EP2477601A2 - Compositions de soin personnel avec des dispersions aqueuses de copolymère éthylène-acide acrylique - Google Patents
Compositions de soin personnel avec des dispersions aqueuses de copolymère éthylène-acide acryliqueInfo
- Publication number
- EP2477601A2 EP2477601A2 EP10755297A EP10755297A EP2477601A2 EP 2477601 A2 EP2477601 A2 EP 2477601A2 EP 10755297 A EP10755297 A EP 10755297A EP 10755297 A EP10755297 A EP 10755297A EP 2477601 A2 EP2477601 A2 EP 2477601A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- personal care
- care composition
- hair
- ethylene
- aqueous dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 150000001746 carotenes Chemical class 0.000 description 1
- 235000005473 carotenes Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 229960002788 cetrimonium chloride Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- QFSKIUZTIHBWFR-UHFFFAOYSA-N chromium;hydrate Chemical compound O.[Cr] QFSKIUZTIHBWFR-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 229940047648 cocoamphodiacetate Drugs 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 229920013750 conditioning polymer Polymers 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000002951 depilatory effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229960000587 glutaral Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 229960004337 hydroquinone Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940100556 laureth-23 Drugs 0.000 description 1
- 229940031674 laureth-7 Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- BOUCRWJEKAGKKG-UHFFFAOYSA-N n-[3-(diethylaminomethyl)-4-hydroxyphenyl]acetamide Chemical group CCN(CC)CC1=CC(NC(C)=O)=CC=C1O BOUCRWJEKAGKKG-UHFFFAOYSA-N 0.000 description 1
- 210000003928 nasal cavity Anatomy 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229940068968 polysorbate 80 Drugs 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 229960002026 pyrithione Drugs 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- GNBVPFITFYNRCN-UHFFFAOYSA-M sodium thioglycolate Chemical compound [Na+].[O-]C(=O)CS GNBVPFITFYNRCN-UHFFFAOYSA-M 0.000 description 1
- 229940046307 sodium thioglycolate Drugs 0.000 description 1
- FWFUWXVFYKCSQA-UHFFFAOYSA-M sodium;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C FWFUWXVFYKCSQA-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- 229960000943 tartrazine Drugs 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- NCYCYZXNIZJOKI-UHFFFAOYSA-N vitamin A aldehyde Natural products O=CC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C NCYCYZXNIZJOKI-UHFFFAOYSA-N 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Definitions
- the present application relates to personal care compositions.
- Conditioning of hair and/or skin is one of the most desired attributes in a personal care composition, particularly conditioners, shampoos, and body washes.
- Cationic polymers are known to provide conditioning benefits, but can tend to build up on hair and cause limp and/or unmanageable hair.
- Other conditioning agents containing oily (silicone) or waxy (fatty acids) material are known, but have several drawbacks, including the proclivity of silicones to wash off the hair when paired with surfactants.
- a conditioning shampoo that can clean, condition, and increase manageability, for example, exhibit improved curl retention and frizz control (that is, a reduction in the appearance or intensity of frizz, a term of art referring to an aesthetically undesirable appearance of individual hair fibers behaving independently and non-uniformly, whether from static, humidity, or damage).
- the present invention provides personal care compositions, comprising an aqueous dispersion comprising an ethylene acrylic acid copolymer and a least one cosmetically acceptable surfactant, emollient, or cosmetic active.
- the present invention provides personal care compositions, comprising an aqueous dispersion comprising an ethylene acrylic acid copolymer and a least one cosmetically acceptable surfactant, emollient, or cosmetic active.
- Personal care relates to compositions to be topically applied to a person (including mouth, ear, and nasal cavities, but not ingested).
- personal care compositions include skin care products (e.g., facial cream, moisturizers, leave on and rinse off lotions, sunscreens, foundation, mascara, eye-liner, lipstick, cleansers, and the like) and hair care products (including shampoos, leave on and rinse off conditioners, styling gels and hairsprays).
- the personal care composition is a shampoo, a rinse-off conditioner, a leave-in conditioner, or a body wash.
- the personal care composition is not an emulsion.
- Cosmetically acceptable refers to ingredients typically used in personal care compositions, and is intended to underscore that materials that are toxic when present in the amounts typically found in personal care compositions are not contemplated as part of the present invention.
- ethylene-acrylic acid (EAA) copolymers which are known as flexible thermoplastics for blister packaging and the like.
- a preferred ethylene acrylic acid copolymer comprises greater than about 15 wt% acrylic acid, preferably greater than about 17 wt% acrylic acid, more preferably about 20 wt% acrylic acid. It should be understood that ranges recited in this disclosure include all
- a preferred EAA copolymer is PRIMACOR 5990 copolymer (20 wt% acrylic acid), which has a melt index of 1300 g/10 minute (ASTM Method D-1238 at 190° C) and a Brookfield viscosity of 13,000 cps at 350° F, and is available from The Dow Chemical Company.
- Another preferred EAA copolymer is PRIMACOR 5980i copolymer (20.5 wt% acrylic acid), which has a melt index of 300 g/10 minute (ASTM Method D-1238 at 190° C), available from The Dow Chemical Company.
- EAA copolymers are also available under the tradename NUCREL 2806, available from E.I. du Pont de Nemours and Company, Inc.
- Ethylene-acrylic acid and ethylene-methacrylic acid copolymers are described in U.S. Pat. Nos. 4,599,392, 4,988,781, and 5,938,437, each of which is incorporated herein by reference in its entirety.
- the solids content of the aqueous dispersion is in a range from about 10% by weight to about 30% by weight, preferably about 20% by weight.
- the aqueous dispersion is present in a range from about 0.05 wt% to about 10 wt% of solids, preferably about 0.25 wt% to about 5 wt%, by weight of the personal care composition.
- the ethylene acrylic acid copolymer is present in a range from about 15 wt% to about 60 wt% of solids by weight of the aqueous dispersion.
- the aqueous dispersion comprising an ethylene acrylic acid copolymer can include additional components, for example, at least one anti-dandruff active (zinc pyrithione, salicylic acid, or selenium compounds), sunscreen actives (organic or inorganic), pigment, fragrance, botanical, amino acid, or vitamin.
- the aqueous dispersion comprises an ethylene acrylic acid copolymer and a metallocene catalyzed polyolefin.
- the ethylene acrylic acid copolymer and metallocene catalyzed polyolefin is in a polymer ratio of about 40:60 to about 15:85.
- the solids content of the aqueous dispersion is in a range from about 30% by weight to about 50% by weight, preferably about 40% by weight.
- the ethylene acrylic acid copolymer is present in a range from about 15 wt% to about 60 wt% of the solids by weight of the aqueous dispersion, preferably in a range from about 35 wt% to about 45 wt% of the solids. This correlates to ethylene acrylic acid copolymer being present in a range from about lwt% to about 25 wt% by weight of the aqueous dispersion, preferably in a range from about 5 wt% to about 20 wt%.
- Metallocene catalyzed polyolefins are polyolefins produced with a metallocene catalyst as described in U.S. Pat. Nos. 4,701,432, 5,322,728, and 5,272,236, each of which is incorporated herein by reference in its entirety.
- the metallocene catalyzed polyolefins are polyethylenes produced with a metallocene catalyst.
- Such metallocene catalyzed polyethylenes are available e.g. from The Dow Chemical Company under the trademark AFFINITY or ENGAGE (ethylene/octene copolymers) and from Exxon Chemical Company under the trademark EXACT
- the metallocene catalyzed polyolefin is at least one of ethylene/octene copolymers, ethylene/butene copolymers, ethylene/hexene copolymers, ethylene/propylene or ethylene/butene/hexene terpolymers, preferably an ethylene octene copolymer.
- the metallocene catalyzed polyolefin is a
- propylene/alpha-olefin copolymer which is further described in details in the U.S. Patent Nos. 6,960,635 and 6,525,157, each of which is incorporated herein by reference in its entirety.
- Such propylene/alpha-olefin copolymers are commercially available from The Dow Chemical Company, under the tradename VERSIFYTM, or from ExxonMobil Chemical Company, under the tradename VISTAMAXXTM.
- the ethylene acrylic acid copolymer and metallocene catalyzed polyolefin are melt-kneaded in an extruder along with water and a neutralizing agent, such as ammonia, potassium hydroxide, or a combination of the two, to form an aqueous dispersion.
- a neutralizing agent such as ammonia, potassium hydroxide, or a combination of the two
- the present invention provides personal care compositions, comprising an aqueous dispersion comprising an ethylene acrylic acid copolymer, optionally, metallocene catalyzed polyolefin, and a silicone, provided that the silicone is not in the aqueous dispersion.
- Silicones include silicone oils, for instance volatile or non-volatile polymethylsiloxanes (PDMS) comprising a linear or cyclic silicone chain, which are liquid or pasty at room temperature, especially cyclopolydimethylsiloxanes (cyclomethicones) such as cyclopentasiloxane and cyclohexadimethylsiloxane, polydimethylsiloxanes comprising alkyl, alkoxy or phenyl groups, which are pendent or at the end of a silicone chain, these groups comprising from 2 to 24 carbon atoms, phenyl silicones, for instance phenyl trimethicones, phenyl dimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes 2-phenylethyltrimethyl siloxysilicates and
- polymethylphenylsiloxanes fluoro oils such as partially hydrocarbon-based and/or partially silicone-based fluoro oils, preferably dimethicone, cyclopentasiloxane, cyclohexasiloxane, or a combination thereof.
- fluoro oils such as partially hydrocarbon-based and/or partially silicone-based fluoro oils
- dimethicone cyclopentasiloxane
- cyclohexasiloxane a combination thereof.
- a preferred blend of dimethicone, Laureth-23, and C 12-15 Pareth-3 is commercially available from Dow-Corning under the tradename DOW CORNING 2-1491 Silicone Emulsion, also described as a 60% large particle size non-ionic emulsion of a blend of ultra-high molecular weight polydimethylsiloxane gum and intermediate molecular weight polydimethylsiloxane fluid.
- the silicone is present in a range from about 0.1 wt% to about 5 wt%, preferably from about 0.75 wt% to about 3 wt%, and more preferably from about 1 wt% to about 2 wt%, by weight of the personal care composition.
- the surfactant is a cationic, anionic, nonionic, or amphoteric surfactant, or a mixture thereof.
- the surfactant is a nonionic/emulsifier surfactant.
- the surfactant is a cationic surfactant, preferably behentrimonium chloride.
- the surfactant is present in an amount from about 0.1 wt% to about 10 wt% by weight of the composition, preferably from about 0.5 wt% to about 7 wt% by weight of the composition, most preferably from about 1 wt% to about 4 wt% by weight of the composition.
- the surfactant is a detergent surfactant.
- the surfactant is present in an amount from about 1 wt% to about 25 wt% by weight of the composition, preferably from about 5 wt% to about 20 wt% by weight of the composition, most preferably from about 7 wt% to about 18 wt% by weight of the composition.
- the detergent surfactant is an anionic surfactant in combination with an amphoteric surfactant.
- the anionic surfactant is ammonium laureth sulfate, ammonium lauryl sulfate, sodium laureth sulfate, or sodium lauryl sulfate.
- the anionic surfactant is present in an amount from about 1 wt% to about 25 wt%, preferably from about 5 wt% to about 20 wt%, more preferably from about 7 wt% to about 15 wt%, by weight of the composition.
- the mixture is an anionic surfactant in combination with a second surfactant that is disodium cocoamphodiacetate, decylglucoside, or cocamidopropyl betaine.
- the second surfactant is present in an amount from about 1 wt% to about 10 wt%, preferably from about 1 wt% to about 8 wt%, more preferably from about 2 wt% to about 6 wt%, by weight of the composition.
- the surfactant is a mixture of sodium laureth sulfate (such as is commercially available from Cognis as under the tradename STAND APOL ES) and disodium cocoamphodiacetate (such as is commercially available from Henkel as under the tradename VELVETEX CDC).
- the surfactant is a mixture of sodium laureth sulfate and disodium cocoamphodiacetate, the ratio of sodium laureth sulfate to disodium
- cocoamphodiacetate is in a range from about 9:1 to about 2:1, most preferably about 6:1.
- the composition includes citric acid to adjust the pH.
- the composition further comprises a cationic polymer.
- Cationic polymer is herein defined as a polysaccharide modified to have a positive charge, for example, cationic cellulose derivatives (including for example PQ 10, PQ 24, and PQ 67), cationic guar derivatives, cationic methacrylamido polymers, and synthetic cationic polymers, such as PQ6 and PQ7.
- the cationic polymer is cationically modified hydroxyethylcellulose, which is commercially available from The Dow Chemical Company under the tradename UCARE.
- Other optional ingredients for personal care compositions of the present invention include cosmetically acceptable emollients, sunscreens, surfactants, emulsifiers,
- preservatives preservatives, rheology modifiers, colorants, dyes, preservatives, pH adjustors, propellants, reducing agents, fragrances, foaming agents, tanning agents, depilatory agents, flavors, astringents, antiseptics, deodorants, antiperspirants, insect repellants, bleaches, lighteners, anti-dandruff agents, adhesives, polishes, strengtheners, fillers, barrier materials, or biocides.
- the personal care composition further comprises an optional rheology modifier as a thickener.
- thickeners include polymers, for example, modified or unmodified carboxy vinyl polymers, such as the products sold under the names CARBOPOL and PEMULEN (INCI name: Acrylates/Cio-30 alkyl acrylate crosspolymer; available from Noveon), polyacrylates and polymethacrylates, such as the products sold under the names LUBRAJEL and NORGEL (commercially available from Guardian) or HISPAGEL (commercially available from Hispano Chimica), polyacrylamides, 2- acrylamido-2-methylpropanesulfonic acid polymers and polymers, which are optionally crosslinked and/or neutralized, for instance the poly(2-acrylamido-2-methylpropane-sulfonic acid) sold by Clariant (INCI name: ammonium polyacryldimethyltauramide), emulsified crosslinked anionic polymers of acrylamide and AMPS, such as those
- Colorants include pigments, which are used especially in make-up, including metal oxide pigments, titanium dioxide, optionally surface-treated, zirconium oxide or cerium oxide, zinc oxide, iron oxide (black, yellow or red), chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, carbon black, pigments of barium, strontium, calcium or aluminum (for example D&C or FD&C), cochineal carmine, mica coated with titanium or with bismuth oxychloride, titanium mica with iron oxides, titanium mica with, especially, ferric blue or chromium oxide, titanium mica with an organic pigment, nacreous pigments based on bismuth oxychloride, goniochromatic pigments, for example pigments with a multilayer interference structure, reflective pigments, for example particles with a silver-coated glass substrate, glass substrate coated with
- nickel/chromium/molybdenum alloy glass substrate coated with brown iron oxide, particles comprising a stack of at least two polymer layers, for instance MIRROR GLITTER
- Dyes include water-soluble dyes such as copper sulfate, iron sulfate, water-soluble sulfopolyesters, rhodamines, natural dyes, for instance carotene and beetroot juice, methylene blue, caramel, the disodium salt of tartrazine and the disodium salt of fuschin, and mixtures thereof. Liposoluble dyes from the list above can also optionally be used.
- Preservatives include alcohols, aldehydes, methylchloroisothiazolinone and methylisothiazolinone, p-hydroxybenzoates, and in particular methylparaben, propylparaben, glutaraldehyde and ethyl alcohol.
- the pH adjustors include inorganic and organic acids and bases and in particular aqueous ammonia, citric acid, phosphoric acid, acetic acid, and sodium hydroxide.
- Reducing agents include ammonium thioglycolate, hydroquinone and sodium thioglycolate.
- Fragrances can be aldehydes, ketones, or oils obtained by extraction of natural substances or synthetically produced as described above. Often, fragrances are accompanied by auxiliary materials, such as fixatives, extenders, stabilizers and solvents.
- Biocides include antimicrobials, bactericides, fungicides, algaecides, mildicides, disinfectants, antiseptics, and insecticides.
- the personal care composition is a shampoo, body wash, or facial cleanser, preferably a shampoo.
- the personal care compositions are applied to hair or skin.
- applying the present personal care compositions constitute a method of conditioning hair.
- the present invention comprises a shampoo that cleans, conditions, and increases manageability, for example exhibits improved curl retention and frizz control.
- compositions of the present invention include aqueous dispersions comprising an ethylene acrylic acid copolymer.
- aqueous dispersions include the following:
- PRIMACOR 5980i 20% ethylene acrylic acid resin (133g), potassium hydroxide (17.2g), and water (200g) are placed in a 300 mL Parr reactor vessel fitted with a Cowles blade. The material is heated to 120°C while mixing slowly. Once the set temperature is reached, the mixer is run on high (-1800 rpm) for 25 minutes. While still mixing on high, the sample is diluted with water fed into the reactor with an HPLC pump at a rate of 40mL/min to the desired concentration of 23% solids by weight based on the amount of Primacor. Heat is removed and stirring continues until the temperature cools to at least 45°C. The Parr is then opened and the dispersion is collected.
- PRIMACOR 5980i 20% ethylene acrylic acid resin (30.7g), potassium hydroxide (4g), and water (92g) are placed in a Parr reactor vessel fitted with a Cowles blade. The material is heated to about 120°C while mixing slowly. Once the temperature is reached, the mixer is run on high (-1800 rpm) for about 25 minutes. Heat is removed and stirring continues until the temperature cools to at least 30°C.
- ZPT Zinc Pyrithione
- Exemplary personal care shampoo compositions contain the components recited in TABLE 1 on a weight/weight basis (wt. %).
- Conventional personal care shampoo compositions contain the components recited in TABLE 2 on a weight/weight basis (wt. %).
- Control shampoos are prepared substantially as described in Example 2, but contain 0.3% of a conventional cationic conditioning polymer (i.e., JAGUAR C-13S guar, UCARE polymer JR400, UCARE polymer LR30M) instead of the aqueous dispersion.
- a conventional cationic conditioning polymer i.e., JAGUAR C-13S guar, UCARE polymer JR400, UCARE polymer LR30M
- compositions substantially according to the protocols of Examples 2 and 3 were prepared. Pre- washed and pre-hydrated tresses of European Virgin-Brown and 8-hour bleached hair (available from International Hair Importers and Products Inc.) were treated with 0.5 g of these shampoo formulations. The shampoo was worked into the hair for 1 min. and then rinsed off under running tap water at 38°C at 0.4 gal./min. water flow.
- the hair tresses were hung for wet sensory evaluation study. After the tresses were completely dried, dry sensory evaluations were conducted. Ten expert panelists trained to evaluate the performance of cosmetic products on hair were asked to evaluate comb-ability and feel in both the wet and dry stage. Each panelist evaluated a pair of tresses, one tress treated with a composition of the invention versus one treated with a comparative
- hair tresses (8 hour bleached) were washed as above using Formulation A or Comparative 3 and dried.
- Objective dry combing measurements were taken using a DIA-STRON device from Dia-Stron Limited, Hampshie, UK. The lower force required to pull the comb through the hair, the more conditioned the hair is.
- Formulation A shows as good or better dry combing force as Comparative 3 with air drying (2189 compared to 2220) and significantly better for blow drying (656 compared o 1621), signifying excellent conditioning even in the absence of a cationic polymer.
- hair tresses (8 hour bleached) were washed as above using Formulation A, Formulation B or Comparative 1 and dried.
- Very damaged hair e.g., 8-hour bleached hair
- Hydrophobicity can be used as a measure of repair by replacing the fatty acid coating and indicates deposition of a substance on the hair during shampooing.
- Formulation A and Formulation B have a hydrophobicity (determined by advancing contact angle) of 55.8 + 11.5, 85.3 + 0.85, respectively, compared to 45.2 + 4.40 for untreated 8 hour bleached hair. Comparative 1 did not increase hydrophobicity, thus, it is believed that the mechanism for hair conditioning of the cationic polymer is different from that of the inventive formulations.
- Exemplary personal care rinse-off conditioning compositions contain the components weight/weight basis (wt. %) recited in TABLE 4.
- Phase A ingredients Combine Phase A ingredients, mix, and heat to 75°C under stirring.
- phase B ingredients are combined, mixed and heated to 75°C under stirring
- Phase B is added to phase A at 75°C under stirring at 470 rpm.
- the reaction mixture is allowed to cool to room temperature while stirring.
- Glydant is added at 35 °C.
- Batch A is added to the mixture at room temperature and mixed in for 20 min. pH of the formulation was adjusted to 4 - 5 using 50% citric acid as needed.
- Comparative personal care rinse-off conditioning compositions contain the components weight/weight basis (wt. %) recited in TABLE 5.
- compositions are prepared as in Example 5, except that Batch A is not present and Glydant and DC 345 are added at 35 °C.
- Compositions substantially according to the protocols of Examples 5 and 6 were prepared. Pre- washed and pre-hydrated ten inch long hair tresses of European single- bleached hair (available from International Hair Importers and Products Inc. (Floral Park, NY)) were treated with 0.1 g of the conditioner formulations, which was worked into the hair for 1 min. and then rinsed off under running tap water at 38°C and 0.4 gal./min. water flow.
- the hair tresses were hung for wet sensory evaluation study. After the tresses were completely dried, dry sensory evaluations were conducted. Ten expert panelists trained to evaluate the performance of cosmetic products on hair were asked to evaluate comb-ability and feel in both the wet and dry stage. Each panelist evaluated a pair of tresses, one tress treated with Formulation C of the present invention versus one treated with a Comparative 4 composition. The panelists were asked to pick one tress that combed easier and felt more slippery/smoother (wet) or silkier/softer (dry). The inventive formulation was found similar to the comparative formulation in all categories tested (differences not statistically significant on wet and dry hair), showing the inventive formulation displayed similar performance to silicones.
- Exemplary personal care leave-on conditioner compositions contain the components recited in TABLE 6 on a weight/weight basis (wt. %).
- CELLOSIZE PCG-10 is sprinkled into rapidly agitating, room temperature water. Once uniform, the solution is heated to 60 °C and cetrimonium chloride is added to the mixture and stirred until dissolved. The pre-mix is then heated to 75°C under stirring. In a separate reaction vessel, fatty alcohols of phase B are combined, mixed until uniform and heated to 75°C under stirring. Vegetable oil is added in under stirring. Phase B is added to phase A at 75°C under stirring at 470 rpm. The reaction mixture is allowed to cool while stirring. Phase C ingredients are added at 35 °C, and pH of the formulation was adjusted to 4 - 5 using 50% citric acid as needed.
- Exemplary personal care shampoo compositions contain the components recited in TABLE 7 on a weight/weight basis (wt. %).
- Conventional personal care shampoo compositions contain the components recited in TABLE 8 on a weight/weight basis (wt. %).
- Control shampoo is prepared substantially as described in Example 9, but contains commercial ZPT dispersion available from Arch Chemical as ZINC OMADINE FPS dispersion.
- compositions substantially according to the protocols of Examples 9 and 10 were prepared and applied to virgin brown hair.
- the tresses were tested substantially according to the methods described in Example 4, and Formulation F deposits at least 25% more zinc onto hair than the Comparative 5 composition (17.1 ppm vs. 13.6 ppm).
- Exemplary personal care shampoo compositions contain the components recited in TABLE 9 on a weight/weight basis (wt. %).
- Conventional personal care shampoo compositions contain the components recited in TABLE 10 on a weight/weight basis (wt. %).
- compositions substantially according to the protocols of Examples 11 and 12 were prepared. Pre- washed and pre-hydrated ten inch long hair tresses of European Virgin Brown and 8-hour bleached hair (available from International Hair Importers and Products Inc. (Floral Park, NY)) were treated with 0.5 g of the formulations, which was worked into the hair for 1 min. and then rinsed off under running tap water at 38°C and 0.4 gal./min. water flow.
- One group of the hair tresses were dried in an oven at 38°C. After the tresses were completely dried, they were curled using a curling iron for one minute. The curls were released and photographs of the curled tresses were taken for evaluation.
- Another group of the hair tresses were roller curled by diagonally applying wet hair onto a 65mm x 20mm curler, held in place with two large bobby pins. These were air dried at ambient temperatures for 3 days, then placed in a 45°C oven for one hour to ensure they were thoroughly dried. Curlers were then removed and the curled hair tresses were placed in a high humidity chamber (25°C, 90% relative humidity) for 24 hours. The curled tresses were removed from the humidity chamber and photographs of the curled tresses were taken for evaluation.
- each recited range includes all combinations and subcombinations of ranges, as well as specific numerals contained therein. Additionally, the disclosures of each patent, patent application, and publication cited or described in this document are hereby incorporated herein by reference, in their entireties.
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Abstract
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US35337210P | 2010-06-10 | 2010-06-10 | |
PCT/US2010/048868 WO2011034883A2 (fr) | 2009-09-15 | 2010-09-15 | Compositions de soin personnel avec des dispersions aqueuses de copolymère éthylène-acide acrylique |
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US (1) | US8771657B2 (fr) |
EP (1) | EP2477601B1 (fr) |
JP (1) | JP5937512B2 (fr) |
CN (1) | CN102791251B (fr) |
BR (1) | BR112012005680B1 (fr) |
WO (1) | WO2011034883A2 (fr) |
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EP2629743B1 (fr) * | 2010-10-20 | 2015-06-10 | Union Carbide Chemicals & Plastics Technology LLC | Produits fixateurs pour les cheveux |
WO2012082624A2 (fr) * | 2010-12-17 | 2012-06-21 | Dow Global Technologies Llc | Dispersions aqueuses de copolymères d'éthylène et d'acide acrylique utilisables en vue de la libération d'un parfum dans les lessives |
CN103608447B (zh) * | 2011-06-17 | 2015-10-07 | 陶氏环球技术有限责任公司 | 织物护理粒料和方法 |
US9872820B2 (en) | 2012-09-24 | 2018-01-23 | Dow Global Technologies Llc | Personal care sensory agents |
WO2014058670A1 (fr) * | 2012-10-11 | 2014-04-17 | Dow Global Technologies Llc | Dérivés de cellulose sans glyoxal pour des compositions de soins personnels |
MX2016003236A (es) | 2013-09-27 | 2016-06-07 | Rohm & Haas | Peliculas dispersables para envasar formulaciones de alto contenido de agua. |
CN105592843B (zh) * | 2013-09-27 | 2021-09-14 | 罗门哈斯公司 | 包含漂白剂的口腔护理组成物 |
WO2015081006A1 (fr) | 2013-11-27 | 2015-06-04 | Rohm And Haas Chemicals Llc | Films et particules dispersibles dans l'eau pour libération déclenchée d'enzymes |
EP3116468B1 (fr) * | 2014-03-10 | 2018-11-14 | Dow Global Technologies LLC | Agents sensoriels de soins capillaires |
CN108289798A (zh) * | 2015-12-11 | 2018-07-17 | 罗门哈斯公司 | 浓缩聚烯烃乳液和含有其的护发组合物 |
CN108307621A (zh) * | 2015-12-11 | 2018-07-20 | 罗门哈斯公司 | 浓缩聚烯烃乳液和含有其的个人护理组合物 |
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US11369561B2 (en) * | 2018-01-22 | 2022-06-28 | Henkel Ag & Co. Kgaa | Compositions and methods for hair coloring |
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CN102791251A (zh) | 2012-11-21 |
US8771657B2 (en) | 2014-07-08 |
US20110064683A1 (en) | 2011-03-17 |
BR112012005680B1 (pt) | 2017-10-31 |
EP2477601B1 (fr) | 2017-09-13 |
JP5937512B2 (ja) | 2016-06-22 |
WO2011034883A3 (fr) | 2012-08-23 |
WO2011034883A2 (fr) | 2011-03-24 |
BR112012005680A2 (pt) | 2016-02-23 |
JP2013504629A (ja) | 2013-02-07 |
CN102791251B (zh) | 2015-07-01 |
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