EP2539043A1 - Procédé pour séparer les composants gazeux accompagnant le gaz naturel ou le pétrole par des membranes poreuses anorganiques - Google Patents
Procédé pour séparer les composants gazeux accompagnant le gaz naturel ou le pétrole par des membranes poreuses anorganiquesInfo
- Publication number
- EP2539043A1 EP2539043A1 EP11704460A EP11704460A EP2539043A1 EP 2539043 A1 EP2539043 A1 EP 2539043A1 EP 11704460 A EP11704460 A EP 11704460A EP 11704460 A EP11704460 A EP 11704460A EP 2539043 A1 EP2539043 A1 EP 2539043A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- membrane
- mesoporous
- separation
- membranes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 107
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000003345 natural gas Substances 0.000 title claims abstract description 25
- 239000003209 petroleum derivative Substances 0.000 title abstract description 5
- 239000012466 permeate Substances 0.000 claims abstract description 45
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 39
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 38
- 239000007789 gas Substances 0.000 claims abstract description 32
- 239000011148 porous material Substances 0.000 claims abstract description 29
- 238000001179 sorption measurement Methods 0.000 claims abstract description 16
- 238000009833 condensation Methods 0.000 claims abstract description 14
- 230000005494 condensation Effects 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000000926 separation method Methods 0.000 claims description 66
- 230000015572 biosynthetic process Effects 0.000 claims description 39
- 238000003786 synthesis reaction Methods 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 33
- 239000010457 zeolite Substances 0.000 claims description 23
- 230000008569 process Effects 0.000 claims description 20
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 239000012465 retentate Substances 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 229910021536 Zeolite Inorganic materials 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 229910052593 corundum Inorganic materials 0.000 claims description 8
- 239000010431 corundum Substances 0.000 claims description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 230000001404 mediated effect Effects 0.000 claims description 5
- 238000007906 compression Methods 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- 238000010335 hydrothermal treatment Methods 0.000 claims 2
- 239000010410 layer Substances 0.000 description 41
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 24
- 150000001335 aliphatic alkanes Chemical class 0.000 description 12
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000000969 carrier Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000034655 secondary growth Effects 0.000 description 2
- 238000007569 slipcasting Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical class CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000001652 electrophoretic deposition Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000005373 porous glass Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- ZASZWSTYEJKHIN-UHFFFAOYSA-N tripropylazanium;hydroxide Chemical compound [OH-].CCC[NH+](CCC)CCC ZASZWSTYEJKHIN-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
- B01D71/0281—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/225—Multiple stage diffusion
- B01D53/226—Multiple stage diffusion in serial connexion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0051—Inorganic membrane manufacture by controlled crystallisation, e,.g. hydrothermal growth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
- B01J20/28035—Membrane, sheet, cloth, pad, lamellar or mat with more than one layer, e.g. laminates, separated sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/11—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by dialysis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/12—Liquefied petroleum gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/308—Pore size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2317/00—Membrane module arrangements within a plant or an apparatus
- B01D2317/02—Elements in series
- B01D2317/025—Permeate series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1025—Natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4012—Pressure
Definitions
- the invention relates to a method for the separation of natural gas or Erdölbegleitgas components of inorganic porous membranes, in which higher hydrocarbons to C 6 from natural gas and associated gas are separated effectively without extensive expansion and cooling using membrane technology continuously.
- HKW hydrocarbons
- Deep-freeze condensation is a process and energy-consuming process which, after expansion, causes a compression of the delivered gas. In some cases, an additional pre-treatment of the gas flow is required.
- zeolite membranes are suitable because they have an inherent, defined pore system.
- the hydrophobic silicalite or low-aluminum ZSM-5 from the group of MFI zeolites is particularly suitable for the separation of non-polar components from natural gases.
- WO 94/01209 describes the synthesis of dense ZSM-5 layers and their use in the selective adsorption of, inter alia, hydrocarbons up to an applied feed pressure of 100 kPa.
- the zeolite membranes on porous supports can be prepared in various ways. Common is in situ crystallization directly on the support, or seed-based synthesis for more oriented, uniform growth.
- Seed crystals are usually prepared and deposited separately for this purpose, see documents DE 10 2004 0001 974 A1 / DE 100 27 685 B4. Or a seed layer is produced directly on the support during a separate synthesis step, as described in patent DE 103 04 322A1. Subsequently, the formation of a continuous synthesis layer from a dilute solution out, the especially to support crystal growth. Both methods are very process-intensive.
- the object of the invention is to provide a process for the separation of natural gas or Erdölbegleitgas components of inorganic porous membranes, in the higher hydrocarbons such as C 3 and C 4 of the lower hydrocarbon Ci from natural gas and Erdölbegleitgas effectively without costly relaxation and cooling using membrane technology
- the separation even on more advanced, inorganic porous membranes without the use of purge gases at elevated, practical pressure conditions and improved separation performance compared to low pressure applications and higher gas flow rate should be made.
- Another object is to use smaller natural gas fields, since by means of membrane technology, a flexible, less complicated procedural method for removing higher hydrocarbons from the raw gas is available. Another object is to also find methods for removing higher hydrocarbons from the hitherto little or no use of associated petroleum gas or other hydrocarbon mixtures.
- Another object is to provide an inorganic porous membrane with altered performance parameters.
- the inventive method for separating natural gas or Erdölbegleitkomponenten of inorganic porous membranes is to supply in a separator gaseous natural gas or Erdölbegleitkomponenten with a pressure of greater than 5 bar the feed side of a supported inorganic porous membrane and dissipate a separated gas stream on the permeate side, wherein the pressure on the permeate side of the membrane is lower than on the feed side and adsorption and condensation of higher hydrocarbons to be separated C to C 6 of Ci and in the pores of the membrane [8], and the temperature is less than 150 ° C, and wherein the membrane on the feed side has a microporous second separation layer which is arranged on a mesoporous first layer, and the first layer is arranged on a macroporous or mesoporous carrier, wherein the mesoporous first layer comprises particles of a ground zeolite having a particle size smaller than 1 ⁇ and the thickness of the mesoporous first layer less than 20
- the process according to the invention surprisingly results in pressure-mediated, intensified adsorption and condensation of the respective higher hydrocarbon from the hydrocarbon mixture present in the membranes used and in the pores of the membrane and by an applied pressure difference between feed and per - Meat for flow increase through the membrane.
- the separation of the respective higher hydrocarbon is favored according to the invention technically.
- This procedurally advantageous effect is only favorable at sufficiently high absolute pressures of the hydrocarbon mixture on the inorganic porous separating layer and by a specific membrane with the structure mentioned below.
- Pressure-mediated is defined as the improved segregation performance of the membrane due to the applied gas pressure of the feed compared to low-pressure applications. As practical pressures, pressures greater than 5 bar are defined, e.g.
- the permeate defined is the gas flow passing through the membrane.
- the feed is defined as the gas flow to the membrane module input.
- the retentate is defined as the gas flow that does not pass through the membrane to the membrane module outlet.
- the membranes required for this purpose were obtained with a prior art improved manufacturing method.
- the earth gas or petroleum feed gas or mixtures of natural gas or petroleum gas entraining components are pressurized to these inorganic porous membranes so that preferably the higher alkane adsorbs and condenses to the inorganic porous layer to a greater extent as low pressure applications and thereby separated from the feed becomes.
- Particularly preferred materials of the inorganic porous layer, here called membrane are densely grown Krästallite on the basis of zeolitic structure types, particularly preferably MFI, FAU, LTA, MOR, FER, MEL, BEA; ITR and KFI, preferably MF1 and FAU, and here particularly preferably the MFI structure with silicalite membranes without Ai content or MFI membranes with an aluminum content.
- zeolitic structure types particularly preferably MFI, FAU, LTA, MOR, FER, MEL, BEA; ITR and KFI, preferably MF1 and FAU, and here particularly preferably the MFI structure with silicalite membranes without Ai content or MFI membranes with an aluminum content.
- Particularly preferred is the known ZSM-5 with öhb0 (0 ⁇ n ⁇ 27).
- Particularly preferred in MFI membranes with aluminum proportions are Si / Al contents of greater than 75.
- the pore sizes in the range of the molecular diameters of the hydrocarbons to be separated are 0.3 to 2 nm, preferably 0.5 to 0.8 nm.
- amorphous inorganic membranes are preferred. Particularly preferred herein are silica membranes and carbon membranes having pore sizes in the range of 0.5-2 nm.
- the membranes should be meso- and macroscopically dense and thus allow only adsorptive processes on the surface, whereby the mass transfer thus proceeds only through the intracrystalline pore system. Transport between the khstallites of the porous inorganic layer must not or only to a very small extent take place due to the applied pressures.
- Advantageous for the separation process are membranes which, due to their small layer thickness, permit high permeate fluxes. Therefore, the thickness of the separating layer is preferably less than 50 ⁇ , e.g. 2-40 ⁇ , more preferably less than 30 ⁇ , e.g. 2 - 20 pm.
- the separation of natural gas or Erdölbegleitgaskomponenten takes place in the simplest case by an applied feed pressure greater than 5 bar and a differential pressure between the feed and permeate side (Fig. 1, Example 1), preferably 4 - 10 bar.
- the feed pressure may deviate from optimum for the membrane process pressure conditions and by other technological processes, such as by the inlet pressure of the delivered raw gas.
- the permeate pressure sets in dependence on the permeate flow and can be lowered by pressure control to the corresponding pressure difference.
- the pressure difference is preferably 1 to 30 bar, especially 4 to 20 bar and especially 4 to 10 bar.
- the temperature on both sides of the membrane is less than 150 ° C and is preferably in the range of - 40 to + 80 ° C.
- a further development of the method further includes the selective separation by means of a modular, cascade separation plant, wherein preferably each of the highest hydrocarbon passes through the membrane and is separated from the feed.
- the retentate has over the input composition, the feed, a depleted in these components composition.
- the resulting retentate passes through another separation unit, which in turn separates the highest alkane contained in this mixture. This process is repeated until the original mixture of the natural gas or associated gas has been separated into its individual components.
- the feed pressure in this process must always be in the area of the pressure-transmitting
- Adsorption and condensation are.
- the highest alkane is defined as the hydrocarbon with the longest C-C carbon compound.
- From the permeate can be done by compression or cooling, the separation of hydrocarbons.
- the permeate is compressed, it is possible to recycle the remaining gaseous hydrocarbon mixture into the feed stream of the membrane reactor with the aim of using it as a whole.
- n-hexane is first separated at the membrane at elevated pressures from the inorganic porous membrane, methane and n-butane remain in the retentate. If the n-hexane is separated off, the separation of n-butane is carried out in a subsequent separation step on a downstream membrane, as shown for example in FIG. 2 and in Examples 1 and 3. This effect is observed at elevated feed pressures of p Feed > 5 bar.
- the process conditions and membrane geometry can be varied so that either individual hydrocarbons are selectively separated or incurred Kohienwasserstoffgemische in the permeate.
- the individual separation is shown, for example, in FIG. 2, where a plurality of membranes are arranged one behind the other and the separated hydrocarbon is removed after each membrane.
- the permeate can be recirculated uncompressed or compressed into the feed stream. The uncompacted recirculation makes sense if a compressor with subsequent condensate separation is already installed upstream of the membrane in the feed.
- porous support In addition to support materials made of metal composite membranes are mainly produced on corundum carriers, since they are cheaper to produce and membrane and support are similar in their chemical composition and their thermal expansion Verhaitenbehhaiten ago. Other carrier materials, such as porous glasses or porous metals, are also suitable.
- Synthesis approach is simplified in that the difficult-to-produce seed layer is replaced by applying a ground slurry with the composition of the subsequent membrane layer.
- An MFi layer for example, applied as a nucleation layer favors a uniform, secondary growth out of a synthesis solution.
- this layer is a barrier layer, whereby the
- Synthesis solution does not enter the porous Korundisme. Both lead to a reduction of the manufacturing costs, since interlayer (s) among other things of Ti0 2 are not required and a complex seed coating omitted from the above publications. In addition, advantages of a technological nature result when using dilute synthesis solutions, for example a better flow through thinner layers.
- the material for the mesoporous layer is prepared by milling commercial zeolite material to a fineness ⁇ 1 pm, preferably ⁇ 500 nm.
- the advantage of ground particles consists in the very good gearing with the macroporous or mesoporous carrier material.
- macroporous refers to pores with> 1000 nm, mesoporous pores with 2-50 nm and microporous pores with 0.1-2 nm.
- the training e.g. a porous silicalite layer is preferably carried out by slip casting.
- the solids content! in the slip is preferably 0.5 to 10 wt .-%.
- electrophoretic deposition of the particles is also possible.
- the mesoporous intermediate layer is heat treated to further enhance the adhesion and burnout of any organic suspending and binding agents, with a temperature below the phase transition of the silicalite being chosen.
- the selected temperature of this temperature treatment is between 400 ° C and 800 ° C, more preferably between 500 and 700 D C.
- the silicon / aluminum molar ratio of the synthesis solution for the secondary growth step is for e.g. MFI exemplifies> 2.5, preferably> 75. Higher proportions of aluminum result in a more hydrophilic behavior and are therefore disadvantageous for the separation of non-polar mixtures.
- composition of a silica synthesis solution can vary with respect to selectivity and flux, depending on the synthesis method, the reagents used, the physical synthesis parameters and the desired membrane properties.
- Possible synthesis compositions in the range of 100 mol Si0 2 : 0 - 35 mol SDA: 0 - 50 mol NaOH: 0 - 17 mol Al 2 0 3 and .000 - 100,000 mol H 2 0, where SDA for the structure-directing agents, also called template , stands.
- SDA can be tripropylammonium hydroxide or tripropylammonium bromide or a mixture of both.
- the synthesis composition is optimized (Example 2).
- Templat portions of from 0.01 to 1.2 mol and water contents of from 4,000 to 40,000 mol per 100 mol of SiO 2 in the synthesis batch are preferred for increasing the fluxes.
- the pH of the synthesis solution is adjusted to 10 to 14, preferably between 1100 and 12.5, depending on the Si0 2 source used.
- Suitable silicon dioxide sources are dispersed SiO 2 , tetraethyl orthosilicate (TEOS) and colloidal SiO 2 , such as LUDOX or LEVASIL.
- the support provided with the mesoporous layer eg of Siialtalt, is prepared prior to the synthesis in such a way that the synthesis solution only comes into contact with the membrane side.
- the outside be sealed with Teflon tape or wax.
- Teflon caps can prevent access to the interior.
- the aim of the seal is to prevent zeolite growth on the desorption side. This results in an asymmetric structure of the carrier.
- the synthesis can be carried out under autogenous pressure, under atmospheric pressure, standing or flowing, for 3 to 120 hours.
- the synthesis is carried out under autogenous pressure at temperatures of 140 ° C to 200 ° C and 12 to 72 h, more preferably between 160 and 180 ° C and 16 to 48 h.
- the supports with the synthesized membrane are rinsed in deionized water until unreacted synthetic components are removed from the pores. This is generally the case when the pH of the wash water, after repeated changes, is at a pH of 7.
- the carriers are then gently dried. This can be done under room air conditions or after slow heating in a drying oven at 60 ° C. After drying, the removal of structure-directing templations takes place, since these are located in the zeolite pores and would thus prevent access of the gases to be separated.
- the calcination is carried out at a heating rate of 0.3 to 5.0 K / min, preferably at 1, 0 K / min at 400 to 550 C ° for 3 to 24 h, more preferably at 420 to 580 ° C for 5 to 12 h , carried out. Cooling is carried out at 0.1 - 5 K / min.
- Fig. 2 Scheme of the method according to the invention in the form of a cascade of several separation membranes
- Fig. 3 Scheme of the process according to the invention with recycling of the retentate to the feed
- the feed 1 consisting essentially of a mixture of Ci-C 4 hydrocarbons, introduced under a pressure P1 in a separation space.
- adsorption and condensation of C 4 takes place.
- the permeate 3 in the form of C 4 which has passed through the membrane into the permeate space, is withdrawn as gas at the lower pressure P2.
- the depleted at C 4 retentate 2 can be recycled or fed to another separation stage.
- Fig. 3 shows the return of the permeate 3 'to the feed 1 and thus a new passage of the pre-separated gas mixture in the circulation.
- FIG. 5 shows an MFI separating layer (top) 14 after the composition of 00 mol of SiO 2 : 0, 169 mol of Al 2 O 3 : 0.6 mol of TPABr: 0.0 mol of TPAOH: 3.3 mol of Na 2 O: 2,000 moles of H 2 O, including MF layer of MFI 13, including corundum MF layer 12, including corundum support layer 11.
- the membranes are tested for their permeation behavior under different conditions. For this they are mounted in a stainless steel module, whereby a seal by means of O-rings takes place to Permeatraum. To perform permeation tests at various temperatures, the module was heated. According to an assignment Under practical conditions, there is always a lower pressure on the permeate side during the measurement than on the feed side (1.4 bar). The pressure on the feed side is adjusted to the test values by means of a back pressure regulator. The retentate flow is kept constant during the measurement by adjusting the feed flow to the permeate flow.
- Test 1 Influence of differential pressure at constant permeate pressure
- Test 2 Influence of a higher alkane on the separation efficiency of methane / propane / n-butane and depletion of the higher alkane on the example of n-hexane.
- the highest alkane is preferably first removed.
- the n-hexane is preferably first separated off.
- the separation of the components methane / propane / n-butane is very low in this case, but can be carried out after separation of the higher alkane, here n-hexane, analogous to the separation 1 with higher separation factors.
- the separation factor is defined as the ratio of the concentrations of the higher alkane in the permeate to the retentate. (Table 2 and 3)
- Korundmonokanäle be used with an outer diameter of 10 mm, an inner diameter of 7 mm and a length of 125 mm.
- the carriers have a microfiltration layer of ⁇ -corundum provided by the manufacturer with an average pore size of 200 nm. The ends are sealed with glass solder.
- the corundum support coated in the interior with milled silicalite crystals is heat-treated at 700 ° C. for 1 h.
- the synthesis solution to form a closed Fiims on the mesopo- Rösen Silikalith für has a composition of 100 mol of Si0 2: 0.169 mole of Al 2 0 3: 3.3 mol of TPABr: 3.3 mol TPAOH: 3.3 moles of Na 2 O: 2.000 Mol H 2 O, see FIG. 4. An average layer thickness of 40-75 pm is observed.
- the flow behavior of a membrane after this synthesis is 4.7 ml / min at a pressure difference on the feed and permeate side of 1 bar.
- TPABr is tetrapropylammonium bromide
- TPAOH is tetrapropylammonium hydroxide.
- the water used is deionized water. Prior to the synthesis, the carriers are wrapped in fabric tape.
- the hydrothermal synthesis is carried out in an autoclave at 180 ° C for 24 h. After synthesis, the Teflon tape is removed and the membranes are rinsed in deionized water. After a space drying of 3 days, the calcination was carried out at 450 ° C for 5 h.
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Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102010009542A DE102010009542A1 (de) | 2010-02-26 | 2010-02-26 | Verfahren zur Abtrennung von Erdgas- oder Erdölbegleitgaskomponenten an anorganisch porösen Membranen |
PCT/EP2011/052587 WO2011104226A1 (fr) | 2010-02-26 | 2011-02-22 | Procédé pour séparer les composants gazeux accompagnant le gaz naturel ou le pétrole par des membranes poreuses anorganiques |
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EP2539043A1 true EP2539043A1 (fr) | 2013-01-02 |
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EP11704460A Ceased EP2539043A1 (fr) | 2010-02-26 | 2011-02-22 | Procédé pour séparer les composants gazeux accompagnant le gaz naturel ou le pétrole par des membranes poreuses anorganiques |
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EP (1) | EP2539043A1 (fr) |
DE (1) | DE102010009542A1 (fr) |
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RU2596257C1 (ru) * | 2015-04-29 | 2016-09-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Способ фракционирования смесей низкомолекулярных углеводородов с использованием капиллярной конденсации на микропористых мембранах |
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CN107653053A (zh) * | 2017-09-26 | 2018-02-02 | 新乡市恒星科技有限责任公司 | 一种自动化程度高的润滑脂制备装置 |
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WO2010138683A1 (fr) * | 2009-05-29 | 2010-12-02 | Shell Oil Company | Procédé de fabrication d'une membrane à tamis moléculaire de séparation de gaz |
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JPS6028826A (ja) * | 1983-07-26 | 1985-02-14 | Hiroshi Suzuki | かご型ゼオライト薄膜表層を有する複合膜及びその製造法 |
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EP0775015B1 (fr) | 1994-07-08 | 2004-09-15 | ExxonMobil Research and Engineering Company | Couches de zeolite a largeur regulee des cristaux et a orientation preferee cultivee sur une couche favorisant la croissance cristalline |
FR2742070B1 (fr) | 1995-12-08 | 1998-01-09 | Inst Francais Du Petrole | Procede d'elaboration controlee de membranes de zeolithe supportee |
GB9905561D0 (en) * | 1999-03-11 | 1999-05-05 | Exxon Chemical Patents Inc | Molecular sieve layers and process for their manufacture |
DE10027685B4 (de) | 2000-05-26 | 2005-11-10 | INSTITUT FüR ANGEWANDTE CHEMIE BERLIN-ADLERSHOF E.V. | Verfahren zur Herstellung von Molekularsieb-Membranen auf porösen Trägern |
FR2813310B1 (fr) * | 2000-08-25 | 2002-11-29 | Inst Francais Du Petrole | Procede de separation de paraffines multibranchees utilisant un absorbant zeolitique de structure mixte |
DE10107539A1 (de) | 2001-02-17 | 2002-09-05 | Aaflowsystems Gmbh & Co Kg | Filterkörper |
DE10304322B4 (de) | 2003-02-04 | 2007-09-13 | Dechema Gesellschaft Für Chemische Technik Und Biotechnologie E.V. | Herstellung von gestützten Zeolithschichten |
DE102004001974A1 (de) | 2004-01-13 | 2005-08-04 | Basf Ag | Komposit-Membran |
EP2032239B1 (fr) * | 2006-06-13 | 2014-03-19 | Basf Se | Procédé de fabrication d'une membrane composite et utilisations |
GB0710265D0 (en) * | 2007-05-30 | 2007-07-11 | Phoenix Ipr Ltd | Membrane structures and their production and use |
WO2009105251A1 (fr) * | 2008-02-21 | 2009-08-27 | Exxonmobil Research And Engineering Company | Séparation du méthane d’hydrocarbures ayant un nombre de carbones supérieur à l'aide de matériaux utilisant des matériaux à structure d'imidazolate zéolitique |
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2010
- 2010-02-26 DE DE102010009542A patent/DE102010009542A1/de not_active Withdrawn
-
2011
- 2011-02-22 WO PCT/EP2011/052587 patent/WO2011104226A1/fr active Application Filing
- 2011-02-22 EP EP11704460A patent/EP2539043A1/fr not_active Ceased
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US20100270239A1 (en) * | 2009-04-24 | 2010-10-28 | Headwaters Technology Innovation, Llc | Zeolite membrane and methods of making and using same for water desalination |
WO2010138683A1 (fr) * | 2009-05-29 | 2010-12-02 | Shell Oil Company | Procédé de fabrication d'une membrane à tamis moléculaire de séparation de gaz |
WO2010138692A1 (fr) * | 2009-05-29 | 2010-12-02 | Shell Oil Company | Procédé de fabrication d'une membrane de tamis moléculaire pour la séparation de gaz |
EP2585197A1 (fr) * | 2010-06-24 | 2013-05-01 | Leibniz-Institut für Katalyse e.V. an der Universität Rostock | Procédé permettant de séparer des hydrocarbures c2+ de gaz naturel ou de gaz associé au pétrole par l'emploi de membranes |
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RU2596257C1 (ru) * | 2015-04-29 | 2016-09-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Способ фракционирования смесей низкомолекулярных углеводородов с использованием капиллярной конденсации на микропористых мембранах |
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