EP2290704A1 - Couche de passivation pour cellules solaires à base de plaquette en silicon crystallin et son procédé de fabrication - Google Patents

Couche de passivation pour cellules solaires à base de plaquette en silicon crystallin et son procédé de fabrication Download PDF

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EP2290704A1
EP2290704A1 EP09168864A EP09168864A EP2290704A1 EP 2290704 A1 EP2290704 A1 EP 2290704A1 EP 09168864 A EP09168864 A EP 09168864A EP 09168864 A EP09168864 A EP 09168864A EP 2290704 A1 EP2290704 A1 EP 2290704A1
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Prior art keywords
layer
passivation layer
solar cell
passivation
substrate
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EP09168864A
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English (en)
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Manfred Englert
Sven Schramm
Roland Trassl
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Applied Materials Inc
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Applied Materials Inc
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Priority to EP09168864A priority Critical patent/EP2290704A1/fr
Priority to US12/555,131 priority patent/US20110048515A1/en
Priority to PCT/EP2010/062348 priority patent/WO2011023701A2/fr
Priority to TW099128703A priority patent/TW201128780A/zh
Publication of EP2290704A1 publication Critical patent/EP2290704A1/fr
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/186—Particular post-treatment for the devices, e.g. annealing, impurity gettering, short-circuit elimination, recrystallisation
    • H01L31/1868—Passivation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier
    • H01L31/068—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by at least one potential-jump barrier or surface barrier the potential barriers being only of the PN homojunction type, e.g. bulk silicon PN homojunction solar cells or thin film polycrystalline silicon PN homojunction solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/547—Monocrystalline silicon PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • Embodiments of the present invention relate to passivation of wafer based solar cells. Particularly, they relate to reactively-sputtered, aluminum-containing passivation layers and methods of depositing same. Specifically, they relate to a solar cell layer stack and a method of manufacturing a solar cell layer stack.
  • PV cells or solar cells are material junction devices which convert sunlight into direct current (DC) electrical power.
  • DC direct current
  • solar cell p-n junctions When exposed to sunlight, i.e. photons, the electric field of solar cell p-n junctions separates pairs of electrons and holes, thus generating a photo-voltage.
  • a circuit from n-side to p-side allows the flow of electrons when the solar cell is connected to an electrical load, while the area and other parameters of the PV cell junction device determine the available current.
  • Solar cells have evolved significantly over the past two decades, with experimental efficiencies increasing from less than about 5% in 1980 to almost 40% in 2008.
  • the most common solar cell material is silicon, which is used, for example, in the form of single or polycrystalline wafers. Because the amortized cost of forming silicon-based solar cells to generate electricity is higher than the cost of generating electricity using traditional methods, there has been an effort to reduce the cost of manufacturing solar cells. Thereby, high light conversion efficiencies have to be provided at reduced costs.
  • the existing efficiency of a PV module has to be stable over the lifetime of the module in order to allow for high acceptance of the modules by the consumer.
  • covering layers and intermediate layers for passivation, high efficiencies, i.e. desired optical properties, and desired properties for the manufacturing process are used.
  • a solar cell layer stack according to independent claim 1 and a method of manufacturing a solar cell layer stack according to independent claim 11 are provided.
  • a solar cell layer stack includes a doped silicon wafer substrate; a further layer deposited on the substrate, wherein the further layer is doped for generation of a p-n-junction with the doped silicon wafer substrate; and a first sputtered and annealed passivation layer deposited on the doped silicon wafer substrate or the further layer, wherein the passivation layer is selected from the group consisting of: an aluminum containing oxide layer, an aluminum containing oxynitride layer, and mixtures thereof.
  • a method of manufacturing a solar cell layer stack includes providing a doped silicon wafer substrate, depositing a further layer on the substrate, wherein the further layer is doped for generation of a p-n-junction with the doped silicon wafer substrate, and reactive sputtering a passivation layer on the doped silicon wafer substrate or on the further layer .
  • the reactive sputtering includes flowing an unreactive gas and an oxygen containing gas, or an unreactive gas and an oxygen containing gas and a nitrogen containing gas in the processing region for depositing the passivation layer.
  • the method of manufacturing further includes annealing the passivation layer.
  • Figure 1 shows a schematic view of a layer stack for a solar cell or solar cell module, respectively, according to embodiments described herein;
  • Figure 2 shows a schematic view of a further layer stack for a solar cell or a solar cell module, respectively according to further embodiments described herein;
  • Figure 3 shows a system for depositing a layer stack according to embodiments described herein.
  • Figure 4 shows a flow chart illustrating a method of manufacturing a layer stack according to embodiments described herein.
  • Embodiments described herein refer to layer stacks for solar cells or solar modules which are based on silicon wafers. Thereby, a passivation layer is sputtered. According to typical embodiments described herein, a reactive sputtering process is used for sputtering the solar cell or the corresponding layer stack. According to yet further embodiments, which can be combined with other embodiments described herein, the middle frequency sputtering having frequencies in the range of 5 kHz to 100 kHz, for example, 30 kHz to 50 kHz, can be provided for manufacturing the solar cell layer stack. According to yet even further embodiments, typically n-doped or p-doped wafers can be used. However, especially for high efficiency solar cell modules, n-doped wafers can be used for embodiments described herein.
  • the sputtering for example the reactive sputtering, described for embodiments of passivation layers generally refers to sputtering of aluminum oxide, aluminum nitride, or aluminum oxynitride (AlO X N Y .) Such layers have been found to be especially useful for passivation of crystalline solar cells. Thereby, for example, the middle frequency process in the frequency range described above can be used to deposit a dielectric layer that contains aluminum.
  • n-type silicon wafers results in a long term stability of the cell efficiency of a solar cell.
  • silicon oxide for passivation of, for example n-type silicon wafers has not shown the desired properties.
  • an alternative passivation layer for wafer-based solar cells is desired.
  • the inventors of the present invention found that reactively sputtered aluminum containing oxide layers, or reactively sputtered aluminum containing oxynitride layers according to embodiments described herein and/or manufactured according to embodiments described herein can improve the passivation of the doped wafer substrate and, thereby, the solar cell efficiency and the long-term stability of the solar cell efficiency.
  • a doped silicon wafer substrate 101 can be used for depositing the individual layers on the substrate for forming the layer stack of a solar cell.
  • a p-type wafer or an n-type wafer can be used.
  • typically an n-type silicon wafer might be used for long term stability of high cell efficiencies.
  • a further doped silicon layer 102 is shown to be deposited on the substrate 101.
  • the doped silicon layer has a doping to generate at p-n-junction for generation of the solar cell. Accordingly, if an n-type wafer 101 is used, a p-type layer 102 is deposited. If a p-type wafer 101 is used, an n-type layer 102 is deposited to form the p-n-junction.
  • the layers stack 100 further includes a passivation layer 114 deposited on the doped silicon layer 102 and an anti-reflection coating 106.
  • a back contact 104 which is typically made of aluminum, is provided on the backside of the substrate 101.
  • a passivation layer 112 is deposited between the wafer 101 and the back contact 104.
  • the passivation layer 112 is typically deposited on the doped silicon wafer substrate 101 before the back contact 104 is provided.
  • figure 1 shows a layer stack having at least the first passivation layer on the back side of the layer stack.
  • through-contacts from the back contact 104 to the substrate 101 and contacts on the front surface of the layers stack are omitted.
  • the top side of the layer stack 100 will be referred to as the front surface of the layer stack, i.e. the surface through which photons enter the solar cell, and the bottom portion of the layers in Fig. 1 will be referred to as the back surface of the solar cell.
  • one or both of the passivation layers 112 and 114 is a sputtered aluminum oxide layer, a sputtered aluminum nitrite layer, or a sputtered aluminum oxynitride layer.
  • the sputtering can be conducted as a reactive sputtering, wherein argon as an un-reactive gas and oxygen and/or nitrogen are used as reactive gases.
  • hydrogen is not used as a process gas for reactive sputtering of the Al 2 O 3 layer.
  • the aluminum containing passivation layer can at least be provided on the p-doped side of the two layers 101 and 102, that is the doped substrate (101) and the further doped layer (102).
  • the layer 102 can also be referred to as the emitter.
  • a sputtered Al 2 O 3 layer is different from Al 2 O 3 layers deposited by other deposition methods such as ALD, SACVD, CVD, or PECVD. Whether or not an Al 2 O 3 layer is sputtered can be determined by the plurality of evaluation methods such as SEM, TEM or the like. Providing the desired layer properties for the aluminum containing dielectric passivation layers described herein is not derivable or obvious over corresponding layers provided by a different deposition method. Further, the desire to reduce the costs per watt for solar cell modules requires a deposition rate of, for example, 5 nm/min to 50 nm/min. Accordingly, for embodiments of manufacturing a layer stack for a solar cell as described herein, a deposition rate of at least 5 nm/min, typically of 5 nm/min to 40 or even 50 nm/min, is provided.
  • the Al 2 O 3 layer can be an aluminum oxide (Al 2 O 3 ) layer, Al2O X (x being in the range of e.g. 2.5 to 3), such as an Al 2 O 2.9 layer, or an aluminum oxide layer with at least 40 atomic % of oxygen.
  • Al 2 O 3 ) layer Al2O X (x being in the range of e.g. 2.5 to 3), such as an Al 2 O 2.9 layer, or an aluminum oxide layer with at least 40 atomic % of oxygen.
  • the passivation layer can be an Al 2 O X layer wherein X is from about 2.5 to 3 or the passivation layer can be an AlO X N Y layer wherein X is from about 2.5 or to 2.9.
  • the optical properties such as the refractive index of the passivation layer needs to be considered for providing a high efficiency solar cell, as the solar cell is also an optical device.
  • the Al 2 O 3 layer can have a refractive index of 1.5 to 2.1 such as, for example, 1.6, 1.65 or 1.9. Thereby if X is reduced in Al 2 O X , the refraction index is increased.
  • values of a refractive index herein the values are measured according to typical experimental setups, e.g., at a wavelength of 589 nm and under one of the accepted standard conditions for temperature and pressure.
  • the sputtering of the passivation layer can be used to adjust the refractive index of the layer by adding materials like nitrogen or by not fully oxidizing the layer.
  • argon, oxygen and nitrogen are introduced in the processing region of the sputtering process.
  • variation of those gases influences the composition of the passivation layer.
  • the gases also influence the deposition rate of the Al 2 O 3 layer during the process.
  • nitrogen can be provided at a flow rate of 0.5 to 1.1 times the flow rate of oxygen, wherein none or only a minority of the nitrogen is incorporated in the layer but serves for process improvements such as process stability, deposition rate, or the like.
  • the deposition of the passivation layer can be conducted at low powers and/or low pressures.
  • the power density can be in the range of 1 W/cm 2 to 10 W/cm 2 and/or the pressure can be in the range of 1*10 -3 mbar to 9*10 -3 mbar, for example 1.5*10 -3 mbar to 8*10 -3 mbar.
  • the power and the pressure can be used to influence the deposition rate and the refraction index of the deposited aluminum oxynitride layer.
  • an annealing step of the passivation layer is conducted.
  • air or nitrogen might be used to generate the environment during an annealing and temperatures ranging from 300°C to 1200°C can be used.
  • the temperature influences the process time. Both temperature and time may depend on the thickness of the Al2O3 layer.
  • annealing can take place from about 30 sec to about 30 min, typically from 2 min to 15 min or typically from 3 min to 8 min.
  • the front surface of the wafer substrate 101 has a structured or textured surface. This allows for better light conversion efficiency because more photons enter the active area of the solar cell layer stack.
  • the thicknesses of the passivation layer 112 and/or 114, respectively can be in a range of 10 nm to 100 nm, typically in a range of 20 nm to 80 nm.
  • the passivation layer on the back side of the solar cell layer stack i.e. the passivation layer 112, which is an AlO X N Y layers according to embodiments described herein, is provided for improvement of the cell efficiency and, particularly, the long-term cell efficiency of a solar cell module.
  • the passivation layer 114, the passivation layer 112 or both passivation layers 112 and 114 can be provided as a AlO X N Y layer as described herein.
  • the aluminum containing dielectric passivation layers can be particularly desirable for high-quality wafer-based solar cells.
  • Solar cells which are based on lower quality silicon wafers, might benefit from hydrogen that can diffuse through passivation layers, particularly from the anti-reflection coating 106. Particularly if high quality doped silicon wafer substrates are used, this diffusion of hydrogen might not be required or can even be disadvantageous. Accordingly, the AlO X N Y passivation layers according to embodiments described herein can be optimized with respect to other parameters such as long-term stability and optical behavior, because diffusion aspects do not need to be taken into account. A further advantage of the AlO X N Y passivation layers can be the high temperature stability and its inertness with respect to aluminum allowing a high deposition rate aluminum evaporation in a subsequent layer, e.g.
  • a yet further advantage of AlO X N Y passivation layers due to the high thermal stability can be that the AlO X N Y passivation layers can serve as a mask for selective front-side texturing.
  • the reactive sputtering can be conducted while the substrate is at substantially room temperature, i.e. the substrate is not additionally heated by heating sources but merely increases its temperature by the energy provided due to the deposition process.
  • the substrate might have a temperature of 50°C or below.
  • hydrogen is not used as a processing gas for the reactive sputtering of the AlO X N Y layer.
  • the aluminum containing oxide layer may also be sputtered at high temperatures such as substrate temperatures of 400 °C or less.
  • the passivation properties can be further improved by depositing another dielectric layer, for example silicon nitrite, on the AlO X N Y layer.
  • the further dielectric layer 202 such as silicon nitride layer, is provided between the doped silicon wafer substrate 101 and the back contact 104. Besides further improvement of the passivation, this might also yield to better optical properties.
  • silicon nitride can be used as the reflective layer such that photons entering the layer stack from the front surface and passing through the solar cell layer stack without generating an electron-hole-pair in the active region of the solar cell are reflected back into the active region. The probability of generation of an electron-hole pair is thereby increased.
  • the passivation layer can have a passivation assist layer, such as for example, aluminum nitride, silicon nitride or another dielectric layer.
  • a passivation assist layer such as for example, aluminum nitride, silicon nitride or another dielectric layer.
  • the deposition rate of aluminum oxide might be comparably low.
  • it might be beneficial for improvement of throughput if the aluminum containing oxide layer or the aluminum containing oxynitride layer is grown as thin as possible and is further assisted by passivation assist layer like AIN, SiN or the like.
  • the layer stack shown in Fig. 2 might have a further AIN layer between the layer 112 and the layer 202.
  • the further dielectric layer on top of the other passivation layer 114 might also improve the passivation layer properties.
  • the optical properties need to be optimized for having photons transmitted into the solar cell layer stack and not for reflecting photons as described with respect to the back side above.
  • the aluminum containing oxide layer or the aluminum containing oxynitride layer can be used for passivation of e.g., the p-doped silicon wafer substrate.
  • a passivation of the doped layer occurs also in light of the charge of the respective layer.
  • a Al containing passivation layer 114 similar to the backside passivation layer might not bee straight forward as generally the doping of layer 102 is different from the doping of the substrate 101, there might be more complex or more sophisticated silicon layer stacks with respective doping profiles that the aluminum containing oxide layer or the aluminum containing oxynitride layer can be used at a back side and at a front side of the layer stack.
  • Figure 3 illustrates a system 300 that can be used for manufacturing an AlO X N Y passivation layer according to embodiments described herein.
  • the system 300 includes two or more chambers.
  • Figure 3 illustrates the first chamber 302 and a second chamber 312.
  • the substrate 100' or a plurality of substrates which can, for example, be provided on a carrier, enters the first chamber 302 through a slit in the chamber wall.
  • the substrate might be inserted from the preceding chamber (not shown), a load lock chamber or the like.
  • the arrangement of chambers allows for low-pressure process in the chamber 302.
  • the substrate is guided on a substrate support 306.
  • the substrate moves continuously along direction 305 while deposition of the passivation layer is conducted.
  • a stationary deposition process can be provided when the substrate is first moved into the chamber 302 and deposition starts after the substrate has been positioned in the deposition region.
  • the example shown in figure 3 includes four rotatable sputtering cathodes 304, which provide the material to be sputtered, i.e. aluminum, to the processing region.
  • four or more cathodes can be provided wherein those cathodes can be planar cathodes or rotatable cathodes.
  • rotatable cathodes can result in reduced manufacturing costs and thus, an improved cost per watt of the solar cell.
  • magnetron sputtering is conducted.
  • reactive sputtering can be provided by flowing reactive gases like oxygen, oxygen containing gases, nitrogen, nitrogen containing gases, carbon containing gases and/or mixtures thereof and un-reactive gases like argon, xenon or the like (typically argon) in the processing region.
  • reactive gases like oxygen, oxygen containing gases, nitrogen, nitrogen containing gases, carbon containing gases and/or mixtures thereof and un-reactive gases like argon, xenon or the like (typically argon) in the processing region.
  • un-reactive gases like argon, xenon or the like (typically argon)
  • the substrate is transferred to the second chamber 312.
  • the substrate support 316 is provided.
  • heating units 314 and 315 are provided in the chamber in order to conduct the annealing process.
  • heating units 314 opposing the deposited surface can be provided in the chamber 312.
  • heating units 315 below the silicon wafer substrate can be provided. The latter can be provided below or within the substrate support for heating the wafer from the side opposing the deposited layer.
  • a system includes at least a deposition chamber for a AlO X N Y passivation layer and an annealing chamber for the deposited passivation layer.
  • further chambers can be provided in the system to deposit two or more of the layers in the layer stacks according to embodiments described herein, and as exemplarily shown in Figs. 1 and 2 .
  • a further chamber (not shown in Fig. 3 ) can be provided which is vacuum sealed communication with respect to the first chamber 302 such that a first passivation layer and a second passivation layer can be deposited without the substrate 100' leaving the vacuum.
  • the passivation layers is a sputtered AlO X N Y passivation layer and an anneal process component is provided after sputter deposition of the AlO X N Y passivation layer, see e.g. chamber 312 in Fig. 3 .
  • the annealing is conducted in an rapid thermal anneal chamber or the annealing can be conducted in an integrated in-situ rapid thermal anneal station post the AlO X N Y deposition, for example in the deposition chamber for depositing the passivation layer itself.
  • the system is adapted for depositing the layers of the layer stack or at least the front-side passivation layer and the back-side passivation layer of the layer stack without breaking the vacuum for the substrate.
  • adjacent chambers can be vacuum sealed with respect to each other, intermediate chambers for transfer of the substrate from a front-side passivation deposition chamber to a back-side passivation deposition layer can be provided, wherein the intermediate chamber are adapted for transferring the substrate under vacuum conditions, or different deposition regions for the front-side passivation layer and the back-side passivation layer can be provided within one chamber, which is adapted for low pressure operation as described above.
  • FIG. 4 illustrates yet further embodiments of methods of manufacturing at solar cell layer stack.
  • a substrate for example a doped wafer substrate
  • a processing system for manufacturing the layer stack In step 402 a substrate, for example a doped wafer substrate, is inserted in a processing system for manufacturing the layer stack.
  • aluminum is sputtered to deposit and aluminum containing dielectric layer, wherein in step 406 a reactive gas such as oxygen and, optionally in step 407 nitrogen as a further reactive gas, is inserted in the deposition region of the sputtering system.
  • a reactive gas such as oxygen and, optionally in step 407 nitrogen as a further reactive gas
  • un-reactive gases like argon can be inserted in the chamber, that is the processing region for the reactive sputtering.
  • Embodiments of aluminum containing oxide layers or aluminum containing oxynitride layers as described herein can provide an improvement for the efficiency of the solar cell or a solar cell module respectively.
  • an aluminum containing oxide layer or aluminum containing oxynitride layer should be an aluminum based layer.
  • the aluminum content should be at least 10 atomic %, at least 20 atomic % or even at least 30%.
  • Examples, wherein Al2O3 is reactively sputtered show an improvement of the lifetime of electron-hole-pairs in the sample.
  • the lifetime in Al2O3 after annealing was about 430 ⁇ s for a 60 nm thick Al2O3 layer and about 550 ⁇ s for a 100 nm thick Al2O3 layer.
  • the lifetime of electron-hole-pairs can be increased by a factor of 4 when the oxygen content in the process is increased from about 50 % oxygen to 100 % oxygen of the mixture of oxygen and nitrogen, wherein 100 % corresponds to Al 2 O 3 that is 60 atomic % oxygen in the layer.
  • the deposition rate of the aluminum containing oxynitride layer is reduced also by a factor of 3 to 4 when the oxygen content is increased as above. Accordingly, the flowing of nitrogen in the processing region can improve throughput by increasing the deposition rate. It is however preferred to have a high oxygen content in the sputtered layer in order to increase the lifetime of the electron-hole-pairs and thereby the cell efficiency.
  • step 408 the sputtered aluminum containing dielectric passivation layer is annealed in step 408 under conditions, which are for example described herein above.
  • step 410 the substrate is moved out of the system.
  • further deposition steps or processing steps of the layer stack for solar cell or solar cell module, respectively can be conducted before the substrate is moved out of the processing system.
  • similar steps as described with respect to step 404, 406, 407, and 408, can be provided for a second aluminum containing passivation layer such that a formula passivation layer is also provided on an opposing side of the substrate.
  • a solar cell layer stack is provided, wherein the layer stack includes a doped silicon wafer substrate; a further layer deposited on the substrate, wherein the further layer is doped for generation of a p-n-junction with the doped silicon wafer substrate; and a first sputtered and annealed passivation layer deposited on the doped silicon wafer substrate or the further layer, wherein the passivation layer is selected from the group consisting of: an aluminum containing oxide layer, an aluminum containing nitride layer, an aluminum containing oxynitride layer, and mixtures thereof.
  • the aluminum content of aluminum containing layers comprising mainly an aluminum oxide or aluminum oxynitride should be at least 10 atomic %, at least 20 atomic % or even at least 30 atomic %. According to some embodiments, which can be combined with other embodiments described herein, the aluminum content can be up to 50 %.
  • the first passivation layer can be selected from the group consisting of: the first passivation layer comprises Al 2 O X or being an Al 2 O X layer wherein X is in the range of 2 to 3, the first passivation layer having an average oxygen content of 40% atomic oxygen or more in the form of aluminum oxide, and the first passivation layer comprises AlO X N Y or being an AlO X N Y layer and wherein X is in the range of 2 to 2.9.
  • the first passivation layer can have a refractive index of 1.55 to 2.1.
  • a further sputtered and annealed passivation layer on the side of the wafer substrate opposing the first sputtered and annealed passivation layer can be provided, wherein the further passivation layer is selected from the group consisting of: an aluminum containing oxide layer, an aluminum containing oxynitride layer, and mixtures thereof.
  • the further passivation layer is selected from the group consisting of: the further passivation layer being an Al 2 O X layer wherein X is in the range of 2 to 3, the further passivation layer having an average oxygen content of 40% atomic oxygen or more in the form of aluminum oxide, and the further passivation layer being an AlO X N Y layer and wherein X is in the range of 2 to 2.9 and/or the further passivation layer has a refractive index of 1.55 to 2.1.
  • Some embodiments may additionally or alternatively have an antireflection layer covering the further passivation layer and/or a reflection layer deposited between the passivation layer and the back contact layer.
  • an n-doped silicon wafer can be used and/or the thickness of the first passivation layer and/or the thickness of the further passivation layer is about 100 nm or less, preferably the thickness is in the range of 10 nm to 100 nm.
  • a method of manufacturing a solar cell layer stack having a back contact layer includes: providing a doped silicon wafer substrate, depositing a further layer on the substrate, wherein the further layer is doped for generation of a p-n-junction with the doped silicon wafer substrate, and reactive sputtering a passivation layer on the doped silicon wafer substrate or on the further layer.
  • the reactive sputtering includes flowing an unreactive gas and an oxygen containing gas, an argon containing gas and a nitrogen containing gas, or an unreactive gas and an oxygen containing gas and a nitrogen containing gas in the processing region for depositing the passivation layer.
  • the method of manufacturing further includes annealing the passivation layer.
  • Further additional or alternative modifications include: depositing a further doped silicon layer on the doped wafer substrate to generate a p-n-junction, reactive sputtering a further passivation layer onto the further doped silicon layer, the reactive sputtering of the further passivation layer includes flowing an argon containing gas and an oxygen containing gas, or an argon containing gas and an oxygen containing gas and a nitrogen containing gas in the processing region, and annealing the further passivation layer; the reactive sputtering of the passivation layer and/or the reactive sputtering of the further passivation layer includes flowing an argon containing gas and an oxygen containing gas and a nitrogen containing gas in the processing region; and wherein the passivation layer and/or the further passivation layer is an Al 2 O X layer wherein X is in the range of 2 to 3; and/or the annealing of the passivation layer and/or the annealing of the further passivation layer is conducted at a temperature
  • a system for depositing solar cell layer stack preferably a layer stack according to embodiments described herein.
  • the system includes one or more chambers adapted for depositing at least a first and a second passivation layer under vacuum atmosphere on a doped silicon wafer substrate, wherein a first deposition region is provided for depositing the first passivation layer and the second deposition region is provided for depositing the second passivation layer.
  • the system further includes at least one sputter cathode for depositing at least a first sputtered passivation layer, wherein the passivation layer is selected from the group consisting of: an aluminum containing oxide layer, an aluminum containing oxynitride layer, and mixtures thereof, the cathode being provided for sputtering in the first deposition region or the second deposition region, and wherein the first deposition region and the second deposition region are in vacuum communication with each other such that the substrate is maintained under vacuum atmosphere while transferred from the first deposition region to the second deposition.
  • the system further comprises an anneal station adapted for annealing the first sputtered passivation layer.
  • adjacent chambers can be vacuum sealed with respect to each other for transfer between back-side and front-side deposition
  • intermediate chambers for transfer of the substrate from a front-side passivation deposition chamber to a back-side passivation deposition layer can be provided, wherein the intermediate chamber are adapted for transferring the substrate under vacuum conditions, or different deposition regions for the front-side passivation layer and the back-side passivation layer can be provided within one chamber, which is adapted for low pressure operation as described above. In the latter case, transfer of the substrate from the first deposition region to the second deposition might even be neglected.
  • the anneal station can be a rapid thermal anneal station which is provided in an anneal chamber or which is integrated for in-situ annealing after the first deposition region.
EP09168864A 2009-08-27 2009-08-27 Couche de passivation pour cellules solaires à base de plaquette en silicon crystallin et son procédé de fabrication Withdrawn EP2290704A1 (fr)

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EP09168864A EP2290704A1 (fr) 2009-08-27 2009-08-27 Couche de passivation pour cellules solaires à base de plaquette en silicon crystallin et son procédé de fabrication
US12/555,131 US20110048515A1 (en) 2009-08-27 2009-09-08 Passivation layer for wafer based solar cells and method of manufacturing thereof
PCT/EP2010/062348 WO2011023701A2 (fr) 2009-08-27 2010-08-24 Couche de passivation pour piles solaires à base de tranche et procédé de fabrication de celle-ci
TW099128703A TW201128780A (en) 2009-08-27 2010-08-26 Passivation layer for wafer based solar cells and method of manufacturing thereof

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