Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
  • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
  • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
  • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring

Definitions

• Berries can also affect all green vine parts, shoot tips, tendrils and inflorescences. Berries, for example, turn brown and shrink.
• the fungus Plasmo- para viticola penetrates through the stomata into the tissue of the green Reborgane. The infection then takes place via zoospores floating in a water film. In the vicinity of stomata they settle and form a germ tube. With the help of nutritional organs, the fungus takes valuable food from the host plant.
• solvent mixtures can also be used.
• aromatic solvents eg Solvesso products, xylene
• paraffins eg petroleum fractions
• alcohols eg methanol, butanol, pentanol, benzyl alcohol
• ketones eg cyclohexanone, gamma-butyrolactone
• pyrrolidones NMP, NOP
• Acetates glycols, dimethyl fatty acid amides, fatty acids and fatty acid esters.
• solvent mixtures can also be used
• ground natural minerals eg kaolins, clays, talc, chalk
• ground synthetic minerals eg fumed silica, silicates
• Emulsifiers such as non-ionic and anionic emulsifiers (eg polyoxygenated ethylene fatty alcohol ethers, alkyl sulfonates and arylsulfonates) and dispersants such as lignin-sulphite liquors and methylcellulose.
• Binders can be added to increase adhesion of the active ingredients to the seed after treatment.
• Suitable binders are, for example, EO / PO Block copolymer surfactants, but also polyvinyl alcohols, Ppolyvinylpyrrolidone, polyacrylates, polymethacrylates, polybutenes, polyisobutylenes, polystyrenes, polyethyleneamines, Polyethylenamide, polyethylenimines (Lupasol ®, Polymin ®), polyethers, polyurethanes, polyvinyl acetates, Tylose and copolymers of these polymers.
• carrageen (Satiagel ®).
• a compound I according to the invention 20 parts by weight of a compound I according to the invention are comminuted with the addition of 10 parts by weight of dispersants and wetting agents and 70 parts by weight of water or an organic solvent in a stirred ball mill to give a fine active substance suspension. Dilution in water results in a stable suspension of the active ingredient.
• the active ingredient content in the formulation is 20% by weight.
• a compound I according to the invention 75 parts by weight of a compound I according to the invention are ground in a rotor-stator mill with the addition of 25 parts by weight of dispersing and wetting agents and silica gel. Dilution in water results in a stable dispersion or solution of the active ingredient.
• the active ingredient content of the formulation is 75% by weight.
• a compound I according to the invention are finely ground and combined with 99.5 parts by weight of carriers. Common processes are extrusion, spray drying or fluidized bed. This gives a granulate for direct application with an active ingredient content of 0.5 wt .-%.
• the active compounds may be used as such, in the form of their formulations or the forms of use prepared therefrom, e.g. in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, scattering agents, granules by spraying, misting, dusting, scattering or pouring.
• the forms of application depend entirely on the intended use; In any case, they should ensure the finest possible distribution of the active compounds according to the invention.
• wetting agents To the active ingredients oils of various types, wetting agents, adjuvants, herbicides, fungicides, other pesticides, bactericides, possibly also just immediately before use (tank mix), are added. These agents can be added to the compositions according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.
• organically modified polysiloxanes eg Break Thru S 240 ®
• Alcohol alkoxylates eg. As Atplus 245 ®, Atplus MBA 1303 ®, Plurafac LF 300 ® and Lutensol ON 30 ®
• EO-PO block polymers eg. B. Pluro- nic RPE 2035 ® and Genapol B ®
• Alcohol ethoxylates eg. As Lutensol XP 80 ®
• sodium dioctylsulfosuccinate e. B. Leophen RA ®.
• the application rates are depending on the application pressure and type of effect desired between 1 and 100Og, preferably 20 and 750g active ingredient per ha.
• the fungicidal compositions according to the invention generally contain between 0.1 and 95, preferably between 0.5 and 90 wt. -% of one or more active substances.
• amounts of active ingredient in the seed treatment, in general, amounts of active ingredient of from 1 to 1000 g, preferably from 1 to 200 g, in particular from 5 to 100 g, per kilogram of seed are required.
• the application rate of active ingredient depends on the type of application and the desired effect. Usual application rates in the protection of the material are, for example, from 0.001 g to 2000 g, preferably from 0.005 g to 1000 g of active ingredient per cubic meter of material treated.
• the use of compounds of general formula (I) may also be carried out in combination with other active substances, e.g. with herbicides, insecticides, growth regulators, other fungicides or with fertilizers.
• other active substances e.g. with herbicides, insecticides, growth regulators, other fungicides or with fertilizers.
• Azoxystrobin dimoxystrobin, enestroburine, fluoxastrobin, kresoxim-methyl, metominostrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, orysastrobin, (2-chloro-5- [1- (3-methyl-benzyloxyimino) -ethyl] -benzyl) -carbamic acid methyl ester, (2-Chloro-5- [1- (6-methylpyridin-2-ylmethoxyimino) ethyl] benzyl) -carbamic acid methyl ester, 2- (ortho- (2,5-dimethylphenyl-oxymethylene) -phenyl) -3- methoxy-methyl acrylate;
• bitertanol bromuconazoles, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fenbuconazole, flusilazole, fluquinconazole, flutriol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, tebuconazole, tetraconazo - Ie, triadimenol, triadimefon, triticonazole;
• - imidazoles cyazofamide, imazalil, pefurazoate, prochloraz, triflumizole;
• Benzimidazoles benomyl, carbendazim, fuberidazole, thiabendazole; - Other: Ethaboxam, Etridiazole, Hymexazole;
• Pyridines fluazinam, pyrifenox, 3- [5- (4-chlorophenyl) -2,3-dimethylisoxazolidin-3-yl] pyridine; Pyrimidines: bupirimate, cyprodinil, ferimzone, fenarimol, mepanipyrim, nuarimol, pyrimethanil;
• Morpholines aldimorph, dodemorph, fenpropimorph, tridemorph;
• Dicarboximides iprodione, procymidone, vinclozolin;
• acibenzolar-S-methyl anilazine, captan, captafol, dazomet, diclomethine, fenoxanil, folpet, fenpropidin, famoxadone, fenamidone, octhilinone, probenazole, proquinazide, pyroquilon, quinoxyfen, tricyclazole, 5-chloro-7- ( 4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazolo [1,5-a] pyrimidine, 2-butoxy-6- iodo-3-propyl-chromen-4-one, 3- (3-bromo-6-fluoro-2-methylindol-1-sulfonyl) - [1, 2,4] triazole-1-sulfonic acid dimethylamide;
• guanidines dodine, iminoctadine, guazatine
• Organometallic compounds fentin salts
• Sulfur-containing heterocyclyl compounds isoprothiolanes, dithianone
• Organophosphorus compounds edifenphos, fosetyl, fosetyl-aluminum, Iprobenfos, pyrazophos, tolclofos-methyl, phosphorous acid and their salts;
• Organochlorine compounds thiophanates methyl, chlorothalonil, dichlofluanid, toiylfluanid, flusulphamides, phthalides, hexachlorobenzene, pencycuron, quintozene; Nitrophenyl derivatives: binapacryl, dinocap, dinobuton;
• alkyl also includes octyl, decyl, tetradecyl and
• Guazatine mixture of the reaction products obtained from the amidation of technical lminodi (octamethylene) diamine containing various guanidines and polyamines [CAS RN 108173-90-6];
• Spiroxamine (8-tert-butyl-1,4-dioxaspiro [4.5] dec-2-yl) diethylamine (EP-A 281 842); Tridemorph, 2,6-dimethyl-4-tridecylmorpholine (DE-A 1 164 152);
• Cycloheximide 4 - ⁇ (2R) -2 - [(1S, 3S, 5S) -3,5-dimethyl-2-oxocyclohexyl] -2-hydroxyethyl ⁇ piperidine-2,6-dione [CAS RN 66- 81-9]; Griseofulvin, 7-chloro-2 ', 4,6-trimethoxy-6'-methylspiro [benzofuran-2 (3H), 1'-cyclohex-2'-ene] -3,4'-dione [CAS RN 126-07 -8th];
• Enilconazole (imazalil), 1 - [2- (2,4-dichlorophenyl) -2- (2-propenyloxy) ethyl] -1H-imidazole (Fruits 28, p. 545, 1973);
• Penconazole 1- [2- (2,4-dichlorophenyl) pentyl] -1 H- [1,2,4] triazole (Pesticide Manual, 12.
• Prothioconazole 2- [2- (1-chlorocyclopropyl) -3- (2-chlorophenyl) -2-hydroxypropyl] -2,4-dihydro- [1,2,4] triazole-3-thione (WO 96/16048) ; Simeconazole, ⁇ - (4-fluorophenyl) - ⁇ - [(trimethylsilyl) methyl] -1H-1,2,4-triazole-1-ethanol
• Triticonazole (5 lbs) -5 - [(4-chlorophenyl) methylene] -2,2-dimethyl-1- (1 H -1, 2,4-triazol-1-ylmethyl) cyclopentanol (FR 26 41 277);
• Maneb manganese ethylene bis (dithiocarbamate) (US 2 504 404); Mancozeb, manganese ethylene bis (dithiocarbamate) polymer complex zinc salt
• Metiram zinc ammonium ethylenebis (dithiocarbamate) (U.S. 3,248,400);
• Propineb, zinc propylene bis (dithiocarbamate) polymer (BE 611 960);
• Zineb zinc ethylene bis (dithiocarbamate) (US 2 457 674);
• Oxycarboxine, 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide 4,4-dioxide (US 3,399,214);
• Famoxadone (/? S) -3-anilino-5-methyl-5- (4-phenoxyphenyl) -1,3-oxazolidine-2,4-dione [CAS RN 131807-57-3];
• Furametpyr 5-Chloro- ⁇ / - (1,3-dihydro-1,1,3-trimethyl-4-isobenzofuranyl) -1,3-dimethyl-1H-pyrazole-4-carboxamide [CAS RN 123572-88- 3];
• Copper oxychloride Cu 2 Cl (OH) 3 [CAS RN 1332-40-7]; Basic copper sulfate, CuSO 4 [CAS RN 1344-73-6];
• Propylpentyl is (US 2 526 660); Dinobutone, (RS) -2-sec-butyl-4,6-dinitrophenyl isopropyl carbonate [CAS RN 973-21-7];
• Nitrothal isopropyl, diisopropyl 5-nitroisophthalate Proc. Br. Insectic. Fungic. Conf.
• Chlorothalonil, 2,4,5,6-tetrachloroisophthalonitrile (US 3,290,353);
• Metrafenone 3'-bromo-2,3,4,6'-tetramethoxy-2 ', 6-dimethylbenzophenone (U.S. 5,945,567); Pencycuron, 1- (4-chlorobenzyl) -1-cyclopentyl-3-phenylurea (DE-A 27 32 257);
• Phthalide (DE-A 16 43 347); Toloclofos-methyl, O-2,6-dichloro-p-tolyl 0,0-dimethyl phosphorothioate (GB 14 67 561);
• Picoxystrobin 3-methoxy-2- [2- (6-trifluoromethyl-pyridin-2-yloxymethyl) -phenyl] -acrylic acid methyl ester (EP-A 278 595);
• Pyraclostrobin N- ⁇ 2- [1- (4-chlorophenyl) -1H-pyrazol-3-yloxymethyl] phenyl ⁇ (N-methoxy) carbamic acid methyl ester (WO 96/01256); Trifloxystrobin, (E) -methoxyimino- ⁇ (E) - ⁇ - [1- ( ⁇ , ⁇ , ⁇ -trifluoro-m-tolyl) ethylideneaminooxy] -o-tolyl ⁇ -acetic acid methyl ester (EP-A 460 575);
• the compounds of general formula (I) may be used with said other fungicides together in generally conventional formulations, e.g. as solutions, emulsions, suspensions, dusts, powders, pastes and granules.
• formulations are prepared by known methods.
• the formulations generally contain between 0.01 and 95% by weight, preferably between 0.1 and 90% by weight of active ingredients.
• the active compound concentrations in the ready-to-use preparations can be varied within wide ranges. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%.
• the active ingredient can also be used with great success in the ultra-low-volume (ULV) process, it being possible to apply formulations containing more than 95% by weight of active ingredient or even the active ingredient without additives.
• UUV ultra-low-volume
• Stock solution A was prepared from dimethomorph ((E, Z) -4- [3- (4-chlorophenyl) -3- (3,4-dimethoxyphenyl) acryloy] morpholine) at 150 g / l as dispersible concentrate (d.c.).
• Stock B was prepared from mandipropamide ((RS) -2- (4-chlorophenyl) -N- [3-methoxy-4- (prop-2-ynyloxy) phenethyl] -2- (prop-2-ynyloxy) acetamide) 40g / l emulsifiable concentrate (ec) produced.
• Stock solution C was prepared from iprovalicarb
• the fungicidal active ingredients described in Example 1 are applied both one day before the treatment with the harmful fungi (preventive treatment) and in each case one day after the treatment with the harmful fungi (curative treatment). After treatment with the harmful fungi, the plants are allowed to stand at 95% humidity and a temperature of 18 ° C overnight. This is followed by an observation phase for 6 days and a final evaluation on the 6th day, the test plants are exposed to daylight for 12 hours each and left in the dark for 12 hours.
• the undersides of the vine leaves are sprayed with water for 24 hours before the end of the evaluation and allowed to stand.
• the evaluation of the experiments is carried out by a determination of the percentage of diseased leaf area of each plant.
• a high percentage value means a high degree of harmful fungus disease
• a low percentage value means a low level of harmful fungus disease.
• a curative treatment resulted in an attack of 65% of the leaf area for the resistant fungi and an infestation of 0% for the sensitive fungi.
• the preventive treatment resulted in an attack of 8% of the leaf area for the resistant fungi and an infestation of 0% of the leaf area for the sensitive fungi.
• curative treatment resulted in an attack of 75% of the resistant fungi and an infestation of 0% in the sensitive fungi.
• Preventive treatment resulted in an attack of 70% of the area for the resistant fungi and an attack of 0% of the surface for the sensitive fungi.
• curative treatment resulted in an attack of 70% of the area for the resistant fungi and an infestation of 0% for the sensitive fungi.
• Preventive treatment resulted in an attack of 55% of the surface area for the resistant fungi and an infestation of 0% of the surface area for the sensitive fungi.

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• Life Sciences & Earth Sciences (AREA)
• Agronomy & Crop Science (AREA)
• Pest Control & Pesticides (AREA)
• Plant Pathology (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Dentistry (AREA)
• General Health & Medical Sciences (AREA)
• Wood Science & Technology (AREA)
• Zoology (AREA)
• Environmental Sciences (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
• Pretreatment Of Seeds And Plants (AREA)

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• 2007
  • 2007-08-24 CA CA002657361A patent/CA2657361A1/en not_active Abandoned
  • 2007-08-24 MX MX2009001086A patent/MX2009001086A/es not_active Application Discontinuation
  • 2007-08-24 BR BRPI0714658-2A patent/BRPI0714658A2/pt not_active IP Right Cessation
  • 2007-08-24 WO PCT/EP2007/058807 patent/WO2008025732A1/de active Application Filing
  • 2007-08-24 US US12/438,963 patent/US20100210652A1/en not_active Abandoned
  • 2007-08-24 AU AU2007291351A patent/AU2007291351A1/en not_active Abandoned
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  • 2007-08-24 EP EP07802856A patent/EP2066175A1/de not_active Withdrawn
  • 2007-08-24 CN CNA200780032078XA patent/CN101511182A/zh active Pending
  • 2007-08-24 KR KR1020097006269A patent/KR20090045401A/ko not_active Application Discontinuation
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  • 2007-08-27 AR ARP070103800A patent/AR062554A1/es not_active Application Discontinuation
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  • 2009-03-11 CR CR10659A patent/CR10659A/es not_active Application Discontinuation
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