EP2488669A2 - Blast furnace tuyere cooling - Google Patents
Blast furnace tuyere coolingInfo
- Publication number
- EP2488669A2 EP2488669A2 EP10823777A EP10823777A EP2488669A2 EP 2488669 A2 EP2488669 A2 EP 2488669A2 EP 10823777 A EP10823777 A EP 10823777A EP 10823777 A EP10823777 A EP 10823777A EP 2488669 A2 EP2488669 A2 EP 2488669A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- series
- serpentine
- circulating fluid
- fluid coolant
- cast
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F7/00—Elements not covered by group F28F1/00, F28F3/00 or F28F5/00
- F28F7/02—Blocks traversed by passages for heat-exchange media
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/16—Tuyéres
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/16—Tuyéres
- C21B7/163—Blowpipe assembly
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B1/00—Shaft or like vertical or substantially vertical furnaces
- F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
- F27B1/16—Arrangements of tuyeres
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B1/00—Shaft or like vertical or substantially vertical furnaces
- F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
- F27B1/24—Cooling arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D9/00—Cooling of furnaces or of charges therein
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/02—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by influencing fluid boundary
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
- F28F3/12—Elements constructed in the shape of a hollow panel, e.g. with channels
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/10—Cooling; Devices therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49316—Impeller making
- Y10T29/49336—Blade making
- Y10T29/49339—Hollow blade
- Y10T29/49341—Hollow blade with cooling passage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4935—Heat exchanger or boiler making
- Y10T29/49359—Cooling apparatus making, e.g., air conditioner, refrigerator
Definitions
- the present invention relates to gas and fluid cooling of equipment, and more particularly to methods and devices for eliminating eddy currents in high velocity coolant flows through the serpentine coolant passageways of blast furnace tuyeres.
- Effective cooling is widely needed in various kinds of industrial equipment and machinery. Engines, smelting furnaces, and other devices can generate enough heat to destroy themselves if cooling were not used to keep the operating temperatures within acceptable limits. Three modes of cooling or heat transfer are possible, thermal radiation, heat conduction, and heat convection. Ordinary cars and trucks use coolants
- Fluid and gas coolers are widely used in metallurgical furnaces, molds for solidification of molten materials, burners, lances, electrode clamps, tuyere forced-air nozzles in iron smelting blast furnaces, etc.
- the most common kinds of cooling medias employed are forced air, circulating water, common oils, and synthetic oils.
- Cooling passages can be manufactured inside metal pieces by drilling, machining, or casting. Coolant pipes of one material can be cast inside the bulk of a second type of material, or the passages can be cast inside using thin wall techniques as is conventional in automobile engine blocks. For example, a copper- nickel pipe can be cast inside a bulk copper piece.
- the round cross section of pipes further reduces the effective cooling channel area, and thus the flow volume.
- a rectangular cross section would better fill the bulk area available .
- Coolers with cored water passages can be manufactured in a single piece. But, with one serious complication.
- the sand cores must somehow be perched in the mold to define the water passages during the casting pour. This generally means
- stems in the sand must be included. These stems create holes in the subsequent castings that must be plugged or welded-shut later.
- a dynamic gas micro-flow measurement can be used to detect the existence of leak flow paths or micro-channels. It looks for and detects pinholes in the material.
- the leak tightness in a metallic gas or fluid cooled piece can be improved by hot working or forging the hot face to refine the metal crystal grain size.
- the average grain size for cast copper can be reduced from approximately ten millimeters to less than one millimeter using hot rolling, hot pressing, etc.
- the exposed water passages are then milled in to the face of the worked part.
- a cover plate or second piece is required to complete the water passage and finish the milled piece.
- Rectangular cross-section coolant passages with rounded corners occupy a larger percentage of the available height and width inside the piece.
- Coolers built this way need less metal, and their cooling efficiencies increase proportionately.
- invention comprises carefully controlled turning radii and profiles inside the serpentine cooling fluid passages cast or milled into a work piece.
- Individual, interdigitated baffles are contoured in the plane of coolant flow to have walls that progressively thicken and then round off at their distal ends.
- the outside radii at these turns are similarly rounded and controlled such that the coolant flows will not be swirled into eddies .
- Fig. 1A is a cross sectional diagram of a cooling system embodiment of the present invention taken along the general plane of a serpentine coolant passageway cast within;
- Fig. IB is a cross sectional diagram of the cooling system of Fig. 1A taken along line IB-IB, and across the general plane of a serpentine coolant passageway cast within;
- Fig. 1C is a cross sectional diagram of the cooling system of Fig. 1A taken along line 1C-1C, and across the general plane of a serpentine coolant passageway cast within where the ends of several baffles are thickest;
- Figs. 2A-2B are flowchart diagrams of similar method embodiments of the present invention for manufacturing the cooling systems, coolers, and tuyeres of Figs. 1A, IB, 1C, 3, 4A, 4B, and 4C, 5A-5E, and 6;
- Fig. 3 is a cutaway diagram of a blast furnace embodiment of the present invention that can include the tuyeres of Figs. 4A, 4B, and 4C;
- Fig. 4A is a rear view of a tuyere embodiment of the present invention useful in the blast furnace of Fig. 3;
- Fig. 4B is a longitudinal cross sectional diagram of the tuyere of Fig. 4A;
- Fig. 4C is a lateral cross sectional diagram of a portion of the conical body of the tuyere of Figs. 4A and 4B and laid out flat for this illustration;
- Figs. 5A-5E are, respectively, perspective, wide end, top, narrow end, and side view diagrams of a cooler plate embodiment of the present invention.
- Fig. 6 is a cross sectional view diagram along the plane of a serpentine loop turn in a coolant passageway disposed in a cast or machined cooler in an embodiment of the present invention. While the invention is amenable to various modifications and alternative forms, specifics thereof have been shown by way of example in the drawings and will be described in detail. It should be understood, however, that the intention is not to limit the invention to the particular embodiments described. On the contrary, the intention is to cover all modifications,
- Figs. 1A-1C represents a cooling system embodiment of the present invention, and is referred to herein by the general reference numeral 100.
- Cooling system 100 comprises a cast metal workpiece 102 with an inlet 104 into a serpentine passageway 106 for a circulating fluid coolant.
- a first turn in the serpentine passageway 106 has an inside turn radius 108 and an outside turn radius 110 with respect to the general plane of the serpentine passageway 106.
- the inside and outside turn radii 108 and 110 are dimensioned and shaped to eliminate or substantially reduce eddies 112 that would otherwise appear in the coolant flow. Such eddies 112 often appear at these points and just downstream in conventional designs. Eddies 112 spin the coolant in useless circles that cannot divest themselves of the heat they pickup or hold .
- a first serpentine loop 114 turns around a first baffle 116 into a second serpentine loop 118.
- Baffle 116 is progressively thickened toward a radius end 119 facing two outside radius corners 120 and 121.
- Such radius end 119, and radius corners 120 and 121, are proportioned to eliminate or substantially reduce any eddies 124 that would otherwise form in the coolant flow if the turns were too sharp and abrupt .
- baffle 116 and the others like it can instead have uniformly thick walls that widen into a teardrop profile just as radius end 119 is reached.
- the facing two outside radius corners 120 and 121 are matched to the teardrop profile reduce eddies as the coolant flow turns.
- baffles 126-131 are disposed in the serpentine passageway 106 to provide for additional turning of the circulating fluid coolant into each of a following series of serpentine loops 132-137. Each such turn invites the formation of more eddies 138-143 in the coolant flow. Such eddies are shown here swirling in the same plane as the serpentine
- baffles 126-131 is also progressively thickened toward their distal ends 144-149 and finished in a radius end.
- the corresponding outside corners that each faces are similar to radius corners 120 and 121.
- the coolant eventually exits to a chiller through an outlet 150.
- CFD Computational fluid dynamics
- Specialized software is commercially available that can report to a user the heat transfer performance and fluid velocities at selected points or modeling cells in a cooling system.
- the ANSYS CFX software product marketed by ANSYS, Inc. (Canonsburg, PA) provides passage fluid flow modeling CFD software and engineering services. See, www.ansys.com/products/ fluid-dynamics /cfx/ .
- the prospect of any eddies 112, 124, and 138- 143 in the coolant are revealed by the modeling cells which are calculated to have zero velocity or whirling flows.
- each loop 114, 118, and 132-137, of serpentine passageway 106 can be seen to have a generally rectangular cross-section.
- the cross-sectional area of the serpentine passageway 106 is held constant as much as is possible given the application. If the serpentine passageway 106 must be narrowed or widened at any point, the transitions should be gradual so as not to tempt the development of eddies.
- Fig. 2A represents a manufacturing method embodiment of the present invention that can be used to fabricate the cooling system 100 of Fig. 1, and is referred to herein by the general reference numeral 200.
- Method 200 begins with application requirements 202 that define the performance needed and the environment a cooling system has to operate within. These requirements can include, e.g., external heat loads, inlet pressures, etc.
- Design constraints 204 further restrict the materials and dimensions available in the cooling system design.
- An initial design 206 represents a prototype or archetype, and would include the rounded baffle ends and inside corner relieving as represented in Figs. 1A-1C, 4A-4C, 5A-5E, and 6.
- a computational fluid dynamic modeling software 208 such as ANSYS CFX, running on a suitable computer system platform produces thermal transfer and velocity simulations for the particular design being iterated.
- a step 210 presents
- a revised design 212 is resubmitted to the computational fluid dynamic modeling software 208.
- the design iterations can stop when the reduction in eddies has apparently been optimized and balanced with other practical considerations, e.g., casting wall thicknesses.
- sand casting cores are constructed in a step 214.
- the castings are poured in liquid copper, for example, in a step 216, and machined in a step 218.
- the sand casting cores usually have stems to support them in position, so after the casting and machining is complete the residual holes in the castings are plugged in a step 220.
- the plugs can be welded or screwed in.
- a step 222 includes
- a principal advantage of the present invention is that workpiece embodiments will have an extended service life that can be budgeted and maintained in a step 226.
- Fig. 2B represents another manufacturing method embodiment of the present invention that can be used to construct a milled cooler, and is referred to herein by the general reference numeral 228.
- Method 228 is very similar to method 200, and begins with application requirements 202 that define the
- An initial design 206 represents a prototype or archetype, and would include the rounded baffle ends and inside corner relieving as represented in Figs. 1A-1C, 4A-4C, 5A-5E, and 6.
- a computational fluid dynamic modeling software 208 running on a suitable computer system platform produces thermal transfer and velocity simulations for the particular design.
- a step 210 presents information so a trained operator can evaluate whether the design needs further tweaking, especially in the baffle end radii and facing inside corner radii of the serpentine passages inside the cooling system. If so, a revised design 212 is resubmitted to the computational fluid dynamic modeling software 208 for as many iterations as are needed. The design iterations can stop when no further improvements in eddy reduction are obtainable .
- a step 230 is worked for finer grain sizes in a step 230.
- the working can be stopped when leakage tests indicate acceptable levels.
- the passages are milled in a step 232, and a passageway cover is machined in a step 234.
- the cover is welded on in a step 236.
- a step 222 is used to inspect, test, and ship the final cooling system.
- workpieces are installed in their particular applications in a step 224.
- the embodiments will have an extended service life that is budgeted for and maintained by service personnel in a step 226.
- Fig. 3 represents a blast furnace 300 embodiment of the present invention in which a number of tuyeres 302 are used to introduce very hot air into the smelting process.
- the tuyeres resemble nozzles and their close proximity to the iron smelting usually requires that they be liquid-cooled and constructed of copper .
- Blast furnaces chemically reduce and physically convert iron oxides into liquid iron at high temperatures .
- Blast furnaces are very large, steel stacks lined with refractory brick that are fed a mixture of iron ore, coke and limestone from the top.
- Preheated air is blown into the bottom through the tuyeres.
- Liquid iron droplets descend to the bottom of the furnace where they collect as slag and liquid iron. These are periodically drained from the furnace as the bottom fills up.
- Raw ore removed from the earth includes Hematite (Fe 2 0 3 ) or Magnetite (FeaC ⁇ ) with an iron content of 50% to 70%, and is sized into small pieces about an inch in diameter.
- An iron-rich powder can be rolled into balls and fired in a furnace to produce marble-sized pellets with 60% to 65% iron.
- Sinter can also be used which is produced from fine raw ore, coke, sand-sized limestone and waste materials with iron. The fines mixed together for a desired product chemistry.
- the raw material mix is then placed on a sintering strand and ignited by a gas fired furnace to fuse the coke fines into larger size pieces.
- the iron ore, pellets and sinter are smelted into the liquid iron produced by the blast furnace. Any of remaining impurities drop into a liquid slag.
- Hard pieces of coke with high energy values provide the permeability, heat, and gases needed to further reduce and melt the iron ore, pellets and sinter.
- limestone An important raw material used in the iron making process is limestone. Limestone mined from the earth by blasting the ore with explosives. It is then crushed and screened to a size that ranges from 0.5 inch to 1.5 inch to become blast furnace flux. This flux can be pure high calcium limestone, dolomitic limestone containing magnesia, or a blend of the two types of limestone.
- a blend target would be to create a low melting point, a high fluidity, and other optimum properties.
- All of the raw materials are usually stored in an ore field and transferred to a nearby stock-house before charging.
- the materials are thereafter loaded into the furnace top, and are subjected to numerous chemical and physical reactions as they descend to the bottom of the furnace.
- the iron oxides drop through a series of purifying reactions to soften, melt, and finally trickle out through the coke as liquid iron droplets which fall to the bottom of the furnace.
- the coke itself drops to the bottom of the furnace where
- preheated air and hot blasts from the tuyeres enters the blast furnace.
- the coke is ignited by the hot blast and immediately reacts to generate more heat.
- the reaction takes place in the presence of excess carbon at a high temperature, so the carbon dioxide is reduced to carbon monoxide.
- the carbon monoxide reduces the iron ore in iron oxide reactions.
- Such reaction requires energy and starts at about 875°C.
- the CaO formed from the reaction is used to remove sulphur from the iron, and is necessary before the hot metal can become steel.
- the CaS becomes part of the slag.
- the slag is also formed from any remaining Silica (S1O 2 ), Alumina (AI 2 O 3 ) , Magnesia (MgO) or Calcia (CaO) that entered with the iron ore, pellets, sinter or coke.
- the liquid slag then trickles through the coke bed to the bottom of the furnace where it will float on top of the more dense liquid iron.
- Hot dirty gases exiting the top of the blast furnace proceed through gas cleaning equipment so particulate matter can be removed and the gas cooled.
- This gas has considerable energy value, so it is burned as a fuel in hot blast stoves that are used to preheat the air entering the blast furnace through the tuyeres.
- the tuyeres are therefore subjected to air temperatures that can well exceed 900 °C.
- the melting point of copper is very near these temperatures at 1083°C. Any of the gas not burned in the stoves is sent to a boiler house to generate steam for turbo blowers that generate "cold blast" compressed air for the stoves.
- Figs . 4A-4C represent a tuyere embodiment of the present invention, and is referred to herein by the general reference numeral 400. Such are useful in the blast furnace 300 of Fig. 3.
- Tuyere 400 includes a cast copper metal body 402 having the general shape of a nozzle, and includes a rear flange 404 that connects through a throat 406 to a nose 408 on its front end.
- a coolant inlet 410 and a coolant outlet 412 are located on the rear flange 404. These connect to an internal serpentine coolant passage 414 like that described in Figs. 1A-1C.
- the coolant being circulated can be water, oil, or a special liquid mixture.
- baffle 416 for example, is like baffles 116, and 126- 131 and radius ends 119, and 144-149 (Figs. 1A-1C) .
- the inside and outside turn radii of internal serpentine coolant passage 414 are dimensioned and shaped to eliminate eddies in the coolant flow .
- the serpentine passages 414 generally proceed in a curved plane within the conical body 402.
- a number of access holes 420 on an outside face of the cast metal body 402 allow supporting stems for the casting cores during metal cast.
- the holes in the castings that result are sealed off with plugs 422.
- Plugs 422 may be conventionally pipe-threaded, welded, brazed, soldered, pressed in, etc.
- Figs . 5A-5E represent a cooler embodiment of the present invention, and is referred to herein by the general reference numeral 500.
- a plate body 502 has a coolant piping inlet 504 and an outlet 506 at one end. These provide external connections to a serpentine coolant passageway 508 inside.
- Three baffles 520- 522 turn the coolant flow around their thickened and rounded ends 523-525 and inside corresponding facing corners 526-531. The geometry and rounding of these ends and corners is designed and verified by simulations, modeling and prototypes to eliminate hot spots when cooler 500 is heavily heat loaded. Manufacturing methods 200 and 228 (Figs. 2A and 2B) can be used to do the design and fabrication, for example.
- Fig. 6 represents a serpentine loop turn 600 in a coolant passageway disposed in a cast or machined cooler 601 in an embodiment of the present invention.
- a baffle 602 thickens and then rounds off at a radius end 604, e.g., in a radius 606.
- a pair of inside rounded corners 608 and 610 face the radius end 604.
- Coolant flow in a passageway loop 612 turns into a next passageway loop 614 around radius end 604 of baffle 602.
- the widths 613-615 are all kept constant as much as is practical when casting metal pieces. The object of keeping the widths constant is to not encourage nor sustain eddies where the coolant flows around the corners in a baffle.
- angles "A" and “B” are each less than 90°, and A+B is less than 180°.
- the center lines of passageway loops 612 and 614 are not parallel to one another. Such an arrangement would help in packing the passageway loops 612 and 614 tighter, especially where every turn is like that of Fig. 6, and the overall design of a serpentine passageway is symmetrical .
- Tuyeres and other coolers can include external surface coatings of refractory or metal, and they can be overlayed with metal. Coatings can be applied in many ways, for example by vapor deposition, manual or hand applied such as painted or toweled, flame sprayed, dipped, and electroplating. Overlays are metal coatings applied using a high energy sources such as welding, laser, flame, or explosion bonding.
- Coolers can also be manufactured with grooves or pockets filled with refractory.
- Tuyere embodiments are manufactured from either a casting or machining a fine-grained metal part. With a casting, the coolant passages are cast in using molds. With a machined part, a tuyere, for example, must be made in two parts. A conventional example can be seen in United states Patent 3,840,219, Fig. 7.
- a closure piece is used to close the water passages and complete the cooler.
- tuyeres may be fluid or gas injected.
- cooler embodiments of the present invention include profiling the coolant passages during design for the elimination of eddies where ever the cooler will be exposed to severe external heat loads.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Furnace Details (AREA)
- Blast Furnaces (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/581,088 US8268233B2 (en) | 2009-10-16 | 2009-10-16 | Eddy-free high velocity cooler |
PCT/US2010/044479 WO2011046666A2 (en) | 2009-10-16 | 2010-08-05 | Blast furnace tuyere cooling |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2488669A2 true EP2488669A2 (en) | 2012-08-22 |
EP2488669A4 EP2488669A4 (en) | 2017-07-19 |
EP2488669B1 EP2488669B1 (en) | 2018-11-07 |
Family
ID=43876784
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10823777.7A Active EP2488669B1 (en) | 2009-10-16 | 2010-08-05 | Cooling system for blast furnace tuyere cooling |
Country Status (9)
Country | Link |
---|---|
US (1) | US8268233B2 (en) |
EP (1) | EP2488669B1 (en) |
KR (1) | KR101319215B1 (en) |
CN (1) | CN102822356B (en) |
BR (1) | BR112012008401A2 (en) |
CA (1) | CA2776958C (en) |
MX (1) | MX2012004245A (en) |
RU (1) | RU2518244C2 (en) |
WO (1) | WO2011046666A2 (en) |
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EP3161106B1 (en) | 2014-06-30 | 2019-09-04 | Suncoke Technology and Development LLC | Horizontal heat recovery coke ovens having monolith crowns |
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DE102014217728A1 (en) * | 2014-09-04 | 2016-03-10 | Mahle International Gmbh | cooling plate |
AU2015317909B2 (en) * | 2014-09-15 | 2020-11-05 | Suncoke Technology And Development Llc | Coke ovens having monolith component construction |
KR102516994B1 (en) | 2014-12-31 | 2023-03-31 | 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 | Multi-modal bed of caulking material |
US11060032B2 (en) | 2015-01-02 | 2021-07-13 | Suncoke Technology And Development Llc | Integrated coke plant automation and optimization using advanced control and optimization techniques |
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- 2009-10-16 US US12/581,088 patent/US8268233B2/en not_active Expired - Fee Related
-
2010
- 2010-08-05 BR BR112012008401A patent/BR112012008401A2/en not_active Application Discontinuation
- 2010-08-05 WO PCT/US2010/044479 patent/WO2011046666A2/en active Application Filing
- 2010-08-05 KR KR1020127009243A patent/KR101319215B1/en active IP Right Grant
- 2010-08-05 RU RU2012112898/02A patent/RU2518244C2/en not_active IP Right Cessation
- 2010-08-05 MX MX2012004245A patent/MX2012004245A/en active IP Right Grant
- 2010-08-05 EP EP10823777.7A patent/EP2488669B1/en active Active
- 2010-08-05 CA CA2776958A patent/CA2776958C/en not_active Expired - Fee Related
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WO2011046666A2 (en) | 2011-04-21 |
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BR112012008401A2 (en) | 2019-10-01 |
EP2488669B1 (en) | 2018-11-07 |
CA2776958C (en) | 2014-12-16 |
KR101319215B1 (en) | 2013-10-16 |
US20110088600A1 (en) | 2011-04-21 |
CN102822356B (en) | 2015-03-11 |
RU2518244C2 (en) | 2014-06-10 |
RU2012112898A (en) | 2013-11-27 |
CA2776958A1 (en) | 2011-04-21 |
MX2012004245A (en) | 2012-06-27 |
EP2488669A4 (en) | 2017-07-19 |
CN102822356A (en) | 2012-12-12 |
KR20120056292A (en) | 2012-06-01 |
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