low-carbon (LC) weathering steel |
CN111101071B (en) * | 2020-02-25 | 2021-04-13 | 湖南华菱涟源钢铁有限公司 | High-strength weathering steel and production method thereof |
CN112593158B (en) * | 2020-12-11 | 2021-11-30 | 湖南华菱涟源钢铁有限公司 | 690MPa low-temperature-resistant ultrahigh-strength weather-resistant steel plate and preparation method thereof |
CN113667883A (en) * | 2021-07-27 | 2021-11-19 | 包头钢铁(集团)有限责任公司 | Manufacturing method of rare earth microalloyed weather-resistant bridge steel for alpine region |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS4925527B1 (en) * | 1969-03-20 | 1974-07-01 | ||
JPS56146853A (en) * | 1980-04-11 | 1981-11-14 | Nippon Steel Corp | Dual-phase steel plate for car with superior weldability and high corrosion resistance |
JP2620068B2 (en) * | 1986-02-14 | 1997-06-11 | 三菱製鋼 株式会社 | Corrosion resistant steel bars for concrete |
JP3456743B2 (en) * | 1994-01-17 | 2003-10-14 | 新日本製鐵株式会社 | Coastal weathering steel |
JPH09118919A (en) * | 1995-10-26 | 1997-05-06 | Sumitomo Metal Ind Ltd | Manufacture of steel product excellent in seawater corrosion resistance |
EP2314730B1 (en) * | 1996-11-28 | 2012-03-21 | Nippon Steel Corporation | High-strength steels having high impact energy absorption properties. |
TW426742B (en) * | 1997-03-17 | 2001-03-21 | Nippon Steel Corp | Dual-phase type high strength steel sheets having high impact energy absorption properties and a method of producing the same |
JP3783378B2 (en) * | 1997-12-04 | 2006-06-07 | Jfeスチール株式会社 | High-strength steel excellent in weldability and seawater resistance and method for producing the same |
JP4061771B2 (en) * | 1999-04-09 | 2008-03-19 | 住友金属工業株式会社 | Steel with excellent beach weather resistance |
JP2001247935A (en) * | 2000-03-06 | 2001-09-14 | Nkk Corp | Rolled shape steel excellent in earthquake resistance and weather resistance and its producing method |
JP3738645B2 (en) * | 2000-03-17 | 2006-01-25 | 住友金属工業株式会社 | High-tensile cold-rolled steel sheet with excellent electroplating adhesion and ductility and method for producing the same |
TW567231B (en) * | 2001-07-25 | 2003-12-21 | Nippon Steel Corp | Multi-phase steel sheet excellent in hole expandability and method of producing the same |
ES2256378T3 (en) * | 2002-09-11 | 2006-07-16 | Thyssenkrupp Steel Ag | HIGHLY RESISTANT FERRITIC / MARTENSITIC STEEL WITH VERY FINE STRUCTURE. |
JP4586489B2 (en) | 2004-10-22 | 2010-11-24 | 住友金属工業株式会社 | Steel and structures with excellent beach weather resistance |
JP5256818B2 (en) * | 2008-03-31 | 2013-08-07 | Jfeスチール株式会社 | Method for producing high toughness steel |
-
2010
- 2010-03-29 WO PCT/EP2010/054086 patent/WO2011120550A1/en active Application Filing
- 2010-03-29 CA CA2793294A patent/CA2793294C/en active Active
- 2010-03-29 BR BR112012024642-9A patent/BR112012024642B1/en active IP Right Grant
- 2010-03-29 ES ES10712049.5T patent/ES2544576T3/en active Active
- 2010-03-29 PL PL10712049T patent/PL2553132T3/en unknown
- 2010-03-29 EP EP20100712049 patent/EP2553132B1/en active Active
- 2010-03-29 US US13/637,461 patent/US20130078135A1/en not_active Abandoned
- 2010-03-29 CN CN201080065812.4A patent/CN102884214B/en active Active
- 2010-03-29 PT PT107120495T patent/PT2553132E/en unknown
- 2010-03-29 DK DK10712049.5T patent/DK2553132T3/en active
-
2012
- 2012-09-21 ZA ZA2012/07137A patent/ZA201207137B/en unknown
-
2015
- 2015-07-30 HR HRP20150826TT patent/HRP20150826T1/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2011120550A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020084332A1 (en) | 2018-10-23 | 2020-04-30 | Arcelormittal | Hot-rolled steel plate and a method of manufacturing thereof |
WO2020084478A1 (en) | 2018-10-23 | 2020-04-30 | Arcelormittal | Hot rolled steel and a method of manufacturing thereof |
Also Published As
Publication number | Publication date |
---|---|
BR112012024642A2 (en) | 2016-06-07 |
BR112012024642B1 (en) | 2018-02-06 |
PT2553132E (en) | 2015-09-10 |
ZA201207137B (en) | 2014-04-30 |
HRP20150826T1 (en) | 2015-11-20 |
CA2793294A1 (en) | 2011-10-06 |
CN102884214B (en) | 2015-09-09 |
CA2793294C (en) | 2015-09-29 |
CN102884214A (en) | 2013-01-16 |
WO2011120550A1 (en) | 2011-10-06 |
EP2553132B1 (en) | 2015-05-06 |
PL2553132T3 (en) | 2015-10-30 |
US20130078135A1 (en) | 2013-03-28 |
ES2544576T3 (en) | 2015-09-01 |
DK2553132T3 (en) | 2015-07-27 |
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