EP2132382A1 - Saugfähiges papier mit einzigartigem prägemuster - Google Patents

Saugfähiges papier mit einzigartigem prägemuster

Info

Publication number
EP2132382A1
EP2132382A1 EP08775645A EP08775645A EP2132382A1 EP 2132382 A1 EP2132382 A1 EP 2132382A1 EP 08775645 A EP08775645 A EP 08775645A EP 08775645 A EP08775645 A EP 08775645A EP 2132382 A1 EP2132382 A1 EP 2132382A1
Authority
EP
European Patent Office
Prior art keywords
protuberances
sheet
sheet according
embossing pattern
absorbent sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP08775645A
Other languages
English (en)
French (fr)
Other versions
EP2132382B1 (de
Inventor
Pierre Graff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Essity Operations France SAS
Original Assignee
Georgia Pacific France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Georgia Pacific France SAS filed Critical Georgia Pacific France SAS
Publication of EP2132382A1 publication Critical patent/EP2132382A1/de
Application granted granted Critical
Publication of EP2132382B1 publication Critical patent/EP2132382B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002Tissue paper; Absorbent paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F1/00Mechanical deformation without removing material, e.g. in combination with laminating
    • B31F1/07Embossing, i.e. producing impressions formed by locally deep-drawing, e.g. using rolls provided with complementary profiles
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/02Patterned paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • D21H27/40Multi-ply at least one of the sheets being non-planar, e.g. crêped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0707Embossing by tools working continuously
    • B31F2201/0715The tools being rollers
    • B31F2201/0723Characteristics of the rollers
    • B31F2201/0733Pattern
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0707Embossing by tools working continuously
    • B31F2201/0715The tools being rollers
    • B31F2201/0723Characteristics of the rollers
    • B31F2201/0738Cross sectional profile of the embossments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/15Sheet, web, or layer weakened to permit separation through thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446Wrinkled, creased, crinkled or creped
    • Y10T428/24455Paper
    • Y10T428/24463Plural paper components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24562Interlaminar spaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24612Composite web or sheet

Definitions

  • the present invention relates to an absorbent sheet comprising at least two plies each consisting of at least one embossed sheet of creped paper towel.
  • the invention particularly relates to an absorbent sheet intended for the field of wiping in household, domestic or industrial use, that is to say that can be used as a paper towel, cloth, etc..
  • a creped absorbent paper of low basis weight usually between 12 and 35 g / m 2 per ply, such as cellulose wadding or the wadded fabric.
  • the absorbent paper may be of the TAD or CWP type, two obtaining techniques well known to those skilled in the art.
  • embossing gives bouffant to the sheet and it induces an improvement in the absorption of liquids, touch and softness. It has been sought to further increase the absorption capacity by creating multilayer sheets obtained by combining at least two layers, also called folds, each consisting of at least one of said embossed sheets.
  • the former is known in the field as "nested" or interlocking. It consists first of embossing each of the plies separately so as to form on the surface protrusions generally substantially frustoconical or truncated pyramid. Then glue is deposited on the top of the protuberances of one of the folds, and the folds are arranged so that the faces having the protuberances come opposite, the protuberances of the one between the protuberances of the other. The folds are finally assembled so that the protuberances having been glued together fit between the protuberances of the other fold.
  • the two plies are linked by glue points between the tops of the protuberances of a fold and unembossed areas between the protuberances of the other fold.
  • a structure is produced whose voids thus formed are suitable for ensuring the sheet an improved absorption.
  • the outer faces have a smooth and soft feel due to the recessed areas formed by the back of the protuberances. This technique is illustrated for example by US Pat. No. 3,867,225. It is also known to replace the bonding bond by a mechanical bond such as knurling or marking.
  • points / points II differs from the previous by the relative disposition of the two folds These, after they have been embossed separately, are brought one on the other in order to make the peaks of the protuberances coincide The folds are connected to one another by the peaks of the protuberances, tips against points This technique is illustrated by the US Pat. No. 3,414,459.
  • protuberances are often arranged in rectilinear rows in uniform networks or in patterns composed of polygonal hexagons or diamonds, distributed uniformly in both directions, direction and cross direction, possibly under form of arches or curves, forming in particular sets regularly distributed on the surface of a cut sheet
  • the absorbent sheet cut or pre-cut intended in particular for wiping, comprises at least two folds or group of folds of creped absorbent paper, weight of between 12 and 35 g / m 2 per fold, at least one of the plies having an embossing pattern composed of protuberances, directed towards the inside of said sheet, and forming cavities between them
  • a portion of said protuberances are distributed over at least one of the folds, so as to define curve portions forming in particular concentric circles around or near the geometric center of the contour of said sheet, and all protuberances belonging to a fold of said sheet form alignments which constitute a central symmetry embossing pattern, vis-à-vis the geometric center of the contour of said sheet
  • said embossing pattern may have a symmetry of order 2
  • at least 50% of said protuberances are aligned in portions of the curve.
  • said embossing pattern comprises a central zone formed of concentric circles.
  • said embossing pattern comprises a central zone formed of spirally aligned protuberances.
  • said embossing pattern may comprise an area complementary to the central zone, formed by lines of protuberances parallel to each other.
  • the lines of protuberances can be straight and / or curved.
  • the embossing pattern further comprises a peripheral zone flanking said central zone and / or said complementary zone.
  • each sheet may comprise two embossed folds associated with each other in a "nested" type arrangement.
  • the folds forming the sheet may be associated together by gluing.
  • the protuberances At the level of each sheet according to the invention, the protuberances have an average density of between 2 and 50 protuberances / cm 2 .
  • FIG. 1 is a representation of an embossed fold forming an outer face of an absorbent sheet according to the invention
  • FIG. 2 is a perspective view of a finite element mesh of square patterns
  • FIG. 3 is a partial view in perspective of a finite element mesh of circular patterns
  • Figures 4 and 5 are variants of Figure 1, respectively for a first and a second fold of a sheet
  • FIG. 6 represents an absorbent sheet of the invention seen from above along line I-I of FIG. 7;
  • FIG. 8 illustrates an embossed fold according to another embodiment of the invention.
  • FIG. 9 relates to an embossed ply according to yet another embodiment of the invention.
  • - Figure 10 is an embossing pattern according to the prior art;
  • FIG. 11 shows comparative absorption curves between a product of the prior art and a product according to the invention.
  • FIGS. 12A and 12B show comparative resistance curves for a TAD-type tissue, respectively in the direction of travel and the cross direction of each sheet, as a function of the thickness of a sheet.
  • FIG. 1 illustrates an absorbent sheet in format, that is to say cut in a contour 1 and having inside said contour 1 an embossing comprising protuberances marked here by points 10.
  • each protuberance 10 is less than 6 mm 2 , although different sizes of protuberances 10 are possible on the same pattern; and the tops of the protuberances are directed towards the interior of the sheet which comprises at least two folds.
  • most (at least 50%) of the protuberances 10 are distributed so as to define concentric circles around a point 0 located substantially at the geometric center of the sheet whose contour 1 is preferably square or substantially square .
  • all the protuberances 10 present on the fold considered form a central symmetry embossing pattern vis-à-vis the geometric center 0 of the contour 1 of the sheet.
  • the embossing pattern has a symmetry of order
  • FIG. 2 shows a mathematical simulation, by a well known finite element method, of the traction behavior in two mutually perpendicular directions: one in the direction of travel SM of one sheet, the other in the cross direction ST.
  • the direction of travel SM is the direction of unwinding of the sheet while the transverse direction ST, perpendicular to the direction SM, is the perforations or pre-cuts between the different formats when making rolls of sheets such as toilet paper or paper towels.
  • FIG. 2 shows a simulation of an embossing configuration according to an array of regularly distributed points forming concentric squares.
  • the simulation concerns embossing consisting of concentric circles formed by regularly spaced points.
  • the mathematical simulation consisted of loading in tension on one of the edges of a rectangular sample as illustrated in FIGS. 2 and 3, the opposite edge E being blocked (embedding).
  • the traction is carried out in the direction of walking SM and one obtains values of induced stresses in the sheet, at each point of the mesh, (that is to say on each protuberance of the sheet), according to the direction of the load.
  • FIG. 3 illustrates embossments according to the invention more specifically Figure 4 shows the embossing of a first fold and Figure 5 the embossing of a second fold associated with the first fold according to the technique "nested".
  • the contour sheets 1 have a geometric center 0, a central zone 2 whose embossing pattern is formed of concentric circles, and a complementary zone 3 whose embossing comprises lines of curved protuberances 32; and a symmetry of order 2 along the two axes in phantom, is achieved.
  • Figures 6 and 7 show in greater detail an embodiment of the central portion of an absorbent sheet consisting of two absorbent plies P1 and P2, each composed of paper fibers, creped cellulose wadding, for example.
  • their basis weight is preferably greater than 20 g / m 2 and at least 12 g / m 2. As can be seen in FIG.
  • each of the plies comprises protuberances 10 and 20 respectively.
  • These protuberances were obtained by embossing the pleats, as is well known in the art, between an engraved cylinder and a rubber-coated cylinder. These protuberances increase the apparent thickness of the folds.
  • the base sheet can be from 0.1 to 0.45 mm thick, and after embossing its apparent thickness can be from 0.55 to 2 mm.
  • Each protuberance on one side corresponds to a cavity on the other side.
  • protuberances are in the form of truncated cone or pyramid whose section may be polygonal, oval, circular or other and whose main axis can be oriented either machine direction or cross direction (the machine direction is that of paper scrolling during of its manufacture)
  • the two folds are associated according to the structure "nested".
  • the protuberances 10B of one of the folds P1 are slightly higher than those of the second fold P2.
  • the connection between the folds can be ensured by a layer of an adhesive substance, generally water-based, interposed between the top of the protuberances 10 and the surface of the fold P2
  • the protuberances 20 are at most the same height as the protuberances 10
  • Figure 6 does not exactly reproduce the appearance of a sheet seen from above, but the protuberances 20 are seen HERE by transparency.
  • a square shape has been given to the section of the protuberances 10 of the ply P1 and a round shape to the protuberances 20 of the ply P2, but in practice this section may be chosen in another form.
  • the protuberances are arranged according to circular directions.
  • the protuberances 10 B of the fold P1, forming between them an entire circle, are nested between two rows 2OA and 2OB concentric protuberances of the fold P2.
  • the protuberances 20B are themselves interleaved between the protuberances 10B and 10C aligned in concentric circles.
  • FIG. 8 illustrates the embossing of a fold comprising a central zone 2 formed of protuberances aligned in a spiral, and a complementary zone 3 in which the protuberances are aligned along lines parallel to each other 31.
  • a portion of the protuberances may be distributed along portions of curves near the geometric center O of the cut sheet.
  • the portions of curves are arranged in quarter of concentric circles towards the four corners of said sheet.
  • the sample is laid flat on a porous sintered glass plate with a pore size of 40 ⁇ m.
  • a plate carrying weights is placed on the sample to keep the sample flat.
  • the sample is thus slightly compressed.
  • the porous plate rests on a plate which comprises in its center an orifice of diameter equal to 3 mm into which a flexible tube opens out from below which in this way puts the volume of the porous plate in communication with a liquid reservoir whose level can be adjusted in height compared to that of the porous plate.
  • the tank itself is placed on a scale. This means makes it possible to know the quantity of liquid which has passed into the sample when the reservoir has been raised relative to the porous plate.
  • the liquid is water with 9 g / l of sodium chloride.
  • the procedure involves impregnating the sample through the porous plate by lowering the level of the sample relative to the reservoir. The amount of liquid absorbed is measured every ten seconds simply by measuring the loss of water in the tank. We proceed with different weights
  • Measurements of absorption capacity can also be carried out without pressure.
  • FIG. 11 gives the curves respectively obtained for an embossed sheet according to the prior art (curve A), and according to the invention (curve I)
  • the thickness of the sheets are identical and only the arrangement of the protuberances forming the embossing pattern differs.
  • the sheets are made from a tissue band obtained according to a technique known as CWP (conventional wet pressed), and the protuberances have an average diameter of about 1 mm, a depth of about 1, 4 mm and their density is 6.7 per cm 2 .
  • samples measured are circles of diameter equal to 7.62 cm made from a tissue of cellulose wadding, in a paper weight of 44.2 g / m 2 , having a thickness of approximately 0.23 mm and with an embossing according to one of FIG. 4 or 5.
  • Curve A has a lower slope initially than curve I, which means that the product according to the prior art has a lower absorption rate.
  • the value of the asymptote of the curve A is lower than that of the curve I, which means that the absorption according to the invention is greater than that of the prior art.
  • FIGS. 12A and 12B illustrate the tensile strength of the sheet according to the invention of the TAD type, with respect to a sheet of the same type according to the prior art, according to the thickness of the sheet.
  • the sheet according to the invention comprises two associated plies according to the NESTED mode and has a grammage of the order of 40 g / m 2.
  • the embossing is that according to FIG. 1.
  • the sheet according to the art previous is identical except for the embossing pattern which corresponds HERE to that of Figure 10.
  • FIGS. 12A and 12B show by the two lines drawn with respect to the measurement points a tendency according to which the sheets according to the invention have a better tensile strength than the sheets according to the prior art, regardless of the direction considered (running direction Figure 12A, or crosswise direction Figure 12B).

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)
  • Sanitary Thin Papers (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
EP08775645.8A 2007-03-28 2008-03-12 Saugfähiger papierbogen mit einzigem prägemuster Active EP2132382B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0702267A FR2914221B1 (fr) 2007-03-28 2007-03-28 Feuille absorbante a motif de gaufrage unique
PCT/FR2008/000316 WO2008132331A1 (fr) 2007-03-28 2008-03-12 Feuille absorbante a motif de gaufrage unique

Publications (2)

Publication Number Publication Date
EP2132382A1 true EP2132382A1 (de) 2009-12-16
EP2132382B1 EP2132382B1 (de) 2014-01-15

Family

ID=38828456

Family Applications (1)

Application Number Title Priority Date Filing Date
EP08775645.8A Active EP2132382B1 (de) 2007-03-28 2008-03-12 Saugfähiger papierbogen mit einzigem prägemuster

Country Status (7)

Country Link
US (1) US8309204B2 (de)
EP (1) EP2132382B1 (de)
CA (1) CA2682214A1 (de)
EA (1) EA017002B1 (de)
FR (1) FR2914221B1 (de)
MX (1) MX2009010080A (de)
WO (1) WO2008132331A1 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1845193A1 (de) 2006-04-14 2007-10-17 Georgia-Pacific France Mehrlagiger saugfähiger Papierbogen, Rolle und Verfahren zu seiner Herstellung
ES2547422T3 (es) * 2012-07-10 2015-10-06 Sca Tissue France Un material textil no tejido con textura similar a tela que comprende fibras de fabricación de papel, un rodillo de calandrado y método de fabricación del mismo
US9915034B2 (en) 2014-05-16 2018-03-13 Gpcp Ip Holdings Llc High bulk tissue product
USD798066S1 (en) * 2015-07-02 2017-09-26 Avintiv Specialty Materials Inc. Nonwoven fabric
USD793098S1 (en) * 2015-07-31 2017-08-01 Joanna Collis Panel for an article of clothing
JP7255978B2 (ja) * 2018-06-04 2023-04-11 大王製紙株式会社 キッチンペーパーロール及びキッチンペーパー
WO2022075993A1 (en) 2020-10-09 2022-04-14 Kimberly-Clark Worldwide, Inc. Embossed tissue

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3414459A (en) * 1965-02-01 1968-12-03 Procter & Gamble Compressible laminated paper structure
US3867225A (en) * 1969-01-23 1975-02-18 Paper Converting Machine Co Method for producing laminated embossed webs
FR2774707B1 (fr) * 1998-02-06 2000-04-07 Fort James France Papier absorbant a usage domestique
EP1149552A1 (de) * 2000-04-28 2001-10-31 Georgia-Pacific France Absorbierendes Papierprodukt wie Servietten oder Taschentücher, Verfahren zur Herstellung und Vorrichtungen zur Durchführung dieser Verfahren
EP1209289B1 (de) * 2000-11-24 2015-09-09 Sca Tissue France Gekreppte, saugfähige Papierbahn, Kreppwalze, und Verfahren zur Herstellung solcher Papierbahn
US7083845B2 (en) * 2001-02-23 2006-08-01 Georgia-Pacific France Sheet of absorbent creped paper, cylinder for embossing such a sheet and an embossing process
DE60126636T2 (de) * 2001-12-27 2007-11-22 Georgia-Pacific France Geprägte Papierbahn
EP1331308A1 (de) * 2002-01-25 2003-07-30 Georgia-Pacific France Gekrepptes Blatt eines saugfähigen Papiers, Prägewalze wie auch entsprechendes Verfahren
ES2371547T3 (es) * 2003-03-07 2012-01-05 Georgia-Pacific France Producto en papel absorbente gofrado.

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008132331A1 *

Also Published As

Publication number Publication date
US20100035011A1 (en) 2010-02-11
FR2914221A1 (fr) 2008-10-03
US8309204B2 (en) 2012-11-13
EA200901266A1 (ru) 2010-04-30
WO2008132331A1 (fr) 2008-11-06
EP2132382B1 (de) 2014-01-15
CA2682214A1 (en) 2008-11-06
EA017002B1 (ru) 2012-09-28
FR2914221B1 (fr) 2009-10-02
MX2009010080A (es) 2009-10-16

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