EP2528959A1 - Procédé de préparation de produits de condensation d'acide phénolsulfonique et d'aldéhyde et leur utilisation en tant qu'agents dessicatifs - Google Patents

Procédé de préparation de produits de condensation d'acide phénolsulfonique et d'aldéhyde et leur utilisation en tant qu'agents dessicatifs

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Publication number
EP2528959A1
EP2528959A1 EP11700431A EP11700431A EP2528959A1 EP 2528959 A1 EP2528959 A1 EP 2528959A1 EP 11700431 A EP11700431 A EP 11700431A EP 11700431 A EP11700431 A EP 11700431A EP 2528959 A1 EP2528959 A1 EP 2528959A1
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EP
European Patent Office
Prior art keywords
polymer
drying
meth
acid
acrylate
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EP11700431A
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German (de)
English (en)
Inventor
Corinna Naundorf
Sebastien Garnier
Ulf Dietrich
Michael Kluge
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BASF SE
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BASF SE
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Priority to EP11700431A priority Critical patent/EP2528959A1/fr
Publication of EP2528959A1 publication Critical patent/EP2528959A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C08G8/18—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenols substituted by carboxylic or sulfonic acid groups
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641—Polyacrylates; Polymethacrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2652—Nitrogen containing polymers, e.g. polyacrylamides, polyacrylonitriles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2664—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of ethylenically unsaturated dicarboxylic acid polymers, e.g. maleic anhydride copolymers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2688—Copolymers containing at least three different monomers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028—Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039—Premixtures of ingredients
    • C04B40/0042—Powdery mixtures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0045—Polymers chosen for their physico-chemical characteristics
    • C04B2103/0057—Polymers chosen for their physico-chemical characteristics added as redispersable powders

Definitions

  • the present invention relates to a process for the preparation of phenolsulfonic acid-aldehyde condensates, and their use as drying aids, in particular in the spray-drying of aqueous polymer dispersions. Furthermore, the present invention relates to a process for the preparation of polymer powders redispersible in aqueous medium and to the redispersible polymer powders and their use.
  • Aqueous polymer dispersions are widely used, for example as binders, in particular for synthetic resin plasters or highly pigmented interior paints, adhesives or coating compositions. Often, however, it is desirable not to use the aqueous polymer dispersion, but the polymer in powder form.
  • the dispersion In order to obtain the polymer in powder form, the dispersion must be subjected to a drying process, for example spray-drying or freeze-drying.
  • spray drying the polymer dispersion is sprayed in a stream of hot air and dehydrated, wherein the dry air and the sprayed dispersion are preferably passed through the dryer in cocurrent.
  • the polymer powder obtained has the disadvantage that its redispersibility in aqueous medium can generally not be fully satisfied because the polymer particle diameter distribution resulting from the redispersion is generally different from that in the aqueous starting dispersion. The reason for this is that aqueous polymer dispersions do not form thermodynamically stable systems, unlike polymerizate solutions.
  • the system attempts to reduce the polymer / dispersion medium interface by combining small primary particles into larger secondary particles (specks, coagulum).
  • secondary particles specks, coagulum
  • this can be prevented for a long time by the addition of dispersants, such as emulsifiers and protective colloids.
  • dispersants such as emulsifiers and protective colloids.
  • the effect of the dispersants frequently no longer suffices and, to a certain extent, irreversible secondary particle formation occurs. That is, the secondary particles remain in the redispersion and reduce the performance properties of the obtainable in the redispersion aqueous polymer dispersion.
  • drying aids In order to prevent or at least reduce the secondary particle formation during drying, it has long been known to use so-called drying aids. These are often referred to as spraying aids, since the spray-drying promotes the formation of irreversibly agglomerated secondary particles in particular. This effect is all the more pronounced, the lower the glass transition temperature (and thus the softening temperature or the minimum film-forming temperature) of the polymer particles, especially if it is below the drying temperature. At the same time drying aids usually reduce the formation of adhering to the dryer wall polymer coating and thus cause an increase in the powder yield.
  • drying aids are known from numerous publications.
  • DE-A-24 45 813 describes a pulverulent polymer which is redispersible in aqueous systems and contains as drying assistant 1 to 20% by weight of a water-soluble condensation product containing sulfonic acid or sulfonate groups of aromatic hydrocarbons and formaldehyde.
  • These condensation products are in particular phenolsulfonic acid or naphthalenesulfonic acid-formaldehyde condensates.
  • About the molecular weight of the condensation products used are no information. It should be noted that the drying of the polymer powder should be carried out at temperatures below the softening temperature.
  • EP-A-78449 describes a process for the preparation of block-resistant, water-redispersible polymer powders by spray-drying aqueous dispersions of polymers having glass transition temperatures below 50 ° C.
  • the dispersions contain as spray a water-soluble copolymer of Vinylpyrroli- don and vinyl acetate and / or a water-soluble alkali and / or alkaline earth metal salt of a naphthalenesulfonic acid-formaldehyde condensation product.
  • a naphthalenesulfonic acid-formaldehyde condensation product there is no information about the molecular weight of the naphthalenesulfonic acid-formaldehyde condensation products used.
  • Conspicuous is the comparatively large amount of spray aids with the sole use of naphthalenesulfonic acid-formaldehyde condensation products (30 wt .-% in Ex. 4, 50 wt .-% in Ex. 5, 30 wt .-% in Ex. 6, in each case on the polymers).
  • EP-A-407 889 describes the use of a water-soluble alkali metal or alkaline earth metal salt of a phenol sulfonic acid-formaldehyde condensation product as a spray aid for the preparation of water-redispersible polymer powders from aqueous polymer dispersions.
  • a water-soluble alkali metal or alkaline earth metal salt of a phenol sulfonic acid-formaldehyde condensation product as a spray aid for the preparation of water-redispersible polymer powders from aqueous polymer dispersions.
  • EP-A-914 365 likewise describes the use of a water-soluble alkali metal salt and / or alkaline earth metal salt of a phenol sulfonic acid-formaldehyde condensate as spray auxiliaries of aqueous polymer dispersions.
  • a particularly suitable molecular weight of the condensation product is given as Mn ⁇ 1500.
  • the polymer powders are obtained in good yields using these condensation products and have good redispersibility.
  • a disadvantage is the coloration of the polymer powders obtained, which can sometimes be colored brownish to reddish.
  • WO 2005/021 145 a redispersible polymer powder is described which contains o-cresolsulfonic acid-formaldehyde condensates.
  • O-cresolsulfonic acid-formaldehyde condensates have the advantage that better control over the molecular weight is possible during their production.
  • WO 2006/034531 discloses a redispersible powder comprising an o-cresolsulfonic acid-formaldehyde condensate containing a certain amount of nitrogen-containing components.
  • the advantage of the nitrogen-containing condensation products is the lower coloration of the redispersible powders produced.
  • the present invention was based on the object to provide drying aids that cause even without the addition of nitrogen-containing compounds, a low color of the redispersible polymer powder.
  • the invention therefore provides a process for the preparation of a phenol-sulfonic acid-aldehyde condensation product, characterized in that the addition rate is selected such that the reaction temperature is preferably ⁇ 80 ° C, particularly preferably ⁇ 70 ° C and that the neutralization of the resulting phenolsulfonic acid condensate does not take place above a pH of 8, preferably 7.5 addition.
  • the phenolsulfonic acid-aldehyde condensate prepared by the process according to the invention causes less color in the redispersed powder.
  • Another object of the invention is the use of this phenolsulfonic acid aldehyde condensate as spraying aid for drying aqueous polymer dispersions.
  • the condensation product is used in the form of its salts, alkali metal or alkaline earth metal salts or ammonium salts, ie salts with ammonia or organic amines, such as triethanolamine, diethanolamine or triethylamine, are generally used.
  • the alkaline earth metal salts and in particular the calcium salts are used.
  • the preparation of the drying aid used according to the invention is generally carried out by condensation of phenolsulfonic acid with the aldehyde under acidic, in particular sulfuric acid, reaction conditions.
  • the phenolsulfonic acid can be prepared or prepared in situ by sulfonation by known methods (compare J. March, Advanced Organic Chemistry, 3rd ed, John Wiley, New York 1985, p 473 ff., And literature cited therein).
  • phenolsulfonic acid is prepared in situ by sulfonation with sulfuric acid, preferably concentrated sulfuric acid.
  • the condensation takes place by reaction of phenolsulfonic acid with aldehyde under acidic reaction conditions, preferably under high-acidic reaction conditions, in particular in concentrated sulfuric acid. If the phenolsulfonic acid is prepared in situ, the condensation is initiated by adding aldehyde to the sulfuric acid reaction mixture.
  • the molar ratio of aldehyde: phenolsulfonic acid is in the range from 1: 1 to 1: 2, preferably in the range from 1: 1, 3 to 1: 1, 7.
  • the aldehyde is added as an aqueous solution.
  • aldehyde according to the invention is understood as meaning formaldehyde, acetaldehyde, glyoxal, glutaraldehyde or mixtures thereof, preferably formaldehyde.
  • the addition is as rapid as possible, the rate of addition being chosen such that the reaction temperature is ⁇ 80 ° C., preferably ⁇ 70 ° C.
  • the present invention also provides a process for the preparation of a polymer powder by drying an aqueous polymer dispersion, wherein the drying assistant used is at least one phenolsulfonic acid-aldehyde condensation product of the type described above or a salt thereof.
  • the condensation products are used as salt, and acidic polymers in the acid form are used.
  • the amount of drying aids used is preferably from 1 to 30% by weight, based on the weight of the polymer of the dispersion, preferably from 3 to 15% by weight and more preferably from 5 to 12% by weight.
  • the compounds according to the invention are particularly advantageous for drying polymer dispersions in which the polymer has a glass transition temperature (DSC, midpoint temperature, ASTM D 3418-82) ⁇ 65 ° C., preferably ⁇ 50 ° C., more preferably ⁇ 25 ° C., and very particularly preferably ⁇ 0 ° C has.
  • the glass transition temperature of the polymers is> -60 ° C., preferably> -40 ° C. and especially> -20 ° C.
  • the glass transition temperature TG can be estimated. It applies to the glass transition temperature of weak or uncrosslinked copolymers at high molecular weights in a good approximation:
  • Tg where X 1 , X 2 , X n are the mass fractions 1, 2, n and T g 1 , T g 2 , T g n mean the glass transition temperatures of each of only one of the monomers 1, 2, n constructed polymers in degrees Kelvin. The latter are z. From Ullmann's Encyclopedia of Industrial Chemistry, VCH, 5.ed. Weinheim, Vol. A 21 (1992) p 169 or from J. fire rup, EH Immergut, Polymer Handbook, 3 rd ed, J. Wiley, New York 1989 known.
  • C n -C m refer to the number of carbons of a particular class of compounds that is possible within the scope of the invention.
  • Alkyl groups can be linear or branched.
  • C n -C m -Alkylaryl represents aryl groups which carry a C n -C m - alkyl radical.
  • vinylaromatic compounds are styrene, ⁇ -methylstyrene or vinyltoluene, such as o-vinyltoluene.
  • esters of ⁇ , ⁇ -monoethylenically unsaturated carboxylic acids are in particular esters of acrylic acid, methacrylic acid, maleic acid, fumaric acid or Itaconic acid.
  • esters are methyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, iso-butyl (meth) acrylate, t-butyl (meth) acrylate, ethylhexyl
  • (meth) acrylate decyl (meth) acrylate or dodecyl (meth) acrylate, dimethyl maleate, di-n-butyl maleate, or di-n-butyl fumarate.
  • Suitable vinyl and alkyl esters are vinyl acetate, vinyl propionate, vinyl n-butyrate, vinyl laurate and vinyl stearate and the corresponding allyl esters.
  • Particularly preferred monomers (a) are n-butyl acrylate, tert-butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, tert-butyl methacrylate, vinyl acetate, vinyl propionate, butadiene and styrene.
  • the monomers (b) are preferably monomers (b ') which have an increased water solubility. These include the abovementioned ⁇ , ⁇ -monoethylenically unsaturated C 3 -C 6 -carboxylic acids, their amides, mono- or dialkylamides, N-alkylolamides and hydroxyalkyl esters, and the nitriles of ⁇ , ⁇ -ethylenically unsaturated carboxylic acids. Also useful are the N-vinyl derivatives of cyclic lactams and the mono- or dialkylaminoalkylamides of the cited C3-C6 carboxylic acids and their quaternization products.
  • Particularly preferred monomers (b ') are acrylamide, methacrylamide, acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, 2-acrylamido-2-methylpropanesulfonic acid, vinylpyrrolidone, hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, N-methylolacrylamide, N-methylolmethacrylamide, quaternized vinylimidazole, ⁇ , ⁇ -dialkylaminoalkyl (meth) acrylates, N, N-dialkylaminoalkyl (meth) acrylamides, trialkylammoniumalkyl (meth) acrylates and trialkylammoniumalkyl (meth) acrylamides.
  • the polymers may also contain, as monomers (b), further monomers (b ") which give higher strength to the polymer films obtainable from the polymers
  • monomers (b") include compounds containing at least two non-conjugated ethylenic double bonds. These include the diesters of dihydroxy compounds with ⁇ , ⁇ -ethylenically unsaturated dicarboxylic acids, such as ethylene glycol di (meth) acrylate, propylene glycol di (meth) acrylate, 1,3-butylene glycol and 1,4-butylene glycol di (meth) acrylate and 2,2-dimethylpropylene glycol di (meth) acrylate, the vinyl and allyl esters of dicarboxylic acids, such as divinyl and diallyl maleate, divinyl and diallyl fumarate, divinyl and diallyl phthalate, furthermore divinylbenzene, cyclopentadienyl acrylate and methacrylate, cyclohexen
  • Such compounds are usually used in amounts of up to 5 wt .-%, based on the total amount of monomer.
  • monomers (b ") are monomers having siloxane groups, such as vinyltrialkoxisilanes, for example vinyltrimethoxysilane, alkylvinyldialkoxysilanes, for example methylvinyldialkoxysilane, or (meth) acryloxyalkyltrialkoxisilanes, for example (meth) acryloxypropyltrimethoxysilane and (Meth) acryloxypropyltriethoxysilane
  • siloxane monomers can be used in amounts of up to 2% by weight, preferably 0.05 to 1% by weight, based on the total weight of the monomers.
  • monomers (b ) are crosslinking monomers such as glycidyl methacrylate or acetoacetoxy methacrylate.
  • Preferred polymer dispersions are furthermore those in which the weight-average diameter d w , of the dispersed polymer particles is> 100 nm and particularly preferably> 300 nm. Usually d w ⁇ 2000 nm. It is also advantageous if the diameters of the dispersed polymer particles are distributed over a wide diameter range.
  • the dw value of the particle size is defined as usual as the weight average particle size, as determined by means of an analytical ultracentrifuge according to the method of W. Scholtan and H. Lange, Kolloid-Z. and Z.-Polymere 250 (1972) pages 782 to 796.
  • Ultracentrifuge measurement provides the integral mass distribution of the particle diameter of a sample. From this it can be seen how many percent by weight of the particles have a diameter equal to or below a certain size.
  • Q is 0.5 to 1.5.
  • the preparation of polymer dispersions having such a particle distribution width is known to the person skilled in the art, for example from DE-A-43 07 683.
  • the ratio of weight-average molecular weight Mw to number-average molecular weight M n of the polymers can be 1 to 30 or 1 to 20 or 1 to 8.
  • the molecular weight may thus be substantially uniform or distributed over a certain width.
  • the preparation of the polymer dispersions to be dried is known. In general, it is carried out by free-radical polymerization, which is preferably carried out in polar solvents, in particular in water.
  • the molecular weight regulating substances can be used. Suitable molecular weight regulators are, for example, compounds which have a thiol group and / or a silane group (for example t-dodecyl, n-butyl). Dodecylmercaptan or mercaptopropyltrimethoxysilane), allyl alcohols or aldehydes such as formaldehyde, acetaldehyde, etc.
  • Suitable initiators are e.g. inorganic peroxides, such as sodium peroxodisulfate or azo compounds.
  • the polymerization can be carried out as a solution or emulsion polymerization.
  • a protective colloid such as polyvinyl alcohol, polyvinylpyrrolidone or cellulose derivatives or anionic and / or nonionic emulsifiers, such as ethoxylated mono-, di- or trialkylphenols, ethoxylated fatty alcohols and alkali metal or ammonium salts of C 8 -C 12 -alkyl sulfates, sulfuric monoesters ethoxylated C 12 -C 18 -alkanols, C 12 -C 18 -alkylsulfonic acids, C 9 -C 18 -alkylarylsulfonic acids and sulfonated alkyldiphenyl ethers.
  • the polymerization temperature is generally in the range from 50 to 120.degree. C., in particular from 70 to 100.degree.
  • the emulsion polymerization in the presence of a seed latex.
  • the seed latex can be prepared separately or in situ. Methods for this purpose are known from the prior art (see EP-A 567 81 1, EPA 567 812, EP-A 567 819, EP-B 40 419, EP-A 129 699, DE-A 31 47 008, DE-A 42 13 967 and DE-A 42 13 968 the content of which is fully incorporated by reference).
  • the polymer dispersions are prepared in the absence of a seed latex.
  • the particle size can be adjusted by surface-active compounds, such as protective colloids or emulsifiers.
  • the dispersion may be a primary dispersion, i. a polymer dispersion which was obtained directly by the method of free-radical aqueous emulsion polymerization. It may also be a secondary dispersion, i. a polymer obtained by solution polymerization is subsequently converted into an aqueous polymer dispersion.
  • the drying of the polymer dispersion can be carried out in the usual manner, for example by freeze-drying or preferably by spray-drying.
  • spray drying the procedure is such that the inlet temperature of the hot air flow in the range of 100 to 200 ° C, preferably 120 to 160 ° C and the outlet temperature of the hot air flow in the range of 30 to 95 ° C, preferably 60 to 80 ° C.
  • the spraying of the aqueous polymer dispersion in the stream of hot air can be carried out, for example, by means of single-fluid or multi-fluid nozzles or via a rotating disk.
  • the deposition of the polymer powder is usually carried out using cyclones or filter separators.
  • the sprayed aqueous polymer dispersion and the hot air stream are preferably conducted in parallel.
  • the phenolsulfonic acid-aldehyde condensation products used according to the invention can be added to the dispersion to be dried as an aqueous solution or as a solid before drying. If it is a primary dispersion, the drying assistant can be added before, during and / or after the emulsion polymerization.
  • drying auxiliaries such as polyvinyl alcohol, polyvinylpyrrolidone, naphthalenesulfonic acid-aldehyde condensates, homopolymers of 2-acrylamido-2-methylpropanesulfonic acid, etc.
  • Anti-caking agents such as finely divided silica, which are usually used for the drying of aqueous polymer dispersions, can also be used in order to prevent caking of the polymer powder during storage. In spray drying, the anti-caking agents are usually sprayed separately.
  • the present invention also provides the polymer powders obtainable according to the invention. They are suitable as binders in hydraulically setting compounds, paints, lacquers, adhesives, coating compositions (in particular for paper) and synthetic resin plasters, as described in EP-A-629 650.
  • the polymer powders obtainable according to the invention are suitable for the modification of mineral binders (mortar-like preparations) containing a mineral binder consisting of 70 to 100% by weight of cement and 0 to 30% by weight of gypsum. This is especially true when cement is the sole mineral binder.
  • the effect according to the invention is essentially independent of the type of cement.
  • oil shale cement, Portland cement, hydrophobic Portland cement, quick-setting cement, swelling cement or alumina cement can be used, with the use of Portland cement proves to be particularly favorable.
  • the ratio of mineral binder to polymer powder is 1: 0.001 to 1: 3.
  • cellulose binders and microsilica are often added to mineral binders.
  • the first are usually thickening and the latter usually form thixotropic agents which further reduce the fluidity of the aqueous mortar before it is solidified when applied.
  • Calcium carbonate and quartz sand usually form the other additives.
  • the polymer powders obtainable according to the invention are suitable e.g. for modifying cementitious repair or reinforcing mortars.
  • conventional reinforcing mandrels for increasing their crack bridging ability still comprise natural or synthetic fibers of materials such as e.g. Dralon (length, e.g., 1 to 10 mm, length-related mass, e.g., 3 to 10 dtex).
  • modifying polymer powder For highest crack bridging requirements, from 4 to 9% by weight modifying polymer powder will be added to the cementitious reinforcing mortar based on cement contained, 9 to 20, with lower crack bridging requirements. Only in the case of particularly low crack bridging requirements is the amount of modifying polymer powder added, in a corresponding manner, limited to 0.1 to 4% by weight.
  • Typical reinforcing mortars consist of a mineral binder ready-to-dry finish
  • modifying polymer powder obtainable according to the invention, up to 25% by weight of customary auxiliaries (for example defoamer or thickener) and, as residual amount, additives such as, for example, Sand, fillers (e.g., CaCOs), pigments (e.g., ⁇ 2) natural and / or synthetic fibers.
  • customary auxiliaries for example defoamer or thickener
  • additives such as, for example, Sand, fillers (e.g., CaCOs), pigments (e.g., ⁇ 2) natural and / or synthetic fibers.
  • sample S1 and comparative sample SV1 were determined according to DIN EN ISO 4630-1 by comparison with the colors of a numbered color scale. The standard closest to the sample was determined and the result reported as the Gardner color number. For this purpose, the transmittance of a 1% solution of the samples to be examined, filled in a 1 1 mm cuvette was used. 2.4 Molecular weight of the spray aids
  • the mobile phase used was a mixture of 60% by weight of a 0.1 M solution of sodium nitrate, 30% by weight of tetrahydrofuran (p.a.) and 10% by weight of acetonitrile (p.a.). As an internal standard for flow correction, 1% acetone was added.
  • the samples were diluted to a solids content of 0.5% by weight with deionized water and chromatographed at a flow rate of 1.50 ml / min and a temperature of 60 ° C.
  • the detection was carried out by UV spectrometry at a wavelength of 254 nm.
  • naphthalene mono-, di- and trisulfonic acid sodium salts were used. The results are summarized in Table 2.
  • the hydrophobic antiblocking agent used was Siperant® D17 from Degussa. This is a precipitated silica with a specific surface area (based on ISO 5794-1, Annex D) of 100 m 2 / g, an average particle size (based on ASTM C690-1992) of 7 ⁇ m and a tapped density (based on to ISO 787-1 1) of 150 g / l, whose surface has been rendered hydrophobic by treatment with a special chlorosilane.
  • Siperant® D17 from Degussa. This is a precipitated silica with a specific surface area (based on ISO 5794-1, Annex D) of 100 m 2 / g, an average particle size (based on ASTM C690-1992) of 7 ⁇ m and a tapped density (based on to ISO 787-1 1) of 150 g / l, whose surface has been rendered hydrophobic by treatment with a special chlorosilane.
  • the spray feed was produced in such a way that 1 part by weight of the aqueous spray assistant solutions S1 and SV1 diluted to 20% were added to 5 parts by weight of the aqueous polymer dispersions D1 and D2 diluted to 40% and the mixture was homogeneously mixed with stirring.

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Abstract

La présente invention concerne un procédé de préparation de condensats d'acide phénolsulfonique et d'aldéhyde, ainsi que leur utilisation en tant qu'agents dessicatifs, en particulier lors du séchage par pulvérisation de dispersions aqueuses de polymérisat.
EP11700431A 2010-01-25 2011-01-18 Procédé de préparation de produits de condensation d'acide phénolsulfonique et d'aldéhyde et leur utilisation en tant qu'agents dessicatifs Withdrawn EP2528959A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11700431A EP2528959A1 (fr) 2010-01-25 2011-01-18 Procédé de préparation de produits de condensation d'acide phénolsulfonique et d'aldéhyde et leur utilisation en tant qu'agents dessicatifs

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10151556 2010-01-25
PCT/EP2011/050585 WO2011089106A1 (fr) 2010-01-25 2011-01-18 Procédé de préparation de produits de condensation d'acide phénolsulfonique et d'aldéhyde et leur utilisation en tant qu'agents dessicatifs
EP11700431A EP2528959A1 (fr) 2010-01-25 2011-01-18 Procédé de préparation de produits de condensation d'acide phénolsulfonique et d'aldéhyde et leur utilisation en tant qu'agents dessicatifs

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AU2011208810A1 (en) 2012-08-16
WO2011089106A1 (fr) 2011-07-28
CN102712731A (zh) 2012-10-03
US20110184104A1 (en) 2011-07-28

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