EP2505562B1 - Method for manufacturing glass substrate, and stirring device - Google Patents
Method for manufacturing glass substrate, and stirring device Download PDFInfo
- Publication number
- EP2505562B1 EP2505562B1 EP11838022.9A EP11838022A EP2505562B1 EP 2505562 B1 EP2505562 B1 EP 2505562B1 EP 11838022 A EP11838022 A EP 11838022A EP 2505562 B1 EP2505562 B1 EP 2505562B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- molten glass
- shaft
- plates
- ancillary
- chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000003756 stirring Methods 0.000 title claims description 136
- 239000011521 glass Substances 0.000 title claims description 70
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 239000000758 substrate Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title description 2
- 239000006060 molten glass Substances 0.000 claims description 317
- 239000000463 material Substances 0.000 claims description 36
- 238000002844 melting Methods 0.000 claims description 16
- 230000008018 melting Effects 0.000 claims description 16
- 230000001174 ascending effect Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 description 29
- 238000011144 upstream manufacturing Methods 0.000 description 28
- 206010040925 Skin striae Diseases 0.000 description 16
- 230000004048 modification Effects 0.000 description 16
- 238000012986 modification Methods 0.000 description 16
- 230000000694 effects Effects 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 230000002093 peripheral effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000004973 liquid crystal related substance Substances 0.000 description 3
- 229910000575 Ir alloy Inorganic materials 0.000 description 2
- 229910001260 Pt alloy Inorganic materials 0.000 description 2
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003292 diminished effect Effects 0.000 description 2
- 238000003280 down draw process Methods 0.000 description 2
- 230000003090 exacerbative effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/235—Heating the glass
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D27/00—Stirring devices for molten material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/07—Stirrers characterised by their mounting on the shaft
- B01F27/072—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis
- B01F27/0722—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis perpendicular with respect to the rotating axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/07—Stirrers characterised by their mounting on the shaft
- B01F27/072—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis
- B01F27/0724—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis directly mounted on the rotating axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/112—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades
- B01F27/1123—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades sickle-shaped, i.e. curved in at least one direction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/112—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades
- B01F27/1125—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades with vanes or blades extending parallel or oblique to the stirrer axis
- B01F27/11251—Stirrers characterised by the configuration of the stirrers with arms, paddles, vanes or blades with vanes or blades extending parallel or oblique to the stirrer axis having holes in the surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/19—Stirrers with two or more mixing elements mounted in sequence on the same axis
- B01F27/191—Stirrers with two or more mixing elements mounted in sequence on the same axis with similar elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/50—Pipe mixers, i.e. mixers wherein the materials to be mixed flow continuously through pipes, e.g. column mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B18/00—Shaping glass in contact with the surface of a liquid
- C03B18/02—Forming sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/18—Stirring devices; Homogenisation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/18—Stirring devices; Homogenisation
- C03B5/187—Stirring devices; Homogenisation with moving elements
Definitions
- the present invention relates to a method of manufacturing a glass substrate, and to a stirring device.
- the glass material is heated to produce molten glass, and the molten glass so produced is formed to manufacture glass articles such as plate glass.
- striae may form in the glass articles. Striae are zones of striated appearance differing in refractive index and/or specific gravity from the surrounding area; in optical components such as lenses, substrates for liquid crystal displays (LCD), and other such applications, there is a need to rigorously eliminate them from the glass articles.
- optical components such as lenses, substrates for liquid crystal displays (LCD), and other such applications
- a typical stirring device is provided with a chamber of round cylindrical shape, and a stirrer.
- the stirrer has a shaft serving as a rotation axis, and blades connected to the side wall of the shaft.
- the molten glass is introduced into the chamber in which the stirrer is disposed, and the molten glass is stirred by the blades, rendering the molten glass homogeneous.
- Patent Document 1 Japanese Unexamined Patent Application Publication S63-8226 discloses a stirrer having a shaft serving as a rotation axis, and blades connected to the side wall of the shaft.
- the blades of the stirrer disclosed in Patent Document 1 are inclined with respect to the stirrer axis, and thereby create a flow of the molten glass towards the upward direction or downward direction of the chamber, enhancing the stirring effect.
- Patent Document 2 Japanese Unexamined Patent Application Publication S58-88126 likewise discloses a stirrer having a shaft serving as a rotation axis, and blades connected to the shaft so that the faces thereof are inclined in the circumferential direction (rotation direction) of the shaft.
- This shaft is provided with several tiers of blades in the lengthwise direction of the shaft, with blades of adjacent tiers inclined in opposite directions. Between the blades of adjacent tiers, there arise two glass flows, i.e., glass flow arising from downward pushing of the molten glass, and glass flow arising from upward pushing of the molten glass, and these flows collide. It is conceivable that higher stirring effect can be obtained, as compared with a case in which the molten glass flows in one direction only.
- US 2003 101 750 A1 discloses a method of manufacturing a glass substrate, comprising a melting step for melting a glass material and obtaining molten glass; a stirring step for stirring, inside a stirred tank, the molten glass obtained in the melting step; and a forming step for forming a glass substrate from the molten glass stirred in the stirring step;
- the stirred tank comprises a chamber for directing the molten glass downward from above or upward from below, and a stirrer for stirring the molten glass inside the chamber;
- the stirrer has a shaft serving as a rotation axis disposed along the vertical direction, and blades disposed on a side wall of the shaft, in a plurality of tiers from the uppermost tier to the lowermost tier along the axial direction of the shaft; the blades have support plates extending orthogonally to the axial direction of the shaft, and ancillary plates disposed on a principal surface of the support plates; and in the stirring step, the stirrer rotates about the
- a method of manufacturing a glass substrate according to the present invention is as defined in claim 1.
- rotation of the stirrer causes the molten glass inside the chamber to be raked towards the shaft by the ancillary plates, or pushed towards the inner wall of the chamber.
- flow in the radial direction of the shaft arises in the molten glass.
- the molten glass is moved in the radial direction of the shaft (the outside direction and the inside direction) while being directed downward from above or upward from below inside the chamber. Consequently, with this method of manufacturing a glass substrate, the molten glass can be stirred more homogeneously, without the need for a complex configuration.
- the stirring device according to the present invention is as deefined in claim 5.
- this stirring device by rotating the stirrer, the molten glass inside the chamber is raked towards the shaft by the ancillary plates, or pushed towards the inner wall of the chamber. Specifically, flow in the radial direction of the shaft arises in the molten glass. In so doing, the molten glass is moved in the radial direction of the shaft (the outside direction and the inside direction) while being directed downward from above or upward from below inside the chamber. Consequently, this stirring device can stir molten glass more homogeneously.
- the method of manufacturing a glass substrate and the stirring device according to the present invention can stir molten glass more homogeneously.
- FIG. 1 is a generic view showing an example of a configuration of a glass manufacturing device 200.
- the glass manufacturing device 200 is provided with a melting tank 40; a fining tank 41; a stirring device 100; a forming device 42; and conduits 43a, 43b, 43c connecting these.
- Molten glass 7 produced in the melting tank 40 flows through the conduit 43a and into the fining tank 41; after fining in the fining tank 41 flows through the conduit 43b and into the stirring device 100; and after being stirred homogeneously in the stirring device 100, flows through the conduit 43c and into the forming device 42, where a glass ribbon 44 is formed by a downdraw method.
- Heating means such as a burner or the like (not shown) is arranged in the melting tank 40, so that a glass material can be melted to obtain the molten glass 7.
- the glass material may be adjusted appropriately to obtain the desired glass.
- the glass material may be prepared so as to obtain glass having substantially the following composition, expressed as mass percent. SiO 2 57-65% Al 2 O 3 15-19% B 2 O 3 8-13% MgO 1-3% CaO 4-7% SrO 1-4% BaO 0-2% Na 2 O 0-1% K 2 O 0-1% As 2 O 3 0-1% Sb 2 O 3 0-1% SnO 2 0-1% Fe 2 O 3 0-1% ZrO 2 0-1%
- substantially means that the presence of trace amounts of components within a range of less than 0.1 mass% is permissible. Consequently, it is permissible for the glass having the aforedescribed composition to have admixed therein trace amounts of other components, within a range of less than 0.1 mass%.
- the proportions of Fe 2 O 3 , As 2 O 3 , Sb 2 O 3 , and SnO 2 in the aforedescribed composition are values derived through conversion, treating all of the components Fe, As, Sb, or Sn having plural valence as Fe 2 O 3 , As 2 O 3 , Sb 2 O 3 , or SnO 2 .
- the glass material prepared in the aforedescribed manner is charged to the melting tank 40.
- the melting tank 40 melts the glass material at a temperature set according to the composition thereof, to obtain molten glass 7 at a temperature of 1500°C or above, for example.
- the molten glass 7 obtained in the melting tank 40 passes from the melting tank 40 through the conduit 43a and flows into the fining tank 41.
- Heating means (not shown) comparable to that of the melting tank 40 is arranged in the fining tank 41.
- the fining tank 41 further raises the temperature of the molten glass 7 to bring about fining.
- the temperature of the molten glass 7 is raised to 1550°C or above, and further to 1600°C or above. Fining of the molten glass 7 is brought about by the rise in temperature.
- the fined molten glass 7 in the fining tank 41 passes from the fining tank 41 through the conduit 43b and flows into the stirring device 100. During passage through the conduit 43b, the molten glass 7 cools, and in the stirring device 100 is stirred at a lower temperature than in the fining tank 41.
- stirring is preferably performed with the temperature of the molten glass set to within the range of 1400°C-1550°C, and with the viscosity of the molten glass adjusted to within the range of 2500 poise-450 poise.
- the molten glass 7 is stirred and homogenized in the stirring device 100.
- the molten glass 7 having been homogenized by the stirring device 100 passes from the stirring device 100 through the conduit 43c and flows into the forming device 42. During passage through the conduit 43c, the molten glass 7 cools, cooling to a temperature suitable for forming (for example, 1200°C). In the forming device 42, the molten glass 7 is formed by the downdraw method. The molten glass 7 flowing into the forming device 42 spills out over the top of the forming device 42 and flows downward along the side wall of the forming device 42. A continuous glass ribbon 44 is formed thereby. The glass ribbon 44 is cooled slowly as it moves downward, and finally is cut into plate glass of the desired size.
- a temperature suitable for forming for example, 1200°C
- FIG. 2 is a side view showing an example of a configuration of the stirring device 100.
- the stirring device 100 is provided with a chamber 101, and a stirrer 102 housed inside the chamber 101.
- the chamber 101 is cylindrical in shape, and communicates with an upstream conduit 103 arranged at the upper side wall, and a downstream conduit 104 arranged at the lower side wall.
- the molten glass 7 flows into the chamber 101 in the horizontal direction from the upstream conduit 103, is directed from above to below in the vertical direction inside the chamber 101, and flows out in the horizontal direction from the inside of the chamber 101 to the downstream conduit 104.
- the stirrer 102 is provided with a shaft 105 of cylindrical post shape adapted for axial rotation; and blades 106a, 106b, 106c, 106d, 106e connected to the side wall of the shaft 105.
- the shaft 105 is disposed inside the chamber 101, such that the rotation axis thereof lies along the vertical direction.
- the blades 106a to 106e are disposed in order at equidistant intervals from above to below along the axial direction (direction of the rotation axis) of the shaft 105.
- the blades 106a to 106e are disposed in five tiers along the axial direction of the shaft 105.
- FIGS. 3 to 6 the configuration of the blades 106a to 106e will be described with reference to FIGS. 3 to 6 .
- the blades 106a, 106c, and 106e have mutually identical shape
- the blades 106b and 106d have mutually identical shape.
- FIG. 3 and FIG. 4 are, respectively, a perspective view and a plan view of the blades 106a, 106c, and 106e, when viewed along the rotation axis of the shaft 105.
- FIG. 5 and FIG. 6 are, respectively, a perspective view and a plan view of the blades 106b and 106d, when viewed along the rotation axis of the shaft 105.
- the blades 106a to 106e are arranged radially towards the outside in the radial direction of the shaft 105.
- Each of the blades 106a to 106e is composed of three support plates 108 orthogonal to the axial direction of the shaft 105; one upper ancillary plate 119a disposed on the upper principal surface of each support plate 108; and one lower ancillary plate 119b disposed on the lower principal surface of each support plate 108.
- the upper ancillary plates 119a and the lower ancillary plates 119b shall be referred to collectively as the ancillary plates 109.
- the three support plates 108 are directly connected to the side wall of the shaft 105 at three symmetrical positions with respect to the rotation axis of the shaft 105.
- Each support plate 108 is connected to the shaft 105 such that the normal line of the principal surface thereof lies along the axial direction of the shaft 105.
- each support plate 108 is disposed on the horizontal.
- the three support plates 108 of each of the blades 106a to 106e are connected to one another by linking portions 110 along the periphery of the shaft 105.
- the three support plates 108 are substantially configured as a single part.
- the three support plates 108 are arranged radially from the shaft 105 towards the inside wall of the chamber 101; and are disposed such that, when the support plates 108 of the blades 106a to 106e disposed in two adjacent tiers are respectively projected onto the bottom face of the chamber 101, the gaps between the first support plates 108 and the other support plates 108 are small.
- the support plates 108 of two blades 106a to 106e adjacently situated along the axial direction of the shaft 105 are disposed so with no mutual overlap, when viewed along the rotation axis of the shaft 105. As an example, FIG.
- FIG. 7 represents the positional relationship of the blade 106a and the blade 106b, when the stirrer 102 is seen in top view along the rotation axis of the shaft 105.
- the support plates 108 of the blade 106a are disposed to be positioned between the support plates 108 of the blade 106b.
- the six support plates 108 of the blade 106a and the blade 106b are disposed at six symmetrical positions with respect to the rotation axis of the shaft 105.
- the ancillary plates 109 are disposed on principal surfaces of the support plates 108, such that the principal surfaces thereof are perpendicular to the principal surfaces of the support plates 108.
- the ancillary plates 109 are disposed on the upper principal surface and lower principal surface of the support plates 108.
- the upper ancillary plates 119a are disposed on the upper principal surfaces of the support plates 108
- the lower ancillary plates 119b are disposed on the lower principal surfaces of the support plates 108.
- the lower ancillary plates 119b are shown by broken lines.
- each ancillary plate 109 is disposed towards the outside peripheral rim of the support plates 108 from the shaft 105.
- each ancillary plate 109 has an inside edge 109a which is the edge on the side closest to the shaft 105, and an outside edge 109b which is the edge situated at the opposite side from the inside edge 109a and on the side closest to the outside peripheral rim of the support plate 108.
- Each ancillary plate 109 is disposed such that, moving from the inside edge 109a towards the outside edge 109b, the principal surfaces thereof diverge from a straight line 111 connecting the inside edge 109a and a center point 113 where the rotation axis of the shaft 105 is positioned.
- the upper ancillary plates 119a are arranged such that the principal surfaces thereof diverge from the straight lines 111 in the counterclockwise direction
- the lower ancillary plates 119b are arranged such that the principal surfaces thereof diverge from the straight lines 111 in the clockwise direction.
- the blades 106b and 106d when the stirrer 102 is seen in top view as shown in FIG.
- the upper ancillary plates 119a are arranged such that the principal surfaces thereof diverge from the straight lines 111 in the clockwise direction, while the lower ancillary plates 119b are arranged such that the principal surfaces thereof diverge from the straight lines 111 in the counterclockwise direction.
- the upper ancillary plates 119a and the lower ancillary plates 119b are arranged to extend in mutually opposite directions. Pairs of ancillary plates 109 between two of the blades 106a to 106e that are situated adjacently along the rotation axis of the shaft 105 are arranged with the principal surfaces thereof diverging from the straight lines 111, in the same direction as one another.
- the lower ancillary plates 119b of the blade 106a and the upper ancillary plates 119a of the blade 106b are arranged such that the principal surfaces thereof diverge from the straight lines 111 in the clockwise direction.
- the ancillary plates 109 are disposed such that the connecting portion of the principal surface thereof to the principal surface of the support plate 108 is not positioned in an edge of the support plate 108. Specifically, when the blades 106a to 106e are viewed along the rotation axis of the shaft 105, the ancillary plates 109 are arranged at positions away from the outside peripheral rim of the support plates 108, except for the inside edge 109a and outside edge 109b.
- FIG. 8 is a diagram depicting flows of molten glass 7 in the stirring device 100.
- the molten glass 7 flows in from the upstream conduit 103 in the horizontal direction.
- the upper end of the shaft 105 of the stirrer 102 is linked to an external motor or the like, and the stirrer 102 rotates counterclockwise as seen from above, with the shaft 105 as the rotation axis.
- the molten glass 7 is stirred by the stirrer 102 while being gradually directed from towards the bottom from the top.
- the stirred molten glass 7 flows out from inside the chamber 101 in the horizontal direction and into the downstream conduit 104.
- the molten glass 7 is stirred by rotation of the blades 106a to 106e about the shaft 105 as the rotation axis.
- the ancillary plates 109 in each of the blades 106a to 106e rake the molten glass 7 towards the shaft 105 from the inner wall of the chamber 101, and also push it from the shaft 105 towards the inner wall of the chamber 101.
- either the upper ancillary plates 119a or the lower ancillary plates 119b rake the molten glass 7 towards the shaft 105 from the inner wall of the chamber 101, while the others push the molten glass 7 from the shaft 105 towards the inner wall of the chamber 101.
- the flows of the molten glass 7 in the radial direction of the shaft 105 are mutually opposite.
- the lower ancillary plates 119b of the blade positioned in the upper tier, and the upper ancillary plates 119a positioned in the lower tier diverge in the same direction from the straight lines 111 at the principal surfaces thereof. Therefore, the flows of the molten glass 7 in the radial direction of the shaft 105 produced by a pair of mutually opposed ancillary plates 109 will share the same direction.
- the upper ancillary plates 119a of the blade 106a positioned in the uppermost tier of the shaft 105 create a flow raking the molten glass 7 from the inner wall of the chamber 101 towards the shaft 105. Because of this, the lower ancillary plates 119b of the blade 106a and the upper ancillary plates 119a of the blade 106b positioned one tier below create a flow pushing the molten glass 7 from the shaft 105 towards the inner wall of the chamber 101.
- the lower ancillary plates 119b of the blade 106b and the upper ancillary plates 119a of the blade 106c create a flow raking the molten glass 7 from the inner wall of the chamber 101 towards the shaft 105.
- the lower ancillary plates 119b of the blade 106e positioned in the lowermost tier then create a flow pushing the molten glass 7 from the shaft 105 towards the inner wall of the chamber 101.
- the molten glass 7 flows in the direction of the arrow 124 shown in FIG. 8 .
- the upper ancillary plates 119a of the blade 106a create a flow moving the molten glass 7 from the inner wall of the chamber 101 towards the shaft 105.
- the upper ancillary plates 119a of the blade 106a further give rise to ascending flow of the molten glass 7 along the side wall of the shaft 105.
- the molten glass 7 having risen into proximity with the liquid level of the molten glass 7 flows towards the inner wall of the chamber 101 from the shaft 105, and then descends along the inner wall of the chamber 101.
- the molten glass 7 forms a circulating flow 123 as shown in FIG. 8 .
- the molten glass 7 in the upper space 121 is stirred by this circulating flow 123.
- the stirring device 100 through axial rotation of the stirrer 102, between any two adjacent blades 106a to 106e, the molten glass 7 flowing into the chamber 101 from the upstream conduit 103 is raked from the inner wall of the chamber 101 towards the shaft 105, or pushed from the shaft 105 towards the inner wall of the chamber 101.
- the flow of the molten glass 7 in the radial direction of the shaft 5 switches between opposite directions in each of the tiers, going from the downward from above inside the chamber 101.
- the molten glass 7 is stirred by alternating movement in the radial direction of the shaft 5, while being directed from the top towards the bottom inside the chamber 101.
- the stirring device 100 can more homogeneously stir the molten glass 7, without the need to provide a complex configuration. For this reason, the occurrence of striae can be minimized, and a high-quality glass product can be obtained.
- the ancillary plates 109 are arranged on the upper principal surfaces and the lower principal surfaces of the support plates 108 in each of the blades 106a to 106e.
- the molten glass 7 flowing inside the chamber 101 is imparted by the ancillary plates 109 with motion in the radial direction of the shaft 105.
- the molten glass 7 in proximity to the support plates 108 is raked or pushed by the ancillary plates 109, and thereby moves in the radial direction along the principal surfaces of the support plates 108.
- the molten glass 7 moves in the radial direction along the principal surfaces of the support plates 108, both with respect to raking and to pushing movement in the radial direction. In so doing, the molten glass 7 is sufficiently stirred by the ancillary plates 109 in each of the blades 106a to 106e.
- the stirring device 100 can more homogeneously stir the molten glass 7, without the need to provide a complex configuration. For this reason, the occurrence of striae can be minimized, and a high-quality glass product can be obtained.
- the upper ancillary plates 119a of the blade 106a positioned in the uppermost tier of the shaft 105 gives rise to flow raking the molten glass 7 from the inner wall of the chamber 101 towards the shaft 105.
- an ascending flow of the molten glass 7 forms at the periphery of the shaft 105, and a descending flow of the molten glass 7 forms along the inner wall of the chamber 101.
- the circulating flow 123 shown in FIG. 8 is thereby formed in the upper space 121 of the molten glass 7.
- the configuration were not one with the blade 106a positioned in the uppermost tier of the shaft 105 rakes the molten glass 7 in the radial direction, for example, in the case of a configuration in which the support plates 108 are not provided with the ancillary plates 109, or in the case of a configuration in which the direction of rotation of the stirrer 102a is the opposite direction from that in the present embodiment, so that the molten glass 7 is pushed in the radial direction, the molten glass 7 above the blade 106a positioned in the uppermost tier would be pushed in the radial direction by the ancillary plates 109 and/or by the centrifugal force received by the support plates 108, thereby pushing it from the shaft 105 towards the inner wall of the chamber 101.
- the pushed molten glass 7 would ascend along the inner wall of the chamber 101 and flow into the upper space 121.
- the molten glass 7 pushed in the radial direction, in the course of movement thereof along the inner wall of the chamber 101, would be directed toward the top of the chamber 101 which is the direction in which it more readily flows, and thereafter reach the liquid level of the molten glass 7.
- the molten glass 7 reaching the liquid level of the molten glass 7 along the inner wall of the chamber 101 would then be directed across the liquid level towards the shaft 105 from the inner wall of the chamber 101, ultimately forming a flow directed along the shaft 105 and towards the bottom of the chamber 101.
- the stirring device 100 can stir the molten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained.
- the molten glass 7 is pushed from the shaft 105 towards the inner wall of the chamber 101.
- the lower ancillary plates 119b of the blade 106e give rise in the molten glass 7 to flow towards the outside in the radial direction of the shaft 105 (arrow 124 in FIG. 8 ), so as to accelerate outflow of molten glass 7 into the downstream conduit 104.
- the upper ancillary plates 119a of the blade 106e and the lower ancillary plates 119b of the blade 106d positioned one tier above the blade 106e give rise in the molten glass 7 to flow towards the inside in the radial direction of the shaft 105, so as to minimize the outflow of molten glass 7 into the downstream conduit 104.
- the stirred molten glass 7 flows out into the downstream conduit 104 from the lower space 122, whereby stagnation of the molten glass 7 in the bottom part inside the chamber 101 can be minimized.
- the stagnated molten glass 7 might include heterogeneous material in which the compositional components are out of balance with respect to the composition of the molten glass 7 flowing inside the chamber 101.
- Such molten glass 7 stagnating in the bottom part inside the chamber 101 might include heterogeneous material such as a zirconia-rich layer of nonhomogeneous composition, or the like.
- molten glass 7 containing heterogeneous material flows out from the downstream conduit 104, striae may occur in the glass ribbon 44 formed by the forming device 42, posing a risk of problems in terms of product quality. Also, if the molten glass 7 including heterogeneous material in which zirconia has become concentrated to high concentration due to stagnation should flow to the forming device 42 in a subsequent step, this may cause devitrification to occur in the forming device 42, so that not only do quality problems arise, but stable operation becomes difficult, and in a worst case scenario, the operation must be halted to perform maintenance.
- outflow of the molten glass 7 into the downstream conduit 104 from the space above the lower space 122 is minimized.
- the molten glass 7 in the lower space 122 is constantly replenished by the molten glass 7 above, thereby minimizing stagnation of the molten glass 7 in the bottom part inside the chamber 101.
- the molten glass 7 is stirred in a reliable manner in each tier, without short-cutting through tiers of the spaces between adjacent support plates 108. Situations in which insufficiently stirred molten glass 7 flows out from the stirring device 100 can be minimized thereby.
- the upstream conduit 103 is disposed in the vicinity of the heightwise position of the blade 106a positioned in the uppermost tier.
- the heightwise position of the blade 106a positioned in the uppermost tier set to be separated by a predetermined distance from the liquid level of the molten glass 7. If the heightwise position of the blade 106a is close to the liquid level, when the liquid level of the molten glass 7 is vibrated by the rotation of the stirrer 102, bubbles and the like floating on the liquid level are readily drawn into the molten glass 7.
- the heightwise position of the blade 106a with respect to the liquid level of the molten glass 7 is determined appropriately, depending on the rotation speed of the stirrer 102 and/or the size of the blades 106a to 106e.
- the flow rate of the molten glass 7 is set in such a way that the liquid level of the molten glass 7 is positioned in the vicinity of the apical part of the upstream conduit 103; and the support plates of the blade 106a are arranged in the lower side of the center of the diameter of the upstream conduit 103.
- the support plates of the blade 106a are arranged at a heightwise position about the same as that of the bottom part of the upstream conduit 103.
- the upper ancillary plates 119a of the blade 106a positioned in the uppermost tier give rise in the molten glass 7 to flow in the radial direction of the shaft 105 (the arrow to the lower side of the circulating flow 123 in FIG. 8 ), so as to accelerate inflow of the molten glass 7 from the upstream conduit 103.
- the stirring device 100 can stir the molten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained.
- the support plates 108 of the any two of the blades 106a to 106e situated adjacently along the rotation axis of the shaft 105 are disposed without mutual overlap, when viewed along the rotation axis of the shaft 105.
- the support plates 108 of the blade 106a are disposed so as to be positioned between two support plates 108 of the blade 106b. For this reason, flow of the molten glass 7 in the axial direction of the shaft 105 (the vertical direction) inside the chamber 101 is inhibited, and the residence time of the molten glass 7 inside the chamber 101 is increased.
- the molten glass 7 in the upper space 121 is made to descend rapidly along the side wall of the shaft 105, and situations of outflow from the downstream conduit 104 in a state of insufficient stirring can be minimized.
- the stirring device 100 can stir the molten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained.
- the ancillary plates 109 in each of the blades 106a to 106e are arranged at positions away from the outside peripheral rims of the support plates 108, except for their inside edge 109a and outside edge 109b.
- the molten glass 7 flowing vertically downward in along the principal surfaces of the upper ancillary plates 109a of the blades 106a to 106e readily collides with the principal surfaces at the upper sides of the support plates 108, and the molten glass 7 flowing vertically upward along the principal surfaces of the lower ancillary plates 109a of the blades 106a to 106e readily collides with the principal surfaces at the lower sides of the support plates 108, whereby movement of the molten glass 7 in the upward and downward directions inside the chamber 101 is minimized.
- the support plates 108 have an initial damming action on the molten glass 7 flowing downward from above or upward from below, inside the chamber 101.
- the molten glass 7 is sufficiently stirred by the ancillary plates 109 of the blades 106a to 106e, and a molten glass 7 short path does not arise.
- the stirring device 100 can stir the molten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained.
- the three support plates 108 in each of the blades 106a to 106e of the stirrer 102 are connected to one another by the linking portions 110 at the periphery of the shaft 105, and therefore constitute substantially one component. For this reason, the strength of the blades 106a to 106e can be improved. Due to the minimal stirring effect at the periphery of the shaft 105, around the shaft 105, the molten glass 7 tends to descend inside the chamber 101 without being stirred. In the present embodiment, descending flow of the molten glass 7 around the shaft 105 can be minimized by the linking portions 110 in each of the blades 106a to 106e.
- the stirring device 100 can stir the molten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained.
- the blades 106a to 106e are disposed in five tiers on the shaft 105, but the number of tiers of the blades 106a to 106e may be determined appropriately in consideration of the size of the chamber 101, and/or the length of the shaft 105, and so on. Likewise, the spacing between two of the blades 106a to 106e situated adjacently along the shaft 105 may be determined appropriately in consideration of the size of the chamber 101, and so on.
- each of the blades 106a to 106e have three support plates 108, but may instead have two, or four or more, support plates 108.
- each of the blades 106a to 106e is constituted by four support plates 108
- the positions of the support plates 108 of adjacent blades 106a to 106e may differ from one another when the stirrer 102 is viewed in the axial direction of the shaft 105, in the manner taught in the present embodiment.
- Through-holes 112 may be formed in the principal surfaces of the support plates 108 in each of the blades 106a to 106e in the present embodiment.
- FIG. 9 is a plan view of a blade 106a, 106c, or 106e having through-holes 112.
- the stirrer 102 rotates about the shaft 105 as the rotation axis, a portion of the molten glass 7 will pass through the through-holes 112.
- a portion of the molten glass 7 passing through the through-holes 112 gives rise to upward or downward flow of the molten glass 7.
- bubbles included in the molten glass 7 can pass through the through-holes 112 and rise to the liquid level of the molten glass 7 in the chamber 101. Specifically, bubbles included in the molten glass 7 can be eliminated effectively.
- the stirrer 102 of the present modification example provided with through-holes 112 would be introduced into the molten glass 7 in the chamber 101, during inspection or repair of the stirrer 102, and/or during use of a new stirrer 102.
- through-holes 112 may be formed the linking portions 110 connecting the support plates 108 to one another around the shaft 105 as well.
- the chamber 101 may be provided with a mechanism for discharging the molten glass 7.
- a discharge port for discharging molten glass 7 that includes a zirconia-rich layer may be placed on the bottom face of the chamber 101, or a discharge port for discharging molten glass 7 that includes bubbles and/or a silica-rich layer may be placed on the side wall of the chamber 101.
- heterogeneous material containing a higher proportion of silica or the like, with respect to the average composition of the molten glass 7 overall is included within the molten glass 7. It is conceivable that this could happen due to irregular composition of the molten glass 7 arising in the melting step, or to volatilization of readily-volatilized components from the molten glass 7. In particular, the aforedescribed heterogeneous material is prone to arise due to volatilization of readily-volatilized components from the molten glass 7 at the liquid level of the molten glass 7.
- the circulating flow 123 of the present embodiment has arisen, notwithstanding the aforedescribed heterogeneous material, bubbles floating on the liquid level of the molten glass 7, and/or other foreign matter present on the liquid level, the molten glass 7 in proximity to the liquid level flows across the liquid level from the shaft 105 towards the inner wall of the chamber 101. Therefore, as taught in the present modification example, by placing a discharge port on an extension line of this flow, heterogeneous material and the like included in the molten glass 7 can be discharged.
- the chamber 101 may be provided with a discharge port formed by part of the inner wall of the chamber 101 protruding towards the outside in the radial direction.
- the stirring device 100 can be kept online.
- the three support plates 108 are arranged radially from the shaft 105 towards the inner wall of the chamber 101; and are disposed such that when the support plates 108 of the blades 106a to 106e disposed in two adjacent tiers are respectively projected onto the bottom face of the chamber 101, the gaps between the support plates 108 and the support plates 108 are small.
- the three support plates 108 may be disposed such that, depending on the area of the principal surface, the area of overlapping sections of the support plates 108 and the support plates 108 is small. In this case, the support plates 108 of two of the blades 106a to 106e situated adjacently along the rotation axis of the shaft 105 would be disposed in mutual partially overlapping fashion when viewed along the rotation axis of the shaft 105.
- the inside edges 109a of the ancillary plates 109 are separated from the shaft 105; however, the ancillary plates 109 may directly connect to the shaft 105 in order to improve the strength of the stirrer 102 and the blades 106a to 106e.
- the method of manufacturing a glass substrate according to the present invention is not limited to the glass compositions mentioned in the present embodiment, nor are the temperature and/or viscosity of the molten glass 7 in the stirring step limited to the aforedescribed values.
- the aforedescribed glass composition was shown to be a glass composition of alkali-free glass or low-alkali glass suited for employment in glass substrates for liquid crystals, the aforedescribed stirring step is effective for glasses containing an alkali component as well.
- the parameters of the stirring step are not limited to the aforedescribed values.
- stirring may take place at a lower temperature set for the molten glass 7, i.e., within a range of 1300°C-1400°C, and with the viscosity of the molten glass 7 adjusted to within the aforedescribed range.
- FIGS. 10 to 20 A second embodiment of a glass manufacturing device employing the method of manufacturing a glass substrate and the stirring device according to the present invention will be described employing FIGS. 10 to 20 .
- the basic configuration, operation, and characteristics of the glass manufacturing device according to the present embodiment are the same as for the glass manufacturing device according to the first embodiment.
- FIG. 10 is a side view showing an example of a configuration of a stirring device according to the present embodiment
- FIG. 11 is a perspective view showing an example of a configuration of a stirrer according to the present embodiment.
- the stirring device 100 is provided with a chamber 1, and a stirrer 2 housed inside the chamber 1.
- the chamber 1 is cylindrical in shape, and communicates with an upstream conduit (inlet pipe) 3 and a downstream conduit (outlet pipe) 4, which are arranged at the upper side wall and the lower side wall.
- the molten glass 7 flows into the chamber 1 from the upstream conduit 3, is directed from the top towards the bottom, and flows out from the chamber 1 to the downstream conduit 4.
- the stirrer 2 is provided with a shaft 5 with a cylindrical shape constituting a rotation axis; and blades 6a, 6b, 6c, 6d, 6e connected to the side wall of the shaft 5.
- the blades 6a to 6e are disposed in order, in five tiers along the axial direction of the shaft 5.
- the number of tiers of the blades 6a to 6e is not limited to five; an appropriate preferred number of tiers may be selected in consideration of the size of the chamber 1, and/or the length of the shaft 5, and so on.
- the spacing between the adjacent blades 6a to 6e along the axial direction of the shaft 5 may be adjusted for efficient stirring of the molten glass 7 in the chamber 1.
- the blades 6a to 6e are disposed extending in a radial pattern in the radial direction of the shaft 5, and in each of the tier, two of the blades 6a to 6e are arranged extending in mutually symmetrical directions with respect to the shaft 5.
- the number of blades 6a to 6e in each of the tier is not limited to two, and could be one, or three or more, for example.
- FIGS. 12 , 13, and 14 are respectively a plan view, a side view, and a perspective view showing an example of a blade configuration in the stirrer according to the present embodiment.
- FIGS. 15, 16 , and 17 are respectively a plan view, a side view, and a perspective view showing an example of another blade configuration in the stirrer according to the present embodiment.
- the blades 6a, 6c, and 6e have the configuration shown in FIGS. 12 to 14
- the blades 6b and 6d have the configuration shown in FIGS. 15 to 17 .
- the blades 6a, 6c, and 6e are identical in shape to one another, and the blades 6b and 6d are identical in shape to one another.
- the blades 6a to 6e are provided with inclined plates 8 directly connected to the shaft 5, and ancillary plates 9 arranged on principal surfaces of the inclined plates 8. Both the blades 6a, 6c, and 6e and the blades 6b and 6d have the inclined plates 8 and the ancillary plates 9, but the direction of incline and/or the disposition and others thereof differ from one another.
- FIG. 18 is a side view showing an example of the configuration of the stirrer according to the present embodiment.
- FIG. 18 is a view of the stirrer 2 along a direction perpendicular to the axial direction of the shaft 5, with the blades 6a to 6e positioned to the front of the shaft 5.
- the principal surfaces of each inclined plate 8 are inclined with respect to a plane 10 perpendicular to the axial direction of the shaft 5.
- the principal surfaces of the inclined plates 8 are flat faces, and the entirety of each principal surface is inclined with respect to the plane 10 perpendicular to the axial direction of the shaft 5; however, for example, a configuration in which only part of each of the inclined plates 8 is inclined with respect to the plane 10 is also acceptable, and the principal surfaces of the inclined plates 8 may be curved faces.
- the blades 6a, 6c, and 6e differ from the blades 6b and 6d in the direction of incline of the inclined plates 8. For this reason, the directions of the flows arising in the molten glass 7 are different from one another.
- the inclined plates 8 of the blades 6a, 6c, and 6e push the molten glass 7 downward, whereas the inclined plates 8 of the blades 6b and 6d push the molten glass 7 upward.
- the directions of the flows arising in the molten glass 7 due to the inclined plates 8 of the blades 6a to 6e differ in alternating fashion along the axial direction of the shaft 5.
- the blade 6e of the lowermost tier pushes the molten glass 7 downward when the stirrer 2 rotates in one direction about the shaft 5 as the rotation axis.
- the molten glass 7 collides with the bottom face of the chamber 1, accelerating stirring of the molten glass 7.
- the distance between the blade 6e of the lowermost tier and the bottom face of the chamber 1 may be any distance such that the downward flow of the molten glass 7 produced by the blade 6e of the lowermost tier collides with the bottom face of the chamber 1 and accelerates stirring of the molten glass 7.
- Through-holes 12 are formed in the principal surfaces of the inclined plates 8.
- the through-holes 12 are inclined with respect to the plane 10 in the same manner as the principal surfaces of the inclined plates 8, and therefore give rise to upward or downward flow in the molten glass 7 due to passage of part of the molten glass 7 through the through-holes 12.
- the directions of these upward or downward flows differ from the directions of the flows arising from upward pushing or downward pushing of the molten glass 7 by the inclined plates 8. Consequently, formation of the through-holes 12 has the effect of increasing the number of directions of flows arising in the molten glass 7.
- the ancillary plates 9 are arranged on the principal surfaces of the inclined plates 8, in such a way that the principal surfaces thereof are perpendicular to the principal surfaces of the inclined plates 8. As shown in FIGS. 12 and 15 , the two ancillary plates 9 are respectively arranged on the upper principal surface and the lower principal surface of each single inclined plate 8. In FIGS. 12 and 15 , the ancillary plates 9 arranged on the lower principal surface are shown by broken lines.
- Each of the ancillary plates 9 has an edge 9a closest to the shaft 5, and an edge 9b which is the edge on the opposite side from the edge 9a; and has a shape extending from the edge 9a to the edge 9b.
- each of the ancillary plates 9 has a shape such that, moving from the edge 9a closest to the shaft 5 towards the edge 9b on the opposite side therefrom, the principal surfaces of the ancillary plate 9 diverge from a straight line 11 connecting the edge 9a and a center point 13 which is the center of rotation of the shaft 5. Due to this shape of the ancillary plates 9, when the stirrer 2 rotates about the shaft 5 as the rotation axis, the molten glass 7 flows along the principal surfaces of the ancillary plates 9, giving rise to flow in the molten glass 7 in the radial direction of the shaft 5.
- the ancillary plates 9 have modes of raking the molten glass 7 from the inner wall of the chamber 1 towards the shaft 5, or modes of pushing from the shaft 5 towards the inner wall of the chamber 1.
- Each of the ancillary plates 9 has either of these two modes.
- the ancillary plates 9 respectively arranged on the upper and lower principal surfaces of the inclined plates 8 have mutually different modes.
- the stirrer 2 rotates in one direction about the shaft 5 as the rotation axis, of the ancillary plates 9 arranged on the upper principal surfaces and the ancillary plates 9 arranged on the lower principal surfaces of the inclined plates 8, the ancillary plates 9 on one face have a mode of raking the molten glass 7 from the inner wall of the chamber 1 towards the shaft 5, while the ancillary plates 9 on the other face have a mode of pushing the molten glass 7 from the shaft 5 towards the inner wall of the chamber 1.
- the ancillary plates 9 arranged on the upper principal surfaces of the inclined plates 8 of the blades 6a, 6c, and 6e have a mode of raking the molten glass 7 when the stirrer 2 rotates about the shaft 5 as the rotation axis in the counterclockwise direction as seen from above; whereas the ancillary plates 9 arranged on the back faces, i.e., the lower principal surfaces thereof, have a mode of pushing the molten glass 7.
- the ancillary plates 9 arranged on the upper principal surfaces of the inclined plates 8 of the blades 6b and 6d have a mode of pushing the molten glass 7 when the stirrer 2 rotates about the shaft 5 as the rotation axis in the counterclockwise direction as seen from above; whereas the ancillary plates 9 arranged on the back faces, i.e., the lower principal surfaces thereof, have a mode of raking the molten glass 7. Because the modes of the ancillary plates 9 are different for the upper principal surfaces versus the lower principal surfaces of the inclined plates 8 in this way, higher stirring effect is obtained.
- Stirring efficiency tends to decline going from the upstream side towards the downstream side of the chamber 1, and in order to minimize this, the height (length in the up and down direction) of the ancillary plates 9 positioned to the downstream side of the chamber 1 may be greater (longer) in comparison with the ancillary plates 9 positioned at the upstream side. Increasing the height of the ancillary plates 9 increases the stirring efficiency, and minimizes the decline in stirring efficiency in the downstream side.
- the height of the ancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of the inclined plates 8 of lower blades may be the same as, or higher than, the height of the ancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of the inclined plates 8 of blades positioned above those blades.
- the ratio of the height of the ancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of the blade 6a of the uppermost tier to the height of the ancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of the blade 6e of the lowermost tier is preferably 1 : 1.3.
- the height of the ancillary plates 9 arranged on each of the inclined plates 8 of the blades 6a, 6b, and 6c positioned on the upper side are equal to one another, and the heights of the ancillary plates 9 arranged on each of the inclined plates 8 of the blades 6d and 6e positioned therebelow are equal to one another, the height of the ancillary plates 9 of the blades 6d and 6e may be 1.3 times higher than the height of the ancillary plates 9 of the blades 6a, 6b, and 6c.
- the top of the chamber 1 is upstream and the bottom is downstream; however, in a case in which the bottom of the chamber 1 is upstream and the top is downstream, for mutually adjacent blades, the height of the ancillary plates arranged on the upper principal surfaces and the lower principal surfaces of the inclined plates of the blades at the top may be the same as, or greater than, the height of the ancillary plates arranged on the upper principal surfaces and the lower principal surfaces of the inclined plates of the blades positioned below these blades.
- the number of ancillary plates 9, and the modes thereof are not limited to those in the aforedescribed embodiment.
- the ancillary plates 9 may be disposed on only one of the principal surfaces of the inclined plates 8.
- the ancillary plates 9 on both principal surfaces of the inclined plates 8 may have identical modes.
- the two ancillary plates (the first ancillary plate and the second ancillary plate) 9 arranged on each of the inclined plates 8 have shapes that respectively diverge from one another moving from the edge 9a towards the edge 9b.
- the through-hole 12 is formed in the inclined plate 8 between these two ancillary plates 9.
- the mode of these two ancillary plates 9 is one of raking the molten glass 7 from the inner wall of the chamber 1 towards the shaft 5 when the stirrer 2 rotates about the shaft 5 as the rotation axis
- the molten glass 7 directed between the two ancillary plates 9 is guided through a progressively smaller gap between the two ancillary plates 9, with a portion thereof flowing through the through-hole 12 and towards the back face of the inclined plate 8, while the remainder flows upward or downward along the principal surfaces of the inclined plate 8.
- the molten glass 7 having passed through the through-hole 12 differs not only in flow direction but also in velocity from the rest of the molten glass 7, therefore giving rise to more complex flows in the molten glass 7.
- the molten glass 7 having passed through the through-hole 12 and flowed towards the back face of the inclined plate 8 is pushed from the shaft 5 towards the inner wall of the chamber 1 by the ancillary plates 9 arranged on the back face of the inclined plate 8. That is, when the molten glass 7 passes through the through-hole 12 and flows towards the back face of the inclined plate 8, the direction of flow thereof is changed to a direction different from that up to that point. For this reason, high stirring effect is obtained.
- the molten glass 7 is directed between two ancillary plates 9 having a mode for pushing the molten glass 7 from the shaft 5 towards the inner wall of the chamber 1, a portion of the molten glass 7 passes through the through-hole 12 and flows towards the back face of the inclined plate 8, while the remainder flows upward or downward along the principal surfaces of the inclined plate 8, creating flows in different directions and differing in velocity. Furthermore, the molten glass 7 having passed through the through-hole 12 and flowed towards the back face of the inclined plate 8 changes flow direction to a direction different from that up to that point, due to the ancillary plates 9 arranged on the back face of the inclined plate 8.
- the principal surfaces of the ancillary plates 9 are curving faces.
- the resistance that the blades 6a to 6e receive from the molten glass 7 can be lower, and less power will be needed to give rise to the intended flow in the molten glass 7.
- the principal surfaces of the ancillary plates 9 may be flat faces, or have other shapes.
- the blades 6e of the lowermost tier and the downstream conduit 4 are disposed in such a way that when an area formed between the inclined plates 8 of the blades 6e of the lowermost tier and the bottom face of the chamber 1 is hypothetically moved along a direction perpendicular to the axial direction of the shaft 5, and in a direction towards the downstream conduit 4, at least a portion of this area constitutes the boundary of the downstream conduit 4 and the chamber 1, and passes through an opening section formed in the side wall of the chamber 1.
- the ancillary plates 9 arranged on the lower principal surface of the blades 6e of the lowermost tier have a mode for pushing the molten glass 7 when the stirrer 2 rotates in one direction about the shaft 5 as the rotation axis.
- the flow arising in the molten glass 7 due to the ancillary plates 9 arranged on the lower principal surface of the blades 6e of the lowermost tier readily affects the flow of molten glass 7 flowing out to the downstream conduit 4.
- the ancillary plates 9 arranged on the lower principal surface of the blades 6e of the lowermost tier have a mode of pushing the molten glass 7 when the stirrer 2 rotates about the shaft 5 as the rotation axis
- the molten glass 7 can be directed from the shaft 5 towards the inner wall of the chamber 1, so that the molten glass 7 flows smoothly out from the chamber 1 into the downstream conduit 4. For this reason, the flow of molten glass 7 in the bottom part of the chamber 1 is smooth, and homogeneous stirring takes place.
- the upstream conduit 3 is arranged in the upper part of the chamber 1 and the downstream conduit 4 is arranged in the lower part of the chamber 1, with the molten glass 7 being directed downward from above in the chamber 1; however, there may also be employed a stirring device configured so that the molten glass 7 is directed upward from below in the chamber 1.
- a downstream conduit may be arranged on the side wall in the top part of the chamber
- a upstream conduit inlet pipe
- the configuration is comparable to the stirring device 100 according to the aforedescribed embodiment.
- FIG. 19 is a plan view showing an example of a yet another blade configuration of the stirrer according to the present embodiment.
- a blade 36 shown in FIG. 19 has an inclined plate 38 connected to the side wall of the shaft 5, and ancillary plates 39 arranged on the principal surfaces of the inclined plate 8.
- a through-hole 32 is formed in the principal surfaces of the inclined plate 38.
- an edge 39a of the ancillary plate 39 arranged towards the shaft 5 is connected to the shaft 5.
- the ancillary plate 39 By connecting the ancillary plate 39 to the shaft 5 in this way, the strength of the ancillary plate 39 and the inclined plate 38 can be improved, making it possible for the ancillary plate 39 and the inclined plate 38 to be thinner, so that the cost of the stirring device 100 can be reduced.
- the temperature of the molten glass 7 stirred by the stirring device 100 is a high temperature on the order of 1400-1600°C. Therefore, members that come into contact with the molten glass 7, such as the upstream conduit 3, the downstream conduit 4, the chamber 1, and the stirrer 2, are preferably made of materials that can withstand such high temperature. For example, these members may be made of platinum, platinum alloy, iridium, iridium alloy, or the like. However, because platinum, platinum alloy, iridium, and iridium alloy are costly, it is preferable to minimize the amounts in which these are employed.
- the inclined plates 8 and/or the ancillary plates 9 are preferably made as thin as possible, within a range of having strength such that no difficulties are encountered in stirring the molten glass 7.
- thinner inclined plates 8 and ancillary plates 9 have less resistance with the molten glass 7, and less power will be needed to give rise to the intended flow in the molten glass 7.
- reduction in the amounts used of costly materials, such as platinum may be achieved by forming platinum or the like only on those sections coming into contact with the molten glass 7. That is, multilayer structures having platinum or the like formed only on the inner wall thereof are acceptable.
- FIG. 20 is a diagram depicting flows of molten glass in the stirring device according to the present embodiment.
- Molten glass 7 flows into the chamber 1 from the upstream conduit 3. While not shown in the drawing, the upper end of the shaft 5 of the stirrer 2 is linked to a motor or the like, and the stirrer 2 rotates counterclockwise as seen from above, with the shaft 5 as the rotation axis.
- the molten glass 7 stirred by the stirrer 2 flows out from the chamber 1 and into the downstream conduit 4. Rotation of the stirrer 2 inside the chamber 1 causes the blades 6a to 6e to rotate about the shaft 5 as the rotation axis, stirring the molten glass 7.
- the modes of the inclined plates 8 differ between respective combinations of the blade 6a and the blade 6b, the blade 6b and the blade 6c, the blade 6c and the blade 6d, and the blade 6d and the blade 6e, and this gives rise in the molten glass 7 to upward or downward flows in mutually different directions.
- this reason between the blade 6a and the blade 6b, between the blade 6b and the blade 6c, between the blade 6c and the blade 6d, and between the blade 6d and the blade 6e, upward flows and downward flows arise respectively, with these flows colliding in certain sections. In these sections, complex flows arise, and the stirring effect on the molten glass 7 is high. Due to the multiple flows and the existence of sections in which these flows collide, the stirring device 100 can stir the molten glass 7 more homogeneously.
- the upstream conduit 3 and the downstream conduit 4 are respectively arranged in the upper side wall and the lower side wall of the chamber 1, and therefore the direction of flow of the molten glass 7 changes between the upper part and the lower part of the chamber 1.
- the molten glass 7 readily stagnates.
- the molten glass 7 does not readily flow at locations above the blade 6a positioned in the uppermost tier and below the blade 6e positioned in the lowermost tier, and it is conceivable that the molten glass 7 in the upper space 21 and the lower space 22 of the chamber 1 may not be sufficiently stirred, as compared with other sections.
- the inclined plates 8 of the blade 6a have a mode of pushing the molten glass 7 downward, when the stirrer 2 rotates about the shaft 5 as the rotation axis, in the counterclockwise direction as viewed from above.
- the ancillary plates 9 arranged on the upper principal surfaces of the inclined plates 8 of the blade 6a have a mode for raking the molten glass 7 from the inner wall of the chamber 1 towards the shaft 5, when the stirrer 2 rotates about the shaft 5 as the rotation axis, in the counterclockwise direction as viewed from above.
- the inclined plates 8 of the blade 6e have a mode of pushing the molten glass 7 downward, when the stirrer 2 rotates about the shaft 5 as the rotation axis, in the counterclockwise direction as viewed from above.
- the blade 6e gives rise to downward flow in the molten glass 7 in the lower space 22 of the chamber 1, and the molten glass 7 is stirred by collision with the bottom face of the chamber 1.
- the ancillary plates 9 are arranged to extend downward from the lower principal surfaces of the inclined plates 8 of the blade 6e.
- the molten glass 7 can be stirred in more homogeneous fashion. For this reason, striae can be minimized, and glass articles of high quality can be obtained.
- the inventors constructed a model of the stirring device according to the present embodiment, and performed stirring tests having parameters physically resembling those of actual operation of the stirring device.
- a transparent, high-viscosity material was employed, and a red liquid was continuously dripped therein from the upstream side of the high-viscosity material flowing into the chamber. The state of stirring could be more readily observed thereby.
- red streaks initially appeared along the flows in the high-viscosity material, but with stirring these red streaks disappeared, and the high-viscosity material turned a red color.
- the inventors performed tests employing a plurality of stirrers having different shapes, observing the state of stirring with each stirrer.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Glass Compositions (AREA)
Description
- The present invention relates to a method of manufacturing a glass substrate, and to a stirring device.
- In processes for high-volume production of glass articles such as plate glass, the glass material is heated to produce molten glass, and the molten glass so produced is formed to manufacture glass articles such as plate glass. If the molten glass is heterogeneous, striae may form in the glass articles. Striae are zones of striated appearance differing in refractive index and/or specific gravity from the surrounding area; in optical components such as lenses, substrates for liquid crystal displays (LCD), and other such applications, there is a need to rigorously eliminate them from the glass articles. Particularly in the case of glass substrates for displays, of which substrates for liquid crystal displays are representative, it is necessary to keep striae to extremely low levels throughout the entire large area of the surface. Stirring of the molten glass by a stirring device is performed in order to prevent striae. A typical stirring device is provided with a chamber of round cylindrical shape, and a stirrer. The stirrer has a shaft serving as a rotation axis, and blades connected to the side wall of the shaft. The molten glass is introduced into the chamber in which the stirrer is disposed, and the molten glass is stirred by the blades, rendering the molten glass homogeneous.
- Patent Document 1 (Japanese Unexamined Patent Application Publication
S63-8226 Patent Document 1 are inclined with respect to the stirrer axis, and thereby create a flow of the molten glass towards the upward direction or downward direction of the chamber, enhancing the stirring effect. - Patent Document 2 (Japanese Unexamined Patent Application Publication
S58-88126 -
US 2003 101 750 A1 discloses a method of manufacturing a glass substrate, comprising a melting step for melting a glass material and obtaining molten glass; a stirring step for stirring, inside a stirred tank, the molten glass obtained in the melting step; and a forming step for forming a glass substrate from the molten glass stirred in the stirring step; wherein the stirred tank comprises a chamber for directing the molten glass downward from above or upward from below, and a stirrer for stirring the molten glass inside the chamber; the stirrer has a shaft serving as a rotation axis disposed along the vertical direction, and blades disposed on a side wall of the shaft, in a plurality of tiers from the uppermost tier to the lowermost tier along the axial direction of the shaft; the blades have support plates extending orthogonally to the axial direction of the shaft, and ancillary plates disposed on a principal surface of the support plates; and in the stirring step, the stirrer rotates about the shaft as the rotation axis, whereby the ancillary plates create, in the molten glass, a flow in the radial direction of the shaft, and the ancillary plates positioned between the support plates of the blades disposed in two adjacent tiers create, in the molten glass, a flow in the same direction. - In the prior art, various stirring devices have been proposed with the object of stirring molten glass. However, these prior art stirring devices cannot be said to have sufficient capability to stir molten glass, and there exists a need for a stirring device capable of stirring molten glass in a more homogeneous manner.
- With the foregoing in view, it is an object of the present invention to provide a method of manufacturing a glass substrate and a stirring device whereby molten glass can be stirred in a more homogeneous manner.
- A method of manufacturing a glass substrate according to the present invention is as defined in
claim 1. - According to this method of manufacturing a glass substrate, rotation of the stirrer causes the molten glass inside the chamber to be raked towards the shaft by the ancillary plates, or pushed towards the inner wall of the chamber. Specifically, flow in the radial direction of the shaft arises in the molten glass. In so doing, the molten glass is moved in the radial direction of the shaft (the outside direction and the inside direction) while being directed downward from above or upward from below inside the chamber. Consequently, with this method of manufacturing a glass substrate, the molten glass can be stirred more homogeneously, without the need for a complex configuration.
- The stirring device according to the present invention is as deefined in
claim 5. - According to this stirring device, by rotating the stirrer, the molten glass inside the chamber is raked towards the shaft by the ancillary plates, or pushed towards the inner wall of the chamber. Specifically, flow in the radial direction of the shaft arises in the molten glass. In so doing, the molten glass is moved in the radial direction of the shaft (the outside direction and the inside direction) while being directed downward from above or upward from below inside the chamber. Consequently, this stirring device can stir molten glass more homogeneously.
- The method of manufacturing a glass substrate and the stirring device according to the present invention can stir molten glass more homogeneously.
-
-
FIG. 1 is a schematic showing an example of a configuration of a glass manufacturing device according to a first embodiment; -
FIG. 2 is a side view showing an example of a configuration of a stirring device according to the first embodiment; -
FIG. 3 is a perspective view of a blade of a stirrer according to the first embodiment; -
FIG. 4 is a plan view of a blade of the stirrer according to the first embodiment; -
FIG. 5 is a perspective view of a blade of the stirrer according to the first embodiment; -
FIG. 6 is a plan view of a blade of the stirrer according to the first embodiment; -
FIG. 7 is a diagram depicting the positional relationship of two blades of the stirrer according to the first embodiment; -
FIG. 8 is a diagram depicting flows of molten glass in the stirring device according to the first embodiment; -
FIG. 9 is a top view of a blade of a stirrer according to a modification example C of the first embodiment; -
FIG. 10 is a side view showing an example of a configuration of a stirring device according to a second embodiment; -
FIG. 11 is a perspective view showing an example of a configuration of a stirrer according to a second embodiment; -
FIG. 12 is a plan view showing an example of a blade configuration in the stirrer according to the second embodiment; -
FIG. 13 is a side view showing an example of a blade configuration in the stirrer according to the second embodiment; -
FIG. 14 is a perspective view showing an example of a blade configuration in the stirrer according to the second embodiment; -
FIG. 15 is a plan view showing an example of another blade configuration in the stirrer according to the second embodiment; -
FIG. 16 is a side view showing an example of another blade configuration in the stirrer according to the second embodiment; -
FIG. 17 is a perspective view showing an example of another blade configuration in the stirrer according to the second embodiment; -
FIG. 18 is a side view showing an example of the configuration of the stirrer according to the second embodiment; -
FIG. 19 is a plan view showing an example of a yet another blade configuration of the stirrer according to the second embodiment; and -
FIG. 20 is a diagram depicting flows of molten glass in the stirring device according to the second embodiment. - A first embodiment of a glass manufacturing device employing the method of manufacturing a glass substrate and the stirring device according to the present invention will be described employing
FIGS. 1 to 9 .FIG. 1 is a generic view showing an example of a configuration of aglass manufacturing device 200. Theglass manufacturing device 200 is provided with amelting tank 40; afining tank 41; astirring device 100; a formingdevice 42; andconduits Molten glass 7 produced in themelting tank 40 flows through theconduit 43a and into thefining tank 41; after fining in thefining tank 41 flows through theconduit 43b and into thestirring device 100; and after being stirred homogeneously in thestirring device 100, flows through theconduit 43c and into the formingdevice 42, where aglass ribbon 44 is formed by a downdraw method. - Heating means such as a burner or the like (not shown) is arranged in the
melting tank 40, so that a glass material can be melted to obtain themolten glass 7. The glass material may be adjusted appropriately to obtain the desired glass. For example, the glass material may be prepared so as to obtain glass having substantially the following composition, expressed as mass percent.SiO2 57-65% Al2O3 15-19% B2O3 8-13% MgO 1-3% CaO 4-7% SrO 1-4% BaO 0-2% Na2O 0-1% K2O 0-1% As2O3 0-1% Sb2O3 0-1% SnO2 0-1% Fe2O3 0-1% ZrO2 0-1% - Herein, "substantially" means that the presence of trace amounts of components within a range of less than 0.1 mass% is permissible. Consequently, it is permissible for the glass having the aforedescribed composition to have admixed therein trace amounts of other components, within a range of less than 0.1 mass%. The proportions of Fe2O3, As2O3, Sb2O3, and SnO2 in the aforedescribed composition are values derived through conversion, treating all of the components Fe, As, Sb, or Sn having plural valence as Fe2O3, As2O3, Sb2O3, or SnO2.
- The glass material prepared in the aforedescribed manner is charged to the
melting tank 40. Themelting tank 40 melts the glass material at a temperature set according to the composition thereof, to obtainmolten glass 7 at a temperature of 1500°C or above, for example. - The
molten glass 7 obtained in themelting tank 40 passes from themelting tank 40 through theconduit 43a and flows into the finingtank 41. Heating means (not shown) comparable to that of themelting tank 40 is arranged in thefining tank 41. The finingtank 41 further raises the temperature of themolten glass 7 to bring about fining. In specific terms, in thefining tank 41, the temperature of themolten glass 7 is raised to 1550°C or above, and further to 1600°C or above. Fining of themolten glass 7 is brought about by the rise in temperature. - The fined
molten glass 7 in thefining tank 41 passes from the finingtank 41 through theconduit 43b and flows into the stirringdevice 100. During passage through theconduit 43b, themolten glass 7 cools, and in thestirring device 100 is stirred at a lower temperature than in thefining tank 41. As one example of parameters for the stirring step in the case of an alkali-free glass and/or low-alkali glass as such as the aforedescribed, stirring is preferably performed with the temperature of the molten glass set to within the range of 1400°C-1550°C, and with the viscosity of the molten glass adjusted to within the range of 2500 poise-450 poise. Themolten glass 7 is stirred and homogenized in thestirring device 100. - The
molten glass 7 having been homogenized by the stirringdevice 100 passes from the stirringdevice 100 through theconduit 43c and flows into the formingdevice 42. During passage through theconduit 43c, themolten glass 7 cools, cooling to a temperature suitable for forming (for example, 1200°C). In the formingdevice 42, themolten glass 7 is formed by the downdraw method. Themolten glass 7 flowing into the formingdevice 42 spills out over the top of the formingdevice 42 and flows downward along the side wall of the formingdevice 42. Acontinuous glass ribbon 44 is formed thereby. Theglass ribbon 44 is cooled slowly as it moves downward, and finally is cut into plate glass of the desired size. -
FIG. 2 is a side view showing an example of a configuration of the stirringdevice 100. The stirringdevice 100 is provided with achamber 101, and astirrer 102 housed inside thechamber 101. Thechamber 101 is cylindrical in shape, and communicates with anupstream conduit 103 arranged at the upper side wall, and adownstream conduit 104 arranged at the lower side wall. Themolten glass 7 flows into thechamber 101 in the horizontal direction from theupstream conduit 103, is directed from above to below in the vertical direction inside thechamber 101, and flows out in the horizontal direction from the inside of thechamber 101 to thedownstream conduit 104. - The
stirrer 102 is provided with ashaft 105 of cylindrical post shape adapted for axial rotation; andblades shaft 105. Theshaft 105 is disposed inside thechamber 101, such that the rotation axis thereof lies along the vertical direction. Theblades 106a to 106e are disposed in order at equidistant intervals from above to below along the axial direction (direction of the rotation axis) of theshaft 105. Specifically, in thestirrer 102, theblades 106a to 106e are disposed in five tiers along the axial direction of theshaft 105. - Next, the configuration of the
blades 106a to 106e will be described with reference toFIGS. 3 to 6 . In the present embodiment, theblades blades FIG. 3 andFIG. 4 are, respectively, a perspective view and a plan view of theblades shaft 105.FIG. 5 andFIG. 6 are, respectively, a perspective view and a plan view of theblades shaft 105. - The
blades 106a to 106e are arranged radially towards the outside in the radial direction of theshaft 105. Each of theblades 106a to 106e is composed of threesupport plates 108 orthogonal to the axial direction of theshaft 105; one upperancillary plate 119a disposed on the upper principal surface of eachsupport plate 108; and one lowerancillary plate 119b disposed on the lower principal surface of eachsupport plate 108. Herein, the upperancillary plates 119a and the lowerancillary plates 119b shall be referred to collectively as the ancillary plates 109. - When the
blades 106a to 106e are seen in plan view, the threesupport plates 108 are directly connected to the side wall of theshaft 105 at three symmetrical positions with respect to the rotation axis of theshaft 105. Eachsupport plate 108 is connected to theshaft 105 such that the normal line of the principal surface thereof lies along the axial direction of theshaft 105. Specifically, eachsupport plate 108 is disposed on the horizontal. As shown inFIGS. 3 to 6 , the threesupport plates 108 of each of theblades 106a to 106e are connected to one another by linkingportions 110 along the periphery of theshaft 105. Specifically, the threesupport plates 108 are substantially configured as a single part. - The three
support plates 108 are arranged radially from theshaft 105 towards the inside wall of thechamber 101; and are disposed such that, when thesupport plates 108 of theblades 106a to 106e disposed in two adjacent tiers are respectively projected onto the bottom face of thechamber 101, the gaps between thefirst support plates 108 and theother support plates 108 are small. In specific terms, thesupport plates 108 of twoblades 106a to 106e adjacently situated along the axial direction of theshaft 105 are disposed so with no mutual overlap, when viewed along the rotation axis of theshaft 105. As an example,FIG. 7 represents the positional relationship of theblade 106a and theblade 106b, when thestirrer 102 is seen in top view along the rotation axis of theshaft 105. As shown inFIG. 7 , thesupport plates 108 of theblade 106a are disposed to be positioned between thesupport plates 108 of theblade 106b. Specifically, the sixsupport plates 108 of theblade 106a and theblade 106b are disposed at six symmetrical positions with respect to the rotation axis of theshaft 105. - The ancillary plates 109 are disposed on principal surfaces of the
support plates 108, such that the principal surfaces thereof are perpendicular to the principal surfaces of thesupport plates 108. The ancillary plates 109 are disposed on the upper principal surface and lower principal surface of thesupport plates 108. As mentioned previously, the upperancillary plates 119a are disposed on the upper principal surfaces of thesupport plates 108, and the lowerancillary plates 119b are disposed on the lower principal surfaces of thesupport plates 108. InFIGS. 4 and6 , the lowerancillary plates 119b are shown by broken lines. - The ancillary plates 109 are disposed towards the outside peripheral rim of the
support plates 108 from theshaft 105. Herein, each ancillary plate 109 has aninside edge 109a which is the edge on the side closest to theshaft 105, and anoutside edge 109b which is the edge situated at the opposite side from theinside edge 109a and on the side closest to the outside peripheral rim of thesupport plate 108. Each ancillary plate 109 is disposed such that, moving from theinside edge 109a towards theoutside edge 109b, the principal surfaces thereof diverge from astraight line 111 connecting theinside edge 109a and acenter point 113 where the rotation axis of theshaft 105 is positioned. In specific terms, for theblades stirrer 102 is seen in top view as shown inFIG. 4 , the upperancillary plates 119a are arranged such that the principal surfaces thereof diverge from thestraight lines 111 in the counterclockwise direction, while the lowerancillary plates 119b are arranged such that the principal surfaces thereof diverge from thestraight lines 111 in the clockwise direction. On the other hand, for theblades stirrer 102 is seen in top view as shown inFIG. 6 , the upperancillary plates 119a are arranged such that the principal surfaces thereof diverge from thestraight lines 111 in the clockwise direction, while the lowerancillary plates 119b are arranged such that the principal surfaces thereof diverge from thestraight lines 111 in the counterclockwise direction. Specifically, in each of theblades 106a to 106e, the upperancillary plates 119a and the lowerancillary plates 119b are arranged to extend in mutually opposite directions. Pairs of ancillary plates 109 between two of theblades 106a to 106e that are situated adjacently along the rotation axis of theshaft 105 are arranged with the principal surfaces thereof diverging from thestraight lines 111, in the same direction as one another. For example, the lowerancillary plates 119b of theblade 106a and the upperancillary plates 119a of theblade 106b are arranged such that the principal surfaces thereof diverge from thestraight lines 111 in the clockwise direction. - The ancillary plates 109 are disposed such that the connecting portion of the principal surface thereof to the principal surface of the
support plate 108 is not positioned in an edge of thesupport plate 108. Specifically, when theblades 106a to 106e are viewed along the rotation axis of theshaft 105, the ancillary plates 109 are arranged at positions away from the outside peripheral rim of thesupport plates 108, except for theinside edge 109a andoutside edge 109b. - The operation of the stirring
device 100 according to the present embodiment will be described with reference toFIG. 8. FIG. 8 is a diagram depicting flows ofmolten glass 7 in thestirring device 100. Inside thechamber 101, themolten glass 7 flows in from theupstream conduit 103 in the horizontal direction. The upper end of theshaft 105 of thestirrer 102 is linked to an external motor or the like, and thestirrer 102 rotates counterclockwise as seen from above, with theshaft 105 as the rotation axis. Inside thechamber 101, themolten glass 7 is stirred by thestirrer 102 while being gradually directed from towards the bottom from the top. The stirredmolten glass 7 flows out from inside thechamber 101 in the horizontal direction and into thedownstream conduit 104. - Inside the
chamber 101, themolten glass 7 is stirred by rotation of theblades 106a to 106e about theshaft 105 as the rotation axis. In specific terms, the ancillary plates 109 in each of theblades 106a to 106e rake themolten glass 7 towards theshaft 105 from the inner wall of thechamber 101, and also push it from theshaft 105 towards the inner wall of thechamber 101. In the present embodiment, in each of theblades 106a to 106e, either the upperancillary plates 119a or the lowerancillary plates 119b rake themolten glass 7 towards theshaft 105 from the inner wall of thechamber 101, while the others push themolten glass 7 from theshaft 105 towards the inner wall of thechamber 101. Specifically, above thesupport plates 108 and below thesupport plates 108 in each of theblades 106a to 106e, the flows of themolten glass 7 in the radial direction of theshaft 105 are mutually opposite. For two of theblades 106a to 106e that are situated adjacently along the rotation axis of theshaft 105, the lowerancillary plates 119b of the blade positioned in the upper tier, and the upperancillary plates 119a positioned in the lower tier, diverge in the same direction from thestraight lines 111 at the principal surfaces thereof. Therefore, the flows of themolten glass 7 in the radial direction of theshaft 105 produced by a pair of mutually opposed ancillary plates 109 will share the same direction. - As shown in
FIG. 8 , in the present embodiment, the upperancillary plates 119a of theblade 106a positioned in the uppermost tier of theshaft 105 create a flow raking themolten glass 7 from the inner wall of thechamber 101 towards theshaft 105. Because of this, the lowerancillary plates 119b of theblade 106a and the upperancillary plates 119a of theblade 106b positioned one tier below create a flow pushing themolten glass 7 from theshaft 105 towards the inner wall of thechamber 101. Similarly, the lowerancillary plates 119b of theblade 106b and the upperancillary plates 119a of theblade 106c create a flow raking themolten glass 7 from the inner wall of thechamber 101 towards theshaft 105. The lowerancillary plates 119b of theblade 106e positioned in the lowermost tier then create a flow pushing themolten glass 7 from theshaft 105 towards the inner wall of thechamber 101. Specifically, in thelower space 122 between theblade 106e positioned in the lowermost tier and the bottom face of thechamber 101, themolten glass 7 flows in the direction of thearrow 124 shown inFIG. 8 . - As shown in
FIG. 8 , in the present embodiment, through axial rotation of thestirrer 102, above thesupport plates 108 of theblade 106a positioned in the uppermost tier, the upperancillary plates 119a of theblade 106a create a flow moving themolten glass 7 from the inner wall of thechamber 101 towards theshaft 105. The upperancillary plates 119a of theblade 106a further give rise to ascending flow of themolten glass 7 along the side wall of theshaft 105. Themolten glass 7 having risen into proximity with the liquid level of themolten glass 7 flows towards the inner wall of thechamber 101 from theshaft 105, and then descends along the inner wall of thechamber 101. Specifically, in theupper space 121 between theblade 106a positioned in the uppermost tier and the liquid level of themolten glass 7, themolten glass 7 forms a circulatingflow 123 as shown inFIG. 8 . Themolten glass 7 in theupper space 121 is stirred by this circulatingflow 123. - In the
stirring device 100 according to the present embodiment, through axial rotation of thestirrer 102, between any twoadjacent blades 106a to 106e, themolten glass 7 flowing into thechamber 101 from theupstream conduit 103 is raked from the inner wall of thechamber 101 towards theshaft 105, or pushed from theshaft 105 towards the inner wall of thechamber 101. The flow of themolten glass 7 in the radial direction of theshaft 5 switches between opposite directions in each of the tiers, going from the downward from above inside thechamber 101. Specifically, themolten glass 7 is stirred by alternating movement in the radial direction of theshaft 5, while being directed from the top towards the bottom inside thechamber 101. - Consequently, the stirring
device 100 according to the present embodiment can more homogeneously stir themolten glass 7, without the need to provide a complex configuration. For this reason, the occurrence of striae can be minimized, and a high-quality glass product can be obtained. - In the
stirring device 100 according to the present embodiment, the ancillary plates 109 are arranged on the upper principal surfaces and the lower principal surfaces of thesupport plates 108 in each of theblades 106a to 106e. With axial rotation of thestirrer 102, themolten glass 7 flowing inside thechamber 101 is imparted by the ancillary plates 109 with motion in the radial direction of theshaft 105. In specific terms, themolten glass 7 in proximity to thesupport plates 108 is raked or pushed by the ancillary plates 109, and thereby moves in the radial direction along the principal surfaces of thesupport plates 108. Due to a configuration in which the ancillary plates 109 are placed on thesupport plates 108, themolten glass 7 moves in the radial direction along the principal surfaces of thesupport plates 108, both with respect to raking and to pushing movement in the radial direction. In so doing, themolten glass 7 is sufficiently stirred by the ancillary plates 109 in each of theblades 106a to 106e. - Consequently, the stirring
device 100 according to the present embodiment can more homogeneously stir themolten glass 7, without the need to provide a complex configuration. For this reason, the occurrence of striae can be minimized, and a high-quality glass product can be obtained. - In the present embodiment, the upper
ancillary plates 119a of theblade 106a positioned in the uppermost tier of theshaft 105 gives rise to flow raking themolten glass 7 from the inner wall of thechamber 101 towards theshaft 105. In this case, in theupper space 121 between theblade 106a positioned in the uppermost tier and the liquid level of themolten glass 7, an ascending flow of themolten glass 7 forms at the periphery of theshaft 105, and a descending flow of themolten glass 7 forms along the inner wall of thechamber 101. The circulatingflow 123 shown inFIG. 8 is thereby formed in theupper space 121 of themolten glass 7. - If the configuration were not one with the
blade 106a positioned in the uppermost tier of theshaft 105 rakes themolten glass 7 in the radial direction, for example, in the case of a configuration in which thesupport plates 108 are not provided with the ancillary plates 109, or in the case of a configuration in which the direction of rotation of the stirrer 102a is the opposite direction from that in the present embodiment, so that themolten glass 7 is pushed in the radial direction, themolten glass 7 above theblade 106a positioned in the uppermost tier would be pushed in the radial direction by the ancillary plates 109 and/or by the centrifugal force received by thesupport plates 108, thereby pushing it from theshaft 105 towards the inner wall of thechamber 101. In this case, the pushedmolten glass 7 would ascend along the inner wall of thechamber 101 and flow into theupper space 121. Specifically, themolten glass 7 pushed in the radial direction, in the course of movement thereof along the inner wall of thechamber 101, would be directed toward the top of thechamber 101 which is the direction in which it more readily flows, and thereafter reach the liquid level of themolten glass 7. Themolten glass 7 reaching the liquid level of themolten glass 7 along the inner wall of thechamber 101 would then be directed across the liquid level towards theshaft 105 from the inner wall of thechamber 101, ultimately forming a flow directed along theshaft 105 and towards the bottom of thechamber 101. Specifically, there would arise a circulating flow of themolten glass 7 in the opposite direction of the circulatingflow 123 in the present embodiment. - In a case in which circulating flow of the
molten glass 7 in the opposite direction has arisen, bubbles present on the surface of themolten glass 7, and/or a silica-rich layer in which the silica component has become relatively large as a result of or volatilization of readily-volatilized components, is sucked in by the descending flow of themolten glass 7 formed at the periphery of theshaft 105 as it draws in themolten glass 7 in proximity to the liquid level toward the bottom of thechamber 101. As a result, there is a risk of exacerbating bubbles and of exacerbating striae in the manufactured glass substrate. - Consequently, according to the present embodiment, by forming an ascending flow of the
molten glass 7 at the periphery of theshaft 105, thereby causing themolten glass 7 in theupper space 121 to rapidly descend along the side wall of theshaft 105, situations of outflow from thedownstream conduit 104 in a state of insufficient stirring can be minimized. - According to the present embodiment, by forming a circulating
flow 123 of themolten glass 7 in theupper space 121, stagnation of themolten glass 7 in proximity to the liquid level of themolten glass 7 can be minimized. - Consequently, the stirring
device 100 according to the present embodiment can stir themolten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained. - In the present embodiment, in the
lower space 122 between theblade 106e positioned in the lowermost tier and the bottom face of thechamber 101, themolten glass 7 is pushed from theshaft 105 towards the inner wall of thechamber 101. Specifically, the lowerancillary plates 119b of theblade 106e give rise in themolten glass 7 to flow towards the outside in the radial direction of the shaft 105 (arrow 124 inFIG. 8 ), so as to accelerate outflow ofmolten glass 7 into thedownstream conduit 104. Meanwhile, the upperancillary plates 119a of theblade 106e and the lowerancillary plates 119b of theblade 106d positioned one tier above theblade 106e give rise in themolten glass 7 to flow towards the inside in the radial direction of theshaft 105, so as to minimize the outflow ofmolten glass 7 into thedownstream conduit 104. - In the present embodiment, for this reason, the stirred
molten glass 7 flows out into thedownstream conduit 104 from thelower space 122, whereby stagnation of themolten glass 7 in the bottom part inside thechamber 101 can be minimized. If themolten glass 7 were to stagnate in the bottom part inside thechamber 101, the stagnatedmolten glass 7 might include heterogeneous material in which the compositional components are out of balance with respect to the composition of themolten glass 7 flowing inside thechamber 101. Suchmolten glass 7 stagnating in the bottom part inside thechamber 101 might include heterogeneous material such as a zirconia-rich layer of nonhomogeneous composition, or the like. Ifmolten glass 7 containing heterogeneous material flows out from thedownstream conduit 104, striae may occur in theglass ribbon 44 formed by the formingdevice 42, posing a risk of problems in terms of product quality. Also, if themolten glass 7 including heterogeneous material in which zirconia has become concentrated to high concentration due to stagnation should flow to the formingdevice 42 in a subsequent step, this may cause devitrification to occur in the formingdevice 42, so that not only do quality problems arise, but stable operation becomes difficult, and in a worst case scenario, the operation must be halted to perform maintenance. - In the present embodiment, outflow of the
molten glass 7 into thedownstream conduit 104 from the space above thelower space 122 is minimized. For this reason, themolten glass 7 in thelower space 122 is constantly replenished by themolten glass 7 above, thereby minimizing stagnation of themolten glass 7 in the bottom part inside thechamber 101. Specifically, themolten glass 7 is stirred in a reliable manner in each tier, without short-cutting through tiers of the spaces betweenadjacent support plates 108. Situations in which insufficiently stirredmolten glass 7 flows out from the stirringdevice 100 can be minimized thereby. - As shown in
FIG. 8 , in the present embodiment, theupstream conduit 103 is disposed in the vicinity of the heightwise position of theblade 106a positioned in the uppermost tier. The heightwise position of theblade 106a positioned in the uppermost tier set to be separated by a predetermined distance from the liquid level of themolten glass 7. If the heightwise position of theblade 106a is close to the liquid level, when the liquid level of themolten glass 7 is vibrated by the rotation of thestirrer 102, bubbles and the like floating on the liquid level are readily drawn into themolten glass 7. On the other hand, if the heightwise position of theblade 106a is distant from the liquid level, the circulating current 123 of themolten glass 7 cannot reach the vicinity of the liquid level, and themolten glass 7 will grow stagnant in the vicinity of the liquid level, as a result of which nonhomogeneousmolten glass 7 will stagnate in the vicinity of the liquid level. Accordingly, the heightwise position of theblade 106a with respect to the liquid level of themolten glass 7 is determined appropriately, depending on the rotation speed of thestirrer 102 and/or the size of theblades 106a to 106e. - Additionally, in the present embodiment, the flow rate of the
molten glass 7 is set in such a way that the liquid level of themolten glass 7 is positioned in the vicinity of the apical part of theupstream conduit 103; and the support plates of theblade 106a are arranged in the lower side of the center of the diameter of theupstream conduit 103. In more specific terms, as shown inFIG. 8 , the support plates of theblade 106a are arranged at a heightwise position about the same as that of the bottom part of theupstream conduit 103. For this reason, the upperancillary plates 119a of theblade 106a positioned in the uppermost tier give rise in themolten glass 7 to flow in the radial direction of the shaft 105 (the arrow to the lower side of the circulatingflow 123 inFIG. 8 ), so as to accelerate inflow of themolten glass 7 from theupstream conduit 103. - Consequently, the stirring
device 100 according to the present embodiment can stir themolten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained. - In the present embodiment, the
support plates 108 of the any two of theblades 106a to 106e situated adjacently along the rotation axis of theshaft 105 are disposed without mutual overlap, when viewed along the rotation axis of theshaft 105. For example, as shown inFIG. 7 , thesupport plates 108 of theblade 106a are disposed so as to be positioned between twosupport plates 108 of theblade 106b. For this reason, flow of themolten glass 7 in the axial direction of the shaft 105 (the vertical direction) inside thechamber 101 is inhibited, and the residence time of themolten glass 7 inside thechamber 101 is increased. In other words, upward or downward flow of themolten glass 7 inside thechamber 101 is initially dammed by thesupport plates 108 in each of theblades 106a to 106e, and therefore in the spaces betweenadjacent blades 106a to 106e, themolten glass 7 temporarily stagnates. For this reason, in the spaces betweenadjacent support plates 108, themolten glass 7 is imparted with sufficient movement in the radial direction of theshaft 105 by the ancillary plates 109 in each of theblades 106a to 106e, and amolten glass 7 short path does not occur. - In the present embodiment, by adopting such a disposition of the
blades 106a to 106e, themolten glass 7 in theupper space 121 is made to descend rapidly along the side wall of theshaft 105, and situations of outflow from thedownstream conduit 104 in a state of insufficient stirring can be minimized. - Consequently, the stirring
device 100 according to the present embodiment can stir themolten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained. - In the
stirring device 100 according to the present embodiment, when thestirrer 102 is viewed along the rotation axis of theshaft 105, the ancillary plates 109 in each of theblades 106a to 106e are arranged at positions away from the outside peripheral rims of thesupport plates 108, except for theirinside edge 109a andoutside edge 109b. For this reason, themolten glass 7 flowing vertically downward in along the principal surfaces of the upperancillary plates 109a of theblades 106a to 106e readily collides with the principal surfaces at the upper sides of thesupport plates 108, and themolten glass 7 flowing vertically upward along the principal surfaces of the lowerancillary plates 109a of theblades 106a to 106e readily collides with the principal surfaces at the lower sides of thesupport plates 108, whereby movement of themolten glass 7 in the upward and downward directions inside thechamber 101 is minimized. Specifically, in the tiers between mutuallyadjacent blades 106a to 106e, thesupport plates 108 have an initial damming action on themolten glass 7 flowing downward from above or upward from below, inside thechamber 101. As a result, in the tiers of spaces betweenadjacent support plates 108, themolten glass 7 is sufficiently stirred by the ancillary plates 109 of theblades 106a to 106e, and amolten glass 7 short path does not arise. - Consequently, the stirring
device 100 according to the present embodiment can stir themolten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained. - In the present embodiment, the three
support plates 108 in each of theblades 106a to 106e of thestirrer 102 are connected to one another by the linkingportions 110 at the periphery of theshaft 105, and therefore constitute substantially one component. For this reason, the strength of theblades 106a to 106e can be improved. Due to the minimal stirring effect at the periphery of theshaft 105, around theshaft 105, themolten glass 7 tends to descend inside thechamber 101 without being stirred. In the present embodiment, descending flow of themolten glass 7 around theshaft 105 can be minimized by the linkingportions 110 in each of theblades 106a to 106e. - Consequently, the stirring
device 100 according to the present embodiment can stir themolten glass 7 more homogeneously. For this reason, the occurrence of striae can be minimized, and high-quality glass articles can be obtained. - In the present embodiment, the
blades 106a to 106e are disposed in five tiers on theshaft 105, but the number of tiers of theblades 106a to 106e may be determined appropriately in consideration of the size of thechamber 101, and/or the length of theshaft 105, and so on. Likewise, the spacing between two of theblades 106a to 106e situated adjacently along theshaft 105 may be determined appropriately in consideration of the size of thechamber 101, and so on. - In the present embodiment, each of the
blades 106a to 106e have threesupport plates 108, but may instead have two, or four or more,support plates 108. - In the present modification example, in a case in which, for example, each of the
blades 106a to 106e is constituted by foursupport plates 108, the positions of thesupport plates 108 ofadjacent blades 106a to 106e may differ from one another when thestirrer 102 is viewed in the axial direction of theshaft 105, in the manner taught in the present embodiment. - Through-
holes 112 may be formed in the principal surfaces of thesupport plates 108 in each of theblades 106a to 106e in the present embodiment.FIG. 9 is a plan view of ablade holes 112. In the present modification example, when thestirrer 102 rotates about theshaft 105 as the rotation axis, a portion of themolten glass 7 will pass through the through-holes 112. A portion of themolten glass 7 passing through the through-holes 112 gives rise to upward or downward flow of themolten glass 7. As a result, in themolten glass 7 in thechamber 101, there arises flow in the axial direction of theshaft 105 due to the through-holes 112, in addition to flow in the radial direction of theshaft 105 due to the ancillary plates 109. For this reason, more complex flows arise in themolten glass 7, and higher stirring effect can be obtained. Moreover, due to the through-holes 112, the resistance received from themolten glass 7 during rotation of thestirrer 102 can be expected to be lower, and less power will be needed to give rise to the intended flow in themolten glass 7. - Moreover, in the present modification example, bubbles included in the
molten glass 7 can pass through the through-holes 112 and rise to the liquid level of themolten glass 7 in thechamber 101. Specifically, bubbles included in themolten glass 7 can be eliminated effectively. For example, there can be considered cases in which thestirrer 102 of the present modification example provided with through-holes 112 would be introduced into themolten glass 7 in thechamber 101, during inspection or repair of thestirrer 102, and/or during use of anew stirrer 102. In such a case, bubbles of air sucked in due to introduction of thestirrer 102 would be able to float not only between theblades 106a to 106e and theblades 106a to 106e of thestirrer 102, but also through the through-holes 112 placed in theblades 106a to 106e. For this reason, it is possible to shorten the time necessary for operation to stabilize. - As shown in
FIG. 9 , in the present modification example, through-holes 112 may be formed the linkingportions 110 connecting thesupport plates 108 to one another around theshaft 105 as well. - In the
stirring device 100 according to the present embodiment, thechamber 101 may be provided with a mechanism for discharging themolten glass 7. For example, a discharge port for dischargingmolten glass 7 that includes a zirconia-rich layer may be placed on the bottom face of thechamber 101, or a discharge port for dischargingmolten glass 7 that includes bubbles and/or a silica-rich layer may be placed on the side wall of thechamber 101. - For example, there may be cases in which heterogeneous material containing a higher proportion of silica or the like, with respect to the average composition of the
molten glass 7 overall, is included within themolten glass 7. It is conceivable that this could happen due to irregular composition of themolten glass 7 arising in the melting step, or to volatilization of readily-volatilized components from themolten glass 7. In particular, the aforedescribed heterogeneous material is prone to arise due to volatilization of readily-volatilized components from themolten glass 7 at the liquid level of themolten glass 7. - In a case in which the circulating
flow 123 of the present embodiment has arisen, notwithstanding the aforedescribed heterogeneous material, bubbles floating on the liquid level of themolten glass 7, and/or other foreign matter present on the liquid level, themolten glass 7 in proximity to the liquid level flows across the liquid level from theshaft 105 towards the inner wall of thechamber 101. Therefore, as taught in the present modification example, by placing a discharge port on an extension line of this flow, heterogeneous material and the like included in themolten glass 7 can be discharged. For example, at a position above theblade 106a of the uppermost tier, preferably at the liquid level or just below the liquid level of themolten glass 7, thechamber 101 may be provided with a discharge port formed by part of the inner wall of thechamber 101 protruding towards the outside in the radial direction. - Normally, it is necessary to halt running of the stirring
device 100 during recovery of foreign matter in themolten glass 7. However, in a case in which the circulatingflow 123 is formed at the periphery of theshaft 105, and flow is formed across the liquid level of themolten glass 7 from theshaft 105 towards the inner wall of thechamber 101, by placing the aforedescribed discharge port,molten glass 7 that includes heterogeneous material and the like can be discharged from thechamber 101 without having to halt running of the stirringdevice 100. For example, even if insufficiently finedmolten glass 7 including bubbles flows to the stirring step from the upstream fining step, themolten glass 7 that includes the bubbles can be discharged from thechamber 101 without halting operation, and thestirring device 100 can be kept online. - In the present embodiment, the three
support plates 108 are arranged radially from theshaft 105 towards the inner wall of thechamber 101; and are disposed such that when thesupport plates 108 of theblades 106a to 106e disposed in two adjacent tiers are respectively projected onto the bottom face of thechamber 101, the gaps between thesupport plates 108 and thesupport plates 108 are small. However, the threesupport plates 108 may be disposed such that, depending on the area of the principal surface, the area of overlapping sections of thesupport plates 108 and thesupport plates 108 is small. In this case, thesupport plates 108 of two of theblades 106a to 106e situated adjacently along the rotation axis of theshaft 105 would be disposed in mutual partially overlapping fashion when viewed along the rotation axis of theshaft 105. - In the present modification example as well, flows of the
molten glass 7 in the upward and downward directions inside thechamber 101 are initially dammed by thesupport plates 108 of theblades 106a to 106e, and therefore in the spaces betweenadjacent blades 106a to 106e, themolten glass 7 temporarily stagnates. For this reason, in each of the spaces betweenadjacent support plates 108, themolten glass 7 is imparted with sufficient movement in the radial direction of theshaft 105 by the ancillary plates 109 of theblades 106a to 106e, and short-path of themolten glass 7 does not occur. - In the present embodiment, the
inside edges 109a of the ancillary plates 109 are separated from theshaft 105; however, the ancillary plates 109 may directly connect to theshaft 105 in order to improve the strength of thestirrer 102 and theblades 106a to 106e. - The method of manufacturing a glass substrate according to the present invention is not limited to the glass compositions mentioned in the present embodiment, nor are the temperature and/or viscosity of the
molten glass 7 in the stirring step limited to the aforedescribed values. For example, whereas the aforedescribed glass composition was shown to be a glass composition of alkali-free glass or low-alkali glass suited for employment in glass substrates for liquid crystals, the aforedescribed stirring step is effective for glasses containing an alkali component as well. - Likewise, the parameters of the stirring step are not limited to the aforedescribed values. As one example, for a glass composition suitable for reinforced glass formed by addition of an alkali component, stirring may take place at a lower temperature set for the
molten glass 7, i.e., within a range of 1300°C-1400°C, and with the viscosity of themolten glass 7 adjusted to within the aforedescribed range. - A second embodiment of a glass manufacturing device employing the method of manufacturing a glass substrate and the stirring device according to the present invention will be described employing
FIGS. 10 to 20 . The basic configuration, operation, and characteristics of the glass manufacturing device according to the present embodiment are the same as for the glass manufacturing device according to the first embodiment. -
FIG. 10 is a side view showing an example of a configuration of a stirring device according to the present embodiment; andFIG. 11 is a perspective view showing an example of a configuration of a stirrer according to the present embodiment. The stirringdevice 100 is provided with achamber 1, and astirrer 2 housed inside thechamber 1. Thechamber 1 is cylindrical in shape, and communicates with an upstream conduit (inlet pipe) 3 and a downstream conduit (outlet pipe) 4, which are arranged at the upper side wall and the lower side wall. Themolten glass 7 flows into thechamber 1 from theupstream conduit 3, is directed from the top towards the bottom, and flows out from thechamber 1 to thedownstream conduit 4. - The
stirrer 2 is provided with ashaft 5 with a cylindrical shape constituting a rotation axis; andblades shaft 5. Theblades 6a to 6e are disposed in order, in five tiers along the axial direction of theshaft 5. The number of tiers of theblades 6a to 6e is not limited to five; an appropriate preferred number of tiers may be selected in consideration of the size of thechamber 1, and/or the length of theshaft 5, and so on. Likewise, the spacing between theadjacent blades 6a to 6e along the axial direction of theshaft 5 may be adjusted for efficient stirring of themolten glass 7 in thechamber 1. Theblades 6a to 6e are disposed extending in a radial pattern in the radial direction of theshaft 5, and in each of the tier, two of theblades 6a to 6e are arranged extending in mutually symmetrical directions with respect to theshaft 5. The number ofblades 6a to 6e in each of the tier is not limited to two, and could be one, or three or more, for example. - The configuration of the blades will be described with reference to
FIGS. 12 to 17 .FIGS. 12 ,13, and 14 are respectively a plan view, a side view, and a perspective view showing an example of a blade configuration in the stirrer according to the present embodiment.FIGS. 15, 16 , and17 are respectively a plan view, a side view, and a perspective view showing an example of another blade configuration in the stirrer according to the present embodiment. Theblades FIGS. 12 to 14 , and theblades FIGS. 15 to 17 . - The
blades blades blades 6a to 6e are provided withinclined plates 8 directly connected to theshaft 5, andancillary plates 9 arranged on principal surfaces of theinclined plates 8. Both theblades blades inclined plates 8 and theancillary plates 9, but the direction of incline and/or the disposition and others thereof differ from one another. - The
inclined plates 8 have a mode of pushing themolten glass 7 upward or pushing it downward, when thestirrer 2 rotates about theshaft 5 as the rotation axis. However, the direction along the axial direction of theshaft 5 is the up and down direction.FIG. 18 is a side view showing an example of the configuration of the stirrer according to the present embodiment.FIG. 18 is a view of thestirrer 2 along a direction perpendicular to the axial direction of theshaft 5, with theblades 6a to 6e positioned to the front of theshaft 5. InFIG. 18 , the principal surfaces of eachinclined plate 8 are inclined with respect to aplane 10 perpendicular to the axial direction of theshaft 5. When thestirrer 2 rotates about theshaft 5 as the rotation axis, themolten glass 7 flows along the principal surfaces of theinclined plates 8, and an upward or downward flow arises in themolten glass 7. Theinclined plates 8 push themolten glass 7 upward or push it downward. Any mode whereby theinclined plates 8 push themolten glass 7 upward or downward when thestirrer 2 rotates is acceptable, and the aforedescribed configuration is not limiting. InFIG. 18 , the principal surfaces of theinclined plates 8 are flat faces, and the entirety of each principal surface is inclined with respect to theplane 10 perpendicular to the axial direction of theshaft 5; however, for example, a configuration in which only part of each of theinclined plates 8 is inclined with respect to theplane 10 is also acceptable, and the principal surfaces of theinclined plates 8 may be curved faces. - As shown in
FIG. 18 , theblades blades inclined plates 8. For this reason, the directions of the flows arising in themolten glass 7 are different from one another. When theshaft 5 rotates counterclockwise as viewed from above, theinclined plates 8 of theblades molten glass 7 downward, whereas theinclined plates 8 of theblades molten glass 7 upward. The directions of the flows arising in themolten glass 7 due to theinclined plates 8 of theblades 6a to 6e differ in alternating fashion along the axial direction of theshaft 5. Consequently, between mutually adjacent tiers of theblades 6a to 6e, both upward and downward flows arise in themolten glass 7. As these two different flows arise, the flows arising in themolten glass 7 become more complex. Furthermore, the two different flows collide between the tiers, producing more complex flows. Higher stirring effect can be obtained thereby, and homogenization of themolten glass 7 is accelerated. - In a preferred mode, the
blade 6e of the lowermost tier pushes themolten glass 7 downward when thestirrer 2 rotates in one direction about theshaft 5 as the rotation axis. When downward flow of themolten glass 7 in this section arises due to theblade 6e of the lowermost tier, themolten glass 7 collides with the bottom face of thechamber 1, accelerating stirring of themolten glass 7. The distance between theblade 6e of the lowermost tier and the bottom face of thechamber 1 may be any distance such that the downward flow of themolten glass 7 produced by theblade 6e of the lowermost tier collides with the bottom face of thechamber 1 and accelerates stirring of themolten glass 7. - Through-
holes 12 are formed in the principal surfaces of theinclined plates 8. When thestirrer 2 rotates about theshaft 5 as the rotation axis, part of themolten glass 7 passes through the through-holes 12. The through-holes 12 are inclined with respect to theplane 10 in the same manner as the principal surfaces of theinclined plates 8, and therefore give rise to upward or downward flow in themolten glass 7 due to passage of part of themolten glass 7 through the through-holes 12. The directions of these upward or downward flows differ from the directions of the flows arising from upward pushing or downward pushing of themolten glass 7 by theinclined plates 8. Consequently, formation of the through-holes 12 has the effect of increasing the number of directions of flows arising in themolten glass 7. For this reason, more complex flows arise in themolten glass 7, and higher stirring effect can be obtained. Moreover, due to the through-holes 12, resistance received from themolten glass 7 during rotation of thestirrer 2 is lower, and less power is needed to give rise to the intended flow in themolten glass 7. - The
ancillary plates 9 are arranged on the principal surfaces of theinclined plates 8, in such a way that the principal surfaces thereof are perpendicular to the principal surfaces of theinclined plates 8. As shown inFIGS. 12 and15 , the twoancillary plates 9 are respectively arranged on the upper principal surface and the lower principal surface of each singleinclined plate 8. InFIGS. 12 and15 , theancillary plates 9 arranged on the lower principal surface are shown by broken lines. Each of theancillary plates 9 has anedge 9a closest to theshaft 5, and anedge 9b which is the edge on the opposite side from theedge 9a; and has a shape extending from theedge 9a to theedge 9b. Viewed along the axial direction of theshaft 5, each of theancillary plates 9 has a shape such that, moving from theedge 9a closest to theshaft 5 towards theedge 9b on the opposite side therefrom, the principal surfaces of theancillary plate 9 diverge from astraight line 11 connecting theedge 9a and acenter point 13 which is the center of rotation of theshaft 5. Due to this shape of theancillary plates 9, when thestirrer 2 rotates about theshaft 5 as the rotation axis, themolten glass 7 flows along the principal surfaces of theancillary plates 9, giving rise to flow in themolten glass 7 in the radial direction of theshaft 5. That is, flow from theshaft 5 towards the inner wall of thechamber 1, or flow from the inner wall of thechamber 1 towards theshaft 5, arises in themolten glass 7. Theancillary plates 9 have modes of raking themolten glass 7 from the inner wall of thechamber 1 towards theshaft 5, or modes of pushing from theshaft 5 towards the inner wall of thechamber 1. Each of theancillary plates 9 has either of these two modes. In preferred practice, theancillary plates 9 respectively arranged on the upper and lower principal surfaces of theinclined plates 8 have mutually different modes. - That is, in a preferred mode, when the
stirrer 2 rotates in one direction about theshaft 5 as the rotation axis, of theancillary plates 9 arranged on the upper principal surfaces and theancillary plates 9 arranged on the lower principal surfaces of theinclined plates 8, theancillary plates 9 on one face have a mode of raking themolten glass 7 from the inner wall of thechamber 1 towards theshaft 5, while theancillary plates 9 on the other face have a mode of pushing themolten glass 7 from theshaft 5 towards the inner wall of thechamber 1. - The
ancillary plates 9 arranged on the upper principal surfaces of theinclined plates 8 of theblades molten glass 7 when thestirrer 2 rotates about theshaft 5 as the rotation axis in the counterclockwise direction as seen from above; whereas theancillary plates 9 arranged on the back faces, i.e., the lower principal surfaces thereof, have a mode of pushing themolten glass 7. Theancillary plates 9 arranged on the upper principal surfaces of theinclined plates 8 of theblades molten glass 7 when thestirrer 2 rotates about theshaft 5 as the rotation axis in the counterclockwise direction as seen from above; whereas theancillary plates 9 arranged on the back faces, i.e., the lower principal surfaces thereof, have a mode of raking themolten glass 7. Because the modes of theancillary plates 9 are different for the upper principal surfaces versus the lower principal surfaces of theinclined plates 8 in this way, higher stirring effect is obtained. - Stirring efficiency tends to decline going from the upstream side towards the downstream side of the
chamber 1, and in order to minimize this, the height (length in the up and down direction) of theancillary plates 9 positioned to the downstream side of thechamber 1 may be greater (longer) in comparison with theancillary plates 9 positioned at the upstream side. Increasing the height of theancillary plates 9 increases the stirring efficiency, and minimizes the decline in stirring efficiency in the downstream side. - In blades situated adjacently to one another in the axial direction of the
shaft 5, the height of theancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of theinclined plates 8 of lower blades may be the same as, or higher than, the height of theancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of theinclined plates 8 of blades positioned above those blades. The ratio of the height of theancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of theblade 6a of the uppermost tier to the height of theancillary plates 9 arranged on the upper principal surfaces and the lower principal surfaces of theblade 6e of the lowermost tier is preferably 1 : 1.3. - For example, where the heights of the
ancillary plates 9 arranged on each of theinclined plates 8 of theblades ancillary plates 9 arranged on each of theinclined plates 8 of theblades ancillary plates 9 of theblades ancillary plates 9 of theblades - In the present embodiment, the top of the
chamber 1 is upstream and the bottom is downstream; however, in a case in which the bottom of thechamber 1 is upstream and the top is downstream, for mutually adjacent blades, the height of the ancillary plates arranged on the upper principal surfaces and the lower principal surfaces of the inclined plates of the blades at the top may be the same as, or greater than, the height of the ancillary plates arranged on the upper principal surfaces and the lower principal surfaces of the inclined plates of the blades positioned below these blades. - Provided that the
molten glass 7 can be homogeneously stirred, the number ofancillary plates 9, and the modes thereof are not limited to those in the aforedescribed embodiment. For example, theancillary plates 9 may be disposed on only one of the principal surfaces of theinclined plates 8. Theancillary plates 9 on both principal surfaces of theinclined plates 8 may have identical modes. - The two ancillary plates (the first ancillary plate and the second ancillary plate) 9 arranged on each of the
inclined plates 8 have shapes that respectively diverge from one another moving from theedge 9a towards theedge 9b. The through-hole 12 is formed in theinclined plate 8 between these twoancillary plates 9. Where the mode of these twoancillary plates 9 is one of raking themolten glass 7 from the inner wall of thechamber 1 towards theshaft 5 when thestirrer 2 rotates about theshaft 5 as the rotation axis, themolten glass 7 directed between the twoancillary plates 9 is guided through a progressively smaller gap between the twoancillary plates 9, with a portion thereof flowing through the through-hole 12 and towards the back face of theinclined plate 8, while the remainder flows upward or downward along the principal surfaces of theinclined plate 8. Themolten glass 7 having passed through the through-hole 12 differs not only in flow direction but also in velocity from the rest of themolten glass 7, therefore giving rise to more complex flows in themolten glass 7. Furthermore, themolten glass 7 having passed through the through-hole 12 and flowed towards the back face of theinclined plate 8 is pushed from theshaft 5 towards the inner wall of thechamber 1 by theancillary plates 9 arranged on the back face of theinclined plate 8. That is, when themolten glass 7 passes through the through-hole 12 and flows towards the back face of theinclined plate 8, the direction of flow thereof is changed to a direction different from that up to that point. For this reason, high stirring effect is obtained. - Likewise, even in a case in which the
molten glass 7 is directed between twoancillary plates 9 having a mode for pushing themolten glass 7 from theshaft 5 towards the inner wall of thechamber 1, a portion of themolten glass 7 passes through the through-hole 12 and flows towards the back face of theinclined plate 8, while the remainder flows upward or downward along the principal surfaces of theinclined plate 8, creating flows in different directions and differing in velocity. Furthermore, themolten glass 7 having passed through the through-hole 12 and flowed towards the back face of theinclined plate 8 changes flow direction to a direction different from that up to that point, due to theancillary plates 9 arranged on the back face of theinclined plate 8. - In preferred practice, the principal surfaces of the
ancillary plates 9 are curving faces. During rotational running of theblades 6a to 6e centering on theshaft 5, if the principal surfaces of theancillary plates 9 are curving faces, the resistance that theblades 6a to 6e receive from themolten glass 7 can be lower, and less power will be needed to give rise to the intended flow in themolten glass 7. Provided that it is possible for theancillary plates 9 to create a flow in the radial direction of theshaft 5 in themolten glass 7, the principal surfaces of theancillary plates 9 may be flat faces, or have other shapes. - In preferred practice, the
blades 6e of the lowermost tier and thedownstream conduit 4 are disposed in such a way that when an area formed between theinclined plates 8 of theblades 6e of the lowermost tier and the bottom face of thechamber 1 is hypothetically moved along a direction perpendicular to the axial direction of theshaft 5, and in a direction towards thedownstream conduit 4, at least a portion of this area constitutes the boundary of thedownstream conduit 4 and thechamber 1, and passes through an opening section formed in the side wall of thechamber 1. Also, in preferred practice, theancillary plates 9 arranged on the lower principal surface of theblades 6e of the lowermost tier have a mode for pushing themolten glass 7 when thestirrer 2 rotates in one direction about theshaft 5 as the rotation axis. - Because the
blades 6e of the lowermost tier and thedownstream conduit 4 are disposed in the aforedescribed manner, the flow arising in themolten glass 7 due to theancillary plates 9 arranged on the lower principal surface of theblades 6e of the lowermost tier readily affects the flow ofmolten glass 7 flowing out to thedownstream conduit 4. Where theancillary plates 9 arranged on the lower principal surface of theblades 6e of the lowermost tier have a mode of pushing themolten glass 7 when thestirrer 2 rotates about theshaft 5 as the rotation axis, themolten glass 7 can be directed from theshaft 5 towards the inner wall of thechamber 1, so that themolten glass 7 flows smoothly out from thechamber 1 into thedownstream conduit 4. For this reason, the flow ofmolten glass 7 in the bottom part of thechamber 1 is smooth, and homogeneous stirring takes place. - In the
stirring device 100 according to the aforedescribed embodiment, theupstream conduit 3 is arranged in the upper part of thechamber 1 and thedownstream conduit 4 is arranged in the lower part of thechamber 1, with themolten glass 7 being directed downward from above in thechamber 1; however, there may also be employed a stirring device configured so that themolten glass 7 is directed upward from below in thechamber 1. Here, a downstream conduit (outlet pipe) may be arranged on the side wall in the top part of the chamber, and a upstream conduit (inlet pipe) may be arranged on the side wall in the bottom part of the chamber, with the chamber communicating respectively with the upstream conduit and the downstream conduit. Except for the aforedescribed points, the configuration is comparable to thestirring device 100 according to the aforedescribed embodiment. - The
ancillary plates 9 discussed above are configured as separate from theshaft 5, but a configuration whereby theancillary plates 9 connect at one end to theshaft 5 is also acceptable. In so doing, the strength of theancillary plates 9 can be improved. Furthermore, the strength of theinclined plates 8 can be improved as well.FIG. 19 is a plan view showing an example of a yet another blade configuration of the stirrer according to the present embodiment. Ablade 36 shown inFIG. 19 has aninclined plate 38 connected to the side wall of theshaft 5, andancillary plates 39 arranged on the principal surfaces of theinclined plate 8. A through-hole 32 is formed in the principal surfaces of theinclined plate 38. In thisblade 36, anedge 39a of theancillary plate 39 arranged towards theshaft 5 is connected to theshaft 5. By connecting theancillary plate 39 to theshaft 5 in this way, the strength of theancillary plate 39 and theinclined plate 38 can be improved, making it possible for theancillary plate 39 and theinclined plate 38 to be thinner, so that the cost of the stirringdevice 100 can be reduced. - The temperature of the
molten glass 7 stirred by the stirringdevice 100 is a high temperature on the order of 1400-1600°C. Therefore, members that come into contact with themolten glass 7, such as theupstream conduit 3, thedownstream conduit 4, thechamber 1, and thestirrer 2, are preferably made of materials that can withstand such high temperature. For example, these members may be made of platinum, platinum alloy, iridium, iridium alloy, or the like. However, because platinum, platinum alloy, iridium, and iridium alloy are costly, it is preferable to minimize the amounts in which these are employed. Theinclined plates 8 and/or theancillary plates 9 are preferably made as thin as possible, within a range of having strength such that no difficulties are encountered in stirring themolten glass 7. Also, thinnerinclined plates 8 andancillary plates 9 have less resistance with themolten glass 7, and less power will be needed to give rise to the intended flow in themolten glass 7. In thechamber 1, theupstream conduit 3, and thedownstream conduit 4, reduction in the amounts used of costly materials, such as platinum, may be achieved by forming platinum or the like only on those sections coming into contact with themolten glass 7. That is, multilayer structures having platinum or the like formed only on the inner wall thereof are acceptable. - The operation of the stirring
device 100 according to the present embodiment will be described with reference toFIG. 20. FIG. 20 is a diagram depicting flows of molten glass in the stirring device according to the present embodiment.Molten glass 7 flows into thechamber 1 from theupstream conduit 3. While not shown in the drawing, the upper end of theshaft 5 of thestirrer 2 is linked to a motor or the like, and thestirrer 2 rotates counterclockwise as seen from above, with theshaft 5 as the rotation axis. Inside thechamber 1, themolten glass 7 stirred by thestirrer 2 flows out from thechamber 1 and into thedownstream conduit 4. Rotation of thestirrer 2 inside thechamber 1 causes theblades 6a to 6e to rotate about theshaft 5 as the rotation axis, stirring themolten glass 7. - Through rotation of the
blades 6a to 6e, themolten glass 7 is pushed up or pushed down by each of theinclined plates 8. For this reason, an upward or downward flow arises in themolten glass 7. Additionally, due to rotation of theblades 6a to 6e, part of themolten glass 7 passes through the through-holes 12. For this reason, upward or downward flows in directions different from the flows produced by theinclined plates 8 arises in themolten glass 7. Furthermore, through rotation of theblades 6a to 6e, themolten glass 7 is raked from the inner wall of thechamber 1 towards theshaft 5, or pushed from theshaft 5 towards the inner wall of thechamber 1, by each of theancillary plates 9. For this reason, flows in the radial direction of theshaft 5 arise in themolten glass 7. Because the aforedescribed multiple flows arise in themolten glass 7 in this manner, a sufficient stirring effect can be obtained, and more homogeneous stirring is possible. - As mentioned previously, the modes of the
inclined plates 8 differ between respective combinations of theblade 6a and theblade 6b, theblade 6b and theblade 6c, theblade 6c and theblade 6d, and theblade 6d and theblade 6e, and this gives rise in themolten glass 7 to upward or downward flows in mutually different directions. For this reason, between theblade 6a and theblade 6b, between theblade 6b and theblade 6c, between theblade 6c and theblade 6d, and between theblade 6d and theblade 6e, upward flows and downward flows arise respectively, with these flows colliding in certain sections. In these sections, complex flows arise, and the stirring effect on themolten glass 7 is high. Due to the multiple flows and the existence of sections in which these flows collide, the stirringdevice 100 can stir themolten glass 7 more homogeneously. - In the aforedescribed embodiment, there exist a plurality of sections in which two different flows, i.e., upward flow and downward flow, arise; however, it will suffice if a section in which two different flows arise exists at a minimum of one location. Consequently, among combinations of mutually adj acent tiers on the
shaft 5, it will suffice if at least one of the sets is a set ofinclined plates 8 having mutually different modes. - In the
stirring device 100, theupstream conduit 3 and thedownstream conduit 4 are respectively arranged in the upper side wall and the lower side wall of thechamber 1, and therefore the direction of flow of themolten glass 7 changes between the upper part and the lower part of thechamber 1. In sections in which the direction of flow of themolten glass 7 changes, themolten glass 7 readily stagnates. In particular, themolten glass 7 does not readily flow at locations above theblade 6a positioned in the uppermost tier and below theblade 6e positioned in the lowermost tier, and it is conceivable that themolten glass 7 in theupper space 21 and thelower space 22 of thechamber 1 may not be sufficiently stirred, as compared with other sections. - The
inclined plates 8 of theblade 6a have a mode of pushing themolten glass 7 downward, when thestirrer 2 rotates about theshaft 5 as the rotation axis, in the counterclockwise direction as viewed from above. Theancillary plates 9 arranged on the upper principal surfaces of theinclined plates 8 of theblade 6a have a mode for raking themolten glass 7 from the inner wall of thechamber 1 towards theshaft 5, when thestirrer 2 rotates about theshaft 5 as the rotation axis, in the counterclockwise direction as viewed from above. When thestirrer 2 rotates, flows arise in themolten glass 7 due to theinclined plates 8 and theancillary plates 9, and synthesis of these flows gives rise to flow of themolten glass 7 upward in the vicinity of theshaft 5, and flow of themolten glass 7 downward in the vicinity of the inner wall of the chamber 1 (circulating flow) within theupper space 21. The flows constituting this circulating flow are shown byflow directions 23. Because of the circulating flow, themolten glass 7 is stirred and does not readily stagnate in theupper space 21. - Furthermore, the
inclined plates 8 of theblade 6e have a mode of pushing themolten glass 7 downward, when thestirrer 2 rotates about theshaft 5 as the rotation axis, in the counterclockwise direction as viewed from above. Theblade 6e gives rise to downward flow in themolten glass 7 in thelower space 22 of thechamber 1, and themolten glass 7 is stirred by collision with the bottom face of thechamber 1. Theancillary plates 9 are arranged to extend downward from the lower principal surfaces of theinclined plates 8 of theblade 6e. Theseancillary plates 9 bring about sufficient stirring of themolten glass 7 of thelower space 22, and push themolten glass 7 from theshaft 5 towards the inner wall of thechamber 1, thereby giving rise in themolten glass 7 to flow towards thedownstream conduit 4, as shown by aflow direction 24. For this reason, themolten glass 7 of thelower space 22 is sufficiently stirred, and is directed into thedownstream conduit 4, without tending to stagnate. - As mentioned previously, complex flows arise in the
molten glass 7 inside thechamber 1 of the stirringdevice 100. The amount ofmolten glass 7 flowing into thechamber 1 and the amount ofmolten glass 7 outflowing from thechamber 1 are constant amounts per unit time; however, due to the complex flows arising in themolten glass 7 in thechamber 1, the speed of flow in thechamber 1 differs by location. - As mentioned previously, according to the
stirring device 100 of the present embodiment, themolten glass 7 can be stirred in more homogeneous fashion. For this reason, striae can be minimized, and glass articles of high quality can be obtained. - The inventors constructed a model of the stirring device according to the present embodiment, and performed stirring tests having parameters physically resembling those of actual operation of the stirring device. At this time, in place of molten glass, a transparent, high-viscosity material was employed, and a red liquid was continuously dripped therein from the upstream side of the high-viscosity material flowing into the chamber. The state of stirring could be more readily observed thereby. By dripping the red liquid, red streaks initially appeared along the flows in the high-viscosity material, but with stirring these red streaks disappeared, and the high-viscosity material turned a red color. The inventors performed tests employing a plurality of stirrers having different shapes, observing the state of stirring with each stirrer.
- Employing a stirrer configured like the stirrer shown in
FIG. 11 (Example 1), a state of stirring of the stirring device like that shown inFIG. 10 was observed. As a result, immediately after starting the test, red streaks swirling around the shaft were visible at the upstream (upper) side of the chamber, but with progression downstream (downward) and the passage of time, the entirety of high-viscosity material in the chamber turned a red color, and the red striations were diminished. The high-viscosity material outflowing to the downstream conduit had no color irregularities, and the high-viscosity material that had turned a red color overall outflowed to the downstream conduit. Consequently, sufficient stirring was considered achieved. According to this stirring device, the occurrence of striae is minimized, and homogeneous stirring can be considered to be achieved. - Employing a stirrer having a configuration comparable to the stirrer of the aforedescribed Example 1, except for having through-holes formed in the inclined plates (Example 2), the state of stirring was observed in a manner comparable to the aforedescribed. Furthermore, employing a stirrer having a configuration comparable to the stirrer of the aforedescribed Example 1, except that the ancillary plates arranged on the upper principal surfaces and lower principal surfaces of the inclined plates both had a mode of raking the high-viscosity material (Example 3), the state of stirring was observed in a manner comparable to the aforedescribed. As result, with the stirrers of both Example 2 and Example 3, like the stirrer of Example 1, red streaks swirling around the shaft were visible at the upstream side of the chamber, but with progression downstream or the passage of time, the entirety of high-viscosity material in the chamber turned a red color, and the red striations were diminished. The high-viscosity material outflowing to the downstream conduit had no color irregularities, and the high-viscosity material that had turned a red color overall outflowed to the downstream conduit. As compared with the stirrer of Example 1, the stirrers of Example 2 and Example 3 required a somewhat longer time for the entirety of high-viscosity material in the chamber to turn a red color. With the stirrers of both Example 2 and Example 3, sufficient stirring was considered achieved. In stirring devices provided with these stirrers, the occurrence of striae is minimized, and homogeneous stirring can be considered to be achieved.
- As a comparative example, a stirrer in which all of the inclined plates had a mode of pushing the high-viscosity material downward was employed, and the state of stirring was observed in a manner comparable to the aforedescribed. Ancillary plates were arranged on both principal surfaces of the inclined plates. As a result, in the stirrer of the comparative example, with the stirrer of the comparative example, color irregularities arising in the high-viscosity material in the chamber remained, and the high-viscosity material failed to become colored in its entirety. In the high-viscosity material outflowing to the downstream conduit, a double-layer structure that was red on the upper side and a transparent on the lower side was visible, and it took considerable time for the entire high-viscosity material outflowing to the downstream conduit to become colored.
-
- 1, 101
- Chamber
- 2, 102
- Stirrer
- 3, 103
- Upstream conduit
- 4, 104
- Downstream conduit
- 5, 105
- Shaft
- 7
- Molten glass
- 6a-6e, 36
- Blade
- 106a-106e
- Blade
- 8, 38
- Inclined plate (support plate)
- 108
- Support plate
- 9, 39, 109
- Ancillary plate
- 119a
- Upstream ancillary plate
- 119b
- Downstream ancillary plate
- 9a, 9b, 39a
- Edge
- 109a
- Inside edge
- 109b
- Outside edge
- 10
- Face
- 110
- Linking portion
- 11, 111
- Straight line
- 12, 32, 112
- Through-hole
- 13, 113
- Center point
- 21, 121
- Upper space
- 22, 122
- Lower space
- 23, 24, 123, 124
- Flow of molten glass
- 40
- Melting tank
- 41
- Fining tank
- 42
- Forming device
- 43a, 43b, 43c
- Conduit
- 44
- Glass ribbon
- 100
- Stirring device
- 200
- Glass manufacturing device
-
- (Patent Document 1)
- Japanese Unexamined Patent Application Publication
S63-8226 - (Patent Document 2)
- Japanese Unexamined Patent Application Publication
S58-88126
Claims (5)
- A method of manufacturing a glass substrate, comprising:a melting step for melting a glass material and obtaining molten glass; a stirring step for stirring, inside a stirred tank, the molten glass obtained in the melting step; and a forming step for forming a glass substrate from the molten glass stirred in the stirring step; wherein the stirred tank comprises a chamber (101) for directing the molten glass downward from above or upward from below, and a stirrer (102) for stirring the molten glass inside the chamber (101);the stirrer (102) has a shaft (105) serving as a rotation axis disposed along the vertical direction, and blades (106a, 106b, 106c, 106d. 106e) disposed on a side wall of the shaft (105), in a plurality of tiers from the uppermost tier to the lowermost tier along the axial direction of the shaft (105);the blades (106a, 106b, 106c, 106d. 106e) have support plates (108) extending orthogonally to the axial direction of the shaft (105), and ancillary plates (119a, 119b) disposed on a principal surface of the support plates (108); andin the stirring step, the stirrer rotates about the shaft (105) as the rotation axis, whereby the ancillary plates (119a, 119b) create, in the molten glass, a flow in the radial direction of the shaft (105), and the ancillary plates (119a, 119b) positioned between the support plates (108) of the blades (106a, 106b, 106c, 106d. 106e) disposed in two adjacent tiers create, in the molten glass, a flow in the same direction,characterised in thatthe blades (106a, 106b, 106c, 106d. 106e) have the ancillary plates (119a, 119b) disposed on the upper principal surfaces and on the lower principal surfaces of the support plates (108);in the stirring step, the stirrer (102) rotates about the shaft (105) as the rotation axis, whereby,in the respective blades (106a, 106b, 106c, 106d. 106e), one of the ancillary plates (119a) arranged on the upper principal surfaces of the support plates (108) or the ancillary plates (119b) arranged on the lower principal surfaces of the support plates (108) creates, in the molten glass, a flow from the inner wall of the chamber (101) towards the shaft (105), and the other of the ancillary plates (119a) arranged on the upper principal surfaces of the support plates (108) or the ancillary plates (119b) arranged on the lower principal surfaces of the support plates (108) creates, in the molten glass, a flow from the shaft (105) towards the inner wall of the chamber, and
the molten glass is moved in the radial direction of the shaft while being directed downward from above or upward from below inside the chamber;an upper ancillary plate (119a) is disposed on the upper principal surface of each support plate (108);a lower ancillary plate (119b) is disposed on the lower principal surface of each support plate (108); andthe ancillary plates (109) are disposed on principal surfaces of the support plates (108) such that the principal surfaces thereof are perpendicular to the principal surfaces of the support plates (108). - The method of manufacturing a glass substrate according to claim 1, whereinthe support plates (108) are arranged radially from the shaft (105) towards the inner wall of the chamber (101); and are disposed such that, when the support plates (108) of the blades (106a, 106b, 106c, 106d. 106e) disposed in two adjacent tiers are respectively projected onto the bottom face of the chamber (101), the gap between the respective support plates (108) is small, or the area of a section where the respective support plates (108) overlap is small.
- The method of manufacturing a glass substrate according to claim 2, whereina plurality of the support plates (108) are arranged radially; andeach of the plurality of the support plates (108) is linked at the periphery of the shaft (105).
- The method of manufacturing a glass substrate according to any one of claims 1 to 3, whereinin the stirring step, the stirrer (102) rotates about the shaft (105) as the rotation axis, whereby the ancillary plates (119a) arranged on the upper principal surfaces of the support plates (108) of the blade (106a, 106b, 106c, 106d. 106e) positioned in the uppermost tier create, above the support plates (108) of the blade (106a, 106b, 106c, 106d. 106e) positioned in the uppermost tier, a first flow moving the molten glass from the inner wall of the chamber (101) towards the shaft (105), and create a second flow ascending the molten glass moved by the first flow along the side wall of the shaft (105).
- A stirring device comprising a chamber (101) for directing molten glass downward from above or upward from below; and a stirrer (102) for stirring the molten glass inside the chamber (101); whereinthe stirrer (102) has a shaft (105) serving as a rotation axis, and blades (106a, 106b, 106c, 106d. 106e) disposed on a side wall of the shaft (105), in a plurality of tiers from the uppermost tier to the lowermost tier along the axial direction of the shaft (105);the blades (106a, 106b, 106c, 106d. 106e) have support plates (108) directly connected to the shaft (105), and ancillary plates (119a, 119b) disposed on a principal surface of the support plates (108);the ancillary plates (119a, 119b) have one edge connected to the shaft (105) or closest to the shaft (105), and another edge positioned on the opposite side from the one edge, and the ancillary plates (119a, 119b), when viewed along the axial direction of the shaft (105), are arranged so as to diverge from a straight line connecting the one edge and a center point that is the center of rotation of the shaft (105), while moving from the one edge towards the another edge; andthe stirrer (102) rotates about the shaft (105) as the rotation axis, whereby the ancillary plates (119a, 119b) create, in the molten glass, a flow in the radial direction of the shaft (105), and the ancillary plates (119a, 119b) positioned between the support plates (108) of the blades (106a, 106b, 106c, 106d. 106e) disposed in two adjacent tiers create, in the molten glass, a flow in the same direction,characterised in thatthe blades (106a, 106b, 106c, 106d. 106e) have the ancillary plates (119a, 119b) disposed on the upper principal surfaces and on the lower principal surfaces of the support plates (108);the stirrer (102) is configured to rotate about the shaft (105) as the rotation axis, whereby,in the respective blades (106a, 106b, 106c, 106d. 106e), one of the ancillary plates (119a) arranged on the upper principal surfaces of the support plates (108) or the ancillary plates (119b) arranged on the lower principal surfaces of the support plates (108) creates, in the molten glass, a flow from the inner wall of the chamber (101) towards the shaft (105), and the other of the ancillary plates (119a) arranged on the upper principal surfaces of the support plates (108) or the ancillary plates (119b) arranged on the lower principal surfaces of the support plates (108) creates, in the molten glass, a flow from the shaft (105) towards the inner wall of the chamber, andthe molten glass is moved in the radial direction of the shaft while being directed downward from above or upward from below inside the chamber;an upper ancillary plate (119a) is disposed on the upper principal surface of each support plate (108);a lower ancillary plate (119b) is disposed on the lower principal surface of each support plate (108); andthe ancillary plates (109) are disposed on principal surfaces of the support plates (108) such that the principal surfaces thereof are perpendicular to the principal surfaces of the support plates (108).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010245209 | 2010-11-01 | ||
PCT/JP2011/075174 WO2012060372A1 (en) | 2010-11-01 | 2011-11-01 | Method for manufacturing glass substrate, and stirring device |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2505562A1 EP2505562A1 (en) | 2012-10-03 |
EP2505562A4 EP2505562A4 (en) | 2014-03-26 |
EP2505562B1 true EP2505562B1 (en) | 2017-12-20 |
Family
ID=46024486
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11838022.9A Active EP2505562B1 (en) | 2010-11-01 | 2011-11-01 | Method for manufacturing glass substrate, and stirring device |
Country Status (7)
Country | Link |
---|---|
US (1) | US8726696B2 (en) |
EP (1) | EP2505562B1 (en) |
JP (2) | JP5580889B2 (en) |
KR (1) | KR101421358B1 (en) |
CN (1) | CN102596826B (en) |
TW (1) | TWI480249B (en) |
WO (1) | WO2012060372A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102020103328A1 (en) | 2020-02-10 | 2021-08-12 | Schott Ag | Method and device for homogenizing viscous liquids |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8256951B2 (en) * | 2006-12-21 | 2012-09-04 | Corning Incorporated | Stirrers for minimizing erosion of refractory metal vessels in a glass making system |
DE102008017045B9 (en) * | 2008-04-03 | 2012-07-05 | Umicore Ag & Co. Kg | Stirring system and method for homogenizing glass melts |
CN103221347B (en) * | 2011-11-18 | 2016-08-03 | 安瀚视特股份有限公司 | The manufacture method of glass and agitating device |
US8988897B2 (en) * | 2012-11-27 | 2015-03-24 | International Business Machines Corporation | Electromagnetic interference mode stirrer |
JP2014136203A (en) * | 2013-01-18 | 2014-07-28 | Chugoku Electric Power Co Inc:The | Agitator |
CN105209397B (en) * | 2013-05-08 | 2018-03-30 | 旭硝子株式会社 | Device for stirring molten glass |
JP6109006B2 (en) * | 2013-08-07 | 2017-04-05 | 住友重機械プロセス機器株式会社 | Stirrer |
DE102014211346A1 (en) * | 2014-06-13 | 2015-12-17 | Schott Ag | Method and device for producing a glass article from a glass melt |
JP6458691B2 (en) * | 2014-10-14 | 2019-01-30 | Agc株式会社 | Molten glass stirring device, plate glass manufacturing device, molten glass stirring method, and plate glass manufacturing method |
CN105621857A (en) * | 2014-11-24 | 2016-06-01 | Lg化学株式会社 | Stirrer for manufacturing LCD glass, manufacturing method thereof, and LCD glass manufacturing method |
EP3059007A1 (en) * | 2015-02-23 | 2016-08-24 | Umicore AG & Co. KG | Stirrer for stirring molten glass, apparatus for stirring molten glass comprising such a stirrer and use of such a stirrer |
CN105080662B (en) * | 2015-09-22 | 2018-04-06 | 何征徽 | A kind of fuel pulverizing plant |
KR102527198B1 (en) * | 2016-03-29 | 2023-04-27 | 니폰 덴키 가라스 가부시키가이샤 | Stirring device for molten glass, and manufacturing method of glass article |
US10618018B2 (en) * | 2016-05-25 | 2020-04-14 | Spx Flow, Inc. | Low wear radial flow impeller device and system |
KR102307125B1 (en) * | 2016-12-22 | 2021-09-30 | 니폰 덴키 가라스 가부시키가이샤 | Stirrer and method for manufacturing glass plate |
CN109092143A (en) * | 2018-09-25 | 2018-12-28 | 台玻安徽玻璃有限公司 | High borofloat glass standby raw material mixed stirring device |
CN219546867U (en) * | 2020-06-25 | 2023-08-18 | 康宁公司 | Glass condition measuring apparatus |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2569459A (en) * | 1945-08-09 | 1951-10-02 | Corning Glass Works | Method and apparatus for stirring glass |
US2569549A (en) | 1949-03-21 | 1951-10-02 | Du Pont | Imidohalides and process of preparing them and their hydrolysis products |
US2570078A (en) * | 1950-02-09 | 1951-10-02 | Corning Glass Works | Stirrer and feeder |
US2570079A (en) * | 1950-02-09 | 1951-10-02 | Corning Glass Works | Glass stirrer and feeder |
US2746729A (en) * | 1952-08-05 | 1956-05-22 | Pittsburgh Plate Glass Co | Method for homogenizing glass |
US2762167A (en) * | 1953-03-23 | 1956-09-11 | Corning Glass Works | Glass blending |
US2831664A (en) * | 1953-10-30 | 1958-04-22 | Corning Glass Works | Glass stirring |
US3419373A (en) | 1967-10-25 | 1968-12-31 | Owens Illinois Inc | Pumping vane type glass feeder |
JPS5888126A (en) | 1981-11-16 | 1983-05-26 | Nippon Sheet Glass Co Ltd | Stirrer for melted glass |
JPS638226A (en) | 1986-06-24 | 1988-01-14 | Hoya Corp | Stirrer for molten glass |
US5120342A (en) * | 1991-03-07 | 1992-06-09 | Glasstech, Inc. | High shear mixer and glass melting apparatus |
US5340372A (en) * | 1991-08-07 | 1994-08-23 | Pedro Buarque de Macedo | Process for vitrifying asbestos containing waste, infectious waste, toxic materials and radioactive waste |
KR100878605B1 (en) | 2001-11-30 | 2009-01-15 | 코닝 인코포레이티드 | Method and apparatus for homogenizing molten glass by stirring |
WO2007077716A1 (en) * | 2006-01-05 | 2007-07-12 | Nippon Electric Glass Co., Ltd. | Molten glass supply apparatus and process for producing glass molded article |
US8256951B2 (en) * | 2006-12-21 | 2012-09-04 | Corning Incorporated | Stirrers for minimizing erosion of refractory metal vessels in a glass making system |
DE102007035203B4 (en) * | 2007-07-25 | 2012-12-06 | Schott Ag | Method and apparatus for homogenizing a molten glass, and use |
DE102008017045B9 (en) * | 2008-04-03 | 2012-07-05 | Umicore Ag & Co. Kg | Stirring system and method for homogenizing glass melts |
JP2010100462A (en) * | 2008-10-22 | 2010-05-06 | Avanstrate Inc | Agitating blade and agitating device for molten glass |
WO2011020625A1 (en) * | 2009-08-21 | 2011-02-24 | Umicore Ag & Co. Kg | Mixing apparatus |
DE102010000546B4 (en) * | 2010-02-25 | 2013-04-25 | Schott Ag | Apparatus for homogenizing a molten glass, stirring device and use |
-
2011
- 2011-11-01 WO PCT/JP2011/075174 patent/WO2012060372A1/en active Application Filing
- 2011-11-01 CN CN201180004233.3A patent/CN102596826B/en active Active
- 2011-11-01 KR KR1020127012872A patent/KR101421358B1/en active IP Right Grant
- 2011-11-01 JP JP2012515282A patent/JP5580889B2/en active Active
- 2011-11-01 EP EP11838022.9A patent/EP2505562B1/en active Active
- 2011-11-01 JP JP2011240153A patent/JP2012111685A/en active Pending
- 2011-11-01 TW TW100139745A patent/TWI480249B/en active
-
2012
- 2012-09-11 US US13/610,747 patent/US8726696B2/en active Active
Non-Patent Citations (1)
Title |
---|
None * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102020103328A1 (en) | 2020-02-10 | 2021-08-12 | Schott Ag | Method and device for homogenizing viscous liquids |
Also Published As
Publication number | Publication date |
---|---|
CN102596826A (en) | 2012-07-18 |
EP2505562A1 (en) | 2012-10-03 |
JP5580889B2 (en) | 2014-08-27 |
EP2505562A4 (en) | 2014-03-26 |
WO2012060372A1 (en) | 2012-05-10 |
CN102596826B (en) | 2015-01-07 |
US20130000358A1 (en) | 2013-01-03 |
JPWO2012060372A1 (en) | 2014-05-12 |
US8726696B2 (en) | 2014-05-20 |
KR101421358B1 (en) | 2014-07-18 |
TWI480249B (en) | 2015-04-11 |
KR20120086713A (en) | 2012-08-03 |
TW201223903A (en) | 2012-06-16 |
JP2012111685A (en) | 2012-06-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2505562B1 (en) | Method for manufacturing glass substrate, and stirring device | |
EP2626334B1 (en) | Method for producing glass and stirring device | |
KR20100044684A (en) | Stirring blade for molten glass and stirring device therefor | |
KR101761457B1 (en) | Apparatus for making a glass article and methods | |
US3236618A (en) | Glass stirring apparatus | |
KR20110130390A (en) | Device for stirring molten glass | |
TWI620723B (en) | Molten glass stirring device | |
JP5768084B2 (en) | Glass plate manufacturing method and glass plate manufacturing apparatus | |
JP2011121863A (en) | Molten glass supply apparatus and method for producing glass molded article | |
JP2011088816A (en) | Glass substrate manufacturing apparatus, glass substrate manufacturing method and stirring apparatus | |
JPS5888126A (en) | Stirrer for melted glass | |
JP7283346B2 (en) | glass manufacturing method | |
JP4793581B2 (en) | Molten glass supply apparatus and method for producing glass molded product | |
KR20130122913A (en) | Method for manufacturing glass substrate, apparatus for manufacturing glass substrate and stirring apparatus | |
JP2016033099A (en) | Method for manufacturing glass plate, and agitator | |
CN103382078B (en) | The manufacture method of glass substrate, the manufacture device of glass substrate and agitating device | |
JP2007204355A (en) | Molten glass supply apparatus and method for producing glass molded article | |
JP2024083253A (en) | Molten glass agitator, apparatus and method for manufacturing glass article, and stirrer | |
JP2010235446A (en) | Method for manufacturing glass formed article |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20120626 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
DAX | Request for extension of the european patent (deleted) | ||
A4 | Supplementary search report drawn up and despatched |
Effective date: 20140221 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: B01F 7/00 20060101ALI20140217BHEP Ipc: F27D 27/00 20100101ALI20140217BHEP Ipc: C03B 5/187 20060101AFI20140217BHEP Ipc: B01F 7/18 20060101ALI20140217BHEP |
|
17Q | First examination report despatched |
Effective date: 20170220 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20170704 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: GEKKO, HITOSHI Inventor name: YAMAMOTO, KOHEI |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 956205 Country of ref document: AT Kind code of ref document: T Effective date: 20180115 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602011044447 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180320 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 956205 Country of ref document: AT Kind code of ref document: T Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180321 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180320 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180420 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602011044447 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 8 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20180921 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181101 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20181130 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181130 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181101 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181101 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20111101 Ref country code: MK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20171220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171220 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20230928 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230929 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20230929 Year of fee payment: 13 |