EP2162227A1 - Coating device and coating method having a constant directing air temperature - Google Patents
Coating device and coating method having a constant directing air temperatureInfo
- Publication number
- EP2162227A1 EP2162227A1 EP08773563A EP08773563A EP2162227A1 EP 2162227 A1 EP2162227 A1 EP 2162227A1 EP 08773563 A EP08773563 A EP 08773563A EP 08773563 A EP08773563 A EP 08773563A EP 2162227 A1 EP2162227 A1 EP 2162227A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- shaping air
- atomizer
- air
- coating
- control unit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 53
- 239000011248 coating agent Substances 0.000 title claims abstract description 43
- 239000007921 spray Substances 0.000 claims abstract description 16
- 238000007493 shaping process Methods 0.000 claims description 120
- 238000001816 cooling Methods 0.000 claims description 29
- 238000010438 heat treatment Methods 0.000 claims description 22
- 238000005496 tempering Methods 0.000 claims description 20
- 239000002826 coolant Substances 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- GRNHLFULJDXJKR-UHFFFAOYSA-N 3-(2-sulfanylethyl)-1h-quinazoline-2,4-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)NC2=C1 GRNHLFULJDXJKR-UHFFFAOYSA-N 0.000 claims 4
- 238000007599 discharging Methods 0.000 claims 2
- 239000003973 paint Substances 0.000 description 7
- 238000010422 painting Methods 0.000 description 5
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007591 painting process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B3/00—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
- B05B3/02—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements
- B05B3/10—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements discharging over substantially the whole periphery of the rotating member, i.e. the spraying being effected by centrifugal forces
- B05B3/1092—Means for supplying shaping gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B3/00—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
- B05B3/001—Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements incorporating means for heating or cooling, e.g. the material to be sprayed
Definitions
- the invention relates to a coating device and a corresponding coating method according to the subordinate claims, in particular for painting motor vehicle body parts.
- rotary atomizers are conventionally used which are pneumatically driven by means of a compressed air turbine and which atomise the paint to be applied by means of a bell disk rotating at high speed. It is also known to mold the applied by the bell cup spray of the paint to be applied by so-called shaping air.
- shaping air for this purpose, in the rotary atomizer axially behind the bell cup steering air nozzles are attached, which deliver a directing air jet substantially in the axial direction from behind onto the spray jet, so that the opening angle of the spray jet can be influenced by the directing air jet.
- JP 08 108 104 A the supplied shaping air by means of an electric heater and a temperature control to a certain temperature preheat temperature, so that the temperature drop of the shaping air when leaving the shaping air nozzles is no longer sufficient to cause the disturbing condensation.
- rotary atomizers with a pneumatic drive by means of a compressed air turbine
- rotary atomizers with a pneumatic drive by means of a compressed air turbine
- the bell cup is driven by an electric motor.
- the steering air can also be used for cooling the electric motor by the steering air is passed through the stator of the electric motor and thereby absorbs part of the resulting in the stator electrical heat loss and dissipates.
- the shaping air during the passage through the rotary atomizer is thus thermally influenced as a function of the operating state of the rotary atomizer, so that the shaping air temperature at the outlet of the shaping air nozzle varies as a function of the operating state of the rotary atomizer, which has a negative effect on the rotational atomizer
- Paint process has an effect, since the applied paint arrives drier or wetter depending on the Lenklufttemperatur on the component to be painted.
- WO 88/00675 A1 discloses only generally a temperature control device for flowable masses. A tempering of the shaping air of an atomizer is not known from this citation.
- the invention is therefore based on the object to improve the quality of painting in the known rotary atomizers and to provide a corresponding operating method for rotary atomizer.
- the invention comprises the general technical teaching to keep the shaping air temperature at the outlet of the shaping air nozzle constant, independently of the operating state of the rotary atomizer, so that the coating quality is not impaired by fluctuations in the shaping air temperature.
- a coating device with an atomizer (eg a rotary atomizer) for applying a spray of a coating agent (eg wet paint) to a component to be coated, such as a motor vehicle body part.
- a coating agent eg wet paint
- the invention is not limited to rotary atomizers in terms of the type of atomizer. Rather, the invention is also feasible with other types of atomizers, such as airless atomizers, airmix atomizers, air atomizers or ultrasonic atomizers, to name but a few possible types of atomizers.
- the invention with respect to the coating composition is not limited to water-based paint, but also with other types of coating materials feasible, such as solvent or powder coatings.
- the invention is not limited to the coating of motor vehicle body parts, but also for the coating of other components used, such as for coating attachments or the like.
- the coating device according to the invention has at least one shaping air nozzle for delivery of shaping air in order to form the spray jet by means of the shaping air.
- the shaping air nozzle can optionally be integrated in the atomizer or structurally separated from the atomizer.
- the coating device according to the invention has a tempering device in order to temper the shaping air, ie to heat or cool it.
- the invention now additionally provides a control unit, which controls the temperature control device as a function of at least one operating variable (eg ambient temperature, volume flow of the shaping air) of the atomizer in order to set a predetermined, preferably constant steering air temperature.
- control unit or control used in the context of the invention is preferably to be understood in the narrower regulation-technical sense, according to which the shaping air temperature is set as a controlled variable as a function of the operating variable of the atomizer serving as a control variable without feedback.
- the term of a control unit or control used in the context of the invention is not limited to the aforementioned conceptual understanding of terms, but also includes, for example, controls with a pilot control or similar combinations of a controller and a controller.
- the shaping air in the preferred embodiment of the invention is at least partially passed through the atomizer to the shaping air nozzle, the atomizer thermally influenced the shaping air depending on its operating state, for example by the electrical heat loss of an electric drive motor or by the Relaxation of the shaping air at the exit from the shaping air nozzle.
- the control unit therefore takes into account when controlling the tempering device for the shaping air preferably the operating size of the atomizer, which also the thermal influence of the shaping air in the atomizer determined. This may be, for example, the drive power of an electric drive motor of the atomizer, since the drive power of the drive motor also determines the heat loss and thus the heating of the shaping air.
- the temperature control device has a heating device which heats the shaping air with an adjustable heating power, which is already known from JP 08 108 104 A and therefore need not be described further.
- the temperature control device has a cooling device which cools the shaping air with an adjustable cooling capacity.
- the term used in the invention of a temperature control thus includes both a targeted heating of the shaping air and a targeted cooling of the shaping air in order to achieve a constant as possible steering air temperature at the output of the shaping air nozzle.
- the atomizer is a rotary atomizer which has an air bearing which is supplied with engine bearing air via a bearing air feed.
- the engine bearing air can also for
- Cooling of the shaping air can be used by, for example, a part of the engine bearing air is added to the shaping air.
- the cooling of the shaping air is effected by a separate coolant supply, which supplies a gaseous or liquid coolant for cooling the shaping air.
- a separate coolant supply which supplies a gaseous or liquid coolant for cooling the shaping air.
- the cooling device it is possible within the scope of the invention for the cooling device to have an electro-thermal converter, for example a Peltier element.
- the invention is therefore not limited to the above-described variants with regard to the mode of operation of the cooling device, but can also be realized in another way.
- the atomizer can be a novel rotary atomizer, in which the bell cup is not driven in a conventional manner by a pneumatic air turbine, but by an electric drive motor.
- the shaping air can be thermally coupled to the drive motor to cool the drive motor during operation by the shaping air.
- the thermal coupling between the shaping air and the drive motor can be achieved by guiding the shaping air at least partially through the drive motor, which is known from the patent application WO 2005/110619 A1 cited above, so that the content of this patent application of this description is fully attributable.
- the heating of the steering air is harmless by the heat loss of the electric drive motor, because this thermal influence can be compensated by the temperature control, so that the steering air temperature kept constant regardless of the drive power of the electric drive motor becomes.
- the tempering device can optionally temper the shaping air upstream of the drive motor or downstream of the drive motor.
- the coating device according to the invention preferably has a thermally conductive connection between the heat-generating drive motor of the atomizer and the heat-emitting outer surface of the atomizer, wherein this heat-conducting compound can be effected for example by a conventional thermal paste.
- control unit controls the temperature control device in dependence on the measured ambient temperature to keep the steering air temperature constant regardless of fluctuations in the ambient temperature.
- the ambient temperature serving as the input variable for the control can hereby optionally be measured, modeled or predetermined in any other way by a temperature sensor.
- control unit preferably controls the temperature control device as a function of the drive power in order to keep the guide air temperature constant, independently of the current drive power and the associated heat loss in the drive motor.
- the drive power used as the input variable for the control can hereby optionally be measured, modeled or predetermined, for example, by a motor controller.
- control unit actuates the temperature control device for the steering air as a function of the current volume flow of the shaping air in order to achieve a constant shaping air temperature independently of changes in the volume flow of the shaping air.
- the volume flow of the shaping air serving as an input variable for the control can be measured, for example, liert or be prescribed in any other way.
- a volumetric flow sensor is provided which measures the volume flow of the shaping air and feeds the measured value to the control unit as an input.
- the atomizer on its outer side has at least one heat sink, for example in the form of cooling fins, in order to achieve as long as possible constant thermal conditions in the atomizer.
- the heat sink can also be formed by the outer surface of the atomizer, that is, in a rotary atomizer through the Zerstäubermantel phenomenon.
- a thermal paste can be used to achieve the best possible thermal contact between the heat-generating drive motor and the heat sink.
- the invention is directed not only to a coating device, but also to a corresponding coating method.
- FIG. 1 is a simplified, schematic representation of a coating device according to the invention with a rotary atomizer and a temperature control device for controlling the tempering air and
- FIG. 2 shows an equivalent circuit diagram of the coating device from FIG. 1.
- FIG. 1 shows in greatly simplified form a coating device according to the invention with a rotary atomizer 1, which can be used for painting motor vehicle body parts or other components.
- the paint to be applied is in this case atomized by a rotating bell cup 2 and discharged in the form of a spray jet 3.
- the bell cup 2 is in this case mounted on a rotatably mounted bell-plate shaft 4, wherein the bell-plate shaft 4 is driven by an electric motor 5 shown here only schematically.
- the rotary atomizer 1 allows a shaping of the spray jet 3 by shaping air, wherein the shaping air is supplied to the rotary atomizer 1 via a connecting flange 6, as will be described in detail.
- the shaping air is guided in shaping air ducts 7 to shaping air nozzles 8 on the front end side of the rotary atomizer 1, where the shaping air is directed essentially axially from behind onto the spray jet 3 of the paint to be applied, so that the opening angle of the spray jet 3 can be adjusted by the delivery of the shaping air from the steering air nozzles 8.
- the shaping air line 7 in this case runs in the rotary atomizer 1 through the stator of the electric motor 5, so that the shaping air is electrically discharged when it is passed through the electric motor 5. absorbs heat loss, which arises during operation in the electric motor 5, which contributes to the cooling of the electric motor 5.
- the shaping air when leaving the shaping air nozzles 8, the shaping air undergoes a sharp drop in temperature due to the throttling, whereby this temperature drop depends inter alia on the volume flow of the applied shaping air and can therefore fluctuate during operation of the rotary atomizer 1.
- the steering air temperature therefore varies as a function of the electrical heat loss which the steering air absorbs when passing through the electric motor 5 from the electric motor 5, the heating of the steering air being dependent on the current drive power of the electric motor 5 by the electric motor 5.
- the deflection air temperature also varies according to the temperature drop when leaving the shaping air nozzles 8 as a function of the volume flow of the shaping air.
- the invention therefore provides that the tempering of the shaping air supplied to the rotary atomizer 1 is controlled as a function of the current operating state of the rotary atomizer 1 so that the shaping air temperature after leaving the shaping air nozzles 8 maintains a predetermined, constant value T SOLL . This is advantageous because the quality of the painting process is then not affected by fluctuations in the shaping air temperature as a function of the operating state of the rotary atomizer 1.
- the coating device according to the invention therefore has a tempering device 9 which can heat and / or cool the shaping air supplied to the rotary atomizer 1 in order to ensure that the shaping air temperature at the outlet of the shaping air nozzles 8 is independent of the operating state of the rotary atomizer 1 and the associated heating or Cooling of the shaping air in the rotary atomizer 1 the predetermined setpoint T SOL L complies.
- the temperature control device is controlled by a control unit 10, wherein the control unit 10 adjusts the heating power or cooling power of the temperature control device 9 as a function of a plurality of operating variables of the rotary atomizer 1 such that the steering air temperature at the output of the shaping air nozzles 8 complies with the predetermined desired value T SOLL .
- the control unit 10 controls the tempering device 9 in such a way that the heating power of the temperature control device 9 is lowered or the cooling power of the tempering device 9 is lowered. tion device 9 is increased to compensate for the increased heat input by the electric motor 5.
- control unit 10 is input connected to a temperature sensor 11 which measures the ambient temperature T AMBIENT, wherein the control ⁇ unit 10 9 controls the temperature control device as a function of the measured ambient temperature T ambient,.
- control unit 10 is connected on the input side to a volumetric flow sensor 12, which measures the total volume flow Q STEERING AIR of the applied shaping air , the control unit 10 also activating the temperature control device 9 as a function of the measured volume flow Q STEERING AIR .
- volume flow Q LENKLUFT is provided by a volume flow controller, wherein the volume flow controller adjusts the flow rate Q LENKLUFT to a predetermined desired value.
- control unit 10 receives on the input side the setpoint T SOLL for the desired shaping air temperature, wherein the control unit 10 also controls the temperature control device 9 as a function of this setpoint T SOLL .
- control unit 10 in the control of the temperature control device 9 also further operating variables of Consider rotary atomizer 1, as indicated here only schematically by a block arrow.
- control unit 10 takes into account the control of the temperature control device 9, the thermal power loss P THERM> generated by the electric motor 5 in the rotary atomizer 1, since the thermal power loss P THERM contributes to the heating of the shaping air in the rotary atomizer 1 and therefore kom within the context of temperature control - should be pensiert.
- the thermal power loss P THERM is in this case calculated by a computing unit 13 from the mechanical drive power P MEC H, which is predetermined by a motor controller 14.
- the temperature control device 9 consists of a heating device 15 and a cooling device 16, wherein the heating device 15 heats the shaping air with an adjustable heating power P HEIZ , while the cooling device 16 can cool the shaping air with an adjustable cooling power P RÜHL .
- the control unit 10 controls the heating device 15 with a corresponding control signal a. In the same way, the control unit 10 activates the cooling device 16 with a corresponding control signal b to set the cooling power P RÜHL .
- a steering air system 17 which reproduces the thermal behavior of the steering air in terms of control technology and by the heating power PHEIZ? the cooling capacity P RÜHL and the thermal power loss PTHERM is influenced.
- the control unit 10 now sets the heating power PHEIZ and the cooling power P RÜHL such that the actual value T IST of the shaping air assumes the desired setpoint T SOLL independently of the current operating state of the rotary atomizer 1.
- the temperature control according to the invention is advantageous because it avoids fluctuations in the steering air temperature during operation of the rotary atomizer 1, which contributes to a consistently good painting result.
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Electrostatic Spraying Apparatus (AREA)
- Coating Apparatus (AREA)
- Nozzles (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
- Spray Control Apparatus (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL08773563T PL2162227T3 (en) | 2007-07-02 | 2008-06-20 | Coating device and coating method having a constant directing air temperature |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007030724A DE102007030724A1 (en) | 2007-07-02 | 2007-07-02 | Coating device and coating method with constant shaping air temperature |
PCT/EP2008/005015 WO2009003602A1 (en) | 2007-07-02 | 2008-06-20 | Coating device and coating method having a constant directing air temperature |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2162227A1 true EP2162227A1 (en) | 2010-03-17 |
EP2162227B1 EP2162227B1 (en) | 2011-01-05 |
Family
ID=39760868
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08773563A Active EP2162227B1 (en) | 2007-07-02 | 2008-06-20 | Coating device and coating method having a constant directing air temperature |
Country Status (9)
Country | Link |
---|---|
US (1) | US8807077B2 (en) |
EP (1) | EP2162227B1 (en) |
JP (1) | JP5439368B2 (en) |
CN (1) | CN101687206B (en) |
AT (1) | ATE494071T1 (en) |
DE (2) | DE102007030724A1 (en) |
ES (1) | ES2358866T3 (en) |
PL (1) | PL2162227T3 (en) |
WO (1) | WO2009003602A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010032387A (en) * | 2008-07-29 | 2010-02-12 | Yamabun Denki:Kk | Temperature measuring method, temperature measuring apparatus, temperature control method, temperature control apparatus, correction method, and correction apparatus |
JP6126867B2 (en) * | 2013-02-25 | 2017-05-10 | 東京応化工業株式会社 | Coating apparatus and coating method |
ITFI20130132A1 (en) * | 2013-06-03 | 2014-12-04 | Eurosider Sas Di Milli Ottavio & C | METHOD AND APPARATUS FOR ELECTROSTATIC PAINTING BY MEANS OF ENRICHED OXYGEN VECTOR FLUID |
CN103464318B (en) * | 2013-09-26 | 2015-12-02 | 无锡美灵数码科技有限公司 | Fine nozzle |
CN104635436A (en) * | 2013-11-07 | 2015-05-20 | 沈阳芯源微电子设备有限公司 | Temperature variable curtain-like developing apparatus |
DE102015009214A1 (en) * | 2015-07-15 | 2017-01-19 | Dürr Systems Ag | Coating plant and corresponding operating method |
DE102020119714A1 (en) | 2020-07-27 | 2022-01-27 | Dürr Systems Ag | Device for disinfecting at least one room, in particular a room where people spend time, with an atomizer |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
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US4108241A (en) * | 1975-03-19 | 1978-08-22 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Heat exchanger and method of making |
EP0481247A1 (en) * | 1986-06-26 | 1992-04-22 | DeVILBISS AIR POWER COMPANY | Air bearing rotary atomizer-manifold |
US4936510A (en) * | 1986-06-26 | 1990-06-26 | The Devilbiss Company | Rotary automizer with air cap and retainer |
DE3624844A1 (en) * | 1986-07-23 | 1988-01-28 | Josef Schucker | TEMPERATURE DEVICE FOR LIQUID ADHESIVES |
JPH08108104A (en) | 1994-10-13 | 1996-04-30 | Mazda Motor Corp | Rotational spray electrostatic coating apparatus |
JPH09225350A (en) * | 1996-02-28 | 1997-09-02 | Mazda Motor Corp | Method for rotary atomization coating and apparatus therefor |
JPH09262509A (en) * | 1996-03-29 | 1997-10-07 | Trinity Ind Corp | Multi-color static coater |
WO2000008802A2 (en) * | 1998-08-03 | 2000-02-17 | Doubleclick Inc. | Network for distribution of re-targeted advertising |
JP2000325860A (en) * | 1999-05-18 | 2000-11-28 | Kansai Paint Co Ltd | Coating method |
JP4589512B2 (en) * | 2000-10-05 | 2010-12-01 | 関西ペイント株式会社 | Coating method |
DE10239517A1 (en) * | 2002-08-28 | 2004-03-11 | Dürr Systems GmbH | Coating device with a rotary atomizer and method for controlling its operation |
JP4409910B2 (en) * | 2003-10-31 | 2010-02-03 | 日本ペイント株式会社 | Spray coating apparatus and coating method |
SE527802C2 (en) * | 2004-05-18 | 2006-06-07 | Lind Finance & Dev Ab | Cooling of engine |
US20060175439A1 (en) * | 2005-02-08 | 2006-08-10 | Steur Gunnar V D | Voltage and turbine speed control apparatus for a rotary atomizer |
US20060188645A1 (en) * | 2005-02-18 | 2006-08-24 | Forti Michael S | Deposition device having a thermal control system |
JP2006326460A (en) | 2005-05-25 | 2006-12-07 | Honda Motor Co Ltd | Method and apparatus for applying coating |
DE102006019890B4 (en) * | 2006-04-28 | 2008-10-16 | Dürr Systems GmbH | Atomizer and associated operating method |
DE102006047269A1 (en) * | 2006-10-04 | 2008-04-10 | Robert Bosch Gmbh | converter motor |
-
2007
- 2007-07-02 DE DE102007030724A patent/DE102007030724A1/en not_active Withdrawn
-
2008
- 2008-06-20 EP EP08773563A patent/EP2162227B1/en active Active
- 2008-06-20 AT AT08773563T patent/ATE494071T1/en active
- 2008-06-20 ES ES08773563T patent/ES2358866T3/en active Active
- 2008-06-20 WO PCT/EP2008/005015 patent/WO2009003602A1/en active Application Filing
- 2008-06-20 DE DE502008002226T patent/DE502008002226D1/en active Active
- 2008-06-20 JP JP2010513739A patent/JP5439368B2/en active Active
- 2008-06-20 CN CN2008800230097A patent/CN101687206B/en active Active
- 2008-06-20 US US12/667,249 patent/US8807077B2/en active Active
- 2008-06-20 PL PL08773563T patent/PL2162227T3/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2009003602A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20110159196A1 (en) | 2011-06-30 |
JP5439368B2 (en) | 2014-03-12 |
PL2162227T3 (en) | 2011-06-30 |
DE502008002226D1 (en) | 2011-02-17 |
ES2358866T3 (en) | 2011-05-16 |
EP2162227B1 (en) | 2011-01-05 |
JP2010531726A (en) | 2010-09-30 |
US8807077B2 (en) | 2014-08-19 |
ATE494071T1 (en) | 2011-01-15 |
CN101687206B (en) | 2013-06-05 |
WO2009003602A1 (en) | 2009-01-08 |
DE102007030724A1 (en) | 2009-01-08 |
CN101687206A (en) | 2010-03-31 |
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