EP2235484A2 - Dispositif de spectroscopie en longueur d'onde à filtres intégrés - Google Patents
Dispositif de spectroscopie en longueur d'onde à filtres intégrésInfo
- Publication number
- EP2235484A2 EP2235484A2 EP09720812A EP09720812A EP2235484A2 EP 2235484 A2 EP2235484 A2 EP 2235484A2 EP 09720812 A EP09720812 A EP 09720812A EP 09720812 A EP09720812 A EP 09720812A EP 2235484 A2 EP2235484 A2 EP 2235484A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- filters
- filter
- detector
- filtering module
- ribbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000004611 spectroscopical analysis Methods 0.000 title claims abstract description 10
- 239000012528 membrane Substances 0.000 claims abstract description 25
- 238000001914 filtration Methods 0.000 claims abstract description 23
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 101100077149 Human herpesvirus 8 type P (isolate GK18) K5 gene Proteins 0.000 claims abstract description 4
- 102100038546 Fibronectin type III and SPRY domain-containing protein 1 Human genes 0.000 claims abstract description 3
- 101001030521 Homo sapiens Fibronectin type III and SPRY domain-containing protein 1 Proteins 0.000 claims abstract description 3
- 125000006850 spacer group Chemical group 0.000 claims description 12
- 238000001514 detection method Methods 0.000 claims description 5
- 238000005516 engineering process Methods 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 5
- 238000003384 imaging method Methods 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 2
- 238000000151 deposition Methods 0.000 description 7
- 238000005530 etching Methods 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 101001022847 Homo sapiens E3 ubiquitin-protein ligase MYCBP2 Proteins 0.000 description 4
- 101001126102 Homo sapiens Pleckstrin homology domain-containing family B member 1 Proteins 0.000 description 4
- 102100030462 Pleckstrin homology domain-containing family B member 1 Human genes 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000008520 organization Effects 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 101100491376 Arabidopsis thaliana APL gene Proteins 0.000 description 2
- 101100243901 Halobacterium salinarum (strain ATCC 700922 / JCM 11081 / NRC-1) phr gene Proteins 0.000 description 2
- 101100385336 Natronomonas pharaonis (strain ATCC 35678 / DSM 2160 / CIP 103997 / JCM 8858 / NBRC 14720 / NCIMB 2260 / Gabara) cry gene Proteins 0.000 description 2
- 101150049436 PHR2 gene Proteins 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 102100031476 Cytochrome P450 1A1 Human genes 0.000 description 1
- 102100026533 Cytochrome P450 1A2 Human genes 0.000 description 1
- 101000941690 Homo sapiens Cytochrome P450 1A1 Proteins 0.000 description 1
- 101000855342 Homo sapiens Cytochrome P450 1A2 Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000012804 iterative process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/12—Generating the spectrum; Monochromators
- G01J3/26—Generating the spectrum; Monochromators using multiple reflection, e.g. Fabry-Perot interferometer, variable interference filters
Definitions
- the present invention relates to a wavelength spectroscopy device.
- the spectrometric analysis aims in particular the search for chemical constituents used in the composition of a solid, liquid or gaseous medium. This involves recording the absorption spectrum in reflection or transmission of this medium. The light that interacts with it is absorbed in certain wavelength bands. This selective absorption is a signature of some or all of the constituents of the medium.
- the range of wavelengths of the spectrum to be measured may belong to ultra-violet and / or visible radiation and / or infrared (near, medium, far).
- a first solution uses the network spectrometer.
- the network acting as a filter is disposed at a substantial distance from the detector. The resolution is even better than this distance is important. It follows that this device can not be miniaturized if one wishes to maintain an acceptable resolution. In addition, the adjustment of this device is complicated and its stability is delicate because it requires precise optical alignment.
- Most other spectrometers use at least one Fabry-Perot filter.
- such a filter is a blade with a parallel face of a material (usually of low refractive index such as air, silica, ...) called spacing membrane (more commonly "spacer” in English terminology -Saxon), this membrane appearing between two mirrors. It is often performed by deposition of thin layers under vacuum.
- the first mirror consists of m alternations of layers of optical thickness ⁇ / 4 of a high index material H and a low index material.
- the spacing membrane frequently consists of 2 layers of the low index material B of optical thickness ⁇ / 4.
- the second mirror is symmetrical with the first.
- the modification of the geometric thickness of the spacer membrane makes it possible to tune the filter to the central wavelength for which the optical thickness is a multiple of ⁇ / 2.
- a finite number of relatively thin bandwidths i.e., a discrete as opposed to a continuous spectrum is sufficient to identify the desired constituents, so that the first solution mentioned above is not optimized.
- a second known solution provides a filtering module comprising a band filter to be analyzed. If the number of bands is n, the production of n filters thus passes through n separate fabrications in vacuum deposition. The cost is thus very important (and almost proportional to the number n of bands) for the small series and becomes really interesting only for sufficiently large series. In addition, here too the possibilities of miniaturization are very limited and it is difficult to envisage a large number of filters.
- a third known solution implements a Fabry-Perot filtering module, the two mirrors being no longer parallel but arranged in a wedge-shaped manner with respect to the profile in a plane perpendicular to the substrate.
- this plane marked Oxy the axes Ox and Oy respectively being collinear and perpendicular to the substrate, the thickness according to Oy of the spacer membrane varies linearly as a function of the position according to Ox where it is measured.
- the subject of the present invention is therefore a wavelength spectroscopy device making it possible to measure a spectrum in transmission or in reflection composed of a finite number of filters, this device having a great mechanical simplicity and, consequently, a cost of the most limited.
- a wavelength spectroscopy device comprises on a substrate a filtering module consisting of two mirrors separated by a spacer membrane; in addition, this filtering module includes a plurality of interferential filters, the thickness of the spacer membrane being constant for a given filter and varying from one filter to another.
- At least one of these filters has a band-pass transfer function.
- At least some of these filters are aligned in a first ribbon.
- at least some of these filters are aligned in a second ribbon parallel to and disjoint from the first ribbon.
- At least two of these adjacent filters are separated by a crosstalk barrier.
- the device further comprises a detector comprising a plurality of compartments, each active compartment being dedicated to one of the filters and optically aligned therewith for detecting the radiation that it emits by means of at least one detection cell.
- a detector comprising a plurality of compartments, each active compartment being dedicated to one of the filters and optically aligned therewith for detecting the radiation that it emits by means of at least one detection cell.
- the device comprises means for producing a signal by combining the output signals of these cells.
- the detector is integrated in CMOS technology.
- the substrate is constituted by an interface appearing on this detector.
- the device comprises an imaging optics to adapt the size of the filters to that of the detector.
- FIG. 1 the block diagram of a one-dimensional filtering module, more particularly:
- FIG. 1a a view from above of this module
- FIGS. 2a to 2c three steps of a first embodiment of this filtering module
- FIG. 3a to 3fc six steps of a second embodiment of this filtering module
- FIG. 4 the block diagram of a two-dimensional filtering module
- FIGS. 5a to 5f each a mask that can be used during an etching step
- FIG. 6 is a diagram of a filter module with 64 filters provided with a screening grid
- FIG. 7 the diagram of a spectroscopy device comprising a filter module directly associated with a detector
- FIG. 8 the diagram of a spectroscopy device comprising a filtering module associated with a detector by means of an imaging optic.
- a filtering module comprises three interference filters of the Fabry-Perot type FP1, FP2, FP3 successively aligned so that they form a ribbon.
- This module is formed by the stack on a substrate SUB, glass or silica, for example, a first mirror M1, a spacing membrane SP and a second mirror MIR2.
- the spacer membrane SP which defines the central wavelength of each filter is therefore constant for a given filter and varies from one filter to another. Its profile has a staircase shape because each filter has a substantially rectangular surface.
- a first method of producing the filtering module in thin film technology is given by way of example.
- the first mirror MIR1 is first deposited on the substrate SUB and then a layer or set of dielectric layers TF called to define the spacing membrane SP. With reference to FIG. 2b, this dielectric is etched:
- the spacer membrane SP at the first filter FP1 has the thickness of the deposit.
- the second mirror MIR2 is deposited on the spacing membrane SP to finalize the three filters.
- Spacing membrane SP can be obtained by deposition of a TF dielectric then successive etchings as presented above, but it can also be obtained by several successive deposition of thin layers.
- a second method of producing the filtering module is now exposed.
- thermal oxidation of a silicon SIL substrate is first performed on its lower face OX1 and on its upper face OX2.
- the lower faces OX1 and upper OX2 of the substrate are respectively covered with a lower layer PHR1 and a top layer PHR2 of photoresist. Then, a rectangular opening is made in the lower layer PHR1 by photolithography.
- the thermal oxide of the lower face OX1 is etched in line with the rectangular opening made in the lower layer.
- SIL crystal orientation 1 - 0 - 0 for example
- the thermal oxide of the lower face OX1 serving as a mask and that of the upper face OX2 serving as etch stop layer.
- It can be either a wet etching with a solution of potash (KOH) or trimethyl ammonium hydroxyl (TMAH) or a dry plasma etching. he As a result of this operation, only an oxide membrane remains at the bottom of the rectangular opening.
- this oxide is etched:
- the first M1 and second M2 mirrors are deposited on the lower faces OX1 and upper OX2 of the substrate SIL.
- the embodiment of the filtering module may optionally be completed by depositing a passivation layer (not shown) on one and / or on the other of the lower OX1 and upper OX2 faces.
- the invention therefore makes it possible to produce a set of aligned filters, which filters can thus be referenced in a one-dimensional space.
- the invention also makes it possible to organize such filters in a two-dimensional space. Such an organization is often called matrix.
- the first ribbon which appears at the top of the figure, corresponds to the first line of a matrix and includes the filters IF11 to IF14.
- the second, the third, and the fourth ribbon respectively comprise filters IF21 to IF24, filters IF31 to IF34, respectively filters IF41 to IF44.
- the organization is called matrix because the filter IFjk belongs to the jth horizontal ribbon and also to a kth vertical ribbon which includes the filters IF1k, IF2k, ..., IF4k.
- the method of producing the filtering module may be analogous to any one of the two methods described above.
- the second mirror is deposited on the spacing membrane thus etched to finalize the 16 filters of the matrix 4-4.
- the matrix 4-4 referred to above is transformed into a matrix 8-8 comprising 64 interference filters.
- the fifth mask MA5 as a logical continuation of the first MA1 and second MA2 masks, represents a horizontal alternation of four black ribbon - white ribbon pairs.
- the sixth mask MA6 as a logical continuation of the third MA3 and fourth MA4 masks, represents a vertical alternation of four black ribbon - white ribbon pairs.
- a grid black in the figure constituting a crosstalk barrier to delimit all the filters.
- This grid will be absorbent if this module is used in reflection or reflecting if it is used in transmission.
- an absorbent grid may be made by deposition and etching of a black chrome (chromium + chromium oxide) while a reflective grid may be made by deposition and etching of chromium.
- the size of the filters is of the order of 300x300 microns 2 . Other filter sizes are of course possible, however, the size must be sufficient to avoid too marked diffraction phenomena.
- the filtering module can present an organization of these filters in line, matrix, hexagonal or of any other nature.
- the shape of the filters can be any (square, rectangle, hexagonal, .
- the filtering module is intended to be associated with a detector capable of measuring the luminous fluxes produced by at least some of the filters, if not all of them.
- This detector is formed of a plurality of compartments, each active compartment being dedicated to a specific filter.
- the detector is integrated.
- the useful radiation is between 350 and 1100 nanometers, it is preferably made in CMOS technology.
- the MF filter module which is shown in Figure 4 by using it in transmission.
- This is optically aligned with the DET detector whose compartments are homothetic filters.
- the first CP11, the second CP12, respectively the third CP13 compartment is provided to receive the light flux transmitted by the first IF11, the second IF12, respectively the third IF13 filter.
- the compartment CPjk which belongs to the jth line and to the kth column of the detector DET receives the radiation transmitted by the filter IFjk belonging to the jth line and the kth column of the filtering module MF.
- a compartment is provided with a plurality of independent detection cells because they commonly have a size of the order of 6 microns.
- Means are then provided for producing a signal for estimating the luminous flux received by this compartment by combining the output signals of these different cells. It is thus possible to average these output signals, to eliminate those signals that depart substantially from this average or to perform any treatment known to those skilled in the art.
- the assembly is very simple because it has few optical parts and there is no moving part. The measurement is therefore very stable and very reproducible.
- the spectroscopy device comprises an OPT imaging optics such as an objective arranged between the filtering module MF and the detector DET.
- This optics aims to adapt the size of the filter module MF to that of the detector DET. It can achieve aggrandisme or reduction. In the latter case, the luminous flux received by the detector is increased in the ratio of the surface of the filter module to that of this detector.
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Spectrometry And Color Measurement (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0800281A FR2926635B1 (fr) | 2008-01-21 | 2008-01-21 | Dispositif de spectroscopie en longueur d'onde a filtres integres |
PCT/FR2009/000056 WO2009112680A2 (fr) | 2008-01-21 | 2009-01-20 | Dispositif de spectroscopie en longueur d'onde à filtres intégrés |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2235484A2 true EP2235484A2 (fr) | 2010-10-06 |
Family
ID=39712384
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09720812A Ceased EP2235484A2 (fr) | 2008-01-21 | 2009-01-20 | Dispositif de spectroscopie en longueur d'onde à filtres intégrés |
Country Status (7)
Country | Link |
---|---|
US (1) | US20110049340A1 (fr) |
EP (1) | EP2235484A2 (fr) |
JP (1) | JP2011510285A (fr) |
CN (1) | CN101965505B (fr) |
CA (1) | CA2712636A1 (fr) |
FR (1) | FR2926635B1 (fr) |
WO (1) | WO2009112680A2 (fr) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2984489B1 (fr) | 2011-12-15 | 2017-09-15 | Office Nat D'etudes Et De Rech Aerospatiales | Lame interferometrique a deux ondes comportant une cavite pleine partiellement resonante et son procede de fabrication |
DE102013213219B4 (de) | 2013-07-05 | 2021-12-23 | Siemens Healthcare Gmbh | Vorrichtung zur Bestimmung einer Verformungsinformation für ein mit einer Last beaufschlagtes Brett |
EP3112828B1 (fr) | 2015-06-30 | 2022-10-05 | IMEC vzw | Circuit intégré et procédé de fabrication de circuit intégré |
EP3182079B1 (fr) * | 2015-12-14 | 2023-08-23 | ams AG | Dispositif de détection optique et procédé de fabrication d'un tel appareil |
FR3050831B1 (fr) * | 2016-04-29 | 2018-04-27 | Silios Technologies | Dispositif d'imagerie multispectrale |
FR3053464B1 (fr) * | 2016-06-30 | 2020-08-14 | Office National D'etudes Et De Rech Aerospatiales | Spectro-imageur multivoie a transformee de fourier |
EP3339821A1 (fr) | 2016-12-23 | 2018-06-27 | IMEC vzw | Capteur d'imagerie |
US10288483B2 (en) * | 2017-04-09 | 2019-05-14 | Cymer, Llc | Recovering spectral shape from spatial output |
CA3075646C (fr) | 2017-09-13 | 2024-03-26 | Materion Corporation | Resine photosensible en tant que masque d'ouverture opaque sur des reseaux de filtres multispectraux |
EP3462148B1 (fr) * | 2017-09-28 | 2023-09-06 | ams AG | Dispositif de détection optique et procédé de fabrication d'un tel appareil |
US10677972B2 (en) * | 2017-12-08 | 2020-06-09 | Viavi Solutions Inc. | Multispectral sensor response balancing |
US11156753B2 (en) | 2017-12-18 | 2021-10-26 | Viavi Solutions Inc. | Optical filters |
FR3084459B1 (fr) * | 2018-07-30 | 2020-07-10 | Silios Technologies | Capteur d'imagerie multispectrale pourvu de moyens de limitation de la diaphonie |
US11789188B2 (en) * | 2019-07-19 | 2023-10-17 | Viavi Solutions Inc. | Optical filter |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2215038B (en) * | 1988-02-05 | 1992-01-08 | Plessey Co Plc | Improvements relating to optical sensing arrangements |
US6031653A (en) * | 1997-08-28 | 2000-02-29 | California Institute Of Technology | Low-cost thin-metal-film interference filters |
JP2002082048A (ja) * | 2000-09-07 | 2002-03-22 | Shimadzu Corp | 非接触式物性測定方法およびその装置 |
US7474350B2 (en) * | 2003-09-08 | 2009-01-06 | Sanyo Electric Co., Ltd. | Solid state image pickup device comprising lenses for condensing light on photodetection parts |
US7256922B2 (en) * | 2004-07-02 | 2007-08-14 | Idc, Llc | Interferometric modulators with thin film transistors |
WO2006130164A2 (fr) * | 2004-08-19 | 2006-12-07 | University Of Pittsburgh | Analyseurs de spectre optiques, de la dimension d'une puce, a resolution accrue |
US7553684B2 (en) * | 2004-09-27 | 2009-06-30 | Idc, Llc | Method of fabricating interferometric devices using lift-off processing techniques |
JP4806197B2 (ja) * | 2005-01-17 | 2011-11-02 | パナソニック株式会社 | 固体撮像装置 |
US8574823B2 (en) * | 2005-10-05 | 2013-11-05 | Hewlett-Packard Development Company, L.P. | Multi-level layer |
US7315667B2 (en) * | 2005-12-22 | 2008-01-01 | Palo Alto Research Center Incorporated | Propagating light to be sensed |
JP2007317750A (ja) * | 2006-05-23 | 2007-12-06 | Matsushita Electric Ind Co Ltd | 撮像装置 |
-
2008
- 2008-01-21 FR FR0800281A patent/FR2926635B1/fr active Active
-
2009
- 2009-01-20 CA CA2712636A patent/CA2712636A1/fr not_active Abandoned
- 2009-01-20 CN CN2009801072663A patent/CN101965505B/zh active Active
- 2009-01-20 EP EP09720812A patent/EP2235484A2/fr not_active Ceased
- 2009-01-20 WO PCT/FR2009/000056 patent/WO2009112680A2/fr active Application Filing
- 2009-01-20 US US12/863,731 patent/US20110049340A1/en not_active Abandoned
- 2009-01-20 JP JP2010542663A patent/JP2011510285A/ja active Pending
Non-Patent Citations (1)
Title |
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None * |
Also Published As
Publication number | Publication date |
---|---|
JP2011510285A (ja) | 2011-03-31 |
CN101965505A (zh) | 2011-02-02 |
FR2926635A1 (fr) | 2009-07-24 |
WO2009112680A2 (fr) | 2009-09-17 |
FR2926635B1 (fr) | 2012-08-03 |
US20110049340A1 (en) | 2011-03-03 |
CA2712636A1 (fr) | 2009-09-17 |
WO2009112680A3 (fr) | 2009-10-29 |
CN101965505B (zh) | 2013-03-27 |
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