EP2334403A1 - Heissgasreinigung - Google Patents

Heissgasreinigung

Info

Publication number
EP2334403A1
EP2334403A1 EP09778421A EP09778421A EP2334403A1 EP 2334403 A1 EP2334403 A1 EP 2334403A1 EP 09778421 A EP09778421 A EP 09778421A EP 09778421 A EP09778421 A EP 09778421A EP 2334403 A1 EP2334403 A1 EP 2334403A1
Authority
EP
European Patent Office
Prior art keywords
gas
desulfurization
stream
hot
plant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09778421A
Other languages
German (de)
English (en)
French (fr)
Inventor
Ralf Abraham
Michael Rieger
Domenico Pavone
Olaf Von Morstein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
Uhde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uhde GmbH filed Critical Uhde GmbH
Publication of EP2334403A1 publication Critical patent/EP2334403A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75—Multi-step processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/024—Dust removal by filtration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/602—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/204—Inorganic halogen compounds
    • B01D2257/2045—Hydrochloric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1621—Compression of synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C10J2300/1823—Recycle loops, e.g. gas, solids, heating medium, water for synthesis gas

Definitions

  • the invention is directed to a method and a plant for the treatment of a hot gas generated by an entrained flow gasification plant.
  • the object of the invention is to carry out a separation of the sulfur- and carbon-containing compounds so that the further use of hot gas is made available.
  • this object is achieved according to the invention in that the hot raw gas, hotter than 600 0 C, a desulfurization and HCl removal is supplied, wherein subsequently taken a partial stream to form a quench gas cooling stream and after Cooling, fine dedusting, drying and compression of the hot raw gas stream is fed back behind the entrained flow gasifier.
  • Recirculated raw gas for cooling comes from the quench gas process, where it is cooled down and freed from dust.
  • a partial stream of the raw gas is cooled with water in a water quench and partially freed of HCl.
  • the cooled, HCl-poorer crude gas is even further to dust off fine.
  • a Venturi scrubber is used for fine dedusting.
  • the cooled and dust-depleted raw gas still contains water.
  • the water present in the raw gas must still be condensed out.
  • the raw gas is cooled by means of heat exchanger surfaces and the condensing water is separated off via separators.
  • the crude gas is still to compress using gas compressor to gasification pressure.
  • sorbent can still be introduced into the crude gas stream. Cooled, compressed crude gas can now be used for cooling the crude gas stream from the reaction zone of the gasification process. Furthermore, it is advantageous to use the obtained Quenchgasstrom after further compression for the combined cleaning of filter elements for the retention of dust and sulfur compounds.
  • An advantage of the method according to the invention is that excessive cooling of this gas is avoided, with the recirculation of a partial flow is an optimal control of the procedure of the invention possible.
  • sorbents may, for example, be calcium oxide or limestone, but also calcium carbonate, calcium hydroxide or iron ore.
  • a further embodiment of the invention consists in that the sorbents (additives) are added to the recirculated quench gas stream and / or the entrained flow gasifier and / or the fuel and / or before dedusting and / or after dedusting. The addition of such sorbents or the place of addition generally depends on the type of system used and / or the additive used.
  • branched Quenchgasstrom is passed before supplying the generated hot raw gas via a water quench, a Venturi scrubber, a crude gas cooling, a H 2 O separation and a crude gas compression, which may also be provided that a part of recirculated Quenchgasstro- mes is supplied via a further crude gas compression as Abthesesgas a candle filter.
  • a further embodiment of the invention advantageously also consists in the fact that the generated hot crude gas stream is cleaned via a cyclone and / or a candle filter, wherein the cyclone and / or a candle filter is positioned in front of or behind the desulfurization.
  • the invention also provides a system for carrying out the method according to one of the preceding claims, which is characterized in that the carburetor in the flow path of the hot gas desulfurization is followed in series, which is followed by a solids separation, wherein behind the solids separation, a partial flow of the gas via a water quench, a Venturi scrubber, a crude gas cooler and a H 2 O separation and a is closer downstream, the flow path is fed back behind the gasification before the desulfurization cooled in the circuit.
  • a somewhat modified system design according to the invention consists in that in series the carburetor in the flow path of the hot gas is followed by a solids separation, which follows the desulfurization and a further solids deposition, behind the solids separation a partial flow of the gas via a water quench, a Venturi scrubber, downstream of a raw gas cooler and an H 2 O separation and a compressor whose flow is returned behind the cooled gasification prior to desulfurization in the circulation.
  • a further advantageous embodiment is that the cooled partial gas flow upstream of the supply line to the main gas flow, a further partial flow is removed with a gas compressor, which cleans a designed as a candle filter solids in the main gas stream.
  • carburetor in addition to fuel and oxygen is also associated with an additive supply and / or the return line of the cooled partial gas flow is associated with an additive supply.
  • An additive supply may also be provided between the cyclone and the desulfurization in the modified plant design.
  • FIG. 1 is a block diagram of a system for carrying out the method according to the invention and in
  • Fig. 2 is a modified block diagram.
  • the system according to the invention has a carburetor 2, wherein the carburetor 2, which is indicated only symbolically in the figures, the fuel 3, oxygen 4 and optionally an additive 5 is supplied. Slag 6 emerges from the gasifier, which is represented by a dashed arrow.
  • the gas leaving the gasifier with a temperature of 1200 to 1600 0 C is cooled with the Quenchgasström 19 to about 800 0 C and fed to the desulfurization, this in turn acted in the course of the gas guide designated 8 cyclone and a candle filter 9, the dust or the discharge of spent additive is shown dashed lines in these parts of the system and designated 10 and 11.
  • a line 13 is indicated, via which a portion of the hot gas is a water quench 14, from there a Venturi scrubber 15, finally a crude gas cooling 16, followed by a H 2 O separation 17, a crude gas compression 18 is supplied, wherein the so compressed and cooled partial gas stream is supplied via a line 19 to the Hauptgas- ström between carburetor 2 and desulfurization 7 for controlling the temperature.
  • Fig. 1 also indicated that a Additive can be attached to this last point of the line 19, which is indicated by a dotted arrow 20.
  • the difference is essentially that the carburetor 2 is first followed by a solids separator formed as a cyclone 8, which is then followed by the desulfurization 7, wherein all other contact elements in FIG. 2 have the same reference numerals as in FIG of Fig. 1 wear.
  • the one possibility of adding additives is shown in FIG. 2 with the dotted arrow 21, the supply being made here between the cyclone 8 and the desulphurisation device 7.
  • Both circuits have in common that in turn a partial flow of the recirculated cooled gas can be supplied via a line 22 to a crude gas compressor 23, which provides a cleaning gas for approximately the candle filter 9, which is represented by the dashed line 22a.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Industrial Gases (AREA)
  • Gas Separation By Absorption (AREA)
EP09778421A 2008-09-30 2009-09-09 Heissgasreinigung Withdrawn EP2334403A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008049579A DE102008049579A1 (de) 2008-09-30 2008-09-30 Heißgasreinigung
PCT/EP2009/006532 WO2010037465A1 (de) 2008-09-30 2009-09-09 Heissgasreinigung

Publications (1)

Publication Number Publication Date
EP2334403A1 true EP2334403A1 (de) 2011-06-22

Family

ID=41402043

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09778421A Withdrawn EP2334403A1 (de) 2008-09-30 2009-09-09 Heissgasreinigung

Country Status (13)

Country Link
US (1) US8512444B2 (ko)
EP (1) EP2334403A1 (ko)
KR (1) KR101652132B1 (ko)
CN (1) CN102164649B (ko)
AU (1) AU2009300131B9 (ko)
BR (1) BRPI0919311A2 (ko)
CA (1) CA2737365A1 (ko)
DE (1) DE102008049579A1 (ko)
RU (1) RU2496555C2 (ko)
TW (1) TWI456044B (ko)
UA (1) UA101683C2 (ko)
WO (1) WO2010037465A1 (ko)
ZA (1) ZA201103103B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008046820A1 (de) * 2008-09-11 2010-03-25 Uhde Gmbh Anlage zur Synthesegasherstellung
DE102009058656A1 (de) 2009-12-16 2011-06-22 Uhde GmbH, 44141 Verfahren und Anlage zur Abscheidung von sauren Komponenten, Staub und Teer aus heißen Gasen von Vergasungsanlagen
US9050551B2 (en) 2011-10-28 2015-06-09 American Air Liquide, Inc. Supersonic venturi scrubber
US9868999B2 (en) 2014-07-15 2018-01-16 Midrex Technologies, Inc. Methods and systems for producing direct reduced iron utilizing a petroleum refinery bottoms or petroleum coke gasifier and a hot gas cleaner
NL2016229B1 (en) 2016-02-05 2017-08-21 Black Bear Carbon B V Method for treatment of a hot pyrolysis gas
DE102017219776A1 (de) * 2017-11-07 2019-05-09 Thyssenkrupp Ag HTW-Vergaseranordnung und Verfahren jeweils zum Aufbereiten von Rohgasen beim Vergasen von Einsatzstoffen sowie Verwendung

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Publication number Priority date Publication date Assignee Title
US4180549A (en) * 1976-08-27 1979-12-25 United States Steel Corporation Desulfurization of hot reducing gas
DE3531918A1 (de) * 1985-09-07 1987-03-19 Krupp Koppers Gmbh Verfahren zur enthalogenierung von partialoxidationsgas
SE457355B (sv) * 1985-09-25 1988-12-19 Skf Steel Eng Ab Saett att framstaella en ren, koloxid och vaetgas innehaallande gas
DE3537493A1 (de) * 1985-10-22 1987-04-23 Uhde Gmbh Verfahren zur aufbereitung von quenchwasser
RU2015158C1 (ru) * 1987-10-02 1994-06-30 Студевик АБ Способ очистки загрязненного горючего газа
SE459584B (sv) * 1987-10-02 1989-07-17 Studsvik Ab Foerfarande foer foeraedling av raagas framstaelld ur ett kolhaltigt material
US4880439A (en) * 1988-05-05 1989-11-14 Texaco Inc. High temperature desulfurization of synthesis gas
US4959080A (en) * 1989-06-29 1990-09-25 Shell Oil Company Process for gasification of coal utilizing reactor protected interally with slag coalescing materials
DE4238934C2 (de) 1992-11-19 1996-07-25 Noell En Und Entsorgungstechni Verfahren zur Vergasung organischer oder organische Materialien enthaltender Roh- und Abfallstoffe
DE4310447A1 (de) * 1993-03-31 1994-10-06 Krupp Koppers Gmbh Verfahren zur Kühlung von durch Vergasung gewonnenem Rohgas
DE4317319B4 (de) 1993-05-25 2005-10-20 Schwarze Pumpe Energiewerke Ag Verfahren der flexiblen und integrierten Reststoffvergasung
FI93701C (fi) * 1993-06-11 1995-05-26 Ahlstroem Oy Menetelmä ja laite kuumien kaasujen käsittelemiseksi
US5403366A (en) * 1993-06-17 1995-04-04 Texaco Inc. Partial oxidation process for producing a stream of hot purified gas
US7618558B2 (en) * 2005-04-15 2009-11-17 Haldor Topsoe A/S Process for cleaning gases from gasification units

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
None *
See also references of WO2010037465A1 *

Also Published As

Publication number Publication date
KR101652132B1 (ko) 2016-08-29
UA101683C2 (ru) 2013-04-25
US20110173886A1 (en) 2011-07-21
KR20110081186A (ko) 2011-07-13
US8512444B2 (en) 2013-08-20
ZA201103103B (en) 2012-01-25
RU2011116929A (ru) 2012-11-20
CN102164649A (zh) 2011-08-24
TW201014904A (en) 2010-04-16
DE102008049579A1 (de) 2010-04-01
AU2009300131B9 (en) 2014-08-21
CA2737365A1 (en) 2010-04-08
AU2009300131B2 (en) 2014-07-17
WO2010037465A1 (de) 2010-04-08
CN102164649B (zh) 2014-02-26
BRPI0919311A2 (pt) 2015-12-22
TWI456044B (zh) 2014-10-11
AU2009300131A1 (en) 2010-04-08
RU2496555C2 (ru) 2013-10-27

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