EP2520710B1 - Silk-effect paper material and corresponding manufacturing method - Google Patents
Silk-effect paper material and corresponding manufacturing method Download PDFInfo
- Publication number
- EP2520710B1 EP2520710B1 EP12167033.5A EP12167033A EP2520710B1 EP 2520710 B1 EP2520710 B1 EP 2520710B1 EP 12167033 A EP12167033 A EP 12167033A EP 2520710 B1 EP2520710 B1 EP 2520710B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- paper material
- fibres
- approximately
- silk
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000463 material Substances 0.000 title claims description 33
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000123 paper Substances 0.000 claims description 35
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- 239000000758 substrate Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 239000000853 adhesive Substances 0.000 claims description 13
- 230000001070 adhesive effect Effects 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 10
- 239000004902 Softening Agent Substances 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- 239000011256 inorganic filler Substances 0.000 claims description 7
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 6
- 238000004381 surface treatment Methods 0.000 claims description 6
- 229920003043 Cellulose fiber Polymers 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229920000881 Modified starch Polymers 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 238000009499 grossing Methods 0.000 claims description 4
- 235000019426 modified starch Nutrition 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000000454 talc Substances 0.000 claims description 4
- 229910052623 talc Inorganic materials 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000012764 mineral filler Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000004049 embossing Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011111 cardboard Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- -1 for example Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/28—Organic non-cellulose fibres from natural polymers
- D21H13/34—Protein fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/02—Synthetic cellulose fibres
- D21H13/08—Synthetic cellulose fibres from regenerated cellulose
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/26—Polyamides; Polyimides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/18—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only forming new compounds in situ, e.g. within the pulp or paper, by chemical reaction with itself, or other added substances, e.g. by grafting on the fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/52—Epoxy resins
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Definitions
- the present invention relates to a silk-effect paper material (paper/cardboard) and to the corresponding manufacturing method. More precisely, the paper material of the invention, thanks to an appropriately devised pulp and to a specific surface treatment, loses the typical feel of paper materials and is characterized by a feel similar to that of silk.
- US 5 334 286 A and WO 00/22231 A1 disclose a tissue-type paper material, not suitable for printing with high quality.
- An aim of the present invention is to provide a paper material that will present a feel different from that of traditional paper materials and will at the same time enable a high printing quality.
- the present invention hence regards a paper material and the corresponding manufacturing method as defined in the annexed Claims 1 and 8, respectively.
- the invention hence provides a silk-effect paper material (paper/cardboard), which, thanks to an appropriately devised pulp and to a specific surface treatment, loses the typical feel of paper materials and is characterized by a feel similar to that of silk.
- the paper material of the invention moreover ensures a high printing quality and enables particular graphic effects to be achieved, which are difficult to obtain with traditional coated papers.
- the paper material of the invention comprises a substrate that is formed by a mixture of cellulose fibres and fibres of natural silk and/or synthetic silk (polyamide) and contains at least one polymeric substance, capable of bestowing (dry and wet) strength on the mixture of fibres, and an inorganic filler, capable of bestowing softness on the material maintaining good characteristics of machinability.
- the substrate has at least one surface (face) treated with at least one surface adhesive and one softening agent so that the paper material, owing to the combined effect of the composition of the substrate and of the surface treatment, presents a feel similar to that of silk.
- both of the faces of the substrate can be treated in the same way.
- the mixture of fibres can contain fibres with a base of natural and/or synthetic silk in a variable amount, preferably up to approximately 10% of the total of the fibres and more preferably in an amount of less than approximately 3%.
- the polymeric substance included in the substrate comprises one or more colophony-based and/or epichlorohydrin-based resins, and/or modified starches
- the inorganic filler is a mineral filler comprising one or more substances selected in the group consisting of carbonates, kaolins, talc, and mixtures thereof.
- the surface adhesive is, for example, an adhesive with a base of starch and/or polyvinyl alcohol and/or acrylic, polyurethane and/or styrene-butadiene polymers.
- the softening agent comprises, for example, sorbitol and/or glycerine.
- the paper material according to the invention is provided with a glossy coating, applied on the treated surface (clearly, the paper material can have both of the surfaces treated and provided with a glossy coating).
- the glossy coating is formed by one or more binding polymers (for example polyurethane-based and/or silicone-based polymers) and/or waxes, mixed with pigments, for example, pigments with a lamellar or flat structure, such as, for example, precipitated calcium carbonate (PCC), calcined and/or lamellar kaolins, in combination with oriented and iridescent metal pigments with lamellar structure.
- binding polymers for example polyurethane-based and/or silicone-based polymers
- waxes mixed with pigments, for example, pigments with a lamellar or flat structure, such as, for example, precipitated calcium carbonate (PCC), calcined and/or lamellar kaolins, in combination with oriented and iridescent metal pigments with lamellar structure.
- PCC precipitated calcium carbonate
- the amount of polymer per face is preferably comprised between 5% and 100% with respect to the pigments; the substance of the paper material is comprised between approximately 90 g/m 2 and approximately 350 g/m 2 ; the amount of glossy coating spread on each face is comprised between approximately 5 g/m 2 and approximately 20 g/m 2 .
- the glossy coating may be coloured and/or spread on a coloured substrate; colours in paste form and organic or inorganic pigments are preferably used.
- the substrate is provided, with a technique of formation of paper that is substantially known, for example, on a paper machine.
- an aqueous pulp is provided of cellulose fibres and of fibres with a base of natural and/or synthetic silk, said pulp containing the polymeric substance (colophony-based and/or epichlorohydrin-based resins, and/or modified starches) and the inorganic filler (carbonates, kaolins, talc, etc.).
- polymeric substance colophony-based and/or epichlorohydrin-based resins, and/or modified starches
- the inorganic filler carbonates, kaolins, talc, etc.
- aqueous solution of surface adhesive for example, an aqueous solution containing 5 to 10 wt% of starch, or acrylic adhesive or other adhesives indicated above
- softening agent for example, sorbitol and/or glycerine
- the method further comprises, preferably after the surface treatment with adhesive and softening agent a step of smoothing of the substrate, where the substrate is smoothed, in particular up to Bendsten ISO 2494 roughness values of less than approximately 50 ml/min and preferably of less than approximately 30 ml/min and indicatively around 20 ml/min, followed by a step of application of the glossy coating described previously.
- application of the glossy coating is performed with an air-blade or smoothing-blade coating machine and is followed by a step of drying of the coating, conducted in an infrared oven and/or hot-air oven at a temperature of between approximately 100°C and approximately 180°C and with an oven time of between 0.5 and 4 minutes.
- the method comprises a step of mechanical treatment of the surface provided with the coating, in particular a smoothing step and/or an embossing step.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Description
- The present invention relates to a silk-effect paper material (paper/cardboard) and to the corresponding manufacturing method. More precisely, the paper material of the invention, thanks to an appropriately devised pulp and to a specific surface treatment, loses the typical feel of paper materials and is characterized by a feel similar to that of silk.
-
US 5 334 286 A andWO 00/22231 A1 - In the paper-making sector there is a constant search for new types of papers having particular appearances and/or finishes, above all designed for wrapping, packaging, production of illustrative material, quality printing, etc.
- Not infrequently, however, these particular effects are obtained at the expense of other characteristics of paper, for example, printability.
- An aim of the present invention is to provide a paper material that will present a feel different from that of traditional paper materials and will at the same time enable a high printing quality.
- The present invention hence regards a paper material and the corresponding manufacturing method as defined in the annexed Claims 1 and 8, respectively.
- Preferred embodiments of the paper material and of the corresponding manufacturing method are defined in the dependent Claims.
- The invention hence provides a silk-effect paper material (paper/cardboard), which, thanks to an appropriately devised pulp and to a specific surface treatment, loses the typical feel of paper materials and is characterized by a feel similar to that of silk.
- The paper material of the invention moreover ensures a high printing quality and enables particular graphic effects to be achieved, which are difficult to obtain with traditional coated papers.
- In detail, the paper material of the invention comprises a substrate that is formed by a mixture of cellulose fibres and fibres of natural silk and/or synthetic silk (polyamide) and contains at least one polymeric substance, capable of bestowing (dry and wet) strength on the mixture of fibres, and an inorganic filler, capable of bestowing softness on the material maintaining good characteristics of machinability.
- The substrate has at least one surface (face) treated with at least one surface adhesive and one softening agent so that the paper material, owing to the combined effect of the composition of the substrate and of the surface treatment, presents a feel similar to that of silk. Clearly, both of the faces of the substrate can be treated in the same way.
- The mixture of fibres can contain fibres with a base of natural and/or synthetic silk in a variable amount, preferably up to approximately 10% of the total of the fibres and more preferably in an amount of less than approximately 3%.
- Preferably, the polymeric substance included in the substrate comprises one or more colophony-based and/or epichlorohydrin-based resins, and/or modified starches, and the inorganic filler is a mineral filler comprising one or more substances selected in the group consisting of carbonates, kaolins, talc, and mixtures thereof.
- The surface adhesive is, for example, an adhesive with a base of starch and/or polyvinyl alcohol and/or acrylic, polyurethane and/or styrene-butadiene polymers.
- The softening agent comprises, for example, sorbitol and/or glycerine.
- Moreover, the paper material according to the invention is provided with a glossy coating, applied on the treated surface (clearly, the paper material can have both of the surfaces treated and provided with a glossy coating).
- In particular, the glossy coating is formed by one or more binding polymers (for example polyurethane-based and/or silicone-based polymers) and/or waxes, mixed with pigments, for example, pigments with a lamellar or flat structure, such as, for example, precipitated calcium carbonate (PCC), calcined and/or lamellar kaolins, in combination with oriented and iridescent metal pigments with lamellar structure.
- The amount of polymer per face is preferably comprised between 5% and 100% with respect to the pigments; the substance of the paper material is comprised between approximately 90 g/m2 and approximately 350 g/m2; the amount of glossy coating spread on each face is comprised between approximately 5 g/m2 and approximately 20 g/m2.
- The glossy coating may be coloured and/or spread on a coloured substrate; colours in paste form and organic or inorganic pigments are preferably used.
- The paper material just described is obtained, according to a further aspect of the present invention, with the method described below.
- First the substrate is provided, with a technique of formation of paper that is substantially known, for example, on a paper machine.
- Basically, an aqueous pulp is provided of cellulose fibres and of fibres with a base of natural and/or synthetic silk, said pulp containing the polymeric substance (colophony-based and/or epichlorohydrin-based resins, and/or modified starches) and the inorganic filler (carbonates, kaolins, talc, etc.).
- Next, water is removed from the pulp to form the substrate of the paper material.
- This is followed by a step of surface treatment of one or both of the faces of the substrate with an aqueous solution of surface adhesive (for example, an aqueous solution containing 5 to 10 wt% of starch, or acrylic adhesive or other adhesives indicated above) and softening agent (for example, sorbitol and/or glycerine).
- The method further comprises, preferably after the surface treatment with adhesive and softening agent a step of smoothing of the substrate, where the substrate is smoothed, in particular up to Bendsten ISO 2494 roughness values of less than approximately 50 ml/min and preferably of less than approximately 30 ml/min and indicatively around 20 ml/min, followed by a step of application of the glossy coating described previously.
- Preferably, application of the glossy coating is performed with an air-blade or smoothing-blade coating machine and is followed by a step of drying of the coating, conducted in an infrared oven and/or hot-air oven at a temperature of between approximately 100°C and approximately 180°C and with an oven time of between 0.5 and 4 minutes.
- Finally, the method comprises a step of mechanical treatment of the surface provided with the coating, in particular a smoothing step and/or an embossing step.
- It then remains understood that modifications and variations may be made to the paper material and to the corresponding manufacturing method described and illustrated herein, without thereby departing from the scope of the invention as defined in the annexed claims.
Claims (18)
- A silk-effect paper material, comprising a substrate, formed by a mixture of cellulose fibres and fibres with a base of natural and/or synthetic silk and containing at least one polymeric substance, apt to bestow strength on the mixture of fibres, and an inorganic filler; and having at least one surface treated with at least one surface adhesive and one softening agent so that the paper material has a silk-like feel,
wherein the mixture of fibres contains up to approximately 10% of fibres with a base of natural and/or synthetic silk with respect to the total of the fibres,
wherein the treated surface is provided with a glossy coating formed by one or more binding polymers and/or waxes, mixed with pigments. - The paper material according to Claim 1, wherein the polymeric substance included in the substrate comprises one or more colophony-based and/or epichlorohydrin-based resins, and/or modified starches.
- The paper material according to any one of the preceding claims, wherein the inorganic filler is a mineral filler and comprises one or more substances selected in the group consisting of carbonates, kaolins, talc, and mixtures thereof.
- The paper material according to any one of the preceding claims, wherein the surface adhesive is an adhesive with a base of starch and/or polyvinyl alcohol and/or acrylic, polyurethane and/or styrene-butadiene polymers.
- The paper material according to any one of the preceding claims, wherein the softening agent comprises sorbitol and/or glycerine.
- The paper material according to any one of the preceding claims, wherein the glossy coating comprises pigments with a lamellar or flat structure, such as, for example, precipitated calcium carbonate (PCC), calcined and/or lamellar kaolins, in combination with oriented and/or iridescent metal pigments with lamellar structure.
- The paper material according to any one of the preceding claims, wherein the binding polymers comprise polyurethane-based and/or silicone-based polymers.
- A method for manufacturing the paper material according to any one of the preceding claims, comprising the steps of:(a) preparing an aqueous pulp of cellulose fibres and of fibres with a base of natural and/or synthetic silk, said pulp containing at least one polymeric substance, apt to bestow strength on the mixture of fibres, and an inorganic filler;(b) removing water from the pulp to form a substrate of the paper material; and(c) treating at least one surface of the substrate with at least one surface adhesive and one softening agent in such a way as to bestow on the paper material a silk-like feel;wherein the mixture of fibres contains fibres with a base of natural and/or synthetic silk in an amount of up to approximately 10% of the total of the fibres, said method further comprising a step of applying a glossy coating to the treated surface, the glossy coating being formed by one or more binding polymers and/or waxes, mixed with pigments.
- The method according to Claim 8, wherein the polymeric substance included in the substrate comprises one or more colophony-based and/or epichlorohydrin-based resins, and/or modified starches.
- The method according to any one of Claims 8 or 9,
wherein the inorganic filler is a mineral filler and comprises one or more substances selected in the group consisting of carbonates, kaolins, talc, and mixtures thereof. - The method according to any one of Claims 8 to 10, wherein the surface adhesive is an adhesive with a base of starch and/or polyvinyl alcohol and/or acrylic, polyurethane and/or styrene-butadiene polymers.
- The method according to any one of Claims 8 to 11, wherein the softening agent comprises sorbitol and/or glycerine.
- The method according to any one of Claims 8 to 12, comprising, after the surface treatment with adhesive and softening agent, a step of smoothing the substrate, wherein the substrate is smoothed up to Bendsten ISO 2494 roughness values of less than approximately 50 ml/min, preferably of less than approximately 30 ml/min, and indicatively around 20 ml/min.
- The method according to any of claims 8 to 13, wherein the coating comprises pigments with a lamellar or flat structure, such as, for example, precipitated calcium carbonate (PCC), calcined and/or lamellar kaolins, in combination with oriented and iridescent metal pigments with lamellar structure.
- The method according to any of claims 8 to 14, wherein the binding polymers comprise polyurethane-based and/or silicone-based polymers.
- The method according to any one of Claims 8 to 15, wherein the step of application of the glossy coating is performed with an air-blade or smoothing-blade coating machine.
- The method according to any one of Claims 8 to 16, comprising a step of drying of the coating, conducted in an infrared oven and/or hot-air oven at a temperature of between approximately 100°C and approximately 180°C and with an oven time of between approximately 0,5 and approximately 4 minutes.
- The method according to any one of Claims 8 to 17, comprising a step of mechanical treatment of the surface provided with the glossy coating, in particular a smoothing step and/or an embossing step.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000778A ITMI20110778A1 (en) | 2011-05-06 | 2011-05-06 | PAPER MATERIAL WITH SILK-EFFECT AND RELATIVE PROCESS OF MANUFACTURING |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2520710A1 EP2520710A1 (en) | 2012-11-07 |
EP2520710B1 true EP2520710B1 (en) | 2014-07-30 |
Family
ID=44357995
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12167033.5A Active EP2520710B1 (en) | 2011-05-06 | 2012-05-07 | Silk-effect paper material and corresponding manufacturing method |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2520710B1 (en) |
ES (1) | ES2519642T3 (en) |
IT (1) | ITMI20110778A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1499213B1 (en) | 2002-04-24 | 2006-03-15 | SKG Italia S.p.A. | Tooth-cleaning device |
US9777143B2 (en) | 2014-04-11 | 2017-10-03 | Georgia-Pacific Consumer Products Lp | Polyvinyl alcohol fibers and films with mineral fillers and small cellulose particles |
US9777129B2 (en) | 2014-04-11 | 2017-10-03 | Georgia-Pacific Consumer Products Lp | Fibers with filler |
IT201800002977A1 (en) * | 2018-02-23 | 2019-08-23 | Gruppo Cordenons Spa | Stratified paper material with high mechanical resistance and relative production method |
CA3241551A1 (en) * | 2021-12-28 | 2023-07-06 | Luca Monacelli | Paper material with virucidal, biocidal and barrier properties to water, fats and oils |
IT202200010112A1 (en) * | 2022-05-16 | 2023-11-16 | Gruppo Cordenons Spa | PAPER MATERIAL IN SHEET WITH TACTILE EFFECT SIMILAR TO PLASTIC AND RELATED PRODUCTION METHOD |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5334286A (en) * | 1993-05-13 | 1994-08-02 | The Procter & Gamble Company | Tissue paper treated with tri-component biodegradable softener composition |
JP3454997B2 (en) * | 1995-12-06 | 2003-10-06 | 河野製紙株式会社 | Hydrolytic paper having moisture retention and method for producing the same |
US6017418A (en) * | 1996-12-23 | 2000-01-25 | Fort James Corporation | Hydrophilic, humectant, soft, pliable, absorbent paper and method for its manufacture |
US6607637B1 (en) * | 1998-10-15 | 2003-08-19 | The Procter & Gamble Company | Soft tissue paper having a softening composition containing bilayer disrupter deposited thereon |
EP1659218A1 (en) * | 2004-11-19 | 2006-05-24 | The Procter & Gamble Company | A tissue paper with silk fibers |
-
2011
- 2011-05-06 IT IT000778A patent/ITMI20110778A1/en unknown
-
2012
- 2012-05-07 EP EP12167033.5A patent/EP2520710B1/en active Active
- 2012-05-07 ES ES12167033.5T patent/ES2519642T3/en active Active
Also Published As
Publication number | Publication date |
---|---|
ITMI20110778A1 (en) | 2012-11-07 |
EP2520710A1 (en) | 2012-11-07 |
ES2519642T3 (en) | 2014-11-07 |
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