EP2300770B1 - Heat exchanger and method of production - Google Patents

Heat exchanger and method of production Download PDF

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Publication number
EP2300770B1
EP2300770B1 EP08875072A EP08875072A EP2300770B1 EP 2300770 B1 EP2300770 B1 EP 2300770B1 EP 08875072 A EP08875072 A EP 08875072A EP 08875072 A EP08875072 A EP 08875072A EP 2300770 B1 EP2300770 B1 EP 2300770B1
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EP
European Patent Office
Prior art keywords
heat exchanger
silicone adhesive
mounting plate
exchanger according
openings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP08875072A
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German (de)
French (fr)
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EP2300770A1 (en
Inventor
Denis Bazika
Rainer Käsinger
Fritz Keller
Wolfgang Knecht
Jens Köppen
Jens Nies
Jürgen ORSO
Andreas Stolz
Werner Zobel
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Modine Manufacturing Co
Original Assignee
Modine Manufacturing Co
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Publication date
Priority claimed from DE102008032287A external-priority patent/DE102008032287B4/en
Application filed by Modine Manufacturing Co filed Critical Modine Manufacturing Co
Publication of EP2300770A1 publication Critical patent/EP2300770A1/en
Application granted granted Critical
Publication of EP2300770B1 publication Critical patent/EP2300770B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/04Arrangements for sealing elements into header boxes or end plates
    • F28F9/16Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling
    • F28F9/162Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling by using bonding or sealing substances, e.g. adhesives
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2275/00Fastening; Joining
    • F28F2275/02Fastening; Joining by using bonding materials; by embedding elements in particular materials
    • F28F2275/025Fastening; Joining by using bonding materials; by embedding elements in particular materials by using adhesives

Definitions

  • the invention relates to a heat exchanger with a collecting box made of plastic or metal, with metallic flat tube ends, which are part of a brazed heat exchanger network and with an adhesive bond, for the metallic flat tube ends in corresponding openings of the collecting tank, each with an annular space around the pipe ends, in which a silicone adhesive is located. Furthermore, the invention relates to a production method for the heat exchanger itself.
  • a heat exchanger with adhesive bond and a manufacturing process are from the previously unpublished German patent application with the file number DE 10 2008 021 544.9 known internally.
  • a silicone-based adhesive is used to make a heat exchanger for automobiles. It is an initially liquid mass, which is poured out there on the inside of a tube plate and then cured. An annular space around the pipe ends is not there. The pipe ends have been deformed, in particular widened, which causes manufacturing expense. Here, a large amount of the adhesive is needed, which also increases the cost of production.
  • the heat exchanger off FR 2 794 227 also has an adhesive connection.
  • the adhesive comes into contact there with the medium flowing through the heat exchanger.
  • EP 159 729A For example, a curable plastic composition is known which contains silicone and has a very short cure time.
  • the plastic composition is suitable for covering optical glass fibers.
  • Radiators for motor vehicles should at least guarantee a shelf life of about 10 years and be able to cope with all imaginable operating situations.
  • Silicone adhesives are either of the so-called condensation-curing type (A) or of addition-curing type (B).
  • the silicone adhesives of the condensation-curing type (A) excrete certain substances, for example acids or alcohols, when they cure, while those of the addition-crosslinking type (B) in the course of their curing lead to the formation of molecular chains without precipitating substances.
  • the type B adhesives may comprise a catalyst, for example platinum or palladium.
  • Such catalysts are usually in one of, for example, two components which must be mixed to prepare the ready-to-use adhesive.
  • the catalysts cause, for example, a shortening of the curing time, and they can also help reduce the required temperature.
  • the object of the invention is to propose or make available a heat exchanger with a permanently adhesive bond and a manufacturing method for it.
  • the elastic modulus or storage modulus of the silicone adhesive is relatively low in order to minimize the forces of changes in length induced by temperature changes and the vibrations in the adhesive bond. It is approximately between 0.1 - 3.0 MPa.
  • the mounting plate is adhesively attached with its top on the collecting box. It can lie with its underside on the fins of the heat exchanger network.
  • annular spaces are filled to about 60-95% with the silicone adhesive, wherein the filled with the silicone adhesive height of the annular spaces about 5 - 15 mm and the width of the annular spaces about 0.5 - 3.0 mm ,
  • an initially approximately rectangular cross-sectional area of the adhesive in the annular space under the mentioned thermal cycling loads in the direction of a parallelogram cross-sectional area - and back to the rectangular shape - move, which is ensured by the elastic properties of the selected adhesive together with the proposed design.
  • a two-component silicone adhesive is used. But it can also be a silicone adhesive with a single component.
  • the tensile strength of the silicone adhesive used is about 3.0 to 7.0 MPa, preferably about 4.0 to 6.0 MPa.
  • the elongation of the silicone adhesive used is greater than 100%, for example, it is 150%.
  • silicone adhesive used has a catalyst from the group of platinum metals or their compounds.
  • the dynamic viscosity of the uncured silicone adhesive is about 20,000 - 60,000 cP. With these values, for example, the adhesive can be applied to the mounting plate like a worm without flowing apart.
  • the annular spaces can have approximately the same width over the filled with the silicone adhesive height.
  • the specified width dimensions refer to conical annular spaces on the median, that is, the specified width dimensions can be slightly exceeded in conical annular spaces.
  • the not filled with the silicone adhesive part of the annular spaces should be arranged pointing to the collection box.
  • the inventive method for producing a heat exchanger with an adhesive connection for metallic flat tube ends in corresponding openings of headers of the heat exchanger, in which a silicone adhesive is introduced into an annular space between the flat tube ends and the openings, is characterized in that the annular spaces with a memory module in Value range of 0.1 - 3.0 MPa possessing silicone adhesive of the addition-crosslinking type by means of a mounting plate filled and sealed.
  • the mounting plate has openings corresponding to the flat tubes in order to be able to push the same onto the flat tube ends, so that, for example, it lies with the underside on cooling-air-side ribs.
  • the opening edges of the mounting plate are close to the flat tube ends to avoid the escape of the adhesive as possible.
  • the silicone adhesive is preferably applied to the top of the mounting plate and through the subsequent merger of mounting plate with the collecting box, whereby the flat tube ends are pushed into the openings of the collecting tank, pressed into the annular spaces.
  • the flat tube ends are pretreated as needed, at least cleaned with a suitable means to z. B. to remove solder flux, which have been found to be detrimental to a quality adhesive bond.
  • the flat tube ends are part of a heat exchanger network of flat tubes and cooling air-side ribs connected by means of CAB brazing processes, both of aluminum or of aluminum alloys.
  • This method of soldering normally uses a non-corrosive flux, although intensive work is being done to completely eliminate flux. In any case, surface treatments may be required and performed on both the flat tube ends and the aperture walls.
  • the mounting plate has openings corresponding to the flat tubes in order to be able to push the same onto the flat tube ends, so that, for example, it lies with the underside on cooling-air-side ribs.
  • the opening edges of the mounting plate are yieldingly close to the flat tube ends in order to be able to compensate for differences between the distances between the openings in the mounting plate and the spacings of the flat tube ends.
  • the distances between the openings can be changed or adapted by means of an elastic or resilient design of the mounting plate. This also ensures that neither the flat tube ends nor the mounting plate are damaged and that no adhesive loss occurs due to too large gaps between the flat tube ends and the opening edges of the mounting plate.
  • Fig. 4 shows that the upper part 60 of the annular space 6 is not filled with the silicone adhesive SK . It has been found that the elasticity and the durability of the adhesive bond is to be further increased if the degree of filling of the annular spaces 6 with silicone adhesive SK is about 60-95% of the total volume of the annular spaces 6 .
  • the silicone adhesive SK used is of the addition-curing type, ie it does not precipitate any substances when it is cured.
  • the storage modulus of the silicone adhesive SK in the exemplary embodiment is about 1.8 MPa, selected from a range between 0.5 and 3.0 MPa. This relatively low value contributes significantly to the durability of the adhesive bond, wherein the adhesive compound has excellent elastic properties and retains over a long period of time.
  • the procedure was as follows: Flat tubes 20 , as in Fig. 5 are alternately assembled with fins 30 to the heat exchanger network 3 .
  • the heat exchanger network 3 becomes CAB soldering prepared accordingly, the soldering process is carried out.
  • the free flat tube ends 2 are optionally freed of residues of the flux or other interfering residues or their surface is treated.
  • a mounting plate 10 a thin film of about 1.0 mm thickness or less, as in FIGS Fig. 2 and 3, is pushed with its openings 12 on the flat tube ends 2 , wherein the opening edges lie quite close to the flat tube walls.
  • the mounting plate 10 can sit with its bottom finally on the ribs 30 without being attached thereto. In the Fig. 4 In contrast, a small distance between the bottom of the mounting plate 10 and the ribs 30 can be seen. Subsequently, a metered amount of silicone adhesive SK , as in Fig. 6 shown, serpentine on the inside of the mounting plate 10 applied.
  • the collection box 5 is pushed with its openings 4 on the free flat tube ends. 2
  • the collecting box 5 comes together with the shell-like mounting plate 10 , that is, the wave-like edge 11 of the mounting plate 10 engages in a correspondingly shaped, circumferential groove 50 in the collecting box 5 a.
  • the top of the mounting plate 10 glued to the bottom of the manifold 5 .
  • the collecting box 5 is integrally formed.
  • An embodiment not shown has a tube sheet of metal or plastic, in which the openings 4 are located, which is later connected to a box part along the peripheral edges to form the collecting box 5 .
  • the flat tube ends 2 practically do not protrude into the interior of the collecting tank 5 , even if the Fig. 4 could give a different impression.
  • the collecting box 5 in its opening or bottom area, the collecting box 5 has a roughly semicircular contour, viewed in cross-section, in order to improve its pressure stability Fig. 4 could appear as if the flat tube ends 2 were clearly inwardly over, which is true only for the lying on the central longitudinal line lot of flat tube ends 2 . The internal pressure loss has therefore been reduced.
  • the total cross section of the collecting tank 5 is round to oval, which is the Fig. 7 should show.
  • the mounting plate 10 , one of the flat tubes 20 and a part of an annular space 6 were indicated there only in stylizing manner.
  • the tensile strength of the silicone adhesive SK in the embodiment is about 5.3 MPa selected from an advantageous range of 3.0 to 7.0 MPa.
  • the viscosity of the silicone adhesive SK is about 35,000 cP, selected from a range between 20,000 and 60,000 cP. With this value, the silicone adhesive SK can be applied without flowing apart.
  • a curing process is carried out, which is carried out in a drying oven, not shown, or on a drying line.
  • the heat exchangers are maintained at a temperature of about 120 ° C for about 30 minutes, selected from a temperature range of 80-180 ° C and a time between 1-60 minutes.
  • the silicone adhesive SK was mixed with a catalyst from the group of platinum metals in order to shorten the curing time.
  • the thickness of the wall parts a , b ( Fig. 5 ) of the flat tubes 20 is extremely low, namely in a range of 0.03 mm - 0.15 mm, because the ribs 30 are only about 0.03 mm - 0.09 mm thick and because, moreover, preferably no metallic tube sheet used
  • a much lighter heat exchanger will be provided. Its performance characteristics are also significantly higher than for ordinary heat exchangers, partly because of the inner inserts c in the flat tubes 20 . Moreover, such heat exchangers require considerably less energy, for example for the soldering process. In the provision Such a heat exchanger makes the proposed invention a significant contribution.
  • Flat tubes 20 are alternately assembled with ribs 30 to the heat exchanger network 3 .
  • the heat exchanger network 3 is prepared according to the CAB-soldering, the soldering process is carried out.
  • the free flat tube ends 2 are optionally freed of residues of the flux or other interfering residues or their surface is treated.
  • a mounting plate 10 a thin film of about 1.0 mm thickness or less is pushed with its openings 12 on the flat tube ends 2 , wherein the resilient opening edges 13 create on the narrow and broad sides of the flat tubes 20 .
  • the opening edges 13 may be formed with cuts 14 and / or tapering 15 , as in the Fig. 8 - 10 is shown.
  • a second embodiment of the opening edges 13 is in Fig. 12 shown, wherein the compliance is represented by a locally reduced material thickness in the form of a paragraph 16 .
  • the locally reduced material thickness is realized by means of grooves 17 or beads, as in Fig. 13 is shown, wherein the shape of the grooves or beads need not be limited to a circular arc-shaped depression in cross-section.
  • Further embodiments show in the Fig. 14 and 15 the resilient configuration of the distances of the openings 12 in the mounting plate 10 by reducing the material thickness in the edge regions between the openings 12 and the wave-like edges 11 of the mounting plate 10 , ( Fig. 14 ), or between the openings 12 across the mounting plate 10 , (FIG. Fig. 15 ).
  • the mounting plate 10 can sit with its bottom finally on the ribs 30 without being attached thereto. In the Fig. 4 In contrast, a small distance between the bottom of the mounting plate 10 and the ribs 30 can be seen. Subsequently, a metered amount of the silicone adhesive SK , a serpentine on the inside of the mounting plate 10 is applied (not shown). Thereafter, the collection box 5 is pushed with its holes 4 on the free flat tube ends. 2 In this case, the collecting box 5 comes together with the shell-like mounting plate 10 , that is, the wave-like edge 11 of the mounting plate 10 engages in a correspondingly shaped, circumferential groove 50 in the collecting box 5 a. The top of the mounting plate 10 glued to the bottom of the manifold 5 .
  • the silicone adhesive SK is pressed into the annular spaces 6 .
  • the edge 11 in the circumferential groove 50 prevents the merging of the collecting box 5 with the mounting plate 10 of the silicone adhesive SK can escape laterally. He is rather forced to enter the annular spaces 6 .
  • FIG. 18 a cooling liquid cooler (heat exchanger) of a truck is shown, the heat exchanger network is traversed by cooling air.
  • Thisdestattkeitkühler has the proposed adhesive bond to the flat tube ends 2 and was prepared according to the described method.
  • the FIGS. 16 and 17 show the production process of thedethekeitskühlers, starting from an already brazed heat exchanger network 3 , consisting of flat tubes 20 and not shown there ribs 30th First, the mounting plate 10 is pushed onto the flat tube ends. The silicon adhesive SK of the addition-curing type is applied and the flat tube ends 2 are inserted into the Openings of the collecting tank 5 is pushed, wherein the mounting plate 10 is brought together with the collecting box 5 and the silicone adhesive is pressed into the annular spaces.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Description

Die Erfindung betrifft einen Wärmetauscher mit einem Sammelkasten aus Kunststoff oder Metall, mit metallischen Flachrohrenden, die Teil eines gelöteten Wärmetauschernetzes sind und mit einer Klebeverbindung, für die metallischen Flachrohrenden in korrespondierende Öffnungen des Sammelkastens, mit je einem Ringraum um die Rohrenden herum, in denen sich ein Silikonkleber befindet. Ferner betrifft die Erfindung ein Herstellungsverfahren für den Wärmetauscher selbst.The invention relates to a heat exchanger with a collecting box made of plastic or metal, with metallic flat tube ends, which are part of a brazed heat exchanger network and with an adhesive bond, for the metallic flat tube ends in corresponding openings of the collecting tank, each with an annular space around the pipe ends, in which a silicone adhesive is located. Furthermore, the invention relates to a production method for the heat exchanger itself.

Ein Wärmetauscher mit Klebeverbindung und ein Herstellungsverfahren sind aus der bisher unveröffentlichten deutschen Patentanmeldung mit dem Aktenzeichen DE 10 2008 021 544.9 intern bekannt.A heat exchanger with adhesive bond and a manufacturing process are from the previously unpublished German patent application with the file number DE 10 2008 021 544.9 known internally.

In der WO 2006/010435A1 wird ebenfalls ein Kleber auf Silikonbasis eingesetzt, um einen Wärmeübertrager für Kraftfahrzeuge herzustellen. Es handelt sich um eine zunächst flüssige Masse, die dort auf der Innenseite eines Rohrbodens ausgegossen wird und danach aushärtet. Ein Ringraum um die Rohrenden herum ist dort nicht vorhanden. Die Rohrenden sind verformt, insbesondere aufgeweitet worden, was fertigungstechnischen Aufwand verursacht. Hier wird auch eine große Menge des Klebstoffes benötigt, die die Herstellungskosten ebenfalls erhöht.In the WO 2006 / 010435A1 Also, a silicone-based adhesive is used to make a heat exchanger for automobiles. It is an initially liquid mass, which is poured out there on the inside of a tube plate and then cured. An annular space around the pipe ends is not there. The pipe ends have been deformed, in particular widened, which causes manufacturing expense. Here, a large amount of the adhesive is needed, which also increases the cost of production.

In der WO 2007/009588A1 wird ein Automobilkühler vorgestellt, der ebenfalls verformte Rohrenden aufweist und keine Ringräume besitzt. Die Rohrenden wurden dort nicht eingeklebt sondern durch Umbiegen der Rohrenden befestigt. Dieser Automobilkühler besitzt außerdem einen separaten metallischen Rohrboden, was als nachteilig anzusehen ist.In the WO 2007 / 009588A1 An automotive radiator is presented, which also has deformed tube ends and has no annular spaces. The pipe ends were not glued there but fixed by bending the pipe ends. This car radiator also has a separate metallic tubesheet, which is to be regarded as disadvantageous.

In der DE 38 09 944 C2 wird ein Kühler für Verbrennungsmotore in Kraftfahrzeugen vorgestellt, der im Wesentlichen dem Oberbegriff des Anspruchs 1 entspricht. Dort sind demnach Ringräume vorhanden. Der Kleber wird mittels einer Dosiervorrichtung über zu den Ringräumen führende Kanäle in dieselben gebracht. Die Ringräume werden komplett mit dem Kleber ausgefüllt. Der Kleber ist relativ teuer, und es wird ziemlich viel Klebstoff benötigt. In dieser Referenz wird vorgeschlagen, Kleber zu verwenden, die unter dem Markennamen "Loctite" auf dem Markt sind. Obwohl dieser relativ alte Vorschlag auch heute noch fortschrittlich erscheint, sind solche Kühler noch nicht am Markt aufgetaucht. Einer der Gründe dafür dürfte darin bestehen, dass es bisher nicht gelungen ist, die Klebeverbindung dauerhaft haltbar zu gestalten.In the DE 38 09 944 C2 a cooler for internal combustion engines in motor vehicles is presented, which essentially corresponds to the preamble of claim 1. There are therefore annular spaces available. The adhesive is brought into the same by means of a metering device via channels leading to the annular spaces. The annuli are filled completely with the glue. The glue is relatively expensive and quite a lot of glue is needed. In this reference, it is proposed to use adhesives marketed under the trade name "Loctite". Although this relatively old proposal still seems progressive today, such coolers have not yet appeared on the market. One of the reasons for this may be that it has not been possible to make the adhesive bond durable.

Der Wärmetauscher aus FR 2 794 227 besitzt ebenfalls eine Klebeverbindung. Der Kleber kommt dort mit dem durch den Wärmetauscher strömenden Medium in Kontakt.The heat exchanger off FR 2 794 227 also has an adhesive connection. The adhesive comes into contact there with the medium flowing through the heat exchanger.

Aus EP 159 729A ist eine härtbare Kunststoffzusammensetzung bekannt, die Silikon enthält und eine sehr kurze Aushärtezeit besitzt. Die Kunststoffzusammensetzung eignet sich zum Bedecken von optischen Glasfasern.Out EP 159 729A For example, a curable plastic composition is known which contains silicone and has a very short cure time. The plastic composition is suitable for covering optical glass fibers.

Kühler für Kraftfahrzeuge sollten wenigstens eine Haltbarkeit von etwa 10 Jahren garantieren und dabei allen vorstellbaren Betriebssituationen gewachsen sein.Radiators for motor vehicles should at least guarantee a shelf life of about 10 years and be able to cope with all imaginable operating situations.

Die Anmelderin hat in umfangreichen Voruntersuchungen alle in Frage kommenden Kleber getestet und ist zu dem Ergebnis gekommen, dass Silikonkleber den größten Erfolg versprechen. Silikonkleber sind entweder vom so genannten kondensationsvernetzenden Typ (A) oder vom additionsvernetzenden Typ (B). Die Silikonkleber vom kondensationsvernetzenden Typ (A) scheiden bei ihrer Aushärtung bestimmte Stoffe, beispielsweise Säuren oder Alkohole, aus, während diejenigen vom additionsvernetzenden Typ (B) im Zuge ihrer Aushärtung zur Bildung von Molekülketten führen ohne dabei Stoffe auszuscheiden. Die Kleber des Typs B können einen Katalysator, beispielsweise Platin oder Palladium, aufweisen. Solche Katalysatoren befinden sich gewöhnlich in einer von beispielsweise zwei Komponenten, die zur Zubereitung des einsatzbereiten Klebers vermischt werden müssen. Die Katalysatoren bewirken beispielsweise eine Verkürzung der Aushärtezeit, und sie können auch die dafür erforderliche Temperatur reduzieren helfen.The applicant has extensively tested all possible adhesives and came to the conclusion that silicone adhesives promise the greatest success. Silicone adhesives are either of the so-called condensation-curing type (A) or of addition-curing type (B). The silicone adhesives of the condensation-curing type (A) excrete certain substances, for example acids or alcohols, when they cure, while those of the addition-crosslinking type (B) in the course of their curing lead to the formation of molecular chains without precipitating substances. The type B adhesives may comprise a catalyst, for example platinum or palladium. Such catalysts are usually in one of, for example, two components which must be mixed to prepare the ready-to-use adhesive. The catalysts cause, for example, a shortening of the curing time, and they can also help reduce the required temperature.

Die Aufgabe der Erfindung besteht darin, einen Wärmetauscher mit einer dauerhaft haltbaren Klebeverbindung sowie ein Herstellungsverfahren dafür vorzuschlagen bzw. zur Verfügung zu stellen.The object of the invention is to propose or make available a heat exchanger with a permanently adhesive bond and a manufacturing method for it.

Diese Aufgabe wird erfindungsgemäß durch einen Wärmetauscher gelöst, der sämtliche Merkmale des Anspruchs 1 aufweist. Die Merkmale des Herstellungsverfahrens befinden sich im Anspruch 23.This object is achieved by a heat exchanger having all the features of claim 1. The features of the manufacturing method are in claim 23.

Es wurde festgestellt, dass die Dauerfestigkeit der Klebeverbindung dadurch verbessert wird, dass der Silikonkleber vom additionsvernetzenden Typ ist, wobei eine Montageplatte angeordnet ist, die die Ringräume begrenzt. Der elastische Modul bzw. der Speichermodul des Silikonklebers ist relativ niedrig, um die Kräfte der durch Temperaturwechsel induzierten Längenänderungen und die Vibrationen in der Klebeverbindung gering zu halten. Er liegt etwa zwischen 0,1 - 3,0 MPa.It has been found that the fatigue strength of the adhesive bond is improved by virtue of the silicone adhesive being of the addition-crosslinking type, with a mounting plate being provided which delimits the annular spaces. The elastic modulus or storage modulus of the silicone adhesive is relatively low in order to minimize the forces of changes in length induced by temperature changes and the vibrations in the adhesive bond. It is approximately between 0.1 - 3.0 MPa.

Die Montageplatte ist mit ihrer Oberseite am Sammelkasten klebend befestigt. Sie kann mit ihrer Unterseite auf den Rippen des Wärmetauschernetzes liegen.The mounting plate is adhesively attached with its top on the collecting box. It can lie with its underside on the fins of the heat exchanger network.

Weitere Wirkungsverbesserungen ergeben sich dadurch, dass die Ringräume etwa zu 60 - 95% mit dem Silikonkleber ausgefüllt sind, wobei die mit dem Silikonkleber ausgefüllte Höhe der Ringräume etwa 5 - 15 mm und die Breite der Ringräume etwa 0,5 - 3,0 mm beträgt.Further improvements in effectiveness result from the fact that the annular spaces are filled to about 60-95% with the silicone adhesive, wherein the filled with the silicone adhesive height of the annular spaces about 5 - 15 mm and the width of the annular spaces about 0.5 - 3.0 mm ,

Die Ausfüllung der Ringräume mit dem Kleber zu etwa 60 - 95 % ihres Volumens, gemeinsam mit den angegebenen bevorzugten Dimensionen der Ringräume, steigert die Elastizität der Klebeverbindung, was aufgrund zahlreicher Versuchsreihen, die von der Anmelderin ausgeführt wurden, bestätigt wird. Eine nicht unerhebliche Anzahl von Kühlern mit solchermaßen ausgebildeten Klebeverbindungen wird demnächst im Praxiseinsatz getestet, das heißt, eingebaut in im Einsatz befindlichen Kraftfahrzeugen auf öffentlichen Straßen. Bisher haben sämtliche im Testlabor und im internen Praxiseinsatz geprüften Kühler die Erwartungen erfüllt.The filling of the annular spaces with the adhesive to about 60-95% of its volume, together with the specified preferred dimensions of the annular spaces, increases the elasticity of the adhesive bond, which is confirmed by numerous series of experiments carried out by the Applicant. A not inconsiderable number of coolers with adhesive bonds formed in this way will soon be tested in practice, that is, installed in motor vehicles in use on public roads. So far, all the coolers tested in the test laboratory and in the field of internal use have met expectations.

Bezüglich der Dimensionierung der Ringräume wurde gefunden, dass diese auch von der im Einzelfall vorgesehenen Länge der Flachrohre und von der Dimensionierung des Querschnitts der Flachrohre abhängt. Beispielsweise wird man für Flachrohre von Ladeluftkühlern, die etwa 10 mm dick (d, Fig.5) sein können, die Breite und Höhe der Ringräume an den oberen Grenzen liegend auswählen. Für Flachrohre von Kühlflüssigkeitskühler, die lediglich etwa 1,0 - 1,5 mm dick (d) sind, sind eher an der unteren Grenze liegende Breitenabmessungen geeignet. Bei etwas längeren Flachrohren, beispielsweise bis zu oder über 1,0 m, wie sie bei LKW anzutreffen sind, würde man ebenfalls eher einen etwas breiteren und höheren befüllten Ringraum vorsehen, weil dann die durch Temperaturwechsel zu erwartenden Längenänderungen der Flachrohre mittels der Elastizität der Klebeverbindungen besser zu kompensieren sind. Beispielsweise wird sich eine ursprünglich etwa rechteckige Querschnittsfläche des Klebers im Ringraum unter den erwähnten Temperaturwechselbelastungen in Richtung auf eine parallelogrammförmige Querschnittsfläche - und wieder zurück zur Rechteckform - verschieben, was durch die elastischen Eigenschaften des ausgewählten Klebers gemeinsam mit der vorgeschlagenen Gestaltung gewährleistet wird.With regard to the dimensioning of the annular spaces, it has been found that this also depends on the length of the flat tubes provided in the individual case and on the dimensioning of the cross section of the flat tubes. For example, for flat tubes of intercoolers, which are about 10 mm thick (d, Figure 5 ), selecting the width and height of the annuli at the upper limits. For flat tubes of cooling liquid coolers, which are only about 1.0-1.5 mm thick (d), the width dimensions are more likely to be at the lower limit. For slightly longer flat tubes, for example, up to or over 1.0 m, as they are found in trucks, you would also rather provide a slightly wider and higher filled annulus, because then expected by temperature changes length changes of the flat tubes by means of the elasticity of the adhesive joints better to compensate. For example, an initially approximately rectangular cross-sectional area of the adhesive in the annular space under the mentioned thermal cycling loads in the direction of a parallelogram cross-sectional area - and back to the rectangular shape - move, which is ensured by the elastic properties of the selected adhesive together with the proposed design.

Bei bisherigen gelöteten Kühlern kommt es oft zu Ausfällen durch Brüche in den Lötverbindungen Rohr/Rohrboden, weil die erforderliche Elastizität nicht vorhanden ist. Es wird erwartet, dass die Erfindung auch diesbezüglich zu Verbesserungen führt. Vorzugsweise kommt ein aus zwei Komponenten bestehender Silikonkleber zum Einsatz. Es kann sich aber auch um einen Silikonkleber mit einer einzigen Komponente handeln.In previous brazed coolers it often comes to failure due to breaks in the solder joints tube / tube sheet, because the required elasticity is not present. It is expected that the invention will also lead to improvements in this respect. Preferably, a two-component silicone adhesive is used. But it can also be a silicone adhesive with a single component.

Die Zugfestigkeit des verwendeten Silikonklebers liegt etwa zwischen 3,0 - 7,0 MPa, vorzugsweise etwa bei 4,0 - 6,0 MPa.The tensile strength of the silicone adhesive used is about 3.0 to 7.0 MPa, preferably about 4.0 to 6.0 MPa.

Die Dehnung des verwendeten Silikonklebers ist größer als 100%, beispielsweise beträgt sie 150%.The elongation of the silicone adhesive used is greater than 100%, for example, it is 150%.

Es ist von Vorteil, wenn der verwendete Silikonkleber einen Katalysator aus der Gruppe der Platinmetalle bzw. deren Verbindungen aufweist.It is advantageous if the silicone adhesive used has a catalyst from the group of platinum metals or their compounds.

Die dynamische Viskosität des nicht ausgehärteten Silikonklebers beträgt etwa 20 000 - 60 000 cP. Mit diesen Werten lässt sich der Kleber beispielsweise auf der Montageplatte wurmförmig auftragen ohne auseinander zu fließen.The dynamic viscosity of the uncured silicone adhesive is about 20,000 - 60,000 cP. With these values, for example, the adhesive can be applied to the mounting plate like a worm without flowing apart.

Die Ringräume können über die mit dem Silikonkleber ausgefüllte Höhe etwa die gleiche Breite aufweisen.The annular spaces can have approximately the same width over the filled with the silicone adhesive height.

Es ist jedoch auch möglich, die Ringräume leicht konisch zu gestalten, wobei sie über die mit dem Silikonkleber ausgefüllte Höhe ein abnehmendes/ansteigendes Breitenmaß aufweisen. Die angegebenen Breitenabmessungen beziehen sich bei konischen Ringräumen auf das Mittelmaß, das heißt, die angegebenen Breitenmaße können bei konischen Ringräumen auch geringfügig überschritten werden.However, it is also possible to make the annular spaces slightly conical, wherein they have over the filled with the silicone adhesive height a decreasing / increasing width dimension. The specified width dimensions refer to conical annular spaces on the median, that is, the specified width dimensions can be slightly exceeded in conical annular spaces.

Der nicht mit dem Silikonkleber ausgefüllte Teil der Ringräume soll zum Sammelkasten hinweisend angeordnet sein.The not filled with the silicone adhesive part of the annular spaces should be arranged pointing to the collection box.

Das erfindungsgemäße Verfahren zur Herstellung eines Wärmetauschers mit einer Klebeverbindung für metallische Flachrohrenden in korrespondierende Öffnungen von Sammelkästen des Wärmetauschers, bei dem ein Silikonkleber in je einen Ringraum zwischen den Flachrohrenden und den Öffnungen eingebracht wird, ist dadurch gekennzeichnet, dass die Ringräume mit einem einen Speichermodul im Wertebereich von 0,1 - 3,0 MPa besitzenden Silikonkleber vom additionsvernetzenden Typ mittels einer Montageplatte befüllt und verschlossen werden. Die Montageplatte besitzt mit den Flachrohren korrespondierende Öffnungen, um dieselbe auf die Flachrohrenden stecken zu können, sodass sie beispielsweise mit der Unterseite auf kühlluftseitigen Rippen liegt. Die Öffnungsränder der Montageplatte liegen eng an den Flachrohrenden an, um das Entweichen des Klebers möglichst zu vermeiden. Der Silikonkleber wird vorzugsweise auf die Oberseite der Montageplatte aufgetragen und durch die anschließende Zusammenführung von Montageplatte mit dem Sammelkasten, wobei auch die Flachrohrenden in die Öffnungen des Sammelkastens geschoben werden, in die Ringräume gedrückt.The inventive method for producing a heat exchanger with an adhesive connection for metallic flat tube ends in corresponding openings of headers of the heat exchanger, in which a silicone adhesive is introduced into an annular space between the flat tube ends and the openings, is characterized in that the annular spaces with a memory module in Value range of 0.1 - 3.0 MPa possessing silicone adhesive of the addition-crosslinking type by means of a mounting plate filled and sealed. The mounting plate has openings corresponding to the flat tubes in order to be able to push the same onto the flat tube ends, so that, for example, it lies with the underside on cooling-air-side ribs. The opening edges of the mounting plate are close to the flat tube ends to avoid the escape of the adhesive as possible. The silicone adhesive is preferably applied to the top of the mounting plate and through the subsequent merger of mounting plate with the collecting box, whereby the flat tube ends are pushed into the openings of the collecting tank, pressed into the annular spaces.

Die Flachrohrenden werden bedarfsweise vorbehandelt, zumindest gereinigt mit einem geeigneten Mittel, um z. B. Lötflussmittel zu entfernen, die sich als schädlich für eine qualitätsgerechte Klebeverbindung erwiesen haben.The flat tube ends are pretreated as needed, at least cleaned with a suitable means to z. B. to remove solder flux, which have been found to be detrimental to a quality adhesive bond.

Die Flachrohrenden sind Teil eines mittels CAB - Lötverfahren verbundenen Wärmetauschernetzes aus Flachrohren und kühlluftseitigen Rippen, beide aus Aluminium bzw. aus Aluminiumlegierungen. Für dieses Lötverfahren wird normalerweise ein nicht korrosives Flussmittel verwendet, obwohl intensiv daran gearbeitet wird, auf Flussmittel komplett zu verzichten. Jedenfalls können Oberflächenbehandlungen sowohl an den Flachrohrenden als auch in den Öffnungswänden erforderlich sein und durchgeführt werden.The flat tube ends are part of a heat exchanger network of flat tubes and cooling air-side ribs connected by means of CAB brazing processes, both of aluminum or of aluminum alloys. This method of soldering normally uses a non-corrosive flux, although intensive work is being done to completely eliminate flux. In any case, surface treatments may be required and performed on both the flat tube ends and the aperture walls.

Die Montageplatte besitzt mit den Flachrohren korrespondierende Öffnungen, um dieselbe auf die Flachrohrenden stecken zu können, sodass sie beispielsweise mit der Unterseite auf kühlluftseitigen Rippen liegt. Die Öffnungsränder der Montageplatte liegen gemäß einer Weiterentwicklung nachgiebig eng an den Flachrohrenden an, um Unterschiede zwischen den Abständen der Öffnungen in der Montageplatte und den Abständen der Flachrohrenden ausgleichen zu können. Alternativ oder zusätzlich sind die Abstände zwischen den Öffnungen durch eine elastische bzw. nachgiebige Gestaltung der Montageplatte veränderbar bzw. anpassbar. Damit ist auch sichergestellt, dass weder die Flachrohrenden noch die Montageplatte beschädigt werden und dass kein Kleberverlust durch zu große Spalte zwischen den Flachrohrenden und den Öffnungsrändern der Montageplatte auftritt.The mounting plate has openings corresponding to the flat tubes in order to be able to push the same onto the flat tube ends, so that, for example, it lies with the underside on cooling-air-side ribs. According to a further development, the opening edges of the mounting plate are yieldingly close to the flat tube ends in order to be able to compensate for differences between the distances between the openings in the mounting plate and the spacings of the flat tube ends. Alternatively or additionally, the distances between the openings can be changed or adapted by means of an elastic or resilient design of the mounting plate. This also ensures that neither the flat tube ends nor the mounting plate are damaged and that no adhesive loss occurs due to too large gaps between the flat tube ends and the opening edges of the mounting plate.

Weitere Merkmale sind Inhalt der beiliegenden Patentansprüche. Ferner gehen Merkmale und deren Wirkungen aus der nachfolgenden Beschreibung von Ausführungsbeispielen anhand der beigefügten Zeichnungen hervor.Further features are content of the appended claims. Furthermore, features and their effects will become apparent from the following description of embodiments with reference to the accompanying drawings.

Die Zeichnungen zeigen Folgendes:

  • Fig. 1 zeigt bevorzugte Abmessungen der Ringräume als Ergebnis durchgeführter Versuche;
  • Fig. 2 zeigt eine perspektivische Teilansicht einer Montageplatte;
  • Fig. 3 zeigt eine perspektivische Gesamtansicht einer Montageplatte;
  • Fig. 4 zeigt einen Teillängsschnitt durch einen Sammelkasten des Wärmetauschers;
  • Fig. 5 zeigt eine Ansicht auf ein Flachrohrende;
  • Fig. 6 zeigt eine Ansicht auf einen Teil der Montageplatte mit Silikonkleber;
  • Fig. 7 zeigt einen Querschnitt durch einen Sammelkasten;
  • Fig. 8 zeigt eine perspektivische Teilansicht einer Montageplatte;
  • Fig. 9 zeigt eine perspektivische und vergrößerte Teilansicht einer Montageplatte;
  • Fig.10 zeigt perspektivisch eine Ausführungsform, wie die Öffnungsränder der Öffnungen der Montageplatte nachgiebig ausgebildet sind, in einer stark vergrößerten Ansicht;
  • Fig. 11 zeigt den Querschnitt einer zweiten Ausführungsform;
  • Fig.12 zeigt den Querschnitt einer dritten Ausführungsform;
  • Fig. 13 zeigt den Querschnitt einer vierten Ausführungsform;
  • Fig. 14 zeigt den Querschnitt einer ersten Ausführungsform zur nachgiebigen Gestaltung der Abstände der Öffnungen;
  • Fig. 15 zeigt den Querschnitt einer zweiten Ausführungsform alternativ zur Fig. 14;
  • Fig. 16 - 18 Herstellungsablauf und Frontansicht eines Wärmetauschers;
  • Zahlreiche praktische Versuche und Simulationsrechnungen haben ergeben, dass die bevorzugte Breite b des Ringraums 6 bzw. der Klebeverbindung 1 zwischen 1, 5 - 2,5 mm liegt und die bevorzugte Höhe h des mit dem Silikonklebers SK befüllten Ringraumes 6 bzw. der Klebeverbindung 1 etwa zwischen 5, 0 - 10, 0 mm zu finden ist. Das soll durch die Fig. 1 verdeutlicht sein. Die Breite b und die Höhe h wurden in der Fig. 4 eingezeichnet.
The drawings show the following:
  • Fig. 1 shows preferred dimensions of the annular spaces as a result of experiments carried out;
  • Fig. 2 shows a partial perspective view of a mounting plate;
  • Fig. 3 shows an overall perspective view of a mounting plate;
  • Fig. 4 shows a partial longitudinal section through a header of the heat exchanger;
  • Fig. 5 shows a view of a flat tube end;
  • Fig. 6 shows a view of a part of the mounting plate with silicone adhesive;
  • Fig. 7 shows a cross section through a collection box;
  • Fig. 8 shows a partial perspective view of a mounting plate;
  • Fig. 9 shows a perspective and enlarged partial view of a mounting plate;
  • Figure 10 shows in perspective an embodiment, as the opening edges of the openings of the mounting plate are resiliently formed in a greatly enlarged view;
  • Fig. 11 shows the cross section of a second embodiment;
  • Figure 12 shows the cross section of a third embodiment;
  • Fig. 13 shows the cross section of a fourth embodiment;
  • Fig. 14 shows the cross section of a first embodiment for compliant configuration of the distances of the openings;
  • Fig. 15 shows the cross section of a second embodiment as an alternative to Fig. 14 ;
  • Fig. 16 - 18 Production process and front view of a heat exchanger;
  • Numerous practical experiments and simulation calculations have shown that the preferred width b of the annular space 6 or the adhesive joint 1 is between 1.5 and 2.5 mm and the preferred height h of the annular space 6 filled with the silicone adhesive SK or of the adhesive joint 1 is approximately between 5, 0 - 10, 0 mm can be found. That should be through the Fig. 1 be clear. The width b and the height h were in the Fig. 4 located.

Aus der erwähnten Fig. 4 geht auch hervor, dass der obere Teil 60 des Ringraums 6 nicht mit dem Silikonkleber SK ausgefüllt ist. Es hat sich erwiesen, dass die Elastizität und die Haltbarkeit der Klebeverbindung weiter zu steigern ist, wenn der Füllungsgrad der Ringräume 6 mit Silikonkleber SK etwa 60 - 95% des Gesamtvolumens der Ringräume 6 beträgt.From the mentioned Fig. 4 also shows that the upper part 60 of the annular space 6 is not filled with the silicone adhesive SK . It has been found that the elasticity and the durability of the adhesive bond is to be further increased if the degree of filling of the annular spaces 6 with silicone adhesive SK is about 60-95% of the total volume of the annular spaces 6 .

Der eingesetzte Silikonkleber SK ist vom additionsvernetzenden Typ, das heißt, er scheidet bei seiner Aushärtung keine Stoffe aus. Der Speichermodul des Silikonklebers SK beträgt im Ausführungsbeispiel etwa 1,8 MPa, ausgewählt aus e nem Bereich zwischen 0,5 - 3,0 MPa. Dieser relativ niedrige Wert trägt zur Dauerhaltbarkeit der Klebeverbindung maßgeblich bei, wobei die Klebeverbindung exzellente elastische Eigenschaften aufweist und über einen langen Zeitraum behält. Bei der Herstellung der Klebeverbindung bzw. des Wärmetauschers des Ausführungsbeispiels wurde wie folgt vorgegangen:
Flachrohre 20, wie in Fig. 5 gezeigt, werden abwechselnd mit Rippen 30 zum Wärmetauschernetz 3 zusammengesetzt. Das Wärmetauschernetz 3 wird zum CAB-Löten entsprechend vorbereitet, der Lötprozess wird ausgeführt. Die freien Flachrohrenden 2 werden gegebenenfalls von Resten des Flussmittels oder anderen störenden Resten befreit bzw. ihre Oberfläche wird behandelt. Eine Montageplatte 10, eine dünne Folie von etwa 1,0 mm Dicke oder weniger, wie in den Fig. 2 bzw. 3 gezeigt, wird mit ihren Öffnungen 12 auf die Flachrohrenden 2 geschoben, wobei die Öffnungsränder recht eng an den Flachrohrwänden anliegen. Die Montageplatte 10 kann mit ihrer Unterseite schließlich auf den Rippen 30 sitzen, ohne daran befestigt zu werden. In der Fig. 4 ist im Gegensatz dazu ein geringer Abstand zwischen der Unterseite der Montageplatte 10 und den Rippen 30 zu sehen. Anschließend wird eine dosierte Menge des Silikonklebers SK, wie in Fig. 6 gezeigt, schlangenlinienartig auf der Innenseite der Montageplatte 10 aufgetragen. Danach wird der Sammelkasten 5 mit seinen Öffnungen 4 auf die freien Flachrohrenden 2 geschoben. Dabei kommt der Sammelkasten 5 mit der schalenartigen Montageplatte 10 zusammen, das heißt, der wellenartige Rand 11 der Montageplatte 10 greift in eine entsprechend geformte, umlaufende Nut 50 im Sammelkasten 5 ein. Die Oberseite der Montageplatte 10 verklebt dabei auch mit der Unterseite des Sammelkastens 5.
The silicone adhesive SK used is of the addition-curing type, ie it does not precipitate any substances when it is cured. The storage modulus of the silicone adhesive SK in the exemplary embodiment is about 1.8 MPa, selected from a range between 0.5 and 3.0 MPa. This relatively low value contributes significantly to the durability of the adhesive bond, wherein the adhesive compound has excellent elastic properties and retains over a long period of time. In the preparation of the adhesive joint or the heat exchanger of the embodiment, the procedure was as follows:
Flat tubes 20 , as in Fig. 5 are alternately assembled with fins 30 to the heat exchanger network 3 . The heat exchanger network 3 becomes CAB soldering prepared accordingly, the soldering process is carried out. The free flat tube ends 2 are optionally freed of residues of the flux or other interfering residues or their surface is treated. A mounting plate 10 , a thin film of about 1.0 mm thickness or less, as in FIGS Fig. 2 and 3, is pushed with its openings 12 on the flat tube ends 2 , wherein the opening edges lie quite close to the flat tube walls. The mounting plate 10 can sit with its bottom finally on the ribs 30 without being attached thereto. In the Fig. 4 In contrast, a small distance between the bottom of the mounting plate 10 and the ribs 30 can be seen. Subsequently, a metered amount of silicone adhesive SK , as in Fig. 6 shown, serpentine on the inside of the mounting plate 10 applied. Thereafter, the collection box 5 is pushed with its openings 4 on the free flat tube ends. 2 In this case, the collecting box 5 comes together with the shell-like mounting plate 10 , that is, the wave-like edge 11 of the mounting plate 10 engages in a correspondingly shaped, circumferential groove 50 in the collecting box 5 a. The top of the mounting plate 10 glued to the bottom of the manifold 5 .

Im Ausführungsbeispiel ist der Sammelkasten 5 einteilig ausgebildet. Ein nicht gezeigtes Ausführungsbeispiel besitzt einen Rohrboden aus Metall oder Kunststoff, in dem sich die Öffnungen 4 befinden, der später mit einem Kastenteil entlang der umlaufenden Ränder verbunden wird, um den Sammelkasten 5 zu bilden.In the exemplary embodiment, the collecting box 5 is integrally formed. An embodiment not shown has a tube sheet of metal or plastic, in which the openings 4 are located, which is later connected to a box part along the peripheral edges to form the collecting box 5 .

Durch die Zusammenführung von schalenartiger Montageplatte 10 mit Sammelkasten 5 wird vor allem der Silikonkleber SK in die Ringräume 6 gedrückt. Durch das erwähnte Eingreifen des Randes 11 in die umlaufende Nut 50 wird verhindert, dass beim Zusammenführen von Sammelkasten 5 mit Montageplatte 5 der Silikonkleber SK seitlich austreten kann. Er wird vielmehr gezwungen in die Ringräume 6 einzutreten. Die Höhe H des Randes 11 ist deshalb so ausgelegt worden, dass er bereits in die Nut 50 eingreift bevor das Eindrücken des Silikonklebers SK in die Ringräume 6 beginnt. Der in der Fig. 4 gezeigte Zustand wird somit erreicht. Der Füllungsgrad der Ringräume 6 beträgt in diesem Ausführungsbeispiel etwa 75%, das heißt, 25 % des Volumens der Ringräume 6 werden nicht mit dem Silikonkleber SK befüllt. In der Fig. 4 sind das die oberen Teile 6 der Ringräume 60. Wie aus der Fig. 4 weiter ersichtlich ist, stecken die allerletzten Enden der Flachrohrenden 2 in sehr engen Öffnungsabschnitten, die Teile der Öffnungen 4 im Sammelkasten 5 sind, um zu vermeiden, dass der Silikonkleber SK später in wesentlichen Kontakt mit dem durch den Wärmetauscher strömenden Medium kommt.By bringing together shell-like mounting plate 10 with collecting box 5 , especially the silicone adhesive SK is pressed into the annular spaces 6 . By the mentioned intervention of the edge 11 in the circumferential groove 50 prevents the merging of collection box 5 with mounting plate 5 of the silicone adhesive SK can escape laterally. He is rather forced to enter the annular spaces 6 . The height H of the edge 11 has therefore been designed so that it already engages in the groove 50 before the impressions of the silicone adhesive SK begins in the annular spaces 6 . The Indian Fig. 4 shown state is thus achieved. The degree of filling of the annular spaces 6 in this embodiment is about 75%, that is, 25% of the volume of the annular spaces 6 are not filled with the silicone adhesive SK . In the Fig. 4 these are the upper parts 6 of the annular spaces 60 . Like from the Fig. 4 It can also be seen that the very last ends of the flat tube ends 2 are in very narrow opening sections, the parts of the Openings 4 in the collecting box 5 are to avoid that the silicone adhesive SK comes later in substantial contact with the medium flowing through the heat exchanger.

Zur Darstellung in Fig. 4 sei noch vermerkt, dass die Flachrohrenden 2 praktisch nicht in das Innere des Sammelkastens 5 ragen, auch wenn die Fig. 4 einen anderen Eindruck vermitteln könnte. Der Sammelkasten 5 besitzt nämlich in seinem Öffnungs - bzw. Bodenbereich eine - im Querschnitt betrachtet - etwa halbrunde Kontur, um seine Druckstabilität zu verbessern, weshalb die Fig. 4 den Anschein erwecken könnte, als stünden die Flachrohrenden 2 deutlich nach innen über, was tatsächlich nur für die auf der Mittellängslinie liegende Partie der Flachrohrenden 2 zutrifft. Der innere Druckverlust ist deshalb reduziert worden. Der Gesamtquerschnitt des Sammelkastens 5 ist rund bis oval ausgebildet, was die Fig. 7 zeigen soll. Die Montageplatte 10, eines der Flachrohre 20 und ein Teil eines Ringraums 6 wurden dort lediglich in stilisierender Weise angedeutet.For presentation in Fig. 4 It should be noted that the flat tube ends 2 practically do not protrude into the interior of the collecting tank 5 , even if the Fig. 4 could give a different impression. Namely, in its opening or bottom area, the collecting box 5 has a roughly semicircular contour, viewed in cross-section, in order to improve its pressure stability Fig. 4 could appear as if the flat tube ends 2 were clearly inwardly over, which is true only for the lying on the central longitudinal line lot of flat tube ends 2 . The internal pressure loss has therefore been reduced. The total cross section of the collecting tank 5 is round to oval, which is the Fig. 7 should show. The mounting plate 10 , one of the flat tubes 20 and a part of an annular space 6 were indicated there only in stylizing manner.

Die Zugfestigkeit des Silikonklebers SK beträgt im Ausführungsbeisl etwa 5,3 MPa, ausgewählt aus einem vorteilhaften Bereich zwischen 3,0 - 7,0 MPa.The tensile strength of the silicone adhesive SK in the embodiment is about 5.3 MPa selected from an advantageous range of 3.0 to 7.0 MPa.

Die Viskosität des Silikonklebers SK beträgt etwa 35 000 cP, ausgewählt aus einem Bereich zwischen 20 000 - 60 000 cP. Mit diesem Wert lässt sich der Silikonkleber SK auftragen, ohne auseinander zu fließen.The viscosity of the silicone adhesive SK is about 35,000 cP, selected from a range between 20,000 and 60,000 cP. With this value, the silicone adhesive SK can be applied without flowing apart.

Im Anschluss an die beschriebene Montage wird ein Aushärteprozess durchgeführt, der in einem nicht gezeigten Trocknungsofen oder auf einer Trocknungsstrecke ausgeführt wird. Die Wärmetauscher werden bei einer Temperatur von ca. 120°C etwa 30 Minuten gehalten, ausgewählt aus einem Temperaturbereich von 80 - 180°C und einer Zeitspanne zwischen 1 - 60 Minuten. Dem Silikonkleber SK wurde ein Katalysator aus der Gruppe der Platinmetalle beigemischt, um die Aushärtezeit zu verkürzen.Following the described assembly, a curing process is carried out, which is carried out in a drying oven, not shown, or on a drying line. The heat exchangers are maintained at a temperature of about 120 ° C for about 30 minutes, selected from a temperature range of 80-180 ° C and a time between 1-60 minutes. The silicone adhesive SK was mixed with a catalyst from the group of platinum metals in order to shorten the curing time.

Weil die Dicke der Wandteile a, b (Fig. 5) der Flachrohre 20 extrem gering ist, nämlich in einem Bereich von 0,03 mm - 0,15 mm liegt, weil die Rippen 30 lediglich etwa 0,03 mm - 0,09 mm dick sind und weil darüber hinaus vorzugsweise kein metallischer Rohrboden eingesetzt wird, wird ein wesentlich leichterer Wärmetauscher zur Verfügung gestells. Auch seine Leistungskennwerte liegen - u. a. wegen der Inneneinsätze c in den Flachrohren 20 - deutlich höher als bei gewöhnlichen Wärmetauschern. Solche Wärmetauscher benötigen darüber hinaus wesentlich weniger Energie beispielsweise für den Lötprozess. Bei der Bereitstellung solcher Wärmetauscher leistet die vorgeschlagene Erfindung einen wesentlichen Beitrag.Because the thickness of the wall parts a , b ( Fig. 5 ) of the flat tubes 20 is extremely low, namely in a range of 0.03 mm - 0.15 mm, because the ribs 30 are only about 0.03 mm - 0.09 mm thick and because, moreover, preferably no metallic tube sheet used A much lighter heat exchanger will be provided. Its performance characteristics are also significantly higher than for ordinary heat exchangers, partly because of the inner inserts c in the flat tubes 20 . Moreover, such heat exchangers require considerably less energy, for example for the soldering process. In the provision Such a heat exchanger makes the proposed invention a significant contribution.

Zahlreiche Fertigungsversuche haben ergeben, dass, bedingt durch verschiedene Fertigungseinflüsse, die genaue Übereinstimmung der Abstände der Flachrohrenden mit den Abständen der Öffnungsränder in der Montageplatte nicht ständig gewährleistet ist. Dies kann zu Beschädigungen der Flachrohrenden und der Montageplatte führen, wodurch das Wärmetauschernetz und die Montageplatte unbrauchbar werden können. Mittels Untersuchungen bezüglich verschiedener Ausführungsformen der Öffnungsränder und den Bereichen zwischen den Öffnungen wurde festgestellt, dass eine nachgiebige Gestaltung der Öffnungsränder und / oder der Abstände der Öffnungen sowohl die Beschädigungsgefahr durch nicht übereinstimmende Abstände, als auch die Gefahr von Kleberverlust durch zu große Spalte ausschließt. Die Nachgiebigkeit der Öffnungsränder und / oder der Abstände der Öffnungen der Montageplatte kann zum Beispiel durch eine örtlich geringere Materialdicke der Montageplatte dargestellt werden, unterstützt durch Schnitte in den Öffnungsrändern.Numerous manufacturing experiments have shown that, due to various manufacturing influences, the exact match of the distances between the flat tube ends with the spacing of the opening edges in the mounting plate is not guaranteed. This can lead to damage of the flat tube ends and the mounting plate, whereby the heat exchanger network and the mounting plate can be unusable. By examining various embodiments of the opening edges and the areas between the openings, it has been found that a compliant design of the opening edges and / or spacing of the openings precludes both the risk of damage from mismatching distances and the risk of adhesive loss due to excessive gaps. The compliance of the opening edges and / or the distances of the openings of the mounting plate can be represented for example by a locally lower material thickness of the mounting plate, supported by cuts in the opening edges.

Bei der Herstellung der Klebeverbindung bzw. des Wärmetauschers des Ausführungsbeispiels wird wie folgt verfahren:In the production of the adhesive joint or the heat exchanger of the embodiment, the procedure is as follows:

Flachrohre 20 werden abwechselnd mit Rippen 30 zum Wärmetauschernetz 3 zusammengesetzt. Das Wärmetauschernetz 3 wird zum CAB-Löten entsprechend vorbereitet, der Lötprozess wird ausgeführt. Die freien Flachrohrenden 2 werden gegebenenfalls von Resten des Flussmittels oder anderen störenden Resten befreit bzw. ihre Oberfläche wird behandelt. Eine Montageplatte 10, eine dünne Folie von etwa 1,0 mm Dicke oder weniger wird mit ihren Öffnungen 12 auf die Flachrohrenden 2 geschoben, wobei die nachgiebigen Öffnungsränder 13 sich an den Schmal- und Breitseiten der Flachrohre 20 anlegen.Flat tubes 20 are alternately assembled with ribs 30 to the heat exchanger network 3 . The heat exchanger network 3 is prepared according to the CAB-soldering, the soldering process is carried out. The free flat tube ends 2 are optionally freed of residues of the flux or other interfering residues or their surface is treated. A mounting plate 10 , a thin film of about 1.0 mm thickness or less is pushed with its openings 12 on the flat tube ends 2 , wherein the resilient opening edges 13 create on the narrow and broad sides of the flat tubes 20 .

Die Öffnungsränder 13 können mit Schnitten 14 und / oder spitz zulaufend 15 ausgebildet sein, wie in den Fig. 8 - 10 dargestellt ist. Eine zweite Ausführungsform der Öffnungsränder 13 ist in Fig. 12 gezeigt, wobei die Nachgiebigkeit durch eine örtlich verringerte Materialdicke in Form eines Absatzes 16 dargestellt ist. Als drittes Ausführungsbeispiel ist die örtlich verringerte Materialstärke mittels Rillen 17 bzw. Sicken verwirklicht, wie in Fig. 13 gezeigt ist, wobei die Form der Rillen bzw. Sicken nicht auf eine im Querschnitt kreisbogenförmige Vertiefung beschränkt sein muss. Weitere Ausführungsbeispiele zeigen in den Fig. 14 und 15 die nachgiebige Gestaltung der Abstände der Öffnungen 12 in der Montageplatte 10 durch Verringerung der Materialdicke in den Randbereichen zwischen den Öffnungen 12 und den wellenartigen Rändern 11 der Montageplatte 10, (Fig. 14), oder zwischen den Öffnungen 12 quer über die Montageplatte 10, (Fig. 15).The opening edges 13 may be formed with cuts 14 and / or tapering 15 , as in the Fig. 8 - 10 is shown. A second embodiment of the opening edges 13 is in Fig. 12 shown, wherein the compliance is represented by a locally reduced material thickness in the form of a paragraph 16 . As a third embodiment, the locally reduced material thickness is realized by means of grooves 17 or beads, as in Fig. 13 is shown, wherein the shape of the grooves or beads need not be limited to a circular arc-shaped depression in cross-section. Further embodiments show in the Fig. 14 and 15 the resilient configuration of the distances of the openings 12 in the mounting plate 10 by reducing the material thickness in the edge regions between the openings 12 and the wave-like edges 11 of the mounting plate 10 , ( Fig. 14 ), or between the openings 12 across the mounting plate 10 , (FIG. Fig. 15 ).

Es sind beliebige jedoch zweckmäßige Kombinationen der vorstehend beschriebenen Ausführungen möglich, um die Nachgiebigkeit zu erreichen, bzw. um dieselbe weiter zu erhöhen.Any but appropriate combinations of the embodiments described above are possible in order to achieve the flexibility, or to increase the same further.

Die Montageplatte 10 kann mit ihrer Unterseite schließlich auf den Rippen 30 sitzen, ohne daran befestigt zu werden. In der Fig. 4 ist im Gegensatz dazu ein geringer Abstand zwischen der Unterseite der Montageplatte 10 und den Rippen 30 zu sehen. Anschließend wird eine dosierte Menge des Silikonklebers SK, schlangenlinienartig auf der Innenseite der Montageplatte 10 aufgetragen ( nicht gezeigt ). Danach wird der Sammelkasten 5 mit seinen Löchern 4 auf die freien Flachrohrenden 2 geschoben. Dabei kommt der Sammelkasten 5 mit der schalenartigen Montageplatte 10 zusammen, das heißt, der wellenartige Rand 11 der Montageplatte 10 greift in eine entsprechend geformte, umlaufende Nut 50 im Sammelkasten 5 ein. Die Oberseite der Montageplatte 10 verklebt dabei auch mit der Unterseite des Sammelkastens 5.The mounting plate 10 can sit with its bottom finally on the ribs 30 without being attached thereto. In the Fig. 4 In contrast, a small distance between the bottom of the mounting plate 10 and the ribs 30 can be seen. Subsequently, a metered amount of the silicone adhesive SK , a serpentine on the inside of the mounting plate 10 is applied (not shown). Thereafter, the collection box 5 is pushed with its holes 4 on the free flat tube ends. 2 In this case, the collecting box 5 comes together with the shell-like mounting plate 10 , that is, the wave-like edge 11 of the mounting plate 10 engages in a correspondingly shaped, circumferential groove 50 in the collecting box 5 a. The top of the mounting plate 10 glued to the bottom of the manifold 5 .

Durch die Zusammenführung der schalenartigen Montageplatte 10 mit dem Sammelkasten 5 wird der Silikonkleber SK in die Ringräume 6 gedrückt. Durch das erwähnte Eingreifen des Randes 11 in die umlaufende Nut 50 wird verhindert, dass beim Zusammenführen vom Sammelkasten 5 mit der Montageplatte 10 der Silikonkleber SK seitlich austreten kann. Er wird vielmehr gezwungen in die Ringräume 6 einzutreten.By merging the shell-like mounting plate 10 with the collecting box 5 , the silicone adhesive SK is pressed into the annular spaces 6 . By the mentioned intervention of the edge 11 in the circumferential groove 50 prevents the merging of the collecting box 5 with the mounting plate 10 of the silicone adhesive SK can escape laterally. He is rather forced to enter the annular spaces 6 .

In der Fig. 18 wird ein Kühlflüssigkeitskühler (Wärmetauscher) eines Lastkraftfahrzeuges gezeigt, dessen Wärmetauschernetz von Kühlluft durchströmt wird. Dieser Kühlflüssigkeitskühler besitzt die vorgeschlagene Klebeverbindung an den Flachrohrenden 2 und wurde gemäß dem beschriebenen Verfahren hergestellt. Die Fig. 16 und 17 zeigen den Herstellungsablauf des Kühlflüssigkeitskühlers, ausgehend von einem bereits gelöteten Wärmetauschernetz 3, bestehend aus Flachrohren 20 und dort nicht gezeichneten Rippen 30. Zunächst wird die Montageplatte 10 auf die Flachrohrenden geschoben. Der Silikonkleber SK vom additionsvernetzenden Typ wird aufgetragen und die Flachrohrenden 2 werden in die Öffnungen des Sammelkastens 5 geschoben, wobei die Montageplatte 10 mit dem Sammelkasten 5 zusammengeführt und der Silikonkleber in die Ringräume gepresst wird.In the Fig. 18 a cooling liquid cooler (heat exchanger) of a truck is shown, the heat exchanger network is traversed by cooling air. This Kühlflüssigkeitkühler has the proposed adhesive bond to the flat tube ends 2 and was prepared according to the described method. The FIGS. 16 and 17 show the production process of the Kühlflüssigkeitskühlers, starting from an already brazed heat exchanger network 3 , consisting of flat tubes 20 and not shown there ribs 30th First, the mounting plate 10 is pushed onto the flat tube ends. The silicon adhesive SK of the addition-curing type is applied and the flat tube ends 2 are inserted into the Openings of the collecting tank 5 is pushed, wherein the mounting plate 10 is brought together with the collecting box 5 and the silicone adhesive is pressed into the annular spaces.

Claims (30)

  1. Heat exchanger having a collecting tank (5) made of plastic or metal, having flat metal tube ends (2) that are part of a brazed heat exchanger network (3) and having an adhesive connection (1) for the flat metal tube ends (2) in corresponding openings (4) in the collecting tank (5), each opening having an annular space (6) around the flat tube ends (2), in which a silicone adhesive (SK) is located, the extreme ends of the flat tube ends (2) being inserted in very narrow opening portions that are part of the openings in the collecting tank, in order to avoid the silicone adhesive later coming into significant contact with the medium flowing through the heat exchanger,
    the silicone adhesive (SK) being of the addition-crosslinking type and having a storage modulus in the range of values between 0.1 and 3.0 MPa,
    a mounting plate (10) being formed and arranged as a thin foil, which closes the annular spaces (8).
  2. Heat exchanger according to Claim 1, characterized in that the annular spaces (6) are filled to approximately 60 to 95% of their volume with the silicone adhesive (SK).
  3. Heat exchanger according to Claim 1, characterized in that the height (h) of the annular spaces (6) that is filled with the silicone adhesive (SK) is approximately 5 to 15 mm and the width (b) of the annular spaces (6) is approximately 0.5 to 3.0 mm.
  4. Heat exchanger according to Claim 1, characterized in that the silicone adhesive (SK) consists of one component or of at least two components.
  5. Heat exchanger according to Claim 1, characterized in that the elongation of the silicone adhesive is greater than 100%, for example 150%.
  6. Heat exchanger according to claim 1, characterized in that the tensile strength of the silicone adhesive (SK) lies approximately between 3.0 and 7.0 MPa, preferably at approximately 4.0 to 6.0 MPa.
  7. Heat exchanger according to Claim 1, characterized in that the silicone adhesive (SK) has a catalyst from the group of platinum metals or their compounds.
  8. Heat exchanger according to Claim 1, characterized in that the dynamic viscosity of the non-cured silicone adhesive (SK) is approximately 20,000 to 60,000 cP.
  9. Heat exchanger according to Claim 1, characterized in that the annular spaces (6) have approximately the same width (b) over the height (h) that is filled with the silicone adhesive (SK).
  10. Heat exchanger according to one of Claims 1 to 8, characterized in that the annular spaces (6) have a decreasing/increasing width (b) over the height (h) that is filled with the silicone adhesive (SK).
  11. Heat exchanger according to Claims 1 and 2, characterized in that the part (60) of the annular spaces (6) that is not filled with the silicone adhesive (SK) is arranged facing the collecting tank (5).
  12. Heat exchanger according to Claim 1, characterized in that the mounting plate (10) is formed with an upright, peripheral edge (11) of the height (H).
  13. Heat exchanger according to Claims 1 and 12, characterized in that the edge (11) of the mounting plate (10) engages in a corresponding groove (50) of the collecting tank (5) and in that the mounting plate (10) either lies with its underside on ribs (30) of the brazed heat exchanger network (3) or is arranged at a small distance from the ribs (30).
  14. Heat exchanger according to Claim 1, characterized in that the collecting tank (5) is of an approximately round to oval form in cross section, in order to improve its compressive stability.
  15. Heat exchanger according to Claim 1, characterized in that the mounting plate (10) has openings (12), the edges (13) of which and/or the distances between the openings (12) are formed in a yielding manner.
  16. Heat exchanger according to Claim 15, characterized in that the yielding compliance of the edges (13) of the openings is represented by a local reduction in the material thickness of the mounting plate (10).
  17. Heat exchanger according to Claims 15 and 16, characterized in that the yielding compliance of the edges of the openings is represented by cuts (14) in the edges (13) of the openings.
  18. Heat exchanger according to Claim 16, characterized in that the local reduction in the material thickness of the mounting plate is represented by a cross section (15) tapering to a point.
  19. Heat exchanger according to Claim 16, characterized in that the local reduction in the material thickness of the mounting plate (10) is represented by a cross section with an offset (16).
  20. Heat exchanger according to Claim 16, characterized in that the local reduction in the material thickness of the mounting plate (10) is represented by a cross section with two or more channels (17).
  21. Heat exchanger according to Claim 15, characterized in that the yielding compliance of the distances between the openings (12) is represented by a reduction in the material thickness between the openings (12) in the mounting plate (10).
  22. Heat exchanger according to Claim 15, characterized in that the yielding compliance of the distances between the openings (12) is represented by a reduction in the material thickness in the regions between the openings (12) in the mounting plate (10) and the wave-like edges (11) of the mounting plate (10).
  23. Method for producing a heat exchanger according to one of Claims 1 - 22, having an adhesive connection (1) for flat metal tube ends (2) in corresponding openings (4) in collecting tanks (5) of the heat exchanger, in which a silicone adhesive is introduced into a respective annular space (6) between the flat tube ends (2) and the openings (4), the silicone adhesive substantially not coming into contact with the medium flowing through the heat exchanger,
    the annular spaces (6) being filled and closed with a silicone adhesive (SK) of the addition-crosslinking type, having a storage modulus in the range of values between approximately 0.1 and 3.0 MPa, by means of a mounting plate (10).
  24. Method according to Claim 23, characterized in that the annular spaces (6) are filled to approximately 60 to 95% of their volume with the silicone adhesive (SK).
  25. Method according to Claim 23, characterized in that a metered amount of the silicone adhesive (SK) is applied in advance to the mounting plate (10) and is forced into the annular spaces (6) by the bringing together of the mounting plate (10) and the collecting tank (5).
  26. Method according to Claim 23, characterized in that the mounting plate (10) has an upright edge (11), which is of such a height that, when the mounting plate (6) is brought together with the collecting tank (5), the edge (11) is first inserted into a corresponding slot (50) within the collecting tank (5) before the forcing-in of the silicone adhesive (SK) is performed.
  27. Method according to Claim 23, characterized in that a catalyst is admixed in advance with the silicone adhesive.
  28. Method according to Claim 23, characterized in that the flat tube ends (2) are freed for example of fluxes in advance, in order to ensure direct metal contact of the silicone adhesive (SK).
  29. Method according to Claim 23, characterized in that the silicone adhesive (SK) either consists of one component or, in preparation for use, is mixed in advance from at least two components.
  30. Method according to Claim 23, characterized in that the adhesive connection or the heat exchanger is exposed to a temperature of approximately 80 to 180°C over a time period of 1 to 60 minutes in order to allow the silicone adhesive (SK) to cure.
EP08875072A 2008-07-09 2008-12-09 Heat exchanger and method of production Not-in-force EP2300770B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008032287A DE102008032287B4 (en) 2008-04-30 2008-07-09 Heat exchanger with a bonded joint, and method of making a heat exchanger
DE102008052723A DE102008052723A1 (en) 2008-04-30 2008-10-22 Adhesive connection for heat exchangers
PCT/EP2008/010422 WO2010003445A1 (en) 2008-07-09 2008-12-09 Adhesive connection for heat exchangers and production method

Publications (2)

Publication Number Publication Date
EP2300770A1 EP2300770A1 (en) 2011-03-30
EP2300770B1 true EP2300770B1 (en) 2012-04-18

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EP08875072A Not-in-force EP2300770B1 (en) 2008-07-09 2008-12-09 Heat exchanger and method of production

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EP (1) EP2300770B1 (en)
WO (1) WO2010003445A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011075071A1 (en) * 2011-05-02 2012-11-08 Behr Gmbh & Co. Kg Heat exchangers, in particular intercoolers
US10371464B2 (en) 2015-07-07 2019-08-06 Mahle International Gmbh Tube header for heat exchanger

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3239950A1 (en) * 1982-10-28 1984-05-03 Thermal-Werke, Wärme-, Kälte-, Klimatechnik GmbH, 6909 Walldorf Heat exchanger and process for the manufacture thereof
NL8400726A (en) 1984-03-07 1985-10-01 Philips Nv CURTAIN PLASTIC COMPOSITION AND METHOD FOR MANUFACTURING A COPOLYMER.
FR2587468A1 (en) * 1985-09-16 1987-03-20 Chausson Usines Sa Method for connecting the tubes to the collector plates of a heat exchanger and exchanger obtained by this method
JPS6287795A (en) * 1985-10-09 1987-04-22 Toyo Radiator Kk Shell and tube type heat exchanger
DE3809944A1 (en) 1988-03-24 1989-10-12 Sueddeutsche Kuehler Behr Heat exchanger, in particular a radiator for an internal-combustion engine of a motor vehicle, and method for producing it
FR2794227B1 (en) 1999-05-26 2001-08-31 Valeo Thermique Moteur Sa HEAT EXCHANGER WITH GLUE TUBES, PARTICULARLY FOR A MOTOR VEHICLE, AND METHOD FOR THE PRODUCTION THEREOF
DE102004036020A1 (en) 2004-07-23 2006-02-16 Behr Gmbh & Co. Kg Heat exchanger, in particular condenser
TW200710364A (en) 2005-07-15 2007-03-16 Dsm Ip Assets Bv Automotive heat exchanger
DE102008021544B4 (en) 2007-07-10 2012-03-08 Modine Manufacturing Co. Production process for heat exchangers and heat exchangers

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WO2010003445A1 (en) 2010-01-14

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