EP2361020A1 - A method for the detoxification of food products and food raw materials contaminated with aflatoxins - Google Patents

A method for the detoxification of food products and food raw materials contaminated with aflatoxins

Info

Publication number
EP2361020A1
EP2361020A1 EP09775282A EP09775282A EP2361020A1 EP 2361020 A1 EP2361020 A1 EP 2361020A1 EP 09775282 A EP09775282 A EP 09775282A EP 09775282 A EP09775282 A EP 09775282A EP 2361020 A1 EP2361020 A1 EP 2361020A1
Authority
EP
European Patent Office
Prior art keywords
food
raw materials
food products
aflatoxins
detoxification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09775282A
Other languages
German (de)
French (fr)
Inventor
Giorgio Gilli
Daniele Tartaro
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valida Srl
Original Assignee
Valida Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Valida Srl filed Critical Valida Srl
Publication of EP2361020A1 publication Critical patent/EP2361020A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B9/00Preservation of edible seeds, e.g. cereals
    • A23B9/16Preserving with chemicals
    • A23B9/18Preserving with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C7/00Other dairy technology
    • A23C7/04Removing unwanted substances other than lactose or milk proteins from milk
    • A23C7/043Removing unwanted substances other than lactose or milk proteins from milk using chemicals in liquid or solid state, e.g. flocculating, adsorbing or extracting agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L11/00Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
    • A23L11/30Removing undesirable substances, e.g. bitter substances
    • A23L11/34Removing undesirable substances, e.g. bitter substances using chemical treatment, adsorption or absorption
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/358Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/276Treatment with inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Definitions

  • the present invention relates to a method for the detoxification of food products and food raw materials contaminated with aflatoxins.
  • Aflatoxins are micotoxins produced by several species of Ascomycetes, genus Aspergillus, particularly Aspergillus flavus and Aspergillus parasiticus, and certain moulds.
  • Aflatoxins are extremely noxious for human health, as they are characterized by a considerable liver carcinogenity resulting from the fact that these substances are metabolized by the liver, by which they are turned into a reactive intermediate, aflatoxin Ml, and an epoxy.
  • Those members of the genus Aspergillus that are suitable to produce aflatoxins are widely found in nature. These micro-organisms can colonize and contaminate cultures, particularly of cereals, both during harvest and storage. Those cultures that are particularly subjected to infection by Aspergillus and accordingly to contamination by aflatoxins are cereals (such as maize, sorghum, millet, rice, wheat), oilseeds (such as peanut, soy, sunflower, cotton), spices and tree nuts (almond, pistachio, nut, coconut, Brazil nut). Aflatoxins can also develop in the milk of animals fed with contaminated feed.
  • cereals such as maize, sorghum, millet, rice, wheat
  • oilseeds such as peanut, soy, sunflower, cotton
  • spices and tree nuts almond, pistachio, nut, coconut, Brazil nut.
  • Aflatoxins can also develop in the milk of animals fed with contaminated feed.
  • the environmental conditions suitable to facilitate the development of Aspergillus are particularly connected to a high amount of humidity (at least 7%) and environmental stress conditions, such as for example drought periods and high temperatures.
  • British patent GB 1,1 17,573 describes the treatment of food materials with an aqueous hydrogen peroxide suspension at a temperature of at least 70°C.
  • An object of the present invention is thus to provide a method for treating food products and food raw materials, which has such characteristics as flexibility of application, low price, high level of effectiveness in eliminating contamination by aflatoxins and/or other specific contaminants, without however causing any change in the visual, organoleptic and nutritional characteristics of the food products being treated or food raw material being treated.
  • Another object of the present invention is to provide a method for treating food products and food raw materials which does not involve the use of substances or conditions that are dangerous for operators and which further provides the operators with a high level of safety in handling the food products or raw materials being treated.
  • the present invention provides a method for the detoxification of food products and food raw materials contaminated with aflatoxins, particularly cereals and tree nuts, comprising the step of atomizing or nebulizing hydrogen peroxide on food products and/or food raw materials to be detoxified.
  • the preferred treatment conditions are as follows: at least 2 minute time of contact between hydrogen peroxide and food product or food raw material to be detoxified, most preferably ranging between 2 and 20 minutes; concentration of the hydrogen peroxide ranging from 1 and 30%, preferably between 6 and 30%, most preferably between 4 and 20%; ambient temperature and pressure.
  • the step of atomiza- tion or nebulization of the hydrogen peroxide is followed by drying the food products and/or food raw materials which have been treated, up to a reduction in the residual humidity content below about 7%.
  • Hydrogen peroxide can be delivered using any atomization or nebulization device that is preferably provided with a predefined control and dosing system.
  • the method of the invention advantageously results in the destruction (denaturation) of the aflatoxins that are present both on the surface of food products and deeply therein, without leaving any chemical residue and without changing neither the aspect nor the nutritional characteristics of the treated food product or food material, while ensuring the disinfection thereof.
  • the method of the invention can be applied to automatic packaging machines or it can be used in "stand-alone" conditions as an operating step to be carried out prior to other manufacturing treatments, such as for example roasting or other.
  • the method of the invention can be directly used both by the manufacturer at a time immediately after the harvest (before storage) or prior to overseas shipping, and by the importer when contaminations are detected in the oncoming cargo.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Botany (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Cereal-Derived Products (AREA)
  • Storage Of Fruits Or Vegetables (AREA)
  • Jellies, Jams, And Syrups (AREA)

Abstract

A method is described for the detoxification of food products and/or food raw materials contaminated with aflatoxins, such as for example cereals and tree nuts, particularly pistachios, comprising the step of atomizing or nebulizing hydrogen peroxide at a concentration preferably ranging between 1 and 30% on food products and/or food raw materials to be detoxified. This treatment results in the elimination or reduction of the aflatoxin content both on the surface of the treated food product and deeply therein.

Description

A method for the detoxification of food products and food raw materials contaminated with aflatoxins
The present invention relates to a method for the detoxification of food products and food raw materials contaminated with aflatoxins.
Aflatoxins are micotoxins produced by several species of Ascomycetes, genus Aspergillus, particularly Aspergillus flavus and Aspergillus parasiticus, and certain moulds.
Aflatoxins are extremely noxious for human health, as they are characterized by a considerable liver carcinogenity resulting from the fact that these substances are metabolized by the liver, by which they are turned into a reactive intermediate, aflatoxin Ml, and an epoxy.
Those members of the genus Aspergillus that are suitable to produce aflatoxins are widely found in nature. These micro-organisms can colonize and contaminate cultures, particularly of cereals, both during harvest and storage. Those cultures that are particularly subjected to infection by Aspergillus and accordingly to contamination by aflatoxins are cereals (such as maize, sorghum, millet, rice, wheat), oilseeds (such as peanut, soy, sunflower, cotton), spices and tree nuts (almond, pistachio, nut, coconut, Brazil nut). Aflatoxins can also develop in the milk of animals fed with contaminated feed.
The environmental conditions suitable to facilitate the development of Aspergillus are particularly connected to a high amount of humidity (at least 7%) and environmental stress conditions, such as for example drought periods and high temperatures.
The main problem of contamination of food products by aflatoxins results from these substances being very difficult to eliminate, and in that they resist to the treatments that are normally used for sterilizing food products. It should be also noted that the maximum rates of aflatoxins in food products as contemplated by law are very low, in the order of parts per billion (ppb). Paulsen MR et al., Journal of Food Science, vol. 14, No. 3, p 667-671, describe detoxification of peanuts contaminated with aflatoxins by dipping the latter within a 5% hydrogen peroxide solution. The Table 2 of this publication, however, indicates that the removal of the cuticle from shelled peanuts is essential to achieve a significant abatement of the afla- toxin contents, even after dipping in the hydrogen peroxide solution.
British patent GB 1,1 17,573 describes the treatment of food materials with an aqueous hydrogen peroxide suspension at a temperature of at least 70°C.
As far as the inventors are aware, no method is known for treating food products and food raw materials, particularly cereals and tree nuts, which is suitable to eliminate or reduce the aflatoxin rate below the limits contemplated by law, which at the same time does not suffer from the drawback of changing the organoleptic, nutritional and visual characteristics of the food product or food material, particularly the natural color thereof.
An object of the present invention is thus to provide a method for treating food products and food raw materials, which has such characteristics as flexibility of application, low price, high level of effectiveness in eliminating contamination by aflatoxins and/or other specific contaminants, without however causing any change in the visual, organoleptic and nutritional characteristics of the food products being treated or food raw material being treated.
Another object of the present invention is to provide a method for treating food products and food raw materials which does not involve the use of substances or conditions that are dangerous for operators and which further provides the operators with a high level of safety in handling the food products or raw materials being treated.
These and other objects are achieved by means of the present invention, which provides a method for the detoxification of food products and food raw materials contaminated with aflatoxins, particularly cereals and tree nuts, comprising the step of atomizing or nebulizing hydrogen peroxide on food products and/or food raw materials to be detoxified. The preferred treatment conditions are as follows: at least 2 minute time of contact between hydrogen peroxide and food product or food raw material to be detoxified, most preferably ranging between 2 and 20 minutes; concentration of the hydrogen peroxide ranging from 1 and 30%, preferably between 6 and 30%, most preferably between 4 and 20%; ambient temperature and pressure.
In a preferred embodiment of the method according to the invention, the step of atomiza- tion or nebulization of the hydrogen peroxide is followed by drying the food products and/or food raw materials which have been treated, up to a reduction in the residual humidity content below about 7%.
The experimental data obtained in the laboratory by applying the above-mentioned treatment conditions, have highlighted a great ability of destructing aflatoxins. Starting from a sample (pistachios) with 350 ppb contamination and exposing the latter to the above treatment conditions for about 2 minutes, including a drying step, levels of aflatoxin <2 ppb have been measured on the tested samples. Table 1 shows the results obtained from the tests, in terms of abatement of aflatoxins, based on the time of treatment.
Table 1
In two pistachio samples which after being treated with hydrogen peroxide for 30 and 45 seconds, respectively, resulted to be almost completely wet due to the accidental formation of condensate, no reduction in the initial content of aflatoxins has been observed (> 50 ppb).
Hydrogen peroxide can be delivered using any atomization or nebulization device that is preferably provided with a predefined control and dosing system.
The method of the invention advantageously results in the destruction (denaturation) of the aflatoxins that are present both on the surface of food products and deeply therein, without leaving any chemical residue and without changing neither the aspect nor the nutritional characteristics of the treated food product or food material, while ensuring the disinfection thereof.
The method of the invention can be applied to automatic packaging machines or it can be used in "stand-alone" conditions as an operating step to be carried out prior to other manufacturing treatments, such as for example roasting or other.
The method of the invention can be directly used both by the manufacturer at a time immediately after the harvest (before storage) or prior to overseas shipping, and by the importer when contaminations are detected in the oncoming cargo.
The application of this method which can, as demonstrated by the experiments, eliminate or however reduce the contamination by aflatoxins to acceptable levels, advantageously allows reducing the risk involved for the operators in charge of the manufacturing process, reducing the risk of contaminating other food products, reducing the damages to end-users' health and reducing the waste of material and the costs deriving from the forced disposal of contaminated product lots.

Claims

1. A method for the detoxification of food products and/or food raw materials contaminated with aflatoxins, comprising the step of atomizing or nebulizing hydrogen peroxide on the food products and/or food raw materials to be detoxified.
2. The method according to claim 1, wherein the food products and/or food raw materials to be detoxified are contacted with the hydrogen peroxide for a period of time not shorter than 2 minutes.
3. The method according to claim 2, wherein the food products and/or food raw materials to be detoxified are contacted with the hydrogen peroxide for a period of time comprised between 2 and 20 minutes.
4. The method according to any claim 1 to 3, wherein the food product and/or raw material to be detoxified is subjected to a drying step after atomization or nebulization of hydrogen peroxide.
5. The method according to claim 4, wherein the drying step is carried out at least until the humidity content has been reduced in the food products and/or food raw materials to less than 7%.
6. The method according to any of claims 1 to 5, wherein the hydrogen peroxide is employed at a concentration ranging between 1 and 30%.
7. The method according to any of claims 1 to 6, wherein the nebulization or atomization is carried out at ambient temperature.
8. The method according to any of claims 1 to 7, wherein the nebulization or atomization is carried out at ambient pressure.
9. The method according to any of claims 1 to 8, for the detoxification of cereals, tree nuts, spices or oilseeds.
10. The method according to claim 9, for the detoxification of pistachio or peanut.
EP09775282A 2008-10-30 2009-10-28 A method for the detoxification of food products and food raw materials contaminated with aflatoxins Withdrawn EP2361020A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITTO2008A000805A IT1395243B1 (en) 2008-10-30 2008-10-30 PROCEDURE FOR DETOXIFICATION OF FOOD AND RAW FOOD MATERIALS CONTAMINATED BY AFLATOSSINE
PCT/IB2009/054767 WO2010049893A1 (en) 2008-10-30 2009-10-28 A method for the detoxification of food products and food raw materials contaminated with aflatoxins

Publications (1)

Publication Number Publication Date
EP2361020A1 true EP2361020A1 (en) 2011-08-31

Family

ID=40897373

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09775282A Withdrawn EP2361020A1 (en) 2008-10-30 2009-10-28 A method for the detoxification of food products and food raw materials contaminated with aflatoxins

Country Status (6)

Country Link
EP (1) EP2361020A1 (en)
IL (1) IL212443A0 (en)
IT (1) IT1395243B1 (en)
MA (1) MA32824B1 (en)
TN (1) TN2011000184A1 (en)
WO (1) WO2010049893A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019162362A1 (en) 2018-02-22 2019-08-29 Universidade De Santiago De Compostela Method for detoxification of food, feed and water contaminated with natural toxins
CN115109650B (en) * 2021-03-19 2024-01-23 丰益(上海)生物技术研发中心有限公司 Method for preparing flavor grease

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1117573A (en) * 1966-06-07 1968-06-19 Council Scient Ind Res Improvements in or relating to the detoxification of foodstuffs containing aflatoxin
WO1994004036A1 (en) * 1992-08-14 1994-03-03 American Sterilizer Company A method of decontamination of food
US20050084415A1 (en) * 2001-02-16 2005-04-21 Steris, Inc. High capacity flash vapor generation systems

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2010049893A1 *

Also Published As

Publication number Publication date
IL212443A0 (en) 2011-06-30
IT1395243B1 (en) 2012-09-05
WO2010049893A1 (en) 2010-05-06
ITTO20080805A1 (en) 2010-04-30
TN2011000184A1 (en) 2012-12-17
MA32824B1 (en) 2011-11-01

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