EP2262750A1 - Mousse avec résistance aux flammes élevée et densité faible - Google Patents

Mousse avec résistance aux flammes élevée et densité faible

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Publication number
EP2262750A1
EP2262750A1 EP09717700A EP09717700A EP2262750A1 EP 2262750 A1 EP2262750 A1 EP 2262750A1 EP 09717700 A EP09717700 A EP 09717700A EP 09717700 A EP09717700 A EP 09717700A EP 2262750 A1 EP2262750 A1 EP 2262750A1
Authority
EP
European Patent Office
Prior art keywords
foam
weight
parts
curing
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09717700A
Other languages
German (de)
English (en)
Inventor
Klaus Hahn
Armin Alteheld
Benjamin Nehls
Bernhard Schmied
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP09717700A priority Critical patent/EP2262750A1/fr
Publication of EP2262750A1 publication Critical patent/EP2262750A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/04—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by dissolving-out added substances
    • C04B38/045—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by dissolving-out added substances the dissolved-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a prepreg obtained by bonding together dissolvable particles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0045—Polymers chosen for their physico-chemical characteristics
    • C04B2103/0065—Polymers characterised by their glass transition temperature (Tg)
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52—Sound-insulating materials

Definitions

  • the invention relates to a process for producing a foam by curing a blowing or blowing foam from an aqueous composition, wherein the aqueous composition
  • Inorganic foams based on aluminosilicates are known, for example, from EP-A 1 423 346 and WO 2007/048729.
  • WO 2007/023089 describes that expandable polystyrene (EPS) can be bonded to form a foam sheet by the use of a binder based on an aqueous silicate solution with the addition of a hydrophobic polymer dispersion. This is characterized by low flammability. Due to the high density of the water-containing binder system consisting essentially of inorganic constituents, the resulting sheets have significantly higher densities than standard EPS sheets without binders. As a result, the higher densities lead to a poorer handling of the resulting molding compositions and a poorer thermal insulation.
  • EPS expandable polystyrene
  • the object of the present invention was to find a foam with high flame resistance and low density, and a process for its preparation.
  • component A) 40 to 95 parts by weight, preferably 50 to 70 parts by weight of an alkali metal silicate solution, in particular water glass solution having a water content of 40 to 90, preferably 50 to 70 wt .-%, used.
  • component B) 0 to 60 parts by weight, preferably 30 to 50 parts by weight of a powdered alkali silicate, in particular water glass powder having a water content of 0 to 30, preferably 1 to 25 wt .-%.
  • the surfactant system should be compatible with the polymer dispersion.
  • Particularly advantageous surfactant systems are those which are suitable for the production and stabilization of aqueous foams in alkaline media and at high electrolyte concentrations.
  • surfactants anionic, cationic, nonionic or ambivalent surfactants or mixtures thereof can be used. Both low molecular weight and polymeric surfactants can be used.
  • Nonionic surfactants are, for example, addition products of alkylene oxides, in particular ethylene oxide, propylene oxide and / or butylene oxide with alcohols, amines, phenols, naphthols or carboxylic acids.
  • the surfactants used are advantageously addition products of ethylene oxide and / or propylene oxide with alcohols containing at least 10 carbon atoms, the addition products containing 3 to 200 moles of ethylene oxide and / or propylene oxide per mole of alcohol.
  • the addition products contain the alkylene oxide units in the form of blocks or in random distribution.
  • nonionic surfactants are the addition products of% mol of ethylene oxide with 1 mol of tallow fatty alcohol, reaction products of 9 mol of ethylene oxide with 1 mol of tallow fatty alcohol and addition products of 80 mol of ethylene oxide with 1 mol of tallow fatty alcohol.
  • nonionic surfactants consist of reaction products of oxo alcohols or Ziegler alcohols with 5 to 12 moles of ethylene oxide per mole of alcohol, in particular with 7 moles of ethylene oxide. Further commercially available nonionic surfactants are obtained by ethoxylation of castor oil. For example, 12 to 80 moles of ethylene oxide are added per mole of castor oil.
  • reaction products of 18 mol of ethylene oxide with 1 mol of tallow fatty alcohol the addition products of 10 mol of ethylene oxide with 1 mol of a C13 / C15 oxoalcohol, or the reaction products of 7 to 8 moles of ethylene oxide with 1 mol of a Ci 3 / Ci5 oxo alcohol.
  • suitable nonionic surfactants are phenol alkoxylates such as p-tert-butylphenol, which is reacted with 9 moles of ethylene oxide, or methyl ethers of reaction products of 1 mole of a Ci2 / Ci8 alcohol and 7.5 moles of ethylene oxide.
  • nonionic surfactants are alkoxylated, preferably ethoxylated silicones. Preference is given here to water-soluble silicone surfactants obtained by reacting short-chain silicones (diemthicones) with a high molar proportion of ethylene oxide.
  • the surfactants described above can be converted, for example, by esterification with sulfuric acid in the corresponding sulfuric acid half esters.
  • the sulfuric acid half esters are used in the form of the alkali metal or ammonium salts as anionic surfactants.
  • Suitable anionic surfactants are, for example, alkali metal or ammonium salts of sulfuric monoesters of addition products of ethylene oxide and / or propylene oxide with fatty alcohols, alkali metal or ammonium salts of alkylbenzenesulfonic acid or alkylphenol ether sulfates. Products of the type mentioned are commercially available.
  • cationic surfactants are suitable. Examples of these are the dimethylsulfate-quaternized reaction products of 6.5 mol of ethylene oxide with 1 mol of oleylamine, distearyldimethylammonium chloride, lauryltrimethylammonium chloride, cetylpyridinium bromide and quaternized stearic acid triethanolamine ester with dimethyl sulfate. Due to interactions with anionic silicates only cationic surfactants are often not suitable for foam stabilization. The combination of cationic surfactants with anionically stabilized polymer latex can lead to destabilization of the dispersion.
  • the surfactants are contained in the aqueous composition preferably in an amount in a range of 0.1 to 15 parts by weight, more preferably in a range of 1 to 10 parts by weight, each based on the weight of the aqueous composition.
  • Stabilizers, thickeners, fillers or cell nucleating agents or mixtures thereof can be used as adjuvants in the process according to the invention. It may be advantageous to use additional thixotropic agents which, for example, allow control of the viscosity of the binder to be foamed.
  • These additives can be organic or inorganic in nature. Frequently used additives are, for example, phyllosilicates, polyphosphates, polyvinyl alcohol, polyvinylpyrrolidone, etc. It is advantageous if these additives have no negative effects with regard to the fire properties.
  • Thickeners are used, for example, to optimize the foam structure and to improve foam stability. Suitable thickeners are all known natural and synthetic polymers which greatly increase the viscosity of an aqueous system. These may be water-swellable or water-soluble synthetic or natural polymers. As thickeners and powdery superabsorbent are suitable.
  • the fillers used are preferably chalks, concreteites, talc, gypsum, aluminum oxide, aluminum hydroxides, boric acid and borates, cement, silica gels or silicic acid, activated carbons, graphites, calcium oxide, zinc oxide, aluminophosphates, boron phosphates, pigments such as titanium dioxide and iron oxide or mixtures thereof become. It may consist of intumescent additives, e.g. Expanded graphite or carbohydrates, are used.
  • a clay mineral can be added as auxiliary to the aqueous composition.
  • Halloysite 8 ISi 4 Oi 0] ⁇ 2 H 2 O, montmorillonite (smectite) AUt (OH) (AI
  • kaolin is particularly preferably used in general, the solid-related weight ratio of clay mineral to alkali metal silicate in the aqueous composition ranges
  • dispersing aids for example Sokalan types from BASF SE
  • Sokalan types from BASF SE
  • the aqueous composition may contain hydrophobizing additives, for example paraffins, silicones, aluminum stearates or the like. Care must be taken in these additions that they do not lead to defoaming.
  • hydrophobizing additives for example paraffins, silicones, aluminum stearates or the like. Care must be taken in these additions that they do not lead to defoaming.
  • the auxiliary agents are preferably contained in the aqueous composition in an amount in a range of 0.01 to 80 parts by weight, more preferably in a range of 0.05 to 10 parts by weight, and more preferably in a range of 0.1 to 5 parts by weight, respectively based on the weight of the aqueous composition.
  • An increase in viscosity for better foamability can also be achieved by the addition of electrolytes, special surfactants or by a change in the pH, the temperature or the concentration.
  • component D) 5 to 40 parts by weight, preferably 10 to 30 parts by weight of a polymer dispersion having a solids content of 10 to 60 wt .-%, preferably 20 to 50 wt .-%.
  • the aqueous composition comprises an aqueous polymer dispersion, which, after drying, to a dried polymer film having a glass transition temperature ranging from -60 to +100 0 C, preferably in the range from -30 ° to + 80 0 C, more preferably in the range of -10 ° to + 60 0 C .
  • the glass transition temperature can be determined by differential scanning calorimetry (DSC).
  • dispersions of block copolymers or mixtures of different polymer dispersions which have two or more glass transition temperatures.
  • a combination of low film formation temperature with increased mechanical stability, better compatibility or increased hydrophobicity may be possible.
  • component D) are, for example, polymers based on monomers such as vinyl aromatic monomers, such as ⁇ -methylstyrene, p-methylstyrene, ethylstyrene, tert-butylstyrene, vinylstyrene, vinyltoluene, 1, 2-diphenylethylene, 1, 1-diphenylethylene, alkenes, such as Ethylene or propylene, dienes, such as 1, 3-butadiene, 1, 3-pentadiene, 1, 3-hexadiene, 2,3-dimethylbutadiene, isoprene, piperylene or isoprene, ⁇ , ß-unsaturated carboxylic acids, such as acrylic acid and methacrylic acid, their Esters, in particular alkyl esters, such as Ci-io-alkyl esters of acrylic acid, in particular the butyl ester, preferably n-butyl acrylate, and the Ci-10-alkyl esters
  • the polymers may optionally contain from 1 to 5% by weight of comonomers, such as (meth) acrylonitrile, (meth) acrylamide, ureido (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, Acrylamidepropanesulfonic acid, methylolacrylamide or the sodium salt of vinylsulfonic acid.
  • comonomers such as (meth) acrylonitrile, (meth) acrylamide, ureido (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, Acrylamidepropanesulfonic acid, methylolacrylamide or the sodium salt of vinylsulfonic acid.
  • the polymers are preferably composed of one or more of the monomers styrene, butadiene, acrylic acid, methacrylic acid, C 1-4 -alkyl acrylates, C 1-4 -alkyl methacrylates, acrylamide, methacrylamide and methylolacrylamide.
  • Particularly suitable polymers are acrylate resins which are used according to the invention as aqueous polymer dispersions, if appropriate additionally with hydraulic binders based on cement, lime cement or gypsum.
  • Suitable polymer dispersions are, for example, by free-radical emulsion polymerization of ethyl- unsaturated monomers, such as styrene, acrylates or methacrylates, as described in WO 00/50480.
  • acrylates or styrene acrylates which are composed of the monomers styrene, n-butyl acrylate, methyl methacrylate (MMA), methacrylic acid, acrylamide or methylolacrylamide.
  • the polymer dispersion is prepared in a manner known per se, for example by emulsion, suspension or dispersion polymerization, preferably in the aqueous phase. It is also possible to prepare the polymer by solution or bulk polymerization, if appropriate to divide it and then to disperse the polymer particles in water in the customary manner. In the polymerization, the initiators, emulsifiers or suspension aids, regulators or other hydrogens customary for the particular polymerization process are used; and polymerization is carried out continuously or batchwise at the temperatures and pressures customary for the particular process in customary reactors.
  • the aqueous composition consists of the components A), B) and D) or A), C) and D) or A), B), C) and D), wherein the components A) and B) to 100 parts sum up.
  • the components A), B), C) and D) can be mixed in any order.
  • foam or blowing foam before curing foam particles can be added from a thermoplastic polymer.
  • the foam particles By adding the foam particles, the insulating performance of the inorganic foam can be improved.
  • the foam particles may be added to the aqueous composition before or after foaming.
  • the foam particles are preferably mixed last with the finished mixture of A), B), C) and D).
  • the blow-up foam is preferably first produced, which is then mixed with the foam particles.
  • the foam particles are preferably added to the aqueous composition of components A), B), C) and D) and the mixture is subsequently foamed.
  • Expanded polyolefin in particular expanded polypropylene (EPP), expanded polyethylene (EPE) or prefoamed particles of expandable styrene polymers (EPS) are preferably used as foam particles. It is also possible to use combinations of different foam particles. Preferably, they are thermoplastic materials. It is also possible to use crosslinked polymers, for example radiation-crosslinked polyolefin foam bodies.
  • the foamed particles based on styrene polymers can be obtained by prefetching EPS with hot air or steam in a prefoamer to the desired density. By prefoaming once or several times in a pressure or continuous prefoamer, final bulk densities of less than 10 g / l can be obtained.
  • athermal solids such as carbon black, aluminum, graphite or titanium dioxide
  • foam particles based on ⁇ -methylstyrene / acrylonitrile copolymer (AMSAN) with high solvent resistance or elastic foam particles based on multiphase blends of styrene polymers and polyolefins can be used.
  • the process can also be used crushed foam particles made of recycled foam moldings.
  • the comminuted foam recycled to 100% or z. B. in proportions of 2 to 90 wt .-%, in particular 5 to 25 wt .-% are used together with virgin material, without significantly affecting the strength and mechanical properties.
  • the foam particles may be equipped with a surface impregnation, for example to improve the connection to the hydrous system.
  • hybrid foams can be obtained from the substantially organic foam particles and the substantially inorganic foam matrix formed from the aqueous composition. Preference is given to hybrid foams which contain 50 to 99% by volume, preferably 60 to 80% by volume, of foamy particles of thermoplastic polymer and 1 to 50% by volume, preferably 20 to 40% by volume, of a foam on base. of silicates obtainable by curing a blowing or blowing foam from the above-described aqueous composition.
  • the density of the foam based on silicates is generally below 1000 kg / m 3 , preferably in the range of 100 to 500 kg / m 3 .
  • the hybrid foam has a density in the range of 10 to 1000 kg / m 3 , preferably in the range of 100 to 300 kg / m 3 .
  • the foaming of the aqueous composition is preferably carried out by mechanical action, in particular shearing, more preferably by vigorous stirring or mixing with mixing with air.
  • the introduction of gas bubbles into the aqueous composition takes place, for example, by means of impact, shaking, stirring or whipping devices.
  • Suitable inert gases are, for example, nitrogen, carbon dioxide, helium, neon and argon.
  • a gas preferably air
  • a gas is introduced into the aqueous composition, optionally with additives and before the introduction of polymer foam particles.
  • This can be done for example by a suitable mixer, dispenser or a porous membrane.
  • thermoplastic foam particles for example prefoamed EPS particles, can be introduced into the formed foaming foam and foamed freely in a mold or optionally compressed. Pressing is particularly recommended for higher proportions of foam particles.
  • the binder can also be supplied under pressure, a gaseous substance as a physical blowing agent, which leads to an increase in volume at a relaxation to atmospheric pressure. It is also possible to use a liquid which is converted into the gaseous state of matter by changes in pressure or temperature.
  • the substance can be present homogeneously dissolved in the essentially aqueous binder (for example, methanol, ethanol, isopropanol, CO 2, formic acid mixtures). ethyl ester or formic acid ethyl ester or form separate phases, for example pentane, etc. In the case of multiphase systems, the use of a dispersant is advantageous.
  • chemical blowing agents which are e.g. form a gas due to chemical decomposition processes; for example, carbonates, azides, hydrazides, hydroxides or peroxides.
  • the release of the gas may be by reaction of one, two or more components and by changing the environmental conditions, e.g. the temperature, to be initiated.
  • Further examples are acids or acid anhydrides in combination with carbonates or isocyanates in combination with water.
  • the solidification of the inorganic portion can be achieved by gelation and SiO 2 formation, which ideally causes solidification after the foam is formed.
  • the curing methods customary for water glass can be used, for example ester hardening by means of triacetin, diacetin or the like, aluminum-containing salts, CO 2 introduction or acid formation from anhydrides.
  • organic systems which may also be part of a hydrophobic acting system. It is advantageous if these systems are soluble or dispersible in aqueous media. Examples of such systems are self-crosslinking dispersions, e.g. by ester formation or water-dispersible isocyanates in combination with functional dispersions or dissolved reactants.
  • crosslinking isocyanates having a functionality of more than 1.
  • the reaction can be controlled. Due to the simultaneous elimination of CO 2 , the isocyanates can be used simultaneously as a blowing agent and hardener for the water glass-containing inorganic foam. In this way one obtains particularly temperature-stable foams.
  • the crosslinking takes place below the softening temperature of the particle foam.
  • An adjustment of the reaction can be made via the choice of reactants, their concentration and catalysts.
  • water-dispersible isocyanates can be reacted with amino-functionalized polymers, the reaction rate being significantly higher with primary amines than with secondary amines. Both reactions are faster than a reaction with water.
  • the heating of the foamed composition is preferably carried out in an oven, a drying oven, with a hot gas stream, by infrared radiation or by microwave radiation.
  • the microwave radiation is not only suitable for curing the foam, but can also foaming or NachWebumen the dried or still wet aqueous composition of components A, B and C, which is optionally mixed with foam particles.
  • the foamed composition is first converted into a shaped body before it is heated.
  • the aqueous composition is converted before foaming into a shaped body and then foamed in this shaped body.
  • foam-like structures with a defined spatial structure can then be obtained.
  • the thickness, length and width of the foam sheets can vary within wide limits and is limited by the size and closing force of the tool.
  • the thickness of the foam sheets is usually 1 to 500 mm, preferably 10 to 300 mm.
  • the density of the foam moldings according to DIN 53420 is generally 10 to 500 kg / m 3 , preferably 30 to 300 kg / m 3
  • the curing and drying of the foamed binder may optionally be continuous or batch by means of a furnace or in hot air stream.
  • the curing of the foam is preferably carried out with air or nitrogen at a temperature in the range of 0 to 80 0 C.
  • the curing and / or foaming can be carried out by irradiation with microwaves.
  • the sintering and / or foaming can take place continuously or discontinuously under the action of microwave energy.
  • microwaves are used in the frequency range between 0.85 and 100 GHz, preferably 0.9 to 10 GHz and irradiation times between 0.1 and 15 minutes. It is also possible to produce foam boards with a thickness of more than 5 cm.
  • the irradiation of the mixture to be hardened can be carried out in a treatment room.
  • a discontinuous embodiment of the treatment room is closed on all sides.
  • the mixture would be carried past the radiation source on a continuously moving belt. Leg- If the prefoamed foam particles still contain propellant, which boils below the evaporation temperature of water, the resulting steam can be used to foam the EPS spheres.
  • foam-particle-containing foams by means of microwave radiation is particularly preferred in the production of foam sheets having a thickness of more than 5 cm. Due to the material density and the insulating effect of optionally added foam particles is a solely thermal curing of the material (crosslinking of the matrix material) significantly delayed.
  • a preferred method (A1) using a blown foam comprises the steps:
  • prefoaming of expandable styrene polymers into foam particles ii) preparation of a blowing foam from an aqueous composition of components A), B), C) and D), iii) adding the foam particles prefoamed in stage i) to that in stage ii iv) curing of the resulting foam with air or nitrogen at a temperature in the range of 80 ° C. or by means of microwaves.
  • the inorganic foam obtainable by the process according to the invention is distinguished by high flame resistance and low density. Pressing under high pressure in the mold is not necessary.
  • Another method (A2) for producing the hybrid foam according to the invention using microwave radiation comprises the steps:
  • thermoplastic foam particles The purely inorganic foams obtainable without the addition of thermoplastic foam particles generally have better flame resistance, mechanical properties and abrasiveness.
  • the thermoplastic foam particles are extracted.
  • the thermal decomposition or extraction of the particle foams can also take place from a silicate matrix having a high density.
  • Suitable particle foam-containing plates are described, for example, in WO 2007/023089 or PCT / EP2007 / 060541.
  • the organic component is removed, leaving behind a substantially inorganic foam structure whose cavities are predetermined by the particle size of the previously used organic foam particles. If one uses foam particles of EPS cavities of 0.4 to 10 mm, preferably 1-6 mm can be produced.
  • the foam moldings obtained in this way (“lost foam”) are preferably postcured, for example by acid catalysis or thermal sintering.
  • foam bodies described above can also be used as "sieves" for high-temperature applications in addition to the construction applications described here, because the use of different foam particle sizes makes it possible to set the sieve size very precisely.
  • Suitable solvents are e.g. Dichloromethane or toluene, in particular to dissolve the preferably used foam particles of expandable polystyrene from the inorganic matrix. Due to the usually weight moderately low levels of foam particles in the inorganic foam, small amounts of solvents are sufficient.
  • the solvents can be recycled in a cycle, for example by extraction in a Soxhlet apparatus.
  • the inventive method is suitable for the production of simple or complex foam moldings, such as plates, blocks, tubes, rods, profiles, etc.
  • plates or blocks which can be subsequently sawed or cut into sheets, produced.
  • they can be used in construction for the insulation of exterior walls or flat roofs.
  • They are particularly preferred as the core layer for producing sandwich elements, for example used so-called structural insulation panels (SIP), which are used for the construction of cold stores or warehouses.
  • SIP structural insulation panels
  • pallets of foam as a substitute for wooden pallets, cover panels, refrigerated containers, caravans. Due to their excellent fire resistance, they are also suitable for airfreight.
  • the foam obtained according to Example 1 was in the sequence about 1 min. irradiated in the microwave (600 W), the foam continued to foam and the density dropped to about 200 g / L.
  • Examples 1 and 2 were also performed with Lutensol® GD70 additions of 2-10 parts and with EPS additions of 2-8 parts.
  • Example 5 Impact foam of the aqueous waterglass solution

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

L'invention concerne un procédé de fabrication d'une mousse par durcissement d'une mousse battue ou expansée à partir d'une composition aqueuse, la composition aqueuse contenant A) 40 à 95 parts en poids d'une solution de silicate alcalin ayant une teneur en eau de 40 à 90 % en poids, B) 0 à 60 parts en poids d'un silicate alcalin sous forme de poudre ayant une teneur en eau de 0 à 30 % en poids, C) 0 à 15 parts en poids d'un tensioactif, D) 5 à 40 parts en poids d'une dispersion polymère aqueuse ayant une teneur en matières solides de 10 à 60 % en poids, ainsi que les mousses pouvant être obtenues par le procédé et leur utilisation sous forme de plaque isolante.
EP09717700A 2008-03-04 2009-03-02 Mousse avec résistance aux flammes élevée et densité faible Withdrawn EP2262750A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP09717700A EP2262750A1 (fr) 2008-03-04 2009-03-02 Mousse avec résistance aux flammes élevée et densité faible

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08152240 2008-03-04
PCT/EP2009/052428 WO2009109537A1 (fr) 2008-03-04 2009-03-02 Mousse avec résistance aux flammes élevée et densité faible
EP09717700A EP2262750A1 (fr) 2008-03-04 2009-03-02 Mousse avec résistance aux flammes élevée et densité faible

Publications (1)

Publication Number Publication Date
EP2262750A1 true EP2262750A1 (fr) 2010-12-22

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP09717700A Withdrawn EP2262750A1 (fr) 2008-03-04 2009-03-02 Mousse avec résistance aux flammes élevée et densité faible

Country Status (7)

Country Link
US (1) US20110034571A1 (fr)
EP (1) EP2262750A1 (fr)
KR (1) KR20110002019A (fr)
CN (1) CN102089259A (fr)
AU (1) AU2009221166A1 (fr)
RU (1) RU2010140203A (fr)
WO (1) WO2009109537A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2501749B1 (fr) 2009-11-20 2013-09-18 Basf Se Mousses de résine contenant des microsphères creuses
US20110189464A1 (en) * 2010-02-03 2011-08-04 Basf Se Melamine-formaldehyde foam with built-in microcapsules
US8937106B2 (en) 2010-12-07 2015-01-20 Basf Se Melamine resin foams with nanoporous fillers
PL226081B1 (pl) 2012-02-16 2017-06-30 Politechnika Łódzka Material medyczny i sposob jego wytwarzania oraz zastosowanie materialu medycznego
DK2897922T3 (en) * 2012-09-24 2016-11-14 Basf Se SYSTEM AND PROCEDURE FOR MANUFACTURING IN-SITU FOAM
AU2016343601B2 (en) * 2015-10-20 2020-06-25 Basf Se System and method for producing in-situ foam
CN109206616A (zh) * 2018-08-09 2019-01-15 苏州思德新材料科技有限公司 一种具有阻燃性能的有机硅泡沫稳定剂的制备方法
KR102301894B1 (ko) * 2019-04-04 2021-09-14 송연배 세라믹과 실리게이트로 조성된 불연 플라스틱의 제조방법
CN111977976B (zh) * 2020-08-31 2023-02-24 武汉佳宝华节能科技有限公司 一种环保型泡沫玻璃保温板及其生产工艺
CN114014693A (zh) * 2021-11-25 2022-02-08 江西九由航空装备有限公司 航空发动机尾喷管高性能专用隔热件

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1592824A (fr) * 1967-11-24 1970-05-19
DE2165912A1 (de) * 1971-12-31 1973-07-05 Bayer Ag Verfahren zur herstellung von schaumstoffen
US5242494A (en) * 1990-08-10 1993-09-07 British Technology Group Ltd. Foamable compositions
DE10141777A1 (de) * 2001-08-25 2003-03-06 Basf Ag Elastischer anorganischer Schaum
RU2417238C9 (ru) * 2005-08-23 2012-04-27 Басф Се Способ получения пенопластовых плит

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2009109537A1 *

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RU2010140203A (ru) 2012-04-10
KR20110002019A (ko) 2011-01-06

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