EP2384820B1 - Cartridge system and application tube for such a cartridge system - Google Patents
Cartridge system and application tube for such a cartridge system Download PDFInfo
- Publication number
- EP2384820B1 EP2384820B1 EP11003052.5A EP11003052A EP2384820B1 EP 2384820 B1 EP2384820 B1 EP 2384820B1 EP 11003052 A EP11003052 A EP 11003052A EP 2384820 B1 EP2384820 B1 EP 2384820B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cartridge
- cartridges
- mixing space
- cartridge system
- closure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 230000003068 static effect Effects 0.000 claims description 10
- 239000004568 cement Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 description 11
- 235000011837 pasties Nutrition 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- 238000007789 sealing Methods 0.000 description 9
- 239000002639 bone cement Substances 0.000 description 7
- 238000004806 packaging method and process Methods 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 239000004926 polymethyl methacrylate Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000001360 synchronised effect Effects 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012371 Aseptic Filling Methods 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010053648 Vascular occlusion Diseases 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000013466 adhesive and sealant Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000009517 secondary packaging Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 208000008918 voyeurism Diseases 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C17/00—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
- B05C17/005—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
- B05C17/00553—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with means allowing the stock of material to consist of at least two different components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/50—Movable or transportable mixing devices or plants
- B01F33/501—Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use
- B01F33/5011—Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use portable during use, e.g. hand-held
- B01F33/50112—Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use portable during use, e.g. hand-held of the syringe or cartridge type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/50—Mixing receptacles
- B01F35/52—Receptacles with two or more compartments
- B01F35/522—Receptacles with two or more compartments comprising compartments keeping the materials to be mixed separated until the mixing is initiated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/71—Feed mechanisms
- B01F35/717—Feed mechanisms characterised by the means for feeding the components to the mixer
- B01F35/7174—Feed mechanisms characterised by the means for feeding the components to the mixer using pistons, plungers or syringes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C17/00—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
- B05C17/005—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
- B05C17/00503—Details of the outlet element
- B05C17/00506—Means for connecting the outlet element to, or for disconnecting it from, the hand tool or its container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C17/00—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
- B05C17/005—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
- B05C17/00503—Details of the outlet element
- B05C17/00506—Means for connecting the outlet element to, or for disconnecting it from, the hand tool or its container
- B05C17/00513—Means for connecting the outlet element to, or for disconnecting it from, the hand tool or its container of the thread type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C17/00—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
- B05C17/005—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
- B05C17/00503—Details of the outlet element
- B05C17/00516—Shape or geometry of the outlet orifice or the outlet element
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C17/00—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
- B05C17/005—Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
- B05C17/00596—The liquid or other fluent material being supplied from a rigid removable cartridge having no active dispensing means, i.e. the cartridge requiring cooperation with means of the handtool to expel the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
- B65D81/325—Containers having parallel or coaxial compartments, provided with a piston or a movable bottom for discharging contents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/20—Mixing of ingredients for bone cement
Definitions
- the invention relates to a cartridge system for mixing and applying a mixed material, in particular a medical cement, comprising two mutually parallel cartridges and a mixing chamber with an outlet opening, wherein the cartridges each comprise at least one opening in the cartridge walls, which connect the cartridges with the mixing chamber, and the cartridges each comprise a delivery piston for expelling output components of the mix from the cartridges through the openings.
- Cartridge systems for mixing and applying a mix may consist of several components and are intended to ensure safe storage and secure closure for components in at least two cartridges prior to use. Immediately before the application of the mix, the cartridge system should be safe and easy to open, with a synchronous opening of the individual cartridges is desirable.
- Cartridge systems for the application of pasty two- or multi-component systems have been known for decades. Examples are the documents CH 669 164 A5 . EP 0 607 102 A1 . EP 0 236 129 A2 . DE 3 440 893 A1 . US 4,690,306 A . US 2009/062808 A1 . EP 0 787 535 A1 . WO 2006/005 206 A1 . EP 0 693 437 A1 . EP 0 294 672 A1 . EP 0 261 466 A1 and EP 2 008 707 A1 called.
- a simple but very effective principle is to close the cartridge head with a rotatable shutter ( EP 0 431 347 A1 . DE 20 17 292 A . US 3,215,298 A ).
- the closure is unscrewed before application.
- a discharge tube is screwed into a thread on the cartridge head or fixed with a thread simulating pin system.
- the disadvantage of this is that the user has to perform twice rotational movements until the paste material can be expelled.
- the closure is unscrewed and the discharge tube is placed later. Between the opening of the cartridges and the insertion of the dispensing tube, especially when volatile substances are contained in the pastes, components of the pastes may evaporate.
- the closure currently used very frequently is based on the fact that the wall material of the cartridge is made very thin at the cartridge head, so that this wall can easily be pierced. When piercing particles are removed from the wall, which thereby enter the pasty material.
- the back of the cartridges is usually closed by moving pistons designed to expel the pastes during application.
- aluminum cartridges can be used, which are closed with plastic piston and are pressed over the sealing aluminum cylinder, which are closed on one side, for sealing.
- the aluminum cylinder which is closed on one side, is moved together with the piston with the help of extrusion guns to the front in the direction of the cartridge head and the paste is expelled.
- contact of pastes with aluminum surfaces can be problematic.
- the polymerizable paste systems can not be used, it is possible to sterilize with the gas ethylene oxide.
- a problem with paste systems containing monomers with high vapor pressure is in such a sterilization with gas, that after the actual sterilization, in the removal of the residual ethylene oxide by the action of vacuum, some of the monomers in the cartridges evaporated, while a gas phase form in the cartridges and thus can exert pressure against the pistons. This means that the pistons are undesirably moved in the direction of the cartridge bottoms and in extreme cases are expelled from the cartridges so that the pastes can flow out.
- polymethyl methacrylate bone cements have been used in medicine for the permanent mechanical fixation of total joint endoprostheses. These are based on powder-liquid systems. Polymethyl methacrylate bone cements based on the use of cement pastes have also recently been proposed ( DE 10 2007 050 762 B3 . DE 10 2008 030 312 A1 . DE 10 2007 052 116 A1 ). For such cements so far no suitable cartridge systems have been proposed.
- An essential ingredient of pasty polymethyl methacrylate bone cements is the monomer methylmethacrylate. This monomer evaporates easily and has a fairly high vapor pressure at room temperature. When using methylmethacrylate-containing pastes, it is therefore essential to note that in the event of vacuum, as in the case of degassing in the context of sterilization with ethylene oxide, the cartridge pistons in the cartridges are moved through the evaporating methyl methacrylate and, in extreme cases, can be expelled from the cartridges.
- a generic cartridge system is based on the packaging of pasty multicomponent systems in tubular bags ( WO 2010/006455 A1 ).
- the sealed tubular bag are introduced into cartridges.
- Tubular bags have the advantage that they are suitable for packaging pastes containing volatile components.
- Tubular bags made of composite materials, such as aluminum composite bags, are particularly suitable for this purpose.
- the opening of the tubular bag is made by cutting, which rotate when the dispensing tube is screwed in. As the blades rotate, the bags are cut open to provide openings in the cartridges for dispensing the contents. The pasty bag contents are then squeezed through these openings in the cartridges in the direction of the static mixer.
- a discharge device which has one or more sealing elements which are pushed out over a pressure built up in the chambers.
- the chambers are opened when a sufficient pressure is built up via pistons, which are advanced into the chambers.
- the object of the invention is therefore to provide a cartridge system that is simple and inexpensive to manufacture, but at the same time ensures a safe and easy opening of the cartridges.
- a secure storage and a secure closure for paste-like components in at least two cartridges before their use should be ensured.
- the cartridge system should be able to be opened safely and quickly with as little effort as possible in order to enable simple application during operations and thus reduce or overcome the problems of the previous cartridge systems and their closure systems. So it should be developed a closure system, which closes cartridges for several components safely and allows a quick uncomplicated opening of the individual cartridges. When placing the dispensing tube as possible operator errors of the user should be avoided.
- a closure arranged displaceably in the mixing chamber is arranged such that it closes the openings of the cartridges in a starting position and that the openings for the mixing chamber are at least partially open in an end position of the displaceable closure, wherein the displaceable Closure is displaceable from the starting position to the end position.
- the sliding closure is a cavity body open on both sides.
- a discharge tube is displaceably arranged in the interior of the mixing chamber, wherein the discharge tube comprises an outlet tube tip facing the outlet opening or extending out of it and an extension facing the cartridge bottom which is completely closed in the direction of the cartridge bottom.
- the extension includes openings in the sidewalls facing the cartridge walls, with a continuous connection extending inside the discharge tube from the openings to the discharge tube tip in which a static mixer is preferably located, the outer diameter of the extension being less than or equal to the inner diameter of the mixing space and greater than the inner diameter of the closure, while the remainder of the discharge tube located inside the mixing space has a smaller outer diameter than the inner diameter of the closure.
- the mixing chamber is a hollow body, in particular a hollow cylinder, with hollow body walls, wherein the openings in the cartridges extend through the hollow body wall into the mixing space.
- the mixing space between the cartridges is arranged, in particular such that the cartridge walls are partially executed with the hollow body wall in one.
- the invention also proposes that the mixing space is arranged parallel to the cartridges.
- a movable rod is arranged parallel to the delivery piston in the interior of the mixing chamber, which is fixedly connected to the delivery piston via at least one web and / or a plate, wherein the rod on the outlet opening side facing a locking means and in the mixing chamber a counter-locking means is mounted, which cooperates with the locking means of the rod such that a movement of the rod out of the mixing chamber and thus the delivery piston from the cartridges out clearly difficult, in particular prevented.
- the cartridge walls and / or the mixing chamber walls have at least one slot starting at the bottom of the cartridge, which is arranged parallel to the cartridge axis, wherein the width of the slot or slots for receiving the or the webs is sufficient and the length of the slot or slots in particular extends to at least half of the cartridge length.
- a stop preferably in the form of pins or webs, is arranged, which limits the movement of the displaceable closure towards the center of the mixing chamber and thereby the end position of the displaceable closure is defined.
- displaceable closure is arranged in press fit in the mixing chamber.
- displaceable closure is displaceable in the longitudinal direction of the mixing space.
- the invention also proposes that the delivery pistons seal the cartridges tightly.
- sealing means in particular sealing rings, are arranged at the openings of the cartridges to the mixing chamber.
- the sealing means are intended to improve the sealing effect of the displaceable closure with respect to the openings in the cartridges, if the sealing effect of the displaceable closure by the interference fit should not be sufficient.
- sealing means are arranged around the openings to the mixing space between the inner wall of the mixing chamber and the displaceable shutter in the starting position.
- a plate and / or at least one web is firmly connected on the bottom side with the delivery piston, and a locking means is connected to the plate and / or the at least one web, wherein the locking means extends into the mixing chamber and there in a Gegenarret istsstoff engages, so that movement of the plate and / or the at least one web and the delivery piston is blocked in the direction of the cartridge bottom and in the interior of the mixing chamber a Entarretiervoriques is provided which is fixedly connected to the sliding closure, so that when moving the shiftable Closure in his Endpostition, a release of the locking means takes place, so that a movement of the plate and / or the at least one web and the delivery piston in the direction of the cartridge bottom is possible.
- the discharge pipe comprises a static mixer.
- the discharge pipe is fixedly connected to the sliding closure, so that both form a common part of the Kartsuchenssystems.
- This cartridge system and the associated closure system of the cartridge system are based on the surprising finding that a reliable and easy-to-use opening of the cartridge system is made possible by means of a movable shutter, without having to destroy a component such as the cartridge wall when opening the cartridges, so that no contamination of the components to be mixed or of the mixed material with the material of the component is to be feared.
- This enables a secure closure of the multi-component cartridges and a quick, uncomplicated, simultaneous opening of the individual cartridges of the system.
- the placement of the dispensing tube causes a forced, synchronous opening of the cartridges, so that the cartridges are opened only when the dispensing tube is mounted, thereby avoiding potential operator errors of the user.
- Such a cartridge system and such a closure system can be made entirely from inexpensive plastic injection molded parts.
- the cartridge system makes it possible to move the pistons synchronously in the cartridges when force is applied in the direction of the cartridge system head and thus to evenly press out the pastes so that the mixing ratio of the pastes to one another is ensured.
- a further simplification and ensuring the operability of such a cartridge system results from the fact that a movement of the delivery piston can be reliably prevented under the influence of vacuum.
- the mixing space is to be understood as meaning the area which is located between the at least two cartridges and the areas adjacent thereto. It extends from the cartridge bottom, ie the rear, bottom-side part of the cartridge system, to the outlet opening on the cartridge system head on the front side of the cartridge system, ie also includes the interior of the cartridge system head. Not everywhere in the mixing chamber, the mixing of the starting components of the mix has to be done, but otherwise only in parts of the same.
- a mixing chamber which is connected with hoses to the cartridges, and therefore the mixing chamber is not in the geometrical sense exactly between the cartridges is also according to the invention.
- a closure is to be understood, which is initially in the initial position by a fixed connection to the walls of the gap, for example, by thin bridges, if this solid compound has predetermined breaking points, which at a force Break on the closure and thus allow the movement of the closure under force.
- the fixed connection or the fixed connections with the predetermined breaking points are provided from the openings of the cartridges in the direction in which the closure, when opening moves to an entry of particles of the fractures into the mix or into the starting components of the mix.
- the end position in the sense of the invention is not to be understood as a final end position.
- the displaceable closure can also be moved from the end position to the starting position and then the cartridges of the cartridge system can be refilled.
- the cartridge system is reusable.
- the starting position like the end position, is to be understood as one of at least two positions into which the displaceable shutter is displaceable.
- FIG. 1 shows an embodiment of a cartridge system according to the invention in cross-sectional view.
- the discharge tube (380) is integrated in the closed position of the closure (360) in the mixing chamber (320) of the cartridge system.
- the discharge pipe (380) from the direction of the cartridge bottom (333) in the direction of the outlet opening (322) is pressed.
- the closure (360) is a hollow cylinder which press-tightly closes the openings (340) in the cartridge walls (332) and thus the cartridges (330) to the mixing space (320) in its initial position.
- the inner diameter of the shutter (360) is larger than the outer diameter of the front part of the discharge pipe (380) facing the discharge pipe tip (381).
- the apertured (385) extension (386) has an outer diameter greater than the inner diameter of the closure (360).
- a step is provided between the extension (386) and the front part of the discharge pipe (380).
- the extension (386) is a hollow cylinder with openings (385) open towards the discharge tube tip (381) and fully closed in the direction of the cartridge bottom (333).
- a static mixer (388) Inside the discharge tube (380) is a static mixer (388).
- the discharge tube (380) When a force is applied to the mixing chamber (320) of this cartridge system from the direction of the cartridge bottom (333), for example with compressed air, the discharge tube (380) is pushed in the direction of the cartridge system head (350). Once the leading edge of the extension (386) facing the dispensing tube tip (381) strikes the cartridge bottom end of the closure (360), the dispensing tube (380) also shifts the closure (360) into the cartridge system head (350). The movement of the closure (360) is limited by a stop (374) located at the top of the cartridge system head (350). In the end position of the closure (360), the latter completely releases the openings (340) and bears against the stop (374). At the same time, the openings (385) of the extension (386) cover the openings (340).
- the static mixer (388) By means of the static mixer (388), the contents of the cartridges (330) in the discharge tube (380) are mixed to form a mix. Finally, the mixed mix is pushed out of the cartridge system by the discharge tube tip (381).
- the shutter (360) is not pushed toward the cartridge bottom (333), but toward the cartridge system head (350) to expose the openings (340).
- the delivery pistons (362) may be interconnected via a web (not shown) such that the movement of the delivery pistons (362) is synchronized.
- displaceable discharge tube (380) in the mixing chamber (320) in the longitudinal direction of the cartridges (330) displaceable discharge tube (380) is located, which contains a static mixer (388) and the cartridge on its side facing away from the cartridge system head (350) side of the outer diameter of the discharge tube (380) is smaller than the inner diameter of the closure (360) in the form of an open hollow cylinder, that on its side facing away from the cartridge system head (350) a hollow, perforated on the lateral surface cylinder as extension (386) is arranged on the the cartridge head (350) facing away from the cartridge is sealed gas-tight whose outer diameter is equal to the inner diameter of the mixing chamber (320), and that in the mixing chamber (320) above the openings (340) of the cartridges (330) pins and / or webs as a stop ( 374) having an inner diameter greater than or equal to the inner diameter of the sliding shutter (360).
- the discharge pipe (380) can be moved from the direction of the cartridge bottom (333) in the direction of the cartridge system head (350) by applying compressed gas.
- the displaceable closure (360) designed as a hollow cylinder is moved in the direction of the cartridge system head (350) until it abuts against webs or pins (374) on the cartridge system head (350).
- This movement of the hollow cylinder (360) towards the cartridge system head (350) exposes the openings (340) of the cartridges (330).
- the perforations (385) of the hollow, perforated cylinder (386) move towards the openings (340) of the cartridges (330). This will open the cartridges (330).
- the movement of the discharge tube (380) may also be by mechanical force via the movement of rods, screws or bolts.
- FIG. 2 shows a plan view of a cartridge system (1) on the cartridge system head (50).
- a look into the outlet opening (22) shows the mixing chamber walls (21), the fastening means (51) and in the middle the displaceable closure (60).
- the cartridge heads (31) of the underlying cartridges (30) (in FIG. 2 not recognizable) attached.
- FIG. 3 shows a plan view of a cartridge system (1) from the direction of the cartridge bottom (33).
- the mixing space (20) bounded by the mixing space walls (21) becomes on both sides of the cartridges (30), of which only the cartridge walls (32) and the delivery pistons (62) can be seen flanked.
- mixing space (20) In the middle of the open in this direction mixing space (20) is the rod (70) which projects into the interior of the mixing chamber (20).
- the rod (70) and the delivery piston (62) are fixedly connected to each other by the web (65).
- a slot (75) is provided in the walls (21, 32) of the mixing chamber (20) and the cartridges (30).
- FIG. 4 shows a cross-sectional view of a cartridge system (1).
- the mixing chamber (20) which is delimited by the mixing chamber wall (21).
- the delivery pistons (62) are constructed as hollow cylinders closed on both sides.
- the rod (70) is arranged inside the mixing chamber (20).
- the rod (70) and the delivery pistons (62) are interconnected by the web (66).
- the cartridges (30) with the mixing chamber (20) connecting walls (21, 32) slots (75) are provided which allow movement of the web (66) and the web (65) inside the cartridge system (1).
- FIG. 5 shows a side view of a cartridge system. Between the two cartridges (30) of the mixing chamber (20) is arranged. Actually, only the mixing chamber walls (21) or the cartridge walls (32) would be visible from the outside. On the head side of the cartridge system (1) of the cartridge system head (50) is arranged, while the cartridge bottom (33) of the web (65) is arranged.
- FIG. 6 shows a plan view of a cartridge bottom of an alternative cartridge system for mixing a mixed material consisting of three components.
- the cartridge system comprises three cartridges, of which only the cartridge walls (132) and the delivery pistons (162) can be seen from the direction of the cartridge bottom. Between the cartridge walls (132) is the mixing chamber (120), in the middle of which a rod (not shown) is arranged. The rod and the delivery piston (162) are fixedly connected to each other with webs (165). The entire cartridge system is enclosed by an additional sheath (179).
- All described embodiments can be easily transferred to a cartridge system with three, four or more cartridges for mixing a mix with three, four or even more components.
- the cartridges are expediently not to be designed with a cylindrical shape.
- cartridge system is understood to mean cartridges which are constructed from two, three, four, five or more cartridges (30, 330), the individual cartridges (30, 330) being arranged parallel to one another.
- the cartridges (30, 330) can be cylindrical hollow bodies. These are so-called side-by-side cartridges.
- the cartridges may already be filled with starting components for a mix to be mixed, but may also be empty, d. H. that they are still with content, such. B. cartridges inserts must be filled.
- the displaceable closure (60, 360) preferably has a closed lateral surface.
- the advantage of the cartridge system is that all openings (40, 340) in the cartridges (30, 330) are closed only by a displaceable closure (60, 360).
- This has a slightly larger cross section than the mixing chamber (20, 120, 320). This means that the lateral surface of the displaceable closure (60, 360) is pressed against the inner wall of the mixing space (20, 120, 320) or its walls (21).
- the slidable closure (60, 360) lies over the openings (40, 340) of the cartridges (30, 330), they are closed.
- the displaceable closure (60, 360) completely overlaps the openings (40, 340) in such a way that a closed lateral surface which is sufficient for the seal abuts the inner wall (21) of the mixing space (20, 120, 320).
- the seal is achieved due to the contact pressure by the close contact of the lateral surface of the displaceable closure (60, 360) with the inner wall (21) of the mixing space (20, 120, 320).
- the cartridges (30, 330) are closed with delivery pistons (62, 362), wherein the delivery pistons (62, 362) are connected to one another at the side facing away from the cartridge bottom (333) by webs (65,) or a plate (695).
- the displaceable closure (60, 360) is preferably designed as a hollow cylinder, wherein it is particularly preferred that the hollow cylinder is closed over the entire cross section only on the side facing the cartridge head (31).
- the perforated extension (386) arranged on the discharge tube (380) or on the displaceable closure (60, 360) is moved in the longitudinal direction of the mixing space (20, 120, 320) and thus the displaceable closure (60, 360 ) is displaced along the mixing space (20, 120, 320), with the openings (385) of the perforated extension (386) being pushed over the openings (40, 340) of the cartridges (30, 330).
- displaceable closure (360) it is also possible to form the displaceable closure (360) as a hollow oval in cross section or in a regular or irregular polygonal cross section. 360.
- the slidable closure (360) may be made of one or more materials, depending on the chemical stability requirements of the pastes and the desired slip characteristics.
- pins, webs or a ring can be arranged as holding means (374) on the inner wall of the mixing chamber (20, 320). They limit the maximum axial displacement of the slidable closure (60, 360) towards the outlet (322).
- the elongated perforated hollow body (86, 386) has a length in the longitudinal direction of the cartridges (30, 330) greater than or at least equal to the length of the openings (40, 340) of the cartridges (30, 330). This ensures that the entire openings (40, 340) of the cartridges (30, 330) can be exposed when attaching the dispensing tube (380). Thus, an exposure of the openings (40, 340) over the entire cross section is possible.
- the holding means (374) are spaced in the longitudinal direction of the cartridges (330) from the openings (40, 340) of the cartridges (30, 330) of at least the length of the extension (386) or of the closure (60 , 360).
- the holding means (374) are necessary so that when displacing the pastes, the displaceable closure (60, 360) can not be moved further than was previously necessary in the opening of the cartridges (30, 330).
- the cartridges (330) may include one or more slots from the cartridge bottom (333) at least half the length of the cartridge aligned parallel to the cartridge axis such that the mixing chamber walls also include slots aligned in the longitudinal direction of the cartridges (330) of equal length how the slots (75) of the cartridges (30, 330) have, wherein the number of slots (75) in the mixing space walls (21) is equal to the number of slots (75) in the cartridges (30, 330) and that the slots (75) of the mixing chamber walls (21) are located above the slots (75) of the cartridges (30, 330) so that the interiors of the cartridges (30, 330) are connected to the mixing space (20, 120, 320).
- the webs 65, 66, 165) have a cross section smaller than the slots (75). This means that when the cartridges (30, 330) are pressed out, the webs (65, 66, 165) can be moved through the slots (75) in the cartridges (30, 330) in the direction of the cartridge system head (50, 350).
- the slots (75) serve as a guide for the webs (65, 66, 165) and thus for the delivery piston (62, 162, 362bei the extrusion movement in the direction of the cartridge head
- the cartridge system according to the invention is used for packaging, storage and application of pasty bone cements, dental multicomponent preparations, adhesives, sealants, cosmetics and foodstuffs. Particularly suitable is the multi-component cartridge system for the storage and application of paste-shaped polymethyl methacrylate bone cements.
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- Surgical Instruments (AREA)
Description
Die Erfindung betrifft ein Kartuschensystem zum Mischen und Applizieren eines Mischguts, insbesondere eines medizinischen Zements, umfassend zwei parallel zueinander angeordnete Kartuschen und einen Mischraum mit einer Auslassöffnung, wobei die Kartuschen jeweils zumindest eine Öffnung in den Kartuschenwänden umfassen, die die Kartuschen mit dem Mischraum verbinden, und die Kartuschen jeweils einen Förderkolben zum Austreiben von Ausgangskomponenten des Mischguts aus den Kartuschen durch die Öffnungen umfassen.The invention relates to a cartridge system for mixing and applying a mixed material, in particular a medical cement, comprising two mutually parallel cartridges and a mixing chamber with an outlet opening, wherein the cartridges each comprise at least one opening in the cartridge walls, which connect the cartridges with the mixing chamber, and the cartridges each comprise a delivery piston for expelling output components of the mix from the cartridges through the openings.
Kartuschensysteme zum Mischen und Applizieren eines Mischguts können aus mehreren Komponenten bestehen und sollen eine sichere Aufbewahrung und einen sicheren Verschluss für Komponenten in zumindest zwei Kartuschen vor ihrer Verwendung gewährleisten. Unmittelbar vor der Applikation des Mischguts soll das Kartuschensystem sicher und schnell zu öffnen sein, wobei eine synchrone Öffnung der einzelnen Kartuschen erstrebenswert ist.Cartridge systems for mixing and applying a mix may consist of several components and are intended to ensure safe storage and secure closure for components in at least two cartridges prior to use. Immediately before the application of the mix, the cartridge system should be safe and easy to open, with a synchronous opening of the individual cartridges is desirable.
Reaktive pastöse Zwei- oder Mehrkomponentensysteme müssen nach ihrer Herstellung bis zur Applikation getrennt aufbewahrt werden, um vorzeitige, unbeabsichtigte Reaktionen der Komponenten zu verhindern. Kartuschensysteme für die Applikation von pastösen Zwei- oder Mehrkomponentensystemen sind seit Jahrzehnten bekannt. Beispielhaft seien dafür die Dokumente
Ein einfaches, aber sehr wirksames Prinzip besteht darin, den Kartuschenkopf mit einem drehbaren Verschluss zu verschließen (
Der gegenwärtig sehr häufig, insbesondere in der Klebstoff- und Dichtungsmittelindustrie verwendete Verschluss basiert darauf, dass am Kartuschenkopf das Wandmaterial der Kartusche sehr dünn ausgebildet ist, so dass diese Wandung leicht durchstochen werden kann. Beim Durchstoßen werden Partikel aus der Wandung abgelöst, die dadurch in das pastöse Material gelangen.The closure currently used very frequently, especially in the adhesives and sealants industry, is based on the fact that the wall material of the cartridge is made very thin at the cartridge head, so that this wall can easily be pierced. When piercing particles are removed from the wall, which thereby enter the pasty material.
Die Rückseite der Kartuschen wird üblicherweise durch bewegliche Kolben verschlossen, die zum Austreiben der Pasten bei der Applikation bestimmt sind. Bei feuchtigkeits- und luftempfindlichen Pasten können Aluminiumkartuschen verwendet werden, die mit Kunststoffkolben verschlossen sind und über die zur Abdichtung Aluminiumzylinder, die an einer Seite geschlossen sind, eingepresst werden. Bei der Applikation der Pasten wird der einseitig geschlossene Aluminiumzylinder zusammen mit dem Kolben mit Hilfe von Auspresspistolen nach vorne in Richtung Kartuschenkopf bewegt und die Paste dabei ausgetrieben. Bei medizinischen Anwendungen kann jedoch ein Kontakt von Pasten mit Aluminiumoberflächen problematisch sein.
Bei der Verwendung von Kartuschensystemen für sterile pastöse Medizinprodukte ist es notwendig, dass nicht nur die Pasten sondern natürlich auch die Kartuschen und das sekundäre Packmittel in steriler Form dem medizinischen Anwender zur Verfügung gestellt werden. So können zum Beispiel nach aseptischer Befüllung der zuvor sterilisierten Kartuschen diese direkt in ein steriles Packmittel überführt werden. Weiterhin kann es bei bestimmten Produkten sinnvoll sein, die Oberflächen der befüllten Kartuschen zusammen mit den Packmitteln nach erfolgter Verpackung zu sterilisieren. Neben der Gammasterilisation, die bei polymerisierbaren Pastensystemen nicht angewendet werden kann, besteht die Möglichkeit mit dem Gas Ethylenoxid zu sterilisieren.The back of the cartridges is usually closed by moving pistons designed to expel the pastes during application. For moisture and air sensitive pastes aluminum cartridges can be used, which are closed with plastic piston and are pressed over the sealing aluminum cylinder, which are closed on one side, for sealing. During the application of the pastes, the aluminum cylinder, which is closed on one side, is moved together with the piston with the help of extrusion guns to the front in the direction of the cartridge head and the paste is expelled. In medical applications, however, contact of pastes with aluminum surfaces can be problematic.
When using cartridge systems for sterile pasty medical devices, it is necessary that not only the pastes but also the cartridges and the secondary packaging are provided in sterile form to the medical user. For example, after aseptic filling of the previously sterilized cartridges, these can be transferred directly into a sterile packaging. Furthermore, it may be useful for certain products to sterilize the surfaces of the filled cartridges together with the packaging after packaging. In addition to the gamma sterilization, the polymerizable paste systems can not be used, it is possible to sterilize with the gas ethylene oxide.
Problematisch bei Pastensystemen, die Monomere mit hohem Dampfdruck enthalten, ist bei einer solchen Sterilisation mit Gas jedoch, dass nach der eigentlichen Sterilisation, bei der Entfernung des restlichen Ethylenoxids durch Einwirkung von Vakuum, ein Teil der Monomere in den Kartuschen verdampft, die dabei eine Gasphase in den Kartuschen ausbilden und somit einen Druck gegen die Kolben ausüben können. Das bedeutet, dass die Kolben unerwünscht in Richtung Kartuschenböden bewegt werden und im Extremfall aus den Kartuschen ausgestoßen werden, so dass die Pasten ausfließen können.A problem with paste systems containing monomers with high vapor pressure, however, is in such a sterilization with gas, that after the actual sterilization, in the removal of the residual ethylene oxide by the action of vacuum, some of the monomers in the cartridges evaporated, while a gas phase form in the cartridges and thus can exert pressure against the pistons. This means that the pistons are undesirably moved in the direction of the cartridge bottoms and in extreme cases are expelled from the cartridges so that the pastes can flow out.
In der Medizin werden seit Jahrzehnten Polymethylmethacrylat-Knochenzemente zur dauerhaften mechanischen Fixierung von Totalgelenkendoprothesen eingesetzt. Diese basieren auf Pulver-Flüssigkeits-Systemen. Es wurden in jüngster Zeit auch Polymethylmethacrylat-Knochenzemente vorgeschlagen, die auf der Verwendung von Zementpasten beruhen (
Bei der Anwendung von Knochenzementen zur Fixierung von Totalgelenkendoprothesen muss immer berücksichtigt werden, dass bei diesen Operationen das OP-Personal unter zeitlichem Druck steht. Bei medizinischen Anwendungen von Kartuschensystemen für die Applikation von pastenförmigen Polymethylmethacrylat-Knochenzementen sollten diese daher grundsätzlich so gestaltet sein, dass sie weitgehend resistent gegenüber Anwenderfehlern sind und auch in Stresssituationen schnell und sicher bedient werden können.When using bone cements for fixation of total joint endoprostheses, it must always be borne in mind that the surgical staff are under pressure during these operations. In medical applications of cartridge systems for the application of paste-like polymethyl methacrylate bone cements, these should therefore be designed in principle so that they are largely resistant to user errors and can be operated quickly and safely even in stress situations.
Ein essentieller Bestandteil von pastenförmigen Polymethylmethacrylat-Knochenzementen ist das Monomer Methylmethacrylat. Dieses Monomer verdampft leicht und hat bei Raumtemperatur einen recht hohen Dampfdruck. Bei der Verwendung von Methylmethacrylat enthaltenden Pasten muss deshalb unbedingt beachtet werden, dass bei Vakuumeinwirkung, wie bei der Entgasung im Rahmen der Sterilisation mit Ethylenoxid, die Kartuschenkolben in den Kartuschen durch das verdampfende Methylmethacrylat bewegt und im Extremfall aus den Kartuschen ausgestoßen werden können.An essential ingredient of pasty polymethyl methacrylate bone cements is the monomer methylmethacrylate. This monomer evaporates easily and has a fairly high vapor pressure at room temperature. When using methylmethacrylate-containing pastes, it is therefore essential to note that in the event of vacuum, as in the case of degassing in the context of sterilization with ethylene oxide, the cartridge pistons in the cartridges are moved through the evaporating methyl methacrylate and, in extreme cases, can be expelled from the cartridges.
Ein gattungsgemäßes Kartuschensystem basiert auf der Verpackung von pastösen Mehrkomponentensystemen in Schlauchbeuteln (
Nachteilig ist hieran, dass die Verpackung von pastösen Materialien in Schlauchbeuteln und zusätzlich in Kartuschen sehr kostenintensiv und nur speziellen Anwendungen vorbehalten ist. Für viele Anwendungen, vor allem im medizinischen Bereich, ist es zudem problematisch, dass sich Teile der geschnittenen Schlauchbeutel ablösen können und dann in die pastösen Komponenten gelangen und so das Mischgut kontaminieren können.The disadvantage of this is that the packaging of pasty materials in tubular bags and in addition in cartridges is very expensive and reserved only for special applications. For many applications, especially in the medical field, it is also problematic that parts of the cut tubular bag can peel off and then get into the pasty components and so can contaminate the mix.
In der
Aufgabe der Erfindung ist es also ein Kartuschensystem bereitzustellen, das einfach und kostengünstig in der Herstellung ist, gleichzeitig aber eine sichere und einfache Öffnung der Kartuschen gewährleistet. Eine sichere Aufbewahrung und ein sicherer Verschluss für pastenförmige Komponenten in zumindest zwei Kartuschen vor ihrer Verwendung sollen gewährleistet sein. Unmittelbar vor der Applikation der Pasten soll das Kartuschensystem mit möglichst geringem Aufwand sicher und schnell zu öffnen sein, um eine einfache Anwendung während Operationen zu ermöglichen und so die Probleme der bisherigen Kartuschensysteme und ihrer Verschlusssysteme vermindern beziehungsweise überwinden. Es soll also ein Verschlusssystem entwickelt werden, welches Kartuschen für mehrere Komponenten sicher verschließt und ein schnelles unkompliziertes Öffnen der einzelnen Kartuschen ermöglicht. Beim Aufsetzen des Austragsrohrs sollen möglichst auch Bedienungsfehler des Anwenders vermieden werden können.The object of the invention is therefore to provide a cartridge system that is simple and inexpensive to manufacture, but at the same time ensures a safe and easy opening of the cartridges. A secure storage and a secure closure for paste-like components in at least two cartridges before their use should be ensured. Immediately prior to the application of the pastes, the cartridge system should be able to be opened safely and quickly with as little effort as possible in order to enable simple application during operations and thus reduce or overcome the problems of the previous cartridge systems and their closure systems. So it should be developed a closure system, which closes cartridges for several components safely and allows a quick uncomplicated opening of the individual cartridges. When placing the dispensing tube as possible operator errors of the user should be avoided.
Diese Aufgaben werden dadurch gelöst, dass im Mischraum ein darin verschiebbar angeordneter Verschluss derart angeordnet ist, dass er die Öffnungen der Kartuschen in einer Ausgangsposition verschließt und dass die Öffnungen zum Mischraum in einer Endposition des verschiebbaren Verschlusses zumindest bereichsweise geöffnet sind, wobei der verschiebbare Verschluss von der Ausgangsposition zur Endposition verschiebbar ist. Der verschiebbare Verschluss ist ein beidseitig offener Hohlraumkörper. Im Inneren des Mischraums ist ein Austragsrohr verschiebbar angeordnet, wobei das Austragsrohr eine der Auslassöffnung zugewandte oder aus ihr herausreichende offene Austragsrohrspitze und eine dem Kartuschenboden zugewandte Verlängerung, die in Richtung des Kartuschenbodens vollständig verschlossen ist, umfasst. Die Verlängerung umfasst Öffnungen in den den Kartuschenwänden zugewandten Seitenwänden, wobei sich im Inneren des Austragsrohrs eine durchgehende Verbindung von den Öffnungen bis zur Austragsrohrspitze erstreckt, in der vorzugsweise ein statischer Mischer angeordnet ist, wobei der Außendurchmesser der Verlängerung kleiner oder gleich dem Innendurchmesser des Mischraums und größer als der Innendurchmesser des Verschlusses ist, während der Rest des im Inneren des Mischraums liegenden Austragsrohrs einen kleineren Außendurchmesser hat als der Innendurchmesser des Verschlusses.These objects are achieved in that a closure arranged displaceably in the mixing chamber is arranged such that it closes the openings of the cartridges in a starting position and that the openings for the mixing chamber are at least partially open in an end position of the displaceable closure, wherein the displaceable Closure is displaceable from the starting position to the end position. The sliding closure is a cavity body open on both sides. A discharge tube is displaceably arranged in the interior of the mixing chamber, wherein the discharge tube comprises an outlet tube tip facing the outlet opening or extending out of it and an extension facing the cartridge bottom which is completely closed in the direction of the cartridge bottom. The extension includes openings in the sidewalls facing the cartridge walls, with a continuous connection extending inside the discharge tube from the openings to the discharge tube tip in which a static mixer is preferably located, the outer diameter of the extension being less than or equal to the inner diameter of the mixing space and greater than the inner diameter of the closure, while the remainder of the discharge tube located inside the mixing space has a smaller outer diameter than the inner diameter of the closure.
Dabei kann vorgesehen sein, dass der Mischraum ein Hohlkörper, insbesondere ein Hohlzylinder, mit Hohlkörperwänden ist, wobei die Öffnungen in den Kartuschen sich durch die Hohlkörperwand bis in den Mischraum erstrecken.It can be provided that the mixing chamber is a hollow body, in particular a hollow cylinder, with hollow body walls, wherein the openings in the cartridges extend through the hollow body wall into the mixing space.
Ferner wird vorgeschlagen, dass der Mischraum zwischen den Kartuschen angeordnet ist, insbesondere derart, dass die Kartuschenwände bereichsweise mit der Hohlkörperwand in einem ausgeführt sind.It is also proposed that the mixing space between the cartridges is arranged, in particular such that the cartridge walls are partially executed with the hollow body wall in one.
Mit der Erfindung wird auch vorgeschlagen, dass der Mischraum parallel zu den Kartuschen angeordnet ist.The invention also proposes that the mixing space is arranged parallel to the cartridges.
Dabei kann vorgesehen sein, dass im Inneren des Mischraums eine bewegliche Stange parallel zu den Förderkolben angeordnet ist, die mit den Förderkolben über zumindest einen Steg und/oder eine Platte fest verbunden ist, wobei die Stange an der der Auslassöffnung zugewandten Seite ein Rastmittel umfasst und im Mischraum ein Gegenrastmittel angebracht ist, das mit dem Rastmittel der Stange derart zusammenwirkt, dass eine Bewegung der Stange aus dem Mischraum heraus und damit der Förderkolben aus den Kartuschen heraus deutlich erschwert, insbesondere verhindert ist.It can be provided that a movable rod is arranged parallel to the delivery piston in the interior of the mixing chamber, which is fixedly connected to the delivery piston via at least one web and / or a plate, wherein the rod on the outlet opening side facing a locking means and in the mixing chamber a counter-locking means is mounted, which cooperates with the locking means of the rod such that a movement of the rod out of the mixing chamber and thus the delivery piston from the cartridges out clearly difficult, in particular prevented.
Dabei kann des weiteren vorgesehen sein, dass die Kartuschenwände und/oder die Mischraumwände zumindest einen Schlitz beginnend am Kartuschenboden aufweisen, der parallel zur Kartuschenachse angeordnet ist, wobei die Breite des oder der Schlitze zur Aufnahme des oder der Stege ausreicht und die Länge des oder der Schlitze insbesondere bis mindestens zur Hälfte der Kartuschenlänge reicht.It can further be provided that the cartridge walls and / or the mixing chamber walls have at least one slot starting at the bottom of the cartridge, which is arranged parallel to the cartridge axis, wherein the width of the slot or slots for receiving the or the webs is sufficient and the length of the slot or slots in particular extends to at least half of the cartridge length.
Dabei kann vorgesehen sein, dass im Mischraum ein Anschlag, vorzugsweise in Form von Zapfen oder Stegen, angeordnet ist, der die Bewegung des verschiebbaren Verschlusses Richtung Zentrum des Mischraums begrenzt und dadurch die Endposition des verschiebbaren Verschlusses definiert ist.It can be provided that in the mixing chamber a stop, preferably in the form of pins or webs, is arranged, which limits the movement of the displaceable closure towards the center of the mixing chamber and thereby the end position of the displaceable closure is defined.
Ferner wird vorgeschlagen, dass der verschiebbare Verschluss in Presspassung im Mischraum angeordnet ist.It is also proposed that the displaceable closure is arranged in press fit in the mixing chamber.
Auch kann vorgesehen sein, dass der verschiebbare Verschluss in Längsrichtung des Mischraums verschiebbar ist.It can also be provided that the displaceable closure is displaceable in the longitudinal direction of the mixing space.
Mit der Erfindung wird zudem vorgeschlagen, dass die Förderkolben die Kartuschen dicht verschließen.The invention also proposes that the delivery pistons seal the cartridges tightly.
Es kann erfindungsgemäß auch vorgesehen sein, dass Dichtmittel, insbesondere Dichtungsringe, an den Öffnungen der Kartuschen zum Mischraum angeordnet sind. Die Dichtmittel sollen die Dichtwirkung des verschiebbaren Verschlusses gegenüber den Öffnungen in den Kartuschen verbessern, wenn die Dichtwirkung des verschiebbaren Verschlusses durch die Presspassung nicht ausreichen sollte.It can also be provided according to the invention that sealing means, in particular sealing rings, are arranged at the openings of the cartridges to the mixing chamber. The sealing means are intended to improve the sealing effect of the displaceable closure with respect to the openings in the cartridges, if the sealing effect of the displaceable closure by the interference fit should not be sufficient.
Dabei kann vorgesehen sein, dass die Dichtmittel um die Öffnungen zum Mischraum zwischen der Innenwand des Mischraums und dem verschiebbaren Verschluss in der Ausgangsposition angeordnet sind.It can be provided that the sealing means are arranged around the openings to the mixing space between the inner wall of the mixing chamber and the displaceable shutter in the starting position.
Mit der Erfindung wird zudem vorgeschlagen, dass eine Platte und/oder zumindest ein Steg bodenseitig mit den Förderkolben fest verbunden ist, und ein Arretierungsmittel mit der Platte und/oder dem zumindest einen Steg verbunden ist, wobei das Arretierungsmittel in den Mischraum reicht und dort in ein Gegenarretierungsmittel greift, so dass eine Bewegung der Platte und/oder des zumindest einen Stegs und der Förderkolben in Richtung des Kartuschenbodens blockiert ist und im Inneren des Mischraums eine Entarretiervorrichtung vorgesehen ist, die fest mit dem verschiebbaren Verschluss verbunden ist, so dass beim Verschieben des verschiebbaren Verschlusses in seine Endpostition, eine Entarretierung der Arretierungsmittel erfolgt, so dass eine Bewegung der Platte und/oder des zumindest einen Stegs und der Förderkolben in Richtung des Kartuschenbodens möglich ist.With the invention it is also proposed that a plate and / or at least one web is firmly connected on the bottom side with the delivery piston, and a locking means is connected to the plate and / or the at least one web, wherein the locking means extends into the mixing chamber and there in a Gegenarretierungsmittel engages, so that movement of the plate and / or the at least one web and the delivery piston is blocked in the direction of the cartridge bottom and in the interior of the mixing chamber a Entarretiervorrichtung is provided which is fixedly connected to the sliding closure, so that when moving the shiftable Closure in his Endpostition, a release of the locking means takes place, so that a movement of the plate and / or the at least one web and the delivery piston in the direction of the cartridge bottom is possible.
Es kann ferner vorgesehen sein, dass das Austragsrohr einen statischen Mischer umfasst. Schließlich wird vorgeschlagen, dass das Austragsrohr fest mit dem verschiebbaren Verschluss verbunden ist, so dass beide ein gemeinsames Teil des Kartsuchenssystems bilden.It can also be provided that the discharge pipe comprises a static mixer. Finally, it is proposed that the discharge pipe is fixedly connected to the sliding closure, so that both form a common part of the Kartsuchenssystems.
Dieses Kartuschensystem und das dazugehörende Verschlusssystem des Kartuschensystems basieren auf der überraschenden Erkenntnis, dass mittels eines beweglichen Verschlusses eine zuverlässige und einfach zu handhabende Öffnung des Kartuschensystems ermöglicht wird, ohne dass beim Öffnen der Kartuschen ein Bauteil, wie die Kartuschenwand, zerstört werden muss, so dass keine Verunreinigung der zu mischenden Komponenten oder des Mischguts mit dem Material des Bauteils zu befürchten ist. Dies ermöglicht einen sicheren Verschluss der Mehrkomponentenkartuschen und ein schnelles, unkompliziertes, zeitgleiches Öffnen der einzelnen Kartuschen des Systems. Das Aufsetzen des Austragsrohrs bewirkt eine zwangsweise, synchrone Öffnung der Kartuschen, so dass die Kartuschen nur bei aufgesetztem Austragsrohr geöffnet sind, wodurch potentielle Bedienungsfehler des Anwenders vermieden werden.This cartridge system and the associated closure system of the cartridge system are based on the surprising finding that a reliable and easy-to-use opening of the cartridge system is made possible by means of a movable shutter, without having to destroy a component such as the cartridge wall when opening the cartridges, so that no contamination of the components to be mixed or of the mixed material with the material of the component is to be feared. This enables a secure closure of the multi-component cartridges and a quick, uncomplicated, simultaneous opening of the individual cartridges of the system. The placement of the dispensing tube causes a forced, synchronous opening of the cartridges, so that the cartridges are opened only when the dispensing tube is mounted, thereby avoiding potential operator errors of the user.
Ein solches Kartuschensystem und ein solches Verschlusssystem kann komplett aus kostengünstigen Kunststoffspritzgussteilen gefertigt werden. Das Kartuschensystem ermöglicht es, bei Krafteinwirkung in Richtung Kartuschensystemkopf die Kolben synchron in den Kartuschen zu bewegen und damit die Pasten gleichmäßig auszupressen, damit das Mischungsverhältnis der Pasten zueinander gewährleistet wird.Such a cartridge system and such a closure system can be made entirely from inexpensive plastic injection molded parts. The cartridge system makes it possible to move the pistons synchronously in the cartridges when force is applied in the direction of the cartridge system head and thus to evenly press out the pastes so that the mixing ratio of the pastes to one another is ensured.
Eine weitere Vereinfachung und Sicherstellung der Bedienbarkeit eines solchen Kartuschensystems ergibt sich dadurch, dass eine Bewegung der Förderkolben bei Einwirkung von Vakuum sicher verhindert werden kann.A further simplification and ensuring the operability of such a cartridge system results from the fact that a movement of the delivery piston can be reliably prevented under the influence of vacuum.
Unter dem Mischraum ist im Sinne der vorliegenden Erfindung der Bereich zu verstehen, der sich zwischen den wenigstens zwei Kartuschen befindet, sowie die daran angrenzenden Bereiche. Er erstreckt sich vom Kartuschenboden, d. h. hinteren, bodenseitigen Teil des Kartuschensystems, bis zur Auslassöffnung am Kartuschensystemkopf an der Vorderseite des Kartuschensystems, umfasst also auch den Innenraum des Kartuschensystemkopfs. Nicht überall im Mischraum muss dabei die Mischung der Ausgangskomponenten des Mischguts erfolgen, sondem nur in Teilbereichen desselben. Ein Mischraum der mit Schläuchen an die Kartuschen angeschlossen ist, und daher der Mischraum nicht im geometrischen Sinne genau zwischen den Kartuschen liegt, ist ebenfalls erfindungsgemäß.For the purposes of the present invention, the mixing space is to be understood as meaning the area which is located between the at least two cartridges and the areas adjacent thereto. It extends from the cartridge bottom, ie the rear, bottom-side part of the cartridge system, to the outlet opening on the cartridge system head on the front side of the cartridge system, ie also includes the interior of the cartridge system head. Not everywhere in the mixing chamber, the mixing of the starting components of the mix has to be done, but otherwise only in parts of the same. A mixing chamber which is connected with hoses to the cartridges, and therefore the mixing chamber is not in the geometrical sense exactly between the cartridges is also according to the invention.
Unter einem verschiebbaren Verschluss im Sinne der vorliegenden Erfindung ist auch ein Verschluss zu verstehen, der zunächst in der Ausgangsposition durch eine feste Verbindung mit den Wänden des Zwischenraums, beispielsweise durch dünne Brücken, verbunden ist, sofern diese feste Verbindung Sollbruchstellen aufweist, die bei einer Krafteinwirkung auf den Verschluss brechen und so das Verschieben des Verschlusses unter Krafteinwirkung ermöglichen. Dabei wird vorgeschlagen, dass die feste Verbindung oder die festen Verbindungen mit den Sollbruchstellen von den Öffnungen der Kartuschen aus gesehen in der Richtung vorgesehen sind, in die sich der Verschluss, beim Öffnen bewegt, um einen Eintrag von Partikeln der Bruchstellen in das Mischgut bzw. in die Ausgangskomponenten des Mischguts zu verhindern. Als Endposition im Sinne der Erfindung ist keine endgültige Endposition zu verstehen. So wäre es beispielsweise vorstellbar vorzusehen, dass der verschiebbare Verschluss auch von der Endposition in die Ausgangsposition bewegbar ist und die Kartuschen des Kartuschensystems dann erneut befüllbar sind. Dadurch ist das Kartuschensystem wiederverwendbar. Ebenso ist dann die Ausgangsposition, wie die Endposition, auch nur als eine von zumindest zwei Positionen zu verstehen, in die der verschiebbare Verschluss verschiebbar ist.Under a sliding closure in the context of the present invention, a closure is to be understood, which is initially in the initial position by a fixed connection to the walls of the gap, for example, by thin bridges, if this solid compound has predetermined breaking points, which at a force Break on the closure and thus allow the movement of the closure under force. It is proposed that the fixed connection or the fixed connections with the predetermined breaking points are provided from the openings of the cartridges in the direction in which the closure, when opening moves to an entry of particles of the fractures into the mix or into the starting components of the mix. The end position in the sense of the invention is not to be understood as a final end position. For example, it would be conceivable to provide that the displaceable closure can also be moved from the end position to the starting position and then the cartridges of the cartridge system can be refilled. As a result, the cartridge system is reusable. Likewise, then, the starting position, like the end position, is to be understood as one of at least two positions into which the displaceable shutter is displaceable.
Im Folgenden werden Ausführungsbeispiele der Erfindung anhand von sechzehn schematisch dargestellten Zeichnungen erläutert. Dabei zeigt:
- Figur 1:
- ein erfindungsgemäßes Kartuschensystem mit integriertem Austragsrohr in Querschnittansicht,
- Figur 2:
- eine Aufsicht auf die Vorderseite eines erfindungsgemäßen Kartuschensystems ,
- Figur 3:
- eine Aufsicht auf den Kartuschenboden eines erfindungsgemäßen Kartuschensystems,
- Figur 4:
- eine Querschnittansicht eines Kartuschensystems ,
- Figur 5:
- eine Seitenansicht eines erfindungsgemäßen Kartuschensystems , und
- Figur 6:
- eine Aufsicht auf einen Kartuschenboden eines zweiten erfindungsgemäßen Kartuschensystems.
- FIG. 1:
- an inventive cartridge system with integrated discharge tube in cross-sectional view,
- FIG. 2:
- a plan view of the front of a cartridge system according to the invention,
- FIG. 3:
- a plan view of the cartridge bottom of a cartridge system according to the invention,
- FIG. 4:
- a cross-sectional view of a cartridge system,
- FIG. 5:
- a side view of a cartridge system according to the invention, and
- FIG. 6:
- a plan view of a cartridge bottom of a second cartridge system according to the invention.
Zu diesem Zweck ist der Verschluss (360) ein Hohlzylinder, der im Presssitz die Öffnungen (340) in den Kartuschenwänden (332) und damit der Kartuschen (330) zum Mischraum (320) in seiner Ausgangsposition verschließt. Der Innendurchmesser des Verschlusses (360) ist größer als der Außendurchmesser des vorderen Teils des Austragsrohrs (380), der der Austragsrohrspitze (381) zugewandt ist. Die mit Öffnungen (385) versehene Verlängerung (386) hat einen Außendurchmesser, der größer als der Innendurchmesser des Verschlusses (360) ist. Zusätzlich ist eine Stufe zwischen der Verlängerung (386) und dem vorderen Teil des Austragsrohrs (380) vorgesehen. Die Verlängerung (386) ist ein Hohlzylinder mit Öffnungen (385), der in Richtung der Austragsrohrspitze (381) offen und in Richtung des Kartuschenbodens (333) vollständig geschlossen ist. Im Inneren des Austragsrohrs (380) befindet sich ein statischer Mischer (388).For this purpose, the closure (360) is a hollow cylinder which press-tightly closes the openings (340) in the cartridge walls (332) and thus the cartridges (330) to the mixing space (320) in its initial position. The inner diameter of the shutter (360) is larger than the outer diameter of the front part of the discharge pipe (380) facing the discharge pipe tip (381). The apertured (385) extension (386) has an outer diameter greater than the inner diameter of the closure (360). In addition, a step is provided between the extension (386) and the front part of the discharge pipe (380). The extension (386) is a hollow cylinder with openings (385) open towards the discharge tube tip (381) and fully closed in the direction of the cartridge bottom (333). Inside the discharge tube (380) is a static mixer (388).
Wenn der Mischraum (320) dieses Kartuschensystems aus Richtung des Kartuschenbodens (333) mit einer Kraft beaufschlagt wird, beispielsweise mit Druckluft, so wird das Austragsrohr (380) in Richtung des Kartuschensystemkopfs (350) geschoben. Sobald die der Austragsrohrspitze (381) zugewandte Vorderkante der Verlängerung (386) auf das kartuschenbodenseitige Ende des Verschlusses (360) trifft, verschiebt das Austragsrohr (380) auch den Verschluss (360) in den Kartuschensystemkopf (350). Die Bewegung des Verschlusses (360) ist durch einen Anschlag (374), der an der Spitze des Kartuschensystemkopfs (350) angeordnet ist, begrenzt. In der Endposition des Verschlusses (360) gibt dieser die Öffnungen (340) vollständig frei und liegt am Anschlag (374) an. Gleichzeitig überdecken die Öffnungen (385) der Verlängerung (386) die Öffnungen (340).When a force is applied to the mixing chamber (320) of this cartridge system from the direction of the cartridge bottom (333), for example with compressed air, the discharge tube (380) is pushed in the direction of the cartridge system head (350). Once the leading edge of the extension (386) facing the dispensing tube tip (381) strikes the cartridge bottom end of the closure (360), the dispensing tube (380) also shifts the closure (360) into the cartridge system head (350). The movement of the closure (360) is limited by a stop (374) located at the top of the cartridge system head (350). In the end position of the closure (360), the latter completely releases the openings (340) and bears against the stop (374). At the same time, the openings (385) of the extension (386) cover the openings (340).
Wird nun einer Kraft, beispielsweise durch Beauftragung mit Druckluft, aus Richtung des Kartuschenbodens (333) auf zwei Förderkolben (362) ausgeübt, so wird der Inhalt der Kartuschen (330) durch die Öffnungen (340) und die Öffnungen (385) in die Verlängerung (386) des Austragsrohrs (380) gedrückt. Mit Hilfe des statischen Mischers (388) werden die Inhalte der Kartuschen (330) im Austragsrohr (380) zu einem Mischgut gemischt. Schließlich wird das gemischte Mischgut durch die Austragsrohrspitze (381) aus dem Kartuschensystem heraus gedrückt.
Bei diesem Ausführungsbeispiel wird, im Gegensatz zu den bisherigen Ausführungsbeispielen, der Verschluss (360) nicht in Richtung des Kartuschenbodens (333), sondern in Richtung des Kartuschensystemkopfs (350) geschoben, um die Öffnungen (340) freizulegen. Die Förderkolben (362) können über einen Steg (nicht gezeigt) miteinander verbunden sein, so dass die Bewegung der Förderkolben (362) synchronisiert ist.If now a force, for example, by application of compressed air, from the direction of the cartridge bottom (333) on two delivery pistons (362) exerted, the contents of the cartridges (330) through the openings (340) and the openings (385) in the extension (386) of the discharge pipe (380). By means of the static mixer (388), the contents of the cartridges (330) in the discharge tube (380) are mixed to form a mix. Finally, the mixed mix is pushed out of the cartridge system by the discharge tube tip (381).
In this embodiment, unlike the previous embodiments, the shutter (360) is not pushed toward the cartridge bottom (333), but toward the cartridge system head (350) to expose the openings (340). The delivery pistons (362) may be interconnected via a web (not shown) such that the movement of the delivery pistons (362) is synchronized.
Es kann also erfindungsgemäß vorgesehen sein, dass sich im Mischraum (320) ein in Längsrichtung der Kartuschen (330) verschiebbares Austragsrohr (380) befindet, das einen statischen Mischer (388) enthält und das an seiner dem Kartuschensystemkopf (350) abgewandten Seite der Außendurchmesser des Austragsrohrs (380) kleiner ist als der Innendurchmesser des Verschlusses (360) in Form eines offenen Hohlzylinders, dass an seiner dem Kartuschensystemkopf (350) abgewandten Seite ein hohler, an der Mantelfläche perforierter Zylinder als Verlängerung (386) angeordnet ist, der an der dem Kartuschenkopf (350) abgewandeten Seite gasdicht verschlossen ist, dessen Außendurchmesser gleich dem Innendurchmesser des Mischraums (320) ist, und dass sich im Mischraum (320) oberhalb der Öffnungen (340) der Kartuschen (330) Zapfen und/oder Stege als Anschlag (374) befinden, die einen Innendurchmesser größer oder gleich dem Innendurchmesser des verschiebbaren Verschlusses (360) besitzen. Das bedeutet, dass sich das Austragsrohr (380) durch Beaufschlagung mit komprimiertem Gas aus der Richtung des Kartuschenbodens (333) in Richtung Kartuschensystemkopf (350) bewegen lässt. Bei dieser Bewegung des Austragsrohrs (380) wird der als Hohlzylinder ausgebildete verschiebbare Verschluss (360) in Richtung Kartuschensystemkopf (350) bewegt, bis dieser an Stege oder Zapfen (374) am Kartuschensystemkopf (350) anschlägt. Durch diese Bewegung des Hohlzylinders (360) in Richtung Kartuschensystemkopf (350) werden die Öffnungen (340) der Kartuschen (330) freigelegt. Gleichzeitig bewegen sich die Perforationen (385) des hohlen, perforierten Zylinders (386) auf die Öffnungen (340) der Kartuschen (330). Dadurch werden die Kartuschen (330) geöffnet. Alternativ kann die Bewegung des Austragsrohrs (380) auch durch mechanische Krafteinwirkung über die Bewegung von Stangen, Schrauben oder Bolzen erfolgen.It may thus be provided according to the invention that in the mixing chamber (320) in the longitudinal direction of the cartridges (330) displaceable discharge tube (380) is located, which contains a static mixer (388) and the cartridge on its side facing away from the cartridge system head (350) side of the outer diameter of the discharge tube (380) is smaller than the inner diameter of the closure (360) in the form of an open hollow cylinder, that on its side facing away from the cartridge system head (350) a hollow, perforated on the lateral surface cylinder as extension (386) is arranged on the the cartridge head (350) facing away from the cartridge is sealed gas-tight whose outer diameter is equal to the inner diameter of the mixing chamber (320), and that in the mixing chamber (320) above the openings (340) of the cartridges (330) pins and / or webs as a stop ( 374) having an inner diameter greater than or equal to the inner diameter of the sliding shutter (360). This means that the discharge pipe (380) can be moved from the direction of the cartridge bottom (333) in the direction of the cartridge system head (350) by applying compressed gas. During this movement of the discharge tube (380), the displaceable closure (360) designed as a hollow cylinder is moved in the direction of the cartridge system head (350) until it abuts against webs or pins (374) on the cartridge system head (350). This movement of the hollow cylinder (360) towards the cartridge system head (350) exposes the openings (340) of the cartridges (330). At the same time, the perforations (385) of the hollow, perforated cylinder (386) move towards the openings (340) of the cartridges (330). This will open the cartridges (330). Alternatively, the movement of the discharge tube (380) may also be by mechanical force via the movement of rods, screws or bolts.
Alle beschriebenen Ausführungsformen lassen sich problemlos auf ein Kartuschensystem mit drei, vier oder noch mehr Kartuschen, zur Mischung eines Mischguts mit drei, vier oder noch mehr Komponenten übertragen. Bei der Verwendung von sehr vielen Komponenten, sind die Kartuschen zweckmäßigerweise nicht mit zylindrischer Form auszugestalten.All described embodiments can be easily transferred to a cartridge system with three, four or more cartridges for mixing a mix with three, four or even more components. When using very many components, the cartridges are expediently not to be designed with a cylindrical shape.
Es ist beispielsweise erfindungsgemäß, dass das Kartuschensystem aus zumindest zwei Kartuschen (30,330) derart aufgebaut ist, dass
- a) um einen inneren Hohlzylinder oder einen inneren unregelmäßig oder regelmäßig geformten Hohlkörper zwei oder mehrere Kartuschen (30330) angeordnet sind, deren Längsachsen parallel zur Achse des inneren Hohlzylinders (20, 120, 320) oder des unregelmäßig oder regelmäßig geformten Hohlkörpers (Mischraum (20, 120, 320) sind,
- b) dass unterhalb der Kartuschenköpfe eine oder mehrere Öffnungen (40, 340) in den Kartuschenwänden (32, 132, 332) angeordnet sind,
- c) dass diese Öffnungen (40, 340) die Innenräume der Kartuschen (30, 330) mit dem Innenraum des inneren Hohlzylinders (20, 120, 320) oder des inneren unregelmäßig geformten Hohlkörpers verbinden,
- d) dass vom hohlen Körper (50, 350) bis zum Kartuschenboden (33, 333) ein durchgängiger Hohlraum ausgebildet ist,
- e) dass im inneren Hohlraum ein in Längsrichtung des Hohlraums verschiebbarer Verschluss (60, 360) in Presspassung angeordnet ist,
- f) dass die Kartuschen (30, 330) mit Förderkolben (62, 162, 362) verschlossen sind,
- g) dass die Förderkolben (62, 162,362) an der dem Kartuschenboden (333) abgewandten Seite durch zumindest einen Steg (65, 165) oder eine Platte miteinander verbunden sind,
- h) dass sich im inneren Hohlzylinder (20, 120, 320) oder inneren unregelmäßig oder regelmäßig geformten Hohlkörper ein Stange (70) befindet, die in Längsrichtung der Förderkolben (62, 162, 362) angeordnet ist, die an den Stegen (65) oder der Platte mit einem Ende befestigt ist, und eine Länge von mindestens der Länge der Förderkolben (62, 162, 362) hat,
- i) dass die Stange (70) an der dem Kartuschenkopf (31) zugewandten Seite gezahnt ist, wobei die Spitzen der Zähne in Richtung Kartuschenboden (333) ausgerichtet sind,
- j) dass die Stange (70) einen Querschnitt kleiner dem Querschnitt des inneren Hohlzylinders (20, 120, 320) oder des inneren unregelmäßig oder regelmäßig geformten Hohlkörpers hat,
- k) dass am Ende des inneren Hohlzylinders (20, 120, 320) oder des inneren unregelmäßig oder regelmäßig geformten Hohlkörpers an der dem Kartuschenboden (333) zugewandten Seite eine flexible Rastung angeordnet ist, die einen Querschnitt kleiner oder gleich der gezahnten Stange (70) hat und einem Austragsrohr (380) mit einem an der Auslassöffnung (381) abgewandten Seite angeordnetem Außengewinde (82), bei dem sich ein statischer Mischer (88, 388) im Innenraum des Austragsrohrs (80, 380) befindet, dass sich an der der Auslassöffnung (381) abgewandten Seite ein an der Mantelfläche perforierter Hohlzylinder (386) oder ein perforierter unregelmäßig oder regelmäßig geformter Hohlkörper befindet, aufgebaut ist.
- a) two or more cartridges (30330) are arranged around an inner hollow cylinder or an inner irregularly or regularly shaped hollow body whose longitudinal axes parallel to the axis of the inner hollow cylinder (20, 120, 320) or the irregular or regularly shaped hollow body (mixing space (20 , 120, 320),
- b) that one or more openings (40, 340) are arranged below the cartridge heads in the cartridge walls (32, 132, 332),
- c) that these openings (40, 340) connect the interior spaces of the cartridges (30, 330) to the interior of the inner hollow cylinder (20, 120, 320) or of the inner irregularly shaped hollow body,
- d) that from the hollow body (50, 350) to the cartridge bottom (33, 333) is formed a continuous cavity,
- e) that in the inner cavity a slidable in the longitudinal direction of the cavity closure (60, 360) is press-fitted,
- f) that the cartridges (30, 330) are closed with delivery pistons (62, 162, 362),
- g) that the delivery pistons (62, 162, 362) are connected to one another at the side facing away from the cartridge bottom (333) by at least one web (65, 165) or a plate,
- h) that in the inner hollow cylinder (20, 120, 320) or inner irregularly or regularly shaped hollow body is a rod (70) which is arranged in the longitudinal direction of the delivery pistons (62, 162, 362) which on the webs (65) or the plate is fixed with one end, and has a length of at least the length of the delivery pistons (62, 162, 362),
- i) that the rod (70) is serrated on the side facing the cartridge head (31), the tips of the teeth being aligned in the direction of the cartridge bottom (333),
- j) that the rod (70) has a cross section smaller than the cross section of the inner hollow cylinder (20, 120, 320) or the inner irregularly or regularly shaped hollow body,
- k) that at the end of the inner hollow cylinder (20, 120, 320) or the inner irregularly or regularly shaped hollow body on the cartridge bottom (333) side facing a flexible latch is arranged, which has a cross section smaller than or equal to the toothed rod (70) has and a discharge pipe (380) with a remote from the outlet opening (381) side external thread (82) in which a static mixer (88, 388) in the interior of the discharge pipe (80, 380) is located on the Facing outlet opening (381) facing away Page is a perforated hollow cylinder (386) perforated on the lateral surface or a perforated irregularly or regularly shaped hollow body is constructed.
Unter dem Begriff Kartuschensystem werden Kartuschen verstanden, die aus zwei, drei, vier, fünf oder mehreren Kartuschen (30, 330) aufgebaut sind, wobei die einzelnen Kartuschen (30, 330) parallel zueinander angeordnet sind. Die Kartuschen (30, 330) können zylinderförmige Hohlköper sein. Es handelt sich um sogenannte Side-by-side-Kartuschen. Die Kartuschen können bereits mit Ausgangskomponenten für ein zu mischendes Mischgut gefüllt sein, können aber auch leer sein, d. h. dass sie noch mit Inhalt, z. B. Kartuscheneinsätzen gefüllt werden müssen.The term cartridge system is understood to mean cartridges which are constructed from two, three, four, five or more cartridges (30, 330), the individual cartridges (30, 330) being arranged parallel to one another. The cartridges (30, 330) can be cylindrical hollow bodies. These are so-called side-by-side cartridges. The cartridges may already be filled with starting components for a mix to be mixed, but may also be empty, d. H. that they are still with content, such. B. cartridges inserts must be filled.
Der verschiebbare Verschluss (60, 360) hat bevorzugt eine geschlossene Mantelfläche.The displaceable closure (60, 360) preferably has a closed lateral surface.
Der Vorteil des Kartuschensystems besteht darin, dass alle Öffnungen (40, 340) in den Kartuschen (30, 330) nur durch einen verschiebbaren Verschluss (60, 360) verschlossen sind. Dieser hat einen geringfügig größeren Querschnitt als der Mischraum (20, 120, 320). Das bedeutet, dass die Mantelfläche des verschiebbaren Verschlusses (60, 360) an die Innenwand des Mischraums (20, 120, 320) bzw. dessen Wände (21) gepresst wird. Wenn der verschiebbare Verschluss (60, 360) über den Öffnungen (40, 340) der Kartuschen (30, 330) liegt, so sind diese verschlossen. Dabei überlappt der verschiebbare Verschluss (60, 360) die Öffnungen (40, 340) vollständig in der Weise, dass noch eine für die Dichtung genügende, geschlossene Mantelfläche an der Innenwand (21) des Mischraums (20, 120, 320) anliegt. Die Dichtung wird infolge des Anpressdrucks durch den engen Kontakt der Mantelfläche des verschiebbaren Verschlusses (60, 360) mit der Innenwand (21) des Mischraums (20, 120, 320) erreicht.The advantage of the cartridge system is that all openings (40, 340) in the cartridges (30, 330) are closed only by a displaceable closure (60, 360). This has a slightly larger cross section than the mixing chamber (20, 120, 320). This means that the lateral surface of the displaceable closure (60, 360) is pressed against the inner wall of the mixing space (20, 120, 320) or its walls (21). When the slidable closure (60, 360) lies over the openings (40, 340) of the cartridges (30, 330), they are closed. In this case, the displaceable closure (60, 360) completely overlaps the openings (40, 340) in such a way that a closed lateral surface which is sufficient for the seal abuts the inner wall (21) of the mixing space (20, 120, 320). The seal is achieved due to the contact pressure by the close contact of the lateral surface of the displaceable closure (60, 360) with the inner wall (21) of the mixing space (20, 120, 320).
Viele der in der Medizin üblichen Kunststoffe, wie Polypropylen, haben nur geringe Haftreibungs- und Gleitreibungskoeffizienten. Das bedeutet, dass bei Gleitpaarungen solcher Kunststoffe durch relativ geringe Krafteinwirkung Gleitvorgänge bewirkt werden können. Der verschiebbare Verschluss (60, 360) kann daher bei Verwendung von geeigneten Kunststoffen durch axiale Bewegung verschoben werden. Dadurch ist es möglich, den verschiebbaren Körper von den Öffnungen (40, 340) der Kartuschen (30, 330) weg zu bewegen und damit die Kartuschen (30, 330) zu öffnen. Wenn sich der verschiebbare Verschluss (60, 360) axial bewegt, können somit synchron die Öffnungen (40, 340) aller Kartuschen (30, 330) gleichzeitig geöffnet werden.Many of the plastics used in medicine, such as polypropylene, have only low static friction and sliding friction coefficients. This means that in sliding pairings of such plastics by relatively small force sliding can be effected. The sliding closure (60, 360) can therefore be displaced by the use of suitable plastics by axial movement. This makes it possible to move the displaceable body away from the openings (40, 340) of the cartridges (30, 330) and thereby open the cartridges (30, 330). Thus, when the slidable shutter (60, 360) moves axially, the openings (40, 340) of all the cartridges (30, 330) can be synchronously opened simultaneously.
Die Kartuschen (30, 330) sind mit Förderkolben (62, 362) verschlossen, wobei die Förderkolben (62, 362) an der dem Kartuschenboden (333) abgewandten Seite durch Stege (65,) oder eine Platte (695) miteinander verbunden sind. Das bedeutet, dass die Förderkolben (62, 362) eine Einheit bilden und nicht einzeln bewegt werden können. Dadurch ist ein gleichmäßiges Austreiben der Pasten aus allen Kartuschen (30, 330) des Kartuschensystems möglich. Diese Eigenschaft ist essentiell, wenn die Kolben durch direkte Beaufschlagung mit komprimiertem Gas bewegt werden sollen.The cartridges (30, 330) are closed with delivery pistons (62, 362), wherein the delivery pistons (62, 362) are connected to one another at the side facing away from the cartridge bottom (333) by webs (65,) or a plate (695). This means that the delivery pistons (62, 362) form a unit and can not be moved individually. This allows a uniform expulsion of the pastes from all cartridges (30, 330) of the cartridge system possible. This feature is essential if the pistons are to be moved by direct pressurization with compressed gas.
Erfindungsgemäß ist, dass der verschiebbare Verschluss (60, 360) bevorzugt als Hohlzylinder ausgebildet ist, wobei besonders bevorzugt ist, dass der Hohlzylinder nur an der dem Kartuschenkopf (31) zugewandten Seite über den gesamten Querschnitt verschlossen ist. Durch den so ausgebildeten Abschluss des Verschlusses (60, 360), der zum Beispiel eine Scheibe sein kann, wird verhindert, dass beim Austreiben der Pasten sich diese im Mischraum (20, 120, 320) in Richtung Kartuschenboden (333) ausbreiten können.According to the invention, the displaceable closure (60, 360) is preferably designed as a hollow cylinder, wherein it is particularly preferred that the hollow cylinder is closed over the entire cross section only on the side facing the cartridge head (31). The thus formed closure of the closure (60, 360), which may be a disk, for example, prevents the latter from spreading in the mixing space (20, 120, 320) in the direction of the cartridge bottom (333) when the pastes are expelled.
Wesentlich für die Erfindung ist, dass die am Austragsrohr (380) oder am verschiebbaren Verschluss (60, 360) angeordnete perforierte Verlängerung (386) in Längsrichtung des Mischraums (20, 120, 320) bewegt wird und damit der verschiebbare Verschluss (60, 360) entlang des Mischraums (20, 120, 320) verschoben wird, wobei die Öffnungen (385) der perforierten Verlängerung (386) über die Öffnungen (40, 340) der Kartuschen (30, 330) geschoben werden. Das bedeutet, dass mit dem Befestigen des Austragsrohrs (380) gleichzeitig der verschiebbare Verschluss (60, 360) verschoben wird und damit die Öffnungen (40, 340) der Kartuschen (30, 330) freigegeben werden und dass sich gleichzeitig die Öffnungen (85, 385) der perforierten Verlängerung (386) über die Öffnungen (40, 340) der Kartuschen (30, 330) schieben und damit die Kartuschen (30, 330) öffnen. Es erfolgt ein zum Einsetzen des Austragsrohrs (380) synchrones Öffnen der Kartuschen (30, 330). Dadurch ist es praktisch unmöglich, dass leicht flüchtige Pastenkomponenten aus den Kartuschen (30, 330) austreten können.It is essential for the invention that the perforated extension (386) arranged on the discharge tube (380) or on the displaceable closure (60, 360) is moved in the longitudinal direction of the mixing space (20, 120, 320) and thus the displaceable closure (60, 360 ) is displaced along the mixing space (20, 120, 320), with the openings (385) of the perforated extension (386) being pushed over the openings (40, 340) of the cartridges (30, 330). This means that by attaching the dispensing tube (380) at the same time the displaceable closure (60, 360) is moved and thus the openings (40, 340) of the cartridges (30, 330) are released and at the same time the openings (85, 385) of the perforated extension (386) slide over the openings (40, 340) of the cartridges (30, 330) and thereby open the cartridges (30, 330). There is a synchronous opening of the dispensing tube (380) opening the cartridges (30, 330). This makes it virtually impossible for volatile paste components to escape from the cartridges (30, 330).
Es ist auch möglich, den verschiebbaren Verschluss (360) als hohlen im Querschnitt ovalen oder im Querschnitt regelmäßig oder unregelmäßig mehreckigen Körper auszubilden. 360. Der verschiebbare Verschluss ( 360) kann aus einem oder mehreren Werkstoffen gefertigt sein, je nach Anforderungen hinsichtlich der chemischen Stabilität gegenüber den Pasten und nach den gewünschten Gleiteigenschaften.It is also possible to form the displaceable closure (360) as a hollow oval in cross section or in a regular or irregular polygonal cross section. 360. The slidable closure (360) may be made of one or more materials, depending on the chemical stability requirements of the pastes and the desired slip characteristics.
Erfindungsgemäß können an der Innenwand des Mischraums (20, 320) Zapfen, Stege oder ein Ring als Haltemittel (374) angeordnet sein. Sie begrenzen die maximale axiale Verschiebung des verschiebbaren Verschlusses (60, 360) in Richtung des Auslasses (322).According to the invention, pins, webs or a ring can be arranged as holding means (374) on the inner wall of the mixing chamber (20, 320). They limit the maximum axial displacement of the slidable closure (60, 360) towards the outlet (322).
Erfindungsgemäß ist, dass der als Verlängerung dienende perforierte Hohlkörper (86, 386) in Längsrichtung der Kartuschen (30, 330) eine Länge größer oder zumindest gleich der Länge der Öffnungen (40, 340) der Kartuschen (30, 330) hat. Dadurch wird gewährleistet, dass die gesamten Öffnungen (40, 340) der Kartuschen (30, 330) beim Befestigen des Austragsrohrs (380) freigelegt werden können. So ist eine Freilegung der Öffnungen (40, 340) über deren gesamten Querschnitt möglich.According to the invention, the elongated perforated hollow body (86, 386) has a length in the longitudinal direction of the cartridges (30, 330) greater than or at least equal to the length of the openings (40, 340) of the cartridges (30, 330). This ensures that the entire openings (40, 340) of the cartridges (30, 330) can be exposed when attaching the dispensing tube (380). Thus, an exposure of the openings (40, 340) over the entire cross section is possible.
Weiterhin ist erfindungsgemäß, .dass die Haltemittel (374) in Längsrichtung der Kartuschen (330) einen Abstand zu den Öffnungen (40, 340) der Kartuschen (30, 330) von mindestens der Länge der Verlängerung (386) bzw. des Verschlusses (60, 360) haben. Die Haltemittel (374) sind notwendig, damit beim Austreiben der Pasten der verschiebbare Verschluss (60, 360) nicht weiter bewegt werden kann, als es zuvor bei der Öffnung der Kartuschen (30, 330) notwendig war.Furthermore, according to the invention, the holding means (374) are spaced in the longitudinal direction of the cartridges (330) from the openings (40, 340) of the cartridges (30, 330) of at least the length of the extension (386) or of the closure (60 , 360). The holding means (374) are necessary so that when displacing the pastes, the displaceable closure (60, 360) can not be moved further than was previously necessary in the opening of the cartridges (30, 330).
Die Kartuschen (330) können einen oder mehrere Schlitze vom Kartuschenboden ( 333) wenigstens bis zur Hälfte der Kartuschenlänge umfassen, die parallel zur Kartuschenachse ausgerichtet sind, so dass auch die Mischraumwände in Längsrichtung der Kartuschen (330) ausgerichtete Schlitze umfassen, die eine gleiche Länge wie die Schlitze (75) der Kartuschen (30, 330) haben, wobei die Anzahl der Schlitze (75) in den Mischraumwänden (21) gleich der Anzahl der Schlitze (75) in den Kartuschen (30, 330) ist und dass die Schlitze (75) der Mischraumwände (21) sich über den Schlitzen (75) der Kartuschen (30, 330) befinden, so dass die Innenräume der Kartuschen (30, 330) mit dem Mischraum (20, 120, 320) verbunden sind.The cartridges (330) may include one or more slots from the cartridge bottom (333) at least half the length of the cartridge aligned parallel to the cartridge axis such that the mixing chamber walls also include slots aligned in the longitudinal direction of the cartridges (330) of equal length how the slots (75) of the cartridges (30, 330) have, wherein the number of slots (75) in the mixing space walls (21) is equal to the number of slots (75) in the cartridges (30, 330) and that the slots (75) of the mixing chamber walls (21) are located above the slots (75) of the cartridges (30, 330) so that the interiors of the cartridges (30, 330) are connected to the mixing space (20, 120, 320).
Es ist erfindungsgemäß, dass die Stege65, 66, 165) einen Querschnitt kleiner den Schlitze (75) haben. Das beutet, dass beim Auspressen der Kartuschen (30, 330) die Stege (65, 66, 165) durch die Schlitze (75) in den Kartuschen (30, 330) in Richtung Kartuschensystemkopf (50, 350) bewegt werden können. Die Schlitze (75) dienen als Führung für die Stege (65, 66, 165) und damit für die Förderkolben (62, 162, 362bei der Auspressbewegung in Richtung KartuschenkopfIt is according to the invention that the
Das erfindungsgemäße Kartuschensystems wird zur Verpackung, Lagerung und Applikation von pastenförmigen Knochenzementen, dentalen Mehrkomponentenzubereitungen, Klebstoffen, Dichtstoffen, Kosmetika und Nahrungsmitteln verwendet. Besonders geeignet ist das Mehrkomponentenkartuschensystem für die Lagerung und Applikation von pastenförmigen Polymethylmethacrylat-Knochenzementen.The cartridge system according to the invention is used for packaging, storage and application of pasty bone cements, dental multicomponent preparations, adhesives, sealants, cosmetics and foodstuffs. Particularly suitable is the multi-component cartridge system for the storage and application of paste-shaped polymethyl methacrylate bone cements.
- 11
- Kartuschensystemcartridge system
- 20, 120, 32020, 120, 320
- Mischraummixing room
- 2121
- MischraumwandMixing chamber wall
- 22, 32222, 322
- Auslassöffnungoutlet
- 30, 33030, 330
- Kartuschecartridge
- 3131
- Kartuschenkopfcartridge head
- 32, 132, 33232, 132, 332
- Kartuschenwandcartridge wall
- 33,33333,333
- Kartuschenbodencartridge base
- 40,34040.340
- Öffnungopening
- 50,35050.350
- KartuschensystemkopfCartridge system head
- 5151
- Befestigungsmittel am KartuschensystemkopfFasteners on the cartridge system head
- 60,36060.360
- Verschlussshutter
- 62,162,36262,162,362
- Förderkolbendelivery piston
- 65, 16565, 165
- Stegweb
- 6666
- Stegweb
- 7070
- Stangepole
- 7171
- Rastmittellatching means
- 7272
- GegenrastmittelSecuring means
- 374374
- Anschlagattack
- 7575
- Schlitzslot
- 7676
- SchlitzendeSlashing
- 380380
- Austragsrohrdischarge pipe
- 381381
- Austragsrohrspitzedispensing tube
- 8282
- Befestigungsmittel am AustragsrohrFasteners on the discharge pipe
- 85, 38585, 385
- Öffnungenopenings
- 86, 38686, 386
- Verlängerungrenewal
- 88,38888.388
- Mischermixer
- 179179
- Ummantelungjacket
Claims (11)
- Cartridge system for mixing and applying a mixing ware, in particular a medical cement, comprising two cartridges (30, 330) that are arranged parallel to each other, and a mixing space (20, 320) having an outlet opening (322), whereby the cartridges (30, 330) each comprise at least one opening (340) in the cartridge walls (32, 332) that connect(s) the cartridges (30, 330) to the mixing space (20, 320), and the cartridges (30, 330) each comprise a feed plunger (62, 362) for expelling starting components of the mixing ware out of the cartridges (30, 330) through the openings (340), whereby a closure (360) that can be shifted in the mixing space (32, 320) is arranged in the mixing space in a manner such that it closes the openings (340) of the cartridges (30, 330) in a starting position and in that the openings (340) to the mixing space (20, 320) are opened, at least in part, in a final position of the shiftable closure (360), whereby the shiftable closure (360) can be shifted from the starting position to the final position, characterised in that the shiftable closure (360) is a hollow body that is open on both sides, and a dispensing tube (380) is arranged such as to be shiftable on the inside of the mixing space (20, 320), whereby the dispensing tube (380) comprises an open dispensing tube tip (381) that faces the dispensing opening (322) or projects from it and an extension (386) facing the cartridge floor (333), which extension is completely closed in the direction of the cartridge floor (333), and the extension (386) comprises openings (385, 485) in the side walls facing the cartridge walls (332), whereby a continuous connection extends on the inside of the dispensing tube (380) from the openings (385, 485) to the dispensing tube tip (381), whereby the external diameter of the extension (386, 486) is smaller than or equal to the internal diameter of the mixing space (20, 320) and is larger than the internal diameter of the closure (360), whereas the remainder of the dispensing tube (380) that is situated inside the mixing space (20, 320) has an external diameter that is smaller than the internal diameter of the closure (360).
- Cartridge system according to claim 1, characterised in that the mixing space (20, 320) is a hollow cylinder with hollow body walls, whereby the openings (340) in the cartridges (30, 330) extend through the hollow body wall (21) into the mixing space (20, 320).
- Cartridge system according to claim 1 or 2, characterised in that the mixing space (20, 320) is arranged between the cartridges (30, 330), in particular is arranged appropriately such that the cartridge walls (32, 332) are provided as the same part as the hollow body wall, at least in part.
- Cartridge system according to any one of the preceding claims, characterised in that
the mixing space (20, 320) is arranged such as to be parallel to the cartridges (30, 330). - Cartridge system according to claim 4, characterised in that the inside of the mixing space (20, 320) has a mobile rod (70) arranged in it parallel to the feed plungers (62, 362) and fixedly connected to the feed plungers (62, 362) through at least one fin (65, 66) and/or a plate, whereby the rod (70) comprises a snap-in locking means on the side facing the outlet opening (22, 322) and an opposite snap-in locking means is attached in the mixing space (20, 320) that acts in concert with the snap-in locking means of the rod (70) in a manner such that a motion of the rod (70) out of the mixing space (20, 320) and therefore a motion of the feed plungers (62, 362) out of the cartridges (30, 330) is significantly hampered, in particular is prevented.
- Cartridge system according to claim 5, characterised in that the cartridge walls (332) and/or the mixing space walls include at least one slit (75) that starts at the cartridge floor (333) and is arranged parallel to the cartridge axis, whereby the width of the slit or slits (75) is sufficient to take up the fin or fins (65, 66, 165) and the length of the slit or slits (75) extends, in particular, to at least half of the length of the cartridge (76).
- Cartridge system according to any one of the preceding claims, characterised in that
a limit stop (374), preferably in the form of pegs or fins, is arranged in the mixing space (20, 320) and limits the motion of the shiftable closure (360) in the mixing space (20, 320) and thus defines the end-position of the shiftable closure (360). - Cartridge system according to claim 7, characterised in that the limit stop (374) is provided in the cartridge system head (350), in particular at the outlet opening (322), and in that the feed plungers (62, 162, 362) and/or the dispensing tube (280) can be subjected to the application of compressed air.
- Cartridge system according to any one of the preceding claims, characterised in that
the shiftable closure (360) is arranged in the mixing space (20, 120, 220, 320) in a press-fit manner and/or is shiftable in longitudinal direction of the mixing space (20, 120, 320). - Cartridge system according to any one of the preceding claims, characterised in that
a plate and/or at least one fin (65, 165) are fixedly connected to the feed plungers (62, 162, 362) on the floor side, and a locking means (70, 71) is connected to the plate and/or at least one fin (65, 165), whereby the locking means (70, 71) extends into the mixing space (20, 120, 320) and therein engages a counter-locking means (72) such that a motion of the plate and/or at least one fin (65, 165) and feed plungers (62, 162, 362) in the direction of the cartridge floor (33, 333) is blocked, and an unlocking facility (691) is provided on the inside of the mixing space (20, 120, 320) that is fixedly connected to the shiftable closure (60, 360) such that shifting the shiftable closure (60, 360) into its end-position is accompanied by an unlocking of the locking means (70, 71) such that a motion of the plate and/or at least one fin (65, 165) and feed plungers (62, 162, 362) in the direction of the cartridge floor (33, 333) is made feasible. - Cartridge system according to any one of the preceding claims, characterised in that
the dispensing tube (380) comprises a static mixer (388).
Applications Claiming Priority (1)
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DE102010019217.1A DE102010019217B4 (en) | 2010-05-04 | 2010-05-04 | cartridge system |
Publications (2)
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EP2384820A1 EP2384820A1 (en) | 2011-11-09 |
EP2384820B1 true EP2384820B1 (en) | 2016-09-07 |
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EP11003052.5A Not-in-force EP2384820B1 (en) | 2010-05-04 | 2011-04-12 | Cartridge system and application tube for such a cartridge system |
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US (1) | US9095871B2 (en) |
EP (1) | EP2384820B1 (en) |
JP (1) | JP5502800B2 (en) |
CN (1) | CN102241304B (en) |
AU (1) | AU2011201857B2 (en) |
CA (1) | CA2737672C (en) |
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-
2010
- 2010-05-04 DE DE102010019217.1A patent/DE102010019217B4/en not_active Expired - Fee Related
-
2011
- 2011-04-12 EP EP11003052.5A patent/EP2384820B1/en not_active Not-in-force
- 2011-04-19 CA CA2737672A patent/CA2737672C/en not_active Expired - Fee Related
- 2011-04-21 AU AU2011201857A patent/AU2011201857B2/en not_active Ceased
- 2011-04-28 US US13/096,260 patent/US9095871B2/en not_active Expired - Fee Related
- 2011-05-03 CN CN201110113235.8A patent/CN102241304B/en not_active Expired - Fee Related
- 2011-05-06 JP JP2011103859A patent/JP5502800B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP2384820A1 (en) | 2011-11-09 |
DE102010019217A1 (en) | 2011-11-10 |
CA2737672A1 (en) | 2011-11-04 |
CA2737672C (en) | 2013-06-25 |
DE102010019217B4 (en) | 2014-01-16 |
AU2011201857B2 (en) | 2013-10-17 |
JP5502800B2 (en) | 2014-05-28 |
CN102241304A (en) | 2011-11-16 |
JP2011235961A (en) | 2011-11-24 |
US20110272436A1 (en) | 2011-11-10 |
CN102241304B (en) | 2014-07-16 |
US9095871B2 (en) | 2015-08-04 |
AU2011201857A1 (en) | 2012-03-01 |
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