EP2181860B1 - Composant en matière dérivée du bois doté de propriétés tactiles particulières et procédé de fabrication d'un tel composant - Google Patents

Composant en matière dérivée du bois doté de propriétés tactiles particulières et procédé de fabrication d'un tel composant Download PDF

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Publication number
EP2181860B1
EP2181860B1 EP09173162A EP09173162A EP2181860B1 EP 2181860 B1 EP2181860 B1 EP 2181860B1 EP 09173162 A EP09173162 A EP 09173162A EP 09173162 A EP09173162 A EP 09173162A EP 2181860 B1 EP2181860 B1 EP 2181860B1
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EP
European Patent Office
Prior art keywords
surface layer
material coating
printed
microstructure
structural element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09173162A
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German (de)
English (en)
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EP2181860A3 (fr
EP2181860A2 (fr
Inventor
Ansgar Wolf
Stephan Rehker
Thorsten Dietz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fritz Egger GmbH and Co OG
Original Assignee
Fritz Egger GmbH and Co OG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE200810052883 external-priority patent/DE102008052883B4/de
Application filed by Fritz Egger GmbH and Co OG filed Critical Fritz Egger GmbH and Co OG
Priority to PL09173162T priority Critical patent/PL2181860T3/pl
Publication of EP2181860A2 publication Critical patent/EP2181860A2/fr
Publication of EP2181860A3 publication Critical patent/EP2181860A3/fr
Application granted granted Critical
Publication of EP2181860B1 publication Critical patent/EP2181860B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/043—Ornamental plaques, e.g. decorative panels, decorative veneers containing wooden elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • B44C5/0476—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper with abrasion resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/02—Designs imitating natural patterns wood grain effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/04—Designs imitating natural patterns of stone surfaces, e.g. marble

Definitions

  • the invention relates to a component, in particular a panel, of wood material, in particular for use as a furniture component or wall, ceiling or floor panel, with a surface layer and a surface layer partially covering the material order. Furthermore, the invention relates to a method for producing such a device in which a surface layer is applied to a carrier plate of wood material or a carrier profile of wood material, and in which a paint-like material order is printed on the surface layer.
  • Wood-based panels with decorative coating are often used as floor panels and for the cladding of walls and ceilings or as furniture components. Such panels usually have a rectangular shape and are usually provided at least at their longitudinal edges with profiles that allow a coupling of adjacent panels to create a large-scale surface can. Wood fiber boards, preferably so-called dry-process MDF (Medium Density Fiberboard) or HDF (High Density Fiberboard) boards, are widely used for this purpose.
  • dry-process MDF Medium Density Fiberboard
  • HDF High Density Fiberboard
  • papers impregnated with a synthetic resin and predried can also be pressed directly onto the surfaces of the plates under high heat and pressure in order to produce the same to apply desired decor. Since these impregnates tend to shrink during compression, they create a tension, which is why these plates must always be provided on both sides with an impregnated paper in order to prevent a voltage-induced bending of the plates.
  • the laminate-coated wood fiber boards also directly coated panels are used for panels of the type mentioned recently.
  • panels are, for example, from the EP 1 645 339 A1 known.
  • the fiberboards are provided with liquid coating compositions, wherein a decor, for example a wood decor is printed on a colored base layer and finally one or more transparent sealing layers are applied.
  • the EP 1 645 339 A1 describes the production of a structured surface by applying a first coating and a second coating with spatially varying application amount.
  • a floor panel which has a base plate (carrier plate), which is printed on its upper side with a decorative layer, wherein on the decorative layer, a first lacquer layer and a second lacquer layer are applied.
  • the first coating layer applied to the decorative layer is harder and less elastic than the subsequent second coating layer.
  • the first lacquer layer contains abrasion-resistant particles, in particular corundum, while the second, softer and elastic lacquer layer contains significantly less, as a rule, no abrasion-resistant particles. It should be so favorable conditions in terms of Wear properties of such floor panels can be achieved.
  • the present invention has for its object to provide a component, in particular panel, wood-based material for use as a furniture component or wall, ceiling or floor panel available, which has a soft-looking surface in haptic terms and can be produced inexpensively.
  • the invention has for its object to provide a method for producing such a device or panel.
  • the component according to the invention has a carrier element, in particular in the form of a plate or a profile made of wood material, which is provided with a surface layer and a material layer arranged thereon layer, the material application does not cover the surface layer over the entire surface, but only partially and forms a microstructure, the a roughness depth in the range of 2 microns to 30 microns, wherein the material coverage covers 10 to 50% of the surface of the surface layer, and wherein the material application defined areas are irregularly limited and irregularly distributed on the surface layer.
  • a carrier element in particular in the form of a plate or a profile made of wood material, which is provided with a surface layer and a material layer arranged thereon layer, the material application does not cover the surface layer over the entire surface, but only partially and forms a microstructure, the a roughness depth in the range of 2 microns to 30 microns, wherein the material coverage covers 10 to 50% of the surface of the surface layer, and wherein the material application defined areas are irregularly limited and irregularly distributed on the surface
  • the method according to the invention provides that a surface layer is applied to a carrier board of wood-based material or a carrier profile of wood-based material, and that a paint-like material application is printed on the surface layer in such a way that it covers 10% to 50% of the surface of the surface layer and after curing forms a microstructure having a surface roughness in the range of 2 microns to 30 microns and irregularly limited and irregularly distributed on the surface layer is arranged.
  • Components made of wood material produced according to the invention have a soft-seeming surface.
  • the impression a soft surface is caused or simulated essentially or significantly by the special microstructure. Since the microstructure is produced by printing a paint-like material application, comparatively favorable production costs for the components according to the invention result.
  • continuous pressure roller machines can be used, which are known per se and very powerful.
  • the machines must be equipped with at least one pressure cylinder designed according to the invention.
  • a particularly preferred embodiment of the method according to the invention is that the material application is printed so that it covers 20-40%, particularly preferably 25-35% of the surface of the surface layer and forms after curing areas that are irregularly limited and irregularly distributed on the Surface layer are arranged.
  • the components or panels produced in this way have a surface which, in terms of haptics, gives an impression which corresponds to that of a smooth, oiled solid wood surface.
  • Such an impression arises in particular when the material application is printed according to a preferred embodiment of the method so that the microstructure has a surface roughness in the range of 5 microns to 20 microns, preferably in the range of 6.5 microns to 15 microns.
  • the material application is printed so that the microstructure formed by it comprises a plurality of separate regions whose respective surface area is in the range of 0.01 mm 2 to 0.1 mm 2 .
  • the material application is printed so that in a surface area of 1 cm 2 of the surface layer at least 200, preferably at least 400 separate microstructure regions are arranged.
  • a further preferred embodiment of the method according to the invention is characterized in that the surface layer is a transparent sealing layer is applied or printed, that before the sealing layer, a wood decor is printed on the carrier plate or the carrier profile, and that on the microstructure forming material one formed from a lacquer Pore structure is printed.
  • a wooden surface can be imitated, and in particular also in optical terms.
  • the three-dimensional pore structure is preferably printed in concordance with the illustrated wood grain of the two-dimensional wood decor, so that the impression of real wood is very much imitated.
  • the three SEM images of the respective FIGS. 1 and 2 were recorded with different degrees of magnification.
  • the SEM image marked A shows a 50-fold each Magnification
  • the SEM image marked with B shows a 100-fold magnification
  • the SEM image marked with C shows a 1000-fold magnification, with the respective image at the lower edge, right with a size scale (200 .mu.m, 100 microns or 10 microns) is provided.
  • the panels or samples according to the invention each have a carrier plate of wood-based material, preferably an MDF or HDF plate.
  • the respective support plate is provided with a single-layer or multi-layer surface layer 1, which, viewed individually, is substantially smooth.
  • a material application 2 is printed as a kind of finishing layer.
  • the material application 2 covers the surface layer 1 only partially and forms a microstructure.
  • microstructure in the present context means a structure having a roughness R Z according to DIN 4768 in the range of 2 microns to 30 microns, preferably 5 microns to 20 microns, more preferably 6.5 microns to 15 microns.
  • the material application 2 is not present over the entire surface, but is localized. The final material application or the finishing layer 2 is therefore not applied over the entire surface.
  • the material application 2, however, is distributed so that with the naked eye can hardly or hardly be recognized, where it is applied and where not.
  • the areas defined by the material application, which form the microstructure comprise a plurality of separate areas whose respective surface area is in the range of 0.01 mm 2 to 0.1 mm 2 .
  • the areas which the Form microstructure comprise a plurality of separate regions, wherein in a surface area of 1 cm 2 of the surface layer 1 at least 200, preferably at least 400 separate microstructure regions are arranged.
  • Figures 1 and 2 show surfaces of inventive components or panels in which the material application 2 10 to 50%, preferably 20 to 40%, particularly preferably 25 to 35% of the surface of the previously applied, preferably printed surface layer 1 covered and the areas defined by the material order 2 irregularly limited and irregularly distributed on the surface layer 1 are arranged.
  • the material order 2 has irregularly large, in particular different height surveys (micro surveys). The surveys are arranged irregularly distributed.
  • the surface layer 1 below the material application 2 is here a transparent, substantially smooth sealing layer. Below the transparent sealing layer is a decor, such as a wood, tile or natural stone decor arranged.
  • the in Figures 1 and 2 The surfaces shown are very haptically smooth and feel like oiled real wood surfaces.
  • the material layer 2 forming the microstructure contains abrasion-resistant and / or scratch-resistant particles.
  • the particle size of these particles which are, for example, corundum particles and / or quartz particles, is less than 20 ⁇ m, preferably less than 15 ⁇ m. Such particles are also referred to as so-called nanoparticles.
  • Fig. 3 schematically a device for direct printing of wood-based panels is shown.
  • a plurality of plates 3 are arranged on a conveyor belt 4, which are supplied individually in series to different processing stations 5, 6, 7, 8.
  • the conveying direction is in Fig. 3 indicated by an arrow and runs from left to right.
  • a larger wood-based panel or an endlessly produced wood-based panel in the device according to Fig. 3 which is divided into individual plates according to the processing described below.
  • a multi-colored, for example, two-tone decor for example a wood decor printed by gravure printing on the plates 3. But this could also be realized in three- or four-color printing or by a digital printing process.
  • Fig. 3 is further shown that the surface of the plates 3 is provided after the imprint of the decor by means of another processing station 7 with a transparent sealing layer.
  • a substantially full surface layer (sealing layer) is applied from a paint.
  • the processing station 7 on an applicator roller 7.1, which applies a uniform, substantially smooth layer of paint on the surface of the plates 3. through a downstream post-processing device 7.2, the applied coating is at least partially dried or cured.
  • the post-processing device 7.2 for example, by means of a hot air flow or electromagnetic radiation, in particular UV radiation cause the drying and curing.
  • the processing station 7 is followed by a further processing station 8 by the application station 8 by means of an applicator roller 8.1, the previously applied surface layer (sealing layer) partially covering material applied or printed, the material application forms a microstructure on the surface layer, for example, a corresponds to the microstructured surfaces shown in Figures 1 to 4.
  • an abrasion-resistant and / or scratch-resistance-increasing particle for example corundum particles and / or quartz particles-containing varnish.
  • the microstructure of this material application 2 is essentially produced by a gravure roll (pressure cylinder roller) 8.1, in whose lateral surface a corresponding microstructure is formed.
  • the microstructured finishing layer is at least partially cured, so that the microstructure is sufficiently solidified and fixed, and does not level due to deliquescence. In this curing step, it may also lead to a possibly incomplete curing of the underneath arranged, with one of the upstream processing stations 5, 6 and / or 7 applied coating (s) come.
  • a pore structure of a lacquer can be printed on the finishing layer forming the microstructure, for example in order to imitate wood pores (depressions) on a wood surface (wood grain).
  • This paint pore structure is preferably formed as a negative pore structure, i. the depressions (pores) of a wooden surface are not formed as depressions, but as small paint elevations.
  • a backslash can be applied on the back (underside) of the support plate 3.
  • the order of the backslash which is preferably executed in color, for example, by means of applicator rolls.
  • For drying the backsheet e.g. Nozzle dryer used.
  • the microstructure of the invention forming material (finish) 2 - and possibly the backsheet - are sufficiently cured, so coated large-sized support plate 3 by means of a saw or the like divided into a plurality of panels.
  • profiles 9, 10 for the positive connection of the panel with a corresponding panel are milled into the longitudinal sides and optionally also the transverse sides of the respective panel.
  • the profiles are designed as a groove 9 and spring 10 (see. Fig. 5 ).
  • FIG. 4 two interconnected panels 3.1, 3.2 are shown, each having on its upper side a wood decor, a sealing layer 1 and a final material application, said indicated by small dots material application 2 forms a microstructure according to the invention.
  • the panels 3.1, 3.2 are designed as floor panels. Likewise, they can also be used to cover walls or ceilings.

Claims (20)

  1. Elément de construction, en particulier panneau, en matériau dérivé du bois, destiné à être utilisé en tant qu'élément de meuble ou panneau de mur, de plafond ou de sol (3.1, 3.2), qui est doté d'une couche de surface (1) et d'un revêtement de matière (2), qui, recouvrant partiellement la couche de surface (1), forme une microstructure, qui présente une profondeur de rugosité de Rz selon DIN 4768, située dans une plage de 2 µm à 30 µm, caractérisé en ce que le revêtement de matière (2) couvre 10 % à 50 % de la surface de la couche de surface (1), et que les zones, définies par le revêtement de matière (2), sont disposées sur la couche de surface (1), en étant limitées irrégulièrement et réparties irrégulièrement.
  2. Elément de construction selon la revendication 1, caractérisé en ce que la microstructure est dotée d'une profondeur de rugosité située dans une plage de 5 µm à 20 µm, de préférence dans une plage de 6,5 µm à 15 µm.
  3. Elément de construction selon revendication 1 ou 2, caractérisé en ce que les zones, définies par le revêtement de matière (2), qui forment la microstructure, comprennent une pluralité de zones séparées, qui présentent chacune une étendue située dans une plage de 0,01 mm2 à 0,1 mm2.
  4. Elément de construction selon l'une des revendications 1 à 3, caractérisé en ce que les zones, définies par le revêtement de matière (2), qui forment la microstructure, comprennent une pluralité de zones séparées, sachant que, dans une zone de 1 cm2 de la couche de surface (1), sont disposées au moins 200, de préférence au moins 400 zones de microstructure séparées.
  5. Elément de construction selon l'une des revendications 1 à 4, caractérisé en ce que la couche de surface (1) est une couche de vitrification transparente, sachant que, sous ladite surface de vitrification, est disposé un décor, de préférence un décor qui imite le bois, le carrelage ou la pierre naturelle.
  6. Elément de construction selon l'une des revendications 1 à 5, caractérisé en ce que le revêtement de matière (2) couvre 20 % à 40 %, de préférence 25 % à 35 % de la surface de la couche de surface (1).
  7. Elément de construction selon l'une des revendications 1 à 6, caractérisé en ce que la couche de surface (1) est une couche de vitrification transparente, sachant que, sous ladite surface de vitrification, est disposé un décor imitant le bois, et sachant que sur le revêtement de matière (2), qui forme la microstructure, est imprimée une structure poreuse, qui consiste en laque.
  8. Elément de construction selon l'une des revendications 1 à 7, caractérisé en ce que la couche de surface (1) est une couche de vitrification transparente, lisse.
  9. Elément de construction selon l'une des revendications 1 à 8, caractérisé en ce que ledit élément de construction consiste en un panneau (3.1, 3.2), qui est doté d'une plaque de support, sachant que la plaque de support est pourvue de la couche de surface (1) et du revêtement de matière (2), qui couvre partiellement ladite couche de surface, et sachant que les côtés d'aboutage longitudinaux et / ou transversaux de la plaque de support sont dotés de profils (9, 10) pour relier par emboîtement le panneau (3.1) à un panneau (3,2) correspondant.
  10. Elément de construction selon l'une des revendications 1 à 9, caractérisé en ce que le revêtement de matière (2), qui forme la microstructure, contient des particules, qui accroissent la résistance à l'abrasion et / ou la résistance aux éraflures et au frottement, de préférence des particules de corindon et / ou des particules de quartz.
  11. Elément de construction selon la revendication 10, caractérisé en ce que les particules accroissant la résistance à l'abrasion et / ou la résistance aux éraflures et au frottement présentent une granulométrie inférieure à 20 µm, de préférence inférieure à 15 µm.
  12. Procédé de fabrication d'un élément de construction, qui est destiné, en particulier, à être utilisé en tant qu'élément de meuble ou de panneau de mur, de plafond ou de sol (3.1, 3.2), dans lequel une couche de surface (1) est appliquée sur une plaque de support en matériau dérivé du bois ou sur un profilé en matériau dérivé du bois, et dans lequel, sur ladite couche de surface, est imprimé un revêtement de matière (2) de type laque, qui présente une profondeur de rugosité Rz selon DIN 4768 située dans une plage de 2 µm à 30 µm, caractérisé en ce que le revêtement de matière (2) est imprimé de sorte qu'il recouvre 10 à 50 % de la surface de la couche de surface (1) et forme, après durcissement, une microstructure et est limité irrégulièrement et réparti irrégulièrement.
  13. Procédé selon la revendication 12, caractérisé en ce que le revêtement de matière (2) est appliqué de sorte que la microstructure présente une profondeur de rugosité située dans une plage de 5 µm à 20 µm, de préférence dans une plage de 6,5 µm à 15 µm.
  14. Procédé selon revendication 12 ou 13, caractérisé en ce que le revêtement de matière (2) est imprimé de sorte que la microstructure formée par lui comprenne une pluralité de zones séparées, qui présentent chacune une étendue située dans une plage de 0,01 mm2 à 0,1 mm2.
  15. Procédé selon l'une des revendications 12 à 14, caractérisé en ce que le revêtement de matière (2) est imprimé de sorte que, que, dans une zone de 1 cm2 de la couche de surface (1), sont disposées au moins 200, de préférence au moins 400 zones de microstructure séparées.
  16. Procédé selon l'une des revendications 12 à 15, caractérisé en ce que, comme couche de surface (1), est appliquée ou imprimée une couche de vitrification transparente et que, sur la plaque de support ou le profilé de support, un décor, de préférence un décor imitant le bois, le carrelage ou la pierre naturelle, est imprimé avant la couche de vitrification.
  17. Procédé selon l'une des revendications 12 à 16, caractérisé en ce que le revêtement de matière (2) est imprimé de sorte qu'il couvre 20 % à 40 %, de préférence 25 % à 35 % de la surface de la couche de surface (1) et forme, après durcissement, des zones, qui sont limitées irrégulièrement et réparties irrégulièrement sur la couche de surface.
  18. Procédé selon l'une des revendications 12 à 17, caractérisé en ce que, comme couche de surface (1), est appliquée ou imprimée une couche de vitrification transparente, que, sur la plaque de support ou le profilé de support, un décor imitant le bois est imprimé avant la couche de vitrification, et que, sur le revêtement de matière (2), qui forme la microstructure, est imprimée une structure poreuse consistant en laque.
  19. Procédé selon l'une des revendications 12 à 18, caractérisé en ce que, comme couche de surface (1), est appliquée ou imprimée une couche de vitrification transparente, lisse.
  20. Procédé selon l'une des revendications 12 à 19, caractérisé en ce que, pour la réalisation du revêtement de matière (2) de type laque, on utilise une laque contenant des particules, qui accroissent la résistance à l'abrasion et / ou la résistance aux éraflures et au frottement, de préférence des particules de corindon et / ou des particules de quartz.
EP09173162A 2008-10-22 2009-10-15 Composant en matière dérivée du bois doté de propriétés tactiles particulières et procédé de fabrication d'un tel composant Active EP2181860B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL09173162T PL2181860T3 (pl) 2008-10-22 2009-10-15 Element konstrukcyjny z materiału drewnianego ze szczególnymi właściwościami haptycznymi oraz sposób wytwarzania takiego elementu konstrukcyjnego

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008052677 2008-10-22
DE200810052883 DE102008052883B4 (de) 2008-10-23 2008-10-23 Bauelement aus Holzwerkstoff mit besonderen haptischen Eigenschaften und Verfahren zur Herstellung eines solchen Bauelements

Publications (3)

Publication Number Publication Date
EP2181860A2 EP2181860A2 (fr) 2010-05-05
EP2181860A3 EP2181860A3 (fr) 2012-03-14
EP2181860B1 true EP2181860B1 (fr) 2013-03-20

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EP09173162A Active EP2181860B1 (fr) 2008-10-22 2009-10-15 Composant en matière dérivée du bois doté de propriétés tactiles particulières et procédé de fabrication d'un tel composant

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EP (1) EP2181860B1 (fr)
ES (1) ES2406358T3 (fr)
PL (1) PL2181860T3 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202012001576U1 (de) 2011-09-07 2012-03-16 Gerda Lüthje Haptisches Figurenset
EP3415316B1 (fr) 2017-06-13 2020-04-08 Hymmen GmbH Maschinen- und Anlagenbau Procédé et dispositif de fabrication d'une surface structurée
PL3415317T5 (pl) 2017-06-13 2023-11-27 Hymmen GmbH Maschinen- und Anlagenbau Sposób i urządzenie do wytwarzania powierzchni dekoracyjnej
DE102019206431A1 (de) 2019-05-03 2020-11-05 Hymmen GmbH Maschinen- und Anlagenbau Verfahren zum Herstellen einer Struktur auf einer Oberfläche
DE102019207277A1 (de) * 2019-05-17 2020-11-19 Hymmen GmbH Maschinen- und Anlagenbau Verfahren zum Herstellen einer dekorativen Oberfläche insbesondere eines Holzwerkstückes

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3585235B2 (ja) * 1993-10-25 2004-11-04 大日本印刷株式会社 化粧シート
SE520926C2 (sv) 2000-12-11 2003-09-16 Pergo Ab Förfarande för framställning av ett dekorativt laminat med ljuddämpande elastomerskikt
PL2218520T3 (pl) 2004-10-05 2013-11-29 Fritz Egger Gmbh & Co Og Sposób i urządzenie do wytwarzania powierzchni strukturyzowanej
DE102006039251B4 (de) 2006-08-22 2015-09-10 Guido Schulte Fußbodenpaneele
DE102007019871A1 (de) * 2007-04-25 2008-10-09 Theodor Hymmen Holding Gmbh Verfahren und Vorrichtung zur Erzeugung einer dünnen dreidimensional strukturierten Oberfläche auf plattenförmigen Werkstoffen

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PL2181860T3 (pl) 2013-10-31
ES2406358T3 (es) 2013-06-06
EP2181860A3 (fr) 2012-03-14
EP2181860A2 (fr) 2010-05-05

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