EP2047012A1 - Device for the surface treatment of a workpiece - Google Patents
Device for the surface treatment of a workpieceInfo
- Publication number
- EP2047012A1 EP2047012A1 EP07725415A EP07725415A EP2047012A1 EP 2047012 A1 EP2047012 A1 EP 2047012A1 EP 07725415 A EP07725415 A EP 07725415A EP 07725415 A EP07725415 A EP 07725415A EP 2047012 A1 EP2047012 A1 EP 2047012A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- workpiece
- surface treatment
- space
- jacket
- section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/04—Tubes; Rings; Hollow bodies
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
- C25D17/12—Shape or form
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/08—Electroplating with moving electrolyte e.g. jet electroplating
Definitions
- the invention relates to a device for surface treatment of a workpiece, according to the preamble of claim 1.
- a metallic coating is applied to a surface of a workpiece by means of a chemical or electrochemical reaction.
- the metallic coating is used to refine the surface of the workpiece, for example with regard to hardness, electrical conductivity, corrosion protection, catalytic properties, optical properties.
- the workpiece In electrochemical plating, the workpiece is placed in an electrolytic bath in which a consumable electrode consisting of the material required for the coating is immersed. By applying a DC voltage tion between the workpiece and the consumable electrode, the latter is removed and the coating is built up on the workpiece. The electric current dissolves metal ions from the consumable electrode and stores them by reduction on the workpiece. Thus, the object to be refined is uniformly coated on all sides. The longer the workpiece is in the bath, the thicker the coating becomes.
- the process of chemical electroplating basically proceeds identically, but uses the potential difference between the workpiece and the coating material typically dissolved in the bath, which is predetermined by the electronegativity of the chemical elements.
- the workpiece is subjected to a multitude of other preparatory and after-treatment surface treatments.
- the workpiece must be cleaned before coating, since the quality of the surface that can be produced by electroplating very much depends on the quality of the surface of the workpiece to be coated.
- the cleaning is done by degreasing and rinsing the surface of the still uncoated workpiece.
- the material of a workpiece to be coated by electroplating is all electrically conductive materials. Non-conductive materials must first be coated with a conductive layer, for example of a silver conductive ink. This process is also known as activation. After coating, the coated surface must first be cleaned of still adhering electrolyte, and then dried.
- galvanic systems consist of a very long series of tanks, in which the various surface treatments or process steps take place successively.
- the tanks are each equipped with a surface treatment required filled liquid.
- a workpiece must be transported from one tub to the other for each process step.
- the process results are not always satisfactory because the quality of the coating, for example, suffers from local heating during the application of the coating. Likewise, it can not be ensured with the known devices that the coating has a uniform thickness.
- the surface treatment is a galvanic metal deposition.
- the device comprises a container which is formed by a jacket which encloses a region which is complementary to a cross-section of the workpiece and is traversed by an electrolyte.
- the workpiece is guided by inlet and outlet nozzles delimiting the container on both sides and can be moved through the container in a continuous process.
- the workpiece and container are not in direct contact, so that the inner dimensions of the container in the cross-sectional direction are slightly larger than the outer dimensions of the workpiece. In such a device, the workpiece must be transported adversely for each surface treatment required to produce a coating.
- US 5,277,785 discloses an apparatus for surface treatment of a metallic workpiece by electroplating.
- the device has a jacket which is complementary to a cross-section of the workpiece and accommodates a part of the workpiece to be subjected to a surface treatment and which can be filled with an electrolyte required as a medium for surface treatment.
- the jacket consists of a plastic tube with lead anode arranged therein, as well as a felt filament arranged inside the anode. rial.
- the jacket is spaced apart from the workpiece by a gap, ie it has internal dimensions which are uniformly slightly larger in the cross-sectional direction than the external dimensions of the cross section of the workpiece.
- a brush material is arranged, which holds the guided through a supply line into the gap electrolyte between the workpiece and the anode.
- the workpiece may rotate about its longitudinal axis during surface treatment in the device.
- Fresh electrolyte can be continuously fed to the gap and spent again be discharged. Again, the workpiece must be transported unfavorably for each surface treatment required to produce a coating.
- JP 60056087 A discloses a device for surface treatment of a workpiece.
- the device has a jacket which is complementary to a cross-section of the workpiece and receives the workpiece to be subjected to a surface treatment and which can be filled with an electrolyte.
- the inside dimensions of the space are slightly larger in the cross-sectional direction than the outside dimensions of the workpiece.
- the mantle consists of two semi-cylindrical inner surfaces which simultaneously serve as electrodes.
- the workpiece forms the counter electrode. Two holders seal the room from the environment. At the same time you hold the workpiece in the room.
- the electrolyte in the room is continuously exchanged. This has the disadvantage that the workpiece has to be transported further for each individual surface treatment required to produce a coating.
- JP 60033383 A discloses a device for surface treatment of a workpiece.
- the device has a jacket which is complementary to a cross-section of the workpiece and accommodates the workpiece to be subjected to a surface treatment and which can be filled with an electrolyte.
- the internal dimensions of the room are small in the cross-sectional direction. gradually larger than the outer dimensions of the workpiece.
- the jacket consists of a non-conductive cylinder and a pair of frontally projecting into the cylinder holders, which also serve as electrodes. The holders close the room. At the same time you hold the workpiece in the room.
- the electrolyte in the room is continuously exchanged.
- the disadvantage is that here too the workpiece has to be transported further for each individual surface treatment required to produce a coating.
- JP 57143488 A discloses a device for surface treatment of a workpiece.
- the device has a jacket which is complementary to a cross-section of the workpiece and receives the workpiece to be subjected to a surface treatment and which can be filled with an electrolyte.
- the inside dimensions of the space are slightly larger in the cross-sectional direction than the outside dimensions of the workpiece.
- the jacket consists of a hollow cylindrical anode and an end piece.
- the workpiece forms the cathode.
- Two holders seal the room from the environment. At the same time you hold the workpiece in the room.
- the electrolyte is continuously exchanged in the room.
- the device has a jacket which is complementary to a cross-section of the workpiece and receives the workpiece to be subjected to a surface treatment and which can be filled with an electrolyte.
- the internal dimensions of the space are slightly larger in the cross-sectional direction than the outer dimensions of the workpiece.
- the jacket consists of a hollow cylindrical anode.
- the workpiece contacted via a holder serving as a cathode forms the cathode.
- Two holders seal the room from the environment. At the same time you hold the workpiece in the room.
- the electrolyte is continuously exchanged in the room. Even with the two latter devices, the workpiece must be transported disadvantageously for each surface treatment required to produce a coating.
- An object of the invention is to provide a device for surface treatment of a workpiece.
- a device for the surface treatment of a workpiece in particular electroplating, cleaning and the like, accordingly comprises a jacket which accommodates at least a part of the workpiece to be subjected to a surface treatment and which has a medium required for a surface treatment, for example a galvanizing agent, detergent or the like fillable space wrapped.
- the inner dimensions of the shell are equally greater in all directions, preferably 0.001 to 10 mm larger than the outer dimensions of the corresponding cross-section of the workpiece.
- the invention in the space which can be filled by the jacket and filled with a medium which is required for the surface treatment, at least during a first surface treatment of the workpiece, there is negative pressure relative to the environment, whereby escape of the normally harmful and especially during application of a coating used media and of resulting vapors and the like from the room into the environment during the surface treatment is prevented.
- the generation of negative pressure in the room can be done, for example, most simply by the fact that liquid media by means of a vacuum source, such as a self-priming pump are sucked through the device according to the invention. This creates a negative pressure in the room.
- a second surface treatment preferably by introducing superheated steam into the space for cleaning the workpiece, there is overpressure to the environment, thereby ensuring highly efficient, simultaneous drying and rinsing of the surface to be treated with minimal water consumption is.
- higher temperatures can be applied for cleaning with superheated steam, with any escape of the superheated steam from the space that occurs possibly having no harmful influence on the environment.
- the introduction of the superheated steam is preferably carried out via a separate supply and removal.
- the use of superheated steam for cleaning has the advantage over the liquids conventionally used that subsequent drying of the workpiece takes place automatically by the heat energy stored in the material and removed from the superheated steam. This represents a considerable simplification of the gelation process.
- the distance between the workpiece and the jacket is substantially the same at all points. Due to the uniform spacing, a uniform thickness of the coating during galvanizing is ensured in the device according to the invention. Due to the complementary shape and thus uniformly small distance between the shell and the workpiece, an acceleration of the coating process is also achieved.
- the workpiece to be coated is, for example, a pipe, a cylindrical piston with an end-side recess, or an otherwise shaped workpiece having a cavity accessible through an opening
- an external and internal coating of the workpiece can be carried out simultaneously. be led, provided that the device covers the opening to the cavity, or enclosing the entire workpiece.
- An advantageous embodiment of the invention provides that the sheath enclosing the at least one cross-section of the workpiece enveloping envelope encloses only a portion of the workpiece in the direction of a perpendicular to the cross-section longitudinal axis of the workpiece, as well as means for sealing between shell and workpiece remaining Columns to the environment features.
- This particular embodiment of the device according to the invention makes it possible to specifically subject individual areas to a surface treatment, for example sections along the longitudinal axis of the workpiece. It is also conceivable to repair or repair individual points or areas of a workpiece previously subjected to a surface treatment by means of the device according to the invention.
- such a device according to the invention comprises means for displacing the jacket which encloses the space complementary to at least one cross section of the workpiece in the direction of the longitudinal axis of the workpiece.
- the coat points here Preferably, substantially in the form of a top and bottom open, one to a suitable cross section of the workpiece complementary cross-section having ring.
- a suitable cross-section is to be regarded as such a cross-section which, apart from, for example, section-wise tapers, recesses and the like, is preferably substantially constant along an axis of the workpiece.
- the ring has peripheral edges, lips or the like projecting inwards in the direction of a workpiece to be wrapped.
- the space enclosed by the jacket is complementary to the entire outer shape of the workpiece to be subjected to a surface treatment, wherein the inner dimensions of the jacket are equally small in all directions, preferably by 0.001 to 10 mm, as the outer dimensions of the workpiece.
- the shell forms a closed example at its bottom and open at its top, with a surface treatment required medium, for example, with galvanizing agents, cleaning agents and the like fillable and closable against the environment container into which the workpiece, for example, from above can be introduced.
- the container is preferably hermetically sealed during the surface treatment of the workpiece.
- An additional advantageous embodiment of the invention provides that for electroplating the workpiece, the jacket is electrically contactable as an electrode.
- the jacket is for this purpose preferably made of an electrochemically stable, electrically conductive material.
- the device comprises means for supplying and discharging different media into the room while different rather surface treatments.
- Suitable means include, for example, a preferably automatically actuated distributor slide.
- the media used for different surface treatments are added and removed separately from each other.
- the separate supply and discharge can be carried out in sections by 5 common supply and discharge lines in and out of the space enclosed by the jacket. It is also conceivable to provide for the different media each have their own supply and discharge lines in and out of the room. This ensures that the device works wastewater-free and as a closed system.
- the device equipped with means for supplying and removing different media into the room during different surface treatments can be automated.
- FIG. 1 is a schematic representation of a device according to the invention in cross section
- Fig. 2 is a schematic representation of a device comprising several devices according to the invention for performing surface treatments of workpieces
- FIG. 3 shows a detailed view of a jacket of the device from FIG. 1 which covers a tubular workpiece to be coated and is designed as a metal tube.
- a device 20 for the surface treatment of a workpiece 1 shown in FIG. 1 essentially comprises a jacket, which is designed, for example, as a metal tube 2.
- the metal tube 2 encloses a space 17 which is complementary to at least one cross-section of the workpiece 1 and accommodates at least a portion of the workpiece 1 to be subjected to a surface treatment.
- the internal dimensions of the metal tube 2 are equally preferably 0.001 in all directions to 10 mm larger than the outer dimensions of the corresponding cross section of the workpiece 1.
- a core of the device 20 according to the invention is the electrode 9 designed as an anode or cathode. It comprises the metal tube 2 forming the jacket, which is electrochemically resistant.
- a non-metallic guide sleeve 4 is inserted, which is used for centering the workpiece 1 and the lower limit of that portion of the workpiece 1 is used, on which a coating is to be applied.
- An upper boundary is formed by the upper edge of the metal tube 2 serving as the electrode 9.
- a baffle plate 13 which distributes, for example, the superheated steam used for rinsing after the coating from the input 10 into the gap 3 between the electrode 9 and the workpiece 1.
- Above the seal 8 is arranged. The seal can be actuated by compressed air and closes the space 17 of the device according to the invention with respect to the environment.
- the seal 8 is placed in its structural arrangement so that it lies outside the sphere of influence of the aggressive media used.
- the electrode 9 is clamped between plates 15, 16. Circumferential seals 14 ensure sealing of the space 17 from the environment.
- the liquid 3 is supplied to the gap 3 between the electrode 9 and the workpiece 1 via the input 5.
- the respective medium is distributed from the inlet 5 in the gap 3 remaining from the space 17 with the workpiece 1 located therein at a very high flow speed from below up.
- the medium used in each case flows with the space 17 or the gap 3 connected via a connecting channel 7 into an annular channel 11 and is sucked off via an outlet 6.
- the device 20 according to the invention is applicable in connection with cylindrical workpieces.
- the device 20 according to the invention allows automatic high-speed coating of cylindrical surfaces or workpieces.
- the term automatic coating refers to the fact that the workpiece 1 after its mechanical production, ie the production of its outer Form by milling, turning, grinding, honing, polishing or the like, is inserted manually or by means of an auxiliary device in a device 20 according to the invention.
- an automated process takes place, in which first the workpiece 1 is clamped by the clamping of a seal 8 and the metal tube 2 enveloped, the workpiece 1 at least partially receiving, located in the device 20 space 17 is sealed against the environment. Then, the workpiece 1 is electrically contacted. Subsequently, the surface treatments by degreasing, rinsing, activating, and then the surface treatment of the coating itself are carried out by plating-preparing surface treatments. For this purpose, a medium required for the respective process step is supplied to the space 17 in each case. Liquid media required for this purpose flow via a connection 5 into the space 17, are distributed over the gap 17 remaining from the workpiece 1 in a ring channel 11 serving as a return space, and flow off again via a line 12 serving as outlet 6.
- the liquid media are sucked off at the line 12 serving as outlet 6.
- the line 12 serving as outlet 6 there is negative pressure in the entire device 20 with respect to the environment.
- none of the liquid media can splash out at a leak.
- gap 3 between anode and cathode, ie between electrode 9 and workpiece 1 very high flow velocities of the liquid media used are achieved, through which the gas bubbles produced during the entire electrolysis process are already entrained during their formation.
- the gas discharges can be separated in a separate, separate from the space 17 gas separator.
- the workpiece 1 is rinsed by introducing superheated superheated steam through the inlet 10 into the space 3 of adhering electrolyte and dried.
- the workpiece can then be coated, cleaned and removed from the device 20.
- the electrical contact is released and the seal 8 is opened.
- the coated workpiece 1 can be removed from the device 20 manually or by means of an auxiliary device.
- An installation AV shown in FIG. 2 and comprising a plurality of apparatuses according to the invention designated here as cells A, B, C comprises a distribution system which has a plurality of tanks I 1 II, III, IV, V for storage for the individual Process steps, ie surface treatments, required media contains.
- the distributor system comprises a preferably automatically actuated distributor slide V1, which assigns the required medium to the respectively running process step.
- the respective medium is drawn in through the individual cells A, B, C via an intake line AS and via a second distributor rail. via V2, after passing through the space under negative pressure relative to the environment, back into the corresponding tank I, II, IM, IV 1 V.
- the system AV according to the invention preferably comprises one or more current sources for the individual cells A, B, C with which an exact dimensional accuracy and quality of the thickness of the coating is achieved.
- the workpieces subjected to a surface treatment in cells A, B, C can be removed in a coated, rinsed and dried state.
- the device according to the invention can be integrated into a production line and can be fully automated.
- the device according to the invention comprises or is part of a system which is tightly sealed with all the media required for all process steps occurring during electroplating, such as, for example, pickle, electrolyte, rinsing water, superheated steam, and is supplied with power.
- a very high current efficiency and thus a high deposition rate combined with a short process time is achieved in the coating step.
- the workpiece 1 to be coated by means of a device 20, as shown in FIG. 3, is a tube 22, a cylindrical piston with an end-side recess or an otherwise shaped workpiece with a cavity 19 accessible through at least one opening 18,
- an outer and inner coating of the workpiece 1 can be carried out by the executed here as a metal tube 2 jacket of the device 20, the opening 18 to the cavity 19 out, or covers the entire workpiece 1.
- the workpiece leaves the device according to the invention cleaned and dried.
- a higher surface quality can be achieved than in the prior art.
- the condensate which optionally drips off after cleaning with superheated steam, can be collected in a disposal tank or returned to the process as needed.
- overpressure relative to the environment prevails in the space enclosed by the jacket, at least during final cleaning.
- the device according to the invention can also be embodied such that the space receiving the workpiece is formed by a ring which is complementary to a cross-section of the workpiece and which is drawn over a cross-section of the workpiece.
- the ring is open on both sides. Sealing lips or otherwise adjustable seals close off the annular gaps on both sides between the ring and the workpiece.
- the ring can be displaced with respect to the longitudinal axis of the workpiece, for example by means of a motor, so as to coat in sections the entire surface of the workpiece, or only parts of the surface.
- the invention is particularly applicable in the field of surface treatment of workpieces, such as in electroplating, as well as in the manufacture of devices and equipment for surface treatment. LIST OF REFERENCE NUMBERS
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006034277A DE102006034277A1 (en) | 2006-07-21 | 2006-07-21 | Device for the surface treatment of a workpiece |
PCT/EP2007/004509 WO2008009325A1 (en) | 2006-07-21 | 2007-05-22 | Device for the surface treatment of a workpiece |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2047012A1 true EP2047012A1 (en) | 2009-04-15 |
EP2047012B1 EP2047012B1 (en) | 2017-07-12 |
Family
ID=38353754
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07725415.9A Active EP2047012B1 (en) | 2006-07-21 | 2007-05-22 | Process for the surface treatment of a workpiece |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2047012B1 (en) |
DE (1) | DE102006034277A1 (en) |
WO (1) | WO2008009325A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113477606A (en) * | 2021-06-29 | 2021-10-08 | 中船黄埔文冲船舶有限公司 | Method for removing paint of ship structure |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015106432A1 (en) * | 2015-04-27 | 2016-10-27 | Gramm Technik Gmbh | Method and device for producing a workpiece |
DE102018110905A1 (en) | 2018-05-07 | 2019-11-07 | Lucas Automotive Gmbh | Electrode for an anodizing process |
AT522169B1 (en) * | 2019-10-16 | 2020-09-15 | Ess Holding Gmbh | Device for the surface treatment of a workpiece in a production line |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1801128A1 (en) * | 1968-10-04 | 1970-05-21 | Walter Hunger | Continuous pass-through electroplating system for long shafts or profiles |
JPS51119333A (en) * | 1975-04-14 | 1976-10-19 | Taisei Corp | Method of vertical alignment |
JPS56142891A (en) * | 1980-04-05 | 1981-11-07 | Kawasaki Steel Corp | High speed plating method in electroplating of radial cell system |
JPS57143487A (en) * | 1981-03-03 | 1982-09-04 | Yamaha Motor Co Ltd | High speed plating device |
JPS57143488A (en) * | 1981-03-03 | 1982-09-04 | Yamaha Motor Co Ltd | High speed plating device |
JPS6033383A (en) * | 1983-08-03 | 1985-02-20 | Toyota Motor Corp | Method and apparatus for high speed plating |
JPS6056087A (en) * | 1983-09-02 | 1985-04-01 | Chuo Seisakusho:Kk | High-speed plating device |
JPS61106791A (en) * | 1984-10-31 | 1986-05-24 | Kooken:Kk | High speed plating method |
JPS63267117A (en) * | 1987-04-21 | 1988-11-04 | Stanley Electric Co Ltd | Electrolytic finisher for cylindrical metal material |
US4853099A (en) * | 1988-03-28 | 1989-08-01 | Sifco Industries, Inc. | Selective electroplating apparatus |
US5277785A (en) * | 1992-07-16 | 1994-01-11 | Anglen Erik S Van | Method and apparatus for depositing hard chrome coatings by brush plating |
JP2001200391A (en) * | 2000-01-19 | 2001-07-24 | Suzuki Motor Corp | Plating pretreatment device |
DE10140934A1 (en) * | 2001-08-10 | 2003-02-20 | Gramm Gmbh & Co Kg | Device for galvanically surface treating workpieces comprises a process chamber having feed openings for introducing process liquid and waste openings for removing process liquid arranged in groups at a distance from the surface |
DE10347991A1 (en) * | 2003-10-15 | 2005-05-12 | Metallglanz Gmbh | Reaction container for continuous high rate electrodeposition of metal layers onto a metal body useful in deposition of platinum, oxide or mixed oxide layers |
RU2258771C1 (en) * | 2003-11-28 | 2005-08-20 | Никифоров Алексей Александрович | Device for oxidation of inner surfaces of hollow cylindrical items |
JP4391893B2 (en) * | 2004-06-16 | 2009-12-24 | 本田技研工業株式会社 | Plating equipment |
JP4391894B2 (en) * | 2004-06-16 | 2009-12-24 | 本田技研工業株式会社 | Plating equipment |
-
2006
- 2006-07-21 DE DE102006034277A patent/DE102006034277A1/en not_active Withdrawn
-
2007
- 2007-05-22 EP EP07725415.9A patent/EP2047012B1/en active Active
- 2007-05-22 WO PCT/EP2007/004509 patent/WO2008009325A1/en active Application Filing
Non-Patent Citations (1)
Title |
---|
See references of WO2008009325A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113477606A (en) * | 2021-06-29 | 2021-10-08 | 中船黄埔文冲船舶有限公司 | Method for removing paint of ship structure |
Also Published As
Publication number | Publication date |
---|---|
DE102006034277A1 (en) | 2008-01-24 |
WO2008009325A1 (en) | 2008-01-24 |
EP2047012B1 (en) | 2017-07-12 |
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