EP2097501A1 - Foaming hard surface cleaner - Google Patents
Foaming hard surface cleanerInfo
- Publication number
- EP2097501A1 EP2097501A1 EP06839936A EP06839936A EP2097501A1 EP 2097501 A1 EP2097501 A1 EP 2097501A1 EP 06839936 A EP06839936 A EP 06839936A EP 06839936 A EP06839936 A EP 06839936A EP 2097501 A1 EP2097501 A1 EP 2097501A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- foamable composition
- horizontal line
- foamable
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Definitions
- Hard surface cleaners are usually mostly water that include cleaning materials, fragrance, and color. Hard Surface cleaners are usually sprayed onto a surface and then wiped to clean the surface. Because hard surface cleaners are mostly water, they will drip when applied to vertical surfaces because of gravity.
- a foamable composition comprising: a) at least one anionic surfactant chosen from a salt of an alkyl sulfate and a salt of an alkyl ether sulfate in an amount of about 0.01 to about 1% by weight of the composition; b) at least one glycol ether in an amount of about 0.1 to about 1.5% by weight of the composition; c) at least one alcohol in an amount of about 2 to about 6 % by weight of the composition; and d) water.
- a foamable composition comprising: a) at least one anionic surfactant chosen from a salt of an alkyl sulfate and a salt of an alkyl ether sulfate; b) at least one glycol ether; and c) at least one alcohol; and d) water, wherein the composition has a run down time of greater than about 15 seconds, wherein the run down time is measured by providing a vertical glass surface, which is perpendicular to the earth's surface, with a first horizontal line that is 10 cm above a second horizontal line and both are parallel to the earth's surface, applying the composition to the vertical glass surface at the first horizontal line from a distance of 20 cm perpendicular to the surface, and measuring the time for the composition to run down from the first horizontal line to the second horizontal line.
- ranges are used as a shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range.
- AU references to amounts in this specification are by active weight of the material in the total composition.
- the active weight of a material is the actual amount of the material not including other materials, such as water, in the form in which it is supplied.
- the counter ion for the salt of a surfactant can be a metal ion, an ammonium ion, or an amine.
- Metal cations that can be used include, but are not limited to, alkali metal ions and alkaline earth ions.
- the metal cation ion can be lithium, sodium, potassium, magnesium, or calcium.
- the amine is triethanolamine.
- the foaming composition includes at least one anionic surfactant chosen from a salt of an alkyl sulfate surfactant and a salt of an alkyl ether sulfate surfactant.
- the surfactant is present in the composition in an amount of about 0.1 to about 1 % by weight.
- the surfactant comprises a triethanolamine alkyl sulfate.
- the alkyl is a ClO to C14 alkyl.
- the surfactant comprises a triethanolamine lauryl sulfate.
- the Methanol amine alkyl sulfate is present in an amounfof about 0.1 to about 0.3% by weight, and in another embodiment in an amount of about 0.18 to about 0.22% by weight.
- the surfactant comprises the salt of an alkyl ether sulfate.
- the alkyl is a ClO to C14.
- the surfactant is a sodium lauiyl ether sulfate.
- the sodium lauryl ether sulfate is present in an amount of about 0.05 to about 0.2% by weight, and in another embodiment at 0.06 to about 0.08% by weight.
- the foaming composition can include an amine oxide surfactant.
- Amine oxide semi-polar nonionic surfactants can comprise compounds and mixtures of compounds having the formula:
- R 1 (C 2 H 4 O) n N ⁇ O R 3
- R ⁇ is an alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl, or 3-alkoxy-2-hydroxypropyl radical in which the alkyl and alkoxy, respectively, contain from 8 to 18 carbon atoms
- R2 and R3 are each methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, or 3-hydroxypropyl
- n is from 0 to 10.
- Particularly preferred are amine oxides of the formula:
- R 3 wherein R ⁇ is a C42-I6 a&yl and R2 and R3 are methyl or ethyl.
- ethylene oxide condensates, amides, and amine oxides are described in U.S. Pat. No. 4,316,824.
- the amine oxides comprise alkyl amine oxides and/ or cocoamidopropyl amine oxide.
- the ratio of anionic surfactant to amine oxide surfactant is about 3:1 to about 4:1.
- the composition additionally includes at least one glycol ether. In one embodiment, the amount of glycol ether is about 0.1 to about 1.5% by weight.
- glycol ethers include, but are not limited to, propylene glycol n-butyl ether, propylene glycol n-propyl ether, ethylene glycol n-hexal ether, ethylene glycol n-butyl ether, dipropylene glycol methyl ether, and combinations thereof.
- the composition includes propylene glycol n-butyl ether in an amount up to about 1.5% by weight, and in another embodiment at about 1.25% by weight.
- the foaming composition includes at least one alcohol. Any alcohol can be used in the composition.
- the alcohol comprises a Ci-C 6 alkyl alcohol.
- the alcohol is chosen from methanol, ethanol, n-propanol, isopropanol, n-butyl alcohol, sec-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, 1- 2- or 3- pentanol, neopentyl alcohol, and/ or hexanol.
- the alcohol is present in the composition in an amount of about 2 to about 6% by weight, about 3 to about 5% by weight, about 3 to about 4.5% by weight, or in another embodiment, the amount is about 4% by weight.
- the at least one alcohol comprises ethanol.
- ethanol is present in the composition in an amount of about 2 to about 6% by weight, about 3 to about 5% by weight, about 3 to about 4.5% by weight, or in another embodiment, the amount is about 4% by weight.
- the alcohol comprises ethanol and isopropanol.
- isopropanol is present in an amount of 0 to about 1.5% by weight, and in another embodiment the isopropanol is present at about 1 % by weight.
- the composition can optionally include at least one dispersant.
- the dispersant can be present in any amount that provides a dispersant effect. In one embodiment, the dispersant is present in an amount of about 0.01 to about 1 % by weight. In one embodiment, the dispersant is a maleic acid/ olefin copolymer. In one embodiment, a dispersant of this type is a maleic acid/d ⁇ sobutylene copolymer available from Rohm and Haas under the trade name ACUSOLTM 460NK.
- the composition can additionally include any fragrance or perfume. In one embodiment, the perfume is present in an amount of about 0.03 to about 0.08% by weight. The composition can additionally include any dye or coloring agent.
- composition can contain any pH agent, a biocide/ antibacterial agent, or any other material for a desired effect.
- ammonium hydroxide and/ or vinegar can be included, and in one embodiment they can be included up to about 0.2% by weight.
- citric acid can be used to adjust the pH of the composition.
- Water can be included in the composition in any amount to make the sum of the amount of materials in the composition total 100 weight percent.
- the composition when applied as a foam to a vertical glass surface will have a run down time of greater than about 15 seconds. In other embodiments, the run down time is greater than about 18 seconds, greater than about 20 seconds, greater than about 23 seconds, or about 15 to about 30 seconds. Run down time is measured by applying the foamed composition to a vertical glass surface, which is perpendicular to the earth's surface, at a first horizontal line marked on the surface from a distance of 20 cm perpendicular to the surface using a foaming dispenser. A second horizontal line is marked 10 cm below the first horizontal line on the glass surface. Run down time is the time that it takes the composition to run down from the first line to the second line. Both the first and second horizontal lines are parallel to the earth's surface.
- the foam is generated by a foaming dispenser that mixes air with the composition when it is dispensed.
- the composition does not contain any propellants that would eject the composition from the container or cause the composition to foam.
- Any foaming dispenser can be used with the composition.
- the dispenser is available from MeadWestvaco Calmar GmbH under the product name TS 800 Top Gun Trigger Sprayer.
- the composition can be used as a cleaner on all surfaces.
- the surface is a horizontal surface, which is parallel to the earth's surface.
- the surface is a non-horizontal surfaces, such as those that are angled at greater than 0 to 90° to the earth's surface.
- the composition can be used as a cleaner on a vertical surface, which is perpendicular to the earth's surface.
- the composition is a glass cleaner.
- the composition can be used in a method for removing soil from a surface comprising applying the composition to the surface and removing the composition.
- Removing includes, but is not limited to, wiping, squeegeeing, rinsing, and mopping.
- the surface can be, horizontal, non-horizontal, or vertical.
- composition according to the invention was prepared by mixing the ingredients.
- the composition was added to a container with a foaming dispenser.
- composition was compared against AJAXTM Triple Action Glass Cleaner, which is commercially available in Europe in a conventional glass cleaner spray bottle, in the run down test described above.
- a positioning device was used to position each container so that they sprayed at the same point on the vertical glass surface.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL06839936T PL2097501T3 (en) | 2006-11-17 | 2006-11-17 | Foaming hard surface cleaner |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2006/061047 WO2008060303A1 (en) | 2006-11-17 | 2006-11-17 | Foaming hard surface cleaner |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2097501A1 true EP2097501A1 (en) | 2009-09-09 |
EP2097501B1 EP2097501B1 (en) | 2012-06-06 |
Family
ID=38255536
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06839936A Not-in-force EP2097501B1 (en) | 2006-11-17 | 2006-11-17 | Foaming hard surface cleaner |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP2097501B1 (en) |
CN (1) | CN101563442B (en) |
AU (1) | AU2006350750B2 (en) |
CA (1) | CA2669329C (en) |
CR (1) | CR10800A (en) |
DK (1) | DK2097501T3 (en) |
EC (1) | ECSP099329A (en) |
ES (1) | ES2388617T3 (en) |
MX (1) | MX2009005155A (en) |
NO (1) | NO20092326L (en) |
NZ (1) | NZ576960A (en) |
PL (1) | PL2097501T3 (en) |
PT (1) | PT2097501E (en) |
WO (1) | WO2008060303A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX338888B (en) * | 2011-03-08 | 2016-05-04 | Sca Hygiene Prod Ab | Low alcohol antimicrobial cleansing composition. |
EP3724309B1 (en) * | 2017-12-12 | 2022-02-02 | Unilever Global IP Limited | Foamable cleaning composition |
CN111718804A (en) * | 2020-07-24 | 2020-09-29 | 上海绿瑞生物科技有限公司 | Foam type cleaning agent composition and application thereof |
MX2023009844A (en) * | 2021-02-24 | 2023-11-24 | Valvoline Licensing & Intellectual Property LLC | Foaming evaporator coil cleaner. |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3463735A (en) * | 1967-10-18 | 1969-08-26 | Drackett Co | Glass cleaning composition |
US4606842A (en) * | 1982-03-05 | 1986-08-19 | Drackett Company | Cleaning composition for glass and similar hard surfaces |
ZA925727B (en) * | 1991-08-09 | 1993-03-10 | Bristol Myers Squibb Co | Glass cleaning composition. |
AU8457898A (en) * | 1997-08-13 | 1999-03-08 | Procter & Gamble Company, The | Glass cleaner compositions having good surface lubricity and alkaline buffer |
GB2339789A (en) * | 1998-07-16 | 2000-02-09 | Reckitt & Colman Inc | Aqueous cleaning and surface treatment compositions |
US7666826B2 (en) * | 2002-11-27 | 2010-02-23 | Ecolab Inc. | Foam dispenser for use in foaming cleaning composition |
US20050026796A1 (en) * | 2003-07-30 | 2005-02-03 | Colgate-Palmolive Company | Foam glass cleaning composition |
DE102005044513A1 (en) * | 2005-09-16 | 2007-03-22 | Henkel Kgaa | Cleaning agent for hard surfaces |
-
2006
- 2006-11-17 PL PL06839936T patent/PL2097501T3/en unknown
- 2006-11-17 AU AU2006350750A patent/AU2006350750B2/en not_active Ceased
- 2006-11-17 MX MX2009005155A patent/MX2009005155A/en active IP Right Grant
- 2006-11-17 NZ NZ576960A patent/NZ576960A/en not_active IP Right Cessation
- 2006-11-17 PT PT06839936T patent/PT2097501E/en unknown
- 2006-11-17 ES ES06839936T patent/ES2388617T3/en active Active
- 2006-11-17 DK DK06839936.9T patent/DK2097501T3/en active
- 2006-11-17 WO PCT/US2006/061047 patent/WO2008060303A1/en active Application Filing
- 2006-11-17 CA CA2669329A patent/CA2669329C/en not_active Expired - Fee Related
- 2006-11-17 EP EP06839936A patent/EP2097501B1/en not_active Not-in-force
- 2006-11-17 CN CN2006800563931A patent/CN101563442B/en not_active Expired - Fee Related
-
2009
- 2009-05-14 EC EC2009009329A patent/ECSP099329A/en unknown
- 2009-05-15 CR CR10800A patent/CR10800A/en unknown
- 2009-06-16 NO NO20092326A patent/NO20092326L/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2008060303A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2669329C (en) | 2013-10-01 |
AU2006350750A1 (en) | 2008-05-22 |
CA2669329A1 (en) | 2008-05-22 |
NO20092326L (en) | 2009-08-04 |
ECSP099329A (en) | 2009-06-30 |
CN101563442A (en) | 2009-10-21 |
CN101563442B (en) | 2013-06-19 |
CR10800A (en) | 2009-09-03 |
PT2097501E (en) | 2012-09-10 |
AU2006350750B2 (en) | 2011-05-12 |
DK2097501T3 (en) | 2012-09-17 |
MX2009005155A (en) | 2009-05-25 |
NZ576960A (en) | 2011-11-25 |
ES2388617T3 (en) | 2012-10-17 |
EP2097501B1 (en) | 2012-06-06 |
PL2097501T3 (en) | 2012-10-31 |
WO2008060303A1 (en) | 2008-05-22 |
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