EP2130472A1 - Verbesserter Flüssigkeitsspender mit Rückzugsschutzfunktion - Google Patents

Verbesserter Flüssigkeitsspender mit Rückzugsschutzfunktion Download PDF

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Publication number
EP2130472A1
EP2130472A1 EP09007274A EP09007274A EP2130472A1 EP 2130472 A1 EP2130472 A1 EP 2130472A1 EP 09007274 A EP09007274 A EP 09007274A EP 09007274 A EP09007274 A EP 09007274A EP 2130472 A1 EP2130472 A1 EP 2130472A1
Authority
EP
European Patent Office
Prior art keywords
liquid
nozzle assembly
delivery article
bottle
thickened
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09007274A
Other languages
English (en)
French (fr)
Inventor
Deirdre Mckeown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser LLC
Original Assignee
Reckitt Benckiser LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reckitt Benckiser LLC filed Critical Reckitt Benckiser LLC
Publication of EP2130472A1 publication Critical patent/EP2130472A1/de
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47KSANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K5/00Holders or dispensers for soap, toothpaste, or the like
    • A47K5/06Dispensers for soap
    • A47K5/12Dispensers for soap for liquid or pasty soap
    • A47K5/122Dispensers for soap for liquid or pasty soap using squeeze bottles or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00Closures with filling and discharging, or with discharging, devices
    • B65D47/04Closures with discharging devices other than pumps
    • B65D47/20Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
    • B65D47/2018Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure
    • B65D47/2031Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure the element being formed by a slit, narrow opening or constrictable spout, the size of the outlet passage being able to be varied by increasing or decreasing the pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00Closures with filling and discharging, or with discharging, devices
    • B65D47/04Closures with discharging devices other than pumps
    • B65D47/32Closures with discharging devices other than pumps with means for venting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005Components or details
    • B05B11/0037Containers
    • B05B11/0039Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005Components or details
    • B05B11/0037Containers
    • B05B11/0039Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means
    • B05B11/0044Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means compensating underpressure by ingress of atmospheric air into the container, i.e. with venting means
    • B05B11/00442Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means compensating underpressure by ingress of atmospheric air into the container, i.e. with venting means the means being actuated by the difference between the atmospheric pressure and the pressure inside the container
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/04Deformable containers producing the flow, e.g. squeeze bottles
    • B05B11/047Deformable containers producing the flow, e.g. squeeze bottles characterised by the outlet or venting means

Definitions

  • the present invention relates to an improved liquid dispenser for the delivery of a liquid composition from a bottle to a specific locus. More particularly, the present invention relates to an improved liquid dispenser for the delivery of a liquid composition, preferably a thickened composition, which liquid dispenser comprises an anti-retraction feature.
  • a nozzle can be used to meter the amount of liquid being dispensed, and/or alternately direct the dispensed liquid exiting the bottle in a particular direction.
  • nozzles are typically single piece bottle inserts which provide for a short, restricted passage of the liquid to pass therethrough from within the interior of the bottle.
  • an improved nozzle assembly with an anti-retraction feature which is useful in conjunction with a container, such as a bottle, for the dispensing of a liquid, and particularly for the targeted delivery of a thickened liquid.
  • an improved liquid dispenser which comprises an improved nozzle assembly with an anti-retraction feature as described herein.
  • a combination package and delivery article useful for both storing and dispensing a liquid treatment composition
  • package and delivery article comprises an improved nozzle assembly with an anti-retraction feature as described herein.
  • an improved nozzle assembly as described herein which is advantageously used for the targeted delivery of a drain treatment composition used to treat slow running but especially clogged drains.
  • FIG. 1 depicts in a cross-sectional view an improved nozzle assembly 10 according to one aspect of the invention.
  • the improved nozzle assembly 10 includes a spout portion 12 from which depends a skirt portion 14.
  • the square portion includes an outer wall 16 having a geometry which is adapted to be inserted into the opening of a bottle or other container (not shown) and to form a liquid-tight seal therewith.
  • the outer wall 16 is connected to the base end 18 of the spout portion 12, which base end 18 includes a central opening 20 which in fluid communication with the open tip end 22 of the spout portion 12.
  • the interior of the spout portion 12 is hollow and defines a continuous annular space between the base and 18 and that the tip and 22.
  • the spout portion 12 is also tapered such that it converges as it extends upward from the base end 18 to the open tip end 22 of the spout portion 12.
  • a lateral plate 24 which provides an interconnection between, and a support for the outer wall 16.
  • the position of the lateral plate 24 also acts to divide the interior space between the outer wall 16 into an outward section 26 and an inward section 28, which are respectively bounded by the upper surface 24a of the lateral plate 24 and the outer wall 16 to its upper margin 30, and the lower surface 24b of the lateral plate 24 and the outer wall 16 to its lower margin 32.
  • the upper margin 30 of the outer wall 16 includes a flange 34 which extends outwardly radially therefrom which is useful in affixing or attaching to the improved nozzle assembly 10 to the opening of a bottle or other container.
  • a least one, but preferably a plurality of air passages 36 are present and extend transversely through the lateral plate 24 and provide for a fluid conduit between the outward section 26 and the inward section 28.
  • the improved nozzle assembly 10 also includes a flow check means which provides an anti-retraction feature.
  • the flow check means in the embodiment according to figure 1 is provided as a flexible valve 40 which is present as part of the improved nozzle assembly 10.
  • the flexible valve 40 includes a hollow barrel portion 42 which is continuously open at one end 44 and at the other end is provided a check-valve, here provided as a matched pair of flaps 46a, 46b which, when the flexible valve 40 is unstressed, are biased into a sealing position as is illustrated.
  • a circumferential flap 48 Extending radially outwardly from the hollow barrel portion 42 is a circumferential flap 48 which functions as a second check-valve, which when the flexible valve 40 is unstressed, are biased into a further sealing position as is illustrated abutting against lateral plate 24 and sealing one or more air passages 36.
  • the flexible valve 40 is retained within the interior of the base end 18 of the spout portion 12 by means of a friction fit between the base and 18 and at least part of the barrel portion 42, which also provides for liquid-tight seal therebetween.
  • FIG 2 illustrates a top plan view of the improved nozzle assembly 10 disclosed on Figure 1 .
  • the open tip ends 22 which, as can be seen when viewing down through its hollow interior or visible parts of the matched pair of flaps 46a, 46.
  • the lateral plate 24 including a series of air passages 36 as well as the flange 34.
  • the airpassages 36 are within the outward section 26 and are understood to be visible from the exterior of an improved nozzle assembly 10 when mounted on a bottle or other container (not shown).
  • the inward section 28 faces the interior of the bottle or other container when the improved nozzle assembly 10 is mounted thereon.
  • FIG. 3A illustrates the condition of the elements from figure 1 wherein the pressure at the inward section 28 is greater then the pressure at the outward section 26, such as for example wherein a flexible bottle or other container is compressed such as by the manual squeezing of the same by a user, and/or by the generation of an internal pressures such as by the generation of a gas which may occur depending upon the nature of a composition contained within the bottle or other container.
  • the fluid (which may be a gas, liquid, gel, or other fluid) simultaneously causes the matched pair of flaps 46a, 46b to open which provides for the fluid to pass thereby (as indicated by the arrow "F") and into the hollow interior 13 of the spout portion 12 and ultimately (though not shown) out through the open tip end 22 of the spout portion 12, while the same fluid urges the circumferential flap 48 of the flexible valve 40 against the lateral plate 24 which functions to the seal the plurality of air passages 36 and thereby denying the passage of the fluid to exit via these air passages 36.
  • the fluid which may be a gas, liquid, gel, or other fluid
  • FIG. 3B this figure illustrates the converse condition namely wherein the pressure at the inward section 28 is less than the pressure at the outward section 26 of the improved nozzle assembly 10.
  • a compressed flexible bottle or other container it is released and is allowed to expand to an unstressed condition which causes a pressure drop within the interior of the bottle or other container with respect to the pressure at the exterior of the bottle or other container.
  • the matched pair of flaps 46a, 46b of the flexible valve 40 or forced together and to form a seal therebetween which denies for the passage of any fluid "F" which may be present within the hollow interior 13 of the spout portion 12, but simultaneously, the circumferential flap 48 of the flexible valve 40 moves away from the lateral plate 24 and permits for the entry of a fluid, preferably ambient air, through one or more of the plurality of air passages 36 (as indicated by arrows "A") from the outward section 26 and into the inward section 28.
  • a fluid preferably ambient air
  • the improved valve assembly 10 is advantageously mounted within an opening of a bottle or other container, such an operation provides an anti-retraction benefit in that it denies for the return of any liquid which had been previously expelled past the flexible valve 40 and into the hollow interior 13 of the spout portion 12, or alternately denies the entry of any liquid which may be present in the hollow interior 13 of the spout portion 12 which had entered via the open tip end 22 of the spout portion 12, past the flexible valve, into the inward section 28 and ultimately into the bottle or other container upon which the improved nozzle assembly 10 is mounted.
  • This eliminates the likelihood of contamination of the composition contained within the interior of the bottle or other container.
  • the operation of the circumferential flap 48 of the flexible valve 40 permits sufficient passage of ambient air to allow a compressed bottle or other container to assume its unstressed and normal shape after the targeted delivery of the composition contained therein.
  • the foregoing features of the improved nozzle assembly 10 and the anti-retraction benefit provided thereby is particularly advantageous for the targeted delivery of a liquid composition through the spout portion 12 particularly when the spout portion 12 is downwardly directed, that is to say when a combination package and delivery article, which may be in its simplest form a bottle or other container having mounted thereon and improved nozzle assembly 10, is inferred it is such that the bottle or other container is directed vertically upwardly and above the improved nozzle assembly 10 and the open tip end 22 is directed downwardly with respect thereto.
  • a combination package and delivery article is used to provide for the targeted delivery of a composition through a second that liquid, such as standing water such as may be present in a sink or other base and having a drain at the bottom thereof
  • the improved nozzle assemblies and the combination package and delivery article are a particularly advantageously employed in the delivery of a thickened liquid, e.g., a drain treatment composition, such as a thickened blcach containing liquid and/or alternately a thickened alkaline liquid, and/or alternately a thickened acidic liquid to a desired position or locus.
  • a thickened liquid generally has a viscosity of at least about 50 cps, preferably at least about 100 cps, yet more preferably at least about 200 cps.
  • such any thickened liquid has a viscosity of not more than about 1500 cps, preferably not more than about 700 cps, and still more preferably not more than about 500 cps.
  • the foregoing viscosities can be easily measured by routine analytical methods at room temperature, such as by the use of Brookfield viscometer using an appropriate spindle and rotational speed.
  • the improved nozzle assemblies are useful in providing for the targeted delivery of a thickened composition, e.g., drain treatment composition, especially a thickened bleach composition having and alkaline pH (a pH of greater than 7, preferably a pH of 10 or greater) to a specific location through a different standing liquid.
  • a thickened composition e.g., drain treatment composition
  • a thickened bleach composition having and alkaline pH (a pH of greater than 7, preferably a pH of 10 or greater) to a specific location through a different standing liquid.
  • the improved nozzle assemblies are particularly useful in providing directly to a sink drain or a sink trap a liquid composition particularly a thickened alkaline compositions such as a thickened bleach composition which may provide a useful benefit in clearing a drain clog.
  • a consumer can conveniently open up a container such as any compressible or squeezable thermoplastic bottle containing a quantity of a drain treatment composition, including but not limited to a thickened bleach composition, invert the bottle such that the tip is pointed downwardly and extends through standing water such as maybe found in a clogged kitchen or bathroom sink, insert the tip has far down in the drain or drain opening as possible, and then squeeze the bottle thereby forcing the composition contained therein down through the nozzle assembly and the directly in the proximity of the drain or drain opening.
  • a container such as any compressible or squeezable thermoplastic bottle containing a quantity of a drain treatment composition, including but not limited to a thickened bleach composition, invert the bottle such that the tip is pointed downwardly and extends through standing water such as maybe found in a clogged kitchen or bathroom sink, insert the tip has far down in the drain or drain opening as possible, and then squeeze the bottle thereby forcing the composition contained therein down through the nozzle assembly and the directly in the proximity of the drain or drain opening.
  • the anti-retraction feature of the nozzle assembly ensures that none of the standing liquid enters into the interior of the container on which the nozzle assembly is mounted.
  • the nozzle assembly also permits for the venting of the contents of the bottle in a safe manner by permitting for the exit of any gas which may be generated by the composition through the nozzle, while at the same time resisting the egress of the liquid composition. Such reduces the incidence of bloating and undesired expansion of the container when stored or between dispensing operations.
  • FIG. 4 there is depicted a further embodiment of an improved nozzle assembly 10 according to the present invention which is substantially similar to the embodiment depicted with reference to Figure 1 except that the embodiment according to Figure 4 further comprises a support washer 50 upon which a portion of the flexible valve 40 is mounted, and wherein the support washer 50 is positioned within the inward section 28 and between the circumferential flap 48 of the flexible valve 40, and the lateral plate 24.
  • a support washer 50 may be utilized for example wherein the configuration of the flexible valve 40 is inconveniently or impossible to directly mount to a portion of the spout portion 12 in the manner described with reference to Figure 1 . Further details of the flexible valve 40 ended the support washer 50 are described with reference to Figs. 5A, 5B and 5C.
  • Fig. 5A illustrates in a cross-sectional view a flexible valve 40 mounted through the central bore 54 of a support washer 50 and also illustrates the respective positioning of air passage slots 52 with respect to the circumferential flap 48 of the flexible valve 40.
  • a flexible valve 40 shown in an unstressed condition, that is to say when there is essentially an equilibrium of pressure between the interior part of a bottle or other container (not shown) and the inward section 28, and the ambient pressure on the exterior of the bottle or other container and the outward section 24 of an improved valve assembly 10 of which the flexible valve 40 forms a part.
  • Fig. 5B illustrates a perspective view and embodiment of a support washer 50 illustrating the central bore 54 and a plurality of air passage slots 52.
  • Fig. 5C illustrate aside plan view of the flexible valve 40, including a view of the circumferential flap 48 and flap 46a.
  • Fig. 6 illustrates a further embodiment of the present invention and in particular illustrates an alternative embodiment of a flexible valve 40 according to the present invention.
  • the flexible valve 40 includes a hollow barrel portion 42 which is continuously open at one end 44 and at the other end is provided a check-valve, provided as a matched pair of flaps 46a, 46b which, when the flexible valve 40 is unstressed, are biased into a sealing position as is illustrated.
  • a circumferential base 56 which includes in an upper part thereof an annular trough 58 which is both in fluid communication with one or more of the air passages 36, and with an inverted check valve 60, and via a corresponding conduit 62.
  • the inverted check valve 60 is a second check valve which is directed into the inward section 28 and works in a manner opposite to that of the first check valve provided by flaps 46a, 46b. More specifically, when the pressure present at the inward section 28 is greater than the pressure at the outward section 24, the flaps 46a, 46b are urged to open and allow for the passage of any fluid past flaps 46a, 46b while simultaneously, the second set of flaps 46a, 46b of the inverted check valve 60 arc urged to close in denying the passage of any of said fluid past them.
  • FIG. 6 illustrates the arrangement of the flexible valve 40 when there is a respective relative equilibrium between the inward section 28 and the outward section 24, corresponding respectively to a pressure equilibrium between the interior of a bottle or flask upon which the improved nozzle assembly 10 is mounted, and the ambient air or atmosphere surrounding the improved nozzle assembly 10.
  • Fig. 7 illustrates an embodiment of a process for the targeted delivery of a treatment composition, here a drain treatment composition from a combination package and delivery article useful for both storing and dispensing a liquid treatment composition, which package and delivery article comprises the improved nozzle assembly.
  • a bottle 70 here a flexible bottle advantageously formed from a flexible polymer which is sufficiently stiff so to substantially return to its uncompressed configuration following release of any compressing pressures, is affixed via its opening to an improved nozzle assembly 10 in a liquid seal-tight relationship.
  • the bottle 70 is inverted is such that the spout portion 12 extends downward lead through a volume of a liquid 71, here water standing in a sink 70 due to the presence of a clog (not shown) within a drainpipe 74 downstream of a drain 72.
  • the open tip end 22 of the spout portion 12 it is positioned to be adjacent to, in the proximity of, but desirably within the drain 72.
  • the skirt portion 14 is above the top surface 74 of the liquid 71 so that the air passages 36 (not visible) are in communication with the ambient air and not immersed within the liquid 71.
  • a user or consumer following positioning of the combination package and delivery article 80 in the manner outlined above may dispense a quantity of a liquid treatment composition contained within the bottle 70 such that it passes downward lead through the spout portion 12, exits via the open tip and 22 and is directed into the drain 72.
  • the bottle 70 cannot be further compressed, it may be released which, due to the anti-retraction feature of the improved nozzle assembly 10 denies for the drawback of any liquid contained within the interior of the spout portion 12 to enter into the interior of the bottle 70, but which allows for the entry of ambient air via the improved nozzle assembly 10 into the interior of the bottle 70 so that it retains its prior unstressed shape and additionally now also contains a volume of air trapped within the interior of the bottle.
  • the consumer may then repeat the application process, and again compress the bottle 70 which forces a further quantity of a treatment composition downwardly from the bottle, through the spout portion and out from the open tip and 22 and into the drain 72.
  • This sequence of steps may be repeated as many times as is thought necessary or desirable by the consumer.
  • the utilization of the improved nozzle assembly 10 ensures that none of the liquid 71 enters into the interior of the bottle 70 to regardless of the number of dispensing applications providing a targeted delivery of the treatment composition as hereinbefore described.
  • nozzle assembly of the invention may be formed of any of a variety of materials, advantageously the use of a synthetic polymers including thermosettable or thermo formable synthetic polymers such as are widely used in casting or injection molding.
  • exemplary synthetic polymers such as polyamides, polyolefins (e.g., polypropylene, polyethylene) as well as polyalkyleneterephalates (i.e., polyethylene terephthalate, polybutylene terephthalate), polystyrenes, polysulfones, polycarbonates as well as copolymers formed from monomers of one or more of the foregoing being several nonlimiting examples of useful synthetic polymers.
  • the material or materials of construction of the nozzle assembly is selected also as to not be deleteriously affected by the contents of the container which are to be used with the nozzle assembly.
  • contents are chemical compositions, e.g., aqueous or non-aqueous liquid compositions which comprise one or more surfactants, solvents, etc.
  • a synthetic polymer which is essentially chemically inert to such compositions is preferably used.
  • all of the elements of the nozzle are formed from non-porous materials, preferably non-porous thermoplastic synthetic polymers such as synthetic polymers based on one or more polyolefins.
  • the flexible valve of the nozzle assembly of the invention maybe formed of any flexible or elastomer material in his most desirably formed of a material which has a "shape memory" and which will return to an unstressed configuration upon the release or removal of any stresses or other pressures causing deformation of the same.
  • Many synthetic elastomer scum as well as naturally occurring may be used including without limitation natural and synthetic rubbers, neoprene, polyisoprenc, silicone based materials and the like.
  • the material of construction for the flexible valve is one which also exhibits an acceptable degree of chemical resistance to any composition which may be dispensed via an improved nozzle assembly as described herein.
  • silicone based materials are advantageously used as a being relatively simple to form, such as by molding into a desired configuration of the flexible valve means, provide a good degree of chemical resistance and at the same time exhibit a good "shape memory".

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Closures For Containers (AREA)
EP09007274A 2008-06-05 2009-06-01 Verbesserter Flüssigkeitsspender mit Rückzugsschutzfunktion Withdrawn EP2130472A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB0810306A GB2460688A (en) 2008-06-05 2008-06-05 Nozzle assembly with flexible valve

Publications (1)

Publication Number Publication Date
EP2130472A1 true EP2130472A1 (de) 2009-12-09

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US (1) US20090302073A1 (de)
EP (1) EP2130472A1 (de)
GB (1) GB2460688A (de)

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AT516449A1 (de) * 2014-11-13 2016-05-15 Wieder Manuel Verschluss für eine Trinkflasche
CN105992541A (zh) * 2013-10-24 2016-10-05 艺康美国股份有限公司 单件三通弹性体阀

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2700588A1 (de) * 2012-08-21 2014-02-26 EP Systems SA Spenderverschluss mit Belüftungsventil
CN105992541A (zh) * 2013-10-24 2016-10-05 艺康美国股份有限公司 单件三通弹性体阀
CN105992541B (zh) * 2013-10-24 2019-06-25 艺康美国股份有限公司 单件三通弹性体阀
AT516449A1 (de) * 2014-11-13 2016-05-15 Wieder Manuel Verschluss für eine Trinkflasche
AT516449B1 (de) * 2014-11-13 2016-07-15 Wieder Manuel Verschluss für eine Trinkflasche
US9834345B2 (en) 2014-11-13 2017-12-05 Manuel Wieder Closure for a bottle

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GB2460688A (en) 2009-12-09
US20090302073A1 (en) 2009-12-10
GB0810306D0 (en) 2008-07-09

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