EP2352875A2 - Procédé et composition pour le traitement de matériaux textiles - Google Patents

Procédé et composition pour le traitement de matériaux textiles

Info

Publication number
EP2352875A2
EP2352875A2 EP09749046A EP09749046A EP2352875A2 EP 2352875 A2 EP2352875 A2 EP 2352875A2 EP 09749046 A EP09749046 A EP 09749046A EP 09749046 A EP09749046 A EP 09749046A EP 2352875 A2 EP2352875 A2 EP 2352875A2
Authority
EP
European Patent Office
Prior art keywords
fabric
fabrics
treating
treatment
soil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09749046A
Other languages
German (de)
English (en)
Inventor
Somnath Das
Amitava Pramanik
Srinivasa Gopalan Raman
Maya Treesa Saji
Vishal Saxena
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP2352875A2 publication Critical patent/EP2352875A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/168—Organometallic compounds or orgometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06—Inorganic compounds
    • C11D9/08—Water-soluble compounds
    • C11D9/10—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

Definitions

  • the invention relates to a method of treating a fabric. It particularly relates to a method of treating a fabric with a rinse product that reduce soil pickup and further ensures that the fabric is cleaner after the subsequent wash.
  • Detergent formulations generally comprise surfactants and builders.
  • Surfactants are believed to work by reducing the surface tension of water thereby ensuring preferential partitioning of the soil from the surface of the fabric into the wash water.
  • Builders are believed to act by reducing the hardness of water, thereby ensuring efficient utilization of the surfactants.
  • Various other benefit agents have been included in detergent formulations e.g. perfumes, optical bhghteners, electrolytes, free flow agents, soil release polymers (SRP), anti-redeposition agents (ARD), enzymes, bleaches, colourants and preservatives.
  • SRP and ARD agents are added to detergent formulation to enhance cleaning by acting on the soil.
  • Soil redeposition is a phenomenon that reduces the effective cleaning as compared to what surfactants can theoretically provide. Soil redeposition is a long standing problem that detergent formulators have long fought to solve. Redeposition is defined as partitioning of soil removed from dirty clothes back on to both dirty/clean clothes during the washing process. This problem is illustrated by showing the gradual greying of a fresh white garment that has never been worn or used but only goes through the wash load. This shows that one of the primary reasons for whiteness loss or greying is due to redeposition of soil. Typically, the whiteness loss due to redeposition is not evident in a single wash cycle but manifests itself gradually after multiple cycles. Some examples of common Anti redeposition polymers are sodium carboxy metyhl cellulose (SCMC), Sokalan CP5 or CP7, poly aspartic acid, Alcosperse and Narlex H1200
  • SRP agents act by mechanisms which makes the soil easier to release from the surface of the fabric.
  • Several agents have been used to give soil release benefits: For example, starches, modified starches, carboxymethyl celluslose, polyethylene glycols, copolymers of maleic anhydride, and anionic surfactants provide improved soil release when sprayed or padded on to polyester or polyamide fabrics prior to soiling.
  • acrylate based copolymers have been successfully deposited on fabric from acidic rinses or rinses containing relatively high concentrations of polyvalent metal ions or water-soluble amine salts to give temporary soil release finishes. Fluorinated soil release agents can also be applied in a rinse mode.
  • Polyester based co-poly(ethylene terepthalate)(polyoxyethylene terepthalate) (PET-POET soil release agents)have been particularly used for polyester fabrics These polymers were commercialized under trade names of Permalose, Cirrasol, PTG, Cirrasol PTN and Milease T.
  • the above agents are generally included in detergent formulations which are added in the wash cycle of the cleaning process. These cleaning formulations do not help much in reducing subsequent post-wash soiling of the fabrics.
  • the present inventors have determined during the course of their extensive research in this area that one of the main ways in which soiling of fabrics can be kept more clean is by ensuring that soil pickup by the fabric post the wash is minimized.
  • the present inventors then invented a heretofore not known step of treating the fabric during the rinse stage with a zinc compound that is able to give the above benefits. Without wishing to be bound by theory, the inventors believe that the present invention renders the surface of the fabric more hydrophobic thereby ensuring soil repellency benefits to the consumer fabrics.
  • Detergent formulations generally comprise surfactants and builders. Surfactants are believed to work by reducing the surface tension of water thereby ensuring preferential partitioning of the soil from the surface of the fabric into the wash water. Builders are believed to act by reducing the hardness of water, thereby ensuring efficient utilization of the surfactants.
  • Various other benefit agents have been included in detergent formulations e.g. perfumes, optical brighteners, electrolytes, free flow agents, soil release polymers (SRP), anti-redeposition agents (ARD), enzymes, bleaches, colourants and preservatives. Of the above, SRP and ARD agents are added to detergent formulation to enhance cleaning by acting on the soil.
  • Soil redeposition is a phenomenon that reduces the effective cleaning as compared to what surfactants can theoretically provide. Soil redeposition is a long standing problem that detergent formulators have long fought to solve. Redeposition is defined as partitioning of soil removed from dirty clothes back on to both dirty/clean clothes during the washing process. This problem is illustrated by showing the gradual greying of a fresh white garment that has never been worn or used but only goes through the wash load. This shows that one of the primary reasons for whiteness loss or greying is due to redeposition of soil. Typically, the whiteness loss due to redeposition is not evident in a single wash cycle but manifests itself gradually after multiple cycles. Some examples of common Anti redeposition polymers are sodium carboxy metyhl cellulose (SCMC), Sokalan CP5 or CP7, poly aspartic acid, Alcosperse and Narlex H1200.
  • SCMC sodium carboxy metyhl cellulose
  • Sokalan CP5 or CP7 Sokalan CP5 or CP7
  • SRP agents act by mechanisms which makes the soil easier to release from the surface of the fabric.
  • Several agents have been used to give soil release benefits: For example, starches, modified starches, carboxymethyl celluslose, polyethylene glycols, copolymers of maleic anhydride, and anionic surfactants provide improved soil release when sprayed or padded on to polyester or polyamide fabrics prior to soiling.
  • acrylate based copolymers have been successfully deposited on fabric from acidic rinses or rinses containing relatively high concentrations of polyvalent metal ions or water-soluble amine salts to give temporary soil release finishes. Fluorinated soil release agents can also be applied in a rinse mode.
  • Polyester based co-poly(ethylene terepthalate)(polyoxyethylene terepthalate) (PET-POET soil release agents)have been particularly used for polyester fabrics These polymers were commercialized under trade names of Permalose, Cirrasol, PTG, Cirrasol PTN and Milease T.
  • the above agents are generally included in detergent formulations which are added in the wash cycle of the cleaning process. These cleaning formulations do not help much in reducing subsequent post-wash soiling of the fabrics.
  • the present inventors have determined during the course of their extensive research in this area that one of the main ways in which soiling of fabrics can be kept more clean is by ensuring that soil pickup by the fabric post the wash is minimized.
  • the present inventors then invented a heretofore not known step of treating the fabric during the rinse stage with a zinc compound that is able to give the above benefits. Without wishing to be bound by theory, the inventors believe that the present invention renders the surface of the fabric more hydrophobic thereby ensuring soil repellency benefits to the consumer fabrics. To the knowledge of the inventors, some papers have been published which describe methods of making substrates more hydrophobic.
  • the present inventors have determined that the process described by the above cited prior art are not suitable for everyday application in the homes for treating consumer fabrics in terms of meeting the desired technical efficacy, safety and convenience to the consumer and cost.
  • Another object of the present invention is to provide a method of treating a fabric during the rinse stage of the fabric cleaning process that reduces subsequent soiling of the fabric during use by the consumer.
  • the present inventors have determined that the process described by the above cited prior art are not suitable for everyday application in the homes for treating consumer fabrics in terms of meeting the desired technical efficacy, safety and convenience to the consumer and cost.
  • Another object of the present invention is to provide a method of treating a fabric during the rinse stage of the fabric cleaning process that reduces subsequent soiling of the fabric during use by the consumer.
  • the present invention provides for a method for treating a fabric comprising the steps of: (a) contacting the fabric with an aqueous solution, at a pH in the range of 7 to 11 , comprising (i) a water- soluble zinc compound, (ii) a deposition aid selected from the group consisting of an amine compound or an amino acid and (iii) a soap and
  • a fabric treatment composition comprising: (i) 20 to 90 % water soluble zinc compound;
  • a deposition aid selected from the group consisting of an amine compound or an amino acid; and (iii) 5 to 50% soap.
  • the present invention provides for method that involves adding a set of compounds to the water during the rinse stage of the washing process.
  • the set of compounds are: (i) a water- soluble zinc compound
  • a deposition aid selected from the group consisting of an amine compound or an amino acid and (iii) a soap
  • treatment media may comprise an alkaline compound.
  • Preferred alkaline compounds are alkali metal carbonate or hydroxide. Most preferred alkaline compounds are sodium carbonate or sodium hydroxide.
  • the alkaline compound is preferably present in 0.01 to 0.5%, more preferably in 0.05 to 0.2% by weight of the treatment media.
  • the step of treating the fabric with the above set of compounds is preferably carried out for a time period of about 15 minutes to about 90 minutes, preferably from 20 minutes to an hour.
  • This treatment step could be with the fabric soaked in the treatment media with no agitation or the treatment media could be agitated.
  • water soluble refers to a substance having solubility of greater than 0.1 g per 100 g of water at a temperature of 25 0 C.
  • the preferred water soluble zinc compounds for use in the present invention are zinc chloride, sulphate, nitrate or acetate, of which zinc nitrate is preferred.
  • the zinc compound is preferably present in 0.01 to 1 %, more preferably in 0.05 to 0.5% by weight of the treatment media.
  • the deposition aid is either an amine compound or an amino acid.
  • Suitable amine compounds are thethanol amine, diethanol amine or mono ethanol amine; triethanol amine being more preferred.
  • Suitable amino acids are alanine, derivatives of alanine like phenyl alanine, 3,4-dihydroxy-L-phenylalanine or histidine.
  • the deposition aid is preferably present in 0.01 % to 0.5%, more preferably from 0.05% to 0.3% by weight of the treatment media.
  • the treatment media also comprises soap.
  • Soap is a salt of a fatty acid.
  • Preferred soaps are C 8 -C 24 soap, preferably Ci 0 -C 2 O soap, and more preferably Ci 2 -Ci 8 soap.
  • the soap may or may not have one or more carbon-carbon double bond or triple bond.
  • the iodine value of the soap which is indicative of degree of unsaturation, is preferably less than 20, more preferably less than 10, and most preferably less than 5. Saturated soap having no carbon-carbon double bond or triple bond is particularly preferred.
  • the soap may be water soluble or water insoluble. According to a preferred aspect, the soap is water soluble.
  • Non-limiting examples of water soluble soaps that can be used according to the present invention include sodium laurate, sodium caprylate, and sodium myristate.
  • the treatment media preferably comprises at least 0.01 to 0.5%, more preferably 0.05 to 0.3% soap by weight of the treatment media.
  • the method of the invention is carried out at a pH of the treatment media in the range of 7 to 11 , more preferably between 8 and 11 and most preferably between 8 and 9.
  • the fabric treatment method of the invention may be carried out without any heating or cooling i.e. at normal room temperature e.g. from 15 to 4O 0 C.
  • liquid to cloth ratio or L/C ratio as used herein means the ratio of mass of the treatment media that is in contact with the fabric to the mass of the fabric. It is preferred that the liquor to cloth ratio in the treatment step is preferably from 2 to 100, more preferably from 5 to 50, most preferably from 5 to 20.
  • the fabrics may be further rinsed although no further rinse step is essential for obtaining the benefits of the invention.
  • the fabrics may be optionally squeezed before drying, although this is not essential.
  • the fabrics are then dried.
  • the fabrics may be air dried, sun dried or dried in a drying machine. It is preferred that the fabrics after drying are ironed.
  • the method of the present invention for treatment of fabric may be carried out in the rinse stage after the fabrics are hand washed or the rinsing may be carried out in a machine.
  • the method of the invention has the additional advantage that the treated fabric has antibacterial property.
  • the bacteria that get transferred to the fabric from the atmosphere during storage and use are either killed or are not allowed to grow.
  • One of the advantages of the anti-bacterial property of the treated fabric is that it affords malodour control to the fabric.
  • zinc compounds give anti-bacterial property to treated substrates. This is traditionally done by coating substrates with zinc oxide.
  • the present invention provides higher anti-bacterial efficacy as compared to prior art method of treating fabric with zinc oxide.
  • a fabric treatment composition comprising: (i) 20 to 90 % water soluble zinc compound;
  • the water soluble zinc compound is preferably present in 30- 80%, more preferably in 55 to 70% by weight of the fabric treatment composition.
  • the deposition aid is present in 5-40% more preferably 10 - 25% by weight of the fabric treatment composition.
  • the soap is preferably present in 5 - 40%, more preferably 15- 25% by weight of the fabric treatment composition.
  • the composition preferably comprises an alkaline compound selected from alkali metal carbonate or hydroxide in the aqueous solution.
  • the alkaline compound is preferably present in 5 to 30 % by weight of the fabric treatment composition.
  • a composition of the invention for treating a fabric to make it hydrophobic to the extent of having a contact angle higher than 90° with water.
  • the contact angle is preferably between 90 and 180° more preferably between 120° and 180°.
  • the contact angle is measured using a tensile drop method immediately after droplet addition.
  • composition of the present invention is preferably in the solid form. Suitable solid forms are powders or granules. Description of the figure
  • Figure 1 shows comparative data from example 18 (example according to the invention, indicated as E-18) and example 19 (comparative example, indicated as E-19).
  • the graph of Figure 1 shows the effect of cleaning (by means of reflectance of light at 460 nm, called R460 values) during 5 soil-wash cycles.
  • AW indicates the value after wash and BW indicates the value before wash; and 1 , 2, 3, 4, and 5 refer to the 1 st , 2 nd , 3 rd , 4 th and 5 th wash cycle respectively.
  • Fabrics were treated by any one of the treatments A, B or C as described below:
  • Treatment A (as per invention) To 1 litre of deionised water 1 g of sodium laurate, 0.8 g of sodium carbonate was added and dissolved completely. To this 1.1 g of triethanolamine was added and finally 2.97 g of Zn(NO 3 ) 2 .6H 2 O were added.
  • Treatment B (as per methods suggested in the past)
  • Treatment D (Treatment as per invention)
  • Treatment E (Treatment as per invention)
  • Treatment F (Treatment as per invention)
  • the fabrics were hung in a Diesel Soil Box chamber using a hanger. It was soiled by applying a load of 4500W for 3 hours.
  • the diesel exhaust fumes mainly comprise of carbon soot particulates along with a small amount of unburnt mineral oil suspended in air and carbon dioxide.
  • Typical wash protocol involved soaking 20 g of fabrics in 1 litre of deionised water containing 3 g of Surf Excel (ex. Malawistan Unilever Limited) for 15 minutes. They were washed in a Tergotometer at 90 rpm for 30 minutes at ambient temperature. After washing, the fabrics were rinsed three times, each with 450 ml of water for 2 minutes in Tergotometer at 90 rpm and dried in air.
  • Table - 1 indicates that the fabrics treated as per the method of the invention (Examples 1 and 4) tended to pick up less soil as compared to fabrics treated as per methods suggested in the past and as compared to untreated fabrics.
  • the data in Table - 2 indicates that the fabrics treated as per the method of the invention (Examples 7, 10-12, 14, 16) generally tended to pick up less soil as compared to fabrics treated as per methods suggested in the past and as compared to untreated fabrics for the same type of fabric and same soiling protocol. Further the fabrics treated as per the method of the invention, after soiling also tended to be cleaner when washed using a standard washing protocol as compared to untreated fabrics or fabrics treated as per methods suggested in the past.
  • Examples 18 and 19 Effect of the method of the invention on the cleaning of fabrics after several treatment -soiling-washing cycles.
  • Fabrics were taken through several cycles, each cycle consisting of (i) treatment as per Treatment method A or Treatment C (ii) soiling of fabrics using Diesel soil box soiling protocol followed by (iii) the washing protocol.
  • Example 18 was an experiment using cotton fabric which was treated as per Treatment A while Example 19 was an experiment using cotton fabric which was treated as per Treatment C.
  • the data on the reflectance during the course of 5 cycles is given in Figure 1.
  • the data in Figure 1 indicates that fabrics treated as per the invention (Example - 18) gives improved cleaning over several wash cycles.
  • Examples 20 to 23 Antibacterial efficacy The antibacterial efficacy of substrates treated as per the invention was compared to antibacterial efficacy of substrates treated with a method of the prior art i.e. treatment with equivalent amount of zinc oxide.
  • a known antimicrobial assay was modified to enable study on treated fabrics.
  • the known method is as follows:
  • Resazurin a blue colored dye, undergoes reduction in the presence of viable bacteria to form a fluorescent pink colored dye resorufin which emits florescence at 590 nm.
  • Measurement of resorufin either by spectrophotometry or fluorimetry after several hours of incubation indicates the activity of bacteria and hence antimicrobial activity of the compound used for the treatment.
  • the modified antibacterial assay was as follows:
  • Staphylococcus spp. bacteria (which is a fatty acid metabolising bacteria) was subcultured on CY agar plates at 37 0 C. The metabolically active cells were collected which gave an optical density of 0.2 at 610 nm. This was further diluted (1 :10) in BHI Brain Heart Infusion) broth - Bacto 237500 media. The bacterial number at this concentration was determined to be 10 7 cells/ml.
  • Four 1 cm x 1 cm fabric swatches (treated and untreated) were aseptically introduced into 24 well plate. About 1 ml of the culture (diluted in BHI) and 0.5 ⁇ l of 1 % resazurin was added in each well. The plates were incubated at 37 0 C. The wells were inspected for change in colour over 5 hrs. Colour was measured using a fluohmeter. The fluro scan was taken at 530EX/620EM. The data is presented in Table - 3. Table - 3
  • Table - 4 indicates that the fabrics treated as per the method of the invention (Examples 24, 26, 28) generally tended to pick up less soil as compared to untreated fabrics when treatment is carried out in hard water . Further the fabrics treated as per the method of the invention, after soiling also tended to be cleaner when washed in hard water as compared to untreated fabrics washed using the same protocol.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

L’invention concerne un procédé de traitement d’un tissu. Elle concerne plus particulièrement un procédé de traitement d’un tissu avec un produit de rinçage qui réduit l’accumulation de salissures et assure en outre que le tissu est plus propre après le lavage ultérieur. Ainsi, un objet de la présente invention concerne un procédé de traitement d’un tissu pour rendre les tissus relativement plus hydrophobes, et plus particulièrement un procédé de traitement d’un tissu pendant le stade de rinçage du procédé de nettoyage du tissu qui réduit le salissement ultérieur du tissu pendant son utilisation par le consommateur.  Il a été découvert que la mise en contact du tissu avec une solution aqueuse neutre, comprenant un composé de zinc soluble dans l’eau, un adjuvant de dépôt choisi parmi le groupe constitué d’un composé d’amine ou d’un acide aminé, et d’un savon avant le séchage dudit tissu, procure une répulsion des salissures au tissu.
EP09749046A 2008-11-20 2009-10-26 Procédé et composition pour le traitement de matériaux textiles Withdrawn EP2352875A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN2442MU2008 2008-11-20
PCT/EP2009/064035 WO2010057743A2 (fr) 2008-11-20 2009-10-26 Procédé de traitement d'un tissu

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EP2352875A2 true EP2352875A2 (fr) 2011-08-10

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CN (1) CN102224291A (fr)
AR (1) AR073421A1 (fr)
BR (1) BRPI0914362A2 (fr)
EA (1) EA201100801A1 (fr)
MX (1) MX2011005401A (fr)
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GB0916485D0 (en) * 2009-09-18 2009-10-28 Hammond Peter Improved materials
BR112012026467A2 (pt) 2010-04-30 2016-08-09 Unilever Nv composição líquida, processo para preparar um substrato hidrofílico de repelência à mancha, utilização de uma composição e dispensador pulverizador
CN106085640A (zh) * 2016-06-02 2016-11-09 湖州市菱湖重兆金辉丝织厂 一种羽绒服环保清洗剂
CN109487533A (zh) * 2018-09-19 2019-03-19 西南大学 一种基于棉织物的油水分离筛的制备方法

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US2243544A (en) * 1939-04-12 1941-05-27 Us Rubber Co Composition of matter
NL239324A (fr) * 1958-06-02
DE10043118A1 (de) * 2000-08-31 2002-03-28 Henkel Kgaa Waschmittel mit desodorierender Wirkung
US20040033916A1 (en) * 2002-06-28 2004-02-19 Kuzmin Vladimir Semenovich Disinfecting composition

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ZA201102814B (en) 2012-06-27
EA201100801A1 (ru) 2012-01-30
BRPI0914362A2 (pt) 2015-10-20
AR073421A1 (es) 2010-11-03
CN102224291A (zh) 2011-10-19
MX2011005401A (es) 2011-06-16
WO2010057743A3 (fr) 2010-10-21

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