EP2488669A2 - Blast furnace tuyere cooling - Google Patents

Blast furnace tuyere cooling

Info

Publication number
EP2488669A2
EP2488669A2 EP10823777A EP10823777A EP2488669A2 EP 2488669 A2 EP2488669 A2 EP 2488669A2 EP 10823777 A EP10823777 A EP 10823777A EP 10823777 A EP10823777 A EP 10823777A EP 2488669 A2 EP2488669 A2 EP 2488669A2
Authority
EP
European Patent Office
Prior art keywords
series
serpentine
circulating fluid
fluid coolant
cast
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10823777A
Other languages
German (de)
French (fr)
Other versions
EP2488669B1 (en
EP2488669A4 (en
Inventor
Allan J. Macrae
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MACRAE, ALLAN J.
Original Assignee
MacRae Allan J
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MacRae Allan J filed Critical MacRae Allan J
Publication of EP2488669A2 publication Critical patent/EP2488669A2/en
Publication of EP2488669A4 publication Critical patent/EP2488669A4/en
Application granted granted Critical
Publication of EP2488669B1 publication Critical patent/EP2488669B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F7/00Elements not covered by group F28F1/00, F28F3/00 or F28F5/00
    • F28F7/02Blocks traversed by passages for heat-exchange media
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/16Tuyéres
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/16Tuyéres
    • C21B7/163Blowpipe assembly
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/10Details, accessories, or equipment peculiar to furnaces of these types
    • F27B1/16Arrangements of tuyeres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00Shaft or like vertical or substantially vertical furnaces
    • F27B1/10Details, accessories, or equipment peculiar to furnaces of these types
    • F27B1/24Cooling arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D9/00Cooling of furnaces or of charges therein
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/02Arrangements for modifying heat-transfer, e.g. increasing, decreasing by influencing fluid boundary
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/12Elements constructed in the shape of a hollow panel, e.g. with channels
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/10Cooling; Devices therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49316Impeller making
    • Y10T29/49336Blade making
    • Y10T29/49339Hollow blade
    • Y10T29/49341Hollow blade with cooling passage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making
    • Y10T29/49359Cooling apparatus making, e.g., air conditioner, refrigerator

Definitions

  • the present invention relates to gas and fluid cooling of equipment, and more particularly to methods and devices for eliminating eddy currents in high velocity coolant flows through the serpentine coolant passageways of blast furnace tuyeres.
  • Effective cooling is widely needed in various kinds of industrial equipment and machinery. Engines, smelting furnaces, and other devices can generate enough heat to destroy themselves if cooling were not used to keep the operating temperatures within acceptable limits. Three modes of cooling or heat transfer are possible, thermal radiation, heat conduction, and heat convection. Ordinary cars and trucks use coolants
  • Fluid and gas coolers are widely used in metallurgical furnaces, molds for solidification of molten materials, burners, lances, electrode clamps, tuyere forced-air nozzles in iron smelting blast furnaces, etc.
  • the most common kinds of cooling medias employed are forced air, circulating water, common oils, and synthetic oils.
  • Cooling passages can be manufactured inside metal pieces by drilling, machining, or casting. Coolant pipes of one material can be cast inside the bulk of a second type of material, or the passages can be cast inside using thin wall techniques as is conventional in automobile engine blocks. For example, a copper- nickel pipe can be cast inside a bulk copper piece.
  • the round cross section of pipes further reduces the effective cooling channel area, and thus the flow volume.
  • a rectangular cross section would better fill the bulk area available .
  • Coolers with cored water passages can be manufactured in a single piece. But, with one serious complication.
  • the sand cores must somehow be perched in the mold to define the water passages during the casting pour. This generally means
  • stems in the sand must be included. These stems create holes in the subsequent castings that must be plugged or welded-shut later.
  • a dynamic gas micro-flow measurement can be used to detect the existence of leak flow paths or micro-channels. It looks for and detects pinholes in the material.
  • the leak tightness in a metallic gas or fluid cooled piece can be improved by hot working or forging the hot face to refine the metal crystal grain size.
  • the average grain size for cast copper can be reduced from approximately ten millimeters to less than one millimeter using hot rolling, hot pressing, etc.
  • the exposed water passages are then milled in to the face of the worked part.
  • a cover plate or second piece is required to complete the water passage and finish the milled piece.
  • Rectangular cross-section coolant passages with rounded corners occupy a larger percentage of the available height and width inside the piece.
  • Coolers built this way need less metal, and their cooling efficiencies increase proportionately.
  • invention comprises carefully controlled turning radii and profiles inside the serpentine cooling fluid passages cast or milled into a work piece.
  • Individual, interdigitated baffles are contoured in the plane of coolant flow to have walls that progressively thicken and then round off at their distal ends.
  • the outside radii at these turns are similarly rounded and controlled such that the coolant flows will not be swirled into eddies .
  • Fig. 1A is a cross sectional diagram of a cooling system embodiment of the present invention taken along the general plane of a serpentine coolant passageway cast within;
  • Fig. IB is a cross sectional diagram of the cooling system of Fig. 1A taken along line IB-IB, and across the general plane of a serpentine coolant passageway cast within;
  • Fig. 1C is a cross sectional diagram of the cooling system of Fig. 1A taken along line 1C-1C, and across the general plane of a serpentine coolant passageway cast within where the ends of several baffles are thickest;
  • Figs. 2A-2B are flowchart diagrams of similar method embodiments of the present invention for manufacturing the cooling systems, coolers, and tuyeres of Figs. 1A, IB, 1C, 3, 4A, 4B, and 4C, 5A-5E, and 6;
  • Fig. 3 is a cutaway diagram of a blast furnace embodiment of the present invention that can include the tuyeres of Figs. 4A, 4B, and 4C;
  • Fig. 4A is a rear view of a tuyere embodiment of the present invention useful in the blast furnace of Fig. 3;
  • Fig. 4B is a longitudinal cross sectional diagram of the tuyere of Fig. 4A;
  • Fig. 4C is a lateral cross sectional diagram of a portion of the conical body of the tuyere of Figs. 4A and 4B and laid out flat for this illustration;
  • Figs. 5A-5E are, respectively, perspective, wide end, top, narrow end, and side view diagrams of a cooler plate embodiment of the present invention.
  • Fig. 6 is a cross sectional view diagram along the plane of a serpentine loop turn in a coolant passageway disposed in a cast or machined cooler in an embodiment of the present invention. While the invention is amenable to various modifications and alternative forms, specifics thereof have been shown by way of example in the drawings and will be described in detail. It should be understood, however, that the intention is not to limit the invention to the particular embodiments described. On the contrary, the intention is to cover all modifications,
  • Figs. 1A-1C represents a cooling system embodiment of the present invention, and is referred to herein by the general reference numeral 100.
  • Cooling system 100 comprises a cast metal workpiece 102 with an inlet 104 into a serpentine passageway 106 for a circulating fluid coolant.
  • a first turn in the serpentine passageway 106 has an inside turn radius 108 and an outside turn radius 110 with respect to the general plane of the serpentine passageway 106.
  • the inside and outside turn radii 108 and 110 are dimensioned and shaped to eliminate or substantially reduce eddies 112 that would otherwise appear in the coolant flow. Such eddies 112 often appear at these points and just downstream in conventional designs. Eddies 112 spin the coolant in useless circles that cannot divest themselves of the heat they pickup or hold .
  • a first serpentine loop 114 turns around a first baffle 116 into a second serpentine loop 118.
  • Baffle 116 is progressively thickened toward a radius end 119 facing two outside radius corners 120 and 121.
  • Such radius end 119, and radius corners 120 and 121, are proportioned to eliminate or substantially reduce any eddies 124 that would otherwise form in the coolant flow if the turns were too sharp and abrupt .
  • baffle 116 and the others like it can instead have uniformly thick walls that widen into a teardrop profile just as radius end 119 is reached.
  • the facing two outside radius corners 120 and 121 are matched to the teardrop profile reduce eddies as the coolant flow turns.
  • baffles 126-131 are disposed in the serpentine passageway 106 to provide for additional turning of the circulating fluid coolant into each of a following series of serpentine loops 132-137. Each such turn invites the formation of more eddies 138-143 in the coolant flow. Such eddies are shown here swirling in the same plane as the serpentine
  • baffles 126-131 is also progressively thickened toward their distal ends 144-149 and finished in a radius end.
  • the corresponding outside corners that each faces are similar to radius corners 120 and 121.
  • the coolant eventually exits to a chiller through an outlet 150.
  • CFD Computational fluid dynamics
  • Specialized software is commercially available that can report to a user the heat transfer performance and fluid velocities at selected points or modeling cells in a cooling system.
  • the ANSYS CFX software product marketed by ANSYS, Inc. (Canonsburg, PA) provides passage fluid flow modeling CFD software and engineering services. See, www.ansys.com/products/ fluid-dynamics /cfx/ .
  • the prospect of any eddies 112, 124, and 138- 143 in the coolant are revealed by the modeling cells which are calculated to have zero velocity or whirling flows.
  • each loop 114, 118, and 132-137, of serpentine passageway 106 can be seen to have a generally rectangular cross-section.
  • the cross-sectional area of the serpentine passageway 106 is held constant as much as is possible given the application. If the serpentine passageway 106 must be narrowed or widened at any point, the transitions should be gradual so as not to tempt the development of eddies.
  • Fig. 2A represents a manufacturing method embodiment of the present invention that can be used to fabricate the cooling system 100 of Fig. 1, and is referred to herein by the general reference numeral 200.
  • Method 200 begins with application requirements 202 that define the performance needed and the environment a cooling system has to operate within. These requirements can include, e.g., external heat loads, inlet pressures, etc.
  • Design constraints 204 further restrict the materials and dimensions available in the cooling system design.
  • An initial design 206 represents a prototype or archetype, and would include the rounded baffle ends and inside corner relieving as represented in Figs. 1A-1C, 4A-4C, 5A-5E, and 6.
  • a computational fluid dynamic modeling software 208 such as ANSYS CFX, running on a suitable computer system platform produces thermal transfer and velocity simulations for the particular design being iterated.
  • a step 210 presents
  • a revised design 212 is resubmitted to the computational fluid dynamic modeling software 208.
  • the design iterations can stop when the reduction in eddies has apparently been optimized and balanced with other practical considerations, e.g., casting wall thicknesses.
  • sand casting cores are constructed in a step 214.
  • the castings are poured in liquid copper, for example, in a step 216, and machined in a step 218.
  • the sand casting cores usually have stems to support them in position, so after the casting and machining is complete the residual holes in the castings are plugged in a step 220.
  • the plugs can be welded or screwed in.
  • a step 222 includes
  • a principal advantage of the present invention is that workpiece embodiments will have an extended service life that can be budgeted and maintained in a step 226.
  • Fig. 2B represents another manufacturing method embodiment of the present invention that can be used to construct a milled cooler, and is referred to herein by the general reference numeral 228.
  • Method 228 is very similar to method 200, and begins with application requirements 202 that define the
  • An initial design 206 represents a prototype or archetype, and would include the rounded baffle ends and inside corner relieving as represented in Figs. 1A-1C, 4A-4C, 5A-5E, and 6.
  • a computational fluid dynamic modeling software 208 running on a suitable computer system platform produces thermal transfer and velocity simulations for the particular design.
  • a step 210 presents information so a trained operator can evaluate whether the design needs further tweaking, especially in the baffle end radii and facing inside corner radii of the serpentine passages inside the cooling system. If so, a revised design 212 is resubmitted to the computational fluid dynamic modeling software 208 for as many iterations as are needed. The design iterations can stop when no further improvements in eddy reduction are obtainable .
  • a step 230 is worked for finer grain sizes in a step 230.
  • the working can be stopped when leakage tests indicate acceptable levels.
  • the passages are milled in a step 232, and a passageway cover is machined in a step 234.
  • the cover is welded on in a step 236.
  • a step 222 is used to inspect, test, and ship the final cooling system.
  • workpieces are installed in their particular applications in a step 224.
  • the embodiments will have an extended service life that is budgeted for and maintained by service personnel in a step 226.
  • Fig. 3 represents a blast furnace 300 embodiment of the present invention in which a number of tuyeres 302 are used to introduce very hot air into the smelting process.
  • the tuyeres resemble nozzles and their close proximity to the iron smelting usually requires that they be liquid-cooled and constructed of copper .
  • Blast furnaces chemically reduce and physically convert iron oxides into liquid iron at high temperatures .
  • Blast furnaces are very large, steel stacks lined with refractory brick that are fed a mixture of iron ore, coke and limestone from the top.
  • Preheated air is blown into the bottom through the tuyeres.
  • Liquid iron droplets descend to the bottom of the furnace where they collect as slag and liquid iron. These are periodically drained from the furnace as the bottom fills up.
  • Raw ore removed from the earth includes Hematite (Fe 2 0 3 ) or Magnetite (FeaC ⁇ ) with an iron content of 50% to 70%, and is sized into small pieces about an inch in diameter.
  • An iron-rich powder can be rolled into balls and fired in a furnace to produce marble-sized pellets with 60% to 65% iron.
  • Sinter can also be used which is produced from fine raw ore, coke, sand-sized limestone and waste materials with iron. The fines mixed together for a desired product chemistry.
  • the raw material mix is then placed on a sintering strand and ignited by a gas fired furnace to fuse the coke fines into larger size pieces.
  • the iron ore, pellets and sinter are smelted into the liquid iron produced by the blast furnace. Any of remaining impurities drop into a liquid slag.
  • Hard pieces of coke with high energy values provide the permeability, heat, and gases needed to further reduce and melt the iron ore, pellets and sinter.
  • limestone An important raw material used in the iron making process is limestone. Limestone mined from the earth by blasting the ore with explosives. It is then crushed and screened to a size that ranges from 0.5 inch to 1.5 inch to become blast furnace flux. This flux can be pure high calcium limestone, dolomitic limestone containing magnesia, or a blend of the two types of limestone.
  • a blend target would be to create a low melting point, a high fluidity, and other optimum properties.
  • All of the raw materials are usually stored in an ore field and transferred to a nearby stock-house before charging.
  • the materials are thereafter loaded into the furnace top, and are subjected to numerous chemical and physical reactions as they descend to the bottom of the furnace.
  • the iron oxides drop through a series of purifying reactions to soften, melt, and finally trickle out through the coke as liquid iron droplets which fall to the bottom of the furnace.
  • the coke itself drops to the bottom of the furnace where
  • preheated air and hot blasts from the tuyeres enters the blast furnace.
  • the coke is ignited by the hot blast and immediately reacts to generate more heat.
  • the reaction takes place in the presence of excess carbon at a high temperature, so the carbon dioxide is reduced to carbon monoxide.
  • the carbon monoxide reduces the iron ore in iron oxide reactions.
  • Such reaction requires energy and starts at about 875°C.
  • the CaO formed from the reaction is used to remove sulphur from the iron, and is necessary before the hot metal can become steel.
  • the CaS becomes part of the slag.
  • the slag is also formed from any remaining Silica (S1O 2 ), Alumina (AI 2 O 3 ) , Magnesia (MgO) or Calcia (CaO) that entered with the iron ore, pellets, sinter or coke.
  • the liquid slag then trickles through the coke bed to the bottom of the furnace where it will float on top of the more dense liquid iron.
  • Hot dirty gases exiting the top of the blast furnace proceed through gas cleaning equipment so particulate matter can be removed and the gas cooled.
  • This gas has considerable energy value, so it is burned as a fuel in hot blast stoves that are used to preheat the air entering the blast furnace through the tuyeres.
  • the tuyeres are therefore subjected to air temperatures that can well exceed 900 °C.
  • the melting point of copper is very near these temperatures at 1083°C. Any of the gas not burned in the stoves is sent to a boiler house to generate steam for turbo blowers that generate "cold blast" compressed air for the stoves.
  • Figs . 4A-4C represent a tuyere embodiment of the present invention, and is referred to herein by the general reference numeral 400. Such are useful in the blast furnace 300 of Fig. 3.
  • Tuyere 400 includes a cast copper metal body 402 having the general shape of a nozzle, and includes a rear flange 404 that connects through a throat 406 to a nose 408 on its front end.
  • a coolant inlet 410 and a coolant outlet 412 are located on the rear flange 404. These connect to an internal serpentine coolant passage 414 like that described in Figs. 1A-1C.
  • the coolant being circulated can be water, oil, or a special liquid mixture.
  • baffle 416 for example, is like baffles 116, and 126- 131 and radius ends 119, and 144-149 (Figs. 1A-1C) .
  • the inside and outside turn radii of internal serpentine coolant passage 414 are dimensioned and shaped to eliminate eddies in the coolant flow .
  • the serpentine passages 414 generally proceed in a curved plane within the conical body 402.
  • a number of access holes 420 on an outside face of the cast metal body 402 allow supporting stems for the casting cores during metal cast.
  • the holes in the castings that result are sealed off with plugs 422.
  • Plugs 422 may be conventionally pipe-threaded, welded, brazed, soldered, pressed in, etc.
  • Figs . 5A-5E represent a cooler embodiment of the present invention, and is referred to herein by the general reference numeral 500.
  • a plate body 502 has a coolant piping inlet 504 and an outlet 506 at one end. These provide external connections to a serpentine coolant passageway 508 inside.
  • Three baffles 520- 522 turn the coolant flow around their thickened and rounded ends 523-525 and inside corresponding facing corners 526-531. The geometry and rounding of these ends and corners is designed and verified by simulations, modeling and prototypes to eliminate hot spots when cooler 500 is heavily heat loaded. Manufacturing methods 200 and 228 (Figs. 2A and 2B) can be used to do the design and fabrication, for example.
  • Fig. 6 represents a serpentine loop turn 600 in a coolant passageway disposed in a cast or machined cooler 601 in an embodiment of the present invention.
  • a baffle 602 thickens and then rounds off at a radius end 604, e.g., in a radius 606.
  • a pair of inside rounded corners 608 and 610 face the radius end 604.
  • Coolant flow in a passageway loop 612 turns into a next passageway loop 614 around radius end 604 of baffle 602.
  • the widths 613-615 are all kept constant as much as is practical when casting metal pieces. The object of keeping the widths constant is to not encourage nor sustain eddies where the coolant flows around the corners in a baffle.
  • angles "A" and “B” are each less than 90°, and A+B is less than 180°.
  • the center lines of passageway loops 612 and 614 are not parallel to one another. Such an arrangement would help in packing the passageway loops 612 and 614 tighter, especially where every turn is like that of Fig. 6, and the overall design of a serpentine passageway is symmetrical .
  • Tuyeres and other coolers can include external surface coatings of refractory or metal, and they can be overlayed with metal. Coatings can be applied in many ways, for example by vapor deposition, manual or hand applied such as painted or toweled, flame sprayed, dipped, and electroplating. Overlays are metal coatings applied using a high energy sources such as welding, laser, flame, or explosion bonding.
  • Coolers can also be manufactured with grooves or pockets filled with refractory.
  • Tuyere embodiments are manufactured from either a casting or machining a fine-grained metal part. With a casting, the coolant passages are cast in using molds. With a machined part, a tuyere, for example, must be made in two parts. A conventional example can be seen in United states Patent 3,840,219, Fig. 7.
  • a closure piece is used to close the water passages and complete the cooler.
  • tuyeres may be fluid or gas injected.
  • cooler embodiments of the present invention include profiling the coolant passages during design for the elimination of eddies where ever the cooler will be exposed to severe external heat loads.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Furnace Details (AREA)
  • Blast Furnaces (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

A cooling system comprises serpentine cooling fluid passages cast into a work piece with carefully controlled turning radii and profiles. Individual interdigitated baffles are contoured in the plane of coolant flow to have walls that thicken and then round off at their distal ends. The outside radii at these turns is similarly rounded and controlled such that the coolant flow will not be swirled into eddies.

Description

BLAST FURNACE TUYERE COOLING
BACKGROUND
1. Field of the Invention
The present invention relates to gas and fluid cooling of equipment, and more particularly to methods and devices for eliminating eddy currents in high velocity coolant flows through the serpentine coolant passageways of blast furnace tuyeres.
2. Description of the Prior Art
Effective cooling is widely needed in various kinds of industrial equipment and machinery. Engines, smelting furnaces, and other devices can generate enough heat to destroy themselves if cooling were not used to keep the operating temperatures within acceptable limits. Three modes of cooling or heat transfer are possible, thermal radiation, heat conduction, and heat convection. Ordinary cars and trucks use coolants
circulated through water jackets and radiators to keep the engine operating temperatures under 200°F. The excess heat collected by convection in the coolant is transferred to the air blowing through the radiator.
Fluid and gas coolers are widely used in metallurgical furnaces, molds for solidification of molten materials, burners, lances, electrode clamps, tuyere forced-air nozzles in iron smelting blast furnaces, etc. The most common kinds of cooling medias employed are forced air, circulating water, common oils, and synthetic oils. Cooling passages can be manufactured inside metal pieces by drilling, machining, or casting. Coolant pipes of one material can be cast inside the bulk of a second type of material, or the passages can be cast inside using thin wall techniques as is conventional in automobile engine blocks. For example, a copper- nickel pipe can be cast inside a bulk copper piece.
When complex cooling patterns are needed, drilling cannot be used and so drilling has been limited to applications with straight-line cooling passages. The casting-in of pipes method allows more complex passageway layouts, but the passageway shapes and layouts obtainable with piping are constrained by pipe size, coupling, bending, and welding considerations. The effectiveness of cooling possible using cast-in-pipe implementations is further limited by standard bend dimensions. For example, in a one-inch Schedule-40 diameter pipe with a short radius 180° return, the center-to-center distance between the pipes is two times the nominal diameter, or two inches. But the inside diameter of the pipe is only 1.049 inches. So, if the pipe is bonded to a casting, then the width of the cooling channel is less than 50% of the bulk, based on minimum center-to-center spacing
constraints .
The round cross section of pipes further reduces the effective cooling channel area, and thus the flow volume. A rectangular cross section would better fill the bulk area available .
Pure castings can be made using cored or machined patterns, and typical cooling passages most commonly use a serpentine pattern implemented with thin-wall baffles. However, these simple designs can produce significant eddies in the coolant flow just past where the coolant is turned in each loop, and the problems are amplified when the coolant velocity is pushed to high levels. Cooling uniformity suffers dramatically when these eddies become significant. So controlling the eddy currents is a way the performance of a cooler can be extended with no other changes .
Coolers with cored water passages can be manufactured in a single piece. But, with one serious complication. The sand cores must somehow be perched in the mold to define the water passages during the casting pour. This generally means
supporting stems in the sand must be included. These stems create holes in the subsequent castings that must be plugged or welded-shut later.
So-called "leak tightness" is a concern in cooler castings.
A dynamic gas micro-flow measurement can be used to detect the existence of leak flow paths or micro-channels. It looks for and detects pinholes in the material. The leak tightness in a metallic gas or fluid cooled piece can be improved by hot working or forging the hot face to refine the metal crystal grain size. For example, the average grain size for cast copper can be reduced from approximately ten millimeters to less than one millimeter using hot rolling, hot pressing, etc. The exposed water passages are then milled in to the face of the worked part. A cover plate or second piece is required to complete the water passage and finish the milled piece.
Rectangular cross-section coolant passages with rounded corners occupy a larger percentage of the available height and width inside the piece. These are entirely possible and
practical to do in castings with cored or machined cooling channels. Coolers built this way need less metal, and their cooling efficiencies increase proportionately.
Larger surface areas inside the coolant passageways can significantly increase the amount of heat transfer possible.
However, the flow regime within the fluid coolant in conventional castings is typically quite poor. Eddies tend to form in the coolant flows aft of where they are being turned by the baffle ends. Hot spots can then develop because the coolant is ineffectually spinning around in small circles and can not carry any absorbed heat away. The heat at those spots can build up high enough to boil the coolant, and that can lead to the failure of the part and the connecting piping.
What is needed is a better baffle and passageway design that eliminates the inefficient eddies and their disastrous
consequences in fast flowing coolants.
SUMMARY OF THE INVENTION
Briefly, a cooling system embodiment of the present
invention comprises carefully controlled turning radii and profiles inside the serpentine cooling fluid passages cast or milled into a work piece. Individual, interdigitated baffles are contoured in the plane of coolant flow to have walls that progressively thicken and then round off at their distal ends. The outside radii at these turns are similarly rounded and controlled such that the coolant flows will not be swirled into eddies .
These and other objects and advantages of the present invention will no doubt become obvious to those of ordinary skill in the art after having read the following detailed description of the preferred embodiments which are illustrated in the various drawing figures.
IN THE DRAWINGS
Fig. 1A is a cross sectional diagram of a cooling system embodiment of the present invention taken along the general plane of a serpentine coolant passageway cast within;
Fig. IB is a cross sectional diagram of the cooling system of Fig. 1A taken along line IB-IB, and across the general plane of a serpentine coolant passageway cast within;
Fig. 1C is a cross sectional diagram of the cooling system of Fig. 1A taken along line 1C-1C, and across the general plane of a serpentine coolant passageway cast within where the ends of several baffles are thickest;
Figs. 2A-2B are flowchart diagrams of similar method embodiments of the present invention for manufacturing the cooling systems, coolers, and tuyeres of Figs. 1A, IB, 1C, 3, 4A, 4B, and 4C, 5A-5E, and 6;
Fig. 3 is a cutaway diagram of a blast furnace embodiment of the present invention that can include the tuyeres of Figs. 4A, 4B, and 4C;
Fig. 4A is a rear view of a tuyere embodiment of the present invention useful in the blast furnace of Fig. 3;
Fig. 4B is a longitudinal cross sectional diagram of the tuyere of Fig. 4A;
Fig. 4C is a lateral cross sectional diagram of a portion of the conical body of the tuyere of Figs. 4A and 4B and laid out flat for this illustration;
Figs. 5A-5E are, respectively, perspective, wide end, top, narrow end, and side view diagrams of a cooler plate embodiment of the present invention; and
Fig. 6 is a cross sectional view diagram along the plane of a serpentine loop turn in a coolant passageway disposed in a cast or machined cooler in an embodiment of the present invention. While the invention is amenable to various modifications and alternative forms, specifics thereof have been shown by way of example in the drawings and will be described in detail. It should be understood, however, that the intention is not to limit the invention to the particular embodiments described. On the contrary, the intention is to cover all modifications,
equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
Figs. 1A-1C represents a cooling system embodiment of the present invention, and is referred to herein by the general reference numeral 100. Cooling system 100 comprises a cast metal workpiece 102 with an inlet 104 into a serpentine passageway 106 for a circulating fluid coolant. A first turn in the serpentine passageway 106 has an inside turn radius 108 and an outside turn radius 110 with respect to the general plane of the serpentine passageway 106. The inside and outside turn radii 108 and 110 are dimensioned and shaped to eliminate or substantially reduce eddies 112 that would otherwise appear in the coolant flow. Such eddies 112 often appear at these points and just downstream in conventional designs. Eddies 112 spin the coolant in useless circles that cannot divest themselves of the heat they pickup or hold .
In general, making the turning radii at turns broader and wider will, at some point, eliminate eddies 112 in the coolant flow. But these increases must be balanced with the negative effects caused by thickening the walls of casting material. Heat transfer performance can suffer with too much rounding. One way to find an optimum balance of eddie current reduction and improving heat transfer efficiencies to increasing wall
thicknesses and decreasing heat transfer efficiencies is to employ computational fluid dynamics modeling software in
simulations .
Referring again to Figs. 1A-1C, a first serpentine loop 114 turns around a first baffle 116 into a second serpentine loop 118. Baffle 116 is progressively thickened toward a radius end 119 facing two outside radius corners 120 and 121. Such radius end 119, and radius corners 120 and 121, are proportioned to eliminate or substantially reduce any eddies 124 that would otherwise form in the coolant flow if the turns were too sharp and abrupt .
In a manufacturing cost savings alternative, baffle 116 and the others like it can instead have uniformly thick walls that widen into a teardrop profile just as radius end 119 is reached. The facing two outside radius corners 120 and 121 are matched to the teardrop profile reduce eddies as the coolant flow turns.
A continuing series of baffles 126-131 are disposed in the serpentine passageway 106 to provide for additional turning of the circulating fluid coolant into each of a following series of serpentine loops 132-137. Each such turn invites the formation of more eddies 138-143 in the coolant flow. Such eddies are shown here swirling in the same plane as the serpentine
passageway 106.
Each of baffles 126-131 is also progressively thickened toward their distal ends 144-149 and finished in a radius end. The corresponding outside corners that each faces are similar to radius corners 120 and 121. The coolant eventually exits to a chiller through an outlet 150.
Eddies, in general, reduce the cooling performance in the immediate vicinity of the cast metal workpiece 102. In the severe blast furnace applications contemplated for tuyere embodiments of the present invention, such loss of cooling performance at any spot can provoke a catastrophic failure incited by the high environmental heats surrounding it.
Computational fluid dynamics (CFD) is a branch of fluid mechanics that uses numerical methods and algorithms to solve and analyze problems that involve fluid flows. Computers are used to perform the many calculations required to simulate interactions of fluids with surfaces defined by boundary conditions.
Specialized software is commercially available that can report to a user the heat transfer performance and fluid velocities at selected points or modeling cells in a cooling system. For example, the ANSYS CFX software product marketed by ANSYS, Inc. (Canonsburg, PA) provides passage fluid flow modeling CFD software and engineering services. See, www.ansys.com/products/ fluid-dynamics /cfx/ . When used to construct embodiments of the present invention, the prospect of any eddies 112, 124, and 138- 143 in the coolant are revealed by the modeling cells which are calculated to have zero velocity or whirling flows.
In Figs. IB and 1C, each loop 114, 118, and 132-137, of serpentine passageway 106 can be seen to have a generally rectangular cross-section. The cross-sectional area of the serpentine passageway 106 is held constant as much as is possible given the application. If the serpentine passageway 106 must be narrowed or widened at any point, the transitions should be gradual so as not to tempt the development of eddies.
Fig. 2A represents a manufacturing method embodiment of the present invention that can be used to fabricate the cooling system 100 of Fig. 1, and is referred to herein by the general reference numeral 200. Method 200 begins with application requirements 202 that define the performance needed and the environment a cooling system has to operate within. These requirements can include, e.g., external heat loads, inlet pressures, etc. Design constraints 204 further restrict the materials and dimensions available in the cooling system design. An initial design 206 represents a prototype or archetype, and would include the rounded baffle ends and inside corner relieving as represented in Figs. 1A-1C, 4A-4C, 5A-5E, and 6.
A computational fluid dynamic modeling software 208, such as ANSYS CFX, running on a suitable computer system platform produces thermal transfer and velocity simulations for the particular design being iterated. A step 210 presents
information so a trained operator can evaluate whether the design needs further tweaking, especially in the baffle end radii and facing inside corner radii of the serpentine passages inside the cooling system. If so, a revised design 212 is resubmitted to the computational fluid dynamic modeling software 208. The design iterations can stop when the reduction in eddies has apparently been optimized and balanced with other practical considerations, e.g., casting wall thicknesses.
When the design is finalized, sand casting cores are constructed in a step 214. The castings are poured in liquid copper, for example, in a step 216, and machined in a step 218. The sand casting cores usually have stems to support them in position, so after the casting and machining is complete the residual holes in the castings are plugged in a step 220. The plugs can be welded or screwed in. A step 222 includes
inspecting, testing, and shipping the final cooling system.
These workpieces are installed in their particular applications in a step 224.
A principal advantage of the present invention is that workpiece embodiments will have an extended service life that can be budgeted and maintained in a step 226.
Fig. 2B represents another manufacturing method embodiment of the present invention that can be used to construct a milled cooler, and is referred to herein by the general reference numeral 228. Method 228 is very similar to method 200, and begins with application requirements 202 that define the
performance needed and the environment a cooling system is to operate within. These requirements can include, for example, external heat loads, inlet pressures, etc. Design constraints 204 further restrict the materials and dimensions available in the cooling system design.
An initial design 206 represents a prototype or archetype, and would include the rounded baffle ends and inside corner relieving as represented in Figs. 1A-1C, 4A-4C, 5A-5E, and 6. A computational fluid dynamic modeling software 208 running on a suitable computer system platform produces thermal transfer and velocity simulations for the particular design. A step 210 presents information so a trained operator can evaluate whether the design needs further tweaking, especially in the baffle end radii and facing inside corner radii of the serpentine passages inside the cooling system. If so, a revised design 212 is resubmitted to the computational fluid dynamic modeling software 208 for as many iterations as are needed. The design iterations can stop when no further improvements in eddy reduction are obtainable .
At this point method 228 differs, if the design is
finalized, then the piece is worked for finer grain sizes in a step 230. The working can be stopped when leakage tests indicate acceptable levels. The passages are milled in a step 232, and a passageway cover is machined in a step 234. The cover is welded on in a step 236. As in method 200, a step 222 is used to inspect, test, and ship the final cooling system. These
workpieces are installed in their particular applications in a step 224. The embodiments will have an extended service life that is budgeted for and maintained by service personnel in a step 226.
Fig. 3 represents a blast furnace 300 embodiment of the present invention in which a number of tuyeres 302 are used to introduce very hot air into the smelting process. The tuyeres resemble nozzles and their close proximity to the iron smelting usually requires that they be liquid-cooled and constructed of copper .
Blast furnaces chemically reduce and physically convert iron oxides into liquid iron at high temperatures . Blast furnaces are very large, steel stacks lined with refractory brick that are fed a mixture of iron ore, coke and limestone from the top.
Preheated air is blown into the bottom through the tuyeres.
Liquid iron droplets descend to the bottom of the furnace where they collect as slag and liquid iron. These are periodically drained from the furnace as the bottom fills up.
The hot air blown into the furnace at the bottom gets involved in many chemical reactions as it percolates to the top. Blast furnaces are run continuously for years with only short interrupts for maintenance. A common reason to interrupt the otherwise continuous operation of an iron smelting blast furnace is to change out its worn or damaged tuyeres 302. Tuyeres that last longer and suffer fewer injuries are therefore highly desirable because they can reduce downtime and operating costs.
Raw ore removed from the earth includes Hematite (Fe203) or Magnetite (FeaC^) with an iron content of 50% to 70%, and is sized into small pieces about an inch in diameter. An iron-rich powder can be rolled into balls and fired in a furnace to produce marble-sized pellets with 60% to 65% iron. Sinter can also be used which is produced from fine raw ore, coke, sand-sized limestone and waste materials with iron. The fines mixed together for a desired product chemistry. The raw material mix is then placed on a sintering strand and ignited by a gas fired furnace to fuse the coke fines into larger size pieces. The iron ore, pellets and sinter are smelted into the liquid iron produced by the blast furnace. Any of remaining impurities drop into a liquid slag. Hard pieces of coke with high energy values provide the permeability, heat, and gases needed to further reduce and melt the iron ore, pellets and sinter.
An important raw material used in the iron making process is limestone. Limestone mined from the earth by blasting the ore with explosives. It is then crushed and screened to a size that ranges from 0.5 inch to 1.5 inch to become blast furnace flux. This flux can be pure high calcium limestone, dolomitic limestone containing magnesia, or a blend of the two types of limestone.
Since the limestone melts and becomes the slag that removes sulphur and other impurities, the blast furnace operator can adjust the blend accordingly to the desired slag chemistry. A blend target would be to create a low melting point, a high fluidity, and other optimum properties.
All of the raw materials are usually stored in an ore field and transferred to a nearby stock-house before charging. The materials are thereafter loaded into the furnace top, and are subjected to numerous chemical and physical reactions as they descend to the bottom of the furnace.
The iron oxides drop through a series of purifying reactions to soften, melt, and finally trickle out through the coke as liquid iron droplets which fall to the bottom of the furnace. The coke itself drops to the bottom of the furnace where
preheated air and hot blasts from the tuyeres enters the blast furnace. The coke is ignited by the hot blast and immediately reacts to generate more heat.
The reaction takes place in the presence of excess carbon at a high temperature, so the carbon dioxide is reduced to carbon monoxide. The carbon monoxide reduces the iron ore in iron oxide reactions. The limestone also descends in the blast furnace, but it remains a solid while going through a first reaction, CaC03 = CaO + CO2. Such reaction requires energy and starts at about 875°C. The CaO formed from the reaction is used to remove sulphur from the iron, and is necessary before the hot metal can become steel. The sulphur removing reaction is, FeS + CaO + C = CaS + FeO + CO. The CaS becomes part of the slag. The slag is also formed from any remaining Silica (S1O2), Alumina (AI2O3) , Magnesia (MgO) or Calcia (CaO) that entered with the iron ore, pellets, sinter or coke. The liquid slag then trickles through the coke bed to the bottom of the furnace where it will float on top of the more dense liquid iron.
Hot dirty gases exiting the top of the blast furnace proceed through gas cleaning equipment so particulate matter can be removed and the gas cooled. This gas has considerable energy value, so it is burned as a fuel in hot blast stoves that are used to preheat the air entering the blast furnace through the tuyeres. The tuyeres are therefore subjected to air temperatures that can well exceed 900 °C. The melting point of copper is very near these temperatures at 1083°C. Any of the gas not burned in the stoves is sent to a boiler house to generate steam for turbo blowers that generate "cold blast" compressed air for the stoves.
Figs . 4A-4C represent a tuyere embodiment of the present invention, and is referred to herein by the general reference numeral 400. Such are useful in the blast furnace 300 of Fig. 3. Tuyere 400 includes a cast copper metal body 402 having the general shape of a nozzle, and includes a rear flange 404 that connects through a throat 406 to a nose 408 on its front end. A coolant inlet 410 and a coolant outlet 412 are located on the rear flange 404. These connect to an internal serpentine coolant passage 414 like that described in Figs. 1A-1C. The coolant being circulated can be water, oil, or a special liquid mixture.
Several baffles turn the coolant flow within the serpentine pattern. Baffle 416, for example, is like baffles 116, and 126- 131 and radius ends 119, and 144-149 (Figs. 1A-1C) . The inside and outside turn radii of internal serpentine coolant passage 414 are dimensioned and shaped to eliminate eddies in the coolant flow .
The serpentine passages 414 generally proceed in a curved plane within the conical body 402. A number of access holes 420 on an outside face of the cast metal body 402 allow supporting stems for the casting cores during metal cast. The holes in the castings that result are sealed off with plugs 422. Plugs 422 may be conventionally pipe-threaded, welded, brazed, soldered, pressed in, etc.
Figs . 5A-5E represent a cooler embodiment of the present invention, and is referred to herein by the general reference numeral 500. A plate body 502 has a coolant piping inlet 504 and an outlet 506 at one end. These provide external connections to a serpentine coolant passageway 508 inside. Three baffles 520- 522 turn the coolant flow around their thickened and rounded ends 523-525 and inside corresponding facing corners 526-531. The geometry and rounding of these ends and corners is designed and verified by simulations, modeling and prototypes to eliminate hot spots when cooler 500 is heavily heat loaded. Manufacturing methods 200 and 228 (Figs. 2A and 2B) can be used to do the design and fabrication, for example.
Fig. 6 represents a serpentine loop turn 600 in a coolant passageway disposed in a cast or machined cooler 601 in an embodiment of the present invention. A baffle 602 thickens and then rounds off at a radius end 604, e.g., in a radius 606. A pair of inside rounded corners 608 and 610 face the radius end 604. Coolant flow in a passageway loop 612 turns into a next passageway loop 614 around radius end 604 of baffle 602. The widths 613-615 are all kept constant as much as is practical when casting metal pieces. The object of keeping the widths constant is to not encourage nor sustain eddies where the coolant flows around the corners in a baffle.
In one embodiment, angles "A" and "B" are each less than 90°, and A+B is less than 180°. In other words, the center lines of passageway loops 612 and 614 are not parallel to one another. Such an arrangement would help in packing the passageway loops 612 and 614 tighter, especially where every turn is like that of Fig. 6, and the overall design of a serpentine passageway is symmetrical .
Tuyeres and other coolers can include external surface coatings of refractory or metal, and they can be overlayed with metal. Coatings can be applied in many ways, for example by vapor deposition, manual or hand applied such as painted or toweled, flame sprayed, dipped, and electroplating. Overlays are metal coatings applied using a high energy sources such as welding, laser, flame, or explosion bonding.
The need, type, location, and thickness of such coatings and overlays are generally empirically derived. Coolers can also be manufactured with grooves or pockets filled with refractory.
Tuyere embodiments are manufactured from either a casting or machining a fine-grained metal part. With a casting, the coolant passages are cast in using molds. With a machined part, a tuyere, for example, must be made in two parts. A conventional example can be seen in United states Patent 3,840,219, Fig. 7.
In a two-piece tuyere, the outer or inner part is machined, and a closure piece is used to close the water passages and complete the cooler. Such tuyeres may be fluid or gas injected.
In general, cooler embodiments of the present invention include profiling the coolant passages during design for the elimination of eddies where ever the cooler will be exposed to severe external heat loads.
Although the present invention has been described in terms of the presently preferred embodiments, it is to be understood that the disclosure is not to be interpreted as limiting.
Various alterations and modifications will no doubt become apparent to those skilled in the art after having read the above disclosure. Accordingly, it is intended that the appended claims be interpreted as covering all alterations and modifications as fall within the "true" spirit and scope of the invention.
What is claimed is:

Claims

IN THE CLAIMS
1. A cooling system, comprising:
a cast or milled metal workpiece;
a serpentine passageway providing for a circulating fluid coolant disposed in the workpiece, and generally proceeding in a single flat, folded, or curved plane; and
a series of baffles disposed within the serpentine passageway and providing for the turning of said circulating fluid coolant in each of a series of serpentine loops;
characterized by:
a progressive thickening of each one of the series of baffles towards their respective distal ends and finishing in a radius end and providing for a turning around of said circulating fluid coolant into a next one of said series of serpentine loops;
a radius of the inside of the serpentine passageway relative to said single flat or curved plane and radial to each progressive thickening of each one of the series of baffles where a turning is provided to said circulating fluid coolant into a next one of said series of serpentine loops;
wherein, said turnings are such that eddies in said circulating fluid coolant are eliminated or reduced over what would otherwise exist.
2. The cooling system of Claim 1, further comprising:
a generally rectangular cross-sectional patterning of the serpentine passageway.
3. The cooling system of Claim 1, further comprising:
a blast furnace tuyere in which the cast or milled metal workpiece is disposed.
4. The cooling system of Claim 1, further comprising:
a number of access holes on an outside face of the cast metal workpiece to allow support of casting cores during metal cast, and that are sealed off with plugs.
5. A tuyere, comprising:
a cast or milled metal body having the general shape of a nozzle and having a front end and outer surface for exposure to heat during operation and connections for a circulating fluid coolant;
a serpentine passageway for said circulating fluid coolant disposed in the cast or milled metal body, and generally proceeding in a single flat or curved plane; and
a series of baffles disposed within the serpentine passageway and providing for the turning of said circulating fluid coolant in each of a series of serpentine loops;
characterized by:
a progressive thickening of each one of the series of baffles towards their respective distal ends and finishing in a radius end around which said circulating fluid coolant is turned into a next one of said series of serpentine loops; and
a radius of the inside of the serpentine passageway relative to said single flat or curved plane and radial to each thickening of each one of the series of baffles where said circulating fluid coolant is turned into a next one of said series of serpentine loops;
wherein, eddies in said circulating fluid coolant are reduced .
6. A blast furnace, characterized by at least one tuyere including :
a cast or milled metal body having the general shape a nozzle and having a front end for exposure to heat during operation and a back end with connections for a circulating fluid coolant ;
a serpentine passageway for said circulating fluid coolant disposed in the cast or milled metal body, and generally proceeding in a single flat or curved plane;
a series of baffles disposed within the serpentine passageway and providing for the turning of said circulating fluid coolant in each of a series of serpentine loops;
a thickening of each one of the series of baffles towards their respective distal ends and finishing in a radius end around which said circulating fluid coolant is turned into a next one of said series of serpentine loops; and
a radius of the inside of the serpentine passageway relative to said single flat or curved plane and radial to each thickening of each one of the series of baffles where said circulating fluid coolant is turned into a next one of said series of serpentine loops;
wherein, eddies in said circulating fluid coolant are reduced .
EP10823777.7A 2009-10-16 2010-08-05 Cooling system for blast furnace tuyere cooling Active EP2488669B1 (en)

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Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020023169A1 (en) * 2018-07-22 2020-01-30 Macrae Technologies, Inc. High heat flux regime coolers
US20190276906A1 (en) * 2011-03-30 2019-09-12 Macrae Technologies, Inc. High heat flux regime coolers
US10684078B1 (en) * 2019-05-24 2020-06-16 Macrae Technologies, Inc. Method for stabilizing thermal conduction of block coolers with cast-in coolant pipes
US9038867B2 (en) * 2011-05-11 2015-05-26 Tyk America, Inc. Degasser snorkel with serpentine flow path cooling
US9644246B2 (en) 2011-05-11 2017-05-09 Tyk America, Inc. Degasser snorkel with serpentine flow path cooling
US9243186B2 (en) 2012-08-17 2016-01-26 Suncoke Technology And Development Llc. Coke plant including exhaust gas sharing
US9359554B2 (en) 2012-08-17 2016-06-07 Suncoke Technology And Development Llc Automatic draft control system for coke plants
US10047295B2 (en) 2012-12-28 2018-08-14 Suncoke Technology And Development Llc Non-perpendicular connections between coke oven uptakes and a hot common tunnel, and associated systems and methods
WO2014105063A1 (en) 2012-12-28 2014-07-03 Suncoke Technology And Development Llc. Systems and methods for maintaining a hot car in a coke plant
EP2938426A4 (en) 2012-12-28 2016-08-10 Suncoke Technology & Dev Llc Systems and methods for removing mercury from emissions
CA2896478C (en) 2012-12-28 2016-06-07 Suncoke Technology And Development Llc. Vent stack lids and associated systems and methods
US9476547B2 (en) 2012-12-28 2016-10-25 Suncoke Technology And Development Llc Exhaust flow modifier, duct intersection incorporating the same, and methods therefor
US10883051B2 (en) 2012-12-28 2021-01-05 Suncoke Technology And Development Llc Methods and systems for improved coke quenching
US9273250B2 (en) 2013-03-15 2016-03-01 Suncoke Technology And Development Llc. Methods and systems for improved quench tower design
CA2935325C (en) 2013-12-31 2022-11-22 Suncoke Technology And Development Llc Methods for decarbonizing coking ovens, and associated systems and devices
EP3161106B1 (en) 2014-06-30 2019-09-04 Suncoke Technology and Development LLC Horizontal heat recovery coke ovens having monolith crowns
AU2015308687A1 (en) 2014-08-28 2017-03-16 Suncoke Technology And Development Llc Improved burn profiles for coke operations
DE102014217728A1 (en) * 2014-09-04 2016-03-10 Mahle International Gmbh cooling plate
AU2015317909B2 (en) * 2014-09-15 2020-11-05 Suncoke Technology And Development Llc Coke ovens having monolith component construction
KR102516994B1 (en) 2014-12-31 2023-03-31 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 Multi-modal bed of caulking material
US11060032B2 (en) 2015-01-02 2021-07-13 Suncoke Technology And Development Llc Integrated coke plant automation and optimization using advanced control and optimization techniques
WO2016109854A1 (en) 2015-01-02 2016-07-07 Suncoke Technology And Development Llc Integrated coke plant automation and optimization using advanced control and optimization techniques
CA3203921A1 (en) 2015-12-28 2017-07-06 Suncoke Technology And Development Llc Method and system for dynamically charging a coke oven
RU2706211C2 (en) * 2016-01-25 2019-11-14 Ансалдо Энерджиа Свитзерлэнд Аг Cooled wall of turbine component and cooling method of this wall
BR112018074924A2 (en) 2016-06-03 2019-03-12 Suncoke Technology And Development Llc methods and systems to automatically generate corrective action in an industrial facility
US10443437B2 (en) * 2016-11-03 2019-10-15 General Electric Company Interwoven near surface cooled channels for cooled structures
KR102392443B1 (en) 2017-05-23 2022-04-28 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 Systems and methods for repairing coke ovens
WO2020140095A1 (en) 2018-12-28 2020-07-02 Suncoke Technology And Development Llc Spring-loaded heat recovery oven system and method
CA3125279A1 (en) 2018-12-28 2020-07-02 Suncoke Technology And Development Llc Improved oven uptakes
CA3125332C (en) 2018-12-28 2022-04-26 Suncoke Technology And Development Llc Decarbonization of coke ovens, and associated systems and methods
US11071935B2 (en) 2018-12-28 2021-07-27 Suncoke Technology And Development Llc Particulate detection for industrial facilities, and associated systems and methods
BR112021012455B1 (en) 2018-12-28 2023-10-24 Suncoke Technology And Development Llc COKE OVEN
BR112021012653B1 (en) 2018-12-28 2024-01-23 Suncoke Technology And Development Llc FLEXIBLE SEAL FOR COKE MANUFACTURING INSTALLATION, METHODS FOR BUILDING OR REPAIRING A TUNNEL IN COKE PLANT AND MECHANICAL ASSEMBLY
BR122023020289A2 (en) 2018-12-31 2024-01-23 SunCoke Technology and Development LLC COKE PLANT AND METHOD OF MODIFYING A HEAT RECOVERY VALUE GENERATOR (HRSG)
WO2020142391A1 (en) 2018-12-31 2020-07-09 Suncoke Technology And Development Llc Methods and systems for providing corrosion resistant surfaces in contaminant treatment systems
CN110094985A (en) * 2019-05-22 2019-08-06 汕头华兴冶金设备股份有限公司 A kind of novel copper cooling plate and its manufacturing method
CA3145190A1 (en) * 2019-06-24 2020-12-30 Macrae Technologies, Inc. Manufacturing methods for improving, and for the long-term stabilization of the overall thermal conduction of block coolers with cast-in coolant pipes
US11390551B2 (en) * 2019-10-01 2022-07-19 Owens-Brockway Glass Container Inc. Cooling panel for a melter
US20220388886A1 (en) * 2020-08-14 2022-12-08 Owens-Brockway Glass Container Inc. Cast cullet-based layer on wall Panel for a Melter
EP4146767A4 (en) 2020-05-03 2024-07-31 Suncoke Tech & Development Llc High-quality coke products
CN112283741A (en) * 2020-10-30 2021-01-29 陕西能源赵石畔煤电有限公司 Device for preventing corrosion of water cooled wall of high-sulfur coal million units boiler
CN114061322B (en) * 2021-09-02 2024-02-27 丰城市天壕新能源有限公司 Intelligent circulating boiler for generating electricity by using waste heat of coke dry quenching
US11946108B2 (en) 2021-11-04 2024-04-02 Suncoke Technology And Development Llc Foundry coke products and associated processing methods via cupolas
JP2024511901A (en) 2021-11-04 2024-03-15 サンコーク テクノロジー アンド ディベロップメント リミテッド ライアビリティ カンパニー Foundry Coke Products and Related Systems, Apparatus and Methods
WO2024097971A1 (en) 2022-11-04 2024-05-10 Suncoke Technology And Development Llc Coal blends, foundry coke products, and associated systems, devices, and methods

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3599952A (en) * 1969-05-07 1971-08-17 Inland Steel Co High-velocity tuyere with variable size cooling medium passage
US4128232A (en) * 1977-06-30 1978-12-05 Pennsylvania Engineering Corporation Cooling assembly for metallurgical vessels
GB2131137A (en) * 1982-12-02 1984-06-13 Brown & Sons Ltd James Cooler for a furnace
RU2170265C2 (en) * 1997-01-08 2001-07-10 Поль Вурт С.А. Method of manufacture of cooling plates for furnaces used in ferrous metallurgy
KR100398404B1 (en) * 1999-12-24 2003-09-19 주식회사 포스코 Injection control apparatus for pulverized coal at blast furnace
JP2002060817A (en) 2000-08-11 2002-02-28 Nippon Steel Corp Stave cooler reduced in pressure loss of cooling water
JP3802745B2 (en) * 2000-10-26 2006-07-26 新日本製鐵株式会社 Stave cooler
US6351381B1 (en) * 2001-06-20 2002-02-26 Thermal Corp. Heat management system
FI118391B (en) * 2001-12-27 2007-10-31 Vahterus Oy Device for improving heat transfer in round plate heat exchangers
WO2003102248A2 (en) * 2002-05-30 2003-12-11 Dofasco Inc. Tuyere cooling system
RU2204611C1 (en) * 2002-10-14 2003-05-20 ОАО Челябинский металлургический комбинат "МЕЧЕЛ" Copper plate-type refrigerator for blast furnace
SE526831C2 (en) * 2004-03-12 2005-11-08 Alfa Laval Corp Ab Heat exchanger plate and plate package
US7824604B2 (en) * 2006-05-17 2010-11-02 Air Liquide Advanced Technologies U.S. Llc Methods of implementing a water-cooling system into a burner panel and related apparatuses

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2011046666A3 *

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US8268233B2 (en) 2012-09-18
WO2011046666A2 (en) 2011-04-21
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BR112012008401A2 (en) 2019-10-01
EP2488669B1 (en) 2018-11-07
CA2776958C (en) 2014-12-16
KR101319215B1 (en) 2013-10-16
US20110088600A1 (en) 2011-04-21
CN102822356B (en) 2015-03-11
RU2518244C2 (en) 2014-06-10
RU2012112898A (en) 2013-11-27
CA2776958A1 (en) 2011-04-21
MX2012004245A (en) 2012-06-27
EP2488669A4 (en) 2017-07-19
CN102822356A (en) 2012-12-12
KR20120056292A (en) 2012-06-01

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