EP2410038A3 - Mixing-assisted oxidative desulfurization method of diesel fuel and device thereof - Google Patents

Mixing-assisted oxidative desulfurization method of diesel fuel and device thereof Download PDF

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Publication number
EP2410038A3
EP2410038A3 EP11161598A EP11161598A EP2410038A3 EP 2410038 A3 EP2410038 A3 EP 2410038A3 EP 11161598 A EP11161598 A EP 11161598A EP 11161598 A EP11161598 A EP 11161598A EP 2410038 A3 EP2410038 A3 EP 2410038A3
Authority
EP
European Patent Office
Prior art keywords
desulfurization
mixing
diesel fuel
fossil fuels
assisted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP11161598A
Other languages
German (de)
French (fr)
Other versions
EP2410038A2 (en
Inventor
Lin Hsin Tung
Wan Meng Wei
Lu Ming Chun
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP2410038A2 publication Critical patent/EP2410038A2/en
Publication of EP2410038A3 publication Critical patent/EP2410038A3/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/28—Recovery of used solvent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/14—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with ozone-containing gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Mixing-assisted oxidative desulfurization method of diesel fuel and the continuous desulfurization device thereof is disclosed herein. Because of the dangers of sulfur content in gasoline and other petroleum products, many governments have required the sulfur content of these petroleum products to be reduced so as to safeguard public safety and health. Desulfurization of fossil fuels is provided by the combination of fossil fuels with an aqueous mixture of ozone or hydrogen peroxide and a Tetraoctylphosphonium salt phase transfer catalyst, and the mixture is then reactive mixed to form oxidize sulfur compounds in the fuel. The polar oxidized sulfones species are removed via another mixing step. The desulfurization device (10) can be in the form of a portable device which provides for continuous mixing-assisted desulfurization for the selective removal of sulfur containing compounds from fossil fuels such as diesel fuel or other hydrocarbons.
EP11161598A 2010-07-20 2011-04-08 Mixing-assisted oxidative desulfurization method of diesel fuel and device thereof Ceased EP2410038A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12/840,259 US20120018350A1 (en) 2010-07-20 2010-07-20 Mixing-assisted oxidative desulfurization of diesel fuel using quaternary ammonium salt and portable unit thereof

Publications (2)

Publication Number Publication Date
EP2410038A2 EP2410038A2 (en) 2012-01-25
EP2410038A3 true EP2410038A3 (en) 2012-05-23

Family

ID=44496518

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11161598A Ceased EP2410038A3 (en) 2010-07-20 2011-04-08 Mixing-assisted oxidative desulfurization method of diesel fuel and device thereof

Country Status (6)

Country Link
US (1) US20120018350A1 (en)
EP (1) EP2410038A3 (en)
JP (1) JP2012025933A (en)
CN (2) CN102337149A (en)
CA (1) CA2744257A1 (en)
TW (1) TWI417375B (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007106943A1 (en) * 2006-03-22 2007-09-27 Ultraclean Fuel Pty Ltd Process for removing sulphur from liquid hydrocarbons
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons
US10214697B2 (en) * 2013-03-15 2019-02-26 Ultraclean Fuel Pty Limited Process for removing sulphur compounds from hydrocarbons
CN103450931B (en) * 2013-09-06 2015-04-15 余国贤 Ultrasonic oxidation-extraction and deep desulfurization method for diesel oil
CN103585954A (en) * 2013-11-04 2014-02-19 安阳工学院 Gasoline desulfurization catalytic adsorbent, and preparation method and desulfurization method thereof
CN104989944A (en) * 2015-06-30 2015-10-21 柳州市山泰气体有限公司 Cylindrical liquefied petroleum gas tank
EP3609984B1 (en) 2017-03-14 2022-05-25 Alternative Petroleum Technologies, Inc. Method for liquid hydrocarbon desulfurization
US11225613B2 (en) * 2017-05-08 2022-01-18 Solvay Sa Process for removing sulfur compounds from a liquid composition
BR102017012313B1 (en) * 2017-06-09 2022-06-28 Petróleo Brasileiro S.A. - Petrobrás CATALYTIC SYSTEM FOR THE REMOVAL OF HETEROATOMIC SULFUR AND/OR NITROGEN COMPOUNDS DISSOLVED IN HYDROCARBONS
CN111417703A (en) 2017-06-26 2020-07-14 替代石油科技公司 System and method for desulfurizing liquid hydrocarbons
US10093868B1 (en) * 2017-11-15 2018-10-09 Baker Hughes, A Ge Company, Llc Ionic liquid-based hydrogen sulfide and mercaptan scavengers
US11198824B2 (en) * 2019-05-16 2021-12-14 Alternative Petroleum Technologies Holdings Corp. System and method for liquid hydrocarbon desulfurization
WO2024095167A1 (en) * 2022-11-03 2024-05-10 Bakhshi Zadeh Shahryar Ultrasound-assisted oxidative desulfurization of fuel oil using metal oxide catalysts

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6402939B1 (en) * 2000-09-28 2002-06-11 Sulphco, Inc. Oxidative desulfurization of fossil fuels with ultrasound
US20060054538A1 (en) * 2004-09-14 2006-03-16 Exxonmobil Research And Engineering Company Emulsion neutralization of high total acid number (TAN) crude oil
WO2007103440A2 (en) * 2006-03-03 2007-09-13 Saudi Arabian Oil Company Catalytic process for deep oxidative desulfurization of liquid transportation fuels
US20080173571A1 (en) * 2006-09-13 2008-07-24 University Of Southern California Ultrasound-Assisted Oxidative Desulfurization of Diesel Fuel Using Quaternary Ammonium Fluoride and Portable Unit for Ultrasound-Assisted Oxidative Desulfurization
US20090236266A1 (en) * 2008-03-20 2009-09-24 Shun-Sheng Cheng Diesel desulfurization method

Family Cites Families (10)

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US54538A (en) * 1866-05-08 Improved method of neutralizing acid on sheet-iron
US173571A (en) * 1876-02-15 Improvement in heat-radiators
US4410422A (en) * 1981-10-23 1983-10-18 General Electric Company Method for removing polyhalogenated hydrocarbons from nonpolar organic solvent solutions
JP3227521B2 (en) * 1992-04-06 2001-11-12 舟越 泉 Method for recovering organic sulfur compounds from liquid oil
US7871512B2 (en) * 2001-05-10 2011-01-18 Petrosonics, Llc Treatment of crude oil fractions, fossil fuels, and products thereof
US6544409B2 (en) * 2001-05-16 2003-04-08 Petroleo Brasileiro S.A. - Petrobras Process for the catalytic oxidation of sulfur, nitrogen and unsaturated compounds from hydrocarbon streams
JP2003193066A (en) * 2001-12-26 2003-07-09 Mitsui Eng & Shipbuild Co Ltd Method for oxidative desulfurization of liquid petroleum product and oxidative desulfurization plant
CN1961061A (en) * 2004-05-31 2007-05-09 新加坡科技研究局 Novel process for removing sulfur from fuels
CN100556992C (en) * 2005-03-18 2009-11-04 中国科学院化学研究所 A kind of catalytic oxidation desulfurization method of petroleum products
CN100569917C (en) * 2006-04-27 2009-12-16 中国石油化工股份有限公司 The method of a kind of oxidation sweetening of light-end products and deodorization

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6402939B1 (en) * 2000-09-28 2002-06-11 Sulphco, Inc. Oxidative desulfurization of fossil fuels with ultrasound
US20060054538A1 (en) * 2004-09-14 2006-03-16 Exxonmobil Research And Engineering Company Emulsion neutralization of high total acid number (TAN) crude oil
WO2007103440A2 (en) * 2006-03-03 2007-09-13 Saudi Arabian Oil Company Catalytic process for deep oxidative desulfurization of liquid transportation fuels
US20080173571A1 (en) * 2006-09-13 2008-07-24 University Of Southern California Ultrasound-Assisted Oxidative Desulfurization of Diesel Fuel Using Quaternary Ammonium Fluoride and Portable Unit for Ultrasound-Assisted Oxidative Desulfurization
US20090236266A1 (en) * 2008-03-20 2009-09-24 Shun-Sheng Cheng Diesel desulfurization method

Also Published As

Publication number Publication date
CN201952397U (en) 2011-08-31
CA2744257A1 (en) 2012-01-20
TWI417375B (en) 2013-12-01
US20120018350A1 (en) 2012-01-26
CN102337149A (en) 2012-02-01
TW201204825A (en) 2012-02-01
JP2012025933A (en) 2012-02-09
EP2410038A2 (en) 2012-01-25

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