EP2300589B1 - Composition de nuançage - Google Patents

Composition de nuançage Download PDF

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Publication number
EP2300589B1
EP2300589B1 EP09749662.4A EP09749662A EP2300589B1 EP 2300589 B1 EP2300589 B1 EP 2300589B1 EP 09749662 A EP09749662 A EP 09749662A EP 2300589 B1 EP2300589 B1 EP 2300589B1
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Prior art keywords
dye
phenyl
treatment composition
laundry treatment
composition according
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German (de)
English (en)
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EP2300589A1 (fr
Inventor
Stephen Norman Batchelor
Jayne Michelle Bird
Susan Barbara Joyce
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Unilever PLC
Unilever NV
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Unilever PLC
Unilever NV
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Priority to PL09749662T priority Critical patent/PL2300589T3/pl
Priority to EP09749662.4A priority patent/EP2300589B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents

Definitions

  • the present invention relates to the delivery of dyes to fabrics.
  • WO 2008/017570 discloses the use of acid azine dyes as shading agents for domestic wash product. Acid azine dyes carry negatively charges substituents making the net charge of the dye anionic. Acid azine dyes deposit onto cotton but do not build up over multiple washes, preventing overblueing. Acid azine dyes deposit poorly to polyester-cotton blended garments and provide no deposition to polyester garments. The poor deposition on polycotton is thought to be due to the low cotton content of these garments. A shading system is required which give good deposition to polycotton, without unacceptably large deposition to cotton garment in the same wash.
  • WO 2007/039042 discloses Basic Violet 5 and Basic Violet 6 for use in laundry detergent compositions.
  • Selected cationic azine dyes have a high substantivity to polycotton whilst depositing well on cotton and are relatively alkaline stable and weight efficient.
  • the cationic azine dyes described herein have the further advantage of being substantive to pure polyester garments.
  • the cationic azine dyes described herein also have the advantage of providing good whiteness improvement to the fabric with little dulling of the fabric.
  • the cationic azine dyes described herein have the further advantage of showing no-build up behaviour on a range of fabrics.
  • the present invention provides a laundry treatment composition comprising:
  • the present invention provides a domestic method of treating a textile, the method comprising the steps of:
  • the aqueous solution used in the method has a fluorescer present.
  • the method is particularly applicable to wash loads containing polyester cotton blend garments/textiles.
  • the formulation may be liquid or granular.
  • the preferred format is that of a granular laundry treatment composition.
  • the cationic azine dye gives a blue or violet colour to the cloth with a hue angle of 250-345, more preferably 265 to 330, most preferably 270 to 300.
  • the cloth used is white bleached non-mercerised woven cotton sheeting.
  • R 5 is an aromatic group selected from: phenyl and naphthyl. Most preferably R 5 is phenyl. It is most preferred that when R 5 is phenyl, the phenyl carries one or two methyl groups.
  • R 1 , R 2 , R 3 and R 4 are independently selected from: H, CH 3 , C 2 H 5 , phenyl, and a benzyl group carrying an amine selected from: -NH 2 ; -N(CH 3 ) 2 ; and, - N(C 2 H 5 ) 2 .
  • phenyl is one or two of the groups R 1 , R 2 , R 3 and R 4 and more preferably the phenyl carries an amine, preferably one, amine that is preferably selected from: -NH 2 ; -N(CH 3 ) 2 ; and, -N(C 2 H 5 ) 2 .
  • the R 1 , R 2 , R 3 and R 4 groups may be a polyether chain.
  • a polyether chain is defined as at least two repeating units that are chemically bound via the ether's oxygen.
  • Preferred polyether chains are selected from ethylene oxides or propylene oxides. Where an alkyl and/or polyether chain is present the chain preferably has a molecular weight of less than 1000, more preferably less than 400, even more preferably less than 200.
  • the cationic azine dye may be further substituted by uncharged organic groups. If the cationic azine dye is further substituted it is preferred that the uncharged organic groups should have a total molecular weight of less than 400, preferably less than 150.
  • Preferred uncharged organic groups may be selected from NHCOCH 3 , CH 3 , C 2 H 5 , CH 3 O, C 2 H 5 O, amine, Cl, F, Br, I, NO 2 , CH 3 SO 2 , and CN.
  • X- is not essential aspect of the invention and may be varied widely.
  • X- may be an anion such as RCOO - , BPh 4 - , ClO 4 - , BF 4 - , PF 6 - , RSO 3 - , RSO 4 - , SO 4 2- , NO 3 - , F - , Cl - , Br - , or I - , with R being hydrogen, optionally substituted alkyl or optionally substituted aryl.
  • X- is selected from: CH 3 SO 3 - , CH 3 CO 2 - , BF 4 - , Cl - , F - , Br - , and I - .
  • the laundry treatment composition is in a container (pack) that has a moisture vapour transfer rate such that when stored at 37 °C at 70 % relative humidity the closed pack containing the laundry treatment composition does not increase in weight by more than 1 wt % for the first day (24 hours) stored at 37 °C at 70 % relative humidity.
  • the cationic azine dye is preferably granulated with an acidic component to reduce hydrolysis on storage as discussed in WO2007/039042 (Unilever).
  • the dye may be added to the slurry to be spray dried or added via post-dosed granules.
  • the dye powder obtained from the dye synthesis is mixed with a Na 2 SO 4 or NaCl or pre-prepared granular base or full detergent formulation to give a 0.1 to 5 dye wt% mixture.
  • This dry mixed is then mixed into the granular formulation.
  • the dye powder is preferably formed by drying a liquid slurry or solution of the dye, for example by vacuum drying, freeze drying, drying in drum dryers, Spin Flash ® (Anhydro), but most preferably by spray drying.
  • the dye powder may be ground before, during or after the making of the slurry. This grinding is preferably accomplished in mills, such as for example ball, swing, bead or sand mills, or in kneaders.
  • the dye powder preferably contains 20 to 100 wt% of the dye.
  • the dye powder has an average particle size, APS, from 0.1 to 300 microns, preferably 10 to 100 microns. Preferably this is as measured by a laser diffraction particle size analyser, preferably a Malvern HP with 100mm lens.
  • other shading colourants may be present that build up over multiple washes, thereby counteracting long term yellowing and greying effect.
  • They are preferably selected from blue and violet pigment such as pigment violet 23, solvent and disperse dyes such as solvent violet 13, bis-azo direct dyes such as direct violet 9, 35, 51 and 99, and triphenodioxazine direct dyes such as direct violet 54.
  • acid azine dyes as described in WO 2008/017570 ; the level of the acid azine dyes should be in the range from 0.0001 to 0.1 wt%.
  • the acid azine dyes provide benefit predominately to the pure cotton garments and the cationic azine dyes to the polycotton garments.
  • Photobleaches such as sulphonated Zn/Al phthalocyanins may be present.
  • the composition comprises between 2 to 70 wt % of a surfactant, most preferably 10 to 30 wt %.
  • a surfactant most preferably 10 to 30 wt %.
  • the nonionic and anionic surfactants of the surfactant system may be chosen from the surfactants described " Surface Active Agents" Vol. 1, by Schwartz & Perry, Interscience 1949 , Vol. 2 by Schwartz, Perry & Berch, Interscience 1958 , in the current edition of " McCutcheon's Emulsifiers and Detergents” published by Manufacturing Confectioners Company or in "Tenside-Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Verlag, 1981 .
  • the surfactants used are saturated.
  • Suitable nonionic detergent compounds which may be used include, in particular, the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene oxide.
  • Specific nonionic detergent compounds are C 6 to C 22 alkyl phenol-ethylene oxide condensates, generally 5 to 25 EO, i.e. 5 to 25 units of ethylene oxide per molecule, and the condensation products of aliphatic C 8 to C 18 primary or secondary linear or branched alcohols with ethylene oxide, generally 5 to 40 EO.
  • Suitable anionic detergent compounds which may be used are usually water-soluble alkali metal salts of organic sulphates and sulphonates having alkyl radicals containing from about 8 to about 22 carbon atoms, the term alkyl being used to include the alkyl portion of higher acyl radicals.
  • suitable synthetic anionic detergent compounds are sodium and potassium alkyl sulphates, especially those obtained by sulphating higher C 8 to C 18 alcohols, produced for example from tallow or coconut oil, sodium and potassium alkyl C 9 to C 20 benzene sulphonates, particularly sodium linear secondary alkyl C 10 to C 15 benzene sulphonates; and sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum.
  • the preferred anionic detergent compounds are sodium C 11 to C 15 alkyl benzene sulphonates and sodium C 12 to C 18 alkyl sulphates.
  • surfactants such as those described in EP-A-328 177 (Unilever), which show resistance to salting-out, the alkyl polyglycoside surfactants described in EP-A-070 074 , and alkyl monoglycosides.
  • Preferred surfactant systems are mixtures of anionic with nonionic detergent active materials, in particular the groups and examples of anionic and nonionic surfactants pointed out in EP-A-346 995 (Unilever).
  • surfactant system that is a mixture of an alkali metal salt of a C 16 to C 18 primary alcohol sulphate together with a C 12 to C 15 primary alcohol 3 to 7 EO ethoxylate.
  • the nonionic detergent is preferably present in amounts greater than 10%, e.g. 25 to 90 wt % of the surfactant system.
  • Anionic surfactants can be present for example in amounts in the range from about 5% to about 40 wt % of the surfactant system.
  • the surfactant may be a cationic such that the formulation is a fabric conditioner.
  • the present invention When the present invention is used as a fabric conditioner it needs to contain a cationic compound.
  • the quaternary ammonium compound is a quaternary ammonium compound having at least one C 12 to C 22 alkyl chain.
  • the quaternary ammonium compound has the following formula: in which R 1 is a C 12 to C 22 alkyl or alkenyl chain; R 2 , R 3 and R 4 are independently selected from C 1 to C 4 alkyl chains and X - is a compatible anion.
  • R 1 is a C 12 to C 22 alkyl or alkenyl chain; R 2 , R 3 and R 4 are independently selected from C 1 to C 4 alkyl chains and X - is a compatible anion.
  • a preferred compound of this type is the quaternary ammonium compound cetyl trimethyl quaternary ammonium bromide.
  • a second class of materials for use with the present invention are the quaternary ammonium of the above structure in which R 1 and R 2 are independently selected from C 12 to C 22 alkyl or alkenyl chain; R 3 and R 4 are independently selected from C 1 to C 4 alkyl chains and X - is a compatible anion.
  • the ratio of cationic to nonionic surfactant is from 1:100 to 50:50, more preferably 1:50 to 20:50.
  • the cationic compound may be present from 1.5 wt % to 50 wt % of the total weight of the composition.
  • the cationic compound may be present from 2 wt % to 25 wt %, a more preferred composition range is from 5 wt % to 20 wt %.
  • the softening material is preferably present in an amount of from 2 to 60% by weight of the total composition, more preferably from 2 to 40%, most preferably from 3 to 30% by weight.
  • the composition optionally comprises a silicone.
  • Builder materials may be selected from 1) calcium sequestrant materials, 2) precipitating materials, 3) calcium ion-exchange materials and 4) mixtures thereof.
  • calcium sequestrant builder materials examples include alkali metal polyphosphates, such as sodium tripolyphosphate and organic sequestrants, such as ethylene diamine tetraacetic acid.
  • precipitating builder materials examples include sodium orthophosphate and sodium carbonate.
  • Examples of calcium ion-exchange builder materials include the various types of water-insoluble crystalline or amorphous aluminosilicates, of which zeolites are the best known representatives, e.g. zeolite A, zeolite B (also known as zeolite P), zeolite C, zeolite X, zeolite Y and also the zeolite P-type as described in EP-A-0,384,070 .
  • zeolites are the best known representatives, e.g. zeolite A, zeolite B (also known as zeolite P), zeolite C, zeolite X, zeolite Y and also the zeolite P-type as described in EP-A-0,384,070 .
  • the composition may also contain 0-65 % of a builder or complexing agent such as ethylenediaminetetraacetic acid, diethylenetriamine-pentaacetic acid, alkyl- or alkenylsuccinic acid, nitrilotriacetic acid or the other builders mentioned below.
  • a builder or complexing agent such as ethylenediaminetetraacetic acid, diethylenetriamine-pentaacetic acid, alkyl- or alkenylsuccinic acid, nitrilotriacetic acid or the other builders mentioned below.
  • Many builders are also bleachstabilising agents by virtue of their ability to complex metal ions.
  • Zeolite and carbonate are preferred builders.
  • the composition may contain as builder a crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate. This is typically present at a level of less than 15%w.
  • Aluminosilicates are materials having the general formula: 0.8-1.5 M 2 O. Al 2 O 3 . 0.8-6 SiO 2 where M is a monovalent cation, preferably sodium. These materials contain some bound water and are required to have a calcium ion exchange capacity of at least 50 mg CaO/g.
  • the preferred sodium aluminosilicates contain 1.5-3.5 SiO 2 units in the formula above. They can be prepared readily by reaction between sodium silicate and sodium aluminate, as amply described in the literature.
  • the ratio of surfactants to alumuminosilicate (where present) is preferably greater than 5:2, more preferably greater than 3:1.
  • phosphate builders may be used.
  • 'phosphate' embraces diphosphate, triphosphate, and phosphonate species.
  • Other forms of builder include silicates, such as soluble silicates, metasilicates, layered silicates (e.g. SKS-6 from Hoechst).
  • the laundry detergent formulation is a non-phosphate built laundry detergent formulation, i.e., contains less than 1 wt% of phosphate.
  • the composition preferably comprises a fluorescent agent (optical brightener).
  • fluorescent agents are well known and many such fluorescent agents are available commercially. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts.
  • the total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 2 wt %, more preferably 0.01 to 0.1 wt %.
  • Preferred classes of fluorescer are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X, Di-amine stilbene di-sulphonic acid compounds, e.g.
  • Preferred fluorescers are: sodium 2 (4-styryl-3-sulfophenyl)-2H-napthol[1,2-d]triazole, disodium 4,4'-bis ⁇ [(4-anilino-6-(N methyl-N-2 hydroxyethyl) amino 1,3,5-triazin-2-yl)]amino ⁇ stilbene-2-2' disulfonate, disodium 4,4'-bis ⁇ [(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino ⁇ stilbene-2-2' disulfonate, and disodium 4,4'-bis(2-sulfostyryl)biphenyl.
  • the aqueous solution used in the method has a fluorescer present.
  • a fluorescer is present in the aqueous solution used in the method it is preferably in the range from 0.0001 g/l to 0.1 g/l, preferably 0.001 to 0.02 g/l.
  • the composition comprises a perfume.
  • the perfume is preferably in the range from 0.001 to 3 wt %, most preferably 0.1 to 1 wt %.
  • CTFA Cosmetic, Toiletry and Fragrance Association
  • compositions of the present invention it is envisaged that there will be four or more, preferably five or more, more preferably six or more or even seven or more different perfume components.
  • top notes are defined by Poucher (Journal of the Society of Cosmetic Chemists 6(2):80 [1955 ]).
  • Preferred top-notes are selected from citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.
  • Perfume and top note may be used to cue the whiteness benefit of the invention.
  • the laundry treatment composition does not contain a peroxygen bleach, e.g., sodium percarbonate, sodium perborate, and peracid.
  • a peroxygen bleach e.g., sodium percarbonate, sodium perborate, and peracid.
  • the composition may comprise one or more polymers.
  • polymers are carboxymethylcellulose, poly (ethylene glycol), poly(vinyl alcohol), polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers and lauryl methacrylate/acrylic acid copolymers.
  • Polymers present to prevent dye deposition for example poly(vinylpyrrolidone), poly(vinylpyridine-N-oxide), and poly(vinylimidazole), are preferably absent from the formulation.
  • the laundry treatment composition may contain an enzyme.
  • Cotton and polycotton fabrics were washed in an aqueous wash solution (demineralised water) containing 1g/L Linear Alkyl benzene sulfonate, 1g/L sodium carbonate and 1g/L sodium chloride at a liquor to cloth ratio of 30:1.
  • aqueous wash solution demineralised water
  • To the wash solution shading were added such that the optical density (5cm) at the maximum optical absorption in the range 400-750nm was 0.5 and 0.1.
  • the clothes were removed rinsed and dried.
  • the reflectance spectra measured on a reflectometer and the colour expressed as CIE L a b values , and the whiteness expressed as the Ganz value.
  • L c , a c , and b c are the CIE L a b values of the control cloths washed without dye
  • L d , a d , and b d are the are the CIE L a b values of the cloths washed with dye.
  • ⁇ Ganz Ganz(dye) - Ganz(control).
  • a model wash load was created containing cotton (woven, knitted and towelling), polycotton (50/50 woven, 65/35 woven, 65/35 knitted), knitted polyester, knitted nylon elastane and knitted cotton-elastane fabrics.
  • the model wash load was washed in 4g/L of a detergent which contained 15% Linear Alkyl benzene sulfonate (LAS) surfactant, 30% Na 2 CO 3 , 40% NaCl, remainder minors included calcite and fluorescer and moisture. Washes were conducted in 26° French Hard water at room temperature with a liquor to cloth ratio of 10:1, for 30 minutes. Following the wash the cloths were rinsed twice in water, dried, their reflectance spectrum measured on a reflectometer and the colour expressed as CIE L a b values. The washes were then repeated until 5 washes had been accomplished.
  • LAS Linear Alkyl benzene sulfonate
  • the powder formulations A, B, C and D were made up with dye 3, dye 4 and dye 5 of the examples respectively as the cationic azine dye.
  • the liquid formulations A, B, C and D were made up with dye 3, dye 4 and dye 5 of the examples respectively as the cationic azine dye.
  • NI(7EO) refers to R-(OCH 2 CH 2 ) n OH, where R is an alkyl chain of C12 to C15, and n is 7.
  • NaLAS linear alkyl benzene sulphonate (LAS) and (SLES(3EO)) is C 12 -C 18 alkyl polyethoxylate (3.0) sulphate.
  • a rinse conditioner formulation for use in the rinse stage of the wash was also created. It contained 13.7wt% N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride, 1.5wt% perfume 0.004wt%, and dye 3, dye 4 and dye 5 of the examples respectively, remainder minors and water.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Claims (9)

  1. Composition pour le traitement du linge comprenant :
    (i) de 2 à 70 % en poids de tensioactif ;
    (ii) de 0,005 à 2 % en poids d'agent fluorescent ; et
    (iii) de 0,0001 à 0,1 % en poids d'un colorant azine cationique bleu ou violet, le colorant azine étant choisi parmi les structures suivantes :
    Figure imgb0017
     dans lesquelles X- est un anion négatif ;
    pas plus d'un des groupes R1, R2, R3 et R4 n'est H et ils sont indépendamment choisis parmi : une chaîne polyéther, une chaîne benzyle, phényle, benzyle substituée par une amine, phényle substituée par une amine, COCH3, H, une chaîne alkyle linéaire ou ramifiée ; une chaîne alkyle linéaire ou ramifiée qui est substituée par un ou plusieurs groupes choisis parmi : les groupes ester ; Cl ; F ; CN ; OH ; CH3O- ; C2H5O- ; et, phényle ;
    R5 est choisi dans le groupe constitué par : un alkyle C1 à C10 ramifié ou linéaire ; un groupe alkyle C1 à C10 ramifié ou linéaire substitué par un groupe phényle ; et, un groupe aromatique ; et, le colorant n'est pas lié par covalence à un substituant à charge négative.
  2. Composition pour le traitement du linge selon la revendication 1, dans laquelle R5 est un groupe aromatique choisi parmi : phényle ou naphtyle.
  3. Composition pour le traitement du linge selon la revendication 2, dans laquelle R5 est phényle.
  4. Composition pour le traitement du linge selon l'une quelconque des revendications précédentes, dans laquelle R1, R2, R3 et R4 sont indépendamment choisis parmi : H, CH3, C2H5, un phényle, et un groupe benzyle portant une amine choisie parmi : -NH2 ; -N(CH3)2 ; et, -N(C2H5)2.
  5. Composition pour le traitement du linge selon l'une quelconque des revendications précédentes, dans laquelle le colorant azine est en outre substitué par des groupes organiques non chargés ayant un poids moléculaire total inférieur à 400.
  6. Composition pour le traitement du linge selon la revendication 5, dans laquelle les groupes organiques non chargés sont choisis parmi : NHCOCH3, CH3, C2H5, CH3O, C2H5O, une amine, Cl, F, Br, I, NO2, CH3SO2, et CN.
  7. Composition pour le traitement du linge selon l'une quelconque des revendications précédentes, dans laquelle l'agent fluorescent est choisi dans le groupe constitué par : le 2-(4-styryl-3-sulfophényl)-2H-naphtol[1,2-d]triazole de sodium, le 4,4'-bis{[(4-anilino-6-(N-méthyl-N-2-hydroxyéthyl)amino-1,3,5-triazin-2-yl)]amino}stilbène-2,2'-disulfonate de disodium, le 4,4'-bis{[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino}stilbène-2,2'-disulfonate de disodium, et le 4,4'-bis(2-sulfostyryl)biphényle de disodium.
  8. Procédé domestique de traitement d'un textile, le procédé comprenant les étapes suivantes :
    (i) le traitement d'un textile avec une solution aqueuse d'un colorant azine selon l'une quelconque des revendications 1 à 6, la solution aqueuse comprenant de 1 ppb à 1 ppm de colorant azine ; et de 0,0 à 3 g/L de tensioactif ; et,
    (ii) le rinçage et le séchage du textile.
  9. Procédé domestique de traitement d'un textile selon la revendication 8, dans lequel la solution aqueuse comprend un agent fluorescent dans la plage de 0,0001 à 0,1 g/l.
EP09749662.4A 2008-05-20 2009-02-16 Composition de nuançage Active EP2300589B1 (fr)

Priority Applications (2)

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PL09749662T PL2300589T3 (pl) 2008-05-20 2009-02-16 Cieniująca kompozycja
EP09749662.4A EP2300589B1 (fr) 2008-05-20 2009-02-16 Composition de nuançage

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EP08156569 2008-05-20
EP09749662.4A EP2300589B1 (fr) 2008-05-20 2009-02-16 Composition de nuançage
PCT/EP2009/051785 WO2009141172A1 (fr) 2008-05-20 2009-02-16 Composition de nuançage

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EP2300589A1 EP2300589A1 (fr) 2011-03-30
EP2300589B1 true EP2300589B1 (fr) 2013-10-23

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US (2) US8632610B2 (fr)
EP (2) EP2300589B1 (fr)
CN (2) CN102037115B (fr)
AR (2) AR071813A1 (fr)
BR (2) BRPI0912868B1 (fr)
CL (2) CL2009001229A1 (fr)
ES (2) ES2443822T3 (fr)
MA (2) MA32281B1 (fr)
MX (1) MX2010012769A (fr)
MY (1) MY155292A (fr)
PL (2) PL2300589T3 (fr)
WO (2) WO2009141173A1 (fr)
ZA (2) ZA201007321B (fr)

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ES2443822T3 (es) 2008-05-20 2014-02-20 Unilever N.V. Composición de matizado
ES2562003T3 (es) * 2009-05-05 2016-03-02 Unilever N.V. Composición de sombreado
PL2519624T3 (pl) * 2009-10-08 2015-04-30 Unilever Nv Cieniująca kompozycja
EP2343359A1 (fr) 2010-01-07 2011-07-13 Unilever PLC Formulation de détergent contenant des granules séchées par atomisation
EP2360232A1 (fr) * 2010-02-12 2011-08-24 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Taux d'agent tensioactif dans des détergents pour la lessive contenant un colorant
EP2534237B1 (fr) 2010-02-12 2014-11-12 Unilever PLC Compositions pour le traitement du linge comprenant des colorants d'ombrage bis-azo
CN103168098B (zh) 2010-10-14 2014-12-24 荷兰联合利华有限公司 洗衣洗涤剂颗粒
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EP2300589A1 (fr) 2011-03-30
ES2443822T3 (es) 2014-02-20
PL2300589T3 (pl) 2014-03-31
EP2288686B1 (fr) 2013-05-29
EP2288686A1 (fr) 2011-03-02
US8062382B2 (en) 2011-11-22
MA32278B1 (fr) 2011-05-02
CL2009001230A1 (es) 2010-03-05
BRPI0912867A2 (pt) 2015-10-06
WO2009141172A1 (fr) 2009-11-26
CN102037115B (zh) 2012-10-03
BRPI0912868B1 (pt) 2020-10-27
MY155292A (en) 2015-09-30
AR071813A1 (es) 2010-07-14
US8632610B2 (en) 2014-01-21
ZA201007323B (en) 2011-12-28
MX2010012769A (es) 2011-03-02
BRPI0912868A2 (pt) 2015-10-06
ZA201007321B (en) 2011-12-28
CN102037115A (zh) 2011-04-27
PL2288686T3 (pl) 2013-11-29
WO2009141173A1 (fr) 2009-11-26
CN102037114A (zh) 2011-04-27
CN102037114B (zh) 2013-03-13
MA32281B1 (fr) 2011-05-02
US20110131736A1 (en) 2011-06-09
BRPI0912867B1 (pt) 2020-08-11
ES2426231T3 (es) 2013-10-22
AR071812A1 (es) 2010-07-14
CL2009001229A1 (es) 2010-06-11

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