CN101563442A - Foaming hard surface cleaner - Google Patents

Foaming hard surface cleaner Download PDF

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Publication number
CN101563442A
CN101563442A CNA2006800563931A CN200680056393A CN101563442A CN 101563442 A CN101563442 A CN 101563442A CN A2006800563931 A CNA2006800563931 A CN A2006800563931A CN 200680056393 A CN200680056393 A CN 200680056393A CN 101563442 A CN101563442 A CN 101563442A
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CN
China
Prior art keywords
composition
foamable composite
alcohol
alkyl
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2006800563931A
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Chinese (zh)
Other versions
CN101563442B (en
Inventor
P·迪特
I·莱奥纳德
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Colgate Palmolive Co
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Colgate Palmolive Co
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Publication of CN101563442A publication Critical patent/CN101563442A/en
Application granted granted Critical
Publication of CN101563442B publication Critical patent/CN101563442B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Abstract

A foamable composition comprising: a) at least one anionic surfactant chosen from a salt of an alkyl sulfate and a salt of an alkyl ether sulfate in an amount of about 0.01 to about 1% by weight of the composition; b) at least one glycol ether in an amount of about 0.1 to about 1.5% by weight of the composition; c) at least one alcohol in an amount of about 2 to about 6% by weight of the composition; and d) water. Also, a foamable composition comprising: a) at least one anionic surfactant chosen from a salt of an alkyl sulfate and a salt of an alkyl ether sulfate; b) at least one glycol ether; c) at least one alcohol; and d) water, wherein the composition has a run down time of greater than about 15 seconds on a vertical glass surface across a distance of 10 cm.

Description

Foaming hard surface cleaner
Background technology
[0001] the common major part of hard surface cleaner is the water that contains cleaning material, perfume compound and pigment (color).Hard surface cleaner is sprayed on the surface usually, and wiping is with the clean surface then.Because the major part of hard surface cleaner is a water, because gravity is on being administered to vertical surface the time, they can drip.
[0002] before hard surface cleaner drops onto the surface that is cleaned, needs the rapid wipe surfaces of people.For playing the better cleaning effect, the drippage of hard surface cleaner does not allow the hard surface cleaner long period to be detained from the teeth outwards.When being applied to surperficial going up, need hard surface cleaner can be trapped in the appropriate location.
Summary of the invention
[0003] a kind of foamable composition, it comprises:
A) anion surfactant of the salt (a salt ofan alkyl ether sulfate) of at least a salt (a salt of an alkyl sulfate) that is selected from alkyl sulfuric ester and alkyl ether sulphate, in the weight of composition, its content is about 0.01-about 1%;
B) at least a glycol ethers (glycol ether), in the weight of composition, its content is about 0.1-about 1.5%;
C) at least a alcohol, in the weight of composition, its content is about 2-about 6%; With
D) water.
[0004] a kind of foamable composition, it comprises:
A) anion surfactant of the salt of at least a salt that is selected from alkyl sulfuric ester and alkyl ether sulphate;
B) at least a glycol ethers (glycol ether); With
C) at least a alcohol; With
D) water,
Wherein said composition has greater than about 15 seconds time that moves downward (run down time), the time that wherein moves downward is measured by following steps: vertically (vertical) glass surface is provided, this glass surface is perpendicular to earth surface, wherein first sea line is higher than the second sea line 10cm and the both is parallel to earth surface, perpendicular to surperficial 20cm first sea line far away composition is being administered to vertical glass surface from distance, and the mensuration composition moved to for the second horizontal time under first horizontal alignment.
Detailed Description Of The Invention
[0005] as using in the text, scope is as each (each) and all simplification expression of each (every) value that are described in this scope.Any value in this scope may be selected the end value of scope.
[0006] the employed in this manual amount active weight that all is the material in whole composition.The active weight of material is the actual amount of material, does not comprise other materials, and water for example is with the form of its supply.
[0007] as using in the text, the gegenion of the salt of tensio-active agent can be metal ion, ammonium ion or amine.Operable metallic cation includes but are not limited to, alkalimetal ion and alkaline-earth metal ions.In some embodiments, metallic cation can be lithium, sodium, potassium, magnesium or calcium.In some embodiments, amine is trolamine.
[0008] foaming composition comprises the anion surfactant of the salt of at least a salt that is selected from the alkylsurfuric acid ester surfactant and alkyl ether sulphate tensio-active agent.In one embodiment, the amount of tensio-active agent in composition is the about 1 weight % of about 0.1-.
[0009] in one embodiment, tensio-active agent comprises trolamine alkyl sodium sulfate ester (alkylsulfate).In one embodiment, alkyl is the C10-C14 alkyl.In another embodiment, tensio-active agent comprises triethenolamine lauryl sulfate.In one embodiment, the amount of trolamine alkyl sodium sulfate ester is the about 0.3 weight % of about 0.1-, and in another embodiment, its consumption is the about 0.22 weight % of about 0.18-.
[0010] in another embodiment, tensio-active agent comprises the salt of alkyl ether sulphate.In one embodiment, alkyl is C10-C14 (alkyl).In one embodiment, tensio-active agent is a sodium lauryl tri(oxyethyl) sulfate.In one embodiment, every mole has the about 10 moles oxyethane of average about 1-.In another embodiment, every mole has average about 2 to about 3 moles oxyethane.In one embodiment, the amount of sodium lauryl tri(oxyethyl) sulfate is the about 0.2 weight % of about 0.05-, in another embodiment, is the about 0.08 weight % of 0.06-.
[0011] except anion surfactant, foaming composition can contain amine oxide surfactant.The amine oxide semi-polar nonionic surfactants can comprise the compound with following general formula and the mixture of compound:
Figure A20068005639300051
R wherein 1Be alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl or 3-alkoxyl group-2-hydroxypropyl, wherein alkyl and alkoxyl group contain 8-18 carbon atom, R separately 2And R 3Be respectively methyl, ethyl, propyl group, sec.-propyl, 2-hydroxyethyl, 2-hydroxypropyl or 3-hydroxypropyl, and n is 0-10.The special preferably amine oxide of following general formula:
Figure A20068005639300061
R wherein 1Be C 12-16Alkyl, and R 2And R 3Be methyl or ethyl.The example of above ethylene oxide condensate, acid amides and amine oxide is in U.S. Patent No. 4,316, discloses in 824.In one embodiment, amine oxide comprises alkyl amine oxide and/or coconut oleoyl amine (cocoamido) propyl group amine oxide.In one embodiment, the ratio of anion surfactant and amine oxide surfactant is about 3: 1 to about 4: 1.
[0012] composition contains at least a glycol ethers in addition.In one embodiment, the amount of glycol ethers is the about 1.5 weight % of about 0.1-.The example of glycol ethers includes but are not limited to, propylene glycol n-butyl ether, propylene glycol n-propyl ether, ethylene glycol n-hexyl (n-hexal) ether, ethylene glycol n-butyl ether, dipropylene glycol methyl ether and composition thereof.In one embodiment, composition comprises propylene glycol n-butyl ether, and its consumption is about at the most 1.5% weight, is about 1.25% weight in another embodiment.
[0013] foaming composition comprises at least a alcohol.Any alcohol can be used in the composition.In one embodiment, alcohol comprises C 1-C 6Alkyl alcohol.In one embodiment, alcohol is selected from methyl alcohol, ethanol, n-propyl alcohol, Virahol, propyl carbinol, sec-butyl alcohol, isopropylcarbinol, the trimethyl carbinol, 1-, 2-or 3-amylalcohol, neopentyl alcohol and/or hexanol.In certain embodiments, the amount of the alcohol that exists in the composition is the about 6 weight % of about 2-, the about 5 weight % of about 3-, about 4.5 weight % of about 3-or in another embodiment, amount is about 4 weight %.
[0014] in one embodiment, at least a alcohol comprises ethanol.In another embodiment, the amount of ethanol in composition is the about 6 weight % of about 2-, the about 5 weight % of about 3-, about 4.5 weight % of about 3-or in another embodiment, amount is about 4 weight %.In another embodiment, alcohol comprises ethanol and Virahol.In another embodiment, the amount of Virahol is about 1.5 weight % of 0-and in another embodiment, and the amount of Virahol is about 1 weight %.
[0015] composition can be chosen wantonly and comprise at least a dispersion agent.Dispersion agent can exist with any amount that dispersion effect is provided.In one embodiment, the amount of dispersion agent is the about 1 weight % of about 0.01-.In one embodiment, dispersion agent is toxilic acid/olefin copolymer.In one embodiment, such dispersion agent is toxilic acid/diisobutylene multipolymer, and it can be from Rohm and Haas company with trade(brand)name ACUSOL TM460NK obtains.
[0016] composition can contain any perfume compound or spices in addition.In one embodiment, the amount of spices is the about 0.08 weight % of about 0.03-.Composition can add and contain any dyestuff or tinting material.In addition, composition can contain any pH agent, biocide/antiseptic-germicide, or other material of any required effect.And, can contain ammonium hydroxide and/or vinegar, and in one embodiment, their content can be up to about 0.2 weight %.In one embodiment, citric acid can be used for regulating the pH value of composition.
[0017] can contain the water of arbitrary quantity in the composition so that the summation that makes the amount of material in the composition is 100 weight % altogether.
[0018] said composition will have when being used for vertical glass surface as foam greater than about 15 seconds time that moves downward.In one embodiment, the time that moves downward is greater than about 18 seconds, greater than about 20 seconds, greater than about 30 seconds of about 23 seconds or about 15-.The time that moves downward is measured by following steps: use the foaming decollator, perpendicular to first sea line of surperficial 20cm mark from the teeth outwards far away the composition of foaming is being administered to vertical glass surface perpendicular to earth surface from distance.On glass surface at the following 10cm of first sea line place mark second sea line.The time of moving downward is that said composition moves to second (level) used time of line under first (level) alignment.First and second sea lines all are parallel to earth surface.
[0019] in one embodiment, foam produces by the foaming divider, and when a minute timing, described foaming divider mixes air and composition.In this embodiment, composition does not contain any propelling agent that composition is sprayed or makes the composition foaming from container.Any foaming divider may be used in the said composition.In one embodiment, divider can obtain with trade(brand)name TS 800Top Gun Trigger Sprayer from MeadWestvaco Calmar GmbH.
[0020] composition can be used as the sanitising agent of all surface.In one embodiment, the surface is a horizontal surface, and it is parallel to earth surface.In one embodiment, the surface is non-horizontal surface, for example has the surface of angle greater than 0 to 90 degree with earth surface.In another embodiment, composition can be used as vertical lip-deep sanitising agent, and this Surface Vertical is in earth surface.In one embodiment, composition is a glass cleaner.
[0021] said composition can be used in from the surface and dispel the method for stain (soil), comprises that said composition is administered to the surface goes up and remove said composition.Removing includes but are not limited to, and wiping, grinds with squeegee and to roll (squeegeeing), flushing (rinsing) and to shampoo (mopping).The surface can be a level, and is non-level or vertical.
[0022] with following embodiment the present invention is described further.Embodiment only is illustrative, and described and scope the present invention for required protection are not had any restriction extremely.
Embodiment 1
[0023] Xia Mian explanation of tables the indication embodiment, it can make by mixing following component.
Material Weight %
Triethenolamine lauryl sulfate 0.18-0.22
Propylene glycol n-butyl ether 0.1-1.5
Ethanol 3-4.5
Auxiliary component (Minors) 0.1-0.3
Deionized water Q.S.
Embodiment 2
[0024] Xia Mian explanation of tables the indication embodiment, it can make by mixing following component.
Material % weight
Triethenolamine lauryl sulfate 0.18-0.22
Propylene glycol n-butyl ether 0.1-1.5
Ethanol 3-4.5
ACUSOL 460NK 0.4
Auxiliary component 0.1-0.3
Deionized water Q.S.
Embodiment 3
[0025] by mixing following component preparation according to following composition of the present invention.Composition is joined in the container with foaming divider.
Material Weight %
Triethenolamine lauryl sulfate 0.2
Propylene glycol n-butyl ether 1.25
Ethanol 4
26 ° of BE ammonium hydroxide 0.44
Deionized water Q.S.
[0026] moving downward in the test more described composition and AJAX as mentioned above TMTriple Action glass cleaner, this sanitising agent can commercially obtain in Europe in conventional glass cleaner spray bottle.To such an extent as to position determining equipment determine each container the position they on vertical glass surface, spray at identical point.Carry out some tests (runs), the results are shown in following table.Time is unit with the second.
Figure A20068005639300091
[0027] can remain on the appropriate location long period than conventional glass cleaner according to foamable composite of the present invention as can be seen from form.

Claims (24)

1. foamable composite comprises:
A) anion surfactant of the salt of at least a salt that is selected from alkyl sulfuric ester and alkyl ether sulphate, in the weight of composition, its content is about 0.01-about 1%;
B) at least a glycol ethers, in the weight of composition, its content is about 0.1-about 1.5%;
C) at least a alcohol, in the weight of composition, its content is about 2-about 6%; With
D) water.
2. foamable composite as claimed in claim 1, anion surfactant wherein comprise trolamine alkyl sodium sulfate ester.
3. foamable composite as claimed in claim 1, anion surfactant wherein is a triethenolamine lauryl sulfate.
4. foamable composite as claimed in claim 1, anion surfactant wherein are the salt of alkyl ether sulphate.
5. foamable composite as claimed in claim 1, anion surfactant wherein is a sodium lauryl tri(oxyethyl) sulfate.
6. foamable composite as claimed in claim 1, glycol ethers wherein is a propylene glycol n-butyl ether.
7. foamable composite as claimed in claim 1, alcohol wherein comprises C 1-C 6Alkyl alcohol.
8. foamable composite as claimed in claim 1, alcohol wherein is ethanol.
9. foamable composite as claimed in claim 1, alcohol wherein comprises ethanol and Virahol.
10. foamable composite as claimed in claim 1, it further comprises amine oxide surfactant.
11. foamable composite as claimed in claim 10, the amount of amine oxide wherein in foamable composite is shown about 3 with the ratiometer of anion surfactant and amine oxide surfactant: about 4: 1 of 1-.
12. foamable composite as claimed in claim 1, it further comprises dispersion agent.
13. foamable composite as claimed in claim 12, dispersion agent wherein comprises the multipolymer of toxilic acid and alkene.
14. foamable composite as claimed in claim 1, wherein anion surfactant comprises triethenolamine lauryl sulfate, and glycol ethers comprises that propylene glycol n-butyl ether and alcohol comprise ethanol.
15. foamable composite as claimed in claim 1 further contains the material that is selected from pH agent, perfume compound, spices, tinting material, dyestuff, biocide/antiseptic-germicide, ammonium hydroxide and vinegar.
16. foamable composite as claimed in claim 1, wherein composition had greater than about 15 seconds time that moves downward, the time that wherein moves downward is measured by following steps: vertical glass surface is provided, wherein first sea line is higher than the second sea line 10cm, perpendicular to surperficial 20cm first sea line far away composition is being administered to vertical glass surface from distance, and the mensuration composition moved to for the second horizontal time under first horizontal alignment.
17. foamable composite as claimed in claim 16, the time that moves downward wherein was greater than about 20 seconds.
18. goods, the foamable composite as claimed in claim 1 that it comprises the container with divider and places this container, described container make the composition foaming that distributes by divider.
19. a foamable composite, it comprises:
A) anion surfactant of the salt of at least a salt that is selected from alkyl sulfuric ester and alkyl ether sulphate;
B) at least a glycol ethers;
C) at least a alcohol; With
D) water,
Wherein said composition had greater than about 15 seconds time that moves downward, the time that wherein moves downward is measured by following steps: vertical glass surface is provided, this glass surface is perpendicular to earth surface, wherein first sea line is higher than the second sea line 10cm and the both is parallel to earth surface, perpendicular to surperficial 20cm first sea line far away composition is being administered to vertical glass surface from distance, and the mensuration composition moved to for the second horizontal time under first horizontal alignment.
20. foamable composite as claimed in claim 19, the time that moves downward wherein was greater than about 20 seconds.
21. one kind is removed the method for stain from surperficial supernatant, comprises that composition with claim 1 is administered to the surface and goes up and remove said composition.
22. method as claimed in claim 21, wherein the surface is vertical surface.
23. one kind is removed the method for stain from surperficial supernatant, comprises that composition with claim 19 is administered to the surface and goes up and remove said composition.
24. method as claimed in claim 23, wherein the surface is vertical surface.
CN2006800563931A 2006-11-17 2006-11-17 Foaming hard surface cleaner Expired - Fee Related CN101563442B (en)

Applications Claiming Priority (1)

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PCT/US2006/061047 WO2008060303A1 (en) 2006-11-17 2006-11-17 Foaming hard surface cleaner

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CN101563442A true CN101563442A (en) 2009-10-21
CN101563442B CN101563442B (en) 2013-06-19

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CN (1) CN101563442B (en)
AU (1) AU2006350750B2 (en)
CA (1) CA2669329C (en)
CR (1) CR10800A (en)
DK (1) DK2097501T3 (en)
EC (1) ECSP099329A (en)
ES (1) ES2388617T3 (en)
MX (1) MX2009005155A (en)
NO (1) NO20092326L (en)
NZ (1) NZ576960A (en)
PL (1) PL2097501T3 (en)
PT (1) PT2097501E (en)
WO (1) WO2008060303A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103415206A (en) * 2011-03-08 2013-11-27 Sca卫生用品公司 Low alcohol antimicrobial cleansing composition
CN111479911A (en) * 2017-12-12 2020-07-31 荷兰联合利华有限公司 Foamable cleaning compositions
CN111718804A (en) * 2020-07-24 2020-09-29 上海绿瑞生物科技有限公司 Foam type cleaning agent composition and application thereof

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US3463735A (en) * 1967-10-18 1969-08-26 Drackett Co Glass cleaning composition
US4606842A (en) * 1982-03-05 1986-08-19 Drackett Company Cleaning composition for glass and similar hard surfaces
ZA925727B (en) * 1991-08-09 1993-03-10 Bristol Myers Squibb Co Glass cleaning composition.
AU8457898A (en) * 1997-08-13 1999-03-08 Procter & Gamble Company, The Glass cleaner compositions having good surface lubricity and alkaline buffer
GB2339789A (en) * 1998-07-16 2000-02-09 Reckitt & Colman Inc Aqueous cleaning and surface treatment compositions
US7666826B2 (en) * 2002-11-27 2010-02-23 Ecolab Inc. Foam dispenser for use in foaming cleaning composition
US20050026796A1 (en) * 2003-07-30 2005-02-03 Colgate-Palmolive Company Foam glass cleaning composition
DE102005044513A1 (en) * 2005-09-16 2007-03-22 Henkel Kgaa Cleaning agent for hard surfaces

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103415206A (en) * 2011-03-08 2013-11-27 Sca卫生用品公司 Low alcohol antimicrobial cleansing composition
CN103415206B (en) * 2011-03-08 2016-09-07 Sca卫生用品公司 Low alcohol antimicrobial cleansing compositions
CN111479911A (en) * 2017-12-12 2020-07-31 荷兰联合利华有限公司 Foamable cleaning compositions
CN111718804A (en) * 2020-07-24 2020-09-29 上海绿瑞生物科技有限公司 Foam type cleaning agent composition and application thereof

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EP2097501A1 (en) 2009-09-09
CA2669329C (en) 2013-10-01
AU2006350750A1 (en) 2008-05-22
CN101563442B (en) 2013-06-19
PT2097501E (en) 2012-09-10
MX2009005155A (en) 2009-05-25
EP2097501B1 (en) 2012-06-06
WO2008060303A1 (en) 2008-05-22
CR10800A (en) 2009-09-03
NZ576960A (en) 2011-11-25
PL2097501T3 (en) 2012-10-31
AU2006350750B2 (en) 2011-05-12
CA2669329A1 (en) 2008-05-22
DK2097501T3 (en) 2012-09-17
NO20092326L (en) 2009-08-04
ECSP099329A (en) 2009-06-30

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