EP2069471B1 - Système de distribution de détergents ou de nettoyants - Google Patents

Système de distribution de détergents ou de nettoyants Download PDF

Info

Publication number
EP2069471B1
EP2069471B1 EP07803452A EP07803452A EP2069471B1 EP 2069471 B1 EP2069471 B1 EP 2069471B1 EP 07803452 A EP07803452 A EP 07803452A EP 07803452 A EP07803452 A EP 07803452A EP 2069471 B1 EP2069471 B1 EP 2069471B1
Authority
EP
European Patent Office
Prior art keywords
weight
shaped
acid
film
preferred
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP07803452A
Other languages
German (de)
English (en)
Other versions
EP2069471B2 (fr
EP2069471A1 (fr
Inventor
Salvatore Fileccia
Rene-Andres Artiga Gonzalez
Georg Meine
Wolfgang Barthel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38712602&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2069471(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL07803452.7T priority Critical patent/PL2069471T5/pl
Publication of EP2069471A1 publication Critical patent/EP2069471A1/fr
Application granted granted Critical
Publication of EP2069471B1 publication Critical patent/EP2069471B1/fr
Publication of EP2069471B2 publication Critical patent/EP2069471B2/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/044—Solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40—Specific cleaning or washing processes
    • C11D2111/42—Application of foam or a temporary coating on the surface to be cleaned
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/17—Surface bonding means and/or assemblymeans with work feeding or handling means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture

Definitions

  • the present invention relates to a washing or cleaning agent dispensing system for polymer-containing moldings, which are strip-shaped, sheet-shaped, disc-shaped, layered, plate-shaped or sheet-like, and its use for the individual dosage of non-liquid detergents or cleaners. Furthermore, the invention relates to a process for the preparation of an aqueous system with cleaning power and a method for local stain treatment of substrates.
  • Solid and liquid detergents and cleaners have been welcome aids in households and businesses for many years and are taken for granted by almost everyone.
  • the object of the present invention was therefore to provide a particularly user-friendly and easy to handle detergent or cleaning agent. This object is solved by the subject matter of the invention.
  • the object of the present invention is a washing or cleaning agent dispensing system comprising a strip-shaped, disc-shaped, disc-shaped, plate-shaped or web-shaped detergent tablet which comprises at least 20% by weight of polymers and comprises a substance with detergency; Shaped body is provided in a removal container, and wherein the shaped body on a surface carries a Klobe Anlagen comprising a polymer at room temperature under Druk and / or in the presence of moisture sticky polymer.
  • a washing or cleaning agent dispensing system in the sense of the invention is an article which comprises at least one dispensing container in which a detergent or cleaning agent shaped article according to the invention, such as preferably a film, is contained.
  • the detergent or cleaner tablet contains at least one substance with cleaning power, in particular bleach and / or surfactant.
  • Under the strip-shaped, sheet-shaped, disc-shaped, layered or web-shaped detergent tablets is preferably a film or a film to understand.
  • the polymer content of the molded article may, in a preferred embodiment, also be well above 20% by weight, e.g. at a value of at least 25% by weight, 30% by weight, 35% by weight, 40% by weight, 45% by weight, 50% by weight, 55% by weight, 60% by weight. %, 65 wt .-%, 70 wt .-% or at least 75 wt .-% or even at least 80 wt .-%, wherein wt .-% based on the total molding.
  • Possible upper limits for the polymer portion of the molded article may e.g.
  • the polymer content of the molded article may therefore be e.g. in the range of from 35% to 70% by weight, or e.g. in the range of 40% to 80% by weight, etc.
  • the shaped body according to the invention can be water-soluble or water-dispersible, but according to another embodiment it is water-insoluble, which is less preferred. It is also possible that it is only partially water-soluble or water-dispersible.
  • a molded article of the invention e.g. a film, be constructed in several layers, for example in the manner of a laminate, wherein different layers differ in their water solubility. It can be e.g. to be a 2-ply film in which the one layer is water-soluble and / or water-dispersible, whereas the other layer is water-insoluble.
  • the shaped body according to the invention preferably the film
  • the coating is water-insoluble, the shaped body, preferably the film, but water-soluble.
  • the shaped body may thus consist of a single (material) layer or of a laminate of more than one layer according to a preferred embodiment, preferably the multilayer molded body is preferably coated.
  • the shaped body comprises a film of preferably flexible material and a substance with cleaning power, which is applied in the film and / or as a layer on the film.
  • the shaped body according to the invention may contain, in addition to the polymer and the substance with cleaning power, other constituents, such as e.g. natural and / or synthetic fabrics, nonwovens, films, paper, rubber and combinations thereof.
  • other constituents such as e.g. natural and / or synthetic fabrics, nonwovens, films, paper, rubber and combinations thereof.
  • the polymer contained may be, for example, a single polymer or a mixture of different polymers. Suitable polymers may be, for example, polyethylene, Polyvinyl alcohol, ethyl vinyl acetate, ethyl vinyl alcohol, polyester, etc. A preferred water-insoluble material is eg polyethylene. A preferred water-soluble polymer is, for example, polyvinyl alcohol.
  • suitable molding materials are e.g. Films or sheets of synthetic resins, e.g. PE, PP, PAN, PUR, PVA, PVC, PA, etc., as well as laminated films thereof, porous films or films of rubber and / or synthetic resins.
  • Fiber films or films such as so-called nonwoven fabrics (which are nonwoven, knitted or knitted fabrics, preferably based on PP, polyester, viscose, acrylic, polyamide), fabric and paper and metal foils are also suitable.
  • the molding comprises one or more materials from the group (optionally acetalized) polyvinyl alcohol (PVAL) and / or PVAL copolymers, polyvinylpyrrolidone, polyethylene oxide, polyethylene glycol, gelatin, cellulose and derivatives thereof, in particular MC, HEC, HPC, HPMC and / or CMC, and / or copolymers and mixtures thereof.
  • PVAL polyvinyl alcohol
  • PVAL polyvinyl alcohol
  • PVAL polyvinylpyrrolidone
  • polyethylene oxide polyethylene glycol
  • gelatin cellulose and derivatives thereof
  • MC MC
  • HEC highC
  • HPMC HPMC
  • CMC / or copolymers and mixtures thereof.
  • the moldings may preferably also be admixed with plasticizers known to the person skilled in the art in order to increase the flexibility of the material or else other auxiliaries or additives.
  • polyvinyl alcohols are very particularly preferred as water-soluble polymers.
  • Polyvinyl alcohols (abbreviated PVAL, occasionally PVOH) is the name for polymers of the general structure in small proportions (about 2%) also structural units of the type contain.
  • polyvinyl alcohols which are available as white-yellowish powders or granules with degrees of polymerization in the range of about 100 to 2500 (molar masses of about 4000 to 100,000 g / mol), have degrees of hydrolysis of 98-99 or 87-89 mol%. , so still contain a residual content of acetyl groups.
  • the polyvinyl alcohols are characterized by the manufacturer by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis, the saponification number or the solution viscosity.
  • polyvinyl alcohols are soluble in water and a few highly polar organic solvents (formamide, dimethylformamide, dimethyl sulfoxide); of (chlorinated) Hydrocarbons, esters, fats and oils are not attacked.
  • Polyvinyl alcohols are classified as toxicologically safe and are biologically at least partially degradable. The water solubility can be reduced by aftertreatment with aldehydes (acetalization), by complexation with Ni or Cu salts or by treatment with dichromates, boric acid or borax.
  • Polyvinyl alcohol is largely impermeable to gases such as oxygen, nitrogen, helium, hydrogen, carbon dioxide, but allows water vapor to pass through.
  • Moldings which are preferred in the context of the present invention are characterized in that they comprise polyvinyl alcohols and / or PVAL copolymers whose degree of hydrolysis is 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
  • polyvinyl alcohols of a certain molecular weight range are used, with those whose molecular weight being in the range from 3500 to 100,000 gmol -1 , preferably from 10,000 to 90,000 gmol -1 , particularly preferably from 12,000 to 80,000 gmol -1 and in particular from 13,000 to 70,000 gmol -1 lies.
  • the degree of polymerization of such preferred polyvinyl alcohols is between about 200 to about 2100, preferably between about 220 to about 1890, more preferably between about 240 to about 1680, and most preferably between about 260 to about 1500.
  • Preferred moldings according to the invention are characterized in that they comprise polyvinyl alcohols and / or PVAL copolymers whose average degree of polymerization is between 80 and 700, preferably between 150 and 400, more preferably between 180 and 300 and / or their molecular weight ratio MW (50%) MW (90%) is between 0.3 and 1, preferably between 0.4 and 0.8 and in particular between 0.45 and 0.6.
  • polyvinyl alcohols described above are widely available commercially, for example under the trade name Mowiol ® (Clariant).
  • Mowiol ® Commercially, for example under the trade name Mowiol ® (Clariant).
  • particularly suitable polyvinyl alcohols are, for example, Mowiol ® 3-83, Mowiol ® 4-88, Mowiol ® 5-88 and Mowiol ® 8-88.
  • polyvinyl alcohols ® ELVANOL 51-05, 52-22, 50-42, 85-82, 75-15, T-25, T-66, 90-50 (trademark of Du Pont)
  • ALCOTEX ® 72.5, 78, B72, F80 / 40, F88 / 4, F88 / 26, F88 / 40, F88 / 47 (trademark of Harlow Chemical Co.)
  • Gohsenol ® NK-05, A-300, AH-22, C -500, GH-20, GL-03, GM-14L, KA-20, KA-500, KH-20, KP-06, N-300, NH-26, NM11Q, KZ-06 (Trademark of Nippon Gohsei KK ).
  • ERKOL types from Wacker.
  • a further preferred group of water-soluble polymers which may be present in the moldings according to the invention are the polyvinylpyrrolidones. These are marketed under the name Luviskol ® (BASF). Polyvinylpyrrolidones [poly (1-vinyl-2-pyrrolidinones)], abbreviation PVP, are polymers of the general formula (I) which are prepared by free-radical polymerization of 1-vinylpyrrolidone by the method of solution or suspension polymerization using free-radical initiators (peroxides, azo compounds) as initiators. The ionic polymerization of the monomer provides only low molecular weight products.
  • polyvinylpyrrolidones have molar masses in the range of about 2500-750000 g / mol, which are characterized by the specification of the K values and - depending on K value - have glass transition temperatures of 130-175 °. They are offered as white, hygroscopic powders or as aqueous solutions. Polyvinylpyrrolidones are readily soluble in water and a variety of organic solvents (alcohols, ketones, glacial acetic acid, chlorinated hydrocarbons, phenols, etc.).
  • copolymers of vinylpyrrolidone with other monomers in particular vinylpyrrolidone / Vinylester copolymers, such as for example, under the trade name Luviskol ® (BASF).
  • Luviskol ® VA 64 and Luviskol ® VA 73, each vinylpyrrolidone / vinyl acetate copolymers are particularly preferred non-ionic polymers.
  • the vinyl ester polymers are vinyl ester-accessible polymers having the moiety of the formula (II) as a characteristic building block of the macromolecules.
  • the vinyl acetate polymers (R CH 3 ) with polyvinyl acetates as by far the most important representatives of the greatest technical importance.
  • the polymerization of the vinyl esters is carried out free-radically by different processes (solution polymerization, suspension polymerization, emulsion polymerization, bulk polymerization).
  • Copolymers of vinyl acetate with vinylpyrrolidone contain monomer units of the formulas (I) and (II).
  • PEG polyethylene glycols
  • PEG polyethylene oxides
  • n can take values between 5 and> 100,000.
  • PEGs are prepared industrially by anionic ring-opening polymerization of ethylene oxide (oxirane), usually in the presence of small amounts of water. Depending on the reaction procedure, they have molar masses in the range of about 200-5,000,000 g / mol, corresponding to degrees of polymerization of about 5 to> 100,000.
  • PEG polyethylene glycols
  • PEOX polyethylene oxides
  • gelatin is a polypeptide (molecular weight: about 15,000 to> 250,000 g / mol), which is obtained primarily by hydrolysis of the collagen contained in the skin and bones of animals under acidic or alkaline conditions.
  • the amino acid composition of gelatin largely corresponds to that of collagen, from which it was obtained and varies depending on its provenance.
  • the use of gelatin as water-soluble coating material is extremely widespread, especially in pharmacy in the form of hard or soft gelatin capsules. In the form of films, gelatin generally has little use because of its high price compared to the polymers mentioned above.
  • Preferred shaped bodies according to the invention are characterized in that they comprise hydroxypropylmethylcellulose (HPMC) which has a degree of substitution (average number of methoxy groups per anhydroglucose unit of the cellulose) of from 1.0 to 2.0, preferably from 1.4 to 1.9, and a molar substitution (average number of hydroxypropoxyl groups per anhydroglucose unit of cellulose) of from 0.1 to 0.3, preferably from 0.15 to 0.25.
  • HPMC hydroxypropylmethylcellulose
  • Further polymers which are suitable according to the invention are water-soluble amphopolymers.
  • Amphoteric polymers ie polymers which contain both free amino groups and free -COOH or SO 3 H groups in the molecule and are capable of forming internal salts, are zwitterionic polymers which contain quaternary ammonium groups in the molecule. COO or -SO 3 - groups, and summarized those polymers containing -COOH or SO 3 H groups and quaternary ammonium groups.
  • amphopolymer suitable is the acrylic resin commercially available as Amphomer ® is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group of acrylic acid, Represents methacrylic acid and its simple esters.
  • preferred amphopolymers are composed of unsaturated carboxylic acids (for example acrylic and methacrylic acid), cationically derivatized unsaturated carboxylic acids (for example acrylamidopropyltrimethylammonium chloride) and optionally further ionic or nonionic monomers.
  • Terpolymers of acrylic acid, methyl acrylate and methacrylamidopropyltrimonium as they are commercially available under the name Merquat ® 2001 N are inventively particularly preferred amphopolymers.
  • Other suitable amphoteric polymers are for example sold under the names Amphomer ® and Amphomer ® LV-71 (DELFT NATIONAL) available octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers.
  • Such grafted polymers of vinyl esters, esters of acrylic acid or methacrylic acid alone or in admixture with other copolymerizable compounds on polyalkylene glycols are obtained by homogeneous-phase polymerization by heating Polyalkylene glycols in the monomers of vinyl esters, esters of acrylic acid or methacrylic acid, in the presence of free radical initiator stirred.
  • Suitable vinyl esters are, for example, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl benzoate and as esters of acrylic acid or methacrylic acid those with aliphatic alcohols of low molecular weight, ie in particular ethanol, propanol, isopropanol, 1-butanol, 2-butanol, 2-methyl 1-propanol, 2-methyl-2-propanol, 1-pentanol, 2-pentanol, 3-pentanol, 2,2-dimethyl-1-propanol, 3-methyl-1-butanol; 3-methyl-2-butanol, 2-methyl-2-butanol, 2-methyl-1-butanol, 1-hexanol, are proven.
  • the polyethylene glycol used has a molecular weight between 200 and several million, preferably between 300 and 30,000.
  • the nonionic monomers may be of very different types and of these preferred are: vinyl acetate, vinyl stearate, vinyl laurate, vinyl propionate, allyl stearate, allylaurate, diethyl maleate, allyl acetate, methyl methacrylate, cetyl vinyl ether, stearyl vinyl ether and 1-hexene.
  • the non-ionic monomers may likewise be of very different types, among which particularly preferably crotonic acid, allyloxyacetic acid, vinylacetic acid, maleic acid, acrylic acid and methacrylic acid are contained in the graft polymers.
  • crosslinkers used are preferably ethylene glycol dimethacrylate, diallyl phthalate, ortho-, meta- and para-divinylbenzene, tetraallyloxyethane and polyallyl sucrose having 2 to 5 allyl groups per molecule of saccharin.
  • cationic polymers are cationic polymers.
  • the permanent cationic polymers are preferred.
  • "permanently cationic” refers to those polymers which have a cationic group independently of the pH. These are usually polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group.
  • Cationic polymers preferred according to the invention are quaternized cellulose derivatives and polymeric dimethyldiallylammonium salts and their copolymers.
  • Cationic cellulose derivatives, in particular the commercial product Polymer® JR 400, are very particularly preferred cationic polymers.
  • the molding material may contain, in addition to the water-soluble polymer or the water-dispersible polymer, further ingredients which in particular improve the processability of the starting materials to form the film.
  • further ingredients which in particular improve the processability of the starting materials to form the film.
  • plasticizers and release agents should be mentioned here.
  • dyes can be incorporated into the film to achieve aesthetic effects there.
  • Suitable release agents which may preferably be applied to the finished, dried films are e.g. Talc, starch or (physically, chemically and / or enzymatically) modified starch. Suitable chemical modifications are e.g. Crosslinking, acetylation, esterification, hydroxyethylation, hydroxypropylation, phosphorylation.
  • the preferably hydrophobic release agent adheres in particular externally to the film.
  • Plasticizers Hydrophilic, high-boiling liquids can be used according to the invention as plasticizers, it also being possible to use solids which are solid at room temperature as a solution, dispersion or melt.
  • Particularly preferred plasticizers are selected from the group glycol, di-, tri-, tetra-, penta-, hexa-, hepta-, octa-, nona-, deca-, undeca-, dodecaethylene glycol, glycerol, neopentyl glycol, trimethylolpropane, pentaerythritol, mono -, di-, triglycerides, surfactants, in particular nonionic surfactants, and mixtures thereof.
  • Plasticizers are preferably used in amounts of from 1 to 50% by weight, preferably from 2 to 40% by weight, in particular from 5 to 30% by weight, based on the total molding.
  • Ethylene Glycol (1,2-Ethanediol, "Glycol”) is a colorless, viscous, sweet-tasting, highly hygroscopic liquid that is miscible with water, alcohols and acetone and has a density of 1.113.
  • the solidification point of ethylene glycol is -11.5 ° C, the liquid boils at 198 ° C.
  • ethylene glycol is recovered from ethylene oxide by heating with water under pressure. Promising manufacturing processes can also be built on the acetoxylation of ethylene and subsequent hydrolysis or on synthesis gas reactions.
  • Diethylene glycol (2,2'-oxydiethanol, digol), HO- (CH 2 ) 2 -O-CH 2 ) 2 -OH, is a colorless, viscous, hygroscopic, sweet-tasting liquid, with a density of 1.12, which is at - 6 ° C and boiling at 245 ° C.
  • the diethylene glycol which is usually abbreviated in practice to diglycol, is prepared from ethylene oxide and ethylene glycol (ethoxylation) and is therefore practically the starting element of the polyethylene glycols (see above).
  • Glycerine is a colorless, clear, heavy-bodied, odorless sweet-tasting hygroscopic liquid of density 1.261, which is at 18.2 ° C. stiffens.
  • Glycerol was originally a by-product of fat saponification but is now technically synthesized in large quantities. Most technical processes are based on propene, which is processed into glycerol via the intermediates allyl chloride, epichlorohydrin. Another technical process is the hydroxylation of allyl alcohol with hydrogen peroxide at the WO 3 contact via the step of the glycide.
  • Trimethylolpropane [TMP, etriol, etiol, 1,1,1-tris (hydroxymethyl) propane] is chemically exactly 2-ethyl-2-hydroxymethyl-1,3-propanediol and comes in the form of colorless, hygroscopic masses having a melting point of 57 -59 ° C and a boiling point of 160 ° C (7 hPa) in the trade. It is soluble in water, alcohol, acetone, but insoluble in aliphatic and aromatic hydrocarbons. The preparation is carried out by reaction of formaldehyde with butyraldehyde in the presence of alkalis.
  • Pentaerythritol [2,2-bis (hydroxymethyl) -1,3-propanediol, penta, PE] is a white, crystalline powder with a sweetish taste that is non-hygroscopic and combustible and has a density of 1.399, a melting point of 262 ° C and has a boiling point of 276 ° C (40 hPa). Pentaerythritol is readily soluble in boiling water, poorly soluble in alcohol and insoluble in benzene, carbon tetrachloride, ether, petroleum ether.
  • pentaerythritol is prepared by reacting formaldehyde with acetaldehyde in aqueous solution of Ca (OH) 2 or NaOH at 15-45 ° C.
  • a mixed aldol reaction takes place in which reacting formaldehyde as a carbonyl component, acetaldehyde as a methylene component. Due to the high carbonyl activity of formaldehyde, the reaction of acetaldehyde with itself almost occurs not a.
  • the thus formed tris (hydroxymethyl) acetaldehyde is converted with formaldehyde in a crossed Cannizzaro reaction into pentaerythritol and formate.
  • Mono-, di-, triglycerides are esters of fatty acids, preferably longer-chain fatty acids with glycerol, wherein depending on the type of glyceride, one, two or three OH-groups of glycerol are esterified.
  • the acid component with which the glycerol can be esterified in mono-, di- or triglycerides which can be used according to the invention there are, for example, hexanoic acid (caproic acid), heptanoic acid (enanthic acid), octanoic acid (caprylic acid), nonanoic acid (pelargonic acid), decanoic acid (capric acid), Undecanoic acid, etc.
  • fatty acids such as dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), tetracosanoic acid (lignoceric acid) are preferred.
  • dodecanoic acid lauric acid
  • tetradecanoic acid myristic acid
  • hexadecanoic acid palmitic acid
  • octadecanoic acid stearic acid
  • eicosanoic acid arachidic acid
  • docosanoic acid behenic acid
  • tetracosanoic acid lignoceric acid
  • Hexacosanoic acid (cerotic acid), triacotinic acid (melissic acid) and the unsaturated species 9c-hexadecenoic acid (palmitoleic acid), 6c-octadecenoic acid (petroselenic acid), 6t-octadecenoic acid (petroselaidic acid), 9c-octadecenoic acid (oleic acid), 9t-octadecenoic acid (elaidic acid), 9c , 12c-octadecadienoic acid (linoleic acid), 9t, 12t-octadecadienoic acid (L inolaidic acid) and 9c, 12c, 15c-octadecatreic acid (linolenic acid).
  • the native fatty substances triglycerides
  • the modified native fatty substances partially hydrolyzed fats and oils
  • fatty acid mixtures can also be prepared by cleavage of native fats and oils and subsequently separated, with the purified fractions subsequently being converted again to mono-, di- or triglycerides.
  • Acids which are here esterified with the glycerol, in particular coconut oil fatty acid (about 6 wt .-% C 8 , 6 wt .-% C 10 , 48 wt.% C 12 , 18 wt .-% C 14 , 10 wt.
  • nonionic surfactants are also suitable as further plasticizers.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • EO ethylene oxide
  • the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 3 EO or 4 EO, C 9-11 alcohols with 7 EO, C 13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12-14 -alcohol with 3 EO and C 12-18 -alcohol with 5 EO.
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • nonionic surfactants having a melting point above room temperature.
  • preferred moldings are characterized in that nonionic surfactant (s) having a melting point above 20 ° C., preferably above 25 ° C., particularly preferably between 25 and 60 ° C. and in particular between 26.6 and 43, are used as plasticizers , 3 ° C, are used.
  • Suitable nonionic surfactants which have melting or softening points in the temperature range mentioned are, for example, low-foaming nonionic surfactants which may be solid or highly viscous at room temperature. If high-viscosity nonionic surfactants are used at room temperature, it is preferred that they have a viscosity above 20 Pas, preferably above 35 Pas and in particular above 40 Pas. Nonionic surfactants which have waxy consistency at room temperature are also preferred.
  • Preferred nonionic surfactants to be used at room temperature are from the groups of the alkoxylated nonionic surfactants, in particular the ethoxylated primary alcohols, and mixtures of these surfactants with structurally complicated surfactants such as polyoxypropylene / polyoxyethylene / polyoxypropylene (PO / EO / PO) surfactants.
  • the nonionic surfactant having a melting point above room temperature is an ethoxylated nonionic surfactant consisting of the reaction of a monohydroxyalkanol or alkylphenol having 6 to 20 carbon atoms, preferably at least 12 mol, more preferably at least 15 mol, especially at least 20 moles of ethylene oxide per mole of alcohol or alkylphenol emerged.
  • a particularly preferred room temperature solid nonionic surfactant is selected from a straight chain fatty alcohol having 16 to 20 carbon atoms (C 16-20 alcohol), preferably a C 18 alcohol and at least 12 moles, preferably at least 15 moles and especially recovered at least 20 moles of ethylene oxide.
  • C 16-20 alcohol straight chain fatty alcohol having 16 to 20 carbon atoms
  • C 18 alcohol preferably a C 18 alcohol and at least 12 moles, preferably at least 15 moles and especially recovered at least 20 moles of ethylene oxide.
  • the so-called “narrow range ethoxylates” are particularly preferred.
  • ethoxylated nonionic surfactant which are selected from C 6-20 monohydroxyalkanols or C 6-20 alkylphenols or C 16-20 fatty alcohols and more than 12 moles, preferably more than 15 moles and in particular more than 20 moles of ethylene oxide per mole of alcohol was recovered (n).
  • the nonionic surfactant preferably additionally has propylene oxide units in the molecule.
  • such PO units make up to 25 wt .-%, particularly preferably up to 20 wt .-% and in particular up to 15 wt.% Of the total molecular weight of the nonionic surfactant from.
  • Particularly preferred nonionic surfactants are ethoxylated monohydroxyalkanols or alkylphenols which additionally have polyoxyethylene-polyoxypropylene block copolymer units.
  • the alcohol or alkylphenol part of such nonionic surfactant molecules preferably constitutes more than 30% by weight, more preferably more than 50% by weight and in particular more than 70% by weight, of the total molecular weight of such nonionic surfactants.
  • More particularly preferred nonionic surfactants having melting points above room temperature contain from 40 to 70% of a polyoxypropylene / polyoxyethylene / polyoxypropylene block polymer blend containing 75% by weight of a reverse block copolymer of polyoxyethylene and polyoxypropylene with 17 moles of ethylene oxide and 44 moles of propylene oxide and 25% by weight. % of a block copolymer of polyoxyethylene and polyoxypropylene initiated with trimethylolpropane and containing 24 moles of ethylene oxide and 99 moles of propylene oxide per mole of trimethylolpropane.
  • R 1 O [CH 2 CH (CH 3 ) O] x [CH 2 CH 2 O] y [CH 2 CH (OH) R 2 ], in which R 1 is a linear or branched aliphatic hydrocarbon radical having 4 to 18 carbon atoms or mixtures thereof, R 2 denotes a linear or branched hydrocarbon radical having 2 to 26 carbon atoms or mixtures thereof and x for values between 0.5 and 1.5 and y is a value of at least 15.
  • nonionic surfactants are the end-capped poly (oxyalkylated) nonionic surfactants of the formula R 1 O [CH 2 CH (R 3 ) O] x [CH 2 ] k CH (OH) [CH 2 ] j OR 2 in which R 1 and R 2 are linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having 1 to 30 carbon atoms, R 3 is H or a methyl, ethyl, n-propyl, iso-propyl, n- Butyl, 2-butyl or 2-methyl-2-butyl radical, x is values between 1 and 30, k and j represent values between 1 and 12, preferably between 1 and 5.
  • each R 3 in the above formula may be different.
  • R 1 and R 2 are preferably linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having 6 to 22 carbon atoms, with radicals having 8 to 18 carbon atoms being particularly preferred.
  • R 3 H, -CH 3 or -CH 2 CH 3 are particularly preferred.
  • Particularly preferred values for x are in the range from 1 to 20, in particular from 6 to 15.
  • each R 3 in the above formula may be different if x ⁇ 2.
  • the alkylene oxide unit in the square bracket can be varied.
  • the value 3 for x has been selected here by way of example and may well be greater, with the variation width increasing with increasing x values and including, for example, a large number (EO) groups combined with a small number (PO) groups, or vice versa ,
  • R 1 , R 2 and R 3 are as defined above and x is from 1 to 30, preferably from 1 to 20 and in particular from 6 to 18.
  • Particularly preferred are surfactants in which the radicals R 1 and R 2 has 9 to 14 C atoms, R 3 is H and x assumes values of 6 to 15.
  • plasticizers may be glycerol carbonate, propylene glycol and propylene carbonate.
  • Glycerol carbonate is accessible by transesterification of ethylene carbonate or dimethyl carbonate with glycerol, as by-products of ethylene glycol or methanol incurred. Another synthetic route is based on glycidol (2,3-epoxy-1-propanol), which is converted under pressure in the presence of catalysts with CO 2 to glycerol carbonate. Glycerine carbonate is a clear, easily agitated liquid with a density of 1.398 gcm -3 , which boils at 125-130 ° C (0.15 mbar).
  • 1,3-Propanediol trimethylene glycol
  • 1,0597 a neutral, colorless and odorless, sweet-tasting liquid of density 1,0597, which solidifies at -32 ° C and boils at 214 ° C.
  • the preparation of 1,3-propanediol succeeds from acrolein and water with subsequent catalytic hydrogenation.
  • 1,2-propanediol (propylene glycol), which is an oily, colorless, almost odorless liquid, density 1.0381, which solidifies at -60 ° C and boils at 188 ° C.
  • 1,2-Propanediol is prepared from propylene oxide by water addition.
  • Propylene carbonate is a water-bright, easily mobile liquid, with a density of 1.21 gcm -3 , the melting point is -49 ° C, the boiling point at 242 ° C. Also propylene carbonate is industrially accessible by reaction of propylene oxide and CO 2 at 200 ° C and 80 bar.
  • additional additives which are preferably in solid form at room temperature.
  • pyrogenic silicas such as the commercially available Aerosil ® or precipitated silicas offer.
  • Particularly preferred methods according to the invention are characterized in that as further additives one or more materials from the group (preferably highly dispersed) silica, dispersion powder, high molecular weight polyglycols, stearic acid and / or stearic acid salts, and / or from the group of inorganic salts such as sodium sulfate, calcium chloride and / or from the group of Inclusiontruckner such as urea, cyclodextrin and / or from the group of superabsorbents such as (preferably crosslinked) polyacrylic acid and / or their salts such as Cabloc 5066 / CTF and mixtures thereof, is / are used.
  • Moldings preferred according to the invention may contain dyes. Suitable dyes, have a high storage stability and insensitivity to the other ingredients of the agent and against light and no pronounced substantivity to the dye-containing agents at least indirectly coming into contact substrates such as textiles, glass, ceramics or plastic dishes, so as not to stain them.
  • the colorants have high storage stability and insensitivity to light. At the same time, it should also be taken into account when choosing suitable colorants that colorants have different stabilities to oxidation.
  • water-insoluble colorants are more stable to oxidation than water-soluble colorants.
  • concentration of the colorant in the moldings varies. In the case of readily water-soluble colorants, it is typical to choose colorant concentrations in the range from a few 10 -2 to 10 -3 % by weight, based on the total molding. In the preferred because of their brilliance, but less water-soluble
  • the suitable concentration of the dyestuff is typically about 10 -3 to 10 -4 % by weight, based on the total molding
  • those dyes are preferred which can be oxidatively destroyed in a washing process and mixtures thereof with suitable blue dyes, so-called blue toners. It has proven to be advantageous to use colorants which are soluble in water or at room temperature in liquid organic substances. Suitable are, for example, anionic colorants, e.g. anionic nitrosofarads.
  • the shaped bodies according to the invention are not packaging material for liquids or solids, detergent pouches or the like.
  • the shaped body bears on one surface an adhesive layer, which is preferably water-dispersible or water-soluble, wherein the adhesive layer comprises a polymer which is adhesive at room temperature under pressure and / or in the presence of moisture.
  • the adhesive layer comprises a polymer which is adhesive at room temperature under pressure and / or in the presence of moisture.
  • a substance with detergency is contained in the adhesive layer, wherein this substance is preferably dispersed in the polymer.
  • the detergent or cleaning agent constituents contained in the adhesive layer are preferably present as viscous liquids, in particular as gel, and / or as solid particles, in particular daylight-active bleach, preferably based on TiO 2 , is contained. If the detergent ingredients are preferably in a viscous state, they can provide a desired tackiness between the substrate surface and the shaped article so as to aid in adhering the shaped article to the stain.
  • a suitable viscous liquid such as a paste, gel, or solution, may preferably have a viscosity of from about 200 to about 1,000,000 cps at low shear rates (less than 1 / s).
  • the viscosity may preferably be about 100,000 to about 800,000 cps and more preferably about 400,000 to about 600,000 cps.
  • a suitable gel may be formed from known gelling agents.
  • the gelling agent may e.g. be a swellable polymer.
  • Suitable gelling agents for use in the present invention may be e.g. Carboxypolymethylene, carboxymethylcellulose, carboxypropylcellulose, poloxamer, carrageenan, veegum, carboxyvinyl polymers and natural gums such as karaya gum, xanthan gum, guar gum, gum arabic, tragacanth gum and mixtures thereof.
  • Suitable gel compositions preferably also contain water, e.g. in amounts of 0.1% to 95%, based on the total gel composition.
  • a pH regulator can also be added to the gel.
  • Suitable materials include, for example, sodium bicarbonate, sodium phosphate, sodium hydroxide, ammonium hydroxide, sodium stannate, triethanolamine, citric acid, hydrochloric acid, sodium citrate, and combinations thereof.
  • the pH regulators may be added in an amount to maintain the pH of the gel composition, e.g. to 3 to about 12, preferably to about 4 to 10, in particular to about 5-9.
  • the pH regulators may e.g. in an amount of from about 0.01% to about 15% and preferably from about 0.05% to about 5% of the weight of the substance.
  • a suitable gel may already have a sufficient adhesive power by itself, but nonetheless additional gelling agents or adhesives may be included in the coating which may enhance adhesion to the textile.
  • the shaped body according to the invention carries an adhesive layer, this layer is preferably provided with a peelable, solid protective film, which corresponds to a preferred embodiment.
  • a suitable shaped body is less than 3000 ⁇ m thick, advantageously less than 2000 ⁇ m thick, in particular less than 1000 ⁇ m thick.
  • the thickness of a suitable shaped article may e.g. at about 500-900 microns, they may also be less than 500 microns, for example, be between 5 and 450 ⁇ m.
  • Preferred film thicknesses are in particular at values of e.g. ⁇ 400 ⁇ m, ⁇ 300 ⁇ m, ⁇ 200 ⁇ m or even less ⁇ 100 ⁇ m. Thicknesses of e.g. ⁇ 80 ⁇ m, ⁇ 60 ⁇ m or ⁇ 40 ⁇ m possible.
  • Possible minimum thicknesses may be, for example, at values such as 2, 3, 4, 5, 6, 7, 8, 9 or 10 ⁇ m. There are also minimum thicknesses of eg 15, 20, 25, 30, 35, 40, 45 or 50 microns possible, even values of at least 60, 70, 80, 90, 100, 150 or 200 microns are possible.
  • a film according to the invention can accordingly be e.g. a thickness of 3 to ⁇ 200 ⁇ m or e.g. from 20 to ⁇ 80 microns, just to name two examples.
  • the minimum length of the film can also be 5, 6, 7 or 8 cm.
  • the minimum width of the film can also be 5, 6, 7 or 8 cm.
  • the foil may e.g. rectangular, square, round or oval. It can also have any other shape, e.g. be heart-shaped, number-shaped or letter-shaped.
  • the shaped body can be produced by all known methods. So z. B. a film according to the invention can be prepared by various known methods for film production. A film may preferably be produced by a blowing or casting process. Methods such as extrusion and other methods are also possible.
  • the removal container is a container which at least partially surrounds the flexible, inflexible or advantageously resealable container, preferably a box, a bag or an envelope (envelope), in particular it is a dispenser.
  • a metering dispenser allows a portionwise removal of the shaped body, preferably a film.
  • the container may be designed so that only a single molded body is enclosed by the container.
  • the container can also be designed so that it encloses several moldings.
  • the container can also be designed so that it encloses a plurality of shaped bodies, wherein the individual shaped bodies are in turn individually surrounded by other containers.
  • a container enclosing a shaped body means that the container surrounds the shaped body at least partially, but in particular completely.
  • the removal container can be any container which is suitable for at least partially enveloping and / or holding together a film-shaped molding.
  • the container may be formed of a flexible, semi-rigid or dimensionally stable material.
  • a dimensionally stable container has the advantage, in particular to protect fragile film-shaped moldings from mechanical influences and to prevent corresponding damage.
  • the container is preferably made water vapor-tight.
  • the container is preferably formed perfume-tight.
  • means for child-safe opening are provided on the container, to prevent inadvertent contact of children with the film-shaped moldings.
  • metering and removal aids for the film-shaped moldings are provided on the container according to the invention.
  • a flexible container it may be e.g. to act a packaging bag, such as a flat bag, sealed edge bag, bottom bag, double bag, bag or bag, e.g. a pouch made of a multilayer, sheet-like and flexible composite material, the pouch preferably having a tear-open aid, such as e.g. has a tear strip or a scribe recess.
  • a packaging bag such as a flat bag, sealed edge bag, bottom bag, double bag, bag or bag, e.g. a pouch made of a multilayer, sheet-like and flexible composite material
  • the pouch preferably having a tear-open aid, such as e.g. has a tear strip or a scribe recess.
  • the film-shaped moldings packaged in one or more flexible containers may be intended for use in tape or sheet dispensers.
  • the extraction container may also comprise or consist of a roll.
  • the strip-shaped, sheet-shaped, disk-shaped or web-shaped, flexible molded body can thus be wound up on a roll, wherein the shaped body is preferably provided with separation points for portionwise removal.
  • Such removal containers are known for example from the field of adhesive tape scooters. Adhesive tape scooters fall under the generic term of tape dispensers. All tape dispensers may be suitable as a removal container.
  • the removal container thus comprises a roller, preferably a tape dispenser, wherein the molded body is provided in particular with separation points for portionwise removal, so is a preferred embodiment.
  • tape dispensers For the production of pieces of tape also devices, so-called tape dispensers, are useful, with which the tape is unwound from a roll and passed over a cutting element. When the free end of the band has reached the desired length, it is cut off with the cutting element.
  • the length of the tape to be cut off is determined by the user by unwinding the tape in the desired length and then cutting it off. To cut it must the tape end over the cutting element, typically a sawtooth cutting blade made of either metal or plastic, lead that this can act on the tape cutting.
  • Such or similar tape dispensers can be advantageously used according to the invention.
  • Refillable tape dispensers are particularly preferred for repeatably receiving a tape roll.
  • Particularly suitable are e.g. also such tape dispensers as are known in the field of correction tape dispensers (film transfer rollers). If the removal container according to the invention is a film transfer roller, this is a preferred embodiment.
  • the housing may be designed to be held directly in the user's hand or may form a cartridge which is inserted into a reusable outer housing.
  • a portion of the band extending between the coils is led out of the housing and around a tip which has a relatively sharp edge which is used to press the band against the surface to which the strip is to be washed
  • Detergent ingredient is to be attached.
  • the tape consists of a carrier tape, such as plastic or paper, one side of which has a coating of a mixture containing detergent or cleaning agent ingredient, which coating is the outer side of the tape as it passes around the tip.
  • the dispenser is held in the hand and the tip is pressed onto the surface with its edge pressing the tape against the surface along the entire width of the tape.
  • the mixture containing detergent or cleaning agent ingredient has an adhesive property and it has a greater adhesiveness to the textile than to its carrier tape, so that when the tip is moved across the Textit Structure in a direction to the edge of the Tip is perpendicular, the tip slides with respect to the carrier tape, which leads to tape being pulled off the supply reel.
  • the consequent rotation of the supply spool also rotates the take-up spool to maintain a substantially constant tension in the belt and the take-up spool reels the spent web over which the spike has passed and from there the coating of mixture containing detergent or cleaning agent ingredient the textile surface has been deposited. In this way a continuous strip of the mixture containing detergent or cleaning agent ingredient is deposited on the textile, this strip having a length corresponding to the distance that the donor tip has been displaced.
  • This principle is advantageously applicable to the present invention.
  • This is a washing or cleaning agent tape dispenser, with which you can apply a washing or cleaning agent mixture like a film on a surface.
  • the mixture containing washing or cleaning agent on the carrier tape is in this case the shaped article according to the invention.
  • a film transfer roller for transferring a washing or cleaning agent applied to textile in the form of a film on a carrier tape is a preferred article according to the invention.
  • Transfer rollers serve to transfer a film from a carrier film to a substrate.
  • a film is transferred to the substrate upon pressure contact between the applicator head of the device and the substrate, and the film carrier dissolved from the film is wound onto a take-up spool.
  • containers for dispensing sheets or strips are also useful. These are devices that contain a stack of sheets, strips or foils, etc., and include a dispensing aid for the sheets, strips or foils.
  • this stack is arranged so that upon removal of the uppermost sheet, the underlying sheet is aligned so that it is then removed without difficulty.
  • the following sheet already tracked so far that it protrudes from the removal slot and can be easily removed afterwards.
  • it is a block of films each having a layer of a flexible polymeric material which may be provided at a second end region with a coating of repositionable pressure-sensitive adhesive material, while remaining free of adhesive along a visually recognizable first end region in a stack with the adjacent ends of the sheets aligned and the first and second ends of successive sheets disposed adjacent one another.
  • the stack may be arranged in a chamber which is partially bounded in the upper wall by a slot through which the first end portion of the uppermost sheet protrudes.
  • a film or film may be applied directly to the stained substrate by the consumer in accordance with the invention.
  • a shaped body according to the invention such as preferably a film, for the preparation of a wash liquor.
  • Moldings according to the invention can be used successfully in particular in connection with textile washing in an automatic washing machine.
  • a shaped article according to the invention can e.g. Aftertreatment and / or care components included.
  • a further subject is therefore a process for the preparation of an aqueous system with cleansing power and / or care capacity, in which at least one portion of the molded body according to the invention is removed from the washing or cleaning agent delivery system according to the invention and added to an aqueous system.
  • the aqueous system with cleaning and / or care properties is a wash liquor for textile, dishwashing, body, floor or window cleaning.
  • the portioning according to the invention of a washing or cleaning agent into shaped bodies according to the invention makes possible an individual dosage of non-liquid washing or cleaning agents, which the consumer can control, for example, via the number of films to be used.
  • Another object is accordingly the use of a washing or cleaning agent dispensing system for the individual dosage of non-liquid washing or cleaning agents.
  • the shaped article according to the invention can be added in an automatic washing machine via the dispensing chamber of the detergent drawer or placed directly to the laundry in the washing drum.
  • Another object of the invention is a method for local stain treatment of substrates, especially textiles or hard surfaces, in which one takes a molding, from the washing or cleaning agent delivery system according to the invention and this directly adheres to the stain to be treated, for example by means of a transfer roller.
  • Stain treatment is to be understood as meaning all those treatments which cause the stain intensity of the spot to be treated to decrease or that the stain is less perceptible and thus less disturbing to the observer. Ideally, the stain is completely removed by the treatment.
  • "Local” means that the stained good, e.g. Textile, need not be subjected to a cleaning process as a whole, for example in an automatic washing machine, but that only the single spot (i.e., the stained area) is treated locally. This procedure is particularly material-friendly, because only the actual soiling areas undergo cleaning.
  • the spot to be treated and / or the shaped body is moistened onto the spot before the application of the shaped body.
  • moistening results in the application of the molding on the substrate to be treated adhesion.
  • water-soluble or water-dispersible films which are pressed onto a moistened spot will develop a certain stickiness on contact with the wet textile as the film material is dissolved by the moisture.
  • the loosened film can adhere to the stain, or, depending on how much the stain was moistened, later on completely absorbed in the stained fabric and there release the active ingredients contained.
  • the desired adhesion can also come from an adhesive which is applied to the molding, preferably film.
  • an adhesive which is applied to the molding, preferably film.
  • Preferably usable e.g. moisture activatable adhesive.
  • Corresponding adhesives are known, e.g. of stamps or envelopes. But it may also be pressure-sensitive, preferably removable adhesives. Such adhesives are known, e.g. sticky sticky notes, which you can simply stick to a surface and solve it without effort.
  • the shaped article is drawn back from the textile (i.e., the stain) after a contact time, for example of at least 30 seconds.
  • the exposure time can also last longer, for example ⁇ 1 minute, ⁇ 2 minutes, ⁇ 3 minutes, ⁇ 4 minutes or ⁇ 5 minutes.
  • the film may also be left on the surface
  • the stained textile is treated after application of the stain / film and waiting for exposure to water, for example, by local rubbing with a damp cloth, in particular by subjecting the textile to a manual or machine textile washing process.
  • the molded article of the invention when intended for stain treatment, preferably has a size such that it completely covers the stain to be treated.
  • This can be handled analogously to a wart patch which is tailored to the size of the wart area and then glued to the wart.
  • the shaped body according to the invention is thus cut to size. In a preferred method, therefore, a shaped body is cut to spot size and then applied to the spot to be treated.
  • a washing or cleaning agent patch which comprises a nonwoven and a plaster mass which, in addition to adhesive constituents, comprises at least one substance with a cleaning action, wherein the plaster composition covers an entire surface side of the nonwoven, is a shaped article which is preferred according to the invention.
  • the shaped body according to the invention is not a plaster.
  • a detergent or cleaning agent patch for example, various ingredients such. As resins, polymers, etc. fused together under heat and still applied warm to the web. For example, before or after application to the nonwoven, a substance with cleaning action can be added to the melt.
  • the shaped body preferably foil, may preferably consist of a soft, deformable material which can adapt to the substrate surface to be treated.
  • the shaped body is advantageously readily adaptable to the shape of the substrate surface, at least after moistening the spot and / or the shaped body.
  • the shaped body according to the invention is preferably transparent, so that it is inconspicuous after application to the surface to be cleaned and is perceptible only on closer inspection.
  • a shaped body according to the invention contains at least one substance with a cleaning action.
  • Suitable substances include, in particular, all materials which provide bleaching action or stain removal.
  • Suitable substances are all surfactants, in particular anionic, nonionic, cationic and / or amphoteric surfactants.
  • Suitable substances are all bleaching agents, e.g. Peroxides, metal chlorites, perborates, percarbonates, peroxyacids.
  • Suitable peroxide compounds are e.g. Hydrogen peroxide, calcium peroxide, carbamide peroxide.
  • Suitable metal chlorites are e.g. Calcium chlorite, barium chlorite, magnesium chlorite, lithium chlorite, sodium chlorite and potassium chlorite. Also suitable may be hypochlorite and chlorine dioxide. A preferred chlorite is sodium chlorite.
  • a shaped article according to the invention contains adhesives in a layer which is applied to the shaped article.
  • Suitable adhesives may have limited water solubility. Such adhesives may e.g. Hydroxyethyl or propylcellulosen included. Preferably, suitable adhesives may also include polyvinylpyrrolidone, preferably having a molecular weight of from about 50,000 to about 300,000
  • an adhesive suitable for use in the present invention may advantageously comprise a combination of copolymers of methyl vinyl ether and maleic anhydride and the polymer carboxymethyl cellulose.
  • a suitable adhesive may include phthalate resins, polyvinyl ether dispersions and acrylate copolymer, for example, a suitable adhesive may be 5-25 wt% phthalate resin, 25-45 wt% polyvinyl ether dispersions and 35-55 wt. % Acrylate copolymer exist, wt .-% based on the adhesive.
  • viscoelastic adhesives in particular those which are permanently tacky and tacky at 20 ° C. and, even with slight substrate specificity, adhere immediately to almost all substrates, in particular textile, even under slight contact pressure.
  • Polymers contained in preferred adhesives are e.g. Natural and synthetic rubbers, polyacrylates, polyesters, polychloroprenes, polyisobutenes, polyvinyl ethers and polyurethanes. These may preferably be used in combination with additives such as resins, plasticizers and / or. Antioxidants are used.
  • Suitable adhesives are in particular all those rubber materials and / or synthetic resins, homopolymers or copolymers which stick well when pressure is applied.
  • Suitable adhesives are, for example, polymers having a glass transition temperature of -10 to -70 ° C.
  • Non-limiting examples of suitable room temperature pressure-adhesive polymers include e.g. Styrene / isoprene / styrene block copolymers, styrene / butadiene rubber, polybutene rubber, polyisoprene rubber, butyl rubber, silicone rubber, natural rubber, synthetic isoprene rubber, synthetic resins such as poly (meth) acrylate, polyvinyl ether, PUR, polyester, Polyamide, ethylene copolymers.
  • Preferred adhesives include acrylate copolymers comprising at least 50% of acrylic or methacrylic acid alkyl esters and vinyl ester monomers.
  • suitable monomers are n-butyl acrylate or methacrylate, hexyl acrylate, 2-ethylbutyl acrylate, isooctyl acrylate, 2-ethylhexyl acrylate or methacrylate, nonyl acrylate, acrylic or methacrylic acid, itaconic acid, maleic acid, maleic anhydride, hydroxyethyl acrylate, acrylamide, acrylonitrile, vinylpyrrolidone, vinylimidazole, vinyl acetate, propionate.
  • the coating of the shaped body may also contain an additional carrier material.
  • Suitable carrier materials may include, for example, humectants. Suitable humectants are, for example, glycerol, sorbitol, polyethylene glycol, propylene glycol and other polyhydric alcohols.
  • Humectants may e.g. in an amount of from about 10% to about 95%, preferably from about 20% to about 80%, and more preferably from about 50% to about 70% by weight of the coating.
  • the coating may include other materials, for example fragrances, opacifying agents, colorants, and chelating agents, e.g. Ethylenediaminetetraacetic acid.
  • the coated shaped body may provide a separating layer between the coating and the actual shaped body.
  • the release layer is a protective or overcoat layer that is substantially impermeable to the active agent.
  • a suitable release layer may preferably comprise a rigid sheet material such as polyethylene, paper, polyester or other material, which in turn may be coated with a non-adhesive type of material, e.g. Wax, silicone, polyester such as Teflon®, fluoropolymers or other non-adhesive materials may be coated.
  • the molding according to the invention is not a so-called wet wipe, as e.g. from the field of glasses cleaning cloths, the body hygiene tissues or even the refreshment wipes is known.
  • a shaped article according to the invention is coated.
  • the preparation of a coating can be done in any way, for example by brushing, spraying or dipping the molding.
  • a polymer which is adhesive at room temperature using pressure and optionally other substances is dissolved in a solvent to produce a coating solution.
  • This coating solution is applied to the surface of the molded article, the coating solution is then dried.
  • a suitable coating in particular an adhesive layer, may also comprise fillers, such as SiO 2 powder, CaCO 3, or supports, such as cyclodextrin or cellulose powder.
  • the shaped body according to the invention is preferably a film or a film.
  • the film production is possible via all known ways.
  • Film production via thermoplastic processing by calendering or extrusion is most preferred. In particular, coextrusion is preferred.
  • the blown film process and the flat film process according to the invention are very preferred processes for film production.
  • blown films The production of blown films is known. For example, mixing of polymeric material, such as e.g. PVOH powder with additives and stabilizers in the solid state. This mixture is melted in the heated extruder. Further ingredients may e.g. be added to the melt. This is followed by the blowing of the melt, the cooling and the winding of the film.
  • polymeric material such as e.g. PVOH powder
  • additives and stabilizers in the solid state.
  • Further ingredients may e.g. be added to the melt. This is followed by the blowing of the melt, the cooling and the winding of the film.
  • Blown films are generally less expensive to produce than cast films, but the film thickness distribution may fluctuate a little more and may possibly lead to more air bubbles.
  • blown films are slightly harder and have less recovery properties than cast films, whereas these can be soft, flexible, almost rubbery and can also have a high tendency to return.
  • the polymer solutions can be prepared according to the invention by use of solvents, which is preferred, or by chemical conversion of insoluble macromolecules into soluble derivatives. Other optional ingredients may be e.g. be added to the polymer solution.
  • solvents which is preferred, or by chemical conversion of insoluble macromolecules into soluble derivatives.
  • Other optional ingredients may be e.g. be added to the polymer solution.
  • wet-casting For example, in cellophane production, a highly viscous cellulose solution is forced through a slot die into a strong acid precipitation bath:
  • the dry casting process for the performance of which belt or drum casting machines can be used.
  • the polymer solution which may optionally contain further ingredients according to the invention, is poured from a storage container preferably through a nozzle onto an endless, preferably highly polished, metal strip .
  • the belt speeds depend strongly on the material used and on the desired film thickness. They can preferably be between 2 and 60 meters per minute.
  • the film can be stripped off after evaporation of most of the solvents. For winding, it is preferably passed through a dryer with hot air or hot rollers. Resulting film thicknesses in this method may preferably be 15 to 300 ⁇ m.
  • the polymer solution beforehand poured over a filter before it is poured onto the metal strip is pressed back and unresolved particles that could otherwise lead to specks. It is likewise possible and preferred to at least partially free the polymer solution from air that is contained in a degassing container before it is poured onto the metal plate.
  • PVOH foils After the casting process is thus e.g. in a batch tank dissolving PVOH powder / granules and plasticizer (e.g., PEG and / or glycerol) in water. Subsequently, the solution is fed to a reservoir. The solution is then heated to about 80 ° C and then fed via a slot die a rolled strip. In the drying process (air heating channel), the solution is expressed as a film. Thereby, e.g. in the batch tank according to the invention to the PVOH mixture perfume oils are added.
  • plasticizer e.g., PEG and / or glycerol
  • Trommelg machineclar Similar to the strip casting method is the Trommelg foolclar.
  • heated drums are used at the location of the metal strip, such as those with a diameter of 2-3 m and widths of about 2 m.
  • films are usually obtained which generally show uniform, uniform film thickness distribution and little air inclusions, although the process is expensive because of the energy-intensive drying.
  • the cast process can produce thinner foils than the blown process.
  • the cast method is preferably applied to those which are not meltable or decompose only with decomposition, e.g. Cellulose or polyimides.
  • the casting process is also preferably used.
  • Rolling or sintering processes are in principle also possible for film production, but only in exceptional cases makes sense, e.g. for the production of tetrafluoroethylene films and polyimide films.
  • a process for the production of a film is also possible, wherein a rollable preparation is first prepared by dissolving or dispersing one or more polymers in a liquid carrier medium and this is then brought into the form of a film by means of rolling with the aid of a rolling device.
  • the liquid carrier medium can be evaporated.
  • a liquid carrier medium preferably comprises solvents or dispersants such as water, alcohols, ethers or hydrocarbons or mixtures of two or more of the substances mentioned, wherein the substances or mixtures of substances are liquid at room temperature (20 ° C.).
  • Suitable alcohols are, for example, the mono- or polyhydric alcohols having 1 to 5 carbon atoms, such as, for example, ethanol, isopropanol, ethylene glycol, glycerol and propylene glycols.
  • the content of the liquid carrier medium may be e.g. in the range of 20 to 90 wt.% or 30 to 70 wt.%.
  • a suitable rollable formulation may e.g. semi-solid or dough-like consistency, or it may be a viscous liquid with which a suitable carrier is coated and the desired film thickness is produced by rolling with a rolling device.
  • the finished film is then removed from the carrier after drying.
  • suitable support materials can be selected suitable support materials.
  • Suitable rolling devices are e.g. the known, with at least two equal or opposite rollers or rollers provided so-called forward roll or reverse roll coater, with a reverse roll method is preferred.
  • the resulting (by all possible methods) films can be further processed, for example, by vapor deposition, coating, printing or flocking.
  • the films according to the invention are foamed films.
  • gas bubbles of a suitable gas e.g. Air included.
  • Such films with trapped gas bubbles are characterized by a particularly good feel. Furthermore, they can show improved water solubility.
  • Preferred films in particular foamed films, have a density of ⁇ 1 kg / m 3 .
  • a blowing or blowing agent can be used. It can e.g. foaming can be achieved by mechanical stirring of the still liquid or viscous carrier mass. It can e.g. to provoke a gas-producing chemical reaction. It can e.g. a volatile solvent may be used, which is evaporated at elevated temperatures. It can e.g. an introduction of a gas or a liquefied gas into the still viscous carrier mass.
  • blowing agents are substances that decompose on heating with evolution of gas, so that e.g. Nitrogen or carbon dioxide are released.
  • Carbonates, bicarbonates, borohydrides, silicon oxyhydrides, etc. are examples of suitable inorganic blowing agents. However, it is also possible to use all organic blowing agents which are known to be used in the production of porous or bubble-containing plastics. Films according to the invention, such as preferably foamed films, can also be present in confetti form. Confetti shape means that it is a variety of foil snippets or foil shreds or small pieces of foil. The term "confetti" is common in the vernacular for small, colorful scraps of paper.
  • Transparencies in confetti form do not necessarily have to be as small as the well-known paper confetti, which is thrown up especially during carnival parades, but also at other celebrations, such as children's birthday parties or weddings in the air.
  • the confetti shape can be regular or irregular, for example, can be circular Folienschnipsel, it can be, for example, heart-shaped Folienschnipsel. Any conceivable shape is possible and obtainable, for example, by punching out the foil confetti from a larger mother foil.
  • the use of films according to the invention in confetti form can be advantageous, for example, in hand-textile washing, if a certain amount of the films in confetti form is scattered in the textile treatment bath.
  • moldings preferably films
  • a shaped article according to the invention may preferably also comprise fragrances (perfume).
  • the shaped article according to the invention comprises at least 0.05% by weight of perfume, preferably at least 0.1% by weight of perfume, in particular at least 0.5% by weight of perfume, based on the entire shaped article.
  • the molded article may also contain larger amounts of perfume, e.g. at least 1, 2, 4, 6, 8 or even at least 15 wt .-% perfume.
  • Useful upper limits of perfume may e.g. at 10 wt%, 9 wt%, 8 wt%, 7 wt%, 6 wt%, 5 wt%, 4 wt%, 3 wt%, 3 or even 1 wt .-% are.
  • fragrances having a boiling point above 250 ° C and a logP value of ⁇ 3.0 so is a preferred embodiment. It has been found that moldings according to the invention which contain such minimum amounts of fragrances having a boiling point above 250 ° C. and a log P value of ⁇ 3.0 have particularly advantageous scent properties.
  • the octanol / water partition coefficient of a perfume ingredient is the ratio between its equilibrium concentration in octanol and in water. Since the distribution coefficients of the perfume ingredients often have high values, eg 1000 or higher, they are more conveniently expressed in the form of their base 10 logarithm, one speaks of the so-called log P value.
  • Preferred fragrances of this invention have a logP of ⁇ 3.0 or higher, e.g. B. of ⁇ 3.1, preferably ⁇ 3.2, in particular ⁇ 3.3.
  • the logP value of numerous fragrances is documented; For example, the Pomona92 database, available from Daylight Chemical Information Systems, Inc., (Daylight CIS), Irvine, California, contains numerous logP values, along with citations to the original literature. However, the logP values are most conveniently calculated by the "CLOGP” program, which is also available from Daylight CIS. This program also lists the experimental logP values if they are available in the Pomona92 database.
  • the "calculated logP" (ClogP value) is determined by the fragment approximation according to Harsch and Leo (see Leo, in Comprehensive Medicinal Chemistry, Vol. 4, C. Harsch, PG Sammens, JB Taylor and CA Ransden, Eds., P.
  • the fragment approximation is based on the chemical structure of each of the perfume ingredients, taking into account the numbers and types of atoms, the atomic bonding ability, and the chemical bond.
  • the ClogP values which are the most reliable and widely used estimates for this physicochemical property, are preferably used in the present invention instead of the experimental logP values in the selection of perfume ingredients useful in the present invention.
  • boiling point values may be obtained, for example, from various known chemistry manuals and databases, such as the Beilstein Handbook, Lange's Handbook of Chemistry, and the CRC Handbook of Chemistry and Physics. If a boiling point is given only at a different pressure, usually a pressure lower than the normal pressure of 760 mm Hg, the boiling point at normal pressure can be determined approximately with the help of boiling point pressure nomographs such as those in " The Chemist's Companion, AJ Gordon and RA Ford, John Wiley & Sons Publishers, 1972, pp. 30-36 , specified, estimated.
  • the boiling point values can also be calculated by computer programs based on the molecular structure data such as those described in " Computer-assisted Prediction of Normal Boiling Points of Pyrans and Pynoles ", DT Starton et al., J. Chem. Inf. Comput. Sci., 32 (1992), pp. 306-316 , " Computer-assisted Prediction of Normal Boiling Points of Furans, Tetrahydrofurans, and Thiophenes "(Computer-Aided Prediction of the Normal Boiling Points of Furans, Tetrahydrofurans and Thiophenes), DT Starton et al., J. Chem. Inf. Comput. Sci., 31 (1992 ), Pp. 301-310 , and the references cited therein, and " Predicting Physical Properties from Molecular Structure ", R. Murugan et al., Chemtech June 1994, pp. 17-23 , All publications mentioned above are incorporated by reference.
  • Table 1 below lists several fragrances that fulfill the criteria boiling point> 250 ° C and ClogP ⁇ 3. Such fragrances which fulfill these criteria are also referred to as persistent fragrances in the further course. Table 1: Examples of persistent fragrances Perfume ingredients Approximately boiling point (° C) ClogP Boiling point> 250 ° C and ClogP> 3.0 Allylcylclohexanpropionat 267 3,935 At brettolid 300 6.261 amyl benzoate 262 3,417 Amylcinnamat 310 3,771 amyl cinnamic aldehyde 285 4,324 Amylzimtaldehyddimethylacetal 300 4,033 iso-amyl salicylate 277 4,601 aurantiol 450 4,216 benzophenone 306 3,120 benzyl 300 4,383 para-tert-butylcyclohexyl acetate +250 4,019 iso-butylquinoline 252 4,193 beta-caryophyllene
  • the shaped articles of the present invention preferably contain at least 3 different resistant fragrances, more preferably at least 4 different resistant fragrances, and even more preferably at least 5 different resistant fragrances.
  • the shaped bodies preferably contain ⁇ 20% by weight, ⁇ 25% by weight, ⁇ 30% by weight, ⁇ 35% by weight, ⁇ 40% by weight, ⁇ 45% by weight. , ⁇ 50 wt .-%, ⁇ 55 wt .-%, ⁇ 60 gel .-%, ⁇ 65 wt .-%, ⁇ 75 wt .-%, ⁇ 80 wt .-%, ⁇ 85 wt .-%, ⁇ 90 wt .-% or even ⁇ 95 wt .-% of persistent fragrances, wt .-% based on the total amount of the fragrances contained in the molding.
  • non-odor or very low odor materials are used as perfume diluents or extenders.
  • these materials are dipropylene glycol, diethyl phthalate, triethyl citrate, isopropyl myristate and benzyl benzoate. These materials are e.g. used to dilute and stabilize some other perfume ingredients. These materials are not included in the calculation of the total amount of fragrances contained in the molding.
  • Non-persistent odorants in the context of this invention are those fragrances which have a boiling point of less than about 250 ° C or a ClogP of less than about 3.0 or both a boiling point of less than about 250 ° C and a ClogP of less than about 3.0.
  • non-resistant fragrances are preferably minimized in the shaped bodies of the present invention, ie the shaped bodies preferably contain ⁇ 60% by weight, ⁇ 55% by weight, ⁇ 50% by weight, ⁇ 45% by weight.
  • non-resistant fragrances are used at least in small amounts, namely to improve the odor of the molded article as such.
  • the shaped bodies of the present invention therefore preferably contain ⁇ 1% by weight, preferably ⁇ 5% by weight, more preferably ⁇ 10% by weight, even more preferably ⁇ 15% by weight, in particular even ⁇ 20, ⁇ 25 or even ⁇ 30 wt .-%, of non-resistant fragrances, wt .-% based on the total amount of fragrances contained in the molding.
  • the molding according to the invention contains perfume precursors, which preferably release fragrances by hydrolysis only in the presence of H 2 O.
  • the perfume precursors may be advantageously selected from ⁇ -amino ketone perfume precursors, aldehyde or ketone releasing perfume precursors, alcohol releasing perfume precursors, preferably silicic acid esters, and orthocarbonate and ortho ester perfume extenders.
  • the fragrance precursors are selected from acetals, ketals, orthoesters, orthocarbonates, and mixtures thereof.
  • a particularly preferred fragrance precursor is of the formula in which R is hydrogen, linear C 1 -C 8 -alkyl, branched C 3 -C 20 -alkyl, cyclic C 3 -C 20 -alkyl, branched cyclic C 6 -C 20 -alkyl, linear C 6 -C 20 -alkenyl, branched C 6 -C 20 -alkenyl, cyclic C6- C20 alkenyl, branched cyclic C6-C20 alkenyl, substituted or unsubstituted C6-C20 aryl, and mixtures thereof;
  • R1, R2 and R3 are independently linear, branched or substituted C1-C20 alkyl; linear, branched or substituted C 2 -C 20 alkenyl; substituted or unsubstituted C3-C20 cyclic alkyl; substituted or unsubstituted C 6 -C 20 aryl, substituted or unsubstituted
  • the fragrance precursor is an acetal or a ketal of the formula contain,
  • R is linear C 1 -C 20 -alkyl, branched C 3 -C 20 -alkyl, cyclic C 6 -C 20 -alkyl, branched cyclic C 6 -C 20 -alkyl, linear C 2 -C 20 -alkenyl, branched C 3 -C 20 alkenyl, C 6 -C 20 cyclic alkenyl, branched cyclic C 6 -C C 6 -C 20 alkenyl, substituted or unsubstituted 20 aryl, and mixtures thereof;
  • R 1 is hydrogen or R;
  • R 2 and R 3 are each independently selected from the group consisting of linear C 1 -C 20 alkyl, branched C 3 -C 20 alkyl, cyclic C 3 -C 20 alkyl, branched cyclic C 6 -C 20 Alkyl, linear C 6 -C 20 alkenyl, branched C 6 -C 20 alkenyl, cyclic C 6 -C 20 alkenyl, branched cyclic C 6 -C 20 alkenyl, C 6 -C 20 aryl, substituted C 7 -C 20 aryl and mixtures thereof.
  • a fragrance precursor having the formula: wherein R 1 , R 2 , R 3 and R 4 are independently linear, branched or substituted C 1 -C 20 alkyl, linear, branched or substituted C 2 -C 20 alkenyl, substituted or unsubstituted, cyclic C 5 -C 20 -Alkyl, substituted or unsubstituted C 6 -C 20 -aryl, substituted or unsubstituted C 2 -C 40 -alkyleneoxy, substituted or unsubstituted C 3 -C 40 -alkyleneoxyalkyl, substituted or unsubstituted C 6 -C 40 -alkylene-aryl, substituted or unsubstituted C 6 -C 32 aryloxy, substituted or unsubstituted C 6 -C 40 alkyleneoxyaryl, C 6 -C 40 oxyalkylene aryl, and mixtures thereof.
  • a molding according to the invention may preferably comprise fragrances selected from the group bergamot oil, tangerine oil, dimethyl anthranilate, dihydromyrcenol (2-methyl-6-methylene-2-octanol), tetrahydrolinalool, isobornyl acetate, ethyllinalool, limonene, orange oil, isobornyl acetate, eucalyptus oil (globulus), Aldehyde C 10, styrolyl acetate, citronitrile ((Z, E) -3-methyl-5-phenyl-2-pentene-nitrile), undecabertol (4-methyl-3-decen-5-ol), styreneyl acetate, tartalide (acetyl hexamethyl tetralin) are selected.
  • fragrances selected from the group bergamot oil, tangerine oil, dimethyl anthranilate, dihydromyrcenol
  • a molded article according to the invention may preferably comprise fragrances selected from the group aldehyde C 14, decalactone gamma, cyclamen aldehyde, troenan (5-methyl-5-propyl-2- (1-methylbutyl) -1,3-dioxane), canthoxal (2 Methyl 3- (para-methoxy-phenyl) -propanal), citronellol, geraniol, musk, phenylethyl alcohol, phenatez (2-phenylethyl 2-methylpropanoate), phenylethyl isobutyrate, jasmelia (2H-pyran-4-ol, 3-butyltetrahydro-5- methyl-acetate), Hexyl cinnamic aldehyde (alpha), ylang, cyclohexyl salicylate, hexenyl salicylate (cis-3), sandelice, guaiacolite,
  • Possible other constituents which may be present in the moldings according to the invention are advantageously selected from the group of builders, bleaches, surfactants, optical brighteners, bleach activators, enzymes, electrolytes, nonaqueous solvents, pH regulators, fluorescers, dyes, hydrotopes, foam inhibitors, Silicone oils, anti redeposition agents, graying inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, corrosion inhibitors, antistatic agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents and UV absorbers.
  • builders bleaches, surfactants, optical brighteners, bleach activators, enzymes, electrolytes, nonaqueous solvents, pH regulators, fluorescers, dyes, hydrotopes, foam inhibitors, Silicone oils, anti redeposition agents, graying inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial
  • Surfactants are preferably present in the molding according to the invention in amounts of ⁇ 0.1 gel .-%, ⁇ 1 wt .-%, ⁇ 3 wt .-%, ⁇ 5 wt .-%, ⁇ 10 wt .-%, ⁇ 15 wt. %, ⁇ 20 wt .-%, in particular ⁇ 25 wt .-%, wt .-%, based on the total molded article.
  • a suitable upper limit for surfactants present in the molding according to the invention may preferably be 40% by weight, 30% by weight, 20% by weight, 15% by weight, 10% by weight or 5% by weight.
  • the shaped body according to the invention contains no surfactants.
  • Bleaching agents and / or bleach activators are preferably present in the molding according to the invention in amounts of ⁇ 0.1% by weight, ⁇ 1% by weight, ⁇ 3% by weight, ⁇ 5% by weight, ⁇ 10% by weight, ⁇ 15% by weight. -%, ⁇ 20 wt .-%, in particular ⁇ 25 wt.% Contain, wt .-% based on the total moldings.
  • a suitable upper limit for bleaching agents and / or bleach activators contained in the molding according to the invention may preferably be 40% by weight, 30% by weight, 20% by weight, 15% by weight, 10% by weight or 5% by weight. lie.
  • the shaped article according to the invention contains no bleaching agents and / or bleach activators.
  • builders in amounts ⁇ 15 wt.%, ⁇ 10 wt.%, ⁇ 9 wt.%, ⁇ 8 wt.%, ⁇ 7 wt.%, ⁇ 6 wt.%, ⁇ 5 wt.%, ⁇ 4 %
  • ⁇ 3% by weight or ⁇ 2% by weight in particular ⁇ 1% by weight,% by weight, based on the total molding.
  • a shaped body according to the invention contains no builders.
  • Enzymes, electrolytes, non-aqueous solvents, pH adjusters, fluorescers, dyes, hydrotropes, foam inhibitors, silicone oils, antiredeposition agents, grayness inhibitors, anti-shrinkage agents, crease inhibitors, dye transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, corrosion inhibitors, antistatic agents, ironing aids, repellents and impregnating agents , Swelling and / or UV absorbers are preferably in amounts of in each case ⁇ 30% by weight, ⁇ 20% by weight, ⁇ 15% by weight, ⁇ 10% by weight, ⁇ 9% by weight, ⁇ 8 wt%, ⁇ 7 wt%, ⁇ 6 wt%, ⁇ 5 wt%, ⁇ 4 wt%, ⁇ 3 wt% or ⁇ 2 wt%, especially ⁇ 1 wt.% Contain, wt.% Based on the total molding.
  • a shaped article according to the invention may be free
  • washing and / or cleaning agent components which are particularly suitable according to the invention will be explained in greater detail below. These constituents may be present in the moldings according to the invention themselves and / or also in the coatings of the moldings. The following ingredients are purely optional but may preferably be included.
  • Anionic surfactants may preferably be present in the moldings according to the invention.
  • a shaped article according to the invention contains anionic surfactants, preferably in amounts of at least 0.1% by weight, based on the entire shaped article.
  • the agent of the invention is substantially free of anionic surfactant, thus advantageously contains ⁇ 5 wt.%, Preferably ⁇ 1 wt .-%, in particular no anionic surfactant.
  • soaps may be present in the moldings of the invention.
  • Particularly suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, and in particular of natural fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures.
  • the content of the composition of soaps, independently of other anionic surfactants is preferably not more than 3% by weight and in particular 0.5 to 2.5% by weight, based on the total agent.
  • the agent according to the invention is free of soap.
  • the anionic surfactants and soaps may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine. Preferably, they are in the form of their sodium or potassium salts, especially in the form of the sodium salts.
  • Anionic surfactants and soaps may also be prepared in situ by incorporating into the spray-dried composition the anionic surfactant acids and optionally fatty acids which are then neutralized by the alkali carriers in the spray-dried composition.
  • nonionic surfactants can be present in the moldings according to the invention.
  • their content may be up to 2 or 3 or 5 wt.%. It may also contain greater amounts of nonionic surfactant, for example up to 5 wt.% Or 10 wt.% Or 15 wt.% Or 20 wt.%, 30 wt.%, 40 wt.% Or up to 50 wt .-% or even beyond, if appropriate, for example up to 60% by weight.
  • Sensible lower limits may be values of 0.01% by weight, 0.1% by weight, 1% by weight, 2% by weight, 3% by weight or 4% by weight. Higher lower limits are also possible, e.g.
  • the nonionic surfactants are in larger quantities, e.g. up to 50% by weight, advantageously from 0.1 to 40% by weight, particularly preferably from 0.5 to 30 and in particular from 2 to 25% by weight, in each case based on the total agent.
  • a shaped article according to the invention contains nonionic surfactants, preferably in amounts of at least 0.1% by weight, based on the entire shaped article.
  • the agent of the invention is substantially free of nonionic surfactant, thus advantageously contains ⁇ 5 wt.%, Preferably ⁇ 1 wt .-% of nonionic surfactant.
  • nonionic surfactants are presented below.
  • the moldings according to the invention may preferably also contain cationic surfactants.
  • Suitable cationic surfactants are, for example, surface-active quaternary compounds, in particular having an ammonium, sulfonium, phosphonium, iodonium or arsonium group.
  • Benzalkonium chlorides with C 8 -C 18 -alkyl radicals, in particular C 12 -C 14 -alkyl-benzyl-dimethylammonium chloride.
  • a particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ®).
  • anionic surfactant-compatible and / or possibly cationic surfactant are preferably used or, in a particular embodiment of the invention, cationic surfactants are completely dispensed with.
  • cationic surfactants as well as quaternary ammonium compounds are described. These too may preferably be contained in the agents according to the invention.
  • the moldings according to the invention may contain one or more cationic surfactants, advantageously in amounts, based on the total composition, of from 0 to 30% by weight, more preferably greater than 0 to 20% by weight, preferably from 0.01 to 10% by weight. , in particular 0.1 to 5 wt .-%. Suitable minimum values may also be 0.5, 1, 2 or 3 wt .-%.
  • a molding according to the invention contains cationic surfactants, preferably in amounts of at least 0.1% by weight, based on the total molding.
  • the agent according to the invention is substantially free of cationic surfactant, thus advantageously contains ⁇ 5 wt .-%, preferably ⁇ 1 wt .-%, in particular no cationic surfactant.
  • the shaped bodies according to the invention may also contain amphoteric surfactants. These are described in more detail below, in particular in connection with conditioning agents and plasticizers.
  • the moldings according to the invention may contain one or more amphoteric surfactants, advantageously in amounts, based on the total composition, of from 0 to 30% by weight, more preferably greater than 0 to 20% by weight, preferably from 0.01 to 10% by weight, in particular 0 , 1 to 5 wt.%.
  • the agent according to the invention is substantially free of amphoteric surfactant, thus advantageously contains ⁇ 5 wt .-%, preferably ⁇ 1 wt .-%, in particular no amphoteric surfactant.
  • ingredients of the moldings of the invention may be inorganic and organic builders.
  • Inorganic builders include water-insoluble or non-water-soluble ingredients such as aluminosilicates and especially zeolites.
  • a shaped body according to the invention contains no phosphate.
  • Soluble builders may preferably be used in an amount of from 0.1% by weight to 40% by weight, preferably from 5% by weight to 25% by weight and more preferably from 10% by weight to 20% by weight, based on the total weight of the agent, with sodium carbonate as the soluble builder being particularly preferred.
  • the agent according to the invention contains less than 10% by weight, for example less than 5% by weight, of soluble builder.
  • the agent according to the invention is free of soluble builder.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne un système de distribution de détergents ou de nettoyants, ce système comprenant des détergents ou des nettoyants sous forme de corps façonnés et un contenant de prélèvement. Les corps façonnés sous forme de ruban, de feuille, de disque, de couche, de plaque ou de bande sont particulièrement adaptés au détachage, p. ex. de textiles, mais aussi de surfaces dures. Ces corps façonnés peuvent être utilisés également pour préparer des bains de lavage.

Claims (12)

  1. Système de distribution d'agent de lavage ou de nettoyage, comprenant un corps moulé de lavage ou de nettoyage en forme de ruban, en forme de feuille, en forme de disque, en forme de couche, en forme de plaque ou en forme de bande, qui est constitué par des polymères à concurrence d'au moins 20 % en poids, ainsi qu'une substance possédant un pouvoir de nettoyage, le corps moulé étant procuré dans un récipient de prélèvement, et dans lequel le corps moulé porte, sur une surface, une couche adhésive, qui comprend un polymère qui colle à la température ambiante sous pression et/ou en présence d'humidité.
  2. Système selon la revendication 1, caractérisé en ce que le corps moulé est constitué d'une seule couche ou bien d'un stratifié de plus d'une couche, le corps moulé constitué éventuellement de plusieurs couches étant de préférence enduit.
  3. Système selon la revendication 1 ou 2, caractérisé en ce que le corps moulé comprend une feuille constituée d'une matière de préférence flexible et une substance possédant un pouvoir de nettoyage est appliquée dans la feuille et/ou sous la forme d'une couche sur la feuille.
  4. Système selon l'une quelconque des revendications précédentes 1 à 3, caractérisé en ce que la substance possédant un pouvoir de nettoyage est un agent tensioactif et/ou un agent de blanchiment.
  5. Système selon l'une quelconque des revendications précédentes 1 à 4, caractérisé en ce que la couche adhésive est apte à se disperser dans l'eau ou est soluble dans l'eau.
  6. Système selon l'une quelconque des revendications précédentes 1 à 5, caractérisé en ce qu'une substance possédant un pouvoir de nettoyage est contenue dans la couche adhésive, cette substance étant de préférence dispersée dans le polymère.
  7. Système selon l'une quelconque des revendications précédentes 1 à 6, caractérisé en ce que des constituants d'agents de lavage ou de nettoyage que contient la couche adhésive sont présents sous la forme de liquides visqueux, en particulier sous la forme d'un gel et/ou sous la forme de particules solides.
  8. Système selon l'une quelconque des revendications précédentes 1 à 7, caractérisé en ce que la couche adhésive est munie d'un film de protection solide retirable.
  9. Système selon l'une quelconque des revendications précédentes 1 à 8, caractérisé en ce que le récipient de prélèvement est un récipient flexible ou non flexible, de manière avantageuse qui peut être refermé et qui entoure au moins en partie le corps moulé, de préférence une boîte, un sachet ou une enveloppe, en particulier un distributeur.
  10. Système selon l'une quelconque des revendications précédentes 1 à 9, caractérisé en ce que le récipient de prélèvement comprend un rouleau et représente de préférence un dévidoir de rouleau, le corps moulé étant muni en particulier de lignes de coupe pour le prélèvement par portions.
  11. Procédé pour le traitement local de taches sur des substrats, en particulier sur des textiles ou sur des surfaces dures, dans lequel on prélève un corps moulé à partir d'un système de distribution d'agents de lavage ou de nettoyage conformément à l'une quelconque des revendications précédentes 1 à 10 et on applique par adhérence le corps moulé sur la tache à traiter.
  12. Procédé selon la revendication 11, pour le traitement de taches constituées par des salissures grasses et/ou colorées, les salissures comprenant de préférence :
    - des anthocyanes ;
    - des bétalaïnes, de préférence des bétacyanes, des bétaxanthines, la bétanine, la bétanidine ;
    - des carotinoïdes, de préférence des carotines, des xanthophylles ;
    - des chlorophylles ;
    - des anthranoïdes ;
    - des quinones ;
    - des flavonoïdes ;
    - des colorants à base de curcuma ;
    - l'hémoglobine ;
    - des tanins bruns du thé, de fruits, de vin rouge ;
    - des acides humiques bruns du café, du thé, du cacao ; et/ou
    - des colorants techniques de préférence de cosmétiques, de marqueurs colorés, d'encres.
EP07803452.7A 2006-10-04 2007-09-13 Système de distribution de détergents ou de nettoyants Active EP2069471B2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07803452.7T PL2069471T5 (pl) 2006-10-04 2007-09-13 Układ do przekazywania środków piorących lub czyszczących

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006047229A DE102006047229A1 (de) 2006-10-04 2006-10-04 Wasch- oder Reinigungsmittelabgabesystem
PCT/EP2007/059632 WO2008040619A1 (fr) 2006-10-04 2007-09-13 Système de distribution de détergents ou de nettoyants

Publications (3)

Publication Number Publication Date
EP2069471A1 EP2069471A1 (fr) 2009-06-17
EP2069471B1 true EP2069471B1 (fr) 2012-06-13
EP2069471B2 EP2069471B2 (fr) 2022-08-10

Family

ID=38712602

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07803452.7A Active EP2069471B2 (fr) 2006-10-04 2007-09-13 Système de distribution de détergents ou de nettoyants

Country Status (6)

Country Link
US (2) US20090249558A1 (fr)
EP (1) EP2069471B2 (fr)
DE (1) DE102006047229A1 (fr)
ES (1) ES2387688T5 (fr)
PL (1) PL2069471T5 (fr)
WO (1) WO2008040619A1 (fr)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202009010918U1 (de) * 2009-08-12 2010-05-06 Chen, Li Fester Grundstoff für Pharmazeutika und Kosmetika mit Aminosalzen von natürlichen Fettsäuren
ES2386603T3 (es) * 2009-12-18 2012-08-23 The Procter & Gamble Company Recipiente flexible y elemento de cierre reusable
US8232238B2 (en) * 2010-06-03 2012-07-31 The Clorox Company Concentrated film delivery systems
CN102971126B (zh) 2010-07-02 2016-03-23 宝洁公司 由非织造纤维网制备膜的方法
CN103025929B (zh) 2010-07-02 2015-11-25 宝洁公司 包含活性剂的长丝、非织造纤维网和制备它们的方法
WO2012003365A1 (fr) 2010-07-02 2012-01-05 The Procter & Gamble Company Filaments comprenant un agent actif ingérable, des voiles non tissées, et procédés de fabrication de ces filaments
JP5759544B2 (ja) 2010-07-02 2015-08-05 ザ プロクター アンド ギャンブルカンパニー 活性剤を送達する方法
JP5788503B2 (ja) 2010-07-02 2015-09-30 ザ プロクター アンド ギャンブルカンパニー ウェブ材料及びその製造方法
TWI467011B (zh) * 2012-04-12 2015-01-01 Ses Mild Internat Co Ltd 清潔果凍膠製造方法
JP5800044B2 (ja) * 2014-02-13 2015-10-28 栗田工業株式会社 蒸気発生設備のスケール除去方法及びスケール除去剤
US20170042311A1 (en) 2014-10-21 2017-02-16 The Procter & Gamble Company Method of Improving Skin Appearance
US10633617B2 (en) * 2015-04-23 2020-04-28 The Procter & Gamble Company Detergent compositions
EP3364935B1 (fr) 2015-10-22 2019-11-20 The Procter and Gamble Company Timbre barrière d'un film expansé et procédés pour améliorer l'aspect de la peau
US9872816B2 (en) 2015-10-22 2018-01-23 The Procter & Gamble Company Barrier patch of a foamed film and methods of improving skin appearance
CN108136230B (zh) 2015-10-22 2022-05-13 宝洁公司 发泡膜的阻隔贴片和改善皮肤外观的方法
US20180100123A1 (en) * 2016-10-12 2018-04-12 Mectra Labs, Inc. Cleaning solution
CN110049803B (zh) 2017-01-09 2022-06-07 宝洁公司 具有可溶性膜的阻隔贴片和改善皮肤外观的方法
US10751265B2 (en) 2017-01-09 2020-08-25 The Procter & Gamble Barrier patch with soluble film and methods of improving skin appearance
US10857076B2 (en) 2017-01-09 2020-12-08 The Procter & Gamble Company Barrier patch with soluble film and methods of improving skin appearance
WO2018140675A1 (fr) 2017-01-27 2018-08-02 The Procter & Gamble Company Compositions sous forme de structures solides solubles comprenant des particules agglomérées effervescentes
US10959918B2 (en) 2017-06-22 2021-03-30 The Procter & Gamble Company Films including a water-soluble layer and a vapor-deposited coating
CN111542590A (zh) 2018-01-26 2020-08-14 宝洁公司 包含香料的水溶性单位剂量制品
US11053466B2 (en) 2018-01-26 2021-07-06 The Procter & Gamble Company Water-soluble unit dose articles comprising perfume
WO2019147533A1 (fr) 2018-01-26 2019-08-01 The Procter & Gamble Company Articles en dose unitaire soluble dans l'eau comprenant une enzyme
WO2019168829A1 (fr) 2018-02-27 2019-09-06 The Procter & Gamble Company Produit de consommation comprenant un conditionnement plat contenant des articles de dose unitaire
WO2019183010A1 (fr) 2018-03-19 2019-09-26 The Procter & Gamble Company Procédé de fabrication d'un timbre barrière à film soluble
US10982176B2 (en) 2018-07-27 2021-04-20 The Procter & Gamble Company Process of laundering fabrics using a water-soluble unit dose article
US11666514B2 (en) 2018-09-21 2023-06-06 The Procter & Gamble Company Fibrous structures containing polymer matrix particles with perfume ingredients
CN113748195B (zh) 2019-01-28 2024-01-19 宝洁公司 可回收利用的、可再生的或可生物降解的包装
EP3712237A1 (fr) 2019-03-19 2020-09-23 The Procter & Gamble Company Articles fibreux de dose unitaire soluble dans l'eau comprenant des structures fibreuses solubles dans l'eau
US11312922B2 (en) 2019-04-12 2022-04-26 Ecolab Usa Inc. Antimicrobial multi-purpose cleaner comprising a sulfonic acid-containing surfactant and methods of making and using the same
CA3134222C (fr) 2019-06-28 2024-01-16 The Procter & Gamble Company Articles fibreux solides solubles contenant des tensioactifs anioniques
MX2023001042A (es) 2020-07-31 2023-02-16 Procter & Gamble Bolsa fibrosa soluble en agua que contiene granulos para el cuidado del cabello.
US11542460B2 (en) * 2021-04-14 2023-01-03 Henkel Ag & Co. Kgaa Multi-chamber detergent single dose packs with detachable and reattachable functionality and methods of using the same
KR102665115B1 (ko) * 2023-07-06 2024-05-10 (주)영진 시트형 세탁세제 제조방법

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3695989A (en) 1970-08-12 1972-10-03 Robert E Albert Cold water soluble foam plastic package
EP0217186A1 (fr) 1985-09-12 1987-04-08 S.C. Johnson & Son, Inc. Feuille de polymère pour la délivrance d'additifs de blanchissage et produit de blanchissage ainsi obtenu
EP0356822A2 (fr) 1988-08-22 1990-03-07 Mitsubishi Kasei Vinyl Company Procédé pour produire une pellicule moussée d'alcool de polyvinyle
EP0700989A1 (fr) 1994-09-12 1996-03-13 The Procter & Gamble Company Détergent emballé par dose
EP1048722A1 (fr) 1998-07-23 2000-11-02 Kao Corporation Article de blanchisserie de type voile
US6162458A (en) 1998-11-17 2000-12-19 Nagaoka & Co., Ltd. Patch for beautification
WO2002026896A2 (fr) 2000-09-27 2002-04-04 Unilever Plc Conditionnement soluble dans l'eau et preparation de celui-ci
US20020077266A1 (en) 2000-04-08 2002-06-20 Gabriel Flor Gutierrez Portable stain removal product
JP2002235098A (ja) 2001-02-09 2002-08-23 Kao Corp シート状洗浄剤
US6576604B1 (en) 1999-03-10 2003-06-10 Kao Corporation Adhesive cleaning sheet
WO2003084579A1 (fr) 2002-04-02 2003-10-16 H.H. Brown Shoe Technologies, Inc. Doing Business As Dico Technologies Produits de polyurethane expanse a liberation progressive d'agents et d'additifs
WO2004087857A1 (fr) 2003-04-03 2004-10-14 Reg Macquarrie Compositions filmogenes pour l'application de savons et de detergents
US6926960B1 (en) 1999-11-05 2005-08-09 Kao Corporation Adhesive cleaning sheet

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB899100A (en) * 1958-09-24 1962-06-20 Robert John Anderson Detergent films
US4804705A (en) * 1986-06-02 1989-02-14 Franz Pum Gel composition
JP3126675B2 (ja) * 1997-01-23 2001-01-22 花王株式会社 シート状洗剤
TW399096B (en) * 1996-07-03 2000-07-21 Kao Corp The sheet-like article for laundry
DE10163578A1 (de) * 2001-12-21 2003-07-03 Henkel Kgaa Wäschevorbehandlungsmittel
US6971431B2 (en) * 2003-04-07 2005-12-06 Robert Steinberger Tape dispenser

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3695989A (en) 1970-08-12 1972-10-03 Robert E Albert Cold water soluble foam plastic package
EP0217186A1 (fr) 1985-09-12 1987-04-08 S.C. Johnson & Son, Inc. Feuille de polymère pour la délivrance d'additifs de blanchissage et produit de blanchissage ainsi obtenu
EP0356822A2 (fr) 1988-08-22 1990-03-07 Mitsubishi Kasei Vinyl Company Procédé pour produire une pellicule moussée d'alcool de polyvinyle
EP0700989A1 (fr) 1994-09-12 1996-03-13 The Procter & Gamble Company Détergent emballé par dose
EP1048722A1 (fr) 1998-07-23 2000-11-02 Kao Corporation Article de blanchisserie de type voile
US6162458A (en) 1998-11-17 2000-12-19 Nagaoka & Co., Ltd. Patch for beautification
US6576604B1 (en) 1999-03-10 2003-06-10 Kao Corporation Adhesive cleaning sheet
US6926960B1 (en) 1999-11-05 2005-08-09 Kao Corporation Adhesive cleaning sheet
US20020077266A1 (en) 2000-04-08 2002-06-20 Gabriel Flor Gutierrez Portable stain removal product
WO2002026896A2 (fr) 2000-09-27 2002-04-04 Unilever Plc Conditionnement soluble dans l'eau et preparation de celui-ci
JP2002235098A (ja) 2001-02-09 2002-08-23 Kao Corp シート状洗浄剤
WO2003084579A1 (fr) 2002-04-02 2003-10-16 H.H. Brown Shoe Technologies, Inc. Doing Business As Dico Technologies Produits de polyurethane expanse a liberation progressive d'agents et d'additifs
WO2004087857A1 (fr) 2003-04-03 2004-10-14 Reg Macquarrie Compositions filmogenes pour l'application de savons et de detergents

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Plastics Technology", 00002002, article JAN SCHUT: "Foamed Films as new Niches"

Also Published As

Publication number Publication date
EP2069471B2 (fr) 2022-08-10
EP2069471A1 (fr) 2009-06-17
US20130178407A1 (en) 2013-07-11
WO2008040619A1 (fr) 2008-04-10
DE102006047229A1 (de) 2008-04-10
PL2069471T5 (pl) 2022-12-05
US20090249558A1 (en) 2009-10-08
ES2387688T5 (es) 2022-10-28
ES2387688T3 (es) 2012-09-28
PL2069471T3 (pl) 2012-11-30

Similar Documents

Publication Publication Date Title
EP2069471B1 (fr) Système de distribution de détergents ou de nettoyants
EP1586631B1 (fr) Corps creux compartimentés comprenant une dose d' un produit de lavage, de mnettoyage ou de rincage
EP3181673A1 (fr) Article de dose unitaire soluble dans l'eau
DE102005048182A1 (de) Faserguss-Verpackung mit Innenbeutel
WO2003099985A2 (fr) Tablettes a dosage dans le compartiment a detergent
JPH02163149A (ja) ポリビニルアルコール系フィルム
EP2069468B1 (fr) Système de distribution d'agents odorants
WO2001000781A1 (fr) Emballage-portion de matiere active
WO2001007560A1 (fr) Portion d'agent de lavage ou de nettoyage et emballage pour agent de lavage ou de nettoyage
US20220033602A1 (en) Water-soluble barrier film
DE10003429A1 (de) Wasch- oder Reinigungsmittelportion mit kontrollierter Wirkstofffreisetzung
EP2895588A1 (fr) Détergent liquide structuré à faible teneur en eau contenant des particules
DE10215601A1 (de) Wasserlöslicher Behälter
DE10244802B4 (de) Pralle Waschmittelformkörper
EP1340808B1 (fr) Corps moulés nettoyants parfumés
DE10149718A1 (de) Portionierte Wasch-, Spül-oder Reinigungsmittel in flexiblen wasserlöslichen Behältern
EP1340807B1 (fr) Corps moulés contenant des tensio-actifs ajoutés postérieurement
WO2001029173A1 (fr) Detergents ou nettoyants a base de gaz inerte en portions
DE19957737A1 (de) Verpackte Wasch- und Reinigungsmittel-Portion
DE10244803B4 (de) Geschrumpfte Waschmittelformkörper
WO2003054121A2 (fr) Dose contenant un detergent
DE10305799B4 (de) Verfahren zur Herstellung eines blasgeformten Waschmittelkörpers
DE10149719A1 (de) Kompartiment-Hohlkörper
WO2003044082A1 (fr) Polymeres a solubilite amelioree
WO2001029174A1 (fr) Detergents ou nettoyants en portions contenant un delitant

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20090212

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK RS

17Q First examination report despatched

Effective date: 20100819

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

DAX Request for extension of the european patent (deleted)
GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 562018

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120615

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502007010064

Country of ref document: DE

Effective date: 20120809

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2387688

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20120928

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20120613

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

Effective date: 20120613

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120914

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

REG Reference to a national code

Ref country code: PL

Ref legal event code: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121013

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121015

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

BERE Be: lapsed

Owner name: HENKEL A.G. & CO. KGAA

Effective date: 20120930

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: THE PROCTER & GAMBLE COMMPANY

Effective date: 20130312

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120930

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 502007010064

Country of ref document: DE

Effective date: 20130312

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120930

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120913

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120930

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120913

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120930

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 562018

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120913

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120913

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120913

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMMPANY

Effective date: 20130312

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070913

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20130312

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20130312

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20170519

Year of fee payment: 17

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20130312

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20130312

PLAY Examination report in opposition despatched + time limit

Free format text: ORIGINAL CODE: EPIDOSNORE2

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180913

PLBC Reply to examination report in opposition received

Free format text: ORIGINAL CODE: EPIDOSNORE3

PLAY Examination report in opposition despatched + time limit

Free format text: ORIGINAL CODE: EPIDOSNORE2

PLBC Reply to examination report in opposition received

Free format text: ORIGINAL CODE: EPIDOSNORE3

PLAY Examination report in opposition despatched + time limit

Free format text: ORIGINAL CODE: EPIDOSNORE2

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

27A Patent maintained in amended form

Effective date: 20220810

AK Designated contracting states

Kind code of ref document: B2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: DE

Ref legal event code: R102

Ref document number: 502007010064

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: DC2A

Ref document number: 2387688

Country of ref document: ES

Kind code of ref document: T5

Effective date: 20221028

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230530

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230920

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20230831

Year of fee payment: 17

Ref country code: FR

Payment date: 20230928

Year of fee payment: 17

Ref country code: DE

Payment date: 20230920

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20231123

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20230927

Year of fee payment: 17