EP2171114A1 - Extruded products in aluminium alloy al-mn with improved mechanical strength - Google Patents
Extruded products in aluminium alloy al-mn with improved mechanical strengthInfo
- Publication number
- EP2171114A1 EP2171114A1 EP08835982A EP08835982A EP2171114A1 EP 2171114 A1 EP2171114 A1 EP 2171114A1 EP 08835982 A EP08835982 A EP 08835982A EP 08835982 A EP08835982 A EP 08835982A EP 2171114 A1 EP2171114 A1 EP 2171114A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- product according
- tube
- spun
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000012438 extruded product Nutrition 0.000 title abstract 2
- 229910000838 Al alloy Inorganic materials 0.000 title description 4
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 46
- 239000000956 alloy Substances 0.000 claims abstract description 46
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000003507 refrigerant Substances 0.000 claims abstract description 16
- 238000004378 air conditioning Methods 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000000137 annealing Methods 0.000 claims abstract description 7
- 238000005266 casting Methods 0.000 claims abstract description 4
- 238000000265 homogenisation Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 7
- 239000012530 fluid Substances 0.000 claims description 5
- 238000009987 spinning Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000000446 fuel Substances 0.000 claims description 3
- 230000006698 induction Effects 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 32
- 239000000047 product Substances 0.000 description 31
- 238000005260 corrosion Methods 0.000 description 18
- 230000007797 corrosion Effects 0.000 description 18
- 239000001569 carbon dioxide Substances 0.000 description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 description 16
- 239000011701 zinc Substances 0.000 description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- 239000010936 titanium Substances 0.000 description 13
- 239000011777 magnesium Substances 0.000 description 12
- 239000011572 manganese Substances 0.000 description 11
- 239000011651 chromium Substances 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 239000010949 copper Substances 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 230000032683 aging Effects 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- 229910018131 Al-Mn Inorganic materials 0.000 description 1
- 229910018461 Al—Mn Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910017706 MgZn Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- PQLVXDKIJBQVDF-UHFFFAOYSA-N acetic acid;hydrate Chemical compound O.CC(O)=O PQLVXDKIJBQVDF-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- -1 i.e. Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12292—Workpiece with longitudinal passageway or stopweld material [e.g., for tubular stock, etc.]
Definitions
- AI-Mn aluminum alloy spun products with improved mechanical strength with improved mechanical strength.
- the invention relates to spun aluminum alloy products Al-Mn (3000 series according to the nomenclature of the Aluminum Association) with improved mechanical strength, in particular tubes intended in particular for pipes or heat exchangers for the automotive industry. .
- HFCs HydroFluoroCarbures
- CO2 Even if it is a greenhouse gas, has a much lower impact than HFCs 3 , which would reduce the harmfulness of emissions related to leaks.
- the operation of an air conditioner using CO2 as a refrigerant gas is based on gas compression and expansion.
- a compressor compresses CO2 at high pressure and it then goes into a gas cooler (traditionally called a condenser, but in which condensation does not occur when the refrigerant is CO2), then in an internal heat exchanger (which allows heat exchanges with the low pressure zone).
- the CO2 which is still gaseous, then passes into a regulator from which a liquid flows out which allows the cooling of the passenger compartment by passing through an evaporator.
- the low pressure gas is then accumulated before circulating in the internal heat exchanger and back into the compressor for a new cycle.
- the spun aluminum products can be used for the manufacture of heat exchangers (gas cooler, evaporator) and / or for the realization of the pipes allowing the refrigerant to circulate between the various elements of the cooling circuit.
- the use of CO2 as a refrigerant is made difficult by the pressure at which it must be used.
- the critical temperature of CO2 is lower than that of HFC-134a and its critical pressure is higher which forces the air conditioning system to operate at higher pressures and temperatures than those currently used, whether in the high pressure part or the low pressure part of the circuit.
- the materials used in the air conditioning circuit must therefore be stronger than current materials while maintaining at least equivalent performance in terms of manufacturing, shaping, assembly and corrosion resistance.
- the CO2 thus needs to be compressed at high pressures of the order of 100 to 200 bar. Therefore, to allow the use of CO2 as a refrigerant, the pipes must withstand an operating pressure of 200 bar for high temperatures of 130-170 ° C which is high compared to current conditions, the order of 5 bars at 60 ° C.
- Alloys have been proposed for the production of flat tubes for heat exchangers (gas coolers, evaporators) of air conditioning systems using CO2 as a refrigerant gas.
- JP 2005-068557 discloses a composition alloy (% by weight)
- Mn 0.8 - 2
- Cu 0.22 - 0.6
- Ti 0.01 - 0.2
- Fe 0.01 - 0.4
- Zn ⁇ 0.2 0.01 - 0.4
- Sn ⁇ 0.018
- JP 2007-070699 discloses an alloy of composition (% by weight) Si: 0.31-0.7, Fe: 0.3-0.6, Mn: 0.01-0.4, and optionally Ti 0.01 - 0.3, Zr 0.05 - 0.3, Cr 0.05 - 0.3.
- the patent application WO 97/46726 of Reynolds Metals relates to an alloy, known under the name X3030, of composition (% by weight): Mn: 0.1 - 0.5, Cu ⁇ 0.03, Mg ⁇ 0.01 , Zn: 0.06 - 1.0, Si: 0.05 - 0.12, Fe ⁇ 0.50,
- Ti 0.03 - 0.30, Cr ⁇ 0.50, remains aluminum.
- the addition of Zn and Ti contributes to the improvement of the corrosion resistance.
- Cr is preferably maintained below 0.20%.
- Ti is preferably maintained above 0.12% and Zn above 0.1%.
- the problem addressed by the present invention is to provide a 3XXX alloy spun product of improved mechanical strength, so as to be able to withstand high pressures and in particular for operating temperatures between 130 and 170 ° C., and having identical or superior performance in terms of manufacturing, shaping, assembly and corrosion resistance to those of current products.
- the subject of the invention is a spun product, in particular a stretched tube, of alloy of composition (% by weight): Si ⁇ 0.30, Fe ⁇ 0.30, Cu ⁇ 0.05, Mn: 0.5 - 1 , 2, Mg 0.5 - 1.0, Zn ⁇ 0.20, Cr: 0.10 - 0.30, Ti ⁇ 0.05, Zr ⁇ 0.05, Ni ⁇ 0.05, others ⁇ 0, 05 each and ⁇ 0.15 total, remains aluminum.
- the preferred contents are (% by weight): Si 0.05 - 0.15, Fe: 0.05 - 0.25, Cu ⁇ 0.01, Mn: 0.9 - 1.1, Mg 0.6 - 0.9, Zn: ⁇ 0.05, Cr: 0.15 - 0.25, Ti ⁇ 0.04, Zr ⁇ 0.04, Ni ⁇ 0.01.
- the subject of the invention is also a process for manufacturing spunbonded alloy tubes according to the invention comprising casting a billet, optionally homogenizing this billet, spinning a tube, stretching said tube one or more passes, and annealing continuously at a temperature between 350 and 500 ° C with a rise in temperature of less than 10 s.
- Yet another object of the invention is the use of a spun product according to the invention in the manufacture of motor vehicles.
- the alloy of the 3XXX series according to the invention has a relatively high magnesium content and a zinc content reduced to the level of impurity. Contrary to the teaching of the prior art which recommends the addition of zinc and titanium to the alloys of the 3XXX series to improve their resistance to corrosion, the alloy according to the invention has a good corrosion behavior with a content zinc and a titanium content reduced to the level of impurities.
- the zinc content should be less than 0.20% by weight, more preferably less than 0.05% by weight and even more preferably less than 0.04% by weight.
- the titanium content must be less than 0.05% by weight, preferably less than 0.04% by weight and even more preferably less than 0.03% by weight.
- the low zinc and titanium contents are an advantage as regards the recycling of the alloy products according to the invention.
- the magnesium content is between 0.5 and 1.0% by weight and preferably between 0.6 and 0.9% by weight.
- the addition of magnesium at a content of at least 0.5% by weight and preferably at least 0.6% by weight makes it possible to increase the mechanical strength very significantly.
- the magnesium content should, however, be limited to a maximum of 1.0% by weight and preferably 0.9% by weight to ensure satisfactory brazeability of the products, as well as good performance in terms of extrusionability.
- the addition of chromium at a concentration of between 0.10 and 0.30% by weight and preferably at a concentration of between 0.15 and 0.25% by weight makes it possible to improve the corrosion resistance of the alloy.
- Manganese is the main alloying element, its addition is carried out at a concentration of between 0.5 and 1.2% by weight and preferably at a concentration of between 0.9 and 1.1% by weight.
- the content of iron and silicon must be less than 0.30% by weight.
- the iron content is at most 0.25% by weight and the silicon content is at most 0.15% by weight. Too high a content of these elements contributes to the degradation of the corrosion resistance. It is preferable, mainly for economic reasons of recycling, that the silicon and iron contents are at least 0.05% by weight.
- the addition of other elements may have a detrimental effect on the alloy and must therefore have a content of less than 0.05% by weight and less than 0.15% in total.
- the presence of zirconium, nickel or copper can degrade the corrosion resistance properties and the content of these elements should be less than 0.05% by weight.
- the nickel and copper content is less than 0.01% by weight and the zirconium content is less than 0.04% by weight.
- the method of manufacturing the spun products comprises casting billets of the indicated alloy, optionally homogenizing the billets, heating them and spinning to obtain a tube in straight length or crown, and optionally one or several stretching passes to bring the product to the desired dimensions.
- the tube can, if it is stretched, then advantageously continuously annealed by high velocity scrolling through a passage oven, preferably an induction furnace. Heating the spun product is very fast, less than 10 seconds, and preferably 2 seconds, and the product scrolls at a speed between 20 and 200 m / min. The oven temperature is maintained between 350 and 500 ° C.
- the product can after the annealing undergo a new stretching to increase the mechanical strength (state H).
- This continuous annealing leads to a fine-grain equiaxed microstructure, of a mean grain size, measured by the intercepts method, of less than 40 ⁇ m, and typically of the order of 25 ⁇ m.
- the fine-grained microstructure is particularly advantageous with respect to the mechanical properties and corrosion resistance of the tubes.
- the products according to the invention have a high mechanical strength.
- the breaking strength at room temperature is increased by at least 40% relative to a product according to the application WO 02/055750 having a comparable manganese content.
- the advantage is even more marked for the tests carried out at high temperature.
- the breaking strength at 170.degree. C. is increased by nearly 60% relative to a product according to the application WO 02/055750 having a comparable manganese content.
- the spun products according to the invention have, in the H12 state, a resistance to rupture Rm greater than 150 MPa at room temperature and greater than 140 MPa at 170 ° C.
- the products spun in accordance with the preferred composition of the invention exhibit in the H12 state a breaking strength Rm greater than 160 MPa at room temperature and greater than 150 MPa at 170 ° C.
- the relative plastic difference R p o / o (R m -R p02 ) / R p0 , 2 , makes it possible to evaluate the plastic deformation ability without rupture.
- the products according to the invention have, in the H12 state, a plastic gap at room temperature slightly lower than that of the products according to the application WO 02/055750 but surprisingly an improved relative plastic gap for test temperatures greater than or equal to 130 ° C.
- the relative plastic difference obtained with the products according to the invention is greater than 5% for a test temperature of 140 ° C.
- the relative plastic difference at the H 12 state remains greater than 5%.
- the products according to the invention also have good corrosion performance.
- the products according to the invention do not exhibit deep pits during a salt spray test of SWAAT type according to the ASTM G85A3 standard. It is possible that this favorable result results, at least in part, from the absence of MgZn 2 precipitates which may form in the event of the simultaneous presence of Mg and Zn and which may have a detrimental effect, in particular on the corrosion resistance.
- a preferred form of the spun product according to the invention is a cylindrical tube having only one cavity.
- the spun products according to the invention can be used especially as tubes in the manufacture of motor vehicles.
- the spun products according to the invention can be used as tubes for fuel lines, oil, brake fluid or refrigerant for automobiles and as tubes for heat exchangers for engine cooling and / or air conditioning systems.
- passenger compartment especially if they use CO2 as a refrigerant gas.
- the tubes, in particular the drawn tubes, according to the invention are more particularly adapted to be used in the form of cylindrical tubes preferably comprising only one cavity for the fluid transfer lines used in the cabin air-conditioning systems. of motor vehicles using CO2 as a refrigerant gas.
- Example 1 Example 1
- Bindings were cast and homogenized in 3 alloys listed A to C.
- the alloys A and B respectively correspond to compositions of alloy AA3103 and according to the application WO 02/055750 of the prior art.
- Alloy C is in accordance with the invention.
- the compositions of the alloys (% by weight) are shown in Table 1.
- the billets were spun into tube crowns and then stretched to obtain tubes 12 mm in diameter and 1.25 mm thick. No significant differences were recorded for the three alloys with respect to their spinning and drawing properties. These rings were annealed continuously in an induction furnace at a temperature set at 470 0 C, with a speed of passage between 60 and 120 m / min. The crowns were then subjected to a new stretching pass to bring them to H12 according to EN 515.
- alloy C according to the invention leads "in mechanical strength greatly improved as compared that of the alloy B for a test performed at room temperature and even more vastly improved for a test carried out at 170 0C.
- the plastic gap for tests performed at at least 140 ° C is also largely improved from 0% for the alloy B greater than 5% for alloy C for temperatures of 140 ° C. and 170 ° C.
- the properties of breaking strength and the yield strength of alloy C were also measured at 130 ° C. aging 72h at 130 ° C and 100Oh at 130 0 C, and measured at 165 ° C after aging from 72h to 165 ° C and from 100Oh to 165 0 C.
- the alloy B has been characterized only in the the most severe conditions, ie measured at 165 0 C after aging 100Oh to 165 ° C. The results are shown in Table 3.
- the alloy C according to the invention retains after aging the mechanical properties of resistance to fracture and yield strength significantly improved since increased by 40% relative to the alloy B.
- the average grain size was measured by the intercepts method on samples from the 3 tubes. The results are shown in Table 4.
- the tubes obtained with the 3 alloys have equiaxized fine grains of the order of 20 microns. 10
- Corrosion resistance was measured using the Sea Water Acetic Acid Test (SWAAT) according to ASTM G85 A3. The measurements were made for periods of 500 cycles at the temperature of 49 ° C., on three tubes of length 200 mm of each alloy A 3 B and C. At the end of the test, the tubes were taken out of the tube. pregnant and stripped in a solution of nitric acid concentrated to 68% in order to dissolve the products of corrosion. On each tube, the depth of the pits is then measured optically on the surface by defocusing and the average depth of the deepest pits is calculated. The average Pmoy of the values obtained for the 3 tubes is then calculated. The corrosion resistance is even better than Pmoy is weak. The results of 5 successive SWAAT test campaigns are shown in Table 5. The number of signs * indicates the number of tubes drilled in the batch of three tubes tested.
- alloy C according to the invention has a corrosion resistance equivalent to that of alloy B of the prior art and significantly improved compared to that of alloy A.
- alloy C does not present no deep sting, it being understood that in the context of the present invention the term deep sting means a Pmoy value greater than 0.5 mm.
- the composition according to the invention, and in particular the addition of Mg, the absence of Zn thus makes it possible to dramatically improve the mechanical strength, in particular for temperatures between 130 ° C. and 170 ° C., without compromising corrosion resistance, compared to alloy B.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Extrusion Of Metal (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0705510A FR2919306B1 (en) | 2007-07-27 | 2007-07-27 | ALUMINUM ALUMINUM ALLOY FILM PRODUCTS WITH IMPROVED MECHANICAL RESISTANCE |
PCT/FR2008/001074 WO2009043993A1 (en) | 2007-07-27 | 2008-07-21 | Extruded products in aluminium alloy al-mn with improved mechanical strength |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2171114A1 true EP2171114A1 (en) | 2010-04-07 |
EP2171114B1 EP2171114B1 (en) | 2017-03-22 |
Family
ID=39167296
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08835982.3A Active EP2171114B1 (en) | 2007-07-27 | 2008-07-21 | Extruded products in aluminium alloy al-mn with improved mechanical strength |
Country Status (9)
Country | Link |
---|---|
US (1) | US20100190027A1 (en) |
EP (1) | EP2171114B1 (en) |
JP (1) | JP2010534766A (en) |
KR (1) | KR20100065289A (en) |
CN (1) | CN101765674A (en) |
BR (1) | BRPI0814138A2 (en) |
FR (1) | FR2919306B1 (en) |
MX (1) | MX2010000785A (en) |
WO (1) | WO2009043993A1 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011080121A (en) * | 2009-10-08 | 2011-04-21 | Mitsubishi Alum Co Ltd | Extruded tube for fin tube type heat exchanger for air conditioner and refrigerant piping for heat exchange cycle |
CN102146543A (en) * | 2010-02-05 | 2011-08-10 | 古河Sky株式会社 | Aluminum alloy extrusion material for a connector which is excellent in extrusion property and sacrificial anode property |
CN105568087A (en) * | 2016-01-25 | 2016-05-11 | 吕五有 | Aluminum alloy for heat exchange and production method thereof |
CN105734370A (en) * | 2016-04-08 | 2016-07-06 | 董超超 | Novel high-strength corrosion-resistant data recorder |
CN105734371A (en) * | 2016-04-08 | 2016-07-06 | 董超超 | Novel high-strength corrosion-resistant aluminum alloy pipeline |
CN105861895A (en) * | 2016-04-08 | 2016-08-17 | 董超超 | Novel high-strength corrosion-resistant building curtain wall framework |
CN105886864A (en) * | 2016-04-08 | 2016-08-24 | 董超超 | Novel high-strength anticorrosion aluminum alloy high-voltage vacuum power distribution cabinet |
CN105838948A (en) * | 2016-04-08 | 2016-08-10 | 董超超 | Novel high-strength corrosion-resistant electric vehicle shell |
CN105714167A (en) * | 2016-04-08 | 2016-06-29 | 董超超 | Novel high-strength and corrosion-resisting outer wall insulating decorative plate |
CN105838949A (en) * | 2016-04-08 | 2016-08-10 | 董超超 | Novel high-strength corrosion-resistant electrical connector element |
CN105803278A (en) * | 2016-04-08 | 2016-07-27 | 董超超 | Novel high-strength corrosion-resistant aluminum alloy door and window |
CN105803279A (en) * | 2016-04-08 | 2016-07-27 | 董超超 | Novel high-strength corrosion-resistant solar cell frame |
CN106929717A (en) * | 2017-03-24 | 2017-07-07 | 淮北津奥铝业有限公司 | Auto parts and components aluminium alloy |
CN112254563A (en) * | 2019-07-22 | 2021-01-22 | 海德鲁铝业(苏州)有限公司 | Long-life aluminum alloy having high corrosion resistance and spiral grooved tube produced from the alloy |
KR102382428B1 (en) * | 2020-02-04 | 2022-04-04 | (주)휘일 | Receiver drier for vehicle with high corrosion resistance aluminum alloy and manufacturing method thereof |
CN111235437A (en) * | 2020-03-18 | 2020-06-05 | 河南誉金技术服务有限公司 | Al-Mn pipe alloy for household air-conditioning heat exchanger and preparation method thereof |
CN112658053A (en) * | 2020-12-02 | 2021-04-16 | 中南大学 | Method for manufacturing fire extinguisher bottle body through pultrusion |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3386717A (en) * | 1965-04-01 | 1968-06-04 | Kaiser Aluminium Chem Corp | Process and apparatus for heat treating aluminum ingots |
US5906689A (en) * | 1996-06-06 | 1999-05-25 | Reynolds Metals Company | Corrosion resistant aluminum alloy |
US5976278A (en) * | 1997-10-03 | 1999-11-02 | Reynolds Metals Company | Corrosion resistant, drawable and bendable aluminum alloy, process of making aluminum alloy article and article |
US20020007881A1 (en) * | 1999-02-22 | 2002-01-24 | Ole Daaland | High corrosion resistant aluminium alloy |
FR2819525B1 (en) * | 2001-01-12 | 2003-02-28 | Pechiney Rhenalu | LAMINATED OR ALUMINUM AL-Mn ALLOY PRODUCTS WITH IMPROVED CORROSION RESISTANCE |
JP2005068557A (en) * | 2003-08-07 | 2005-03-17 | Showa Denko Kk | Aluminum alloy excellent in high-temperature strength, member for heat exchanger, heat exchange tube, and heat exchanger |
-
2007
- 2007-07-27 FR FR0705510A patent/FR2919306B1/en active Active
-
2008
- 2008-07-21 CN CN200880100602A patent/CN101765674A/en active Pending
- 2008-07-21 JP JP2010517445A patent/JP2010534766A/en active Pending
- 2008-07-21 WO PCT/FR2008/001074 patent/WO2009043993A1/en active Application Filing
- 2008-07-21 MX MX2010000785A patent/MX2010000785A/en unknown
- 2008-07-21 KR KR1020107004041A patent/KR20100065289A/en not_active Application Discontinuation
- 2008-07-21 BR BRPI0814138-0A2A patent/BRPI0814138A2/en not_active Application Discontinuation
- 2008-07-21 EP EP08835982.3A patent/EP2171114B1/en active Active
- 2008-07-21 US US12/670,538 patent/US20100190027A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2009043993A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2009043993A1 (en) | 2009-04-09 |
EP2171114B1 (en) | 2017-03-22 |
KR20100065289A (en) | 2010-06-16 |
FR2919306B1 (en) | 2009-10-02 |
US20100190027A1 (en) | 2010-07-29 |
JP2010534766A (en) | 2010-11-11 |
MX2010000785A (en) | 2010-03-30 |
BRPI0814138A2 (en) | 2015-02-03 |
FR2919306A1 (en) | 2009-01-30 |
CN101765674A (en) | 2010-06-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2171114B1 (en) | Extruded products in aluminium alloy al-mn with improved mechanical strength | |
EP2171111B1 (en) | Extruded product made from aluminium alloy al-mg-si with improved resistance to corrosion | |
JP4563204B2 (en) | Aluminum alloy extruded material for heat exchanger and method for producing the same | |
CA2832085C (en) | Aluminium-copper-magnesium alloys that perform well at high temperature | |
JP4630323B2 (en) | Copper alloy tube for heat exchangers with excellent fracture strength | |
CN108456812B (en) | Low-Sc high-strength high-toughness high-hardenability aluminum-zinc-magnesium alloy and preparation method thereof | |
CA2961712C (en) | Isotropic aluminium-copper-lithium alloy sheets for producing aeroplane fuselages | |
EP2981632B1 (en) | Thin sheets made of an aluminium-copper-lithium alloy for producing airplane fuselages | |
FR2797454A1 (en) | ALUMINUM ALLOY TAPE OR TUBE FOR MANUFACTURING ARM HEAT EXCHANGERS | |
EP2283166A1 (en) | Al-mn based aluminium alloy composition combined with a homogenization treatment | |
FR2837499A1 (en) | High strength aluminum-magnesium alloy products for welded structures, notably for road, rail and industrial vehicles, includes manganese and zinc | |
EP1349965B1 (en) | Rolled or extruded aluminium al-mn alloy products with improved corrosion resistance | |
EP3728667B1 (en) | Improved process for manufacturing sheets made of aluminium-copper-lithium alloy for aircraft fuselage manufacture and corresponding sheet | |
WO2017093627A9 (en) | Highly rigid thin sheet metal for car body | |
WO2003044235A2 (en) | Aluminium alloy strips for heat exchangers | |
JP2008050657A (en) | Aluminum piping material for automobile heat exchanger | |
JPH07197165A (en) | High wear resistant free cutting aluminum alloy and its production | |
FR2944029A1 (en) | 6XXX SERIES ALLOY ALLOY ALLOY | |
FR2857981A1 (en) | Thin sheet or strip of aluminum alloy for bottle caps and wrapping foil has a thickness of less than 200 microns, is essentially free of manganese, and has increased mechanical strength | |
EP2716403A1 (en) | Copper alloys for heat exchangers | |
JPH11199961A (en) | Aluminum alloy piping material and its production | |
WO2023187301A1 (en) | Recycled 6xxx alloy sheet and manufacturing process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20100203 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA MK RS |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: PIGNATEL, JEROME Inventor name: BIGOT, ANNABELLE Inventor name: MORERE, BRUCE |
|
17Q | First examination report despatched |
Effective date: 20100929 |
|
DAX | Request for extension of the european patent (deleted) | ||
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: CONSTELLIUM FRANCE |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: CONSTELLIUM ISSOIRE |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R079 Ref document number: 602008049384 Country of ref document: DE Free format text: PREVIOUS MAIN CLASS: C22F0001040000 Ipc: C22C0021000000 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: F28F 21/08 20060101ALI20160913BHEP Ipc: C22F 1/04 20060101ALI20160913BHEP Ipc: C22C 21/00 20060101AFI20160913BHEP |
|
INTG | Intention to grant announced |
Effective date: 20161018 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 877849 Country of ref document: AT Kind code of ref document: T Effective date: 20170415 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602008049384 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20170322 Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170622 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170623 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 877849 Country of ref document: AT Kind code of ref document: T Effective date: 20170322 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170622 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170722 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170724 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602008049384 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 |
|
26N | No opposition filed |
Effective date: 20180102 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170731 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170721 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170731 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20170731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170721 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 11 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20080721 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170322 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230411 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20230727 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230725 Year of fee payment: 16 Ref country code: DE Payment date: 20230727 Year of fee payment: 16 |